EP1527154B1 - Detergent compositions - Google Patents
Detergent compositions Download PDFInfo
- Publication number
- EP1527154B1 EP1527154B1 EP03792208A EP03792208A EP1527154B1 EP 1527154 B1 EP1527154 B1 EP 1527154B1 EP 03792208 A EP03792208 A EP 03792208A EP 03792208 A EP03792208 A EP 03792208A EP 1527154 B1 EP1527154 B1 EP 1527154B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- copolymer
- laundry detergent
- mole
- detergent composition
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 44
- 239000003599 detergent Substances 0.000 title claims description 29
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 19
- 229920001577 copolymer Polymers 0.000 claims description 18
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 17
- 239000002689 soil Substances 0.000 claims description 16
- -1 alkylbenzene sulphonate Chemical class 0.000 claims description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 239000004615 ingredient Substances 0.000 claims description 10
- 239000010457 zeolite Substances 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 229920005604 random copolymer Polymers 0.000 claims description 5
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 5
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 description 22
- 239000000843 powder Substances 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 239000007844 bleaching agent Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 10
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 10
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 10
- 239000002243 precursor Substances 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 239000000344 soap Substances 0.000 description 6
- 239000000264 sodium ferrocyanide Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000004115 Sodium Silicate Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000975 dye Substances 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 5
- 229910052911 sodium silicate Inorganic materials 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- FYUWIEKAVLOHSE-UHFFFAOYSA-N ethenyl acetate;1-ethenylpyrrolidin-2-one Chemical compound CC(=O)OC=C.C=CN1CCCC1=O FYUWIEKAVLOHSE-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000010705 motor oil Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 102000013142 Amylases Human genes 0.000 description 2
- 108010065511 Amylases Proteins 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 102000004882 Lipase Human genes 0.000 description 2
- 239000004367 Lipase Substances 0.000 description 2
- 108090001060 Lipase Proteins 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 235000019418 amylase Nutrition 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 150000001860 citric acid derivatives Chemical class 0.000 description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- 229940071087 ethylenediamine disuccinate Drugs 0.000 description 2
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- 235000019421 lipase Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-K pentetate(3-) Chemical compound OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O QPCDCPDFJACHGM-UHFFFAOYSA-K 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229940045872 sodium percarbonate Drugs 0.000 description 2
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000002888 zwitterionic surfactant Substances 0.000 description 2
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 1
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
- MPJQXAIKMSKXBI-UHFFFAOYSA-N 2,7,9,14-tetraoxa-1,8-diazabicyclo[6.6.2]hexadecane-3,6,10,13-tetrone Chemical compound C1CN2OC(=O)CCC(=O)ON1OC(=O)CCC(=O)O2 MPJQXAIKMSKXBI-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- LVVZBNKWTVZSIU-UHFFFAOYSA-N 2-(carboxymethoxy)propanedioic acid Chemical class OC(=O)COC(C(O)=O)C(O)=O LVVZBNKWTVZSIU-UHFFFAOYSA-N 0.000 description 1
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 1
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
- JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical class OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
- WFRXSOIFNFJAFL-UHFFFAOYSA-N P1(OCCCCO1)=O.C(CN)N Chemical compound P1(OCCCCO1)=O.C(CN)N WFRXSOIFNFJAFL-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical compound OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 239000004193 disodium 5'-ribonucleotide Substances 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- WMKBLOXVQBXSQM-UHFFFAOYSA-N n'-(2-aminoethyl)ethane-1,2-diamine;2-hydroxy-1,3,2$l^{5}-dioxaphosphocane 2-oxide Chemical compound NCCNCCN.OP1(=O)OCCCCCO1 WMKBLOXVQBXSQM-UHFFFAOYSA-N 0.000 description 1
- WKGHJBXTMFXUNA-UHFFFAOYSA-N n,n,n',n'-tetrahexadecylethane-1,2-diamine Chemical compound CCCCCCCCCCCCCCCCN(CCCCCCCCCCCCCCCC)CCN(CCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCC WKGHJBXTMFXUNA-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 229940055076 parasympathomimetics choline ester Drugs 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical group CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
Definitions
- the present invention relates to laundry detergent compositions containing certain vinyl pyrrolidone copolymers.
- the compositions exhibit improved detergency on oily soils as well as reduced soil redeposition during the wash.
- Polyvinyl pyrrolidone and some related polymers are known ingredients of laundry detergent compositions, providing the benefit of reduced dye transfer between fabrics in a mixed load.
- Laundry detergent compositions containing polyvinyl pyrrolidone as a dye transfer inhibitor are disclosed, for example, in WO 92 18597A, WO 94 03567A, WO 95 03390A, WO 95 17496A, WO 95 27028A and WO 95 34627A (Procter & Gamble), and WO 94 06354A, WO 94 24249A and WO 97 03166A (Henkel).
- GB 1 354 498 discloses laundry detergent compositions containing vinyl pyrrolidone/vinyl acetate copolymers as antiredeposition agents. During the wash, the polymers effectively prevent or reduce redeposition onto washed fabrics of soil suspended in the wash liquor. Polyvinyl pyrrolidone itself is stated to be ineffective.
- vinyl pyrrolidone/vinyl alcohol copolymers are also effective to enhance oily soil detergency, especially in detergent compositions containing anionic surfactants, more especially alkylbenzene sulphonate.
