EP1132456A2 - Application of fatty derivatives as grill lighter - Google Patents
Application of fatty derivatives as grill lighter Download PDFInfo
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- EP1132456A2 EP1132456A2 EP01105624A EP01105624A EP1132456A2 EP 1132456 A2 EP1132456 A2 EP 1132456A2 EP 01105624 A EP01105624 A EP 01105624A EP 01105624 A EP01105624 A EP 01105624A EP 1132456 A2 EP1132456 A2 EP 1132456A2
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- alcohols
- fatty
- fatty acid
- oil
- grill
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L11/00—Manufacture of firelighters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L11/00—Manufacture of firelighters
- C10L11/04—Manufacture of firelighters consisting of combustible material
Definitions
- the invention relates to the use of fat derivatives with a solidification point less than 0 ° C, an iodine number below 20 and a surface tension of more than 25mN / m as a grill lighter.
- fat derivatives with a freezing point less than 0 ° C, an iodine number below 20 and a surface tension of more than 25 mN / m, in particular fatty acid esters, fatty alcohols and / or Guerbet alcohols Excellent as a grill lighter and at the same time harmless to health are. They burn soot-free and behave odorless, at the same time they are not subject to labeling according to the new guidelines.
- Liquid grill lighters can be used with the fat derivatives to be used according to the invention also the usual from the prior art for fixed grill lighter Soak materials and thus also produce solid grill lighters.
- the low intrinsic coloration as well as little self-odor as possible are decisive criteria for acceptance and enable in addition, by adding dyes and / or fragrances, the production special Customized grill lighter.
- the viscosity of the fat derivatives can be adjusted by adding thickeners.
- fatty acid esters are understood to mean esters of the fatty acids listed in the formula (I) with linear or branched, saturated or unsaturated alcohols having 1 to 20 C atoms.
- esters of fatty acids with polyhydric alcohols can also be used, and in addition to glycerol, trimethylolpropane, for example, can also be used as the alcohol component.
- the esters of C 8 to C 18 fatty acids with C 1 to C 8 alcohols, in particular linear C 1 to C 4 and / or branched to C 3 to C 8 alcohols, are preferably used.
- the examples (B1 to B3) and comparative examples (V1 to V3) according to the invention were carried out using the grill lighters specified in Table 1.
- 20 ml of the oil were placed in a crucible, provided with a 12.5 cm long wick and lit. The flame was extinguished after 20 minutes of burning.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Fats And Perfumes (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Die Erfindung betrifft die Verwendung von Fettderivaten mit einem Erstarrungspunkt kleiner 0°C, einer Iodzahl unter 20 und einer Oberflächenspannung von mehr als 25mN/m als Grillanzünder.The invention relates to the use of fat derivatives with a solidification point less than 0 ° C, an iodine number below 20 and a surface tension of more than 25mN / m as a grill lighter.
Eine Vielzahl verschiedenster Öle wurde als Grillanzünder eingesetzt, so offenbart beispielsweise die GB 0002610 ein Verfahren zur Herstellung von Ölen ausgehend von pflanzlichen Ölen, wie Leinöl oder Sesamöl. Es handelt sich dabei um ein sehr aufwendiges Verfahren. Weitere Anmeldung aus den Jahren 1861 und 1870 beinhalten Verfahren zur Aufreinigung von Mineralöl [GB 0003175] beziehungsweise Petroleum [GB 0000709] zum Einsatz als Lampenöle. Andere Entwicklungen gingen dahin, Öle einzusetzen, deren Dämpfe beispielsweise desinfizierend wirken sollten [GB 0001487]. Die Mehrzahl der Anmeldungen beschäftigte sich jedoch mit verschiedenen Verfahren zur Herstellung von Grillanzündern aus Mineralöl bzw. Petroleum.A variety of different oils were used as grill lighters, for example GB 0002610 discloses a process for the production of oils from vegetable oils such as linseed oil or sesame oil. It is a very complex process. Further applications from the years 1861 and 1870 include processes for the purification of mineral oil [GB 0003175] or petroleum [GB 0000709] for use as lamp oils. Other developments have been to use oils, the vapors of which, for example, should have a disinfecting effect [GB 0001487]. The majority of the applications, however, dealt with various processes for producing grill lighters from mineral oil or petroleum.
