EP0935695B1 - Papier pourvu d'une couche pour l'impression par jet d'encre - Google Patents

Papier pourvu d'une couche pour l'impression par jet d'encre Download PDF

Info

Publication number
EP0935695B1
EP0935695B1 EP97945864A EP97945864A EP0935695B1 EP 0935695 B1 EP0935695 B1 EP 0935695B1 EP 97945864 A EP97945864 A EP 97945864A EP 97945864 A EP97945864 A EP 97945864A EP 0935695 B1 EP0935695 B1 EP 0935695B1
Authority
EP
European Patent Office
Prior art keywords
weight
mixture
pigment
paper according
binder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97945864A
Other languages
German (de)
English (en)
Other versions
EP0935695A1 (fr
Inventor
Werner Bergmann
Hans-Jürgen Bucerius
Peter Pfeifer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi HiTec Paper Bielefeld GmbH
Original Assignee
Mitsubishi HiTec Paper Bielefeld GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi HiTec Paper Bielefeld GmbH filed Critical Mitsubishi HiTec Paper Bielefeld GmbH
Publication of EP0935695A1 publication Critical patent/EP0935695A1/fr
Application granted granted Critical
Publication of EP0935695B1 publication Critical patent/EP0935695B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/42—Coatings with pigments characterised by the pigments at least partly organic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Definitions