- the present invention provides a the use of a water-soluble random copolymer of vinyl pyrrolidone and vinyl acetate in a laundry detergent composition comprising an organic surfactant and optionally a detergency builder to improve the oily soil detergency of the composition.
- PVP/PA copolymer The random copolymer of vinyl pyrrolidone/vinyl acetate used in accordance with the present invention will be referred to hereinafter for convenience as a PVP/PA copolymer.
- the PVP/PA copolymer preferably contains not more than 30 mole% of vinyl acetate (VA) monomer units. Copolymers containing higher proportions of VA units are less water-soluble and therefore less preferred. More preferably the copolymer contains not more than 50 mole% of VA units.
- VA vinyl acetate
- the copolymer contains from 50 to 70 mole% of vinyl pyrrolidone (VP) monomer units and from 30 to 50 mole% of VA units.
- VP vinyl pyrrolidone
- the copolymer preferably has a molecular weight within the range of from 10 000 to 100 000, more preferably from 25 000 to 75 000.
- PVP/PA copolymers A wide selection of PVP/PA copolymers is available from International Speciality Products (ISP). These are supplied as solutions (clear viscous liquids) in ethanol, isopropanol or water, or as solid (white powder). Some examples are shown in the table below.
- Grade Solvent or form Mole ratio VP:VA Approximate molecular weight E-335 Ethanol 30:70 28 800 E-535 50:50 36 700 E-635 60:40 38 200 E-735 70:30 56 700 1-335 Isopropanol 35:65 12 700 I-535 50:50 19 500 I-735 70:30 22 300 W-735 Water 70:30 27 300 S-630 Solid 60:40 51 000
- the solutions have a solids content of approximately 50 wt%.
- PVP/PA copolymers are also available from BASF as the Luviskol (Trade Mark) VA series. Luviskol VA Solvent or form Mole ratio VP:VA 28E Ethanol 20:80 37E 30:70 55E 50:50 64E 60:40 28I Isopropanol 20:80 37I 30:70 55I 50:50 64I 60:40 64W Water 60:40 73W 70:30 64 powder Solid 60:40
- polymers are marketed as film-formers for cosmetic and personal products, and for use in hair styling formulations such as mousses, gels and setting lotions.
- the laundry detergent composition is a laundry detergent composition
- the polymer is present in an amount sufficient to enhance oily soil detergency.
- the polymer is present in an amount of from 0.5 to 3 wt%, preferably from 1 to 2 wt%.
- the detergent composition may suitably comprise:
- the organic surfactant is the organic surfactant
- the detergent composition in accordance with the invention may contain any organic surfactants (detergent-active compounds) suitable for incorporation into laundry detergent compositions.
- Detergent-active compounds may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent-active compounds, and mixtures thereof.
- suitable detergent-active compounds are available and are fully described in the literature, for example, in "Surface-Active Agents and Detergents", Volumes I and II, by Schwartz, Perry and Berch.
- the preferred detergent-active compounds that can be used are soaps and synthetic non-soap anionic and nonionic compounds.
- the total amount of surfactant present is suitably within the range of from 5 to 60 wt%, preferably from 5 to 40 wt%.
- Anionic surfactants are well-known to those skilled in the art. Examples include alkylbenzene sulphonates, particularly linear alkylbenzene sulphonates having an alkyl chain length of C 8 -C 15 ; primary and secondary alkylsulphates, particularly C 8 -C 20 primary alkyl sulphates; alkyl ether sulphates; olefin sulphonates; alkyl xylene sulphonates; dialkyl sulphosuccinates; and fatty acid ester sulphonates.
- Sodium salts are generally preferred.
- Nonionic surfactants that may be used include the primary and secondary alcohol ethoxylates, especially the C 8 -C 20 aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and more especially the C 10 -C 15 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol.
- Non-ethoxylated nonionic surfactants include alkylpolyglycosides, glycerol monoethers, and polyhydroxyamides (glucamide).
- Cationic surfactants that may be used include quaternary ammonium salts of the general formula R 1 R 2 R 3 R 4 N + X - wherein the R groups are long or short hydrocarbyl chains, typically alkyl, hydroxyalkyl or ethoxylated alkyl groups, and X is a solubilising anion (for example, compounds in which R 1 is a C 8 -C 22 alkyl group, preferably a C 8 -C 10 or C 12 -C 14 alkyl group, R 2 is a methyl group, and R 3 and R 4 , which may be the same or different, are methyl or hydroxyethyl groups); and cationic esters (for example, choline esters).
- R 1 is a C 8 -C 22 alkyl group, preferably a C 8 -C 10 or C 12 -C 14 alkyl group
- R 2 is a methyl group
- R 3 and R 4 which may be the same or different, are methyl or
- Amphoteric surfactants and/or zwitterionic surfactants may also be present.
- Preferred amphoteric surfactants are amine oxides. These are materials of the general formula R 1 R 2 R 3 N ⁇ O wherein R 1 is typically a C 8 -C 18 alkyl group, for example, C 12 -C 14 alkyl, and R 2 and R 3 , which may be the same or different, are C 1 -C 3 alkyl or hydroxyalkyl groups, for example, methyl groups.