Aufgrund der Verfügbarkeit und des günstigen Preises haben sich Grillanzünder auf Basis fossiler Brennstoffe, insbesondere mineralölbasiert, durchgesetzt und werden üblicherweise auch heute noch eingesetzt. Eine typische Zusammensetzung der heutzutage zu verwendenden Grillanzünder ist im Deutschen Ärzteblatt 92, Heft 39, 1995 (55) angegeben, danach bestehen diese überwiegend aus homologen n-Alkanen einer Kettenlänge von C9 bis C18. Als Hauptvertreter sind angeführt: n-Decan (15,8 Gew.-%), n-Undecan (8,6Gew.-%), n-Dodecan (23,6 Gew.-%), n-Tridecan (38,2 Gew.-%) sowie n-Tetradecan (11,8 Gew.-%). Die toxikologischen Bedenken bezüglich der im Handel befindlichen Grillanzünder richten sich gegen die Aspirationsgefahr und daraus folgender Lösungsmittelpneumonie. Gerade innerhalb der letzten Jahre kam es daher zu heftigen Diskussionen über mineralölbasierte Grillanzünder [Deutsches Ärzteblatt 1995 (35)] und daraus entstand die Forderung zu einer Änderung der Gefahrstoffverordnung. Im Rahmen der 22. Anpassung an den technischen Fortschritt (ATP), deren Basis die Dangerous Substances Directives 67/548 EEC bilden, werden diese Stoffe zukünftig statt des Gefahrenhinweises R 22 für die Aspirationsgefahr die Kennzeichnung R 65 tragen müssen ("gesundheitsschädlich, kann beim Verschlucken zu Lungenschädigung führen") sowie weiterhin das Gefahrensymbol "Xn" (gesundheitsschädlich).Due to the availability and the low price, grill lighters based on fossil fuels, in particular mineral oil-based, have become established and are usually still used today. A typical composition of the grill lighters to be used today is given in Deutsches Ärzteblatt 92, number 39, 1995 (55) , after which these consist predominantly of homologous n-alkanes with a chain length of C 9 to C 18 . The main representatives are: n-decane (15.8% by weight), n-undecane (8.6% by weight), n-dodecane (23.6% by weight), n-tridecane (38.2 % By weight) and n-tetradecane (11.8% by weight). The toxicological concerns about the grill lighters on the market are directed against the risk of aspiration and the resulting solvent pneumonia. Especially in the last few years there have been fierce discussions about mineral oil-based grill lighters [Deutsches Ärzteblatt 1995 (35)] and this has resulted in a request to change the Hazardous Substances Ordinance. As part of the 22nd adaptation to technical progress (ATP), which is based on the Dangerous Substances Directives 67/548 EEC, these substances will in future have to be labeled R 65 instead of the hazard warning R 22 for the risk of aspiration ("harmful to health can Ingestion leads to lung damage ") as well as the danger symbol" Xn "(harmful to health).
Die komplexe Aufgabe der vorliegenden Erfindung war es daher, diese gesundheitsschädlichen Grillanzünder durch gesundheitlich unbedenklichere zu ersetzen, bei gleichzeitiger Beibehaltung der guten anwendungstechnischen Eigenschaften, insbesondere einer möglichst rußfreien Flamme. Gleichzeitig sollten die Grillanzünder über eine möglichst geringe Eigenfärbung sowie Eigengeruch verfügen und sich insbesondere leicht durch Zusatz von Duft- und/ oder Farbstoffen Käuferwünschen entsprechend anpassen lassen.The complex object of the present invention was therefore to make these harmful to health Grill lighter to replace with less harmful to health, at the same time Maintaining good application properties, in particular a soot-free flame. At the same time, the lighter should have one if possible have low intrinsic color and odor and are particularly light Adjust buyer wishes accordingly by adding fragrances and / or dyes to let.
