EP0956247B1 - Aerosolvorrichtung auf basis einer zusammensetzung von fixierstoffen, die ein klebefreies haarformen ermöglichen - Google Patents

Aerosolvorrichtung auf basis einer zusammensetzung von fixierstoffen, die ein klebefreies haarformen ermöglichen Download PDF

Info

Publication number
EP0956247B1
EP0956247B1 EP97952060A EP97952060A EP0956247B1 EP 0956247 B1 EP0956247 B1 EP 0956247B1 EP 97952060 A EP97952060 A EP 97952060A EP 97952060 A EP97952060 A EP 97952060A EP 0956247 B1 EP0956247 B1 EP 0956247B1
Authority
EP
European Patent Office
Prior art keywords
les
radical
hair
aerosol
par
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97952060A
Other languages
English (en)
French (fr)
Other versions
EP0956247A1 (de
Inventor
Henri Samain
Patrice Lerda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LOreal SA filed Critical LOreal SA
Publication of EP0956247A1 publication Critical patent/EP0956247A1/de
Application granted granted Critical
Publication of EP0956247B1 publication Critical patent/EP0956247B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers or packages with special means for dispensing contents for delivery of liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant for a product delivered by a propellant
    • B65D83/75—Aerosol containers not provided for in groups B65D83/16 - B65D83/74
    • B65D83/752—Aerosol containers not provided for in groups B65D83/16 - B65D83/74 characterised by the use of specific products or propellants

