EP1220610A4 - Composition herbicide et adjuvant - Google Patents
Composition herbicide et adjuvantInfo
- Publication number
- EP1220610A4 EP1220610A4 EP00913957A EP00913957A EP1220610A4 EP 1220610 A4 EP1220610 A4 EP 1220610A4 EP 00913957 A EP00913957 A EP 00913957A EP 00913957 A EP00913957 A EP 00913957A EP 1220610 A4 EP1220610 A4 EP 1220610A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- glyphosate
- composition according
- herbicidal composition
- salt
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
Definitions
- the present invention relates to a herbicidal composition and in particular a composition containing the herbicide glyphosate.
- N-phosphonomethylglycine known by its common name glyphosate, is a well known broad spectrum herbicide which is widely used in domestic and broadacre weed control.
- Glyphosate is a water insoluble acid and is therefore formulated as a water soluble salt, generally the isopropylamine salt.
- Glyphosate is sold and used in a range of formulation types.
- the manufacturers of glyphosate generally prepare it for transport and shipping as an aqueous concentrate from which commercial products can readily be prepared by dilution and in some cases the addition of additives.
- Glyphosate may be formulated for sale as an aqueous concentrate which is diluted by the end user prior to application. Concentrates may be packaged with surfactants and may be used with adjuvants which are mixed with the herbicide in a spray tank before use. Glyphosate is also sold to domestic markets as a dilute solution packaged with a spray applicator ready for direct application to weeds. Water soluble granules or powders are also available which contain a glyphosate salt and generally also a surfactant. These dry formulations are dissolved in water by the end user before application.
- compositions are stable at a wide range of concentrations. For example, the viscosity of aqueous solutions is reduced allowing the composition to be more easily dispensed or allowing the concentration to be significantly increased while remaining stable. This finding was surprising as the ammonium salt of glyphosate is much less soluble than the isopropylamine salt.
- the compositions of the invention also generally exhibit good compatibility with other pesticides.
- a glyphosate composition including the monoisopropylamine salt of glyphosate and the ammonium salt of glyphosate.
- the ratio of said monoisopropylamine salt to said ammonium salt is typically in the range of from 80:20 to 97:3 based on the weight of glyphosate in the acid form. In this ratio of salt the composition is surprisingly versatile allowing extremely high concentrations to be handled more easily and with enhanced stability.
- the weight ratio of said monoisopropylamine salt to said ammonium salt is in the range of 85:15 to 95:5 based on the weight of glyphosate in the acid form.
- the glyphosate composition of the invention may use glyphosate at a wide range of concentrations.
- the composition may have a high concentration of 600g/L, based on the weight of glyphosate in the acid form, or more such as may be used for transport and shipping, it may be a concentrate of the type to be diluted prior to use or it may be a dilute composition prepared from the concentrate or of the type sold in spray packs for domestic use.
- the glyphosate concentrate compositions of the invention will typically include at least 300g/L of glyphosate.
- the compositions of the invention are particularly advantageous when they include at least 360g/L glyphosate based on acid form and preferably they include at least 450g/L. Even more preferably the concentration is at least 490g/L and most preferably the glyphosate concentration is at least 500g/L.
- concentration of up to 540g/L or more may be formed with a viscosity allowing easy dispensing by the container pump systems used by farmers. Further the composition is generally stable even at low temperatures for example at 5°C.
- Manufacturing concentrates may be prepared with concentrations of as high as 620g/L or more. Although concentrated compositions of at least 360g/L glyphosate are preferred the composition of the invention may be in the form of a diluted composition if desired. The concentration will preferably be at least 3.6g/L For example it may be in the form of a dilute formulation prepared from a concentrate before application or it may be a dilute solution of the type packaged for the domestic market.
- the composition of the invention may and typically will contain other additives.
- the composition may include a surfactant component.
