EP1137752B1 - Use of detergent compositions - Google Patents
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- EP1137752B1 EP1137752B1 EP99973306A EP99973306A EP1137752B1 EP 1137752 B1 EP1137752 B1 EP 1137752B1 EP 99973306 A EP99973306 A EP 99973306A EP 99973306 A EP99973306 A EP 99973306A EP 1137752 B1 EP1137752 B1 EP 1137752B1
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- detergent
- detergent composition
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- wash
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
Definitions
- the present invention relates to the use of laundry detergent compositions suitable for washing both white and coloured fabrics.
- the compositions which contain a sequestrant, iminodisuccinate or hydroxyiminodisuccinate, in controlled amounts, have been found to give improved maintenance and/or restoration of colour fidelity during the wash.
- the presence of the sequestrant also reduces dye fading due to chlorine in water, and in addition provides improved stain removal.
- Coloured articles may become darker or the colour may change as a result of laundering, thus changing the appearance and shortening the useful life of the articles.
- White articles may also become discoloured, for example, yellowed, with time.
- the benefits are especially marked if the wash is carried out at low pH.
- Iminodisuccinate is known as a detergency builder and, in bleaching detergent compositions, as a stabiliser for peroxy bleach precursors.
- US 3 697 453 discloses detergent compositions having a pH of from 9 to 12, containing iminodisuccinate as a detergency builder, used together with detergent surfactant in a weight ratio of 0.25:1 to 10:1. IDS as a detergency builder is also disclosed in EP 757 094A (Bayer).
- US 5 318 726 discloses detergent compositions containing hydroxyiminodisuccinate (HIDS) as a detergency builder or bleach stabiliser.
- JP 09 110 813A (Nippon Shokubai)
- JP 09 104 897A (Nippon Shokubai).
- DE 4 311 440A (Henkel) discloses zero-phosphate detergent compositions containing a builder system comprising zeolite, HIDS and silicate.
- GB 474 082 discloses the use of aminopolycarboxylic acids, including IDS, in textile treatment processes or washing processes, to delay the precipitation of metal salts or to redissolve such precipitates.
- EP 509 382A (W R Grace & Co/Hampshire Chemical Corporation) discloses a bleaching detergent composition comprising a bleaching agent and a bleach stabiliser of defined formula which includes IDS.
- the use of IDS as a bleach stabiliser is also disclosed in WO 97 20907A (Procter & Gamble).
- JP 09 249 895A (Lion) and JP 09 310 097A (Lion) disclose detergent compositions containing 3 to 20 wt% IDS or HIDS to improve the stability or fabric substantivity of fluorescers (optical brighteners).
- JP 09 100 497A Lion
- JP 09 279 188A Lion
- JP 07 011294A discloses high bulk density granular detergent compositions containing aminopolycarboxylic acids (eg IDS or HIDS) to improve foaming behaviour and rinsability.
- WO 98 38276A (Procter & Gamble) discloses laundry detergent compositions containing 0.1-50 wt% of a colour care agent.
- the colour care agents are amines substituted with, for example, hydroxyalkyl groups.
- the preferred material is N,N,N',N'-tetrakis-(2-hydroxypropyl)ethylenediamine.
- WO 91 17234A discloses low-pH granular laundry detergent compositions containing chlorine scavengers which minimise the fading of pH-sensitive and chlorine-sensitive fabric dyes during laundering.
- Preferred chlorine scavengers are ammonium salts, for example, ammonium sulphate.
- the present invention accordingly provides the use of a non-bleaching laundry detergent composition for the protection for new white or coloured textile fabrics from colour degradation on laundering, the composition comprising surfactant, builder, and optionally other non-bleach detergent ingredients, and also containing from 0.05 to 1.5 wt% of a compound of the formula (I): wherein Y is H or OH and X is H or a solubilising cation.
- a further subject of the invention is a method of protecting new white or coloured textile fabrics from colour degradation on laundering, which comprises laundering the fabrics by hand or machine in a wash liquor containing the use of a detergent composition as defined above.
- a further subject of the invention is the use of a non-bleaching laundry detergent composition as defined above as a chlorine scavenger to prevent the fading of chlorine-sensitive dyes on coloured textile fabrics during laundering.
- the detergent compositions used in the invention contain, as an essential ingredient, a compound of the formula I: wherein Y is H or OH, preferably H; and X is H or a solubilising cation, preferably a sodium ion.
- I iminodisuccinic acid or a water-soluble salt thereof.
- IDS in the following description, the abbreviation "IDS" will be used to denote this material whether in acid or salt form. IDS is commercially available from Bayer AG, Leverkusen, Germany, and from Nippon Shokubai KK, Japan.
- the formula I represents hydroxyiminodisuccinic acid or a water-soluble salt thereof.
- HIDS HIDS
- Nippon Shokubai KK Japan.
- the IDS or HIDS may be, and preferably is, in the form of a salt, ie X in the formula I is a stable solubilising cation, preferably an alkali metal cation, more preferably sodium.
- IDS or HIDS is present in an amount of from 0.05 to 1.5 wt%, preferably from 0.2 to 1.5 wt%, more preferably from 0.3 to 1.5 wt% and most preferably from 0.5 to 1.0 wt%.
- the lower levels appear to provide the greatest benefit and no additional benefit is observed if higher amounts, greater than 2.5 wt%, are used.
- the preferred material is IDS, most preferably in sodium salt form.
- composition used in the invention also contains other conventional detergent ingredients, other than bleaching ingredients.
- Essential ingredients are surfactants (detergent-active compounds) and detergency builders, and other non-bleach ingredients may optionally be present.
- a preferred detergent composition used according to the invention comprises:
- the detergent compositions used in the invention may be of any physical form.
- the detergent compositions will contain, as essential ingredients, one or more detergent active compounds (surfactants) which may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
- surfactants may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
- surfactants may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
- surfactants may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent active compounds, and mixtures thereof.