Definitions

  • the present invention relates to new aerosol devices allowing the shaping and / or the maintenance of the hairstyle without formation of welds between the hair.
  • the fixing products that are applied as an aerosol to the dry hair is practical to use and provides shaping and maintenance of strong and lasting hairstyle, but hairstyles thus treated often have an appearance frozen visual and an unnatural touch.
  • Styling products that are applied to damp hair are less practical to use. They lead to weaker fixation when are applied in small quantities. The visual aspect and the touch are however more natural than for fixing products. When applied in large quantity on dry hair, we can stick the hair between them and find so much the fixing properties of fixing products as their appearance related problems visual and to the touch of the hair, without the advantages of their mode of application.
  • the Applicant has now found that by selecting the diffusion parameters of the usual aerosol compositions, it was possible to combine the practicality of using fixing products and a good level of setting in the shape of the hair, with the visual aspect and the more natural touch linked to styling products.
  • the present invention therefore relates to a new aerosol device allowing the shaping and / or the maintenance of the hairstyle without formation of welds between the hair.
  • Fixing products for shaping and / or maintaining the hairstyle are spray compositions essentially consisting of a usually alcoholic or aqueous solution and one or more materials, generally polymer resins, the function of which is to form welds between the hair, also called fixing materials, mixed with various cosmetic additives.
  • This solution is generally packaged either in a suitable aerosol container pressurized with a propellant, or in a pump bottle.
  • the fixing materials applied to the hair do not form welds between the hair, but allow the hairstyle to be maintained, which is similar to that of styling products. Broadcast settings are selected from so that little fixing material is deposited on the hair to avoid formation of welds, but in sufficient quantity to ensure the maintenance of the hairdressing.
  • the sufficient quantity of fixing material is expressed by the flow rate in dry matter, while the maximum amount of material deposited on the hair is expressed by the wetting power at 20 cm.
  • the present invention therefore relates to a new aerosol device consisting of a container containing an aerosol composition consisting of a leaves by a liquid phase or juice containing at least one fixing material in an appropriate medium and secondly a propellant, and a means of distributing said aerosol composition, the device being suitable for obtaining a flow rate dry matter less than or equal to about 12 mg / s and a wetting power of 20 cm less than or equal to about 100 mg / s.
  • the distribution means generally consists of a valve distribution controlled by a distribution head, itself comprising a nozzle through which the aerosol composition is vaporized.
  • the dry matter flow rate corresponds to the quantity of dry extract which leaves the aerosol device per unit of time.
  • the concentration of dry matter in the aerosol composition corresponds to the amount of dry matter reduced to 100 g of aerosol composition (juice + propellant).
  • the dry matter concentration is expressed as a percentage and is measured after spraying by evaporation of the volatile components from the spray residue for 1 hour 30 minutes at 105 ° C.
  • an appropriate device comprising means for supporting the aerosol device, and means allowing the three-dimensional adjustment of the nozzle position in relation to the vertical sheet.
  • This device can also be equipped with a pneumatic control device spray (trigger and duration), so as to precisely control the duration of spraying.
  • the assembly can be controlled by a computer.
  • the path of the product between the nozzle and the sheet will advantageously be protected horizontally and vertically through the walls of a tunnel of appropriate dimensions.
  • the vaporization of the product is advantageously carried out under controlled atmosphere, preferably at a temperature of 20 ° C and 50% relative humidity.
  • the aerosol device according to the invention is suitable for obtaining a dry matter flow rate between 2 and 12 mg / s.
  • the aerosol device according to the invention is suitable for obtaining a wetting power at 20 cm between 10 mg / s and 100 mg / s, more preferably between 20 and 80 mg / s.
  • the characteristics of dry matter flow rate and wetting power of the aerosol devices according to the invention depend on the one hand on the aerosol composition, and on the other hand on the distribution means, both of which must be suitable for obtaining the desired characteristics.
  • the parameters likely to influence these characteristics there will be mentioned more particularly the dry matter concentration (C MS ), the flow rate of aerosol composition (D CA ) and the phase of the aerosol composition.
  • the dry matter concentration (C MS ) is less than or equal to 6% by weight relative to the total weight of the aerosol composition (juice + propellant), preferably between 0.4 and 5% by weight. weight, more preferably between 0.6 and 3.25% by weight.
  • the flow rate in aerosol composition (D CA ) will then be suitable for obtaining a flow rate in dry matter (D MS ) as defined above.
  • the D CA will be greater than or equal to 200 mg / s, advantageously between 200 and 600 mg / s, more preferably between 300 and 400 mg / s.
  • the phase of the aerosol composition is preferably a phase long, i.e. the juice / propellant weight ratio is greater than 1, plus preferably between 1.2 and 3.
  • the fixing material essentially consists of at least one fixing polymer, alone or in combination with usual cosmetic additives, for example plasticizers, or neutralizing agents.