- the most preferred amine oxide is coco dimethylamine oxide.
- Preferred zwitterionic surfactants are betaines, and especially amidobetaines.
- Preferred betaines are C 8 -C 18 alkyl amidoalkylbetaines, for example, coco amidopropyl betaine (CAPB).
- CAPB coco amidopropyl betaine
- the composition comprises a sulphonate anionic surfactant.
- the sulphonate anionic surfactant comprises linear alkylbenzene sulphonate (LAS).
- the compositions contains from 3 to 30 wt%, more preferably from 10 to 25 wt%, of LAS.
- the detergent compositions in accordance with the invention also contain one or more detergency builders.
- the total amount of detergency builder in the compositions may suitably range from 5 to 80 wt%, preferably from 10 to 60 wt%.
- Preferred builders are alkali metal aluminosilicates, more especially crystalline alkali metal aluminosilicates (zeolites), preferably in sodium salt form.
- zeolites crystalline alkali metal aluminosilicates
- Zeolite builders may suitably be present in a total amount of from 5 to 60 wt%, preferably from 10 to 50 wt%.
- the zeolites may be supplemented by other inorganic builders, for example, amorphous aluminosilicates, or layered silicates such as SKS-6 ex Clariant.
- the zeolites may be supplemented by organic builders, for example, polycarboxylate polymers such as polyacrylates and acrylic/maleic copolymers; monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-, di- and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates, hydroxyethyliminodiacetates, alkyl- and alkenylmalonates and succinates; and sulphonated fatty acid salts.
- polycarboxylate polymers such as polyacrylates and acrylic/maleic copolymers
- monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-, di- and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates, hydroxyethyliminodiacetates, alkyl- and
- compositions in accordance with the invention may contain phosphate builders, for example, sodium tripolyphosphate.
- phosphate builders for example, sodium tripolyphosphate.
- organic builders are citrates, suitably used in amounts of from 1 to 30 wt%, preferably from 2 to 15 wt%; and acrylic polymers, more especially acrylic/maleic copolymers, suitably used in amounts of from 0.5 to 15 wt%, preferably from 1 to 10 wt%.
- Builders, both inorganic and organic, are preferably present in alkali metal salt, especially sodium salt, form.
- the detergency builder which is present in an amount of from 5 to 80 wt%, preferably from 10 to 60 wt%, is selected from sodium tripolyphosphate, zeolites, sodium carbonate and mixtures thereof.
- Detergent compositions in accordance with the invention may also suitably contain a bleach system.
- a bleach system Preferably this will include a peroxy bleach compound, for example, an inorganic persalt or an organic peroxyacid, capable of yielding hydrogen peroxide in aqueous solution.
- Preferred inorganic persalts are sodium perborate monohydrate and tetrahydrate, and sodium percarbonate, the latter being especially preferred.
- the sodium percarbonate may have a protective coating against destabilisation by moisture.
- the peroxy bleach compound is suitably present in an amount of from 5 to 35 wt%, preferably from 10 to 25 wt%.
- the peroxy bleach compound may be used in conjunction with a bleach activator (bleach precursor) to improve bleaching action at low wash temperatures.
- the bleach precursor is suitably present in an amount of from 1 to 8 wt%, preferably from 2 to 5 wt%.
- Preferred bleach precursors are peroxycarboxylic acid precursors, more especially peracetic acid precursors and peroxybenzoic acid precursors; and peroxycarbonic acid precursors.
- An especially preferred bleach precursor suitable for use in the present invention is N,N,N' ,N'-tetracetyl ethylenediamine (TAED).
- a bleach stabiliser may also be present.
- Suitable bleach stabilisers include ethylenediamine tetraacetate (EDTA), diethylenetriamine pentaacetate (DTPA), ethylenediamine disuccinate (EDDS), and the polyphosphonates such as the Dequests (Trade Mark), ethylenediamine tetramethylene phosphonate (EDTMP) and diethylenetriamine pentamethylene phosphate (DETPMP).
- compositions in accordance with the invention may contain alkali metal, preferably sodium, carbonate, in order to increase detergency and ease processing.
- Sodium carbonate may suitably be present in amounts ranging from 1 to 60 wt%, preferably from 2 to 40 wt%.
- sodium silicate may also be present.
- the amount of sodium silicate may suitably range from 0.1 to 5 wt%.
- Sodium silicate, as previously indicated, is preferably introduced via the second base granule.
- Powder flow may be improved by the incorporation of a small amount of a powder structurant.
- powder structurants include, for example, fatty acids (or fatty acid soaps), sugars, acrylate or acrylate/maleate polymers, sodium silicate, and dicarboxylic acids (for example, Sokalan (Trade Mark) DCS ex BASF).
- fatty acids or fatty acid soaps
- sugars acrylate or acrylate/maleate polymers
- sodium silicate for example, Sokalan (Trade Mark) DCS ex BASF
- dicarboxylic acids for example, Sokalan (Trade Mark) DCS ex BASF.
- One preferred powder structurant is fatty acid soap, suitably present in an amount of from 1 to 5 wt%.
- antiredeposition agents such as cellulosic polymers; soil release agents; anti-dye-transfer agents; fluorescers; inorganic salts such as sodium sulphate; enzymes (proteases, lipases, amylases, cellulases); dyes; coloured speckles; perfumes; and fabric conditioning compounds. This list is not intended to be exhaustive.
