EP0996496A1 - Membranes poreuses a renforcement par non tisses integres - Google Patents
Membranes poreuses a renforcement par non tisses integresInfo
- Publication number
- EP0996496A1 EP0996496A1 EP98939624A EP98939624A EP0996496A1 EP 0996496 A1 EP0996496 A1 EP 0996496A1 EP 98939624 A EP98939624 A EP 98939624A EP 98939624 A EP98939624 A EP 98939624A EP 0996496 A1 EP0996496 A1 EP 0996496A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fleece
- integrally
- polymer
- approximately
- reinforced porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000002787 reinforcement Effects 0.000 title claims abstract description 11
- 239000012528 membrane Substances 0.000 claims abstract description 74
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 22
- 239000000835 fiber Substances 0.000 claims abstract description 18
- 230000035699 permeability Effects 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims description 23
- -1 polypropylene Polymers 0.000 claims description 8
- 229920002678 cellulose Polymers 0.000 claims description 6
- 229920000620 organic polymer Polymers 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 239000012779 reinforcing material Substances 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 229920002301 cellulose acetate Polymers 0.000 claims description 4
- 229920006393 polyether sulfone Polymers 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 3
- 150000004677 hydrates Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 150000002823 nitrates Chemical class 0.000 claims description 3
- 229920001220 nitrocellulos Polymers 0.000 claims description 3
- 229920002492 poly(sulfone) Polymers 0.000 claims description 3
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 3
- 238000001914 filtration Methods 0.000 abstract description 18
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000012530 fluid Substances 0.000 abstract description 2
- 244000005700 microbiome Species 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 4
- 244000052616 bacterial pathogen Species 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000186146 Brevibacterium Species 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000010353 genetic engineering Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/10—Supported membranes; Membrane supports
- B01D69/107—Organic support material
- B01D69/1071—Woven, non-woven or net mesh
Definitions
- the invention relates to integrally fleece-reinforced porous membranes with improved properties.
- the membranes according to the invention are used as filter materials in known filter modules and are suitable for the filtration of fluids, in particular liquids, in which a long service life, filtration performance and filtration reliability are important.
- Porous membranes are to be understood as ultrafiltration and microfiltration membranes which have pores with diameters in the range from approximately 0.001 to approximately 0.1 ⁇ m or from approximately 0.01 to approximately 30 ⁇ m.
- they are made from organic polymers.
- Such membranes are often sensitive to breakage and have little mechanical stress.
- porous membranes made from organic polymers are reinforced with a wide variety of carrier materials.
- a frequently encountered group are textile-reinforced membranes, in which the reinforcement consists of a woven, knitted, fleece or a film. From the type of connection between membrane and reinforcement material, one can basically differentiate between integrally and non-integrally reinforced membranes.
- Integrally reinforced membranes are to be understood to mean those membranes in which the still liquid membrane material is brought into contact with the reinforcement and the membrane is subsequently formed.
- the reinforcement has at least partially penetrated the membrane or is completely enclosed by it.
- the membrane can be reinforced on one or both sides.
- the finished membrane is applied directly to the reinforcement, for example by lamination or by means of an adhesive
- Integrally fleece-reinforced membranes are preferred for production and application reasons.
- the object of the invention is therefore to find integrally fleece-reinforced porous membranes with an improved service life, filtration performance and retention capacity
- integrally reinforced porous membranes which have reinforcing materials made of compressed nonwovens.
- These compacted nonwovens are selected from a group of nonwovens that have a basis weight between approximately 20 to 40 g / m 2 , a thickness between approximately 90 to 170 ⁇ m and have an air permeability between approximately 1200 and 2400 1 / m 2 s at 0.002 bar
- membranes according to the invention have a number of unexpected advantages over integrally fleece-reinforced membranes of the prior art with the same flow rate for water. For example, they have an approximately two to five times longer service life and filtration performance and a better one Retention capacity, for example for microorganisms
- the membranes according to the invention can moreover be tested for integrity with greater certainty, since they have a bubble point which is approximately up to 40% higher and a diffusion which is reduced by a factor of 10 to 20 Filtration systems that have modules equipped with such membranes can be tested for integrity with greater certainty, which ensures a high safety standard, particularly in sensitive filtration areas, such as the pharmaceutical, biotechnological, beverage and food industries, as well as in medical and genetic engineering facilities .
- the nonwoven fabric consists of a non-woven multicomponent nonwoven fabric, the multicomponent fibers comprising a first polymer and a second polymer such that the second polymer is present on at least a portion of the surface of the multicomponent fibers and has a softening temperature which is below that Softening temperature of the first polymer is.