Gegenstand der Erfindung ist die Verwendung von Fettderivaten mit einem Erstarrungspunkt kleiner 0°C, einer Iodzahl unter 20 und einer Oberflächenspannung von mehr als 25mN/m als Grillanzünder.The invention relates to the use of fat derivatives with a solidification point less than 0 ° C, an iodine number below 20 and a surface tension of more than 25mN / m as a grill lighter.
Es wurde nun überraschenderweise gefunden, dass sich Fettderivate mit einem Erstarrungspunkt kleiner 0°C, einer Iodzahl unter 20 und einer Oberflächenspannung von mehr als 25 mN/m, insbesondere Fettsäureester, Fettalkohole und/ oder Guerbetalkohole hervorragend als Grillanzünder eignen und dabei gleichzeitig gesundheitlich unbedenklich sind. Sie verbrennen rußfrei und verhalten sich geruchsneutral, gleichzeitig sind sie gemäß der neuen Richtlinien nicht kennzeichnungspflichtig. Neben dem Einsatz als flüssige Grillanzünder lassen sich mit den erfindungsgemäß zu verwendenden Fettderivaten auch die üblichen aus dem Stand der Technik für feste Grillanzünder bekannte Materialien tränken und somit auch feste Grillanzünder herstellen.It has now surprisingly been found that fat derivatives with a freezing point less than 0 ° C, an iodine number below 20 and a surface tension of more than 25 mN / m, in particular fatty acid esters, fatty alcohols and / or Guerbet alcohols Excellent as a grill lighter and at the same time harmless to health are. They burn soot-free and behave odorless, at the same time they are not subject to labeling according to the new guidelines. In addition to use as Liquid grill lighters can be used with the fat derivatives to be used according to the invention also the usual from the prior art for fixed grill lighter Soak materials and thus also produce solid grill lighters.
Die erfindungsgemäß einzusetzenden Fettderivate weisen vorzugsweise eine Farbe von weniger als 100 APHA (= American Public Health Association, s. Römpp 9. Auflage S 1306, Farbzahl) auf und sind damit eher farblos. Die geringe Eigenfärbung sowie ein möglichst geringer Eigengeruch sind entscheidende Kriterien für die Akzeptanz und ermöglichen zusätzlich durch Zugabe von Farb- und/ oder Duftstoffen die Herstellung speziellen Käuferwünschen angepasster Grillanzünder. Je nach gewünschtem Einsatzgebiet lässt sich die Viskosität der Fettderivate durch Zugabe von Verdickern einstellen. The fat derivatives to be used according to the invention preferably have a color of less than 100 APHA (= American Public Health Association, see Römpp 9th edition p 1306, color number) and are therefore rather colorless. The low intrinsic coloration as well as little self-odor as possible are decisive criteria for acceptance and enable in addition, by adding dyes and / or fragrances, the production special Customized grill lighter. Depending on the desired area of application the viscosity of the fat derivatives can be adjusted by adding thickeners.
Unter Fettderivaten im Sinne der vorliegenden Anmeldung sind Fettsäureglyceride, sowie daraus gewonnene Fettsäureester, Fettalkohole und/ oder Guerbetalkohole, sowie deren technische Gemische zu verstehen. Im Sinne der vorliegenden Erfindung werden vorzugsweise Fettsäureester eingesetzt.Fat derivatives within the meaning of the present application include fatty acid glycerides and derived fatty acid esters, fatty alcohols and / or Guerbet alcohols, and their understand technical mixtures. For the purposes of the present invention, are preferred Fatty acid esters used.
