EP1144705A2 - Method and device for producing coated metal strands, especially steel strips - Google Patents
Method and device for producing coated metal strands, especially steel stripsInfo
- Publication number
- EP1144705A2 EP1144705A2 EP00901068A EP00901068A EP1144705A2 EP 1144705 A2 EP1144705 A2 EP 1144705A2 EP 00901068 A EP00901068 A EP 00901068A EP 00901068 A EP00901068 A EP 00901068A EP 1144705 A2 EP1144705 A2 EP 1144705A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- thickness
- metal strand
- stripping
- bath
- melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 37
- 239000002184 metal Substances 0.000 title claims abstract description 37
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 16
- 239000010959 steel Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims description 13
- 239000000155 melt Substances 0.000 claims abstract description 24
- 238000007711 solidification Methods 0.000 claims abstract description 22
- 230000008023 solidification Effects 0.000 claims abstract description 22
- 238000005266 casting Methods 0.000 claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims abstract description 3
- 238000009499 grossing Methods 0.000 claims description 43
- 238000002425 crystallisation Methods 0.000 claims description 20
- 230000008025 crystallization Effects 0.000 claims description 20
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 230000005499 meniscus Effects 0.000 claims description 4
- 238000005096 rolling process Methods 0.000 description 11
- 239000012071 phase Substances 0.000 description 9
- 239000013078 crystal Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000002131 composite material Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 235000011837 pasties Nutrition 0.000 description 5
- 229910000975 Carbon steel Inorganic materials 0.000 description 3
- 239000010962 carbon steel Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000002631 hypothermal effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/008—Continuous casting of metals, i.e. casting in indefinite lengths of clad ingots, i.e. the molten metal being cast against a continuous strip forming part of the cast product
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0035—Means for continuously moving substrate through, into or out of the bath
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0036—Crucibles
- C23C2/00361—Crucibles characterised by structures including means for immersing or extracting the substrate through confining wall area
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/50—Controlling or regulating the coating processes
Definitions
- the invention relates to a method and a device for producing coated strands of metal, in particular steel strips, in which a metal strand is passed through the bottom of a vessel filled with melt of the same or different composition as the metal strand, the residence time of the Metal strand depending on the molten pool height, the casting speed, the metal strand thickness and the preheating temperature of the metal strand is selected so that the deposited melt on the metal strand assumes a desired thickness of several times the initial thickness of the metal strand and the metal strand with crystallized layer after exiting the Melt bath experiences a smoothing stitch, which is carried out when the surface temperature of the crystallized strand is lower than the solidus temperature of the melt pool and thus at least the surface of the crystallized layer is solidified.
- the belt then experiences severe hypothermia as it passes through the pair of smoothing rollers, which causes the tendency to crack both along and across the belt direction. This danger increases with higher casting and rolling speeds.
- the smoothing stitch is therefore carried out there when the surface temperature of the crystallized strand is lower than the solidus temperature of the melt pool and thus at least the surface of the crystallized layer has solidified. Nevertheless, it cannot be ruled out that the thickness of the crystallized layer fluctuates.
- the invention is therefore based on the object of providing a method and a device which ensure smoothing of the strip with a strip thickness tolerance of at most 2% without cracking both in the surface and in the interior of the strip while controlling the thickness of the crystallization.
- the main features for producing defect-free, flat-coated strips for example with a width / thickness ratio greater than 60 and a total thickness of at most 12 mm, preferably 2 to 6 mm, from one material or from composite materials of different metal qualities such as carbon steel as mono- material or carbon steel with a stainless steel coating of at least 5% of the total strip thickness as a composite material and a maximum thickness deviation of 2% between the edge (40 mm from the edge) and the center of the strip are the same with regard to the desired goal Thickness of the crystallized layer in particular characterized in that between the molten bath and the start of solidification on the strip surface, the crystallization is stripped to a smaller thickness with a desired thickness. In the end, only as much material is stripped or carried as is necessary to make the same To achieve the thickness of the crystallized layer over the length of the strand. The excess of the crystallized layer is thus stripped off.