- the surfactant component may include one or more surfactants and is preferably present in an amount of up to 20% by weight of the total composition. In cases where the surfactant is present at the upper end of this range the glyphosate concentration will be relatively low. More preferably the surfactant is present in an amount of up to 5% by weight of the total composition. At such surfactant concentrations higher amounts of glyphosate may be used to provide at least 500g/L glyphosate.
- surfactants which may be useful include alkanolamides, betaine derivatives, ethoxylated propoxylated block copolymers, glycerol esters, glycol esters, imidazolines and imidazoline derivatives, lanolin derivatives, lecithin derivatives, tertiary or quaternary polyoxyalkylene alkylamines, polyoxyalkylene and non-polyoxyalkylene alkylamine oxides, polyoxyalkylene alkylethers, polyoxyalkylene alkylarylethers, polyoxyalkylene alkylesters, alkoxylated and non- alkoxylated sorbitan esters, alkyl glycosides, alkyl polyglycosides, sucrose esters, sucrose glycerides, alkyl sulphates or phosphates, olefin sulfonates, alkylaryl sulfonates, polyoxyalkylene alkylether sulphates or phosphates
- the properties of the composition are particularly useful when the surfactant includes a phosphate ester, particularly an ethoxylated alcohol phosphate ester which may be in the form of a salt such as the ammonium or alkylamine salt such as the monoisopropylamine salt. It is particularly preferred that the surfactant includes the ammonium salt of the ethoxylated alcohol phosphate ester.
- Dinitroanilines are one of the most commercially successful classes of herbicides.
- trifluralin is widely used in pre-sowing application to soil in many important crops. It is effective against both grassy weeds and broad-leave weeds.
- Herbicides of the triazine family, particularly atrazine, are also used at the time of sowing crops, particularly canola.
- compositions of the invention exhibit improved compatibility.
- ammonium salt of an ethoxylated alcohol phosphate ester is used as the surfactant in the compositions of the invention the formulation is compatible with dinitroanilines or triazines and mixtures of these herbicides with glyphosate do not generally suffer loss of efficacy to the same extent as conventional formulations. Indeed there is a significant improvement in efficacy when compared with combinations of the presently available herbicide compositions at corresponding concentrations.
- a glyphosate formulation including the monoisopropylamine salt of glyphosate and the ammonium salt of glyphosate wherein the ratio of said monoisopropylamine salt and ammonium salt is in the range from 80:20 to 97:3 (preferably 85:15 to 95:5) and therein the formulation includes a surfactant including the ammonium salt of an ethoxylated alcohol phosphate ester.
- the ethoxylated alcohol phosphate ester is preferably present in an amount of up to 5% by weight of the composition and most preferably from 0.5 to 5% by weight of the total composition.
- composition of the invention may be used as a stand alone product by diluting it with water to the required glyphosate concentration. It is desirable in many circumstances to use the herbicide composition in combination with an adjuvant. When the herbicide composition is to be used with other herbicides or with hard diluting water (over 1000 ppm) then use of an adjuvant is particularly preferred. Suitable adjuvants for use with glyphosate are known in the industry and they may be used if desired.
- Suitable adjuvants include equivalently acceptable inorganic salts, dispersants, wetters and antifoam agents.
- acceptable inorganic salts include ammonium sulphate, ammonium nitrate, potassium phosphate, tetrapotassium pyrophosphate, sodium bisulphate, sodium sulphate, ammonium bicarbonate. Ammonium sulphate is particularly preferred.
- dispersants and wetters include the surfactants referred to above, however preferred dispersants include long aliphatic quaternary ammonium compounds, aliphatic amines, alkylpolysaccharides and ethoxylated phosphates. Ethoxylated fatty amine surfactants such as soya amine ethoxylate and tallow amine ethoxylate, alkylpolysaccharides and ethoxylated alcohol phosphate ester or mixtures, of two or more thereof, or with the above examples of surfactants are particularly useful.
- the adjuvant may if desired contain crop oils such as paraffinic oils, vegetable oils or vegetable oil derivatives.