- suitable detergent active compounds are available and are fully described in the literature, for example, in "Surface-Active Agents and Detergents", Volumes I and II, by Schwartz, Perry and Ber
- the preferred detergent active compounds that can be used are soaps and synthetic non-soap anionic and nonionic compounds.
- Anionic surfactants are well-known to those skilled in the art. Examples include alkylbenzene sulphonates, particularly linear alkylbenzene sulphonates having an alkyl chain length of C 8 -C 15 ; primary and secondary alkylsulphates, particularly C 8 -C 15 primary alkyl sulphates; alkyl ether sulphates; olefin sulphonates; alkyl xylene sulphonates; dialkyl sulphosuccinates; and fatty acid ester sulphonates.
- Sodium salts are generally preferred.
- Nonionic surfactants that may be used include the primary and secondary alcohol ethoxylates, especially the C 8 -C 20 aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and more especially the C 10 -C 15 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol.
- Non-ethoxylated nonionic surfactants include alkylpolyglycosides, glycerol monoethers, and polyhydroxyamides (glucamide).
- Cationic surfactants that may be used include quaternary ammonium salts of the general formula R 1 R 2 R 3 R 4 N + X - wherein the R groups are long or short hydrocarbyl chains, typically alkyl, hydroxyalkyl or ethoxylated alkyl groups, and X is a solubilising cation (for example, compounds in which R 1 is a C 8- C 22 alkyl group, preferably a C 8 -C 10 or C 12 -C 14 alkyl group, R 2 is a methyl group, and R 3 and R 4 , which may be the same or different, are methyl or hydroxyethyl groups); and cationic esters (for example, choline esters).
- R 1 is a C 8- C 22 alkyl group, preferably a C 8 -C 10 or C 12 -C 14 alkyl group
- R 2 is a methyl group
- R 3 and R 4 which may be the same or different, are methyl or hydroxy
- R 1 represents a C 8 -C 10 or C 12 -C 14 alkyl group
- R 2 and R 3 represent methyl groups
- R 4 presents a hydroxyethyl group.
- Amphoteric surfactants for example, amine oxides, and zwitterionic surfactants, for example, betaines, may also be present.
- the quantity of anionic surfactant is in the range of from 5 to 50% by weight of the total composition. More preferably, the quantity of anionic surfactant is in the range of from 8 to 35% by weight.
- Nonionic surfactant if present, is preferably used in an amount within the range of from 1 to 20% by weight.
- the total amount of surfactant present is preferably within the range of from 5 to 60 wt%.
- compositions may suitably contain from 10 to 80%, preferably from 15 to 70% by weight, of detergency builder.
- the quantity of builder is in the range of from 15 to 50% by weight.
- the detergent compositions may contain as builder a crystalline aluminosilicate, preferably an alkali metal aluminosilicate, more preferably a sodium aluminosilicate (zeolite).
- a crystalline aluminosilicate preferably an alkali metal aluminosilicate, more preferably a sodium aluminosilicate (zeolite).
- the zeolite used as a builder may be the commercially available zeolite A (zeolite 4A) now widely used in laundry detergent powders.
- the zeolite may be maximum aluminium zeolite P (zeolite MAP) as described and claimed in EP 384 070B (Unilever), and commercially available as Doucil (Trade Mark) A24 from Crosfield Chemicals Ltd, UK.
- Zeolite MAP is defined as an alkali metal aluminosilicate of zeolite P type having a silicon to aluminium ratio not exceeding 1.33, preferably within the range of from 0.90 to 1.33, preferably within the range of from 0.90 to 1.20.
- zeolite MAP having a silicon to aluminium ratio not exceeding 1.07, more preferably about 1.00.
- the particle size of the zeolite is not critical. Zeolite A or zeolite MAP of any suitable particle size may be used.
- phosphate builders especially sodium tripolyphosphate. This may be used in combination with sodium orthophosphate, and/or sodium pyrophosphate.
- inorganic builders that may be present additionally or alternatively include sodium carbonate, layered silicate, amorphous aluminosilicates.
- Organic builders that may be present include polycarboxylate polymers such as polyacrylates and acrylic/maleic copolymers; polyaspartates; monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-di- and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates, hydroxyethyliminodiacetates, alkyl- and alkenylmalonates and succinates; and sulphonated fatty acid salts.
- polycarboxylate polymers such as polyacrylates and acrylic/maleic copolymers
- polyaspartates monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-di- and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates, hydroxyethyliminodiacetates, alkyl-
- Organic builders may be used in minor amounts as supplements to inorganic builders such as phosphates and zeolites.
- Especially preferred supplementary organic builders are citrates, suitably used in amounts of from 5 to 30 wt %, preferably from 10 to 25 wt %; and acrylic polymers, more especially acrylic/maleic copolymers, suitably used in amounts of from 0.5 to 15 wt %, preferably from 1 to 10 wt%.
- Builders both inorganic and organic, are preferably present in alkali metal salt, especially sodium salt, form.
- the detergent compositions may also contain one or more enzymes. Suitable enzymes include the proteases, amylases, cellulases, oxidases, peroxidases and lipases usable for incorporation in detergent compositions.
- Preferred proteolytic enzymes are catalytically active protein materials which degrade or alter protein types of stains when present as in fabric stains in a hydrolysis reaction. They may be of any suitable origin, such as vegetable, animal, bacterial or yeast origin.
- Proteolytic enzymes or proteases of various qualities and origins and having activity in various pH ranges of from 4-12 are available. Proteases of both high and low isoelectric point are suitable.
- enzymes that may suitably be present include lipases, amylases, and cellulases including high-activity cellulases such as "Carezyme”).
- detergency enzymes are commonly employed in granular form in amounts of from about 0.1 to about 3.0 wt%. However, any suitable physical form of enzyme may be used in any effective amount.
- Antiredeposition agents for example cellulose esters and ethers, for example sodium carboxymethyl cellulose, may also be present.