Die erfindungsgemäß als Ausgangsmaterialien einzusetzenden Fettsäureglyceride können
die üblichen natürlichen pflanzlichen oder tierischen Fette oder Öle sein. Hierzu gehören
beispielsweise Palmöl, Palmkernöl, Baumwollsaatöl, Rapsöl, Kokosöl, Erdnußöl, Olivenöl,
Leinöl, Babassuöl, Teeöl, Olivenkernöl, Meadowfoamöl, Chaulmoograöl, Korianderöl,
Sojaöl, Rizinusöl, Lardöl, Rindertalg, Schweineschmalz, Fischöl, sowie Sonnenblumenöl
und Rapsöl der alten und neuen Züchtung. Die Hauptbestandteile dieser Fette und Öle
sind Glyceride verschiedener Arten von Fettsäuren, die beträchtliche Mengen an Verunreinigungen
wie etwa Aldehydverbindungen, Phospholipidverbindungen und freie Fettsäuren
enthalten. Diese Materialien können direkt oder nach vorheriger Aufreinigung
eingesetzt werden. In manchen Fällen ist es besonders empfehlenswert, die freien Fettsäuren
in einer vorgeschalteten Reaktion mit niederen Alkoholen zu verestern. Neben
den natürlichen Fettsäureglyceriden können auch synthetische Fettsäureglyceride eingesetzt
werden, die man z.B. durch Veresterung von Glycerin mit Fettsäuren erhält. Unter
Fettsäuren sind dabei aliphatische Carbonsäuren der Formel (I) zu verstehen,
Unter Fettalkoholen sind primäre aliphatische Alkohole der Formel (II) zu verstehen,
Unter Fettsäureestern sind im Rahmen der vorliegenden Erfindung Ester der in der Formel (I) aufgeführten Fettsäuren mit linearen oder verzweigten, gesättigten oder ungesättigten Alkoholen mit 1 bis 20 C-Atomen zu verstehen. Es können jedoch auch Ester der Fettsäuren mit mehrwertigen Alkoholen verwendet werden, wobei neben Glycerin z.B. auch Trimethylolpropan als Alkoholkomponente eingesetzt werden kann. Vorzugsweise werden die Ester der C8 bis C18-Fettsäuren mit C1 bis C8 Alkoholen, insbesondere linearen C1 bis C4 und/ oder verzweigten bis C3 bis C8 Alkoholen eingesetzt. Besonders bevorzugt werden Methyl-, 2-Ethylhexyl-, Ethyl-, Butyl, Isopropyl sowie Trimethylolpropanester, eingesetzt. Als Fettsäurekomponenten eignen sich insbesondere technische Gemische von Fettsäuren gemäß Formel (I) sowie vorzugsweise die aus Lauricölen, insbesondere Palm-, Palmkern-, Talg- und/oder Kokosöl gewonnenen Fettsäureschnitte. Bevorzugt ist die Verwendung eines C12/18-Methylesters insbesondere bevorzugt ist die Verwendung von Edenor® E814 einem C8/14-2-Ethylhexylester, der sich zusätzlich dadurch auszeichnet, dass er in der Wassergefährdungsklasse 0 eingeordnet ist. Des weiteren lässt sich seine Viskosität durch Zugabe von Verdickern hervorragend einstellen. Die aufgeführten Fettsäureester zeichnen sich durch ihre geringe Eigenfärbung sowie den geringen Eigengeruch aus, gleichzeitig lassen sie sich durch Farb- und Duftstoffe hervorragend modifizieren und weisen eine außerordentlich hohe Farbstabilität auf. Auch bei erhöhter Temperatur zeigen die Fettsäureester eine gute Farbstabilität.In the context of the present invention, fatty acid esters are understood to mean esters of the fatty acids listed in the formula (I) with linear or branched, saturated or unsaturated alcohols having 1 to 20 C atoms. However, esters of fatty acids with polyhydric alcohols can also be used, and in addition to glycerol, trimethylolpropane, for example, can also be used as the alcohol component. The esters of C 8 to C 18 fatty acids with C 1 to C 8 alcohols, in particular linear C 1 to C 4 and / or branched to C 3 to C 8 alcohols, are preferably used. Methyl, 2-ethylhexyl, ethyl, butyl, isopropyl and trimethylolpropane esters are particularly preferably used. Suitable fatty acid components are, in particular, technical mixtures of fatty acids of the formula (I) and preferably the fatty acid cuts obtained from lauric oils, in particular palm, palm kernel, tallow and / or coconut oil. The use of a C 12/18 methyl ester is preferred. The use of Edenor® E814, a C 8/14 -2-ethylhexyl ester, which is additionally distinguished by the fact that it is classified in water hazard class 0, is particularly preferred. Furthermore, its viscosity can be adjusted excellently by adding thickeners. The fatty acid esters listed are characterized by their low intrinsic color and low intrinsic odor, at the same time they can be modified by dyes and fragrances and have an extraordinarily high color stability. The fatty acid esters show good color stability even at elevated temperatures.