  • the invention relates to a paper with a applied to at least one of its sides Recording layer containing a Pigment mixture of organic and inorganic Pigment, binder and cationic auxiliary. Furthermore, the invention relates to a method for the production of the paper as well as the use.
  • Papers of the type specified above become Use as a print carrier for the so-called inkjet process (Inkjet printing process) used.
  • inkjet printing process Inkjet printing process
  • Hentzschel / Pelzer in the DE reference Weekly paper production 18 (1996): “Improving the printability of inkjet papers by polyvinyl alcohol and others Components ". Accordingly, between the surface glued papers for the usual Office use and high quality painted Papers, especially for color prints be used, differentiated.
  • Starch possibly cationic starch, is used, contain the coated papers in addition to pigment and binder a cationic additive.
  • DE-A-43 22 178 discloses as a binder Polyvinyl alcohol, polyvinyl pyrrolidone, Vinyl acetate homopolymer and / or vinyl acetate copolymer. One becomes a cationic substance quaternary ammonium compound indicated. As Amorphous silicas, clay and Zeolite revealed.
  • EP-A-0 514 633 describes a recording material for the inkjet process in which the recording layer contains polyvinyl alcohol, an amorphous silica with a large specific surface area, a particle size of 2 to 12 ⁇ m and a cationic polymer without crosslinking groups. Cationic polyamides, polyacrylamides or polyamines are disclosed as the cationic component. In addition to good print image quality, this known recording material is said to have improved light and water resistance.
  • EP-A-0 671 282 The production of a primarily transparent recording sheet - using a plastic film as a coating carrier - is described in EP-A-0 671 282.
  • Two layers are applied, of which the recording layer contains a hydrophilic binder and hollow spherical pigments or solid plastic particles as filler in the form of spheres with an average diameter of 0.1 to 50 ⁇ m .
  • further fillers can be added in an amount of up to 60% by weight, with colloidal silicates, titanium dioxide, calcium carbonate, aluminum hydroxide and bright white types of clay being proposed.
  • a coating color is known from DE-A-195 34 327
  • Manufacture of an inkjet paper known for Solution to the problem is using a coating color high pigment concentration and relative to provide low viscosity, so that a well covering line can be applied can, in short, the generation of a satisfactory typeface guaranteed.
  • preferred binders are copolymers of Styrene-butadiene or styrene-acrylate with functional cationic groups and / or cationic polyvinyl acetates
  • cationic Polyvinyl alcohol and their copolymers are disclosed.
  • starch, methyl cellulose, Hydroxymethyl cellulose, carboxymethyl cellulose, Alginates, proteins and polyvinyl alcohols, if necessary can also be used in cationic form.
  • pigments suitable according to that document almost all in the field of paper coating usual pigments, such as. B. like and natural calcium carbonate, precipitated or pyrogenic silica, kaolin, calcined kaolin, Talc, titanium dioxide, but also organic Pigments such as B. melamine-formaldehyde resin, disclosed. If possible, pigment mixtures are disclosed, these relate to the mixing of calcium carbonate / calcium silicate hydrate, fumed silica / calcium carbonate, precipitated Silicic acid / calcium carbonate, kaolin / titanium dioxide.
  • the mixture of binders made of polyvinyl alcohol and cationic starch Mixture of cationic starch and cationic Plastic binder or a mixture of cationic starch / polyvinyl alcohol and cationic plastic binder disclosed.
  • the specified proportion of binder is 10 to 30 % By weight, based on pigment.
  • Another time is an inkjet recording paper, that after one Cast coating process is produced in the EP-B-0 529 308.
  • This script comes from calcium carbonate and silicon dioxide composite pigment for use, which in an amount of at least 50% by weight, preferably at least 80% by weight in the recording layer is present.
  • Another object of the invention is Development of methods for applying the recording layer for the production of the invention Paper.
  • the existing task is accomplished by the invention a paper with at least one of his Sides of the recording layer applied, which is a pigment mixture of organic and inorganic Pigment, binder and cationic auxiliary contains, the recording layer is characterized in that the pigment mixture - based on 100% by weight of total pigment mixture - 10 to 30% by weight of an organic amide resin Contains pigment and 40 to 90 wt.% Talc and that Binder a mixture of starch ether and Contains polyvinyl alcohol.
  • the organic pigment preferably consists of Melamine-formaldehyde resin, urea-formaldehyde resin or a mixture of these organic pigments.
  • the organic pigment has an internal pore volume of 1.5 to 4.5 cm 3 / g.
  • a proportion of binder in the Range from 35 to 70% by weight based on 100 parts by weight Total pigment mixture, proven.
  • binder mixture calculated as Dry weight parts - from 12 to 25 parts by weight Polyvinyl alcohol and 88 to 75 parts by weight Starch ether.
  • the binder mixture in addition Starch ether and polyvinyl alcohol as others Component one or more latices contain.
  • the latex portion should however less than 12% by weight, based on the Binder mixture.
  • An application weight of the recording layer in the range from 10 to 30 g / m 2 and side has proven to be particularly suitable; in particular an application weight of 18 to 24 g / m 2 and side is preferred.