- compositions in accordance with the invention may be of any suitable physical form, for example, particulates (powders, granules, tablets), liquids, pastes, gels or bars.
- the detergent composition is in particulate form.
- Powders of low to moderate bulk density may be prepared by spray-drying a slurry, and optionally postdosing (dry-mixing) further ingredients.
- “Concentrated” or “compact” powders may be prepared by mixing and granulating processes, for example, using a high-speed mixer/granulator, or other non-tower processes.
- Tablets may be prepared by compacting powders, especially "concentrated” powders.
- liquid detergent compositions which may be prepared by admixing the essential and optional ingredients in any desired order to provide compositions containing the ingredients in the requisite concentrations.
- the polymers may be incorporated at any suitable stage in the manufacture of the compositions in accordance with the invention. As previously indicated, the polymers are commercially available both in solution form and in solid form.
- polymer in powder or solution preferably aqueous form may be incorporated in the slurry.
- polymer powder or solution may be easily introduced into mixing and granulating apparatus, either alone or in admixture with other solid or liquid ingredients as appropriate.
- wash liquors containing 1 g/litre or 2.5 g/litre of a notional detergent composition (the "product") containing linear alkylbenzene sulphonate (LAS) and sodium carbonate were prepared to the following general formulation: Ingredient Weight% in "product” Weight% in 1 g/l wash liquor Weight% in 2.5 g/l wash liquor Sodium LAS 14.82 0.1482 0.3705 Sodium carbonate 11.50 0.1150 0.2785 Polymer (see below) 0, 0.20 or 0.80 0, 0.0020 or 0.0080 0, 0.0050 or 0.0200 Water Balance Balance Balance Balance Balance Balance Balance
- Detergency on white cotton cloth soiled with dirty motor oil was assessed using a high throughput small scale wash method.
- the wash was carried out in water of 20° (French) hardness (Ca:Mg 2:1), at a temperature of 20°C for 20 minutes.
- Whiteness before and after the wash was determined using the technique of colour change by image analysis using a greyness scale.
- the results are analogous to reflectance changes at 460 nm as measured by a reflectance spectrophotometer and are expressed as ⁇ R and ⁇ R.
- Soil removal was determined using samples of woven white cotton cloth soiled with two different model oily soils coloured to increase visibility: soya bean oil coloured with violet dye, and mechanical grease mixed with carbon black.
- the assessments were carried out in tergotometers at a wash temperature of 20-25°C in water of 19° French hardness (Ca:Mg 2:1) at a liquor to cloth ratio of 8:1.
- the wash regime was as follows: 10 minute soak, 15 minute wash, two 2 minute rinses.
- the product dosage for the soak and wash was 4.4 g/l.
- Example 17 the wash liquor for both soak and wash additionally included a 70:30 PVP/VA polymer (W735 ex ISP as described above). The amounts used were:
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Description
- The present invention relates to laundry detergent compositions containing certain vinyl pyrrolidone copolymers. The compositions exhibit improved detergency on oily soils as well as reduced soil redeposition during the wash.
- Polyvinyl pyrrolidone and some related polymers are known ingredients of laundry detergent compositions, providing the benefit of reduced dye transfer between fabrics in a mixed load.
- Laundry detergent compositions containing polyvinyl pyrrolidone as a dye transfer inhibitor are disclosed, for example, in WO 92 18597A, WO 94 03567A, WO 95 03390A, WO 95 17496A, WO 95 27028A and WO 95 34627A (Procter & Gamble), and WO 94 06354A, WO 94 24249A and WO 97 03166A (Henkel).
- GB 1 354 498 (Unilever) discloses laundry detergent compositions containing vinyl pyrrolidone/vinyl acetate copolymers as antiredeposition agents. During the wash, the polymers effectively prevent or reduce redeposition onto washed fabrics of soil suspended in the wash liquor. Polyvinyl pyrrolidone itself is stated to be ineffective.
- DE 2 165 898A (Henkel) also discloses the antiredeposition benefits of these copolymers.
- It has now been discovered that vinyl pyrrolidone/vinyl alcohol copolymers are also effective to enhance oily soil detergency, especially in detergent compositions containing anionic surfactants, more especially alkylbenzene sulphonate.
- The present invention provides a the use of a water-soluble random copolymer of vinyl pyrrolidone and vinyl acetate in a laundry detergent composition comprising an organic surfactant and optionally a detergency builder to improve the oily soil detergency of the composition.
- The random copolymer of vinyl pyrrolidone/vinyl acetate used in accordance with the present invention will be referred to hereinafter for convenience as a PVP/PA copolymer.
- The PVP/PA copolymer preferably contains not more than 30 mole% of vinyl acetate (VA) monomer units. Copolymers containing higher proportions of VA units are less water-soluble and therefore less preferred. More preferably the copolymer contains not more than 50 mole% of VA units.
- Most preferably, the copolymer contains from 50 to 70 mole% of vinyl pyrrolidone (VP) monomer units and from 30 to 50 mole% of VA units.
- The copolymer preferably has a molecular weight within the range of from 10 000 to 100 000, more preferably from 25 000 to 75 000.