Die alkalische Kondensation von Alkoholen zu höhermolekularen, verzweigten IsoAlkoholen wurde erstmals von Guerbet 1899 veröffentlicht. Machemer stellte 1952 wesentliche Schritte der Reaktion dar [vgl. Angewandte Chemie 64, 213 (1952) ]. Neben der Dehydrierung zum Keton, bei der Wasserstoff abgespalten wird, und der Aldolkondensation ist die Crotonisierung, bei der Wasser abgespalten wird, ein wichtiger Schritt im Reaktionsablauf. Stand der Technik ist eine Reaktionsführung bei Normaldruck und einer Reaktionstemperatur von 240 bis 260 °C. Die so erhaltenen verzweigten Alkohole werden als Guerbetalkohole bezeichnet. Aus dem Stand der Technik sind inzwischen eine Vielzahl weiterer Verfahren bekannt, gemäß derer man Guerbetalkohole erhalten kann. Erfindungsgemäß können auch beliebige Mischungen der aufgeführten Fettderivate mit einem Erstarrungspunkt unter 0°C, vorzugsweise zwischen -5 und -40 °C, einer Oberflächenspannung oberhalb von 25 mN/m - zur Verminderung der Aspirationsgefahr - sowie einer Iodzahl unterhalb von 20 - um eine möglichst geringe Rußbildung zu gewährleisten - eingesetzt werden. Die erfindungsgemäß einzusetzenden Fettderivate sind vorzugsweise farb- und geruchlos.The alkaline condensation of alcohols to form higher molecular weight, branched isoalcohols was first published by Guerbet in 1899. Machemer outlined essential steps of the reaction in 1952 [cf. Angewandte Chemie 64, 213 (1952) ]. In addition to dehydrogenation to ketone, in which hydrogen is split off, and aldol condensation, crotonization, in which water is split off, is an important step in the course of the reaction. State of the art is a reaction at normal pressure and a reaction temperature of 240 to 260 ° C. The branched alcohols obtained in this way are referred to as Guerbet alcohols. A large number of other processes are now known from the prior art, according to which Guerbet alcohols can be obtained. According to the invention, any mixtures of the listed fat derivatives with a solidification point below 0 ° C, preferably between -5 and -40 ° C, a surface tension above 25 mN / m - to reduce the risk of aspiration - and an iodine number below 20 - by as much as possible to ensure low soot formation - are used. The fat derivatives to be used according to the invention are preferably colorless and odorless.
Insbesondere die aufgeführten Fettsäureester eignen sich hervorragend als Grillanzünder, da sich Duft- und Farbstoffe sehr gut einarbeiten lassen und sie einen außerordentlich geringen Eigengeruch besitzen. Des weiteren verfügen sie über eine gute Farbstabilität auch bei erhöhten Temperaturen und sie verbrennen rückstandsfrei. Bei einigen Fettderivaten, insbesondere bei Triglyceriden, wie beispielsweise Olivenöl, Leinöl, oder auch Sesamöl, stellt sich das Problem einer stark rußenden Flamme, da die Iodzahl oberhalb von 20 liegt. Zur erfindungsgemäßen Verwendung ist es in diesen Fällen daher erforderlich, diese mit anderen Fettderivaten abzumischen und/ oder durch teilweise Hydrierung die Iodzahl herabzusetzen. The listed fatty acid esters are particularly suitable as grill lighters, because fragrances and dyes can be worked in very well and they are extraordinary have a low odor. Furthermore, they have good color stability even at elevated temperatures and they burn without residue. With some Fat derivatives, particularly in the case of triglycerides, such as, for example, olive oil, linseed oil, or Also sesame oil, the problem of a very sooty flame arises because of the iodine number is above 20. It is therefore for the use according to the invention in these cases necessary to mix these with other fat derivatives and / or by partially Hydrogenation to reduce the iodine number.