  • Quaternary agents come as cationic aids Ammonium compounds into consideration, preferably Polydiallyldimethylammonium chloride (Polydadmac) and dimethyldistearylammonium chloride and Benzyldimethylstearylammonium chloride. Furthermore has quaternized polymethacrylate resin as proven suitable as it is called Polycat L 452 from the company CTP paper auxiliaries GmbH & Co. KG in Bobingen, Germany, will be produced. Suitable amounts are used in the range of 2 to 18 parts by weight / 100 parts by weight Pigment mixture (preferably 2 to 7 parts by weight).
  • an aid for crosslinking the binder mixture.
  • An addition of 0.1 to 3.5 has proven suitable % (Otro), based on pigment, proven.
  • Ammonium zirconium carbonate is preferred and / or an epoxy resin is used.
  • a suitable one Epoxy resin is specified in WO 95/05505.
  • base paper for the order of Recording layer in particular comes full bulk glued base paper is used, in particular such a base paper that additionally a surface sizing, especially from starch in combination with a synthetic surface sizing agents, e.g. B. an acrylic styrene dispersion.
  • a surface sizing especially from starch in combination with a synthetic surface sizing agents, e.g. B. an acrylic styrene dispersion.
  • the process of producing the paper according to the invention has proven to be particularly suitable for the cast coating process, in particular a cast coating process in which an aqueous coating color is applied to the paper web, leveled and contacted with a heated high-gloss cylinder with simultaneous drying to form the recording layer.
  • the aqueous coating slip preferably contains a pigment mixture which, based on 100% by weight of the total pigment mixture, contains 10 to 30% by weight of organic pigment consisting of amide resin and 40 to 90% by weight of talc and also a binder which comprises a mixture of starch ether and Contains polyvinyl alcohol.
  • the production of the paper according to the invention is, however, not tied to the casting process described above; rather, the production can also be carried out by the re-wet method or the coagulation process.
  • the coating color according to the invention with the specified pigment and binder mixture can also be applied to a paper web, leveled by means of a knife coating device or a doctor blade, and then dried and calendered.
  • the coating color for producing the recording layer can also contain other auxiliary agents such as optical brighteners, shading dye, dispersing and wetting agents, thickening aids and, in the case of production by the casting process, still releasing agents such as the stearates of Contain sodium and calcium and / or suitable oils. Defoamers and agents for regulating the pH can also be present. Overall, it is preferred that the auxiliaries be present in the coating in an amount of no more than 4 to 7 parts by weight, based on 100 parts by weight of total solid.
  • the starch ethers known from WO 95/05505 can be used in the context of the present invention. Low-viscosity types with a high degree of hydrolysis are preferably used as polyvinyl alcohol.
  • film press is one Understand device in which the coating color first applied to transfer rollers and equalized there and the pre-dosed coating color then from the transfer rollers to the is applied to both sides of the paper web.
  • the Predosing / leveling of the coating color can thereby both of knife coaters, of rotating squeegees or rotating Dosing rollers are made.
  • the paper according to the invention is used preferably for printing in an inkjet printer, especially in a multi-color inkjet printer.
  • An aqueous slurry of 78 parts by weight of talc and 22 parts by weight of a urea-formaldehyde pigment with a specific surface area of 20 m 2 / g and an internal pore volume of 2.6 cm 3 / g is made using 17 parts by weight.
  • Parts of a 20% Polydadmac solution are dispersed and then 127 parts by weight of a 24% solution of a hydroxypropyl starch ether with a degree of substitution of 0.07 and 45 parts by weight of a 20% solution of a low-viscosity polyvinyl alcohol with a high degree of hydrolysis are added.
  • the coating color has after setting to a pH of 8.1 a solids content of 39% by weight.
  • aqueous pigment slurry consisting of 81 parts by weight of talc and 19 parts by weight of a urea-formaldehyde pigment. About this slurry become 17.3 parts by weight of a 20% Polydadmac solution added.
  • a binder 131 parts by weight of those given in Example 1
  • 19 parts by weight are used as the release agent a 35% calcium stearate and further 17 parts by weight of a 15% solution of optical brightener and shading dye.
  • 21 parts by weight of a 20 % solution of quaternized polymethacrylate resin added.
  • the finished coating color is on a solids content of 44.3% by weight and a pH set from 7.8.
  • Example 1 or 2 With the coating color specified in Example 1 or 2, a coating base paper with a basis weight of 55 g / m 2 , which is fully glued in the mass and is provided with a surface preparation of starch, is coated on one side on a cast coating machine.
  • the application weight is 25 g / m 2 .
  • the cast coating method used is the so-called direct method, in which the coating color is applied to the paper and the wet coating color is pressed against a heated high-gloss cylinder. A very smooth surface is achieved.
  • the recording papers produced can be printed excellently in multicolor printing using the inkjet printing process.

