EP1002036A1 - Utilisation de polysaccharides oxydes dans des compositions detergentes - Google Patents
Utilisation de polysaccharides oxydes dans des compositions detergentesInfo
- Publication number
- EP1002036A1 EP1002036A1 EP98935395A EP98935395A EP1002036A1 EP 1002036 A1 EP1002036 A1 EP 1002036A1 EP 98935395 A EP98935395 A EP 98935395A EP 98935395 A EP98935395 A EP 98935395A EP 1002036 A1 EP1002036 A1 EP 1002036A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polysaccharide
- oxidation
- use according
- polycarboxy
- degree
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/223—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin oxidised
Definitions
- the invention relates to the use of polycarboxy polysaccharides in detergent compositions.
- Detergent compositions contain a builder to neutralise the effect of water hardness, dissolution of soil and the like.
- phosphate is an effective builder, its use is undesired for environmental reasons.
- Zeolites have largely replaced phosphates as builder.
- they require the presence of a cobuilder which prevents the redeposition of soil and the precipitation of calcium carbonate, and improves whiteness of the washed laundry.
- Synthetic polymers, such as polyacrylates have found extensive use as cobuilders, but they are poorly biodegradable. Thus there is need for biodegradable and yet effective cobuilder materials for use in textile washing compositions, dish-washing compositions and the like.
- EP- A- 755944 discloses a method for the production of oxidising maltodextrins having a DE (dextrose equivalent) between 2 and 20, especially a DE of 11-14, using oxygen or hydrogen peroxide under alkaline conditions in the absence of a catalyst followed by bleaching. This oxidation results in conversion of the reducing end groups in arabinonic acid groups.
- the product can be used as a cobuilder in detergent compositions wherein it improves whiteness and reduces inorganic incrustation, or as a binder or thickening agent.
- dicarboxylic polysaccharides such as dicarboxy starch and dicarboxy amylodextrins as a calcium sequestering agent has been described in various documents, e.g. Kohn and Tihlarik, Coll. Czech. Chem. Commun. 49 (1984) 2116, EP-A-427349 and NL-A-8802907.
- the polysaccharides to be oxidised according to the invention are primarily starch and starch derivatives such as hydrolysed starch and carboxymethyl starch.
- Other glucans such as cellulose derivatives, 1,3-glucans or 1,6-glucans, galactomannans (e.g. guar) and other vegetal and bacterial gums, can also be used. These have molecular weights of 1600-12,000 (10-75 anhydromonose units), preferably of 2000-10,000 (12-60 amu's), most preferably 2900-7300 (18-40 amu's).
- Other classes of suitable poly-saccharides are fructans (e.g.
- inulin which can be used with molecular weights from about 240 upwards, especially 500-12,000, more preferably 1600-5000 (10-30 amu's), and pentosans, such as xylans (hemicellulose), e.g. from waste carbohydrates, with molecular weights of 1500-12,000, preferably 2000-8000, most preferably 2600- 6600 (20-50 amu's).
- the degree of oxidation is preferably from 0.12 to 0.6, preferably from 0.15 to 0.55, especially form 0.2 to 0.5.
- the oxidised polysaccharides are preferably obtained by treatment of the poly- saccharide (e.g. starch) with a hypochlorite solution at pH 7.5-10, especially at pH 8-9, the hypochlorite being added gradually in order to be able to maintain the pH more or less constant by addition of a base.
- the reaction temperature can be e.g. between 0 and 40 °C, especially at ambient temperature.
- the oxidised product can be isolated by known techniques, including ethanol precipitation and freeze-drying. Such precipitation has the advantage of removing products that have excessive degrees of oxidation.
- C2-C3 oxidation of glucans, mannans, xylans etc. are also suitable, for example oxidation with periodate (cf. WO 95/12619 or Nieuwenhuizen et al, StarchlSt ⁇ rke, 37 (1985) 192-200), followed by chlorite oxidation.
- Other oxidations can also be used, e.g. oxidation with hydrogen peroxide in the presence of acetylated polysaccharides, or oxidation with hydrogen peroxide in the presence of copper and magnesium or other oxidation catalysts.
- Combinations of oxidation processes may also be used.
- a hydrolysis step (acid or enzymatic) may precede or follow the oxidation step.
- the invention also pertains to detergent compositions containing a polycarboxy polysaccharide as described above as a cobuilder, anti-redeposition agent and/or soil dispersant.
