EP0858662A2 - Lower-energy hydrogen methods and structures - Google Patents

Lower-energy hydrogen methods and structures

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Publication number
EP0858662A2
EP0858662A2 EP96919010A EP96919010A EP0858662A2 EP 0858662 A2 EP0858662 A2 EP 0858662A2 EP 96919010 A EP96919010 A EP 96919010A EP 96919010 A EP96919010 A EP 96919010A EP 0858662 A2 EP0858662 A2 EP 0858662A2
Authority
EP
European Patent Office
Prior art keywords
energy
hydrogen
hydrogen atoms
cell according
atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP96919010A
Other languages
German (de)
French (fr)
Other versions
EP0858662A4 (en
Inventor
Randell L. Mills
William R. Good
Arthur I. Popov
Jonathan Phillips
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Brilliant Light Power Inc
Original Assignee
BlackLight Power Inc
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Filing date
Publication date
Application filed by BlackLight Power Inc filed Critical BlackLight Power Inc
Publication of EP0858662A2 publication Critical patent/EP0858662A2/en
Publication of EP0858662A4 publication Critical patent/EP0858662A4/en
Withdrawn legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21B—FUSION REACTORS
    • G21B3/00—Low temperature nuclear fusion reactors, e.g. alleged cold fusion reactors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02G—HOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G1/00—Hot gas positive-displacement engine plants
    • F02G1/04—Hot gas positive-displacement engine plants of closed-cycle type
    • F02G1/043—Hot gas positive-displacement engine plants of closed-cycle type the engine being operated by expansion and contraction of a mass of working gas which is heated and cooled in one of a plurality of constantly communicating expansible chambers, e.g. Stirling cycle type engines
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02G—HOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G2243/00—Stirling type engines having closed regenerative thermodynamic cycles with flow controlled by volume changes
    • F02G2243/30—Stirling type engines having closed regenerative thermodynamic cycles with flow controlled by volume changes having their pistons and displacers each in separate cylinders
    • F02G2243/50—Stirling type engines having closed regenerative thermodynamic cycles with flow controlled by volume changes having their pistons and displacers each in separate cylinders having resonance tubes
    • F02G2243/52—Stirling type engines having closed regenerative thermodynamic cycles with flow controlled by volume changes having their pistons and displacers each in separate cylinders having resonance tubes acoustic
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02G—HOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
    • F02G2254/00—Heat inputs
    • F02G2254/10—Heat inputs by burners
    • F02G2254/11—Catalytic burners
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00—Energy generation of nuclear origin
    • Y02E30/10—Nuclear fusion reactors

Definitions

  • This invention relates to methods and apparatus for releasing energy from hydrogen atoms (molecules) as their electrons are stimulated to relax to lower energy levels and smaller radii (smaller semimajor and semiminor axes) than the "ground state" by providing a transition catalyst which acts as an energy sink or means to remove energy resonant with the electronic energy released to stimulate these transitions according to a novel atomic model.
  • the transition catalyst should not be consumed in the reaction. It accepts energy from hydrogen and releases the energy to the surroundings. Thus, the transition catalyst returns to the origin state. Processes that require collisions are common.
  • the exothermic chemical reaction of H + H to form H 2 requires a collision with a third body, , to remove the bond energy - H + H + ⁇ ⁇ H 2 + .
  • the third body distributes the energy from the exothermic reaction, and the end result is the H 2 molecule and an increase in the temperature of the system.
  • the electron(s) couples to another electron transition or electron transfer reaction, for example, which can absorb the exact amount of energy that must be removed from the hydrogen atom (molecule), a resonant energy sink.
  • the end result is a lower-energy state for the hydrogen and increase in temperature of the system.
  • each transition is hereafter referred to as a shrinkage transition: each energy sink or means to remove energy resonant with the hydrogen electronic energy released to effect each transition is hereafter referred to as an energy hole, and the electronic energy removed by the energy hole to effect or stimulate the shrinkage transition is hereafter referred to as the resonance shrinkage energy.
  • An energy hole comprising a reactant ion that is spontaneously regenerated following an endothermic electron ionization reaction of energy equal to the resonance shrinkage energy is hereafter referred to as an electrocatalvtic ion.
  • An energy hole comprising two reactants that are spontaneously regenerated following the an endothermic electron transfer reaction between the two species wherein the differences in their ionization energies is equal to the resonance shrinkage energy is hereafter referred to as an electrocatalvtic couple.
  • the present invention of an electrolytic cell energy reactor, pressurized gas energy reactor, and a gas discharge energy reactor comprises: a source of hydrogen; one of a solid, molten, liquid, and gaseous source of energy holes; a vessel containing hydrogen and the source of energy holes wherein the shrinkage reaction occurs by contact of the hydrogen with the source of energy holes; and a means for removing the (molecular) lower-energy hydrogen so as to prevent an exothermic shrinkage reaction from coming to equilibrium.
  • the present invention further comprises methods and structures for repeating this shrinkage reaction to produce shrunken atoms (molecules) to provide new materials with novel properties such as high thermal stability.
  • the present invention comprises methods and apparatuses for releasing heat energy from hydrogen atoms (molecules) by stimulating their electrons to relax to quantized potential energy levels below that of the "ground state” via electron transfer reactions of reactants including electrochemical reactant(s) (electrocatalvtic ion(s) or couple(s)) which remove energy from the hydrogen atoms (molecules) to stimulate these transitions.
  • this application includes methods and apparatuses to enhance the power output by enhancing the reaction rate- the rate of the formation of the lower-energy hydrogen.
  • the present invention further comprises a hydrogen spillover catalyst, a multifunctionality material having a functionality which dissociates molecular hydrogen to provide free hydrogen atoms which spill over to a functionality which supports mobile free hydrogen atoms and a functionality which can be a source of the energy holes.
  • the energy reactor includes one of an electrolytic cell, a pressurized hydrogen gas cell, and a hydrogen gas discharge cell.
  • a preferred pressurized hydrogen gas energy reactor comprises a vessel; a source of hydrogen; a means to control the pressure and flow of hydrogen into the vessel; a material to dissociate the molecular hydrogen into atomic hydrogen, and a material which can be a source of energy holes in the gas phase.
  • the gaseous source of energy holes includes those that sublime, boil, and/or are volatile at the elevated operating temperature of the gas energy reactor wherein the shrinkage reaction occurs in the gas phase.
  • the present invention further comprises methods and apparatuses for repeating a shrinkage reaction according to the present invention to cause energy release and to provide shrunken atoms and molecules with novel properties such as high thermal stability, and low reactivity.
  • the lower-energy state atoms and molecules are useful for heat transfer, cryogenic applications, as a buoyant gas. as a medium in an engine such as a Sterling engine or a turbine, as a general replacement for helium, and as a refrigerant by absorbing energy including heat energy as the electrons are excited back to a higher energy level.
  • a H is the Bohr radius for the hydrogen atom (52.947 pm )
  • e is the magnitude of the charge of the electron
  • ⁇ makeup is the vacuum permittivity. Mills' theory predicts that Eq. (2b), should be replaced by Eq. (2c).
  • the third body distributes the energy from the exothermic reaction, and the end result is the H 2 molecule and an increase in the temperature of the system.
  • the electron couples to another electron transition or electron transfer reaction which can absorb the exact amount of energy that must be removed from the hydrogen atom, a resonant energy sink called an energy hole.
  • the end result is a lower-energy state for the hydrogen and increase in temperature of the system .
  • Mills Wave Equation Solutions of the Hydrogen Atom Recently, Mills [Mills, R., The Grand Unified Theory of Classical Quantum Mechanics. ( 1995), Technomic Publishing Company, Lancaster, PA] has built on the work generally known as quantum mechanics by deriving a new atomic theory based on first principles.
  • the novel theory hereafter referred to as Mills' theory unifies Maxwell's Equations, Newton's Laws, and Einstein's General and Special Relativity.
  • the central feature of this theory is that all particles (atomic- size and macroscopic particles) obey the same physical laws.
  • the current-density function must not possess space-time Fourier components that are synchronous with waves traveling at the speed of light.
  • an electron is a spinning, two-dimensional spherical surface, hereafter called an electron orbitsphere. that can exist in a bound state at only specified distances from the nucleus. More explicitly, the orbitsphere comprises a two dimensional spherical shell of moving charge.
  • the corresponding current pattern of the orbitsphere comprises an infinite series of correlated orthogonal great circle current loops. The current pattern (shown in Figure 1.4 of Mills [Mills.
  • the total function that describes the spinning motion of each electron orbitsphere is composed of two functions.
  • One function, the spin function is spatially uniform over the orbitsphere, spins with a quantized angular velocity, and gives rise to spin angular momentum.
  • the other function, the modulation function can be spatially uniform — in which case there is no orbital angular momentum and the magnetic moment of the electron orbitsphere is one Bohr magneton — or not spatially uniform — in which case there is orbital angular momentum.
  • the modulation function also rotates with a quantized angular velocity. Numerical values for the angular velocity, radii of allowed orbitspheres. energies, and associated quantities are calculated by Mills.
  • Orbitsphere radii are calculated by setting the centripetal force equal to the electric and magnetic forces.
  • the orbitsphere is a resonator cavity which traps photons of discrete frequencies.
  • the radius of an orbitsphere increases with the absorption of electromagnetic energy.
  • the solutions to Maxwell's equations for modes that can be excited in the orbitsphere resonator cavity give rise to four quantum numbers, and the energies of the modes are the experimentally known hydrogen spectrum.
  • Excited states are unstable because the charge-density function of the electron plus photon have a radial doublet function component which corresponds to an electric dipole.
  • the doublet possesses spacetime Fourier components synchronous with waves traveling at the speed of light; thus it is radiative.
  • the delta function does not possess spacetime Fourier components synchronous with waves traveling at the speed of light; thus, each is nonradiative.
  • n The nonradiative boundary condition of Mills and the relationship between the electron and the photon give the "allowed" hydrogen energy states which are quantized as a function of the parameter n.
  • Each value of n corresponds to an allowed transition effected by a resonant photon which excites the electronic transition.
  • values of fractions are allowed which correspond to transitions with an increase in the central field (charge) and decrease in the size of the hydrogen atom. This occurs, for example, when the electron couples to another electronic transition or electron transfer reaction which can absorb energy, an energy sink. This is the absorption of an energy hole. The absorption of an energy hole destroys the balance between the centrifugal force and the increased central electric force. As a result, the electron undergoes a transition to a lower energy nonradiative state.
  • the radius of the orbitsphere, agro shrinks to — — and after p cycles of resonant + 1 shrinkage, the radius is — tL — .
  • the radial ground state field can be mp + 1 considered as the superposition of Fourier components.
  • the removal of negative Fourier components of energy m X 27.2 eV, where rn is an integer increases the positive central electric field inside the spherical shell b rn times the charge of a proton.
  • the resultant electric field is a time-harmonic solution of Laplace's Equations in spherical coordinates.
  • the radius at which force balance and nonradiation are a. achieved is where m is an integer. In decaying to this
  • a hydrogen atom with its electron in a lower than "ground state" energy level corresponding to a fractional quantum number is hereafter referred to as a hvdrino atom.
  • FIGURE 2 The size of the electron orbitsphere as a function of potential energy is given in FIGURE 2.
  • Lower-energy hydrogen atoms, hydrinos. can act as a source of energy holes that can cause resonant shrinkage because the excitation and/or ionization energies are m X 27.2 eV (Eq. (3)).
  • Hydrogen is a source of energy holes.
  • the ionization energy of hydrogen is 13.6 eV. Disproportionation can occur between three hydrogen atoms whereby two atoms provide an energy hole of 27.21 eV for the third hydrogen atom.
  • the shrinkage cascade for the pth cycle of the hydrogen-type with two hydrogen atoms, H ⁇ as the source of energy holes that cause resonant shrinkage is represented by ⁇ *
  • energy holes are provided by electron transfer reactions of reactants including electrochemical reactant(s) (electrocatalytic ion(s) or couple(s)) which cause heat to be released from hydrogen atoms as their electrons are stimulated to relax to quantized potential energy levels below that of the "ground state".