- the invention provides an adjuvant composition for use with glyphosate herbicide compositions the adjuvant including: ammonium sulphate, an alkylammonium sulphate or mixture thereof; a surfactant component including an ammonium salt of an ethoxylated alcohol phosphate ester and an amphoteric surfactant.
- the alkylammonium sulphate when present may be a mono-, di- or trialkyl- ammonium sulphate.
- the alkyl group or groups preferably contain up to six carbon atoms, more preferably up to 4 carbon atoms and most preferably are isopropyl. Ammonium sulphate is preferably present.
- the amphoteric surfactant is preferably a phospholipid with an acidic buffer, particularly propionic acid .
- the preferred concentration of components in the adjuvant are as follows: from 5 to 30% w/w of ammonium sulphate alkylammonium sulphate or mixture thereof; from 0 to 25% w/w, preferably from 0.5 to 25% w/w of ammonium salt of an ethoxylated alcohol phosphate ester and; from 0.5 to 10% w/w of amphoteric surfactant which is preferably a phospholipid.
- the adjuvant of the invention may be used with the glyphosate composition of the invention or it may be used with other glyphosate compositions such as those which are commercially available from numerous sources.
- the adjuvant composition of the invention will generally be mixed with a glyphosate composition shortly before use.
- the composition will normally be mixed in the spray tank however it is preferred that at least a portion of the adjuvant to be used is added to the spray tank prior to the glyphosate. Preferably all of the adjuvant component to be used will be added to the spray tank prior to addition of the glyphosate composition.
- a glyphosate composition in accordance with the invention was prepared by combining the following components in the relative quantities specified:
- the glyphosate acid wetcake contained approximately 86% w/w glyphosate based on glyphosate acid (11 % w/w water). The purity of the glyphosate was 96.5% on a dry basis.
- composition which contains 540g/L glyphosate could readily be delivered using standard pumps used by farmers and was stable in solution at temperatures of 5°C for extended periods.
- GERONOL CF/AR surfactant sold by Rhodia is the 2-propanamine salt of ethoxylated alcohol phosphate ester.
- RHODOFAC ARB-70 sold by Rhodia is an ethoxylated alcohol phosphate ester and forms the ammonium salt in solution.
- Li-700 from Loveland Industries Inc, U S A is a mixture of soyal phospholipids and propionic acid.
- the combination of components in the adjuvant composition generally allows for better physical compatibility and improved efficacy even in hard water.
- composition according to the present invention comprising the glyphosate composition of Example 1 and the adjuvant formulation of Example 2, was compared with a leading commercial glyphosate formulation containing 490g/L glyphosate (based on glyphosate acid) in the form of the isopropylamine salt (Comparative example).
- Figure 1 is a graph comparing the viscosity of the glyphosate formulation of the invention with a leading 490g/L glyphosate formulation.
- Figure 2 is a bar chart comparing the low use rate efficiency of a 1 :1 mixture (by volume) of the composition/adjuvant formulation of Example 1 /Example 2 with the comparative glyphosate/adjuvant combination (Comparative example) - in the recommended mixing ratio - at the rate of grams of active ingredient per hectare.
- Figure 3 is a bar chart comparing the weed control performance of the composition of the Example 1 when used with the adjuvant of Example 2 in a 1 :1 volume ratio with the composition of Comparative example when used with the recommended surfactant adjuvant.
- Figure 4 is a bar chart comparing the efficiency obtained by the crop performance of the glyphosate/adjuvant combination of Examples 1 and 2 (1 :1 volumetric ratio) with the composition of Comparative example when used together with TRIFLUR trifluralin formulation.
- Figure 5 is a bar chart comparing the performance of the glyphosate/adjuvant combination of Examples 1 and Example 2 (1 :1 volumetric ratio) with the composition of the Comparative example, when each are used with NUTRAZINE brand atrazine formulation.
- the viscosity of the composition of the invention is significantly less than the prior art formulation despite containing 540g/L compared with the prior art containing 490g/L.