- compositions may also contain soil release polymers, for example sulphonated and unsulphonated PET/POET polymers, both end-capped and non-end-capped, and polyethylene glycol/polyvinyl alcohol graft copolymers such as Sokolan (Trade Mark) HP22.
- soil release polymers for example sulphonated and unsulphonated PET/POET polymers, both end-capped and non-end-capped, and polyethylene glycol/polyvinyl alcohol graft copolymers such as Sokolan (Trade Mark) HP22.
- Especially preferred soil release polymers are the sulphonated non-end-capped polyesters described and claimed in WO 95 32997A (Rhodia Chimie).
- ingredients that may be present include solvents, hydrotropes, fluorescers, photobleaches, foam boosters or foam controllers (antifoams) as appropriate, sodium carbonate, sodium bicarbonate, sodium silicate, sodium sulphate, calcium chloride, other inorganic salts, fabric conditioning compounds, and perfumes.
- compositions used in the invention may be of any suitable physical form, for example, particulates (powders, granules, tablets), liquids, pastes, gels or bars.
- the detergent composition is in particulate form.
- the IDS may be incorporated in particulate compositions in the form of granules containing an inert carrier material.
- compositions in powder form may be of any bulk density and may be prepared by spray-drying, non-tower granulation, or any combination of these techniques.
- the detergent composition is in liquid form.
- Liquid detergent compositions may be prepared by admixing the essential and optional ingredients in any desired order to provide compositions containing the ingredients in the the requisite concentrations.
- the colour benefit associated with the compositions used in the invention is twofold: protection (maintenance) of the colour or whiteness of new fabrics, and restoration (recovery) of the colour or whiteness of previously washed fabrics.
- New fabrics when washed with the compositions used the invention, show reduced colour degradation as compared with fabrics washed in control formulations without IDS.
- the fabrics maintain a new appearance even after multiple washing. This protection or maintenance benefit has been found to apply both to white and to coloured fabrics.
- a cause of the colour degradation resulting from the laundry process may be heavy metal ions, especially iron but also copper, zinc and manganese: these may originate from the water or water pipes, from washing machine parts, from the detergent composition used, or from the soil present on the fabric.
- the colour care benefit obtained according to the present invention may be attributed to the sequestration by the IDS of any heavy metal ions present in the wash liquor.
- IDS nitrilotriacetate
- the composition has a 0.25% aqueous solution pH (in demineralised water at 30°C) not exceeding 10.5, preferably not exceeding 10.0.
- the preferred pH range is from 8.0 to 10.5, more preferably from 8.5 to 10.0.
- a further subject of the invention is a process in which white or coloured fabrics are laundered using the composition of the invention.
- the process is carried out in a wash liquor having a pH not exceeding 10.5, more preferably not exceeding 10.0.
- the two preferred conditions previously mentioned - very low pH, and low sequestrant level - have especial relevance to the handwash as carried out, for example, in South East Asia. In that region, it is a common habit to presoak or prerinse the fabrics in water, without detergent, to remove gross soiling.
- the wash liquor pH may be as low as 6.0 to 7.0.
- the wet fabrics are then immersed in the main wash liquor (detergent solution).
- the additional water imported into the wash liquor from the wet fabrics has the dual effect of diluting the wash liquor (and thus lowering the sequestrant level) and lowering the pH.
- IDS has also been found to reduce the fading upon laundering of chlorine-sensitive dyes. This fading occurs due to the presence of sodium hypochlorite, which is routinely put into supply water for hygiene purposes: levels of 0.5 ppm are typical. This causes fading of dyes of a wide range of colours.
- the incorporation of IDS in accordance with the present invention can significantly reduce the amount of fading attributable to chlorine in the wash water.
- the sequestrants used were as follows:
- the fabrics were washed in demineralised water containing copper ions (0.5 ppm Cu 2+ ex CuCl 2 ) at a liquor to cloth ratio of 200:1 in tergotometers for 30 minutes at 30°C at 90 rpm.
- Colour changes were monitored as reflectances differences at 620 nm. Two different effects are in operation here: dye fading, which leads to a generally small reflectance increase; and dye darkening (colour degradation) resulting from the presence of the copper ions, leading to a rather larger reflectance decrease. Both effects are undesirable and result in deterioration of the appearance of the fabric.
- the reflectance difference observed should be close to zero or a small increase (not greater than 3 units, and preferably not greater than 2 units).
- Example Sequestrant Lower sequestrant level (0.5%) Higher sequestrant level (1.0%) pH 9.5 pH 6.5 pH 9.5 pH 6.5 A Water alone + 2.40 + 2.49 + 2.40 + 2.49 B Water + Cu 2+ - 5.62 -20.00 - 5.62 -20.00 1 IDS + 1.04 + 0.95 + 2.64 + 1.22 C NTA + 4.05 + 3.38 + 4.95 + 4.11 D EDTMP + 0.87 -10.23 + 1.06 - 6.10 E EDDS + 4.43 - 4.35 + 4.91 + 3.98 F STP - 6.03 -20.90 -15.72 -15.71 G Mg silicate - 3.88 -15.40 - 4.18 -13.27
- Example 1 The procedure of Example 1 was repeated at pH 6.5 using white cotton fabrics and a "cocktail" of heavy metal ions: Cu 2+ 0.5 ppm Fe 3+ 2.5 ppm Mn 2+ 2.0 ppm Zn 2+ 5.0 ppm
- Example Sequestrant 0.5% 1.0% H Water alone - 0.20 - 0.20 J Water + ions - 1.66 - 1.66 2 IDS - 0.32 - 0.38 K NTA - 1.62 - 1.30 L EDTMP - 0.54 - 0.54 M EDDS - 2.37 - 2.03 N STP - 0.89 - 0.71 P Mg silicate - 2.23 - 1.71
- a detergent powder formulation was prepared by conventional spray-drying and postdosing techniques to the following formulation: wt% Sodium linear alkylbenzene sulphonace (NaLAS) 22.92 Sodium silicate (anhydrous) 4.67 Sodium tripolyphosphate 18.67 Sodium carboxymethyl cellulose 0.25 Polyacrylate polymer 0.70 Calcite 10.00 Sodium sulphate, water, impurities, sequestrant if present to 100 Comparative Example Q no sequestrant Example 3 plus 1.25 wt% IDS
- the fabrics were washed five times in a wash liquor comprising 20/6° FH (Ca/Mg) water containing a "cocktail" of heavy metal ions and 2.5 g/litre of the detergent composition, and with the pH adjusted to 9.5 using dilute sulphuric acid.