  • electrochemical reactant(s) electrochemical reactant(s) (electrocatalytic ion(s) or couple(s)) which cause heat to be released from hydrogen atoms as their electrons are stimulated to relax to quantized potential energy levels below that of the "ground state”.
  • the energy removed by an electron transfer reaction, energy hole is resonant with the hydrogen energy released to stimulate this transition.
  • the source of hydrogen atoms can be the production on the surface of a cathode during electrolysis of water in the case of an electrolytic energy reactor and hydrogen gas or a hydride in the case of a pressurized gas energy reactor or gas discharge energy reactor.
  • the central force equation for hydrogen-type molecules has orbital solutions which are circular, elliptic, parabolic, or hyperbolic.
  • the former two types of solutions are associated with atomic and molecular orbitals. These solutions are nonradiative if the boundary condition for nonradiation given in the One Electron Atom Section of The Unification of Spacetime. the Forces. Matter, and Energy. Mills, R., Technomic Publishing Company, Lancaster, PA, (1992), is met.
  • the mathematical formulation for zero radiation is that the function that describes the motion of the electron must not possess space-time Fourier components that are synchronous with waves traveling at the speed of light.
  • A ⁇ ab (24) where 2b is the length of the semiminor axis and 2a is the length of the semimajor axis.
  • the geometry of molecular hydrogen is elliptic with the internuclear axis as the principle axis; thus, the electron orbital is a two dimensional ellipsoidal- time harmonic function.
  • the mass follows geodesies time harmonically as determined by the central field of the protons at the foci. Rotational symmetry about the internuclear axis further determines that the orbital is a prolate spheroid.
  • ellipsoidal orbits of molecular bonding hereafter referred to as ellipsoidal molecular orbitals (M. O. 's) have the general equation
  • the semiprinciple axes of the ellipsoid are a. b, c.
  • An ellipsoidal M. O. is equivalent to a charged conductor whose surface is given by Eq. (25). It carries a total charge q, and it's potential is a solution of the Laplacian in ellipsoidal coordinates, Eq. (26).
  • FIGURE 3 A schematic drawing of the total energy well of hydrogen-type molecules and molecular ions is given in FIGURE 3.
  • the exothermic reaction involving transitions from one potential energy level to a lower level below the "ground state” is also hereafter referred to as ⁇ ydroCatalysis .
  • a hydrogen-type molecule with its electrons in a lower than "ground state" energy level corresponding to a fractional quantum number is hereafter referred to as a dihvdri no molecule .
  • the designation for a dihydrino molecule of F5 internuclear distance, 2c' °- where p is an integer, is
  • FIGURE 4 A schematic drawing of the size of hydrogen- type molecules as a function of total energy is given in FIGURE 4.
  • the ellipsoidal "ground state" field of the hydrogen molecule can be considered as the superposition of Fourier components.
  • the resultant electric field is a time harmonic solution of the Laplacian in ellipsoidal coordinates.
  • energy holes each of approximately mX48.6 eV ⁇ are provided by electron transfer reactions of reactants including electrochemical reactant(s) (electrocatalytic ion(s) or couple(s)) which cause heat to be released from hydrogen molecules as their electrons are stimulated to relax to quantized potential energy levels below that of the "ground state".
  • electrochemical reactant(s) electrochemical reactant(s) (electrocatalytic ion(s) or couple(s)) which cause heat to be released from hydrogen molecules as their electrons are stimulated to relax to quantized potential energy levels below that of the "ground state".
  • the energy removed by an electron transfer reaction, energy hole is resonant with the hydrogen energy released to stimulate this transition.
  • the source of hydrogen molecules can be the production on the surface of a cathode during electrolysis of water in the case of an electrolytic energy reactor and hydrogen gas or a hydride in the case of a pressurized gas energy reactor or gas discharge energy reactor.
  • the present invention of an electrolytic cell energy reactor, pressurized gas energy reactor, and a gas discharge energy reactor comprises: a source of hydrogen; one of a solid, molten, liquid, and gaseous source of energy holes; a vessel containing hydrogen and the source of energy holes wherein the shrinkage reaction occurs by contact of the hydrogen with the source of energy holes; and a means for removing the (molecular) lower-energy hydrogen so as to prevent the exothermic shrinkage reaction from coming to equilibrium.
  • the shrinkage reaction rate and let power output are increased by conforming the energy hole to match the resonance shrinkage energy.
  • power output can be optimized by controlling the temperature, pressure of the hydrogen gas, the source of the energy hole including the electrocatalytic ion or couple which provides the energy hole, the counterion of the electrocatalytic ion or couple, and the area of the surface on which the shrinkage reaction occurs.
  • the present invention further comprises a hydrogen spillover catalyst, a multifunctionality material having a functionality which dissociates molecular hydrogen to provide free hydrogen atoms which spill over to a functionality which supports mobile free hydrogen atoms and a functionality which can be a source of the energy holes.
  • a preferred pressurized hydrogen gas energy reactor comprises a vessel; a source of hydrogen; a means to control the pressure and flow of hydrogen into the vessel; a material to dissociate the molecular hydrogen into atomic hydrogen, and a material which can be a source of energy holes in the gas phase.
  • the gaseous source of energy holes includes those that sublime, boil, and/or are volatile at the elevated operating temperature of the gas energy reactor wherein the shrinkage reaction occurs in the gas phase.
  • FIGURE 1 is a schematic drawing of the total energy well of the hydrogen atom
  • FIGURE 2 is a schematic drawing of the size of electron orbitspheres as a function of potential energy
  • FIGURE 4 is a schematic drawing of the size of hydrogen- type molecules, as a function of total energy
  • FIGURE 5 is a schematic drawing of an energy reactor in accordance with the invention.
  • FIGURE 6 is a schematic drawing of an electrolytic cell energy reactor in accordance with the present invention
  • FIGURE 7 is a schematic drawing of a pressurized gas energy reactor in accordance with the present invention
  • FIGURE 8 is a schematic drawing of a gas discharge energy reactor in accordance with the invention.
  • FIGURE 9 is a plot of the excess heat release from flowing hydrogen in the presence of nickel oxide powder containing strontium niobium oxide (Nb 3+ / Sr 2* electrocatalytic couple) by the very accurate and reliable method of heat measurement, thermopile conversion of heat into an electrical output signal.
  • An energy hole is provided by the transition of an electron of a species to an excited state species including a continuum excited state(s) of atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the excited state transition of an electron of one species whereby the transition energy of the accepting species equals approximately mX21.2 ⁇ eV where m is an integer.
  • An energy hole is provided by the transfer of an electron between participating species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the transfer of an electron from one species to another species whereby the sum of the ionization energy of the electron donating species minus the ionization energy or electron affinity of the electron accepting species equals approximately mX21.2 ⁇ eV where m is an integer.
  • An energy hole is provided by the ionization of an electron from a participating species including an atom, an ion, a molecule, and an ionic or molecular compound to a vacuum energy level.
  • the energy hole comprises the ionization of an electron from one species to a vacuum energy level whereby the ionization energy of the electron donating species equals approximately mX21.2 ⁇ eV where m is an integer.
  • the shrinkage cascade for the pth cycle is represented by ⁇ _
  • Rubidium is a so a cata yst (e ectrocatalytic ion).
  • the second ionization energy is 27.28 eV.
  • An energy hole is provided by the transfer of multiple electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximately mX21.2 ⁇ eV where m and t are integers.
  • An energy hole is provided by the transfer of multiple electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the transfer of t electrons from one species to another whereby the t consecutive electron affinities and/or ionization energies of the electron donating species minus the t consecutive ionization energies and/or electron affinities of the electron acceptor equals approximately mX21.2 ⁇ eV where m and t are integers .
  • the electron acceptor species is an oxide such as MnO x , AlO x , SiO x .
  • a preferred molecular electron acceptor is oxygen, O 2 .
  • a catalytic system that provides an energy hole hinges on the ionization of two electrons from an atom, ion, or molecule to a vacuum energy level such that the sum of two ionization energies is approximately 27.21 eV.
  • a catalytic system that provides an energy hole hinges on the transfer of two electrons from an atom, ion, or molecule to another atom or molecule such that the sum of two ionization energies minus the sum of two electron affinities of the participating atoms, ions, and/or molecules is approximately 27.21 eV.
  • a catalytic system that hinges on the transfer of two electrons from an atom to a molecule involves palladium and oxygen.
  • the first and second ionization energies of palladium are 8.34 eV and 19.43 eV, respectively.
  • the first and second electron affinities of the oxygen molecule are 0.45 eV and 0.1 1 eV, respectively.
  • the energy hole resulting from a two electron transfer is appropriate for resonant absorption.
  • the combination of Pd to Pd 2+ and O 2 to O 2 ⁇ then, has a net energy change of 27.21 eV.
  • Additional atoms, molecules, or compounds which could be substituted for O 2 are those with first and second electron affinities of approximately 0.45 eV and 0.11 eV, respectively, such as a mixed oxide (MnO x , AlO x , SiO x ) containing O to form
  • a catalytic system that provides an energy hole hinges on the transfer of two electrons from an atom, ion, or molecule to another atom, ion, or molecule such that the sum of two ionization energies minus the sum of one ionization energy and one electron affinity of the participating atoms, ions, and/or molecules is approximately 27.21 eV.
  • a catalytic system that hinges on the transfer of two electrons from an atom to an ion involves xenon and lithium.
  • the first and second ionization energies of xenon are 12.13 eV and 21.21 eV, respectively.
  • the first ionization energy and the first electron affinity of lithium are 5.39 eV and 0.62 eV, respectively.
  • the energy hole resulting from a two electron transfer is appropriate for resonant absorption.
  • the combination of Xe to Xe 2* and Li * to Li ' then, has a net energy change of 27.33 eV.
  • a catalytic system that provides an energy hole hinges on the transfer of two electrons from an atom, ion, or molecule to another atom, ion, or molecule such that the sum of two ionization energies minus the sum of two ionization energies of the participating atoms and/or molecules is approximately 27.21 eV.
  • a catalytic system that hinges on the transfer of two electrons from a first ion to a second ion involves silver( Ag * ) and silver (Ag 2 *).
  • the second and third ionization energies of silver are 21.49 eV and 34.83 eV, respectively.
  • the second and first ionization energies of silver are 21.49 eV and 7.58 eV, respectively.
  • the energy hole resulting from a two electron transfer is appropriate for resonant absorption.
  • a catalytic system that provides an energy hole hinges on the transfer of three electrons from an ion to another ion such that the sum of the electron affinity and two ionization energies of the first ion minus the sum of three ionization energies of the second ion is approximately 27.21 eV.
  • a catalytic system that hinges on the transfer of three electrons from an ion to a second ion involves Li ' and Cr 3* .
  • the electron affinity, first ionization energy, and second ionization energy of lithium are 0.62 eV, 5.392 eV, and 75.638 eV, respectively.
  • the third, second, and first ionization energies of Cr 3* are 30.96 eV, 1 6.50 eV, and 6.766 eV, respectively.
  • the energy hole resulting from a three electron transfer is appropriate for resonant absorption.
  • a catalytic system that provides an energy hole hinges on the transfer of three electrons from an atom, ion, or molecule to another atom, ion, or molecule such that the sum of three consecutive ionization energies of the electron donating species minus the sum of three consecutive ionization energies of the electron accepting species is approximately 27.21 eV.
  • a catalytic system that hinges on the transfer of three electrons from an atom to an ion involves Ag and Ce 3* .
  • the first, second, and third ionization energies of silver are 7.58 eV, 21.49 eV, and 34.83 eV, respectively.
  • the third, second, and first ionization energies of Ce 3* are 20.20 eV, 10.85 cV, and 5.47 eV, respectively.
  • the energy hole resulting from a three electron transfer is appropriate for resonant absorption.
  • an energy hole of energy equal to the total energy released for a below "ground state" electronic transition of the hydrogen atom is provided by the transfer of an electron between participating species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the transfer of an electron from one species to another species whereby the sum of the ionization energy of the electron donating species minus the ionization energy or electron affinity of the electron m accepting species equals approximately —27.21 eV; where m is an integer.
  • An energy hole is provided by the transfer of multiple electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximately —27.21 eV where m and t are integers.