  • the fixing material having a temperature of glass transition (Tg) greater than or equal to 30 ° C.
  • transition temperature glassy (Tg) means the Tg of the fixing material in the dry extract, the dry extract consisting of all of the non-volatile materials in the juice, or dry matter.
  • any fixing polymer known per se can be used.
  • the fixing polymers can be used in dissolved form or in the form of dispersions of solid polymer particles.
  • the cationic fixing polymers which can be used according to the present invention are preferably chosen from polymers comprising primary, secondary, tertiary and / or quaternary amine groups forming part of the polymer chain or directly connected to it, and having a weight molecular between 500 and around 5,000,000 and preferably between 1,000 and 3,000,000.
  • the fixing polymers are preferably anionic or amphoteric polymers.
  • the anionic fixing polymers generally used are polymers containing groups derived from carboxylic, sulfonic acid or phosphoric and have a weight average molecular weight between around 500 and 5,000,000.
  • the carboxylic groups are provided by mono or unsaturated carboxylic diacid monomers such as those corresponding to the formula: in which n is an integer from 0 to 10, A 1 denotes a methylene group, optionally linked to the carbon atom of the unsaturated group or to the neighboring methylene group when n is greater than 1 via a heteroatom such as oxygen or sulfur, R 10 denotes a hydrogen atom, a phenyl or benzyl group, R 8 denotes a hydrogen atom, a lower alkyl or carboxyl group, R 9 denotes a hydrogen atom, a lower alkyl group, a group -CH 2 -COOH, phenyl or benzyl; In the above formula a lower alkyl radical preferably denotes a group having 1 to 4 carbon atoms and in particular, methyl and ethyl.
  • the polymers comprising the sulfonic groups are polymers containing vinylsulfonic, styrene sulfonic, naphthalene units sulfonic or acrylamido alkylsulfonic.
  • the anionic fixing polymers are preferably chosen from acrylic acid copolymers such as acid terpolymers acrylic / ethyl acrylate / N-tert-butylacrylamide sold in particular under the name ULTRAHOLD STRONG by BASF, the copolymers derived from crotonic acid such as acetate terpolymers vinyl / vinyl tertiary butyl benzoate / crotonic acid and acid terpolymers crotonic / vinyl acetate / vinyl neododecanoate sold in particular under the name Resin 28-29-30 by the company NATIONAL STARCH, polymers derived from maleic, fumaric acids or anhydrides, itaconic with vinyl esters, vinyl ethers, halides vinyl, phenylvinyl derivatives, acrylic acid and its esters such as mono-esterified methyl vinyl ether / maleic anhydride copolymers marketed for example under the name GANTREZ by
  • the most particularly preferred anionic fixing polymers are chosen from methyl vinyl ether / mono maleic anhydride copolymers esterifieds marketed under the name GANTREZ ES 425 by the company ISP, acrylic acid / ethyl acrylate / N-tert-butylacrylamide terpolymers marketed under the name ULTRAHOLD STRONG by the company BASF, copolymers of methacrylic acid and methyl methacrylate marketed under the name EUDRAGIT L by the company ROHM PHARMA, vinyl acetate / vinyl tert-butyl benzoate terpolymers / crotonic acid and crotonic acid / vinyl acetate / terpolymers vinyl neododecanoate sold under the name Resin 28-29-30 by the company NATIONAL STARCH, the copolymers of methacrylic acid and of ethyl acrylate sold under the name LUVIMER MAEX OR MAE by BASF,
  • Amphoteric fixing polymers which can be used in accordance with the invention can be chosen from polymers comprising units B and C statistically distributed in the polymer chain where B denotes a derivative pattern of a monomer comprising at least one basic nitrogen atom and C denotes a motif derived from an acidic monomer comprising one or more groups carboxylic or sulfonic or else B and C can denote groups derived from zwitterionic monomers of carboxybetaines or sulfobetaines; B and C can also denote a cationic polymer chain comprising primary, secondary, tertiary or quaternary amine groups, in which at least one of the amine groups carries a carboxylic group or sulfonic linked via a hydrocarbon radical or else B and C are part of a chain of a polymer containing an ethylene a, b-dicarboxylic one of the carboxylic groups has been reacted with a polyamine comprising one or more primary or secondary amine groups.
  • N-substituted acrylamides or methacrylamides more particularly preferred according to the invention are the groups whose radicals alkyl contain from 2 to 12 carbon atoms and more particularly N-ethylacrylamide, N-tertiobutyl acrylamide, N-tertiooctyl acrylamide, N-octylacrylamide, N-decylacrylamide, N-dodecylacrylamide as well as corresponding methacrylamides.
  • the acidic comonomers are chosen more particularly from the acrylic, methacrylic, crotonic, itaconic, maleic, fumaric acids as well as alkyl monoesters having 1 to 4 carbon atoms of the acids or maleic or fumaric anhydrides.
  • the preferred basic comonomers are aminoethyl methacrylates, of butyl aminoethyl, of N, N'-dimethylaminoethyl, of N-tertio-butyl-aminoethyl.
  • amphoteric fixing polymers which are particularly preferred according to the invention are those of the family (3) such as the copolymers whose CTFA name is Octylacrylamide / acrylates / butylaminoethylmethacrylate copolymer such as the products sold under the names AMPHOMER, AMHOMER LV 71 or LOVOCRYL 47 by the company NATIONAL STARCH and those of the family (4) such as methacrylate copolymers methyl / dimethyl carboxymethylammonio ethyl methylmethacrylate by example marketed under the name DIAFORMER Z301 by the company SANDOZ.
  • family (3) such as the copolymers whose CTFA name is Octylacrylamide / acrylates / butylaminoethylmethacrylate copolymer such as the products sold under the names AMPHOMER, AMHOMER LV 71 or LOVOCRYL 47 by the company NATIONAL STARCH