- the washes were carried out in tergotometers at a liquor to cloth ratio of 200:1 for 30 minutes at 30°C and 90 rpm. After each wash, two rinses were carried out at a liquor to cloth ratio of 200:1 and the fabrics were line dried.
- the "cocktails" of heavy metal ions were as follows: Wash Rinse Cu 2+ 0.5 ppm 0.05 ppm Fe 3+ 2.5 ppm 0.1 ppm Mn 2+ 2.0 ppm 2.0 ppm Zn 2+ 5.0 ppm 1.1 ppm
- Example 3 The procedure of Example 3 was repeated using the same powder formulation but the pH was adjusted to the lower value of 8.5, and a total of 10 washes per example were carried out. Reflectances were measured after 5 and 10 washes.
- the sequestrants used were IDS (invention) and NTA (comparative), at a level of 1.25 wt%.
- a detergent powder composition was prepared by conventional spray-drying and postdosing techniques to the following formulation: wt% Sodium linear alkylbenzene sulphonate (NaLAS) 22.92 Sodium silicate (anhydrous) 5.37 Sodium tripolyphosphate 18.67 Sodium carboxymethyl cellulose 0.25 Polyacrylate polymer 0.70 Calcite 10.00 Sodium sulphate, fluorescer, zeolite, perfume, enzymes, water, impurities, sequestrant if present to 100 Comparative Example T: no sequestrant Example 5 IDS at 0.625% of the formulation.
- the coloured monitors were line-dried in the shade.
- Fabric Visual assessment (grey scale, 1-5) T No sequestrant 5 IDS 0.625% Red linen 1.9 2.5 Yellow cotton 2.3 2.8 Deep green cotton 2.9 3.1 Light blue Cotton 2.5 2.9 Lavender cotton 3.1 3.3 Light blue poly-cotton 2.9 3.1
- the fabrics used were cotton dyed with Direct Red 80. They were pre-treated with demineralised water containing 0.5 ppm Cu 2+ ions and having the pH adjusted to 6.5 by means of sodium hydroxide. The pretreatment was carried out using tergotometers at 30°C, 90 rpm and a liquor to cloth ratio of 200:1, then the fabrics were line dried.
- the fabrics were then washed in a wash liquor containing 2.5 g/l of the detergent composition used in Example 3, and 0.5 ppm Cu 2+ , in 20/6° Ca/Mg French hard water): the pH was adjusted from 9.9 to 9.5 using dilute sulphuric acid.
- the washes were carried out in tergotometers at 30°C, 90 rpm and a liquor to cloth ratio of 200:1.
- the washes were followed by two rinses in 20/6° Ca/Mg French hard water containing 0.05 ppm Cu 2+ at a liquor to cloth ratio of 200:1, and the fabrics were then line dried.
- the sequestrants, where present, were dosed directly into the wash liquor in the amounts indicated in the table below (percentages based on the detergent composition).
- Detergent composition without sequestrant -11.98 - 8.51 - 6.86 6 IDS 1.25% - 3.50 - 2.64 - 0.31 W NTA 1.71% - 6.44 - 4.42 - 1.50 X STP 3.85% -12.32 - 9.55 - 3.18
- Example 6 The procedure of Example 6 was repeated using, instead of copper ions alone, the "cocktails" of heavy metal ions (different for wash and for rinse) used in Example 3. For the pretreatment step the same "cocktail" was used as for the wash.
- Example 6 The procedure of Example 6 was repeated using six different formulations of varying pH.
- the tergotometer method of previous examples was used.
- the initial pH was adjusted slightly downwards, using dilute sulphuric acid, to mimic the effect of soil on wash pH.
- Example 6 The washing and rinsing regime was as described in Example 6, and colour changes were monitored as reflectance changes ( ⁇ R) at 620 nm.
- Example 17 A multi-wash tergotometer experiment was carried out using the detergent composition of Example 3, without sequestrant (Comparative Example EE) or containing 1 wt% of IDS (Example 17). The colour care benefit was determined using a range of coloured cotton monitors.
- the wash conditions were as follows:
- the washed fabrics were line-dried in the shade.
- the wash conditions were as follows:
- the washed fabrics were line-dried in the shade.
- the washed fabrics were line-dried in the shade.
- Stain removal results are shown below. These are a measure of the stain removed so the larger the figure, the better the result. The improvement here was statistically significant and visually apparent.
- Phosphate-built and zeolite-built detergent powder formulations of high bulk density (850-900 g/l) containing IDS were prepared to the following formulations: 20 21 22 NaLAS 15.63 22.82 18.00 Nonionic C 12-15 7EO 7.00 3.25 Na sulphate 1.30 Na tripolyphosphate 30.57 SCMC 0.60 0.77 1.00 Polymer** 1.96 2.00 Zeolite (78%) 44.65 23.13 50.00 Na carbonate 12.12 6.73 19.00 Na bicarbonate 17.77 5.87 Enzyme 6 2.00 Enzyme 7 0.51 Enzyme 4 0.45 IDS 1.25 1.25 1.25 Fluorescer, perfume, speckles, water to 100 to 100 to 100 0.25% solution pH 9.8 10.0 10.6
- Liquid detergent compositions containing IDS Liquid detergent compositions containing IDS
- Liquid detergent compositions were prepared to the following formulations: 23 24 NaLAS 12.50 10.50 Nonionic C 12-15 7EO 2.25 SLES 6.66 2.25 Na tripolyphosphate 15.00 Mg sulphate (7H 2 O) 2.50 Na tetraborate 4.00 Boric acid 0.50 Glycerine CP 6.00 Polymer 0.12 Preservatives 0.08 Blue dye 0.02 IDS 1.25 1.25 Perfume 0.15 0.40 Water to 100 to 100 0.25% solution pH 6.5 9.0
- a liquiid detergent composition containing a lower level of IDS was prepared to the following formulation.