- A wide selection of PVP/PA copolymers is available from International Speciality Products (ISP). These are supplied as solutions (clear viscous liquids) in ethanol, isopropanol or water, or as solid (white powder). Some examples are shown in the table below.
Grade Solvent or form Mole ratio VP:VA Approximate molecular weight E-335 Ethanol 30:70 28 800 E-535 50:50 36 700 E-635 60:40 38 200 E-735 70:30 56 700 1-335 Isopropanol 35:65 12 700 I-535 50:50 19 500 I-735 70:30 22 300 W-735 Water 70:30 27 300 S-630 Solid 60:40 51 000 - The solutions have a solids content of approximately 50 wt%.
- PVP/PA copolymers are also available from BASF as the Luviskol (Trade Mark) VA series.
Luviskol VA Solvent or form Mole ratio VP:VA 28E Ethanol 20:80 37E 30:70 55E 50:50 64E 60:40 28I Isopropanol 20:80 37I 30:70 55I 50:50 64I 60:40 64W Water 60:40 73W 70:30 64 powder Solid 60:40 - These polymers are marketed as film-formers for cosmetic and personal products, and for use in hair styling formulations such as mousses, gels and setting lotions.
- In a laundry detergent composition in accordance with the invention, the polymer is present in an amount sufficient to enhance oily soil detergency. Suitably the polymer is present in an amount of from 0.5 to 3 wt%, preferably from 1 to 2 wt%.
- The detergent composition may suitably comprise:
- (a) from 5 to 60 wt%, preferably from 10 to 40 wt%, of organic surfactant,
- (b) optionally from 5 to 80 wt%, preferably from 10 to 60 wt%, of detergency builder,
- (c) from 0.5 to 3 wt%, preferably from 1 to 2 wt%, of the random copolymer of vinyl pyrrolidone and vinyl acetate,
- (d) optionally other detergent ingredients to 100 wt%.
- The detergent composition in accordance with the invention may contain any organic surfactants (detergent-active compounds) suitable for incorporation into laundry detergent compositions.
- Detergent-active compounds (surfactants) may be chosen from soap and non-soap anionic, cationic, nonionic, amphoteric and zwitterionic detergent-active compounds, and mixtures thereof. Many suitable detergent-active compounds are available and are fully described in the literature, for example, in "Surface-Active Agents and Detergents", Volumes I and II, by Schwartz, Perry and Berch. The preferred detergent-active compounds that can be used are soaps and synthetic non-soap anionic and nonionic compounds. The total amount of surfactant present is suitably within the range of from 5 to 60 wt%, preferably from 5 to 40 wt%.
- Anionic surfactants are well-known to those skilled in the art. Examples include alkylbenzene sulphonates, particularly linear alkylbenzene sulphonates having an alkyl chain length of C8-C15; primary and secondary alkylsulphates, particularly C8-C20 primary alkyl sulphates; alkyl ether sulphates; olefin sulphonates; alkyl xylene sulphonates; dialkyl sulphosuccinates; and fatty acid ester sulphonates. Sodium salts are generally preferred.
- Nonionic surfactants that may be used include the primary and secondary alcohol ethoxylates, especially the C8-C20 aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and more especially the C10-C15 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol. Non-ethoxylated nonionic surfactants include alkylpolyglycosides, glycerol monoethers, and polyhydroxyamides (glucamide).
- Cationic surfactants that may be used include quaternary ammonium salts of the general formula R1R2R3R4N+ X- wherein the R groups are long or short hydrocarbyl chains, typically alkyl, hydroxyalkyl or ethoxylated alkyl groups, and X is a solubilising anion (for example, compounds in which R1 is a C8-C22 alkyl group, preferably a C8-C10 or C12-C14 alkyl group, R2 is a methyl group, and R3 and R4, which may be the same or different, are methyl or hydroxyethyl groups); and cationic esters (for example, choline esters).
- Amphoteric surfactants and/or zwitterionic surfactants may also be present.
- Preferred amphoteric surfactants are amine oxides. These are materials of the general formula
R1R2R3N→O
wherein R1 is typically a C8-C18 alkyl group, for example, C12-C14 alkyl, and R2 and R3, which may be the same or different, are C1-C3 alkyl or hydroxyalkyl groups, for example, methyl groups. The most preferred amine oxide is coco dimethylamine oxide. - Preferred zwitterionic surfactants are betaines, and especially amidobetaines.
- Preferred betaines are C8-C18 alkyl amidoalkylbetaines, for example, coco amidopropyl betaine (CAPB).
- According to a preferred embodiment of the invention, the composition comprises a sulphonate anionic surfactant. According to an especially preferred embodiment, the sulphonate anionic surfactant comprises linear alkylbenzene sulphonate (LAS).
- An especially favourable interaction between LAS and the PVP/VA copolymer has been observed, giving improved primary detergency on difficult oily soils such as dirty motor oil. Without being bound by theory, it is postulated that the this benefit may be attributed to a reduction in the critical micelle concentration (CMC) of the LAS.
- The known benefit of reduced redeposition of soil onto the washload during the wash (sometimes referred to as secondary detergency) is also observed.
- Preferably, the compositions contains from 3 to 30 wt%, more preferably from 10 to 25 wt%, of LAS.