- the composition contains 0.5-5 wt.% of the cobuilder prepared according to the invention, and further a detergent (12-25, especially 16-20 wt.%), a zeolite or silicate builder (15-30, especially 20-28 wt.%), a carboxylate such as sodium citrate (3-5 wt.%), a bleaching agent such as sodium perborate (10-20 wt.%), a catalyst such as TAED (3-4 wt.%), and optional further components such as enzymes (about 1-2 %: amylases, proteases), foaming or defoaming agents, odorants and the like.
- Starch was oxidised generally according to Floor, "Oxidation of maltodextrins and starch with alkaline sodium hypochlorite", Thesis, Chapter 6, Delft (NL), 1989, as follows: 75 g of potato starch was suspended in 250 ml water. The pH was adjusted to 8.5. The appropriate amount of sodium hypochlorite solution (4% or 16% active chlorine) was added at a rate of 10 ml/min for the first half hour and 20 ml/min afterwards for 4 % Cl 2 (2.5 and 5 ml/min, respectively, for 15% CI2) at ambient temperature. The pH was maintained at 8.5 by the addition of 5 M NaOH. After 20 h the pH was adjusted to 9 and 500 ml of ethanol 98% was added.
- the suspension was stored at -4°C for 16 h and then decanted.
- the precipitate was dissolved in 150 ml water and 300 ml of ethanol was added.
- the suspension was again stored at -4°C for 16 h and then decanted.
- the precipitate was dissolved in 150 ml water and the solution was freeze-dried.
- DCS-1 Paselli 6 (molecular weight of native starch reduced by a factor 6), 550 ml 4% Cl 2 , dicarboxy content 9% (carboxyl content 0.36 per anhydromonose unit), MW about 5400;
- DCS-2 Paselli 2, 500 ml 15% Cl 2 , dicarboxy content 19% (carboxyl content 0.48), MW about 3200;
- DCS-3 native potato starch, 390 ml 15% Cl , dicarboxy content 18% (carboxyl content 0.36), MW about 4700;
- DCS-4 native potato starch, 500 ml 15% Cl 2 , dicarboxy content 21% (carboxyl content 0.48), MW about 3600.
- Example 3 Wash tests Two co-builders were tested in a standard heavy duty formulation (HDF: see table 1) during 25 wash cycles using the 60°C cotton washing programme without prewash.
- product R HDF with reference cobuilder Sokalan CP 5 (a commercial polyacrylate cobuilder)
- the washing tests were carried out in commercial drum-type domestic washing machines Miele Novotronic W 918.
- the test of each product was made in alternating machines, in order to avoid effects caused by specific differences of the machines.
- the tests were carried out at a water hardness of 2.86 mmol/1 in a 60°C cotton programme without prewash.
- the total machine load was 4.5 kg.
- the dosage of formulation was 80 g per wash.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Polysaccharides polycarboxy, en particulier dicarboxymaltodextrines, dont le poids moléculaire est situé entre 1.600 et 12.000 et dont le degré d'oxydation (DO) est de 0,12 à 0,6 groupe carboxyle par unité d'anhydromonose, qui peuvent être utilisés comme co-adjuvant, en particulier comme agent d'antiredéposition et comme agent de dispersion de la saleté dans des compositions détergentes.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP98935395A EP1002036A1 (fr) | 1997-07-15 | 1998-07-15 | Utilisation de polysaccharides oxydes dans des compositions detergentes |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97202196 | 1997-07-15 | ||
EP97202196A EP0892041A1 (fr) | 1997-07-15 | 1997-07-15 | Utilisation des polysaccharides oxydés dans les compositions détergentes |
EP98935395A EP1002036A1 (fr) | 1997-07-15 | 1998-07-15 | Utilisation de polysaccharides oxydes dans des compositions detergentes |
PCT/NL1998/000409 WO1999003961A1 (fr) | 1997-07-15 | 1998-07-15 | Utilisation de polysaccharides oxydes dans des compositions detergentes |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1002036A1 true EP1002036A1 (fr) | 2000-05-24 |
Family
ID=8228559
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97202196A Withdrawn EP0892041A1 (fr) | 1997-07-15 | 1997-07-15 | Utilisation des polysaccharides oxydés dans les compositions détergentes |