- multi-component nonwovens made from core sheath fibers are used, the core preferably being made of a solid polymer softening at a higher temperature, e.g. B. polypropylene and the sheath of a more chemically resistant thermoplastic polymer, e.g. consists of polyethylene.
- membrane polymers which are suitable for the formation of porous membranes according to the phase inversion principle can be used as membrane polymers, namely both by the evaporation process, the precipitation bath process and by a mixed process.
- Membrane polymers selected from the group of polysulfones, polyether sulfones, polyamides, polyacrylonitriles, cellulose hydrates and cellulose esters are particularly suitable.
- Polyether sulfones, polyamides and cellulose acetates and nitrates or mixtures thereof are particularly preferred.
- integrally fleece-reinforced porous membranes according to the invention can be processed as flat filters and in pleated form or as tubular membranes and can also be processed as reinforcing material for further membrane layers.
- the invention will be explained in more detail using the exemplary embodiments below.
- a membrane casting solution which contains 7.2% by weight of cellulose acetate is applied in a thickness of approximately 130 ⁇ m to a compacted nonwoven fabric.
- the fiber fleece consists of core sheath fibers with a core made of polypropylene and a sheathing made of polyethylene.
- the thickness of the nonwoven fabric is 130 ⁇ m with a basis weight of about 30 g / m 2.
- the air permeability is about 1800 1 / m 2 s at 0.002 bar.
- the membrane is formed on the nonwoven fabric by phase inversion according to the known evaporation process
- the integrally fleece-reinforced membrane thus formed has a bubble point of 3.2 bar.
- the diffusion is ⁇ 2.3 • 10 "3 ml / cm 2 min at a pressure difference of 2 bar or ⁇ 0.8 • 10 " 3 ml / cm 2 min at a pressure difference of 1.5 bar.
- the permeability to RO water at room temperature is 14.8 ml / cm 2 min bar.
- the service life of the membrane is 450% based on a standard membrane.
- the service life (filtration performance) is determined as the throughput (amount of filtrate) when a 10% aqueous brown raw sugar solution is filtered through the membrane sample at 1 bar pressure difference and a filtration time of 10 minutes, based on the throughput of this solution through a standard membrane (0.45 ⁇ m membrane made of polyamide 6.6) under identical conditions
- the service life is stated in% of the performance of the comparative filter
- Example 2 Analogously to Example 1, an integrally fleece-reinforced membrane is produced, but instead of the compressed fiber fleece, a core sheath fiber fleece of the prior art is used Technology used. The thickness of this nonwoven is 250 microns at one
- Basis weight of about 30 g / m 2 .
- the air permeability is approximately 4000 1 / m 2 s
- the comparison membrane has a bubble point of 2.8 bar.
- the diffusion is> 34.6 * 10 "3 ml / cm 2 min at a pressure difference of 2 bar or ⁇ 13.1 • 10 "
- the membrane has a permeability to RO water of 14.9 ml / cm 2 min bar at room temperature and has a service life of 97% of the standard membrane with filtration of 10% aqueous brown raw sugar solution.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Laminated Bodies (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
L'invention concerne des membranes poreuses à renforcement par non tissés intégrés, présentant des caractéristiques améliorées telles qu'une vie utile plus longue, un plus grand pouvoir filtrant et une plus grande capacité de retenue. Les membranes poreuses à renforcement par non tissés intégrés présentées disposent de matériaux de renforcement constitués de non tissés en fibres compactés qui sont choisis dans un groupe comprenant des non tissés présentant un grammage compris entre environ 20 et 40 g/m2, une épaisseur comprise entre environ 90 et 170 νm et une perméabilité à l'air comprise entre environ 1200 et 2400 l/m2s à 0,002 bars. Par rapport aux membranes de l'état antérieur, les membranes selon l'invention ont une vie utile et un pouvoir filtrant supérieurs d'environ 2 à 5 fois ainsi qu'une meilleure capacité de retenue, par exemple pour les micro-organismes, et leur intégrité peut être contrôlée avec une plus grande sécurité. Les membranes selon l'invention sont utilisées comme matériaux filtrants dans des modules filtrants connus et conviennent à la filtration de fluides, en particuliers de liquides, pour lesquels il est important d'avoir une longue vie utile, un grand pouvoir filtrant et une grande sécurité de filtration.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19729456 | 1997-07-10 | ||