  • An energy hole is provided by the transition of an electron of a species to an excited state species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the excited state transition of an electron of one species whereby the transition energy of the accepting species is mp 2 XA8.6 eV where m and p are integers.
  • An energy hole is provided by the transfer of an electron between participating species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the transfer of an electron from one species to another species whereby the sum of the ionization energy of the electron donating species minus the ionization energy or electron affinity of the electron accepting species equals approximately mp 2 XA8.6 eV where m and p are integers.
  • An efficient catalytic system that hinges on the coupling of three resonator cavities involves yttrium.
  • the fourth ionization energy of gallium is 64.00 eV. This energy hole is obviously too high for resonant absorption.
  • Pb 2* releases 15.03 eV when it is reduced to Pb*.
  • An energy hole is provided by the ionization of an electron from a participating species including an atom, an ion, a molecule, and an ionic or molecular compound to a vacuum energy level.
  • the energy hole comprises the ionization of an electron from one species to a vacuum energy level whereby the ionization energy of the electron donating species equals approximately mp 2 XA8.6 eV where m and p are integers.
  • An energy hole is provided by the transfer of multiple electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximately mp 2 XA8.6 eV where m, p, and t are integers.
  • An energy hole is provided by the transfer of multiple electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the transfer of t electrons from one species to another whereby the t consecutive electron affinities and/or ionization energies of the electron donating species minus the t consecutive ionization energies and/or electron affinities of the electron acceptor equals approximately mp 2 XA8.6 eV where m, p, and t are integers.
  • the electron acceptor species is an oxide such as MnO x , AlO x , SiO x .
  • a preferred molecular electron acceptor is oxygen, O 2 .
  • a catalytic system that provides an energy hole hinges on the ionization of two electrons from an atom, ion, or molecule to a vacuum energy level such that the sum of two ionization energies is approximately mp 2 XA8.6 eV where m, and p are integers.
  • a catalytic system that provides an energy hole hinges on the transfer of two electrons from an atom, ion, or molecule to another atom or molecule such that the sum of two ionization energies minus the sum of two electron affinities of the participating atoms, ions, and/or molecules is approximately mp 2 XA8.6 eV where m and p are integers.
  • a catalytic system that provides an energy hole hinges on the transfer of two electrons from an atom, ion, or molecule to another atom, ion, or molecule such that the sum of two ionization energies minus the sum of one ionization energy and one electron affinity of the participating atoms, ions, and/or molecules is approximately mp 2 XA8.6 eV where m and p are integers.
  • energy holes In another embodiment, energy holes, each of approximately
  • electrochemical reactant(s) electrochemical reactant(s) (electrocatalytic ion(s) or couple(s)) which cause heat to be released from hydrogen molecules as their electrons are stimulated to relax to quantized potential energy levels below that of the "ground state".
  • the energy removed by an electron transfer reaction, energy hole, is resonant with the hydrogen energy released to stimulate this transition.
  • the source of hydrogen molecules is the production on the surface of a cathode during electrolysis of water in the case of an electrolytic energy reactor and hydrogen gas or a hydride in the case of a pressurized gas energy reactor or gas discharge energy reactor.
  • An energy hole is provided by the transfer of one or more electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximately mX67.8 eV where m and t are integers.
  • the energy removed by an electron transfer reaction, energy hole is resonant with the hydrogen energy released to stimulate this transition.
  • the source of hydrogen molecules is the production on the surface of a cathode during electrolysis of water in the case of an electrolytic energy reactor and hydrogen gas or a hydride in the case of a pressurized gas energy reactor or gas discharge energy reactor.
  • An energy hole is provided by the transfer of one or more electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximately mX3 ⁇ .9A eV ( ⁇ q. (222)) where m and t are integers.
  • An energy hole is provided by the transfer of one or more electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds.
  • the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximr ely mX95.1 eV where m and t are integers.
  • An energy reactor 50 in accordance with the invention, is shown in FIGURE 5 and comprises a vessel 52 which contains an energy reaction mixture 54, a heat exchanger 60, and a steam generator 62.
  • the heat exchanger 60 absorbs heat released by the shrinkage reaction, when the reaction mixture, comprised of shrinkable material, shrinks.
  • the heat exchanger exchanges heat with the steam generator 62 which absorbs heat from the exchanger 60 and produces steam.
  • the energy reactor 50 further comprises a turbine 70 which receives steam from the steam generator 62 and supplies mechanical power to a power generator 80 which converts the steam energy into electrical energy, which can be received by a load 90 to produce work or for dissipation.
  • the energy reaction mixture 54 comprises an energy releasing material 56 including a source of hydrogen isotope atoms or a source of molecular hydrogen isotope, and a source of energy holes 58 which resonantly remove approximately mX27.2 ⁇ eV to cause atomic hydrogen "shrinkage" and approximately m 48.6 eV to cause molecular hydrogen
  • the source of hydrogen can be hydrogen gas, dissociation of water including thermal dissociation, electrolysis of water, hydrogen from hydrides, or hydrogen from metal-hydrogen solutions.
  • the source of energy holes can be one or more of an electrochemical, chemical, photochemical, thermal, free radical, sonic, or nuclear reaction(s) or inelastic photon or particle scattering reaction(s).
  • the present invention of an energy reactor comprises a particle source 75b and/or photon source 75a to supply the said energy holes.
  • a photon source 75a dissociates hydrogen molecules to hydrogen atoms.
  • the photon source producing photons of at least one energy of m approximately mX27.2 ⁇ eV, — 27.21 eV, or 40.8 eV causes stimulated emission of energy as the hydrogen atoms undergo the shrinkage reaction.
  • a photon source 75a producing photons of at least one energy of approximately mXAS. ⁇ eV, 95.7 eV, or mX3l.9A eV causes stimulated emission of energy as the hydrogen molecules undergo the shrinkage reaction.
  • a selected external energy device 75 such as an electrode may be used to supply an electrostatic potential or a current (magnetic field) to decrease the activation energy of the resonant absorption of an energy hole.
  • the mixture 54 further comprises a surface or material to dissociate and/or absorb atoms and/or molecules of the energy releasing material 56.
  • Such surfaces or materials to dissociate and/or absorb hydrogen, deuterium, or tritium comprise an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite).
  • transition elements and inner transition elements iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, I
  • a source of energy holes to shrink hydrogen atoms comprises a catalytic energy hole material 58, typically comprising electrocatalytic ions and couples that provide an energy hole of approximately m 27.21 eV plus or minus 1 eV.
  • a source of energy holes to shrink hydrogen molecules comprises a catalytic energy hole material 58, typically comprising electrocatalytic ions and couple(s) including those that provide an energy hole of approximately 777X48.6 eV plus or minus 5 eV .
  • the electrocatalytic ions and couple(s) include the electrocatalytic ions and couples described in my previous U.S . Patent Applications entitled “Energy/Matter Conversion Methods and Structures", Serial No.
  • a further embodiment is the vessel 52 containing a source of energy holes including an electrocatalytic ion or couple(s) (source of energy holes) in the molten, liquid, gaseous, or solid state and a source of hydrogen including hydrides and gaseous hydrogen.
  • a source of energy holes including an electrocatalytic ion or couple(s) (source of energy holes) in the molten, liquid, gaseous, or solid state and a source of hydrogen including hydrides and gaseous hydrogen.
  • the embodiment further comprises a means to dissociate the molecular hydrogen into atomic hydrogen including an element, compound, alloy, or mixture of transition elements, inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Lr, Au, Hg, Ce, Pr, Nd. Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated
  • the present invention of an electrolytic cell energy reactor, pressurized gas energy reactor, and a gas discharge energy reactor comprises: a source of hydrogen; one of a solid, molten, liquid, and gaseous source of energy holes; a vessel containing hydrogen and the source of energy holes wherein the shrinkage reaction occurs by contact of the hydrogen with the source of energy holes; and a means for removing the (molecular) lower-energy hydrogen so as to prevent an exothermic shrinkage reaction from coming to equilibrium.
  • the present energy invention is further described in my previous U.S . Patent Applications entitled “Energy/Matter Conversion Methods and Structures", Serial No. 08/467,051 filed on June 6, 1995 which is a continuation-in-part application of Serial No. 08/416,040 filed on April 3, 1995 which is a continuation-in-part application of Serial No.
  • a preferred embodiment of the energy reactor of the present invention comprises an electrolytic cell forming the reaction vessel 52 of FIGURE 5 including a molten electrolytic cell.
  • the electrolytic cell 100 is shown generally in FIGURE 6.
  • An electric current is passed through the electrolytic solution 102 having a electrocatalytic ions or couples providing energy holes equal to the resonance shrinkage energy (including the electrocatalytic ions and couples described in my previous U.S. Patent Applications incorporated herein by reference) by the application of a voltage to an anode 104 and cathode 106 by the power controller 108 powered by the power supply 110.
  • Ultrasonic or mechanical energy may also be imparted to the cathode 106 and electrolytic solution 102 by vibrating means 112. Heat can be supplied to the electrolytic solution 102 by heater 114.
  • the pressure of the electrolytic cell 100 can be controlled by pressure regulator means 1 16 where the cell can be closed.
  • the reactor further comprises a means 101 that removes the (molecular) lower-energy hydrogen such as a selective venting valve to prevent the exothermic shrinkage reaction from coming to equilibrium.
  • the electrolytic cell is operated at zero voltage gap by applying an overpressure of hydrogen with hydrogen source 121 where the overpressure can be controlled by pressure control means 122 and 1 16.
  • Water can be reduced to hydrogen and hydroxide at the cathode 106, and the hydrogen can be oxidized to protons at the anode 104.
  • An embodiment of the electrolytic cell energy reactor comprises a reverse fuel cell geometry which removes the lower-energy hydrogen under vacuum.
  • a preferred cathode 106 of this embodiment has a modified gas diffusion layer and comprises a gas route means including a first Teflon membrane filter and a second carbon paper/Teflon membrane filter composite layer.
  • a further embodiment comprises a reaction vessel that can be closed except for a connection to a condensor 140 on the top of the vessel 100.
  • the cell can be operated at a boil such that the steam evolving from the boiling electrolyte 102 can be condensed in the condensor 140, and the condensed water can be returned to the vessel 100.
  • the lower-energy state hydrogen can be vented through the top of the condensor 140.
  • the condensor contains a hydrogen/oxygen recombiner 145 that contacts the evolving electrolytic gases. The hydrogen and oxygen are recombined, and the resulting water can be returned to the vessel 100.
  • the heat released from the exothermic reaction whereby the electrons of the electrolytically produced hydrogen atoms (molecules) are induced to undergo transitions to energy levels below the "ground state” and the heat released due to the recombination of the electrolytically generated normal hydrogen and oxygen can be removed by a heat exchanger 60 of FIGURE 5 which can be connected to the condensor 140.
  • the energy hole to stimulate a hydrogen atom (molecule) to undergo a shrinkage transition is mX27.2 ⁇ eV (mXA8.6 eV) where m is an integer.
  • This resonance shrinkage energy can be altered when the atom (molecule) is in a media different from vacuum.
  • An example is a hydrogen atom (molecule) absorbed to the cathode 106 present in the aqueous electrolytic solution 102 having an applied electric field and an intrinsic or applied magnetic field provided by external magnetic field generator 75. Under these conditions the energy hole required can be slightly different from mX27.2 ⁇ eV (mXA8.6 eV).
  • a source of energy holes including electrocatalytic ion and couple reactants can be selected which has a redox (electron transfer) energy resonant with the resonance shrinkage energy when operating under these conditions.
  • a nickel cathode 106 is used to electrolyze an aqueous solution 102 where the cell is operating within a voltage range of 1.4 to 5 volts
  • the K+/K+ and Rb+ (Fe 3 +/Li+ and Sc3+/Sc3+) electrocatalytic ions and couples are preferred embodiments to shrink hydrogen atoms (molecules).
  • the cathode provides hydrogen atoms (molecules), and the shrinkage reaction occurs at the surface of the cathode where hydrogen atoms (molecules) and the source of energy holes (electrocatalytic ion or couple) are in contact.