EP98935395A Withdrawn EP1002036A1 (fr) | 1997-07-15 | 1998-07-15 | Utilisation de polysaccharides oxydes dans des compositions detergentes |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97202196A Withdrawn EP0892041A1 (fr) | 1997-07-15 | 1997-07-15 | Utilisation des polysaccharides oxydés dans les compositions détergentes |
Country Status (5)
Country | Link |
---|---|
EP (2) | EP0892041A1 (fr) |
JP (1) | JP2001510232A (fr) |
AU (1) | AU8465998A (fr) |
CA (1) | CA2295481A1 (fr) |
WO (1) | WO1999003961A1 (fr) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7727945B2 (en) | 2005-07-15 | 2010-06-01 | Akzo Nobel N.V. | Modified polysaccharides |
JP5544107B2 (ja) * | 2008-03-31 | 2014-07-09 | 花王株式会社 | 高分子ビルダー |
JP2009263641A (ja) * | 2008-03-31 | 2009-11-12 | Kao Corp | ポリウロン酸塩の製造方法 |
EP2261262A4 (fr) * | 2008-03-31 | 2013-07-10 | Kao Corp | Procédé de fabrication de polyuronate |
US9376648B2 (en) | 2008-04-07 | 2016-06-28 | The Procter & Gamble Company | Foam manipulation compositions containing fine particles |
DE102008053607A1 (de) | 2008-10-20 | 2010-04-22 | Südzucker AG Mannheim/Ochsenfurt | Solubilisierungsmittel für Metallionen |
FR2961394B1 (fr) * | 2010-06-21 | 2012-06-01 | Oreal | Composition cosmetique comprenant au moins un polysaccharide oxyde non cationique et une huile, de preference polaire |
MX2016011467A (es) * | 2014-03-11 | 2016-11-16 | Du Pont | Poli alfa-1,3-glucano oxidado como mejorador de detergente. |
EP3797146A1 (fr) * | 2018-05-23 | 2021-03-31 | Dow Global Technologies, LLC | Formules de lave-vaisselle anhydre |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL8802907A (nl) * | 1988-11-25 | 1990-06-18 | Avebe Coop Verkoop Prod | Werkwijze voor het vervaardigen van dicarboxypolysacchariden. |
DK0427349T3 (da) * | 1989-11-10 | 1995-11-20 | Tno | Fremgangsmåde til fremstilling af polydicarboxysaccharider, og erstatninger for phosphater i detergenter baseret på polydicarboxsaccharider |
IT1249883B (it) * | 1990-08-13 | 1995-03-30 | Ferruzzi Ricerca & Tec | Agenti sequestranti del calcio a base di carboidrati ossidati e loro impiego come builder per detergenti |
DE4134914A1 (de) * | 1991-10-23 | 1993-04-29 | Henkel Kgaa | Wasch- und reinigungsmittel mit ausgewaehlten builder-systemen |
EP0542496B1 (fr) * | 1991-11-14 | 1998-05-20 | The Procter & Gamble Company | Amidon oxydé à C6/C2-C3 utilisé comme ingrédient pour détergent |
ATE143378T1 (de) * | 1991-12-23 | 1996-10-15 | Cerestar Holding Bv | Verfahren zur herstellung von sauerstoffsäuren aus kohlenhydraten |
NL9301905A (nl) * | 1993-11-04 | 1995-06-01 | Inst Voor Agrotech Onderzoek | Werkwijze voor het oxideren van koolhydraten. |
GB9514090D0 (en) * | 1995-07-11 | 1995-09-13 | Cerestar Holding Bv | Non-catalysed oxidation of maltodextrin with an oxygen containing oxidant |
-
1997
- 1997-07-15 EP EP97202196A patent/EP0892041A1/fr not_active Withdrawn
-
1998
- 1998-07-15 CA CA002295481A patent/CA2295481A1/fr not_active Abandoned
- 1998-07-15 JP JP2000503169A patent/JP2001510232A/ja active Pending
- 1998-07-15 WO PCT/NL1998/000409 patent/WO1999003961A1/fr not_active Application Discontinuation
- 1998-07-15 AU AU84659/98A patent/AU8465998A/en not_active Abandoned
- 1998-07-15 EP EP98935395A patent/EP1002036A1/fr not_active Withdrawn
Non-Patent Citations (1)
Title |
---|
See references of WO9903961A1 * |
Also Published As
Publication number | Publication date |
---|---|
CA2295481A1 (fr) | 1999-01-28 |
AU8465998A (en) | 1999-02-10 |
WO1999003961A1 (fr) | 1999-01-28 |
JP2001510232A (ja) | 2001-07-31 |
EP0892041A1 (fr) | 1999-01-20 |
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Legal Events
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
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17P | Request for examination filed |
Effective date: 20000106 |
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AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE |
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17Q | First examination report despatched |
Effective date: 20010424 |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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18D | Application deemed to be withdrawn |
Effective date: 20010905 |