Landscapes

  • Paper (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Claims (15)

  1. Papier portant sur au moins une de ses faces une couche d'enregistrement contenant un mélange de pigments organiques et minéraux, des liants et des adjuvants cationiques, caractérisé par le fait que le mélange de pigments contient - rapporté à 100 % en poids du mélange de pigments total - de 10 à 30 % en poids d'un pigment organique à base de résine amide et de 40 à 90 % en poids de talc, et par le fait que le liant contient un mélange d'éther d'amidon et de poly(alcool vinylique).
  2. Papier selon la revendication 1, caractérisé par le fait que le pigment organique est constitué de résine mélamine-formaldéhyde, de résine urée-formaldéhyde ou d'un mélange de ces pigments organiques.
  3. Papier selon une des revendications 1 et 2, caractérisé par le fait que le pigment organique présente un volume poreux interne compris entre 1,5 et 4,5 cm3/g.
  4. Papier selon une des revendications 1 et 3, caractérisé par le fait que la couche d'enregistrement contient comme pigment minéral supplémentaire du carbonate de calcium précipité ou finement broyé, du dioxyde de titane, de l'argile calcinée, de l'oxyde d'aluminium, de l'hydroxyde d'aluminium, de la bentonite modifiée ou un mélange de ces pigments, en une quantité n'excédant pas 50 % en poids - rapporté au mélange de pigments total.
  5. Papier selon une des revendications 1 et 4, caractérisé par le fait que la couche d'enregistrement contient de 35 à 70 % en poids de liant, rapporté à 100 parties en poids du mélange de pigments total.
  6. Papier selon une des revendications 1 et 5, caractérisé en ce que la couche d'enregistrement contient un agent de réticulation du liant.
  7. Papier selon une des revendications 1 et 6, caractérisé par le fait que l'agent de réticulation est présent dans la couche d'enregistrement à raison de 0,1 à 5 % en poids, rapporté au pigment.
  8. Papier selon une des revendications 1 et 7, caractérisé par le fait que l'agent de réticulation est choisi dans le groupe formé par le carbonate d'ammonium-zirconium et des résines époxy.
  9. Papier selon une des revendications 1 à 8, caractérisé par le fait que la couche d'enregistrement est appliquée à raison de 10 à 30 g/m2/face.
  10. Procédé de fabrication d'un papier selon une des revendications 1 à 9, caractérisé par le fait que l'on applique la couche d'enregistrement contenant un mélange de pigments contenant - rapporté à 100 % en poids du mélange de pigments total - de 10 à 30 % en poids d'un pigment organique à base de résine amide et de 40 à 90 % en poids de talc, ainsi qu'un liant contenant un mélange d'éther d'amidon et de poly(alcool vinylique), selon une technique de couchage à haut brillant.
  11. Procédé de fabrication d'un papier selon la revendication 10, caractérisé par le fait que l'on applique une composition aqueuse de couchage contenant un mélange de pigments contenant - rapporté à 100 % en poids du mélange de pigments total - de 10 à 30 % en poids d'un pigment organique à base de résine amide et de 40 à 90 % en poids de talc, ainsi qu'un liant contenant un mélange d'éther d'amidon et de poly(alcool vinylique), sur une bande de papier afin de former la couche d'enregistrement, que l'on égalise et que l'on met la couche en contact avec un cylindre chauffé, à haut brillant tout en la séchant.
  12. Procédé, de fabrication d'un papier selon l'une des revendication 1 à 9, caractérisé par le fait que l'on applique sur une bande de papier une composition de couchage aqueuse contenant un mélange de pigments contenant - rapporté à 100 % en poids du mélange de pigments total - de 10 à 30 % en poids d'un pigment organique à base de résine amide et de 40 à 90 % en poids de talc, ainsi qu'un liant contenant un mélange d'éther d'amidon et de poly(alcool vinylique), que l'on égalise le dépôt à l'aide d'un dispositif de couchage à couteau ou d'une raclette rotative, que l'on sèche et que l'on réalise ensuite un calandrage.
  13. Procédé de fabrication d'un papier selon une des revendications 1 à 9, caractérisé par le fait que l'on applique sur une bande de papier au moyen d'une presse à films, une composition de couchage aqueuse contenant un mélange de pigments contenant - rapporté à 100 % en poids du mélange de pigments total - de 10 à 30 % en poids d'un pigment organique à base de résine amide et de 40 à 90 % en poids de talc, ainsi qu'un liant contenant un mélange d'éther d'amidon et de poly(alcool vinylique).
  14. Utilisation d'un papier selon une des revendications 1 à 9 dans une imprimante à jet d'encre.
  15. Utilisation d'un papier selon une des revendications 1 à 9 dans une imprimante couleur à jet d'encre.
EP97945864A 1996-10-31 1997-10-22 Papier pourvu d'une couche pour l'impression par jet d'encre Expired - Lifetime EP0935695B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19644014 1996-10-31
DE19644014A DE19644014C2 (de) 1996-10-31 1996-10-31 Papier mit Aufzeichnungsschicht und Verfahren zu seiner Herstellung
PCT/EP1997/005818 WO1998019011A1 (fr) 1996-10-31 1997-10-22 Papier pourvu d'une couche pour l'impression par jet d'encre