- the IDS was incorporated in liquid form (30% active).
- Ingredient Weight % Sodium linear alkylbenzene sulphonate 8.655
- Nonionic surfactant 7EO 2.885 Zeolite 20.000 Glycerol 4.000 Borax 3.200 Citric acid 2.500 Sodium hydroxide 1.719 IDS (sodium salt) 0.667 Silicone oil/silica 0.200 Sodium xylene sulphonate 0.200 Calcium chloride dihydrate 0.150
- Protease 0.100 0.100
- Fluorescer 0.025 Perfume 0.250 Preservative 0.016 Water to 100% 42.378
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Abstract
Description
- IDS:
- iminodisuccinate, tetrasodium salt, ex Bayer
- NTA:
- nitrilotriacetate, trisodium salt, ex Aldrich
- EDTMP:
- ethylenediaminetetramethylene phosphonate, calcium salt (Dequest (Trade Mark) 2047 ex Monsanto)
- EDDS:
- ethylenediamine disuccinate, tetrasodium salt (Octaquest (Trade Mark) E30 ex Associated Octel)
- STP:
- sodium tripolyphosphate (Polyphos technical grade ex Thai Polyphosphate and Chemicals)
Example | Sequestrant | Lower sequestrant level (0.5%) | Higher sequestrant level (1.0%) | ||
pH 9.5 | pH 6.5 | pH 9.5 | pH 6.5 | ||
A | Water alone | + 2.40 | + 2.49 | + 2.40 | + 2.49 |
B | Water + Cu2+ | - 5.62 | -20.00 | - 5.62 | -20.00 |
1 | IDS | + 1.04 | + 0.95 | + 2.64 | + 1.22 |
C | NTA | + 4.05 | + 3.38 | + 4.95 | + 4.11 |
D | EDTMP | + 0.87 | -10.23 | + 1.06 | - 6.10 |
E | EDDS | + 4.43 | - 4.35 | + 4.91 | + 3.98 |
F | STP | - 6.03 | -20.90 | -15.72 | -15.71 |
G | Mg silicate - | 3.88 | -15.40 | - 4.18 | -13.27 |
Cu2+ | 0.5 ppm |
Fe3+ | 2.5 ppm |
Mn2+ | 2.0 ppm |
Zn2+ | 5.0 ppm |
Example | Sequestrant | 0.5% | 1.0% |
H | Water alone | - 0.20 | - 0.20 |
J | Water + ions | - 1.66 | - 1.66 |
2 | IDS | - 0.32 | - 0.38 |
K | NTA | - 1.62 | - 1.30 |
L | EDTMP | - 0.54 | - 0.54 |
M | EDDS | - 2.37 | - 2.03 |
N | STP | - 0.89 | - 0.71 |
P | Mg silicate | - 2.23 | - 1.71 |
wt% | |
Sodium linear alkylbenzene sulphonace (NaLAS) | 22.92 |
Sodium silicate (anhydrous) | 4.67 |
Sodium tripolyphosphate | 18.67 |
Sodium carboxymethyl cellulose | 0.25 |
Polyacrylate polymer | 0.70 |
Calcite | 10.00 |
Sodium sulphate, water, impurities, sequestrant if present | to 100 |
Comparative Example Q | no sequestrant |
Example 3 | plus 1.25 wt% IDS |
Wash | Rinse | |
Cu2+ | 0.5 ppm | 0.05 ppm |
Fe3+ | 2.5 ppm | 0.1 ppm |
Mn2+ | 2.0 ppm | 2.0 ppm |
Zn2+ | 5.0 ppm | 1.1 ppm |
Example | Sequestrant | ΔR (450 nm) | |
after 1 wash | after 5 washes | ||
Q | None | - 1.71 | - 2.60 |
3 | IDS | - 1.25 | - 1.63 |
Example | Sequestrant | ΔR (450 nm) | |
after 5 washes | after 10 washes | ||
R | None | - 0.85 | - 1.72 |
4 | IDS | + 0.42 | + 0.66 |
S | NTA | - 0.11 | - 0.57 |
wt% | |
Sodium linear alkylbenzene sulphonate (NaLAS) | 22.92 |
Sodium silicate (anhydrous) | 5.37 |
Sodium tripolyphosphate | 18.67 |
Sodium carboxymethyl cellulose | 0.25 |
Polyacrylate polymer | 0.70 |
Calcite | 10.00 |
Sodium sulphate, fluorescer, zeolite, perfume, enzymes, water, impurities, sequestrant if present | to 100 |
Comparative | Example T: no sequestrant |
Example 5 | IDS at 0.625% of the formulation. |
- Trace levels of iron (2.5-ppm) and copper (0.5 ppm)
- Product dosage: 5 g/l (formulation below)
- Water hardness: 10 °FH Ca
- Liquor to cloth ratio in the main wash: 6 to 1
- Liquor to cloth ratio in the rinse: 20 to 1
- Number of rinses: 2
- Rubbing time: 30 seconds per piece.
- Wash temperature: 30 °C.
- Total washload weight: 1 kg.