Geeignete Verdickungsmittel sind beispielsweise Polysaccharide, insbesondere XanthanGum, Guar-Guar, Agar-Agar, Alginate und Tylosen, Carboxy-methylcellulose und Hydroxyethylcellulose, ferner höhermolekulare Polyethylenglycolmono- und -diester von Fettsäuren, Polyacrylate, (z.B. Carbopole® von Goodrich oder Synthalene® von Sigma), Polyacrylamide, Polyvinylalkohol und Polyvinylpyrrolidon, Tenside wie beispielsweise ethoxylierte Fettsäureglyceride, Ester von Fettsäuren mit Polyolen wie beispielsweise Pentaerythrit oder Trimethylolpropan, Fettalkoholethoxylate mit eingeengter Homologenverteilung oder Alkyloligoglucoside. Besonders bevorzugt wird Polypropylenglycol als Verdickungsmittel eingesetzt. Die Verdickungsmittel können in einer Menge von 0 bis 25, vorzugsweise 5 bis 20 Gew.-%, bezogen auf das Fettderivat, eingesetzt werden. Erfindungsgemäß weisen die Grillanzünder vorzugsweise eine Viskosität - bestimmt nach Höppler - von mindestens 2, vorzugsweise mindestens 4 und insbesondere mehr als 7cStokes bei 40 °C aufSuitable thickeners are, for example, polysaccharides, in particular xanthan gum, Guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, also higher molecular weight polyethylene glycol mono- and diesters of Fatty acids, polyacrylates (e.g. Carbopole® from Goodrich or Synthalene® from Sigma), Polyacrylamides, polyvinyl alcohol and polyvinyl pyrrolidone, surfactants such as ethoxylated fatty acid glycerides, esters of fatty acids with polyols such as Pentaerythritol or trimethylolpropane, fatty alcohol ethoxylates with a narrow homolog distribution or alkyl oligoglucosides. Polypropylene glycol is particularly preferred as Thickeners used. The thickeners can be used in an amount of 0 to 25, preferably 5 to 20 wt .-%, based on the fat derivative, are used. According to the invention the grill lighters preferably have a viscosity - determined Höppler - of at least 2, preferably at least 4 and in particular more than 7cStokes at 40 ° C
Als Duftstoffe zur Herstellung von Grillanzündern mit verschiedenen Geruchsnoten lassen sich Parfümöle einsetzen. Als Parfümöle seien beispielhaft genannt die Extrakte von Blüten (Lavendel, Rosen, Jasmin, Neroli), Stengeln und Blättern (Geranium, Patchouli, Petitgrain), Früchten (Anis, Koriander, Kümmel, Wacholder), Fruchtschalen (Bergamotte, Zitrone, Orangen), Wurzeln (Macis, Angelica, Sellerie, Kardamon, Costus, Iris, Calmus), Hölzern (Sandel-, Guajak-, Zedern-, Rosenholz), Kräutern und Gräsern (Estragon, Lemongras, Salbei, Thymian), Nadeln und Zweigen (Fichte, Tanne, Kiefer, Latschen), Harzen und Balsamen (Galbanum, Elemi, Benzoe, Myrrhe, Olibanum, Opoponax). Weiterhin kommen tierische Rohstoffe in Frage, wie beispielsweise Moschus, Zibet und Castoreum. Als synthetische bzw. halbsynthetische Parfümöle kommen Ambroxan, Eugenol, Isoeugenol, Citronellal, Hydroxycitronellal, Geraniol, Citronellol, Geranylacetat, Citral, Ionon und Methylionon in Betracht. Daneben lassen sich Duftstoffe einsetzen, wie sie bereits in der GB 0001679 aus dem Jahre 1855 beschrieben sind. Leave as fragrances for the production of grill lighters with different smell notes use perfume oils. The extracts of Flowers (lavender, roses, jasmine, neroli), stems and leaves (geranium, patchouli, Petitgrain), fruits (anise, coriander, caraway, juniper), fruit bowls (bergamot, Lemon, oranges), roots (mace, angelica, celery, cardamom, costus, iris, calmus), Woods (sandal, guaiac, cedar, rosewood), herbs and grasses (tarragon, lemongrass, Sage, thyme), needles and twigs (spruce, fir, pine, mountain pine), resins and balsams (galbanum, elemi, benzoin, myrrh, olibanum, opoponax). Farther animal raw materials are possible, such as musk, civet and castoreum. Ambroxan, eugenol, isoeugenol, synthetic or semi-synthetic perfume oils are Citronellal, hydroxycitronellal, geraniol, citronellol, geranyl acetate, citral, ionone and methyl ionone. In addition, fragrances can be used, as already in GB 0001679 from 1855 are described.