  • the shrinkage reaction can be dependent on the surface area of the cathode.
  • an increase in surface area increases the reactants available to undergo the shrinkage reaction.
  • an increase in cathode surface area decreases the resistance of the electrolytic cell which improves the electrolysis efficiency.
  • a preferred cathode of the electrolytic cell including a nickel cathode has the properties of a high surface area, a highly stressed and hardened surface such as a cold drawn or cold worked surface, and a large number of grain boundaries.
  • the source of energy holes can be incorporated into the cathode, mechanically by methods including cold working the source of energy holes into the surface of the cathode; thermally by methods including melting the source of energy holes into the surface of the cathode and evaporation of a solvent of a solution of the source of energy holes in contact with the surface of the cathode, and electrostatically by methods including electrolytic deposition, ion bombardment, and vacuum deposition.
  • the shrinkage reaction rate can be dependent upon the composition of the cathode 106. Hydrogen atoms (molecules) are reactants to produce energy via the shrinkage reaction. Thus, the cathode must efficiently provide a high concentration of hydrogen atoms (molecules).
  • 106 can be comprised of any element, compound, alloy, or mixture of a conductor or semiconductor including transition elements and compounds, actinide and lanthanide elements and compounds, and group IIIB and IVB elements and compounds.
  • Transition metals dissociate hydrogen gas into atoms to a more or lesser extent depending on the metal.
  • Nickel and titanium readily dissociate hydrogen molecules and are preferred embodiments for shrinking hydrogen atoms.
  • the cathode can alter the energy of the absorbed hydrogen atoms (molecules) and affect the energy of the shrinkage reaction.
  • a cathode material can be selected which provides resonance between the energy hole and the resonance shrinkage energy.
  • the relationship of the cathode material to the reaction rate can be: Pt ⁇ Pd « Ti,Fe ⁇ Ni
  • reaction rate can be increased by using a cathode which weakly absorbs the hydrogen atoms with little perturbation of their electronic energies.
  • a paramagnetic or ferromagnetic cathode increases the reaction rate by increasing the coupling of the resonance shrinkage energy of the hydrogen atom and energy hole comprising an electrocatalytic ion or couple.
  • a magnetic field can be applied with the magnetic field generator 75. Magnetic fields at the cathode alter the energy of absorbed hydrogen and concomitantly alter the resonance shrinkage energy. Magnetic fields also perturb the energy of the electrocatalytic reactions (energy hole) by altering the energy levels of the electrons involved in the reactions.
  • the magnetic properties of the cathode are selected as well as the strength of the magnetic field which is applied by magnetic field generator 75 to optimize shrinkage reaction rate-the power output.
  • a preferred ferromagnetic cathode is nickel.
  • a preferred method to clean the cathode of the electrolytic cell including a nickel cathode is to anodize the cathode in a basic electrolytic solution including approximately 0.57 M X2CO3 (X is the alkali cation of the electrolyte including K+) and to immerse the cathode in a dilute solution of H2O2 such as approximately 3% H2O 2.
  • a further embodiment of the cleaning method cyclic voltametry with a second electrode of the same material as the first cathode is performed. The cathode can be then thoroughly rinsed with distilled water.
  • Organic material on the surface of the cathode inhibits the catalytic reaction whereby the electrons of the electrolytically produced hydrogen atoms (molecules) are induced to undergo transitions to energy levels below the "ground state”. Cleaning by this method removes the organic material from the cathode surface and adds oxygen atoms onto the cathode surface.
  • Doping the metal surface, including a nickel surface, with oxygen atoms by anodizing the cathode and cleaning the cathode in H2O 2 increases the power output by decreasing hydrogen recombination to molecular hydrogen and by decreasing the bond energy between the metal and the hydrogen atoms (molecules) which conforms the resonance shrinkage energy of the absorbed hydrogen to the energy hole provided by the source of energy holes including the K+/K+ (Sc 3 +/Sc 3+ ) electrocatalytic couples.
  • Nickel, platinum, and dimensionally stable anodes including platinized titanium are preferred anodes.
  • nickel is a preferred anode.
  • Nickel is also a preferred anode for use in basic solutions with a nickel cathode. Nickel is inexpensive relative to platinum, and fresh nickel can be electroplated onto the cathode during electrolysis .
  • a preferred method to clean a dimensionally stable anode including a platinized titanium anode is to place the anode in approximately 3 M HC1 for approximately 5 minutes and then to rinse it with distilled water.
  • hydrogen atoms at the surface of the cathode 106 form hydrogen gas which can form bubbles on the surface of the cathode. These bubbles act as an boundary layer between the hydrogen atoms and the electrocatalytic ion or couple.
  • the boundary can be ameliorated by vibrating the cathode and/or the electrolytic solution 102 or by applying ultrasound with vibrating means 112; and by adding wetting agents to the electrolytic solution 102 to reduce the surface tension of the water and prevent bubble formation.
  • the use of a cathode having a smooth surface or a wire cathode prevents gas adherence.
  • an intermittent current, provided by an on- off circuit of power controller 108 provides periodic replenishing of hydrogen atoms which are dissipated by hydrogen gas formation followed by diffusion into the solution while preventing excessive hydrogen gas formation which could form a boundary layer.
  • the shrinkage reaction can be temperature dependent. Most chemical reactions double their rates for each 10 °C rise in temperature. Increasing the temperature increases the collision rate between the hydrogen atoms (molecules) and the electrocatalytic ion or couple which will increase the shrinkage reaction rate. With large temperature excursions from room temperature, the kinetic energy distribution of the reactants can be sufficiently altered to cause the energy hole and the resonance shrinkage energy to conform to a more or lesser extent. The rate can be proportional to the extent of the conformation or resonance of these energies. The temperature can be adjusted to optimize the shrinkage reaction rate-energy production rate. In the case of the K+/K+ electrocatalytic couple, a preferred embodiment can be to run the reaction at a temperature above room temperature by applying heat with heater 114.
  • the shrinkage reaction can be dependent on the current density.
  • An increase in current density can be equivalent, in some aspects, to an increase in temperature.
  • the collision rate increases, and the energy of the reactants increases with current density.
  • the rate can be increased by increasing the collision rate of the reactants; however, the rate may be increased or decreased depending on the effect of the increased reactant energies on the conformation of the energy hole and the resonance shrinkar; energy.
  • increased current dissipates more energy jy ohmic heating and may cause hydrogen bubble formation, in the case of the shrinkage of hydrogen atoms. But, a high flow of gas may dislodge bubbles which diminishes any hydrogen gas boundary layer.
  • the current density can be adjusted with power controller 108 to optimize the excess energy production. In a preferred embodiment, the current density can be in the range 1 to 1000 milliamps per square centimeter.
  • the pH of the aqueous electrolytic solution 102 can affect the shrinkage reaction rate.
  • an increase in the pH will reduce the concentration of hydronium at the negative cathode; thus, the concentration of the electrocatalytic ion or couple cations will increase.
  • An increase in reactant concentration increases the reaction rate.
  • a preferred pH can be basic (7.1-14).
  • the counterion of the electrocatalytic ion or couple of the electrolytic solution 102 can affect the shrinkage reaction rate by altering the energy of the transition state.
  • the transition state complex of the K+/K+ electrocatalytic couple with the hydrogen atom has a plus two charge and involves a three body collision which can be unfavorable.
  • a negative two charged oxyanion can bind the two potassium ions; thus, it provides a neutral transition state complex of lower energy whose formation depends on a binary collision which can be greatly favored.
  • the rate can be dependent on the separation distance of the potassium ions as part of the complex with the oxyanion. The greater the separation distance, the less favorable can be the transfer of an electron between them. A close juxtaposition of the potassium ions will increase the rate.
  • the relationship of the reaction rate to the counterion in the case where the K+/K+ couple is used can be :
  • a planar negative two charged oxyanion including carbonate with at least two binding sites for K+ which provides close juxtaposition of the K+ ions can be preferred as the counterion of the K+/K+ electro atalytic couple.
  • the carbonate counterion can be also a preferred counterion for the Rb+ electrocatalytic ion.
  • a power controller 108 comprising an intermittent current, on-off, electrolysis circuit will increase the excess heat by providing optimization of the electric field as a function of time which provides maximum conformation of reactant energies, provides an optimal concentration of hydrogen atoms (molecules) while minimizing ohmic and electrolysis power losses and, in the case of the shrinkage of hydrogen atoms, minimizes the formation of a hydrogen gas boundary layer.
  • the frequency, duty cycle, peak voltage, step waveform, peak current, and offset voltage are adjusted to achieve the optimal shrinkage reaction rate and shrinkage reaction power while minimizing ohmic and electrolysis power losses.
  • a preferred embodiment can be to use an intermittent square-wave having an offset voltage of approximately 1.4 volts to 2.2 volts; a peak voltage of approximately 1.5 volts to 3.75 volts; a peak current of approximately 1 mA to 100 mA per square centimeter of cathode surface area; approximately a 5 -90% duty cycle; and a frequency in the range of 1 Hz to 1500 Hz.
  • a cathode 106 can be used which will facilitates multiple shrinkage reactions of hydrogen atoms (molecules).
  • One embodiment is to use a cathode which can be fissured and porous to the electrocatalytic ion or couple such that it can contact shrunken atoms (molecules) which have diffused into a lattice, including a metal lattice.
  • a further embodiment is to use a cathode of alternating layers of a material which provides hydrogen atoms (molecules) during electrolysis including a transition metal and an electrocatalytic ion or couple such that shrunken hydrogen atoms (molecules) periodically or repetitively diffuse into contact with the electrocatalytic ion or couple.
  • the shrinkage reaction can be dependent on the dielectric constant of the media.
  • the dielectric constant of the media alters the electric field at the cathode and concomitantly alters the energy of the reactants.
  • Solvents of different dielectric constants have different solvation energies, and the dielectric constant of the solvent can also lower the overpotential for electrolysis and improve electrolysis efficiency.
  • a solvent, including water, can be selected for the electrolytic solution 102 which optimizes the conformation of the energy hole and resonance shrinkage energy and maximizes the efficiency of electrolysis.
  • the solubility of hydrogen in the reaction solution can be directly proportional to the pressure of hydrogen above the solution. Increasing the pressure increases the concentration of reactant hydrogen atoms (molecules) at the cathode 106 and thereby increases the rate. But, in the case of the shrinkage of hydrogen atoms this also favors the development of a hydrogen gas boundary layer.
  • the hydrogen pressure can be controlled by pressure regulator means 116 to optimize the shrinkage reaction rate.
  • the cathode 106 of the electrolytic cell comprises the catalytic material including a hydrogen spillover catalyst described in the Pressurized Gas
  • the cathode comprises multiple hollow vessels comprising a thin film conductive shell whereby lower-energy hydrogen diffuses through the thin film and collects inside each vessel and undergoes disproportionation reactions therein.
  • the heat output can be monitored with thermocouples present in at least the vessel 100 and the condensor 140 of FIGURE 6 and the heat exchanger 60 of FIGURE 5.
  • the output power can be controlled by a computerized monitoring and control system which monitors the thermistors and controls the means to alter the power output. Pressurized Gas Energy Reactor
  • a pressurized gas energy reactor comprises the first vessel 200 of FIGURE 7 containing a source of hydrogen including hydrogen from metal-hydrogen solutions, hydrogen from hydrides, hydrogen from the dissociation of water including thermal dissociation, hydrogen from the electrolysis of water, or hydrogen gas.
  • the reactor further comprises a means to dissociate the molecular hydrogen into atomic hydrogen such as a dissociating material including an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite) or electromagnetic radiation including UV light provided by photon source 205 such that the dissociated hydrogen atoms (molecules) contact a source of energy holes including a molten, liquid, gaseous, or solid source of the energy holes including the electrocata dissociating material including an element, compound, alloy, or
  • thermoelectric lower-energy hydrogen such as a selective venting valve to prevent the exothermic shrinkage reaction from coming to equilibrium.
  • One embodiment comprises heat pipes as heat exchanger 60 of FIGURE 5 which have a lower-energy hydrogen venting valve at a cold spot.