Fabric | ΔE | |
T (no sequestrant) | 5 (IDS 0.625%) | |
Red linen | 4.3 | 3.7 |
Yellow cotton | 7.3 | 6.2 |
Deep green cotton | 2.0 | 1.8 |
Light blue Cotton | 7.7 | 6.8 |
Lavender cotton | 4.3 | 3.9 |
Fabric | Visual assessment (grey scale, 1-5) | |
T No sequestrant | 5 IDS 0.625% | |
Red linen | 1.9 | 2.5 |
Yellow cotton | 2.3 | 2.8 |
Deep green cotton | 2.9 | 3.1 |
Light blue Cotton | 2.5 | 2.9 |
Lavender cotton | 3.1 | 3.3 |
Light blue poly-cotton | 2.9 | 3.1 |
Example | 200:1 tergo | 25:1 handwash | 7:1 handwash | |
U | After pretreatment | -19.93 | -19.93 | -19.93 |
V | Detergent composition without sequestrant | -11.98 | - 8.51 | - 6.86 |
6 | IDS 1.25% | - 3.50 | - 2.64 | - 0.31 |
W | NTA 1.71% | - 6.44 | - 4.42 | - 1.50 |
X | STP 3.85% | -12.32 | - 9.55 | - 3.18 |
Example | 200:1 tergo | |
Y | After pretreatment | -23.68 |
Z | Detergent composition without sequestrant | -13.40 |
7 | IDS 1.25% | - 5.69 |
8 | HIDS 1.25% | - 5.28 |
Example | 200:1 tergo | 25:1 handwash | 7:1 handwash | |
AA | After pretreatment | -18.08 | -18.08 | -18.08 |
BB | Detergent composition without sequestrant | -10.61 | -14.83 | -14.10 |
9 | IDS 1.25% | - 2.59 | - 7.59 | - 7.73 |
CC | NTA 1.71% | - 3.38 | - 8.22 | -11.50 |
DD | STP 3.85% | - 7.76 | -15.69 | -13.11 |
Ex. | pH | ΔR at 620 nm | ||||
Initial | Adjusted | After pretreatment | No sequestrant | IDS 1.25% | NTA 1.71% | |
10 | 8.8 | 8.6 | -20.31 | -8.52 | -3.11 | -4.37 |
11 | 9.4 | 8.9 | -19.97 | -8.55 | -2.40 | -3.59 |
12 | 9.6 | 9.1 | -19.99 | -7.37 | -1.80 | -2.30 |
13 | 9.6 | 9.1 | -18.50 | -4.23 | -2.14 | -3.30 |
14 | 9.9 | 9.4 | -19.72 | -7.83 | -2.27 | -3.52 |
15 | 10.3 | 9.8 | -19.27 | -4.13 | -2.14 | -3.30 |
16 | 10.5 | 10.0 | -19.50 | -3.47 | -1.60 | -1.92 |
- Trace levels of metal ions:
Fe = 2.5 ppm, Cu = 0.5 ppm, Zn = 5 ppm, Mn = 2 ppm - Trace level of NaOCl: 0.5 ppm
- Product dosage: 2.5 g/l (formulation below)
- Water hardness (wash and rinse): 26 °FH Ca
- Liquor to cloth ratio in the wash and rinse: 200 to 1
- Wash time: 20 minutes
- Number of rinses: 2
- Agitation: 75 rpm
- Wash temperature: 40 °C.
Colour of cotton monitor | Wavelength measured | Reflectance change | |
Example EE (No sequestrant) | Example 17 (IDS 1.0%) | ||
Yellow | 460 nm | 13.59 | 0.51 |
Orange | 510 nm | 3.25 | 0.72 |
Navy | 620 nm | 2.97 | 0.79 |
wt% | |
Sodium linear alkylbenzene sulphonate (NaLAS) | 23.71 |
Sodium silicate (anhydrous) | 7.37 |
Sodium tripolyphosphate | 18.77 |
Sodium carbonate | 7.00 |
Sodium carboxymethyl cellulose | 0.52 |
Polyacrylate polymer | 0.54 |
Calcite | 9.88 |
Sodium sulphate, fluorescer, zeolite, perfume, enzymes, water, impurities, sequestrant if present | to 100 |
Comparative Example FF | no sequestrant |
Comparative Example GG | 1 wt% NTA |
Example 18 | 1 wt% IDS |
- Trace levels of metal ions: Fe = 0.1 ppm, Cu = 0.01 ppm, Zn = 0.1 ppm, Mn = 0.2 ppm
- Product dosage: 2 g/l
- Water hardness:
- Wash: 45 °FH (Ca:Mg 3:1)
- Rinse: 25 °FH (Ca:Mg 3:1)
- Liquor to cloth ratio in the soak and wash: 7 to 1
- Liquor to cloth ratio in the rinse: 3 to 1
- Soak time: 20 minutes
- Number of rinses: 2
- Rubbing time: 30 seconds per piece
- Wash temperature: 22°C
- Total load weight: ca. 700 g.
Example | Sequestrant | ΔE (residual stain) | ||
Blood | Tea | Red mud | ||
FF | None | 7.84 | 30.13 | 19.66 |
18 | IDS | 7.20 | 28.90 | 14.98 |
GG | NTA | 7.62 | 30.00 | 19.86 |
- Trace levels of metal ions:
Fe = 2.5 ppm, Cu = 0.5 ppm, Zn = 5 ppm, Mn = 2 ppm - Product dosage: 2.5 g/l
- Water hardness (wash and rinse): 26 °FH Ca
- Liquor to cloth ratio in the wash and rinse: 200 to 1
- Wash time: 20 minutes
- Number of rinses: 2
- Agitation: 75 rpm
- Wash temperature: 40°C.