- the stripping of the crystallization with a desired thickness to a smaller thickness is advantageously carried out in the device between the molten bath and the start of solidification on the strip surface, the walls of the space accommodating the pair of smoothing rollers and the pair of smoothing rollers themselves being designed to be heat-controlled.
- Mechanical stripping devices in the form of preferably knives are advantageously suitable for stripping, alternatively a pneumatic stripping device can be used.
- Figure 1 is an overall view of the method and its device for smoothing coated strands of metal, preferably steel strips;
- FIG. 2 shows a temperature field of the strand between the strip entry into the crystallizer and the pair of smoothing rollers during casting
- FIG. 3 shows a coated strip between the melt pool surface in the crystallizer and the pair of smoothing rollers, detail from FIG. 1.
- FIGS. 1 and 2 show the overall view of the method and the device for smoothing coated strands, preferably strips of steel 1, using a pair of smoothing rollers 2.
- the mother tape 1.1 is in the crystallizer 3, filled with melt 3.3, which is introduced via a melt inlet 3.1, through the nozzles of a bottom inlet device 3.2 with a casting and rolling speed 7.1 of 0.05 to 10 m / s by means of a pair of drive rollers 1.5 below Promoted crystal lisators.
- the mother tape 1.1 With a temperature of either 20 to 80 ° C before entering the crystallizer 3, begins above the steel meniscus 3.5 at the nozzle outlet 3.2 with the crystallization 3.6 of melt in point 3.6.1 and removes the melt 3.3 from superheating and crystallization energy simultaneous warming.
- This energy flow 4 from the melt into the mother tape takes place when the mother tape passes through the melt pool 3.3 between the meniscus 3.5 and the bath surface 3.4 over the melt pool height 3.3.1.
- the coated strip 1 At the exit 5 of the coated strip 1 from the bath surface 3.4 of the melt pool with a surface roughness 1.3, it has reached a certain thickness 1.2, which is essentially determined by the strip temperature when it enters the crystallizer, the melt temperature and the contact time of the strip with the melt , with which the strip 1 enters the roll gap 2.1 of the pair of smoothing rollers 2.
- the strip 1 coated in this way is "doughy" at the exit 5 from the bath 3.4 on the surface (two phases: melt and crystal) and has a surface roughness 1.3 of greater than 2%, which meets the flatness criteria of a strip with a width / thickness Ratio greater than 60 does not do it justice.
- the solidification runs from the exit 5 to the pair of smoothing rollers 2 and beyond in the crystallized layer, which consists of melt and crystal, from the outside in, ie the energy flow 6 reverses compared to the heat flow 4 in the melt 3.3 um and runs from the inside (middle of the strip) to the outside into the walls 6.1 with a heat-controlled passage.
- This controlled heat flow can be divided by wall elements 6.2 into zones corresponding to the temperature control of the strip 1 in the casting and rolling direction 7.
- the crystallization 3.6 in the bath 3.3 has on its surface 4.1 a temperature 8 (Tx) which is greater than the solidus temperature and lower than the liquidus temperature (T-Ii> Tx> T-sol) and has a two-phase state , consisting of melt and crystal. This crystallization steadily decreases in temperature from the surface perpendicular to the mother tape 1.1. Functional to the surface profile 4.1 of the crystallization 3.6, the liquidus isotherm 10 runs in the molten bath up to the bath surface 3.4.
- Tx temperature 8
- T-Ii> Tx> T-sol liquidus temperature
- the coated strip 1 emerges from the bath 3.4 at point 5
- the melted layer 9.2 of the mother strip 1.1 is largest, which began in the melt bath 3.3 at point 9.1 when the solidus temperature was reached.
- the welding between the mother tape 1.1 and the crystallized layer 3.6 begins.
