EP0931128B1 - Verwendung von schmiermittel auf basis von polyolen beim schneiden von elastomeren - Google Patents

Verwendung von schmiermittel auf basis von polyolen beim schneiden von elastomeren Download PDF

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Publication number
EP0931128B1
EP0931128B1 EP97943878A EP97943878A EP0931128B1 EP 0931128 B1 EP0931128 B1 EP 0931128B1 EP 97943878 A EP97943878 A EP 97943878A EP 97943878 A EP97943878 A EP 97943878A EP 0931128 B1 EP0931128 B1 EP 0931128B1
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EP
European Patent Office
Prior art keywords
cutting
lubricant
cut
adhesive
polyol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97943878A
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German (de)
English (en)
French (fr)
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EP0931128A1 (de
Inventor
Horst Beck
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Henkel Teroson GmbH
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Henkel Teroson GmbH
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/30Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/32Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
    • C10M107/34Polyoxyalkylenes
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24Polyethers
    • C10M145/26Polyoxyalkylenes
    • C10M145/28Polyoxyalkylenes of alkylene oxides containing 2 carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24Polyethers
    • C10M145/26Polyoxyalkylenes
    • C10M145/30Polyoxyalkylenes of alkylene oxides containing 3 carbon atoms only
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24Polyethers
    • C10M145/26Polyoxyalkylenes
    • C10M145/34Polyoxyalkylenes of two or more specified different types
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/40Polysaccharides, e.g. cellulose
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/1033Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C10M2209/1045Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only used as base material
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/105Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
    • C10M2209/1055Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only used as base material
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/106Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only
    • C10M2209/1065Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/107Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/107Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106
    • C10M2209/1075Polyethers, i.e. containing di- or higher polyoxyalkylene groups of two or more specified different alkylene oxides covered by groups C10M2209/104 - C10M2209/106 used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C10M2209/1085Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/109Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
    • C10M2209/1095Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12Polysaccharides, e.g. cellulose, biopolymers
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/30Refrigerators lubricants or compressors lubricants
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/32Wires, ropes or cables lubricants
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/34Lubricating-sealants
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/36Release agents or mold release agents
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/38Conveyors or chain belts
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/40Generators or electric motors in oil or gas winning field
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/42Flashing oils or marking oils
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/44Super vacuum or supercritical use
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/50Medical uses
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01Emulsions, colloids, or micelles

Definitions

  • the present invention relates to the use of a lubricant based on water Solutions and / or emulsions of polyether polyols when cutting of cured elastomers.
  • US-A-5,476,411 discloses a composition containing glycerin, Polyethylene glycols and alkyl polyglycoside and their use as a liquid auxiliary for wet grinding processes. According to the teaching of this document, those disclosed there are suitable Compositions for wet grinding of plastics and / or dried or cross-linked coatings of varnishes to achieve a smooth surface. additionally these compositions still contain finely divided abrasive particles, which in the Liquid are suspended. It is also proposed that this Compositions in water can be rinsed off the treated surface or should before further finish treatments can be carried out.
  • US-A-4128452 describes a knife for separating adhesively bonded Materials, especially self-adhesive labels.
  • This knife has the Blade in a scabbard that has an inner lining made of absorbent material contains.
  • a lubricant such as Silicone oil is even on the absorbent material of the vagina distributed.
  • a thin layer of lubricant will be on all Spread surfaces of the blade. This enables an almost smooth contact between the blade and the material to be separated. Thereby the Lubricant prevent the stickiness of the cut adhesive.
  • the object was therefore to provide a lubricant and coolant which makes it possible to cut elastomers without developing a lot of frictional heat, the cut surfaces produced in this way being intended to remain suitable for a renewed bonding process of the elastomer parts.
  • This is of particular importance in the case of repair of directly bonded car windows, since a so-called "residual bead", ie an adhesive layer of different thickness, remains on the car body when replacing car windows that have become defective.
  • the adhesive for a pane to be newly glued is then applied directly to this cut surface, or the cut surface serves as a contact surface for the adhesive applied to the newly inserted pane.
  • a bonded car window in particular the windshield and rear window, is an integral part of the strength and rigidity of a car body
  • Polyether polyols based on linear or branched are particularly preferred Polyethylene glycols, polypropylene glycols or their copolymers.
  • the molecular weight or the OH number and the viscosity of the polyetherols can vary widely Limits vary. Preferred ranges for the OH number are 500 to 15 mg KOH / g, whole OH numbers of 50 to 20 mg KOH / g are particularly preferred.
  • the viscosity of such Polyether polyols at 25 ° C are between 500 mPa.s and 3000 mPa.s.
  • the determination the OH number is according to DIN 53240, the viscosity according to DIN 51550.
  • a lubricant concentrate was produced from the following constituents: 29% by weight polyether polyol (Lupranol 2040 from BASF, hydroxyl number approx. 28 mg KOH / g), 0.8% by weight alkyl polyglycoside from Henkel, 0.2% by weight % Acticid SPX, from Thorchemie, 70% by weight demineralized water.
  • the polyol and the surfactant were introduced and water was slowly added with a dissolver while stirring vigorously. It is particularly important to achieve particularly intensive mixing in the highly viscous phase so that a stable emulsion with finely dispersed polyol droplets is created.
  • the lubricant was used according to Example 1 for the actual Application 1:15 diluted with water and this liquid on the adhesive bead one glazed car windscreen sprayed.
  • the cured bead of adhesive was able to can be cut using a commercially available vibration knife without generating heat.
  • the accessible, perpendicular to the cut surface were Surfaces of the cured adhesive bead on the one hand with the lubricant / coolant according to the invention sprayed and for comparison a according to the Tool manufacturer made solution of a baby shampoo with water on the Glue bead sprayed and the test specimens cut accordingly.
  • a according to the Tool manufacturer made solution of a baby shampoo with water on the Glue bead sprayed and the test specimens cut accordingly.
  • new glass strips were taken, which were pre-cleaned with the primer Terostat 8510 from Teroson were pretreated.
  • An appropriate amount of Terostat 8597 was applied to the primer surface.
  • the sheet metal strips from the cutting tests on which the no further pretreated residual bead was used to simulate re-bonding, see above that again an adhesive joint with 5mm layer thickness was created.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
EP97943878A 1996-10-01 1997-09-22 Verwendung von schmiermittel auf basis von polyolen beim schneiden von elastomeren Expired - Lifetime EP0931128B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19640489 1996-10-01
DE19640489A DE19640489A1 (de) 1996-10-01 1996-10-01 Schmiermittel auf Basis von Polyolen und dessen Verwendung beim Schneiden von Elastomeren
PCT/EP1997/005185 WO1998014539A1 (de) 1996-10-01 1997-09-22 Schmiermittel auf basis von polyolen und dessen verwendung beim schneiden von elastomeren