Example | Sequestrant | ΔR 580 (Stain removal) |
Red wine (Empa 114) | ||
HH | None | 12.67 |
19 | IDS | 14.59 |
20 | 21 | 22 | |
NaLAS | 15.63 | 22.82 | 18.00 |
Nonionic C12-15 7EO | 7.00 | 3.25 | |
Na sulphate | 1.30 | ||
Na tripolyphosphate | 30.57 | ||
SCMC | 0.60 | 0.77 | 1.00 |
Polymer** | 1.96 | 2.00 | |
Zeolite (78%) | 44.65 | 23.13 | 50.00 |
Na carbonate | 12.12 | 6.73 | 19.00 |
Na bicarbonate | 17.77 | 5.87 | |
Enzyme 6 | 2.00 | ||
Enzyme 7 | 0.51 | ||
Enzyme 4 | 0.45 | ||
IDS | 1.25 | 1.25 | 1.25 |
Fluorescer, perfume, speckles, water | to 100 | to 100 | to 100 |
0.25% solution pH | 9.8 | 10.0 | 10.6 |
23 | 24 | |
NaLAS | 12.50 | 10.50 |
Nonionic C12-15 7EO | 2.25 | |
SLES | 6.66 | 2.25 |
Na tripolyphosphate | 15.00 | |
Mg sulphate (7H2O) | 2.50 | |
Na tetraborate | 4.00 | |
Boric acid | 0.50 | |
Glycerine CP | 6.00 | |
Polymer | 0.12 | |
Preservatives | 0.08 | |
Blue dye | 0.02 | |
IDS | 1.25 | 1.25 |
Perfume | 0.15 | 0.40 |
Water | to 100 | to 100 |
0.25% solution pH | 6.5 | 9.0 |
Ingredient | Weight % |
Sodium linear alkylbenzene sulphonate | 8.655 |
Nonionic surfactant 7EO | 2.885 |
Zeolite | 20.000 |
Glycerol | 4.000 |
Borax | 3.200 |
Citric acid | 2.500 |
Sodium hydroxide | 1.719 |
IDS (sodium salt) | 0.667 |
Silicone oil/silica | 0.200 |
Sodium xylene sulphonate | 0.200 |
Calcium chloride dihydrate | 0.150 |
Soil release polymer (PET/POET) | 0.100 |
Sodium polyacrylate (Sokalan PA50) | 0.100 |
Protease | 0.100 |
Amylase | 0.100 |
Fluorescer | 0.025 |
Perfume | 0.250 |
Preservative | 0.016 |
Water to 100% | 42.378 |
Claims (9)
- Use of a non-bleaching laundry detergent composition comprising surfactant, builder, and optionally other non-bleach detergent ingredients, and also containing from 0.05 to 1.5 wt% of a compound of the formula I: wherein Y is H or OH, and X is H or a solubilising cation to protect new white or coloured textile fabrics from colour degradation on laundering.
- Use of a detergent composition as claimed in claim 1, characterised in that it comprises:(a) from 5 to 60 wt% of one or more detergent surfactants,(b) from 10 to 80 wt% of one or more detergency builders,(c) from 0.05 to 1.5 wt% of a compound of the formula I,(d) optionally other non-bleach detergent ingredients to 100 wt%.
- Use of a detergent composition as claimed in claim 1 or claim 2, characterised in that it comprises from 0.2 to 1.5 wt% of the compound of the formula I.
- Use of a detergent composition as claimed in any preceding claim, characterised in that the compound of the formula I is iminodisuccinic acid or a salt, preferably the sodium salt, thereof.
- Use of a detergent composition as claimed in any preceding claim, characterised in that it has an 0.25% aqueous solution pH (in demineralised water at 30°C) not exceeding 10.5, preferably not exceeding 10.0, more preferably not exceeding 9.5.
- Use of a detergent composition as claimed in any preceding claim, characterised in that it is in particulate form.
- Use of a detergent composition as claimed in any one of claims 1 to 5, characterised in that it is in liquid form.
- A method of protecting new white or coloured textile fabrics from colour degradation on laundering, which comprises laundering the fabrics by hand or machine in a wash liquor containing the use of a detergent composition as claimed in any one of claims 1 to 7.
- Use of non-bleaching laundry detergent composition comprising surfactant, builder, and optionally other non-bleach detergent ingredients, and also containing from 0.05 to 1.5 wt% of a compound of the formula I: wherein Y is H or OH, and X is H or a solubilising cation, as a chlorine scavenger to prevent the fading of chlorine-sensitive dyes on coloured textile fabrics during laundering.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9827225 | 1998-12-10 | ||
GBGB9827225.5A GB9827225D0 (en) | 1998-12-10 | 1998-12-10 | Detergent compositions |
GBGB9927101.7A GB9927101D0 (en) | 1998-12-10 | 1999-11-16 | Detergent compositions |
GB9927101 | 1999-11-16 | ||
PCT/GB1999/004139 WO2000034427A1 (en) | 1998-12-10 | 1999-12-09 | Detergent compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1137752A1 EP1137752A1 (en) | 2001-10-04 |
EP1137752B1 true EP1137752B1 (en) | 2005-04-20 |
Family
ID=26314818
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99973306A Expired - Lifetime EP1137752B1 (en) | 1998-12-10 | 1999-12-09 | Use of detergent compositions |
Country Status (13)
Country | Link |
---|---|
EP (1) | EP1137752B1 (en) |
CN (1) | CN1271190C (en) |
AT (1) | ATE293671T1 (en) |
AU (1) | AU4519100A (en) |
BR (1) | BR9916083A (en) |
CA (1) | CA2353958A1 (en) |
DE (1) | DE69924874T2 (en) |
ES (1) | ES2238876T3 (en) |
HU (1) | HUP0104685A3 (en) |
MX (1) | MXPA01005821A (en) |
PL (1) | PL348830A1 (en) |
TR (1) | TR200101590T2 (en) |
WO (1) | WO2000034427A1 (en) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9930240D0 (en) * | 1999-12-21 | 2000-02-09 | Unilever Plc | Detergent compositions |
GB0013501D0 (en) | 2000-06-02 | 2000-07-26 | Unilever Plc | Detergent compositions |