  • a preferred embodiment of the pressurized gas energy reactor of the present invention comprises a first reaction vessel 200 with inner surface 240 comprised of a material to dissociate the molecular hydrogen into atomic hydrogen including an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite).
  • a material to dissociate the molecular hydrogen into atomic hydrogen including an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel
  • the inner surface 240 can be comprised of a proton conductor.
  • the first reaction vessel 200 can be sealed in a second reaction vessel 220 and receives hydrogen from source 221 under pressure which can be controlled by pressure measurement and control means 222 and 223.
  • the hydrogen pressure can be in the range of 10 -3 atmospheres to 100 atmospheres.
  • the wall 250 of the first vessel 200 can be permeable to hydrogen.
  • the outer surface 245 and/or outer vessel 220 has a source of energy holes equal to the resonance shrinkage energy.
  • the source of energy holes can be a mixture or solution containing energy holes in the molten, liquid, or solid state.
  • an electric current can be passed through the material having a source of energy holes.
  • the reactor further comprises a means to control the reaction rate such as current source 225 and heating means 230 which heat the first reaction vessel 200 and the second reaction vessel 220.
  • the outer reaction vessel 220 contains oxygen
  • the inner surface 240 comprises one or more of a coat of nickel, platinum, or palladium.
  • the outer surface 245 can be coated with one or more of copper, tellurium, arsenic, cesium, platinum, or palladium and an oxide such as CuO x , PtO , PdO x , MnO x , AlO x , SiO x .
  • the electrocatalytic ion or couple can be regenerated spontaneously or via a regeneration means including heating means 230 and current source 225.
  • the pressurized gas energy reactor comprises only a single reaction vessel 200 with a hydrogen impermeable wall 250.
  • a hydrogen dissociating materials including transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite) are coated on the inner surface 240 with a source of energy holes including one or more of copper, tellurium, arsenic, cesium, platinum, or palladium and an oxide such as
  • the source of energy hole can be one of a inelastic photon or particle scattering reaction(s).
  • the photon source 205 supplies the energy holes where the energy hole corresponds to stimulated emission by the photon.
  • the photon source 205 dissociates hydrogen molecules into hydrogen atoms.
  • the photon source producing photons of at least one energy of approximately mX27.2 ⁇ eV, — X27.21 eV, or 40.8 eV causes stimulated emission of energy as the hydrogen atoms undergo the shrinkage reaction.
  • a photon source 205 producing photons of at least one energy of approximately m 48.6 eV , 95.7 eV, or m 31.94 eV causes stimulated emission of energy as the hydrogen molecules undergo the shrinkage reaction.
  • a preferred inner surface, 240, and outer surface, 245, of the pressurized gas energy reactor including a nickel surface has the properties of a high surface area, a highly stressed and hardened surface such as a cold drawn or cold worked surface, and a large number of grain boundaries.
  • the source of energy holes can be incorporated into the inner surface, 240, and outer surface, 245, mechanically by methods including cold working the source of energy holes into the surface material and thermally by methods including melting the source of energy holes into the surface material (fusion).
  • a preferred method to clean the inner surface 240 and the outer surface 245 including a nickel surface is to fill the inner vessel and the outer vessel with a basic electrolytic solution including approximately 0.57 M X2CO3 (X is the alkali cation of the electrolyte including K+) and to fill the inner vessel and the outer vessel with a dilute solution of H2O2.
  • X is the alkali cation of the electrolyte including K+
  • Each of the inner vessel and the outer vessel can be then thoroughly rinsed with distilled water.
  • at least one of the vessel 200 or the vessel 220 can be then filled with a solution of the energy hole including an approximately 0.57 M K2CO3 solution.
  • textural and/or structural promoters are incorporated with the source of energy holes to increase the shrinkage reaction rate.
  • hydrogen can be introduced inside of the first vessel from source 221 under pressure which can be controlled by pressure control means 222.
  • the molecular hydrogen can be dissociated into atomic hydrogen by a dissociating material or electromagnetic radiation including UV light provided by photon source 205 such that the dissociated hydrogen atoms contact a source of energy holes including a molten, liquid, gaseous, or solid source of the energy holes.
  • the atomic (molecular) hydrogen releases energy as its electrons are stimulated to undergo transitions to lower energy levels by the energy holes.
  • the hydrogen dissociates on the inner surface 240, diffuses though the wall 250 of the first vessel 200 and contacts a source of energy holes on the outer surface 245 or contact a source of energy holes including a molten, liquid, gaseous, or solid source of the energy holes as hydrogen atoms or recombined hydrogen molecules.
  • the atomic (molecular) hydrogen releases energy as its electrons are stimulated to undergo transitions to lower energy levels by the energy holes.
  • the electrocatalytic ion or couple can be regenerated spontaneously or via a regeneration means including heating means 230 and current source 225.
  • the (molecular) lower- energy hydrogen can be removed from vessel 200 and/or vessel 220 by a means to remove the (molecular) lower- energy hydrogen such as a selective venting valve means 201 which prevents the exothermic shrinkage reaction from coming to equilibrium.
  • a means to remove the (molecular) lower- energy hydrogen such as a selective venting valve means 201 which prevents the exothermic shrinkage reaction from coming to equilibrium.
  • an electric current can be passed through the material having a source of energy holes equal to the resonance shrinkage energy with current source 225, and/or the first reaction vessel 200 and the second reaction vessel 220 are heated by heating means 230.
  • the heat output can be monitored with thermocouples present in at least the first vessel 200, the second vessel 220, and the heat exchanger 60 of FIGURE 5.
  • the output power can be controlled by a computerized monitoring and control system which monitors the thermistors and controls the means to alter the power output.
  • the (molecular) lower-energy hydrogen can be removed by a means 201 to prevent the exothermic shrinkage reaction from coming to equilibrium.
  • a method of preparation of the catalytic material of the present invention of catalytic systems that hinge on the transfer of an electron from a cation to another capable of producing energy holes for shrinking hydrogen atoms includes the steps of:
  • Example of a Ceramic Catalytic Material Strontium Niobium Oxide ( SrNboO ⁇ on Ni Powder: To prepare the ceramic catalytic material: strontium niobium oxide (SrNb 2 ⁇ 6) on Ni powder, 2.5 kg of SrNb 2 ⁇ 6 are added to 1.5 kg of -300 mesh Ni powder. The materials are mixed to make a homogeneous mixture. The powder can be sintered or calcinated in an oven at 1600°C in atmospheric air for 24 hours. The material can be cooled and ground to remove lumps. The material can be re-sintered at 1600°C in air for another 24 hours. The material can be cooled to room temperature and powderized.
  • SrNboO ⁇ on Ni Powder To prepare the ceramic catalytic material: strontium niobium oxide (SrNb 2 ⁇ 6) on Ni powder, 2.5 kg of SrNb 2 ⁇ 6 are added to 1.5 kg of -300 mesh Ni powder. The materials are mixed to make a homogeneous mixture. The powder can
  • a method of preparation of the catalytic material of the present invention of catalytic systems that hinge on the transfer of an electron from a cation to another capable of producing energy holes for shrinking hydrogen atoms includes the steps of:
  • ionic salts of the cations • Dissolving ionic salts of the cations into a solvent.
  • the ionic salts are dissolved in deionized demineralized water to concentration of 0.3 to 0.5 molar.
  • potassium carbonate (K 2 C0 3 ) on Ni powder a 1 liter solution of 0.5 M K2CO3 in water is poured over 500 grams of -300 mesh Ni powder. The materials are stirred to remove air pockets around the grains of Ni. The excess solution can be drained off. The powder can be dried in an oven at 200°C. If necessary the material can be ground to remove lumps.
  • the source of hydrogen atoms for the catalytic shrinkage reaction comprises a hydrogen spillover catalyst.
  • a hydrogen spillover catalyst according to the present invention comprises: • A hydrogen dissociation material or means which forms free hydrogen atoms or protons;
  • a support material into which the former materials are embedded as a mixture, compound, or solution.
  • Such hydrogen dissociation materials include surfaces or materials to dissociate hydrogen, deuterium, or tritium, comprise an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu,
  • Such conduit materials onto which free hydrogen atoms spill and which supports free, mobile hydrogen atoms and which provides a path or conduit for the flow of hydrogen atoms include nickel, platinum, carbon, tin, iron, aluminum, and copper and their compounds, mixtures, or alloys.
  • support materials into which the former materials are embedded as a mixture, compound, or solution includes carbon, silica, nickel, copper, titania, zinc oxide, chromia, magnesia, zirconia, alumina, silica-alumina, and zeolites.
  • one or more of the other components are deposited on the support material by electroplating.
  • the source of energy holes to cause atomic hydrogen "shrinkage” are preferably of approximately 777X27.21 eV and/or to cause molecular hydrogen "shrinkage" are of approximately rnX48.6 eV where m is an integer including the electrocatalytic ions and couples described in my previous U.S. Patent Applications entitled “Energy/Matter Conversion Methods and Structures", Serial No. 08/467,051 filed on June 6, 1995 which is a continuation-in-part application of Serial No. 08/416,040 filed on April 3, 1995 which is a continuation-in-part application of Serial No.
  • organic ions including benzoic acid, phthalate, salicylate, aryl sulfonate, alky sulfate, alkyl sulfonate, and alkyl carboxylate, and the anion of an acid which forms an acid anhydride including sulfite, sulfate, carbonate, bicarbonate, nitrite, nitrate, perchlorate, phosphite, hydrogen phosphite, dihydrogen phosphite, phosphate, hydrogen phosphate, and dihydrogen phosphate.
  • the anion can be in equilibrium with its acid and its acid anhydride.
  • the functionalities of the hydrogen spillover catalyst are combined with the other functionalities as separate species or as combinations comprising a mixture, solution, compound, or alloy of more than one functionality.
  • the hydrogen dissociation material and the source of energy holes each comprise homogeneous crystals- each crystal contains one component, and these functionalities are mixed with the conduit material without a support material.
  • the hydrogen dissociation material and the source of energy holes comprise heterogeneous crystals-each crystal contains both of the components, and the heterogeneous crystals are mixed with the conduit material which coats a support material.
  • the source of energy holes can be embedded in the conduit material, and this combined species can be mixed with the hydrogen dissociation material which can be embedded in the same or a different conduit material without a support material.
  • a method of preparation of the hydrogen spillover catalytic material of the present invention includes the steps of:
  • a further method of preparation of the hydrogen spillover catalytic material of the present invention includes the steps of:
  • An incipient wetness method of preparation of the hydrogen spillover catalytic material of the present invention comprising a source of energy holes for shrinking hydrogen atoms that hinge on the transfer of an electron from a cation to another includes the steps of:
  • the ionic salts are dissolved in deionized demineralized water. • Preparing an incipiently wet conduit-hydrogen dissociation material by uniformly wetting the conduit-hydrogen dissociation material with the dissolved salt solution so that the pores of the material are just filled.
  • the total volume of solvent required can be the desired amount, and the weight percent of the ionic salts of the cations in the final material can be determined by the desired weight of the ionic salts of the cations dissolved in the desired volume of solvent.
  • KNO 3 potassium nitrate
  • the aqueous KNO3 solution can be slowly added to 0.6 kg of l %-Pd-on--300-mesh-graphitic carbon powder as the slurry can be mixed.
  • the slurry can be then placed on an evaporation dish which can be inserted into an oven at 150°C for one hour. Heating causes the water to evaporate from the slurry.
  • the KNO3 coated 1 %-Pd-on-graphitic carbon can be ground into a powder.
  • Another incipient wetness method of preparation of the hydrogen spillover catalytic material of the present invention comprising a source of energy holes for shrinking hydrogen atoms that hinge on the transfer of an electron from a cation to another includes the steps of:
  • the ionic salts are dissolved in deionized demineralized water.
  • Example of a Ionic Hydrogen Spillover Catalytic Material 40% by Weight Potassium Nitrate (KNO J) on Graphitic Carbon Powder with 5% by Weight 1 %-Pd-on-Graphitic Carbon Powder:
  • KNO J Potassium Nitrate
  • Incipient wetness requires 1 ml of H 0 per gram of -300 mesh graphite powder, and 0.40 grams of KNO3 are required per gram of graphite powder to achieve a 40% by weight KNO3 content in the final material.