- Preferably, the detergent compositions in accordance with the invention also contain one or more detergency builders. The total amount of detergency builder in the compositions may suitably range from 5 to 80 wt%, preferably from 10 to 60 wt%.
- Preferred builders are alkali metal aluminosilicates, more especially crystalline alkali metal aluminosilicates (zeolites), preferably in sodium salt form.
- Zeolite builders may suitably be present in a total amount of from 5 to 60 wt%, preferably from 10 to 50 wt%.
- The zeolites may be supplemented by other inorganic builders, for example, amorphous aluminosilicates, or layered silicates such as SKS-6 ex Clariant.
- The zeolites may be supplemented by organic builders, for example, polycarboxylate polymers such as polyacrylates and acrylic/maleic copolymers; monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-, di- and trisuccinates, carboxymethyloxysuccinates, carboxymethyloxymalonates, dipicolinates, hydroxyethyliminodiacetates, alkyl- and alkenylmalonates and succinates; and sulphonated fatty acid salts.
- Alternatively, the compositions in accordance with the invention may contain phosphate builders, for example, sodium tripolyphosphate.
Especially preferred organic builders are citrates, suitably used in amounts of from 1 to 30 wt%, preferably from 2 to 15 wt%; and acrylic polymers, more especially acrylic/maleic copolymers, suitably used in amounts of from 0.5 to 15 wt%, preferably from 1 to 10 wt%. Builders, both inorganic and organic, are preferably present in alkali metal salt, especially sodium salt, form. - According to a preferred embodiment of the invention, the detergency builder, which is present in an amount of from 5 to 80 wt%, preferably from 10 to 60 wt%, is selected from sodium tripolyphosphate, zeolites, sodium carbonate and mixtures thereof.
- Detergent compositions in accordance with the invention may also suitably contain a bleach system. Preferably this will include a peroxy bleach compound, for example, an inorganic persalt or an organic peroxyacid, capable of yielding hydrogen peroxide in aqueous solution.
Preferred inorganic persalts are sodium perborate monohydrate and tetrahydrate, and sodium percarbonate, the latter being especially preferred. The sodium percarbonate may have a protective coating against destabilisation by moisture. The peroxy bleach compound is suitably present in an amount of from 5 to 35 wt%, preferably from 10 to 25 wt%. - The peroxy bleach compound may be used in conjunction with a bleach activator (bleach precursor) to improve bleaching action at low wash temperatures. The bleach precursor is suitably present in an amount of from 1 to 8 wt%, preferably from 2 to 5 wt%. Preferred bleach precursors are peroxycarboxylic acid precursors, more especially peracetic acid precursors and peroxybenzoic acid precursors; and peroxycarbonic acid precursors. An especially preferred bleach precursor suitable for use in the present invention is N,N,N' ,N'-tetracetyl ethylenediamine (TAED).
- A bleach stabiliser (heavy metal sequestrant) may also be present. Suitable bleach stabilisers include ethylenediamine tetraacetate (EDTA), diethylenetriamine pentaacetate (DTPA), ethylenediamine disuccinate (EDDS), and the polyphosphonates such as the Dequests (Trade Mark), ethylenediamine tetramethylene phosphonate (EDTMP) and diethylenetriamine pentamethylene phosphate (DETPMP).
- The compositions in accordance with the invention may contain alkali metal, preferably sodium, carbonate, in order to increase detergency and ease processing. Sodium carbonate may suitably be present in amounts ranging from 1 to 60 wt%, preferably from 2 to 40 wt%.
As previously indicated, sodium silicate may also be present. The amount of sodium silicate may suitably range from 0.1 to 5 wt%. Sodium silicate, as previously indicated, is preferably introduced via the second base granule. - Powder flow may be improved by the incorporation of a small amount of a powder structurant. Examples of powder structurants, some of which may play other roles in the formulation as previously indicated, include, for example, fatty acids (or fatty acid soaps), sugars, acrylate or acrylate/maleate polymers, sodium silicate, and dicarboxylic acids (for example, Sokalan (Trade Mark) DCS ex BASF). One preferred powder structurant is fatty acid soap, suitably present in an amount of from 1 to 5 wt%.
- Other materials that may be present in detergent compositions in accordance with the invention include antiredeposition agents such as cellulosic polymers; soil release agents; anti-dye-transfer agents; fluorescers; inorganic salts such as sodium sulphate; enzymes (proteases, lipases, amylases, cellulases); dyes; coloured speckles; perfumes; and fabric conditioning compounds. This list is not intended to be exhaustive.
- The compositions in accordance with the invention may be of any suitable physical form, for example, particulates (powders, granules, tablets), liquids, pastes, gels or bars. According to one especially preferred embodiment of the invention, the detergent composition is in particulate form.
- Powders of low to moderate bulk density may be prepared by spray-drying a slurry, and optionally postdosing (dry-mixing) further ingredients. "Concentrated" or "compact" powders may be prepared by mixing and granulating processes, for example, using a high-speed mixer/granulator, or other non-tower processes.
- Tablets may be prepared by compacting powders, especially "concentrated" powders.
- Also preferred are liquid detergent compositions, which may be prepared by admixing the essential and optional ingredients in any desired order to provide compositions containing the ingredients in the requisite concentrations.