  • those of the family (4) such as meth
  • Anionic or amphoteric fixing polymers can be so necessary partially or totally neutralized.
  • Neutralizing agents are for example soda, potash, 2-amino-2-methyl-propanol-1, monoethanolamine, triethanolamine or triisopropanolamine, acids minerals or organic such as hydrochloric acid or citric acid.
  • the appropriate medium contains at least 50% by volume of alcohol, preferably at least 70% by volume of alcohol.
  • alcohol is meant according to the invention a C 1 -C 4 aliphatic alcohol, preferably ethanol.
  • the propellant consists of compressed or liquefied gases usually used for the preparation of aerosol compositions.
  • compressed air carbon dioxide or nitrogen, or a gas which may or may not be soluble in the composition, such as dimethyl ether, halogenated hydrocarbons (in particular fluorinated) or not and their mixtures.
  • C MS and phase The particular characteristics defined above (C MS and phase) can be obtained by selecting the appropriate distribution means and / or by acting on the formulation.
  • Valves suitable for the above particular compositions are in particular AQUASOL type valves from the company PRECISION, described in particular in patent application FR 2 382 637 (ABPLANALP) comprising separate individual conduits which are intended for products liquids and gaseous propellant communicating with a Venturi ejector type shock mixing, in which freely introduced propellants and fluids collide and mix so as to give a fine dispersion which is ejected through an orifice, and including maneuverable distribution elements simultaneously by a single organ controlling each current or their mixtures.
  • AQUASOL type valves from the company PRECISION, described in particular in patent application FR 2 382 637 (ABPLANALP) comprising separate individual conduits which are intended for products liquids and gaseous propellant communicating with a Venturi ejector type shock mixing, in which freely introduced propellants and fluids collide and mix so as to give a fine dispersion which is ejected through an orifice, and including maneuverable distribution elements simultaneously by a single organ controlling each current or
  • a valve will be used with a jet at two 0.5 mm diameter holes, a 0.36 or 0.58 mm valve body, with a nozzle opening of 0.36 and 0.60 mm respectively, and a member 0.25 x 0.25 mm two-channel disc shape (hereinafter designated V36 and V58).
  • Diffusers suitable for the above particular compositions are in particular the vortex nozzle pushbuttons, such as that distributed by the company PRECISION under the reference 216943-40.
  • the present invention also relates to a method of treatment keratin fibers, in which is applied to said fibers composition comprising a fixing material by means of a suitable device to obtain a dry matter flow rate of 12 mg / s or less and a power wetting at 20 cm less than or equal to 100 mg / s.
  • composition A Crotonic acid / vinyl acetate / t.butyl vinyl benzoate 3.00 g 2-amino-2-methyl-propanol-1 0.31 g Monomethyl ether of tripropylene glycol 0.24 g Ethanol qs 100.00 g
  • the device 1 according to the invention is prepared from the above composition with a V36 valve and a PRECISION push button ref. 216943-40.
  • the comparative device 2 is equipped with a valve PRECISION ref. P135 / S90 and a REBOUL push button ref. M40134830.
  • Tests carried out on five models show each time that the hair treated with the device 1 according to the invention has an appearance and a feel natural and have a significant strengthening effect on the hairstyle. When you pass your hand through your hair, you don't feel any discomfort, hair appears free, although styled and maintained.
  • the hair treated by device 2 outside of the invention does not have a natural feel and one feels hooking points when you run your hand through your hair.
  • Example 2 Device according to the invention
  • composition B Octylacrylamide / acrylates / butylaminoethylmethacrylate copolymer sold under the name AMPHOMER by the company NATIONAL STARCH 2.00 g 2-amino-2-methyl-propanol-1 0.36 g Ethanol qs 100.00 g
  • This device 3 according to the invention are as follows: Device 3 D MS (mg / s) 3.9 Wetting power at 20 cm (mg / s) 25
  • Tests of this device have been carried out on models.
  • the models are styled, then the device is applied for 20 seconds by continuous spray by distributing the spray evenly over the entire hair.
  • Tests carried out on five models show each time that the hair treated with the device 3 according to the invention has an appearance and a feel natural and have a significant strengthening effect on the hairstyle.
  • composition C Crotonic acid / vinyl acetate / t.butyl vinyl benzoate 12.00 g 2-amino-2-methyl-propanol-1 1.24 g Monomethyl ether of tripropylene glycol 0.96 g Ethanol qs 100.00 g
  • This comparative device 4 The characteristics of this comparative device 4 are as follows: Device 4 D MS (mg / s) 15.6 Wetting power at 20 cm (mg / s) 31
  • Tests carried out on five models show each time that the hair treated with the device 1 according to the invention has an appearance and a feel natural and have a significant strengthening effect on the hairstyle. When you pass your hand through your hair, you don't feel any discomfort, hair appears free, although styled and maintained.
  • the hair treated by the comparative device 4 shows that there are welds in places. The sustaining effect does not appear natural due to these welds.
  • the device according to the invention does not cause the formation of welds, although than applied longer, while the device 4 still drives in places to the formation of welds, with a solidification effect of the hair.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Cosmetics (AREA)