  • the aqueous KNO 3 solution can be slowly added to 0.55 kg of graphite powder as the slurry can be mixed.
  • the slurry can be then placed on an evaporation dish which can be inserted into an oven at 150°C for one hour. Heating causes the water to evaporate from the slurry.
  • the KNO3 coated graphite can be ground into a powder.
  • the powder can be weighed. Approximately 50 grams (5% of the weight of the KNO 3 coated graphite) of 1 %- Pd-on— 300-mesh graphitic carbon powder can be mixed into the KNO3 coated graphitic carbon powder.
  • the catalytic material can be placed into the pressurizable vessel 200.
  • the vessel can be flushed with an inert gas such as He, Ar, or Ne to remove air contaminants in the vessel.
  • the vessel and its contents are heated to the operational temperature, typically 100 °C to 400 °C, before the vessel can be pressurized with hydrogen, typically 20 to 140 PSIG.
  • the source of energy holes is potassium ions (K+/K+) or rubidium ions (Rb + ) intercalated into carbon.
  • the source of energy holes is an amalgam of the electrocatalytic ion or couple and its reduced metallic form such as rubidium ions (Rb+) and rubidium metal or potassium ions (K+/K+) and potassium metal .
  • the source of hydrogen atoms is a hydrogen dissociation means including a hydrogen gas stream blown over a hot filament or grid such as a hot refractory metal including a filament or grid of Ti, Ni, Fe, W, Au, Pt, or Pd at an elevated temperature such as 1800°C.
  • the dissociation means provides hydrogen atoms as well as hydrogen ions, and the momentum of the atoms brings them in contact with the source of energy holes. Or, the hydrogen atoms and ions sputter onto the spillover catalyst.
  • a low pressure can be maintained by pressure regulator means 222 and a pump means 223 to minimize hydrogen atom recombination into molecular hydrogen and remove (molecular) lower-energy hydrogen.
  • the source of hydrogen atoms is water which dissociates to hydrogen atoms and oxygen on a water dissociation material such as an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y. Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce. Pr, Nd, Pm, Sm, Eu, Gd,
  • a water dissociation material such as an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y. Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce. Pr, Nd,
  • the water dissociation material can be maintained at an elevated temperature by a heat source and temperature control means 230.
  • the source of hydrogen can be from hydrocarbons including natural gas which can be reformed on a reforming a material such as nickel, cobalt, iron, or a platinum-group metal to hydrogen atoms and carbon dioxide.
  • the reforming material can be maintained at an elevated temperature by a heat source and a temperature control means 230.
  • the source of hydrogen atoms can be from the decomposition of a metal hydride where the decomposition can be controlled by controlling the temperature of the metal hydride with the heat source and temperature control means 230.
  • the hydride can be coated by methods including electroplating with another material such as the hydrogen dissociation material .
  • a product of the shrinkage reaction (molecular) lower-energy hydrogen
  • a product of the shrinkage reaction (molecular) lower-energy hydrogen
  • the forward energy yielding reaction rate can be increased.
  • One means to remove lower-energy (molecular) hydrogen is to supply the reaction mixture with a scavenger for lower-energy hydrogen.
  • the scavenger absorbs or reacts with the product, lower-energy, hydrogen, and the resulting species can be removed from the reaction mixture.
  • lower-energy hydrogen which is absorbed on the catalysts can be removed via displacement with an inert molecule or atom such as helium that flows through the vessel 200.
  • the reactor comprises a trickle-bed reactor, a bubble-column reactor, or a slurry reactor.
  • the fluidized bed reactor 200 comprises the hydrogen spillover catalytic material: 40% by weight potassium nitrate (KN0 3 ) on graphitic carbon powder with 5% by weight 1 %-Pd-on-graphitic carbon powder.
  • the reacting hydrogen gas can be passed up through a bed of the finely divided solid catalytic material, preferably having a particle size in the range of about 20 to 100 ⁇ m , which can be highly agitated and assumes many of the characteristics of a fluid.
  • a cyclone separator 275 returns the fines to the bed.
  • the hydrogen pressure and flow rate are controlled by pressure and flow rate control means 222.
  • the corresponding maximum linear velocity can be less than 60 cm/s .
  • a preferred hydrogen gas energy reactor for the release of energy by an electrocatalytic and/or a disproportination reaction, wherein the electrons of hydrogen atoms undergo transitions to lower energy states in the gas phase comprises a vessel 200 of FIGURE 7 capable of containing a vacuum or pressures greater than atmospheric; a source of hydrogen 221 ; a means 222 to control the pressure and flow of hydrogen into the vessel; a source of atomic hydrogen in the gas phase, and a source of energy holes in the gas phase.
  • the reaction vessel 200 comprises a vacuum or pressure vessel comprised of a temperature resistance material such as ceramic, stainless steel, tungsten, alumina, Incoloy, and Inconel .
  • the source of hydrogen atoms in the gas phase is a hydrogen dissociation means including a hydrogen gas stream blown over a hot filament or grid 280 such as a hot refractory metal including a filament or grid of Ti, Ni, Fe, W, Au, Pt, or Pd at an elevated temperature such as 1800°C.
  • the dissociation means provides hydrogen atoms as well as hydrogen ions, and the momentum of the atoms brings them in contact with the source of energy holes.
  • a low pressure can be maintained by pressure regulator means 222 and a pressure measurement and pump means 223 to minimize hydrog i atom recombination into molecular hydrogen.
  • the pressure can be measured by measuring the power dissipated in the hot filament or grid which can be operated at constant resistance by a servo loop 285 comprising a voltage and current measurement means, a power supply, and a voltage and current controller where the hydrogen pressure versus power dissipation of the filament or grid at the operating resistance has been calibrated.
  • the source of atomic hydrogen comprises one or more hydrogen dissociation materials which provide hydrogen atoms by dissociation of molecular hydrogen.
  • Such hydrogen dissociation materials include surfaces or materials to dissociate hydrogen, deuterium, or tritium, including a hydrogen spillover material such as palladium or platinum on carbon and an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W,
  • a hydrogen spillover material such as palladium or platinum on carbon and an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W,
  • nonequilibrium conditions of the hydrogen and hydride are maintained by controlling the temperature and hydrogen pressure to provide atomic hydrogen in the gas phase.
  • the source of atomic hydrogen comprises a tungsten capillary which on the outlet can be heated by electron bombardment to 1800-2000 K such as the atomic hydrogen source described by Bischler [Bischler, U.; Bertel, E., J. Vac. Sci. Technol., A.
  • the tungsten capillary can be heated by the energy released by the hydrogen shrinkage reaction.
  • the source of atomic hydrogen comprises an inductively coupled plasma flow tube such as that described by Gardner [Gardner, W. L., J. Vac. Sci. Technol., A. (1995), 13(3, Pt. 1), 763-6] which is incorporated herein by reference, and the hydrogen dissociation fraction can be measured with the sensor of Gardner.
  • the source of energy holes can be placed in a chemically resistant open container such as a ceramic boat 290 inside the reaction vessel. Or, the source of energy holes can be placed in a vessel which has a connection for the passage of the gaseous source of energy holes to the reaction vessel.
  • the gaseous source of energy holes includes those that sublime, boil, and/or are volatile at the elevated operating temperature of the gas energy reactor wherein the shrinkage reaction occurs in the gas phase.
  • RbNO,and KNO-. are each volatile at a temperature much less than that at which each decomposes [C. J. Hardy, B. 0. Field, J. Chem. Soc, (1963), pp. 5130-5134].
  • the ionic hydrogen spillover catalytic material 40% by weight potassium or rubidium nitrate on graphitic carbon powder with 5% by weight 1 %-Pd-on-graphitic carbon powder can be operated at a temperate at which the potassium or rubidium nitrate can be volatile. Further disproportionation reactions of the product, lower-energy hydrogen atoms, release additional heat energy.
  • the source of energy holes is a thermally stable salt of rubidium or potassium such as RbF, RbCl, RbBr, Rbl, Rb 2 S 2 , RbOH, Rb 2 S0 4 , Rb 2 CO ? , Rb,P0 4 , and
  • the following compounds are preferred gaseous sources of energy holes in the gas energy reactor. Higher temperatures result in a higher vapor pressure of the source of energy holes which increases the reaction rate; however, the increase in total pressure increases the recombination rate of hydrogen atoms to hydrogen molecules.
  • the operating temperature of the energy reactor can be that which provides an optimal reaction rate.
  • the cell temperature can be about 50°C higher than the (highest) melting point of the source of energy holes (in the case that the source of energy holes comprises an electron transfer between two cations—an electrocatalytic couple).
  • the hydrogen pressure can be maintained at about
  • molecular hydrogen can be dissociated with a hot filament or grid 280 of FIGURE 7.
  • Single Ion Catalysts Single-ion catalysts (electrocatalytic ions) capable of producing energy holes for shrinking hydrogen atoms.
  • Two-ion catalysts capable of producing energy holes for shrinking hydrogen atoms.
  • the anion in an embodiment wherein the anion can be reduced by hydrogen, the anion is chemically stabilized.
  • the product of the reduction is added to the gas cell to stabilize the anion.
  • the anion can be replaced continuously or intermittently.
  • the product ammonia can be removed from the vessel, oxidized to nitrate, and returned to the cell.
  • the product ammonia can be removed from the vessel by collection in a condensor and can be oxidized to nitrate on a platinum or iridium screen at elevated temperatures such as 912 °C.
  • the nitrate ion to ammonia reaction can be minimized by decreasing the hydrogen pressure while optimizing the vapor phase catalytic hydrogen shrinkage reaction.
  • a low pressure of hydrogen atoms can be generated by dissociation of molecular hydrogen on a hot filament or grid 280 of FIGURE 7. A low pressure of molecular hydrogen can be maintained via the hydrogen supply 221 , the hydrogen flow control means 222, and the hydrogen pressure measurement and vacuum means 223.
  • the hydrogen pressure can be maintained at a low pressure by adjusting the supply through the inlet with flow controller 222 versus the amount pumped away at the outlet by the pressure measurement and pump means 223.
  • the pressure can be adjusted to maximize the output power while minimizing the degradation of nitrate.
  • the optimal hydrogen pressure can be less than about one torr.
  • the source of hydrogen atoms in the gas phase can be a hydrogen dissociation means including a hydrogen gas stream blown over a hot filament or grid 280 such as a hot refractory metal including a filament or grid of Ti, Ni, Fe, W, Au, Pt, or Pd at an elevated temperature such as 1800°C.
  • the hydrogen molecular source can be directed over the filament or grid and onto the gaseous source of energy holes.
  • the pressure and flow of the hydrogen atoms prohibits the collision of the counterion of the source of energy holes (such as the nitrate ion) from contacting the hot filament or grid.
  • the thermal decomposition or reduction of the anion on the filament or grid can be prevented.
  • a negative potential can be maintained as a grid electrode 287 surrounding the filament or grid.
  • the grid electrode permits the passage of hydrogen atoms rom the filament or grid and repels the anion from contacting the hot filament or grid.
  • the thermal or chemical breakdown of the anion (couterion) can be prevented.
  • the source of energy holes is an electrocatalytic ion or electrocatalytic couple comprising cation-anion pairs in the gas phase wherein the cation-anion pairs are dissociated by external source means 75 of FIGURE 5 which includes, for example, a particle source 75b and/or photon source 75a and/or a source of heat, acoustic energy, electric fields, or magnetic fields.
  • the cation-anion pairs are thermally dissociated by heat source 230 or photodissociated by photon source 205 of FIGURE 7.
  • the source of energy holes is atomized with an atomizer means 295 to provide a gaseous source of energy holes.
  • atoms are boiled, sublimed, or vaporized by a heating means such as the boat heating means 299, and the gaseous atoms are ionized to form a source of energy holes including the electrocatalytic ions or electrocatalytic couples of my previous patent applications incorporated herein by reference.
  • the atoms are thermally ionized by the heating means 230, by the hydrogen atom source 280 including a hot filament or grid, or by an inductively coupled plasma flow tube.