- The polymers may be incorporated at any suitable stage in the manufacture of the compositions in accordance with the invention. As previously indicated, the polymers are commercially available both in solution form and in solid form.
- For example, in the manufacture of spray-dried particulate compositions, polymer in powder or solution (preferably aqueous) form may be incorporated in the slurry. For non-tower particulates, polymer powder or solution may be easily introduced into mixing and granulating apparatus, either alone or in admixture with other solid or liquid ingredients as appropriate.
- The invention is further illustrated by the following Examples, in which parts and percentages are by weight unless otherwise stated.
- Wash liquors containing 1 g/litre or 2.5 g/litre of a notional detergent composition (the "product") containing linear alkylbenzene sulphonate (LAS) and sodium carbonate were prepared to the following general formulation:
Ingredient Weight% in "product" Weight% in 1 g/l wash liquor Weight% in 2.5 g/l wash liquor Sodium LAS 14.82 0.1482 0.3705 Sodium carbonate 11.50 0.1150 0.2785 Polymer (see below) 0, 0.20 or 0.80 0, 0.0020 or 0.0080 0, 0.0050 or 0.0200 Water Balance Balance Balance - The polymers used, all commercial products from ISP provided as 40 wt% solutions, were as follows:
Example Trade name VP/VA mole ratio Solvent 1, 2, 9, 10 E535 50:50 ethanol 3, 4, 11, 12 E735 70:30 ethanol 5, 6, 13, 14 I535 50:50 isopropanol 7, 8, 15, 16 I735 70:30 isopropanol - Detergency on white cotton cloth soiled with dirty motor oil was assessed using a high throughput small scale wash method. The wash was carried out in water of 20° (French) hardness (Ca:Mg 2:1), at a temperature of 20°C for 20 minutes.
- Whiteness before and after the wash was determined using the technique of colour change by image analysis using a greyness scale. The results are analogous to reflectance changes at 460 nm as measured by a reflectance spectrophotometer and are expressed as ΔR and ΔΔR.
-
Example Polymer Polymer level in "product" ΔR ΔΔR A none 0 81.76 0 1 E535 0.2 84.53 + 2.77 2 E535 0.8 83.78 + 2.02 3 E735 0.2 83.86 + 2.10 4 E735 0.8 85.05 + 3.29 5 I535 0.2 82.99 + 1.23 6 I535 0.8 83.16 + 1.40 7 E735 0.2 84.90 + 3.14 8 E735 0.8 84.66 + 2.90 -
Example Polymer Polymer level in "product" ΔR ΔΔR B none 0 82.04 0 9 E535 0.2 84.53 + 2.49 10 E535 0.8 82.51 + 0.47 11 E735 0.2 83.69 + 1.65 12 E735 0.8 84.65 + 2.61 13 I535 0.2 83.59 + 1.55 14 I535 0.8 82.38 + 0.34 15 E735 0.2 84.99 + 2.95 16 E735 0.8 84.58 + 2.54 - A detergent powder composition was prepared to the following formulation:
Ingredient Weight% Sodium linear alkylbenzene sulphonate 9.31 Nonionic surfactant 3.58 Sodium tripolyphosphate 21.32 Sodium carbonate 12.97 Sodium hydroxide 1.95 Sodium carboxymethyl cellulose 0.62 Sodium silicate (r = 2.4) 5.18 Fluorescers 0.13 Zeolite 1.24 Sodium perborate tetrahydrate 15.00 Tetraacetyl ethylenediamine 3.80 Enzymes (protease, lipase, amylase) 2.27 Antifoam granule 2.00 Dequest 2047 0.50 Granular sodium tripolyphosphate 10.00 Perfume 0.65 Citric acid 2.75 Water to 100.00 - Soil removal was determined using samples of woven white cotton cloth soiled with two different model oily soils coloured to increase visibility: soya bean oil coloured with violet dye, and mechanical grease mixed with carbon black.
- The assessments were carried out in tergotometers at a wash temperature of 20-25°C in water of 19° French hardness (Ca:Mg 2:1) at a liquor to cloth ratio of 8:1. The wash regime was as follows: 10 minute soak, 15 minute wash, two 2 minute rinses. The product dosage for the soak and wash was 4.4 g/l.
- In Example 17, the wash liquor for both soak and wash additionally included a 70:30 PVP/VA polymer (W735 ex ISP as described above). The amounts used were:
- Soak: 0.20 g/l, equivalent to 4 wt% of the product
- Wash: 0.05 g/l, equivalent to 1 wt% of the product Example C was a control without polymer.
-
- The SRI results were as shown in the Table below.
Soil Example C Example 17 Soya bean oil with violet dye 84.07 84.69 Mechanical grease/carbon black 51.24 57.08
Claims (10)
- Use of a water-soluble random copolymer of vinyl pyrrolidone and vinyl acetate in a laundry detergent composition comprising an organic surfactant and optionally a detergency builder to improve the oily soil detergency of the composition.
- Use as claimed in claim 1, characterised in that the copolymer contains not more than 30 mole%, preferably not more than 50 mole%, of vinyl acetate monomer units.
- Use as claimed in claim 2, characterised in that the copolymer contains from 50 to 70 mole% of vinyl pyrrolidone monomer units and from 30 to 50 mole% of vinyl acetate units.