- the dual salt composition of the invention gives a viscosity which is typically 30% less than the prior art high loading compositions which merely contain 490g/L glyphosate acid
- Biological incompatibility may result from interactions between herbicides resulting in poorer weed control than when the herbicides are separately applied.
- Figures 4 and 5 show that the glyphosate composition of the invention exhibits a high compatibility rate when compared with a high rate glyphosate composition.
- Figure 4 compares the invention with the prior art composition when each are used with a commercial Trifluralin composition.
- Figure 5 compares composition of the invention with the prior art composition when used with commercial atrazine formulation.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPQ339399 | 1999-10-13 | ||
AUPQ3393A AUPQ339399A0 (en) | 1999-10-13 | 1999-10-13 | Herbicidal composition and adjuvant |
AUPQ4059A AUPQ405999A0 (en) | 1999-11-15 | 1999-11-15 | Herbicidal composition and adjuvant |
AUPQ405999 | 1999-11-15 | ||
PCT/AU2000/000283 WO2001026469A1 (fr) | 1999-10-13 | 2000-04-04 | Composition herbicide et adjuvant |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1220610A1 EP1220610A1 (fr) | 2002-07-10 |
EP1220610A4 true EP1220610A4 (fr) | 2003-01-22 |
Family
ID=25646174
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00913957A Withdrawn EP1220610A4 (fr) | 1999-10-13 | 2000-04-04 | Composition herbicide et adjuvant |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP1220610A4 (fr) |
JP (1) | JP2003511397A (fr) |
AR (1) | AR024815A1 (fr) |
BR (1) | BR0014702A (fr) |
CA (1) | CA2387173A1 (fr) |
CZ (1) | CZ20021309A3 (fr) |
EG (1) | EG22348A (fr) |
MX (1) | MXPA02003660A (fr) |
NO (1) | NO20021674L (fr) |
NZ (1) | NZ518149A (fr) |
PL (1) | PL354618A1 (fr) |
WO (1) | WO2001026469A1 (fr) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MY158895A (en) | 2000-05-19 | 2016-11-30 | Monsanto Technology Llc | Potassium glyphosate formulations |
US8236730B2 (en) | 2002-01-29 | 2012-08-07 | Rhodia Chimie | Aqueous herbicidal concentrate comprising a betaine type surfactant |
WO2006023431A2 (fr) | 2004-08-19 | 2006-03-02 | Monsanto Technology Llc | Composition herbicide a base de sels de glyphosate |
US9045720B2 (en) | 2004-12-30 | 2015-06-02 | Rhodia Chimie | Herbicidal composition comprising an aminophosphate or aminophosphonate salt, a betaine and an amine oxide |
BRPI0611373A2 (pt) | 2005-05-24 | 2010-08-31 | Monsanto Technology Llc | aperfeicoamento da compatibilidade de herbicida |
EP1951039B1 (fr) | 2005-11-14 | 2015-02-25 | Solvay USA Inc. | Compositions d adjuvant agricole, compositions de pesticides et procedes d utilisation de telles compositions |
US9416065B2 (en) * | 2007-02-12 | 2016-08-16 | Archer Daniels Midland Company | Adjuvants and methods of using them |
EP2603075B1 (fr) | 2010-08-10 | 2017-07-12 | Rhodia Operations | Compositions pesticides agricoles |
ES2541287T3 (es) | 2010-10-01 | 2015-07-17 | Nufarm Australia Limited | Método para la preparación de una composición concentrada acuosa de glifosato que tiene una mezcla de sales de amina |
AU2013202664B2 (en) * | 2010-10-01 | 2015-02-12 | Nufarm Australia Limited | Method for preparation of an aqueous glyphosate concentrate composition having mixture of amine salt |