- the solidification of the residual melt in the crystallized layer begins from the surface of the strip 1 perpendicular to the strip center and in the surface itself in the direction of the pair of smoothing rollers 2 parallel to the casting and rolling direction 7, ie the surface temperature of the strip decreases steadily from the bath surface 3.4 at point 5 in the direction of the pair of smoothing rollers 2, the solidus temperature passes through in point 9.3 Inlet 2.1.1 of the coated belt 1 into the pair of smoothing rolls 2, where it then assumes a value which is below T-Solidus.
- the thickness 1.2 of the coated strip between the strip surface 3.4 and the start of solidification 9.3, that is to say still in the "pasty" (two phases: melt and crystal) strip surface area 24, is reduced to a smaller thickness 21 by a stripping 20. This reduction must take place before solidification 9.3 in order to obtain a clean and flat belt surface.
- This stripping 20 or control of the coating thickness can alternatively exist both with a mechanical stripper 22 (knife), which is made of metal and / or ceramic and can also be cooled, as well as with a pneumatic stripper, which is operated with an oxygen-free gas jet 23 .
- both types of wipers 22 and 23 can be used in succession.
- both wipers are in their position, i.e. with their distance to the belt surface 1.3, to the bath surface 3.4 and to each other freely selectable.
- the position 2.4 of the pair of smoothing rollers 2 the energy flow 6 into the walls with heat-controlled passageways 6.1 and 6.2 and the pouring and rolling speed 7.1 in the sense of the invention are to be controlled in such a way that the surface temperature of the coated strip 1 before entering the pair of smoothing rollers 2 is below the solidus temperature and thus the coated strip is at least solidified in its surface.
- These conditions of the coated belt 1 in the pair of smoothing rollers can, at a given casting speed 7.1 with the help of the regulation of the heat flows 6 and 2.7 by means of the wall elements 6.1 and 6.2 and / or the smoothing roller pair 2 with internal cooling 2.5 adjustable in relation to the distance from the casting level 2.4.1 , can be set.
- the strip 1 with its rough surface 1.3 can now be rolled or smoothed 1.4 with a decrease in thickness of up to 20% by adjusting the pair of smoothing rollers 2 in the thickness direction 2.3, without surface cracks or internal cracks occurring in the crystallized layer while at the same time ensuring good welding between the mother tape 1.1 and the crystallized layer 3.6.
- the thus smoothed and flat band 1.4.1 is crack-free in its surface 1.4 and in the interior of its solidified, crystallized layer 3.6.
- the flatness or the resulting profile of the band 1.4.1 can be a tolerance of max. 2% of the thickness can be set in the transverse and longitudinal directions.
- FIG. 3 shows the area of the pair of smoothing rollers 2 in somewhat more detail.
- the coated strip 1 with its crystallization 3.6 runs in the roll gap 2.1.1 a surface temperature, T-2.1.1 less than T-Solidus (T-2.1.1 ⁇ T-sol) and occurs with a controlled reduced temperature T-2.1.2 less than T-2.1.1 (T-2.1.2 ⁇ T-2.1.1 ⁇ T-sol) out of the roll gap 2.1 at its outlet 2.1.2.
- the temperature loss in the roll gap should be controlled and kept small. According to the invention, this can be achieved by means of a correspondingly heat-controlled, controlled pair of smoothing rollers 2 with internal cooling 2.5 and heat-controlling layer 2.6 or layers.
- the cooling, the materials and the thickness of the rollers 2, their layer structure 2.6 and the choice of different roller materials such as Steel, metals, metal ceramics and / or ceramics can be coordinated.
- the entire space 11 above the bath surface 3.4 is controlled in its temperature and atmosphere (nitrogen and / or argon), so that the conditions described above are ensured and oxidation of the bath surface is avoided.