Als Farbstoffe können die für kosmetische Zwecke geeigneten und zugelassenen Substanzen verwendet werden, wie sie beispielsweise in der Publikation "Kosmetische Färbemittel" der Farbstoffkommission der Deutschen Forschungsgemeinschaft, Verlag Chemie, Weinheim, 1984, S.81-106 zusammengestellt sind. Diese Farbstoffe werden üblicherweise in Konzentrationen von 0,001 bis 0,1 Gew.-%, bezogen auf die gesamte Mischung, eingesetzt. The dyes which can be used are those substances which are suitable and approved for cosmetic purposes, as compiled, for example, in the publication "Cosmetic Dyes" by the Dye Commission of the German Research Foundation, Verlag Chemie, Weinheim, 1984, pp . 81-106 . These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
Die erfindungsgemäßen Beispiele ( B1 bis B3) und Vergleichsbeispiele (V1 bis V3) wurden mit den in der Tabelle 1 angegebenen Grillanzündern durchgeführt. Dazu wurden jeweils 20 ml des Öls in einen Tiegel gegeben, mit einem 12,5 cm langem Docht versehen und angezündet. Nach 20 Minuten Brenndauer wurde die Flamme gelöscht. In der Tabelle bedeutet gl = gelblich, ff = fast farblos, f = farblos und st = stark. The examples (B1 to B3) and comparative examples (V1 to V3) according to the invention were carried out using the grill lighters specified in Table 1. For this purpose, 20 ml of the oil were placed in a crucible, provided with a 12.5 cm long wick and lit. The flame was extinguished after 20 minutes of burning. In the table, gl means yellowish, ff = almost colorless, f = colorless and st = strong.
Claims (7)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19716911A DE19716911C1 (en) | 1997-04-22 | 1997-04-22 | Use of fat derivatives as lamp oil and grill lighter |
DE19716911 | 1997-04-22 | ||
EP98106696A EP0874038B1 (en) | 1997-04-22 | 1998-04-11 | Application of fatty derivatives as lamp oil |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98106696A Division EP0874038B1 (en) | 1997-04-22 | 1998-04-11 | Application of fatty derivatives as lamp oil |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1132456A2 true EP1132456A2 (en) | 2001-09-12 |
EP1132456A3 EP1132456A3 (en) | 2002-01-09 |
EP1132456B1 EP1132456B1 (en) | 2003-10-01 |
Family
ID=7827342
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98106696A Expired - Lifetime EP0874038B1 (en) | 1997-04-22 | 1998-04-11 | Application of fatty derivatives as lamp oil |
EP01105624A Expired - Lifetime EP1132456B1 (en) | 1997-04-22 | 1998-04-11 | Application of fatty derivatives as grill lighter |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98106696A Expired - Lifetime EP0874038B1 (en) | 1997-04-22 | 1998-04-11 | Application of fatty derivatives as lamp oil |
Country Status (6)
Country | Link |
---|---|
EP (2) | EP0874038B1 (en) |
AT (2) | ATE251209T1 (en) |
DE (3) | DE19716911C1 (en) |
DK (2) | DK0874038T3 (en) |
ES (2) | ES2202681T3 (en) |
PT (2) | PT1132456E (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011116772A1 (en) * | 2010-03-22 | 2011-09-29 | Agowa Ip Aps | Fatty acid ester based firelighter |
EP2738240A1 (en) | 2012-11-30 | 2014-06-04 | Schepers Handels- en domeinnamen B.V. | Use of a Gas-to-Liquids gas oil in a lamp oil composition or fire lighter |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1149888A1 (en) * | 2000-04-26 | 2001-10-31 | Cognis Deutschland GmbH | Application of fatty acidesters as illuminating oil |