Claims (11)

  1. Aerosolvorrichtung, die aus einem Behälter, der eine Aerosolzusammensetzung enthält, die aus einer flüssigen Phase oder einem Saft, die in einem geeigneten Medium mindestens einen festigenden Stoff enthält, und aus einem Treibmittel besteht, und einem Mittel zur Verteilung der Aerosolzusammensetzung besteht, dadurch gekennzeichnet, dass die Vorrichtung geeignet ist, einen Durchsatz der Trockensubstanz von kleiner oder gleich etwa 12 mg/s und ein Benetzungsvermögen (20 cm) von kleiner oder gleich etwa 100 mg/s zu erzielen.
  2. Vorrichtung nach Anspruch 1, dadurch gekennzeichnet, dass sie geeignet ist, einen Durchsatz der Trockensubstanz im Bereich von 2 bis 12 mg/s zu erzielen.
  3. Vorrichtung nach einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, dass sie geeignet ist, ein Benetzungsvermögen im Bereich von 10 bis 100 mg/s und vorzugsweise von 20 bis 80 mg/s zu erzielen.
  4. Vorrichtung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Trockensubstanzkonzentration (KTS), bezogen auf das Gesamtgewicht der Aerosolzusammensetzung (Saft + Treibmittel), kleiner oder gleich 6 Gew,-% ist und vorzugsweise im Bereich von 0,4 bis 5 Gew.-% und noch bevorzugter im Bereich von 0,6 bis 3,25 Gew.-% liegt.
  5. Vorrichtung nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass der Durchsatz der Aerosolzusammensetzung (DAZ) größer oder gleich 200 mg/s ist und vorzugsweise im Bereich von 200 bis 600 mg/s und noch bevorzugter im Bereich von 300 bis 400 mg/s liegt.
  6. Vorrichtung nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass das Gewichtsverhältnis Saft/Treibmittel größer 1 ist und vorzugsweise im Bereich von 1,2 bis 3 liegt.
  7. Vorrichtung nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass der festigende Stoff eine Glasübergangstemperatur (Tg) von größer oder gleich 30 °C aufweist.
  8. Vorrichtung nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass der festigende Stoff im wesentlichen aus mindestens einem festigenden Polymer besteht.
  9. Vorrichtung nach Anspruch 8, dadurch gekennzeichnet, dass das festigende Polymer unter anionischen, kationischen, amphoteren und nichtionischen Polymeren sowie deren Gemischen ausgewählt ist.
  10. Vorrichtung nach einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, dass das geeignete Medium mindestens 50 Vol.-% Alkohol und vorzugsweise mindestens 70 Vol.-% Alkohol enthält.
  11. Verfahren zur Behandlung von Keratinfasern, dadurch gekennzeichnet, dass eine Zusammensetzung, die einen festigenden Stoff enthält, mit einer Vorrichtung auf die Fasern aufgebracht wird, die geeignet ist, einen Durchsatz der Trockensubstanz von kleiner oder gleich 12 mg/s und ein Benetzungsvermögen (20 cm) von kleiner oder gleich 100 mg/s zu erzielen.
EP97952060A 1997-01-31 1997-12-15 Aerosolvorrichtung auf basis einer zusammensetzung von fixierstoffen, die ein klebefreies haarformen ermöglichen Expired - Lifetime EP0956247B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9701104A FR2758983B1 (fr) 1997-01-31 1997-01-31 Dispositif aerosol a base de compositions de materiaux fixants permettant un coiffage sans soudures entre les cheveux
FR9701104 1997-01-31
PCT/FR1997/002301 WO1998033725A1 (fr) 1997-01-31 1997-12-15 Dispositif aerosol a base de compositions de materiaux fixants permettant un coiffage sans soudures entre les cheveux

Publications (2)

Publication Number Publication Date
EP0956247A1 EP0956247A1 (de) 1999-11-17
EP0956247B1 true EP0956247B1 (de) 2001-10-04

Family

ID=9503194

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97952060A Expired - Lifetime EP0956247B1 (de) 1997-01-31 1997-12-15 Aerosolvorrichtung auf basis einer zusammensetzung von fixierstoffen, die ein klebefreies haarformen ermöglichen

Country Status (7)

Country Link
US (1) US20020141948A1 (de)
EP (1) EP0956247B1 (de)
JP (1) JP2000509355A (de)
AU (1) AU5562698A (de)
DE (1) DE69707158T2 (de)
FR (1) FR2758983B1 (de)
WO (1) WO1998033725A1 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005018588A2 (de) * 2004-08-18 2005-03-03 Henkel Kommanditgesellschaft Auf Aktien Kompakthaarspray