Publications (2)

Publication Number Publication Date
EP0935695A1 EP0935695A1 (fr) 1999-08-18
EP0935695B1 true EP0935695B1 (fr) 2001-10-10

Family

ID=7809736

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97945864A Expired - Lifetime EP0935695B1 (fr) 1996-10-31 1997-10-22 Papier pourvu d'une couche pour l'impression par jet d'encre

Country Status (5)

Country Link
EP (1) EP0935695B1 (fr)
AT (1) ATE206783T1 (fr)
DE (2) DE19644014C2 (fr)
ES (1) ES2162329T3 (fr)
WO (1) WO1998019011A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19745935C2 (de) * 1997-10-17 2001-12-13 Mitsubishi Hitec Paper Bielefe Papier mit Tintenstrahlaufzeichnungsschicht
DE10054219C2 (de) 2000-11-01 2003-04-24 Mitsubishi Hitec Paper Flensbu Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4064304A (en) * 1973-06-18 1977-12-20 Kanzaki Paper Manufacturing Company, Ltd. Coated synthetic paper adapted for offset printing and method for production thereof
ES437298A1 (es) * 1974-06-10 1977-04-01 Dow Chemical Co Un metodo para preparar un latex.
NL190611C (nl) * 1979-12-21 1994-05-16 Hercules Inc Entcopolymeer in deeltjesvorm en werkwijze voor het bereiden van papier waarbij een dergelijk entcopolymeer wordt toegepast.
JPH0214098A (ja) * 1988-06-29 1990-01-18 Kanzaki Paper Mfg Co Ltd 光沢塗被紙の製造方法
JPH081038B2 (ja) * 1991-08-27 1996-01-10 日本製紙株式会社 インクジェット記録用紙
JPH06234268A (ja) * 1992-12-16 1994-08-23 Mitsubishi Paper Mills Ltd インクジェット記録シート
US5670242A (en) * 1993-06-15 1997-09-23 Canon Kabushiki Kaisha Cast coated paper for ink jet recording
DE4327366C1 (de) * 1993-08-14 1995-01-05 Feldmuehle Ag Stora Papier oder Karton mit einer im Gußstreichverfahren aufgebrachten Beschichtung, Verfahren zur Herstellung und Verwendung
JPH07290818A (ja) * 1994-03-04 1995-11-07 Mitsubishi Paper Mills Ltd インクジェット記録用タックシート
DE19500195A1 (de) * 1995-01-05 1996-07-11 Bayer Ag Verwendung weißgetönter Kunststoffe zum Weißtönen von Papierstreichmassen und derart weißgetönte Papierstreichmassen
DE19534327A1 (de) * 1995-09-15 1996-02-22 Md Papier Gmbh Streichfarbe für Tintenstrahlpapier

Also Published As

Publication number Publication date
DE59704892D1 (de) 2001-11-15
WO1998019011A1 (fr) 1998-05-07
ATE206783T1 (de) 2001-10-15
DE19644014A1 (de) 1998-05-07
EP0935695A1 (fr) 1999-08-18
ES2162329T3 (es) 2001-12-16
DE19644014C2 (de) 1999-07-22