  • the gas energy cell shown in Figure 7 comprises rubidium or potassium metal in the boat 290 which has a vapor pressure that can be controlled by controlling the temperature of the boat by heating means 230 and or 299. Hydrogen molecules are dissociated to atoms on the hot filament or grid 280.
  • the rubidium (potassium) metal in the gas phase can be ionized to Rb+ (K+) by the same or different hot filament or grid 280.
  • the Rb+ (K+/K+) electrocatalytic ion (couple) serves as a source of energy holes to shrink the hydrogen atoms.
  • the hot filament c grid 280 comprises a metal(s) or can be electroplated with a metal(s) which boils off as a cation(s) that are a source of energy holes.
  • Mo 2 + ions Mo 2 + electrocatalytic ion
  • the hot molybdenum filament or grid 280 also dissociates hydrogen molecules to hydrogen atoms.
  • Ni 2+ and Cu + ions Ni 2 +/Cu+ electrocatalytic couple
  • the photon source 75a and the particle source 75b of FIGURE 5, including an electron beam ionize species such as atoms in the gas phase to form the source of energy holes including the electrocatalytic ions or electrocatalytic couples of my previous patent applications incorporated herein by reference.
  • the atoms or ions are ionized chemically by a volatilized reactant such as an ionic species which oxidizes or reduces the atoms or ions to form a source of energy holes.
  • the power of the gas energy reactor can be controlled by controlling the amount of the source of energy holes (electrocatalytic ion or couple) in the gas phase and/or by controlling the concentration of atomic or lower-energy hydrogen.
  • the concentration of the gaseous source of energy holes (electrocatalytic ion or couple) can be controlled by controlling the initial amount of the volatile source of energy holes (electrocatalytic ion or couple) present in the reactor, and/or by controlling the temperature of the reactor with temperature control means 230 which determines the vapor pressure of the volatile source of energy holes (electrocatalytic ion or couple).
  • the reactor temperature further controls the power by changing the rate of the catalytic hydrogen shrinkage reaction.
  • the concentration of atomic hydrogen can be controlled by controlling the amount of atomic hydrogen provided by the atomic hydrogen source 280.
  • the amount of hydrogen atoms in the gas phase can be controlled by controlling the flow of hydrogen over or through the hot filament or grid, the tungsten capillary heated by electron bombardment, or the inductively coupled plasma flow tube; by controlling the power dissipated in the inductively coupled plasma flow tube; by controlling the temperature of the hot filament or grid, or the tungsten capillary heated by electron bombardment; by controlling the pressure of the hydrogen and temperature of the hydride maintained under nonequilibrium conditions, and by controlling the rate of removal of recombined hydrogen from the cell by pump means 223.
  • Another means to control the shrinkage reaction rate can be by controlling the pressure of a non reactive gas with non reactive gas source 299, non reactive gas flow control means 232, and pressure measurement and pump means 223.
  • the non reactive gas such as a noble gas competes with collisions between the source of energy holes (electrocatalytic ion or couple) and hydrogen atoms or competes with collisions that yield lower-energy hydrogen disproportionation reactions.
  • Noble gases include He, Ne, and Ar.
  • reaction non reactive " reaction quenching" gases include carbon dioxide and nitrogen.
  • the hydrogen partial pressure can be further controlled by throttling hydrogen into the cell by a hydrogen value control means 222 while monitoring the pressure with a pressure measurement means 222 and 223.
  • the hydrogen pressure can be controlled by controlling the temperature with heating means 230 of the gas energy reactor which further comprises a hydrogen storage means such as a metal hydride or other hydride including saline hydrides, titanium hydride, vanadium, niobium, and tantalum hydrides, zirconium and hafnium hydrides, rare earth hydrides, yttrium and scandium hydrides, transition element hydrides, intermetalic hydrides, and their alloys known in the art as given by W. M. Mueller, J. P. Blackledge, and G.
  • a hydrogen storage means such as a metal hydride or other hydride including saline hydrides, titanium hydride, vanadium, niobium, and tantalum hydrides, zirconium and hafnium hydrides, rare
  • the temperature of the cell can be controlled by a temperature control and measurement means 230 such that the vapor pressure of the hydrogen in equilibrium with the hydrogen storage material can be the desired pressure.
  • nonequilibrium conditions of the hydrogen and hydride are maintained by controlling the temperature and hydrogen pressure to provide atomic hydrogen.
  • the hydrogen storage means can be a rare earth hydride with an operating temperature of about 800 °C; lanthanum hydride with an operating temperature of about 700 °C; gadolinium hydride with an operating temperature of about 750 °C; neodymium hydride with an operating temperature of about 750 °C; yttrium hydride with an operating temperature of about 800 °C; scandium hydride with an operating temperature of about 800 °C; ytterbium hydride with an operating temperature of about 850-900 °C; titanium hydride with an operating temperature of about 450 °C; cerium hydride with an operating temperature of about 950 °C; praseodymium hydride with an operating temperature of about 700 °C; zirconium-titanium (50%/50%) hydride with an operating temperature of about 600 °C; an alkali metal/alkali metal hydride mixture such as Rb/RbH or K/KH with an
  • the heat output can be monitored with thermocouples present in at least the vessel 200 and the heat exchanger 60 of
  • the rate of the shrinkage reaction rate can be monitored by ultraviolet or electron spectroscopy of the photons or electrons emitted via lower-energy hydrogen transitions, by X-ray photoelectron spectroscopy (XPS) of lower-energy hydrogen, and by mass spectroscopy, Raman or infrared spectroscopy, and gas chromatography of the molecular lower-energy hydrogen (dihydrino).
  • XPS X-ray photoelectron spectroscopy
  • mass spectroscopy Raman or infrared spectroscopy
  • gas chromatography of the molecular lower-energy hydrogen (dihydrino).
  • Lower-energy hydrogen atoms and molecules are identified by XPS as higher binding energy species than normal hydrogen.
  • the dihydrino can be identified by gas chromatography at low temperature such as gas chromatography with an activated carbon (charcoal) column at liquid nitrogen temperature or with a column that will separate para from ortho hydrogen such as an Rt-Alumina column, or a HayeSep column at liquid nitrogen temperature wherein normal hydrogen can be retained to a greater extent than dihydrino.
  • the dihydrino can be identified by Raman and infrared spectroscopy as a molecule with higher vibrational and rotational energy levels as compared to those of normal hydrogen.
  • the output power can be controlled by a computerized monitoring and control system which monitors the thermistors, spectrometers, and gas chromatograph and controls the means to alter the power output.
  • the (molecular) lower-energy hydrogen can be removed by a means 201 to prevent the exothermic shrinkage reaction from coming to equilibrium.
  • hydrogen atoms are produced by a pyrolysis reaction such as the combustion of a hydrocarbon wherein the catalytic source of energy holes can be in the gas phase with the hydrogen atoms.
  • the pyrolysis reaction occurs in an internal combustion engine whereby the hydrocarbon or hydrogen containing fuel comprises a source of energy holes that are vaporized (become gaseous) during the combustion.
  • the source of energy holes is a thermally stable salt of rubidium or potassium such as RbF, RbCl, RbBr, Rbl, Rb 2 S 2 , RbOH, Rb 2 S0 4 , Rb 2 C0 3 , Rb 3 P0 4 , and KF, KG, KBr, KI, K 2 S 2 , KOH, K S0 4 , K 2 C0 3 , K 3 P0 4 ,K GeF 4 .
  • a thermally stable salt of rubidium or potassium such as RbF, RbCl, RbBr, Rbl, Rb 2 S 2 , RbOH, Rb 2 S0 4 , Rb 2 C0 3 , Rb 3 P0 4 , and KF, KG, KBr, KI, K 2 S 2 , KOH, K S0 4 , K 2 C0 3 , K 3 P0 4 ,K GeF 4 .
  • the hydrocarbon or hydrogen containing fuel further comprises water as a mixture and a solvated source of energy holes including emulsified electrocatalytic ions or couples.
  • water serves as a further source of hydrogen atoms which undergo a shrinkage reaction catalyzed by the source of energy holes wherein the water can be dissociated to hydrogen atoms thermally or catalytically on a surface such as the cylinder or piston head which can be comprised of material which dissociates water to hydrogen and oxygen.
  • the water dissociation material includes an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite).
  • transition elements and inner transition elements iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm
  • R (8.8 X 10 '25 ) J ⁇ D ° ⁇ 2
  • r is the distance between the donor and the acceptor
  • J is the overlap integral between the resonance shrinkage energy distribution of the donor hydrino atom and the distribution of the energy hole provided by the acceptor hydrino atom
  • ⁇ is the dielectric constant
  • ⁇ 2 is a function of the mutual orientation of the donor and acceptor transition moments. Electronic transitions of lower-energy hydrogen atoms occur only by nonradiative energy transfer; thus, the quantum yield of the fluorescence of the donor, ⁇ D , of Eq.
  • Eq. (6.38) The factor of one half in Eq. (6.38) corrects for double counting of collisions [Levine, I., Physical Chemistry, McGraw-Hill Book Company, New York, (1978), pp. 420-421].
  • the power, P m ,p t is given by the product of the rate of the transition, Eq. (6.38), and the energy of the disproportination reaction (Eq. (5.27)).
  • reaction rate is dependent on the collision rate between the reactants and the efficiency of resonant energy transfer.
  • the average velocity, v avg can be calculated from the temperature, T, [Bueche, F. J., Introduction to Physics for Engineers, McGraw-Hill Book Company, New York, (1986), pp. 261-265].
  • the rate of the catalytic reaction, r , to cause resonant shrinkage is given by the product of the collision rate per unit volume, Z r . , the volume, V, and the efficiency, E, of
  • the power, P m p is given by the product of the rate of the transition, Eq. (6.45), and the energy of the transition, Eq.
  • an electron transfer occurs between two cations which comprises an energy hole for a hydrogen or hydrino atom.
  • the reaction rate is dependent on the collision rate between catalytic cations and hydrogen or hydrino atoms and the efficiency of resonant energy transfer with a concomitant electron transfer with each shrinkage reaction.
  • the rate of the catalytic reaction, r m p to cause resonant shrinkage is given by the product of the collision rate per unit volume, Z , the volume, V, and a L ⁇ Catalyst the efficiency, E e , of resonant energy transfer given by ⁇ q. (6.37) where r is given by the average distance between cations in the reaction vessel.
  • the power, P m p is given by the product of the rate of the transition, ⁇ q. (6.51). and the energy of the transition, ⁇ q. (5.8).
  • a gas discharge energy reactor comprises a hydrogen isotope gas filled glow discharge vacuum chamber 300 of FIGURE 8 including an ozonizer-type capacitor, a hydrogen source 322 which supplies hydrogen to the chamber 300 through control valve 325, and a voltage and current source 330 to cause current to pass between a cathode 305 and an anode 320.
  • a dielectric barrier such as glass or a ceramic moiety.
  • the cathode further comprises a source of energy holes of approximately mX27.21 eV to cause atomic hydrogen "shrinkage" and/or approximately mX48.6 eV to cause molecular hydrogen
  • a preferred cathode 305 for shrinking hydrogen atoms is a palladium cathode whereby a resonant energy hole can be provided by the ionization of electrons from palladium to the discharge current.
  • a second preferred cathode 305 for shrinking hydrogen atoms comprises a source of energy holes via electron transfer to the discharge current including at least one of beryllium, copper, platinum, zinc, and tellurium and a hydrogen dissociating means such as a source of electromagnetic radiation including UV light provided by photon source 350 or a hydrogen dissociating material including the transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo.
  • a hydrogen dissociating means such as a source of electromagnetic radiation including UV light provided by photon source 350 or a hydrogen dissociating material including the transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo.
  • the reactor further comprises a means to control the energy dissipated in the discharge current when electrons are transferred from an electron donating species to provide an energy hole for hydrogen atoms (molecules) including pressure controller means 325 and current (voltage) source 330.
  • the gas discharge energy reactor further comprises a means 301 to remove the (molecular) lower-energy hydrogen such as a selective venting valve to prevent the exothermic shrinkage reaction from coming to equilibrium.
  • the source of energy hole can be one of a inelastic photon or particle scattering reaction(s).
  • the photon source 350 supplies the energy holes where the energy hole corresponds to stimulated emission by the photon.