- Use as claimed in any preceding claim, characterised in that the copolymer has a molecular weight within the range of from 10 000 to 100 000, preferably from 25 000 to 75 000.
- Use as claimed in any preceding claim, characterised in that the laundry detergent composition contains from 0.5 to 3 wt%, preferably from 1 to 2 wt%, of the copolymer.
- Use as claimed in any preceding claim, characterised in that the laundry detergent composition comprises:(a) from 5 to 60 wt%, preferably from 10 to 40 wt%, of organic surfactant,(b) optionally from 5 to 80 wt%, preferably from 10 to 60 wt%, of detergency builder,(c) from 0.5 to 3 wt%, preferably from 1 to 2 wt%, of the random copolymer of vinyl pyrrolidone and vinyl acetate,(d) optionally other detergent ingredients to 100 wt%.
- Use as claimed in any preceding claim, characterised in that the organic surfactant comprises a sulphonate anionic surfactant.
- Use as claimed in claim 7, characterised in that the organic surfactant comprises linear alkylbenzene sulphonate.
- Use as claimed in claim 8, characterised in that the laundry detergent composition contains from 3 to 30 wt%, preferably from 10 to 25 wt%, of linear alkylbenzene sulphonate.
- Use as claimed in any preceding claim, characterised in that the laundry detergent composition comprises from 5 to 80 wt%, preferably from 10 to 60 wt%, of detergency builder selected from sodium tripolyphosphate, zeolites, sodium carbonate and mixtures thereof.
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GBGB0218636.9A GB0218636D0 (en) | 2002-08-10 | 2002-08-10 | Detergent compositions |
GB0218636 | 2002-08-10 | ||
PCT/EP2003/007753 WO2004018602A1 (en) | 2002-08-10 | 2003-07-16 | Detergent compositions |
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EP1527154B1 true EP1527154B1 (en) | 2006-09-20 |
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EP03792208A Expired - Lifetime EP1527154B1 (en) | 2002-08-10 | 2003-07-16 | Detergent compositions |
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EP (1) | EP1527154B1 (en) |
AR (1) | AR040833A1 (en) |
AT (1) | ATE340240T1 (en) |
AU (1) | AU2003250085A1 (en) |
BR (1) | BR0312344A (en) |
DE (1) | DE60308526T2 (en) |
ES (1) | ES2273076T3 (en) |
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Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
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GB1354498A (en) * | 1970-08-12 | 1974-06-05 | Unilever Ltd | Detergent composition |
BE793420A (en) * | 1971-12-31 | 1973-06-28 | Henkel & Cie Gmbh | DETERGENT CONTAINING ADDITIVES INHIBITORS OF TERNISSURE |
GB1536136A (en) * | 1975-03-03 | 1978-12-20 | Unilever Ltd | Detergent composition |
EP0350449A3 (en) * | 1988-07-08 | 1990-10-24 | Ciba-Geigy Ag | Liquid detergent containing optical brighteners |
DE3840056A1 (en) * | 1988-11-28 | 1990-05-31 | Henkel Kgaa | METHOD FOR THE WASHING OF COMPOSITE SENSITIVE TEXTILES |
US5466802A (en) * | 1993-11-10 | 1995-11-14 | The Procter & Gamble Company | Detergent compositions which provide dye transfer inhibition benefits |
CN1146779A (en) * | 1994-03-04 | 1997-04-02 | 普罗格特-甘布尔公司 | Polyhydroxy amides to provide dye transfer inhibition benefits during fabric laundering |
GB9526181D0 (en) * | 1995-12-21 | 1996-02-21 | Unilever Plc | A detergent composition |
US5912406A (en) * | 1997-05-28 | 1999-06-15 | Black; Robert H. | Method of cleaning soiled fabrics |
-
2002
- 2002-08-10 GB GBGB0218636.9A patent/GB0218636D0/en not_active Ceased
-
2003
- 2003-07-16 DE DE60308526T patent/DE60308526T2/en not_active Expired - Fee Related
- 2003-07-16 ES ES03792208T patent/ES2273076T3/en not_active Expired - Lifetime
- 2003-07-16 EP EP03792208A patent/EP1527154B1/en not_active Expired - Lifetime
- 2003-07-16 AU AU2003250085A patent/AU2003250085A1/en not_active Abandoned
- 2003-07-16 AT AT03792208T patent/ATE340240T1/en not_active IP Right Cessation
- 2003-07-16 BR BR0312344-8A patent/BR0312344A/en not_active IP Right Cessation
- 2003-07-16 WO PCT/EP2003/007753 patent/WO2004018602A1/en active IP Right Grant
- 2003-08-08 AR AR20030102873A patent/AR040833A1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
GB0218636D0 (en) | 2002-09-18 |
AU2003250085A1 (en) | 2004-03-11 |
DE60308526D1 (en) | 2006-11-02 |
DE60308526T2 (en) | 2007-01-18 |
BR0312344A (en) | 2005-04-12 |
ES2273076T3 (en) | 2007-05-01 |
ATE340240T1 (en) | 2006-10-15 |
AR040833A1 (en) | 2005-04-20 |
WO2004018602A1 (en) | 2004-03-04 |
EP1527154A1 (en) | 2005-05-04 |
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