Similar Documents

Publication Publication Date Title
DE4330428C2 (de) Tintenstrahlaufzeichnungsblatt
DE69208773T2 (de) Durch Tintenstrahlverfahren bedrucktes Papier
DE69315135T2 (de) Papier für Tintenstrahldruck und Verfahren zur Herstellung
DE69117884T2 (de) Beschichtete Aufzeichnungsfolie
DE69413179T2 (de) Tintenstrahl-aufzeichnungsblatt
DE69202766T2 (de) Aufzeichnungsblatt für Tintenstrahlschreiber.
DE69604179T2 (de) Farbstoffempfangsschicht für tintenstrahldruck
DE69804558T2 (de) Tintenstrahlaufzeichnungsmaterial, das UV-Absorbierungsmittel enthält
DE19505295C2 (de) Tintenstrahl-Aufzeichnungsblatt
DE69700580T2 (de) Tintenstrahlaufzeichnungsblatt mit einer hochglänzenden Schicht
DE69708999T2 (de) Aufzeichnungsmaterial für den Tintenstrahldruck
CN102470682B (zh) 用于高速数字喷墨印刷的印刷介质及其制造方法
DE112010002826T5 (de) BESCHICHTETES DRUCKPAPiER
DE69912339T2 (de) Aufzeichnungsmedium und Tintenstrahlaufzeichnungsverfahren damit
DE3237381A1 (de) Ink-jet-aufzeichnungsblatt
DE69923114T2 (de) Tintenstrahlaufzeichnungsmaterial, das kationisches Harz enthält, und Aufzeichnungsverfahren
DE69712421T2 (de) Mattgestrichenes papier und verfahren zu siener herstellung
DE60107725T3 (de) Für eine pigmenthaltige Tinte geeignetes Tintenstrahlaufzeichnungsmaterial
EP3323624B1 (fr) Matériau de transfert adhésif microporeux
EP3098085A1 (fr) Matériau de transfert pour l'impression par sublimation
DE69717326T2 (de) Tintenstrahlaufzeichnungsschicht und Tintenstrahlaufzeichnungsverfahren
EP0387893B1 (fr) Papier d'enregistrement par jet d'encre
DE3832112C2 (de) Aufzeichnungspapier für Tintenstrahldrucker
DE69805470T2 (de) Aufzeichnungsmaterial für mehrfarbiges Tintenstrahldruckverfahren mit wässerigen Tinten
EP0790135A2 (fr) Méthode pour la fabrication d'un support pour l'impression utilisé pour l'impression par jet d'encre sans contact, papier fabriqué par ce procédé et son utilisation

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19990316

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE DE ES FR GB IT

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: MITSUBISHI HITEC PAPER BIELEFELD GMBH

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

17Q First examination report despatched

Effective date: 20001010

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

ITF It: translation for a ep patent filed
GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE DE ES FR GB IT

REF Corresponds to:

Ref document number: 206783

Country of ref document: AT

Date of ref document: 20011015

Kind code of ref document: T

REF Corresponds to:

Ref document number: 59704892

Country of ref document: DE

Date of ref document: 20011115

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2162329

Country of ref document: ES

Kind code of ref document: T3

ET Fr: translation filed
REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20020114

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20030922

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20031022

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20031028

Year of fee payment: 7

Ref country code: AT

Payment date: 20031028

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20041022

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20041022

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20041031

BERE Be: lapsed

Owner name: *MITSUBISHI HITEC PAPER BIELEFELD G.M.B.H.

Effective date: 20041031

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20041022

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050630

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

BERE Be: lapsed

Owner name: *MITSUBISHI HITEC PAPER BIELEFELD G.M.B.H.

Effective date: 20041031

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20081015

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20081022

Year of fee payment: 12

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20091022

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20110405

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110323

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20091023

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20161101

Year of fee payment: 20

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 59704892

Country of ref document: DE