Publications (2)

Publication Number Publication Date
EP0931128A1 EP0931128A1 (de) 1999-07-28
EP0931128B1 true EP0931128B1 (de) 2003-05-28

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EP97943878A Expired - Lifetime EP0931128B1 (de) 1996-10-01 1997-09-22 Verwendung von schmiermittel auf basis von polyolen beim schneiden von elastomeren

Country Status (14)

Country Link
EP (1) EP0931128B1 (ko)
JP (1) JP2001503084A (ko)
KR (1) KR20000048565A (ko)
AT (1) ATE241686T1 (ko)
AU (1) AU719234B2 (ko)
CA (1) CA2267865A1 (ko)
CZ (1) CZ115199A3 (ko)
DE (2) DE19640489A1 (ko)
HU (1) HUP0000048A3 (ko)
NZ (1) NZ334964A (ko)
PL (1) PL332505A1 (ko)
TR (1) TR199900583T2 (ko)
WO (1) WO1998014539A1 (ko)
ZA (1) ZA978763B (ko)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6347292B1 (en) 1999-02-17 2002-02-12 Den-Con Electronics, Inc. Oilfield equipment identification method and apparatus
DE10053940C2 (de) * 2000-10-27 2003-02-06 Friedrich Huber Aeronova Gmbh Verfahren zur Entfernung von Polymeren auf Polyurethanbasis von Oberflächen
DE102007033430A1 (de) * 2007-07-18 2009-01-22 Evonik Goldschmidt Gmbh Siliconfreies Schneidöl und seine Verwendung
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JP2001503084A (ja) 2001-03-06
HUP0000048A3 (en) 2001-05-28
PL332505A1 (en) 1999-09-13
ATE241686T1 (de) 2003-06-15
ZA978763B (en) 1998-04-01
AU719234B2 (en) 2000-05-04
NZ334964A (en) 2001-04-27
TR199900583T2 (xx) 1999-07-21
EP0931128A1 (de) 1999-07-28
CA2267865A1 (en) 1998-04-09
DE19640489A1 (de) 1998-04-09
DE59710181D1 (de) 2003-07-03
AU4556097A (en) 1998-04-24
WO1998014539A1 (de) 1998-04-09
CZ115199A3 (cs) 1999-11-17
HUP0000048A2 (hu) 2000-05-28
KR20000048565A (ko) 2000-07-25

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