- the strip coated in this way is fed directly or indirectly to a further rolling mill 12 and rolling process for producing finished hot strip and / or cold strip both as a mono material and as a composite material with or without an upstream pickling line.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Continuous Casting (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Wire Processing (AREA)
- Ropes Or Cables (AREA)
- Coating With Molten Metal (AREA)
- Metal Rolling (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19902066A DE19902066A1 (en) | 1999-01-20 | 1999-01-20 | Method and device for producing coated strands of metal, in particular steel strips |
DE19902066 | 1999-01-20 | ||
PCT/EP2000/000060 WO2000043563A2 (en) | 1999-01-20 | 2000-01-07 | Method and device for producing coated metal strands, especially steel strips |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1144705A2 true EP1144705A2 (en) | 2001-10-17 |
EP1144705B1 EP1144705B1 (en) | 2002-06-12 |
EP1144705A3 EP1144705A3 (en) | 2002-11-13 |
Family
ID=7894810
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00901068A Expired - Lifetime EP1144705B1 (en) | 1999-01-20 | 2000-01-07 | Method and device for producing coated metal strands, especially steel strips |
Country Status (6)
Country | Link |
---|---|
US (1) | US6565925B1 (en) |
EP (1) | EP1144705B1 (en) |
AT (1) | ATE219160T1 (en) |
AU (1) | AU2106200A (en) |
DE (2) | DE19902066A1 (en) |
WO (1) | WO2000043563A2 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005030766A1 (en) * | 2005-07-01 | 2007-01-04 | Sms Demag Ag | Device for the hot dip coating of a metal strand |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1621339A1 (en) * | 1967-04-29 | 1971-06-03 | Siemens Ag | Process for the production of copper wire coated with tin or a predominantly tin-containing alloy, in particular copper jumper wire, by hot-dip metallization |
US4339480A (en) * | 1980-04-11 | 1982-07-13 | Bethlehem Steel Corporation | Gas wiping apparatus and method of using |
DE3600548A1 (en) * | 1986-01-10 | 1987-07-16 | Alfred Haderlapp | Apparatus for the tin-plating of rod-shaped objects |
DE4319569C1 (en) * | 1993-06-08 | 1994-06-16 | Mannesmann Ag | Method and appts. for prodn. of a semi-finished prod. - with smooth-rolling of the deposited metal ensures a small thickness tolerance |
DE19509681C1 (en) * | 1995-03-07 | 1996-05-02 | Mannesmann Ag | Continuous prodn. of metal strip by inversion casting |
DE19638905C1 (en) * | 1996-09-23 | 1998-01-02 | Schloemann Siemag Ag | Production of continuous coated metal products, in particular, metal strips |
DE19638906C1 (en) * | 1996-09-23 | 1998-01-02 | Schloemann Siemag Ag | Production of continuous coated metal products, in particular metal strips |
CA2225537C (en) * | 1996-12-27 | 2001-05-15 | Mitsubishi Heavy Industries, Ltd. | Hot dip coating apparatus and method |
US6037011A (en) * | 1997-11-04 | 2000-03-14 | Inland Steel Company | Hot dip coating employing a plug of chilled coating metal |
-
1999
- 1999-01-20 DE DE19902066A patent/DE19902066A1/en not_active Withdrawn
-
2000
- 2000-01-07 WO PCT/EP2000/000060 patent/WO2000043563A2/en active IP Right Grant
- 2000-01-07 DE DE50000212T patent/DE50000212D1/en not_active Expired - Fee Related
- 2000-01-07 AU AU21062/00A patent/AU2106200A/en not_active Abandoned
- 2000-01-07 EP EP00901068A patent/EP1144705B1/en not_active Expired - Lifetime
- 2000-01-07 US US09/889,521 patent/US6565925B1/en not_active Expired - Fee Related
- 2000-01-07 AT AT00901068T patent/ATE219160T1/en not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of WO0043563A2 * |
Also Published As
Publication number | Publication date |
---|---|
WO2000043563A2 (en) | 2000-07-27 |
WO2000043563A3 (en) | 2002-09-26 |
DE50000212D1 (en) | 2002-07-18 |
EP1144705B1 (en) | 2002-06-12 |
AU2106200A (en) | 2000-08-07 |
US6565925B1 (en) | 2003-05-20 |
EP1144705A3 (en) | 2002-11-13 |
DE19902066A1 (en) | 2000-08-03 |
ATE219160T1 (en) | 2002-06-15 |
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