DE19729456A DE19729456C1 (de) | 1997-07-10 | 1997-07-10 | Integral vliesverstärkte poröse Membranen |
PCT/EP1998/004228 WO1999002247A1 (fr) | 1997-07-10 | 1998-07-08 | Membranes poreuses a renforcement par non tisses integres |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0996496A1 true EP0996496A1 (fr) | 2000-05-03 |
Family
ID=7835208
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98939624A Withdrawn EP0996496A1 (fr) | 1997-07-10 | 1998-07-08 | Membranes poreuses a renforcement par non tisses integres |
Country Status (5)
Country | Link |
---|---|
US (1) | US6293411B1 (fr) |
EP (1) | EP0996496A1 (fr) |
JP (1) | JP2001509430A (fr) |
DE (1) | DE19729456C1 (fr) |
WO (1) | WO1999002247A1 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007014416A1 (fr) * | 2005-08-04 | 2007-02-08 | Intellectual Property Development Corporation Pty Ltd | Pulverisateur |
US7441667B2 (en) * | 2005-12-15 | 2008-10-28 | E.I. Du Pont De Nemours And Company | Composite membranes for liquid filtration having improved uniformity and adhesion of substrate to membrane |
US8678201B2 (en) * | 2010-06-04 | 2014-03-25 | Goodrich Corporation | Aircraft potable water system |
DE102016013019A1 (de) * | 2016-10-31 | 2018-05-03 | Sartorius Stedim Biotech Gmbh | Poröses Flächengebilde, Filterelement, Verfahren zu ihrer Herstellung und ihre Verwendung |
US11998879B2 (en) | 2017-03-24 | 2024-06-04 | Mitsubishi Paper Mills Limited | Semipermeable membrane support |
DE102018002261A1 (de) * | 2018-03-19 | 2019-09-19 | Sartorius Stedim Biotech Gmbh | Filtermodul mit randverstärkter Membran, Verfahren zur Herstellung des Filtermoduls sowie dessen Verwendung |
JP7032460B2 (ja) * | 2020-01-28 | 2022-03-08 | 株式会社エフ・シー・シー | 濾過フィルタの製造方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DK170416B1 (da) * | 1978-05-15 | 1995-08-28 | Pall Corp | Mikroporøs, hydrofil, hindefri, alkoholuopløselig polyamidharpiksmembran, fremgangsmåde til dens fremstilling, anvendelse af membranen i filterelementer samt harpiksstøbeopløsning til brug ved fremgangsmåden |
JPS61222506A (ja) * | 1985-03-29 | 1986-10-03 | Japan Vilene Co Ltd | 半透膜支持体及びその製造方法 |
US4894157A (en) * | 1987-10-05 | 1990-01-16 | Micron Separations, Inc. | Process for producing supported celluosic membranes and products |
US5108827A (en) * | 1989-04-28 | 1992-04-28 | Fiberweb North America, Inc. | Strong nonwoven fabrics from engineered multiconstituent fibers |
DE3928934C2 (de) * | 1989-08-31 | 1999-04-29 | Sartorius Gmbh | Textilverstärktes mikroporöses Membranfilter, Verfahren zu seiner Herstellung und seine Verwendung |
TW205513B (fr) * | 1991-02-28 | 1993-05-11 | Hoechst Ag | |
EP0641249A1 (fr) * | 1992-05-18 | 1995-03-08 | Costar Corporation | Membranes microporeuses soutenues |
DE4234816C1 (de) * | 1992-10-15 | 1993-10-07 | Seitz Filter Werke | Textilverstärkte Membran und Verfahren zu deren Herstellung |
US5433859A (en) * | 1993-07-12 | 1995-07-18 | Pall Corporation | Supported microporous filtration membrane and method of using same |
CA2160282A1 (fr) * | 1995-02-14 | 1996-08-15 | Michael R. Gildersleeve | Ensemble a membrane supportee |
DE19543954A1 (de) * | 1995-11-25 | 1997-05-28 | Sartorius Gmbh | Druckstabile, poröse polymere Rohrmembran für Rohrmodule und Verfahren zu ihrer Herstellung |
-
1997
- 1997-07-10 DE DE19729456A patent/DE19729456C1/de not_active Expired - Fee Related
-
1998
- 1998-07-08 WO PCT/EP1998/004228 patent/WO1999002247A1/fr not_active Application Discontinuation
- 1998-07-08 JP JP2000501827A patent/JP2001509430A/ja active Pending
- 1998-07-08 EP EP98939624A patent/EP0996496A1/fr not_active Withdrawn
-
1999
- 1999-09-27 US US09/406,046 patent/US6293411B1/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO9902247A1 * |
Also Published As
Publication number | Publication date |
---|---|
JP2001509430A (ja) | 2001-07-24 |
WO1999002247A1 (fr) | 1999-01-21 |
US6293411B1 (en) | 2001-09-25 |
DE19729456C1 (de) | 1998-10-22 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19990901 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): FR GB |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 20040203 |