EP2505061A1 (fr) | 2011-03-30 | 2012-10-03 | Rhodia Opérations | Nouvelles utilisations de chlorure de choline dans des formulations agrochimiques |
EP3590335A1 (fr) * | 2012-03-05 | 2020-01-08 | Archer Daniels Midland Company | Utilisation d'une microemulsion comme un degraisseur |
US11109591B2 (en) | 2017-04-24 | 2021-09-07 | Taminco Bvba | Single phase liquids of alkanolamine salts of dicamba |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0274369A1 (fr) * | 1986-12-04 | 1988-07-13 | Monsanto Company | Formulation herbicide glyphosphate-sulfate d'ammonium |
EP0378985A1 (fr) * | 1988-12-30 | 1990-07-25 | Monsanto Company | Formulations de glyphosate |
WO1999004635A1 (fr) * | 1997-07-22 | 1999-02-04 | Monsanto Company | Formulations a concentration elevee de sel d'ammonium de glyphosate |
WO1999021423A1 (fr) * | 1997-10-24 | 1999-05-06 | Brian Parker | Composition herbicide comprenant du glyphosate et un n-acyle-sarcosinate |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06505256A (ja) * | 1991-01-24 | 1994-06-16 | モンサント・カンパニー | 改良されたグリホセート処方物 |
ES2079633T3 (es) * | 1991-02-08 | 1996-01-16 | Monsanto Europe Sa | Composiciones solidas de glifosato y su uso. |
US5317003A (en) * | 1992-07-16 | 1994-05-31 | Monsanto Company | Herbicidal compositions comprising glyphosate salts and alkoxylated quaternary amine surfactants |
-
2000
- 2000-04-04 JP JP2001529269A patent/JP2003511397A/ja active Pending
- 2000-04-04 MX MXPA02003660A patent/MXPA02003660A/es unknown
- 2000-04-04 NZ NZ518149A patent/NZ518149A/en not_active IP Right Cessation
- 2000-04-04 BR BR0014702-8A patent/BR0014702A/pt not_active IP Right Cessation
- 2000-04-04 EP EP00913957A patent/EP1220610A4/fr not_active Withdrawn
- 2000-04-04 CZ CZ20021309A patent/CZ20021309A3/cs unknown
- 2000-04-04 CA CA002387173A patent/CA2387173A1/fr not_active Abandoned
- 2000-04-04 PL PL00354618A patent/PL354618A1/xx not_active Application Discontinuation
- 2000-04-04 WO PCT/AU2000/000283 patent/WO2001026469A1/fr active IP Right Grant
- 2000-07-11 EG EG20000889A patent/EG22348A/xx active
- 2000-07-20 AR ARP000103744 patent/AR024815A1/es unknown
-
2002
- 2002-04-09 NO NO20021674A patent/NO20021674L/no not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0274369A1 (fr) * | 1986-12-04 | 1988-07-13 | Monsanto Company | Formulation herbicide glyphosphate-sulfate d'ammonium |
EP0378985A1 (fr) * | 1988-12-30 | 1990-07-25 | Monsanto Company | Formulations de glyphosate |
WO1999004635A1 (fr) * | 1997-07-22 | 1999-02-04 | Monsanto Company | Formulations a concentration elevee de sel d'ammonium de glyphosate |
WO1999021423A1 (fr) * | 1997-10-24 | 1999-05-06 | Brian Parker | Composition herbicide comprenant du glyphosate et un n-acyle-sarcosinate |
Non-Patent Citations (1)
Title |
---|
See also references of WO0126469A1 * |
Also Published As
Publication number | Publication date |
---|---|
NO20021674L (no) | 2002-06-06 |
AR024815A1 (es) | 2002-10-23 |
PL354618A1 (en) | 2004-02-09 |
NZ518149A (en) | 2003-10-31 |
JP2003511397A (ja) | 2003-03-25 |
WO2001026469A1 (fr) | 2001-04-19 |
CZ20021309A3 (cs) | 2003-01-15 |
NO20021674D0 (no) | 2002-04-09 |
EG22348A (en) | 2002-12-31 |
EP1220610A1 (fr) | 2002-07-10 |
BR0014702A (pt) | 2002-06-18 |
MXPA02003660A (es) | 2003-10-14 |
CA2387173A1 (fr) | 2001-04-19 |
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Legal Events
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