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IN148848B (de) * 1977-03-02 1981-06-27 Abplanalp Robert H
FR2390951A1 (fr) * 1977-05-17 1978-12-15 Oreal Nouvelles compositions cosmetiques sous forme de laques aerosols pour fixer la chevelure
US5068099A (en) * 1990-01-16 1991-11-26 S. C. Johnson & Son, Inc. Hair spray package with low volatile organic compound emission
FR2658417B1 (fr) * 1990-02-16 1992-05-07 Oreal Laque aerosol capillaire contenant un tetrapolymere d'acide acrylique, de n,n-dimethylacrylamide, de n-tertiobutylacrylamide et de methacrylate d'ethyle et un gaz propulseur non halogene.
US5304368A (en) * 1993-02-19 1994-04-19 American Telecast Corporation Non-foaming, non-viscous, alcohol-free, water-based, pressurized hair spray product

Also Published As

Publication number Publication date
WO1998033725A1 (fr) 1998-08-06
JP2000509355A (ja) 2000-07-25
FR2758983B1 (fr) 1999-04-23
DE69707158T2 (de) 2002-02-28
AU5562698A (en) 1998-08-25
US20020141948A1 (en) 2002-10-03
DE69707158D1 (de) 2001-11-08
FR2758983A1 (fr) 1998-08-07
EP0956247A1 (de) 1999-11-17

Similar Documents

Publication Publication Date Title
FR2786391A1 (fr) Composition de coiffage comprenant un polymere aux caracteristiques particulieres et un polymere filmogene ionique
FR2733910A1 (fr) Composition sous forme de mousse aerosol a base de polyurethanne et de polymere anionique
FR3004902A1 (fr) Dispositif aerosol a diffusion a multi-orifices pour la mise en forme des cheveux et/ou le maintien de la coiffure
FR3063605A1 (fr) Dispositif aerosol pour la mise en forme des cheveux et/ou le maintien de la coiffure
EP0774248B1 (de) Zusammensetzung zur Behandlung von Keratinfasern, die mindestens ein fixierendes Polymer und mindestens eine Verbindung vom Ceramidtyp enthält, und Verfahren
EP0791351B1 (de) Zusammensetzung, die ein fixierendes Polymer, ein C5-C8-n-Alkan und Aceton enthält
EP1357887B1 (de) Kosmetische zusammensetzung, die ein fixierendes polymer und ein kationisches polyvinyllactam enthält
EP0956247B1 (de) Aerosolvorrichtung auf basis einer zusammensetzung von fixierstoffen, die ein klebefreies haarformen ermöglichen
EP1366751A1 (de) Aerosolvorrichtung mit zwei Kammern enthaltend eine wässrige Haarsformungszusammensetzung und Verfahren zur Haarformung
CA2221566C (fr) Dispositif aerosol a base de compositions alcooliques de materiaux fixants
EP1435226B1 (de) Aerosol-Sprühvorrichtung enthaltend ein wässriges haarfestigendes Mittel mit einem Copolymer auf Basis von N-Vinylpyrrolidon und N-Vinylimidazol
WO1999059532A1 (fr) Composition cosmetique comprenant au moins un ester de cellulose du type phtalate, acetophtalate ou acetotrimellitate de cellulose
EP2651372B2 (de) Aerosolvorrichtung mit zwei behältern welche eine (hydro)alkoholische haarstylingzusammenstzung enthält sowie methode zum haarstyling
EP1115367A1 (de) Kosmetisches mittel enhaltend mindestens eines polymer mit hydroxystyrol-einheiten
EP1488779A1 (de) Haarkosmetische Zusammensetzung die Tridecyl Trimellitat und ein fixierendes Polymer enthält.
FR2968541A1 (fr) Dispositif aerosol a deux compartiments comprenant une composition de coiffage, alcoolique ou hydroalcoolique, et procede de coiffage
FR3076210A1 (fr) Composition aerosol comprenant un polymere fixant et un materiau particulaire lamellaire, un procede et un dispositif
FR2968542A1 (fr) Dispositif aerosol a deux compartiments comprenant une composition de coiffage, alcoolique ou hydroalcoolique, et procede de coiffage
FR2968543A1 (fr) Dispositif aerosol a deux compartiments comprenant une composition de coiffage, alcoolique ou hydroalcoolique, et procede de coiffage

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19990831

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): DE ES FR GB IT

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

17Q First examination report despatched

Effective date: 20010423

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE ES FR GB IT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRE;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.SCRIBED TIME-LIMIT

Effective date: 20011004

REF Corresponds to:

Ref document number: 69707158

Country of ref document: DE

Date of ref document: 20011108

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20011219

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20020430

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20061207

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20061208

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20061213

Year of fee payment: 10

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20071215

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080701

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20081020

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071215

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20071231