AU2001267449A1 (en) * | 2000-06-05 | 2001-12-17 | Dowding, Michael K. | Detergent composition |
GB0030877D0 (en) | 2000-12-18 | 2001-01-31 | Unilever Plc | Enhancement of air bleaching catalysts |
GB0106285D0 (en) | 2001-03-14 | 2001-05-02 | Unilever Plc | Air bleaching catalysts with moderating agent |
AU2002237306B2 (en) | 2001-03-14 | 2005-03-24 | Unilever Plc | Bleaching catalysts with unsaturated surfactant and antioxidants |
GB0121394D0 (en) * | 2001-09-04 | 2001-10-24 | Unilever Plc | Improvements relating to fabric treatment compositions and process of fabric treatment |
GB0222501D0 (en) | 2002-09-27 | 2002-11-06 | Unilever Plc | Composition and method for bleaching a substrate |
GB0520380D0 (en) | 2005-10-07 | 2005-11-16 | Unilever Plc | Stain removal |
EP2152842B1 (en) * | 2007-05-11 | 2017-10-11 | Ecolab Inc. | Cleaning of polycarbonate |
DE102007047433A1 (en) * | 2007-10-04 | 2009-04-09 | Lanxess Deutschland Gmbh | Liquid washing and liquid cleaning agents |
US9074167B2 (en) * | 2011-09-28 | 2015-07-07 | Jilin Hengtai Garment Washing and Dyeing Science and Technology Institute | Color enhancing detergent for colored textile and preparation method therefor |
JP6111774B2 (en) * | 2013-03-22 | 2017-04-12 | セイコーエプソン株式会社 | Ink jet ink, recording apparatus and recorded matter |
PT3011004T (en) | 2013-06-20 | 2017-10-19 | Chemsenti Ltd | Bleach and oxidation catalyst |
CA2921480A1 (en) | 2013-08-16 | 2015-02-19 | Chemsenti Limited | Composition |
CN110072985B (en) * | 2016-12-15 | 2021-04-20 | 高露洁-棕榄公司 | Fabric color protection using citric acid and iminodisuccinate in fine fabric liquid detergents |
CN107287041A (en) * | 2017-05-30 | 2017-10-24 | 花舜 | A kind of environmental-protective detergent |
WO2020093280A1 (en) * | 2018-11-07 | 2020-05-14 | Kemira Oyj | A composition for use as peroxide stabilizer |
DE102018131883A1 (en) * | 2018-12-12 | 2020-06-18 | Henkel Ag & Co. Kgaa | Detergent or cleaning agent containing iminodisuccinate and / or iminotrisuccinate |
EP3967742A1 (en) | 2020-09-15 | 2022-03-16 | WeylChem Performance Products GmbH | Compositions comprising bleaching catalyst, manufacturing process thereof, and bleaching and cleaning agent comprising same |
EP4008765A1 (en) | 2020-12-07 | 2022-06-08 | WeylChem Performance Products GmbH | Compositions comprising protonated triazacyclic compounds and bleaching agent and cleaning agent comprising same |
EP4296343A1 (en) | 2022-06-24 | 2023-12-27 | WeylChem Performance Products GmbH | Compositions comprising protonated triazacyclic compounds and manganese(ii) acetate, manufacturing thereof, and bleaching and cleaning agent comprising same |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB474082A (en) * | 1936-03-24 | 1937-10-25 | Ig Farbenindustrie Ag | Process for avoiding or delaying the formation of precipitates in aqueous liquids or for redissolving the same, particularly the precipitates formed owing to the hardness of water |
US3697453A (en) * | 1971-03-08 | 1972-10-10 | Pfizer | Iminodisuccinic acid salts as detergent builders |
WO1991017234A1 (en) * | 1990-05-08 | 1991-11-14 | The Procter & Gamble Company | Granular laundry detergent compositions containing chlorine scavengers |
DE4024552A1 (en) * | 1990-08-02 | 1992-02-06 | Henkel Kgaa | DERIVATIVE AMINO STINIC ACID AS A COMPLEXING AGENT |
DE4311440A1 (en) * | 1993-04-07 | 1994-10-13 | Henkel Kgaa | Builder for detergents or cleaners |
JP3197990B2 (en) * | 1993-06-23 | 2001-08-13 | 花王株式会社 | Detergent composition |
-
1999
- 1999-12-09 MX MXPA01005821A patent/MXPA01005821A/en unknown
- 1999-12-09 PL PL99348830A patent/PL348830A1/en unknown
- 1999-12-09 DE DE69924874T patent/DE69924874T2/en not_active Expired - Lifetime
- 1999-12-09 BR BR9916083-8A patent/BR9916083A/en not_active Application Discontinuation
- 1999-12-09 CA CA002353958A patent/CA2353958A1/en not_active Abandoned
- 1999-12-09 AU AU45191/00A patent/AU4519100A/en not_active Abandoned
- 1999-12-09 CN CN99814218.2A patent/CN1271190C/en not_active Expired - Fee Related
- 1999-12-09 EP EP99973306A patent/EP1137752B1/en not_active Expired - Lifetime
- 1999-12-09 AT AT99973306T patent/ATE293671T1/en not_active IP Right Cessation
- 1999-12-09 WO PCT/GB1999/004139 patent/WO2000034427A1/en active IP Right Grant
- 1999-12-09 TR TR2001/01590T patent/TR200101590T2/en unknown
- 1999-12-09 HU HU0104685A patent/HUP0104685A3/en unknown
- 1999-12-09 ES ES99973306T patent/ES2238876T3/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
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ES2238876T3 (en) | 2005-09-01 |
HUP0104685A3 (en) | 2002-12-28 |
HUP0104685A2 (en) | 2002-04-29 |
CN1271190C (en) | 2006-08-23 |
CN1329657A (en) | 2002-01-02 |
CA2353958A1 (en) | 2000-06-15 |
AU4519100A (en) | 2000-06-26 |
DE69924874T2 (en) | 2005-11-17 |
BR9916083A (en) | 2001-09-04 |
EP1137752A1 (en) | 2001-10-04 |
WO2000034427A1 (en) | 2000-06-15 |
ATE293671T1 (en) | 2005-05-15 |
TR200101590T2 (en) | 2001-11-21 |
DE69924874D1 (en) | 2005-05-25 |
PL348830A1 (en) | 2002-06-17 |
MXPA01005821A (en) | 2002-03-27 |
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