NL1015863C2 (en) * | 2000-08-02 | 2002-02-05 | Sel Chemie B V | Liquid, water-miscible fuel composition. |
US7524339B2 (en) | 2003-12-02 | 2009-04-28 | Lumetique, Inc. | Lamp oil composition and lighter fluid composition |
GB0721573D0 (en) * | 2007-11-02 | 2007-12-12 | Standard Brands Uk Ltd | Firefighter fluid |
DK2396390T3 (en) * | 2009-02-11 | 2017-01-16 | Agowa Ip Aps | Use of a preparation as a lamp fuel |
US20150153038A1 (en) * | 2013-12-02 | 2015-06-04 | Lamplight Farms Incorporated | Methyl ester torch fuel |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL8400490A (en) * | 1984-02-15 | 1985-09-02 | Gerrit Jan | Combustible block or tablet for open fire, firelighter etc. - has combustible pressed pref. saw-cut carrier of e.g. cellulose-contg. material impregnated with low vapour pressure fat |
CA2057322A1 (en) * | 1991-12-09 | 1993-06-10 | Shirley Isabelle Lalonde | Fire starter |
-
1997
- 1997-04-22 DE DE19716911A patent/DE19716911C1/en not_active Expired - Fee Related
-
1998
- 1998-04-11 PT PT01105624T patent/PT1132456E/en unknown
- 1998-04-11 ES ES98106696T patent/ES2202681T3/en not_active Expired - Lifetime
- 1998-04-11 PT PT98106696T patent/PT874038E/en unknown
- 1998-04-11 EP EP98106696A patent/EP0874038B1/en not_active Expired - Lifetime
- 1998-04-11 DK DK98106696T patent/DK0874038T3/en active
- 1998-04-11 DE DE59809827T patent/DE59809827D1/en not_active Expired - Lifetime
- 1998-04-11 AT AT01105624T patent/ATE251209T1/en active
- 1998-04-11 ES ES01105624T patent/ES2210051T3/en not_active Expired - Lifetime
- 1998-04-11 DK DK01105624T patent/DK1132456T3/en active
- 1998-04-11 EP EP01105624A patent/EP1132456B1/en not_active Expired - Lifetime
- 1998-04-11 DE DE59808865T patent/DE59808865D1/en not_active Expired - Lifetime
- 1998-04-11 AT AT98106696T patent/ATE244291T1/en active
Non-Patent Citations (2)
Title |
---|
DATABASE WPI Section Ch, Week 8539 Derwent Publications Ltd., London, GB; Class H09, AN 85-241030 XP002098462 & NL 8 400 490 A (TE KIEFTE G J), 2. September 1985 (1985-09-02) * |
DATABASE WPI Section Ch, Week 9335 Derwent Publications Ltd., London, GB; Class H09, AN 93-273263 XP002098461 & CA 2 057 322 A (LALONDE S I), 10. Juni 1993 (1993-06-10) * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011116772A1 (en) * | 2010-03-22 | 2011-09-29 | Agowa Ip Aps | Fatty acid ester based firelighter |
EP2738240A1 (en) | 2012-11-30 | 2014-06-04 | Schepers Handels- en domeinnamen B.V. | Use of a Gas-to-Liquids gas oil in a lamp oil composition or fire lighter |
Also Published As
Publication number | Publication date |
---|---|
EP0874038A2 (en) | 1998-10-28 |
EP1132456B1 (en) | 2003-10-01 |
ATE251209T1 (en) | 2003-10-15 |
ATE244291T1 (en) | 2003-07-15 |
ES2210051T3 (en) | 2004-07-01 |
DK1132456T3 (en) | 2004-02-09 |
DE59809827D1 (en) | 2003-11-06 |
EP0874038B1 (en) | 2003-07-02 |
PT874038E (en) | 2003-11-28 |
DE59808865D1 (en) | 2003-08-07 |
EP1132456A3 (en) | 2002-01-09 |
EP0874038A3 (en) | 1999-05-26 |
DK0874038T3 (en) | 2003-11-03 |
DE19716911C1 (en) | 1998-10-01 |
PT1132456E (en) | 2004-02-27 |
ES2202681T3 (en) | 2004-04-01 |
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