  • the photon source 350 dissociates hydrogen molecules into hydrogen atoms.
  • a photon source 350 producing photons of at least one energy of approximately mXA8.6 eV , 95.7 eV , or mX31.94 eV causes stimulated emission of energy as the hydrogen molecules undergo the shrinkage reaction.
  • a magnetic field can be applied by magnetic field generator 75 of FIGURE 5 to produce a magnetized plasma of the gaseous ions which can be a nonlinear media. Coupling of resonator cavities and enhancement of the transfer of energy between them can be increased when the media is nonlinear.
  • the reaction rate transfer of the resonance shrinkage energy of the hydrogen atoms to the energy holes, the electrocatalytic ions or couples
  • hydrogen from source 322 can be introduced inside of the chamber 300 through control valve
  • a current source 330 causes current to pass between a cathode 305 and an anode 320.
  • the hydrogen contacts the cathode which comprises a source of energy holes of approximately mX27.21 eV to cause atomic hydrogen "shrinkage" and approximately mX48.6 eV to cause molecular hydrogen "shrinkage" where m is an integer.
  • electrons are transferred from an electron donating species present on the cathode 305 to the discharge current to provide energy holes for hydrogen atoms (molecules).
  • the molecular hydrogen can be dissociated into atomic hydrogen by a dissociating material on the cathode 305 or by a source of electromagnetic radiation including UV light provided by photon source 350 such that the dissociated hydrogen atoms contact a source of energy holes including a molten, liquid, gaseous, or solid source of the energy holes.
  • the atomic (molecular) hydrogen releases energy as its electrons are stimulated to undergo transitions to lower energy levels by the energy holes.
  • the energy dissipated in the discharge current when electrons are transferred from an electron donating species can be controlled to provide an energy hole equal to the resonance shrinkage energy for hydrogen atoms (molecules) by controlling the gas pressure from source 322 with pressure controller means 325 and the voltage with the current (voltage) source 330.
  • the heat output can be monitored with thermocouples present in at least the cathode 305, the anode 320, and the heat exchanger 60 of FIGURE 5.
  • the output power can be controlled by a computerized monitoring and control system which monitors the thermistors and controls the means to alter the power output.
  • the (molecular) lower-energy hydrogen can be removed by a means 301 to prevent the exothermic shrinkage reaction from coming to equilibrium.
  • a preferred cathode 305 comprises the catalytic material including a spillover catalyst described in the
  • gas discharge energy reactor comprises a gaseous source of energy holes wherein the shrinkage reaction occurs in the gas phase, and the gaseous hydrogen atoms are provided by a discharge of molecular hydrogen gas.
  • gaseous source of energy holes can be provided by a discharge current which produces the gaseous source of energy holes (electrocatalytic ion or couple) such as a discharge in potassium metal to form K+/K+, rubidium metal to form Rb + , or titanium metal to form Ti 2 +.
  • the embodiment comprises a hydrogen isotope gas filled glow discharge chamber 300.
  • the glow discharge cell can be operated at an elevated temperature such this the source of energy holes (electrocatalytic ion or couple) can be sublimed, boiled, or volatilized into the gas phase.
  • the counterion of the source of energy holes (electrocatalytic ion or couple) can be the hydride anion ( H ⁇ ) such as rubidium hydride (Rb+ electrocatalytic ion) and/or potassium hydride (K+/K+ electrocatalytic couple).
  • the source of energy holes can be an electrocatalytic ion or electrocatalytic couple comprising cation-anion pairs in the gas phase wherein the cation-anion pairs are dissociated by external source means 75 of FIGURE 5 which includes, for example, a particle source 75b and/or photon source 75a and/or a source of heat, acoustic energy, electric fields, or magnetic fields.
  • the cation-anion pairs are thermally dissociated by heat source 75 of FIGURE 5 or photodissociated by photon source 350 of FIGURE 8.
  • Refrigeration Means A further embodiment of the present invention comprises a refrigeration means which comprises the electrolytic cell of FIGURE 6, the pressurized hydrogen gas cell of FIGURE 7, and the hydrogen gas discharge cell of FIGURE 8 of the present invention wherein a source of lower-energy atomic (molecular) hydrogen is supplied rather than a source of normal hydrogen.
  • the lower-energy hydrogen atoms are reacted to a higher energy state with the absorption of heat energy according to the reverse of the catalytic shrinkage reaction such as those given by Eqs. (4-6); (7-9); ( 10- 12); (13- 15); ( 16- 18); (48-50); (51 -53); (54-56); (57-59); (60-62), (63-
  • means 101 , 201 and 301 of FIGURES 6, 7, and 8, respectively, serve to remove the normal hydrogen such as a selective venting valves to prevent the endothermic reaction from coming to equilibrium.
  • compositions of Matter Comprising at Least Lower-Energy Hydrogen Atom(s) and/or Lower-Energy Hydrogen MoleculeCs
  • the present invention further comprises molecules containing lower-energy hydrogen atoms.
  • Lower-energy hydrogen can be reacted with any atom of the periodic chart or known organic or inorganic molecule or compound or metal, nonmetal, or semiconductor to form an organic or inorganic molecule or compound or metal, nonmetal, or semiconductor containing lower-energy hydrogen atoms and molecules.
  • the reactants with lower-energy hydrogen include neutral atoms, negatively or positively charged atomic and molecular ions, and free radicals.
  • lower-energy hydrogen can be reacted with water or oxygen to form a molecule containing lower-energy hydrogen and oxygen
  • lower-energy hydrogen can be reacted with singly ionized helium to form a molecule containing helium and lower-energy hydrogen.
  • Lower-energy hydrogen can be also reacted with metals.
  • lower- energy hydrogen produced during operation at the cathode can be incorporated into the cathode by reacting with it; thus, a metal-lower-energy hydrogen material can be produced. In all such reactions, the reaction rate and product yield are increased by applying heat, and/or pressure.
  • Lower-energy hydrogen molecules are purified from hydrogen gas by combustion of the normal hydrogen.
  • Oxygen can be mixed with the sample to be purified, and the sample can be ignited.
  • the sample can be flowed over a hydrogen recombiner which reacts with the normal hydrogen in the gas stream to form water.
  • lower-energy hydrogen molecules (dihydrinos) are collected in a cathode of an electrolytic energy reactor of the present invention such as a metal cathode including a nickel cathode or a carbon cathode.
  • the cathode can be heated in a vessel to a first temperature which causes normal hydrogen to preferentially off gas by external heating or by flowing a current through the cathode.
  • the normal hydrogen can be pumped off, then the cathode can be heated to a second higher temperature at which dihydrino gas can be released and collected.
  • the gas sample is purified by cryofiltration including gas chromatography at low temperature such as gas chromatography with an activated carbon (charcoal) column at liquid nitrogen temperature and with a column which will separate para from ortho hydrogen such as an Rt-Alumina column, or a HayeSep column at liquid nitrogen temperature wherein normal hydrogen can be retained to a greater extent than dihydrino.
  • the gas sample is purified by cryodistillation wherein normal hydrogen can be liquefied and separated from gaseous lower-energy hydrogen (dihydrino).
  • the dihydrino can be concentrated by liquefaction in liquid helium.
  • Transitions to these lower energy states are stimulated in the presence of pairs of potassium ions (K+/K+ electrocatalytic couple) which provide 27.2 eV energy sinks.
  • Mills et al. report the experimental evidence supporting the Mills theory that an exothermic reaction occurs wherein the electrons of hydrogen atoms and deuterium atoms are stimulated to relax to quantized potential energy levels below that of the "ground state” via electrochemical reactants K+ and K+; Pd 2+ and Li+, or Pd and 0 of redox energy resonant with the energy hole which stimulates this transition.
  • Calorimetry of pulsed current and continuous electrolysis of aqueous potassium carbonate (K+/K+ electrocatalytic couple) at a nickel cathode was performed. The excess power out of 41 watts exceeded the total input power given by the product of the electrolysis voltage and current by a factor greater than 8.
  • the "ash” of the exothermic reaction is atoms having electrons of energy below the "ground state” which are predicted to form molecules.
  • the predicted molecules were identified by lack of reactivity with oxygen, by separation from molecular deuterium by cryofiltration, and by mass spectroscopic analysis.
  • Palladium sheets coated on one side with a hydrogen impermeant gold layer and coated on the other surface with an oxide coat were deuterium or hydrogen loaded at NTT Laboratories. Heat was observed from light and heavy hydrogen only when the mixed oxide coat was present (Pd/0 electrocatalytic couple).
  • NISHIOKA Direct Evidence for Nuclear Fusion Reactions in Deuterated Palladium
  • Proc. 3rd Int. Conf. Cold Fusion , Nagoya, Japan, October 21-25, 1992, p. 179
  • E. YAMAGUCHI and T. NISHIOKA "Helium-4 Production from Deuterated Palladium at Low energies” NTT Basic Research Laboratories and IMRA Europe S. A., Personal Communication (1992)].
  • Example 3 Pennsylvania State University has determined excess heat release from flowing hydrogen in the presence of nickel oxide powder containing strontium niobium oxide (Nb 3 +/Sr 2 + electrocatalytic couple) by the very accurate and reliable method of heat measurement, thermopile conversion of heat into an electrical output signal [Phillips, J., "A Calorimetric Investigation of the Reaction of Hydrogen with Sample PSU #1 ", September 1 1 , 1994, A Confidential Report submitted to HydroCatalysis Power Corporation provided by HydroCatalysis Power Corporation, Great Valley Corporate Center, 41 Great Valley Parkway, Malvern, PA 19355]. Excess power and heat were observed with flowing hydrogen over the catalyst which increased with increasing flow rate.
  • the source of heat is assigned to the electrocatalytic, exothermic reaction whereby the electrons of hydrogen atoms are induced to undergo transitions to quantized energy levels below the conventional "ground state".
  • Nb3+/Sr2+ electrocatalytic couple which provide 27.2 eV energy sinks.
  • the paradox of the paucity of solar neutrinos to account for the solar energy output by the pp chain is resolved by assigning a major portion of the solar output to lower-energy hydrogen transitions.
  • the photosphere of the Sun is 6000 K; whereas, the temperature of the corona based on the assignment of the emitted X-rays to highly ionized heavy elements is in excess of 10 6 K. No satisfactory power transfer mechanism is known which explains the excessive temperature of the corona relative to that of the photosphere.
  • Example 5 Pennsylvania State University has determined excess heat release from flowing hydrogen in the presence of ionic hydrogen spillover catalytic material: 40% by weight potassium nitrate (KNO3) on graphitic carbon powder with 5% by weight 1 %-Pd-on-graphitic carbon (K+/K+ electrocatalytic couple) by the very accurate and reliable method of heat measurement, thermopile conversion of heat into an electrical output signal [Phillips, J., Shim, ⁇ ., "Additional Calorimetric Examples of Anomalous Heat from Physical Mixtures of K/Carbon and Pd/Carbon", January 1 , 1996, A Confidential Report submitted to HydroCatalysis Power Corporation provided by HydroCatalysis Power Corporation, Great Valley Corporate Center, 41 Great Valley Parkway, Malvern, PA 19355].
  • KNO3 potassium nitrate
  • Example 6 Excess heat from a pressurized gas energy cell having a gaseous source of energy holes has been observed by HydroCatalysis Power Corporation [manuscript in progress] with low pressure hydrogen in the presence of molybdenum iodide (MoI ) (Mo 2 + electrocatalytic ion) which was volatilized at the operating temperature of the cell, 210 °C.
  • MoI molybdenum iodide
  • the calorimeter was placed inside a large convection oven that maintained the ambient temperature of the cell at the operating temperature.
  • the cell comprised a 40 cc stainless steel pressure vessel that was surrounded by a 2 inch thick molded ceramic thermal insulator.
  • the cell was sealed with a vacuum tight flange that had a two hole Buffalo gland for a tungsten wire to dissociate molecular hydrogen, a perforation for a Type K thermocouple, a 1/16 inch inlet for hydrogen which was connected to a 1/4 inch stainless steel tube which connected to the hydrogen supply.
  • the flange was sealed with a copper gasket.
  • the bottom of the vessel had a 1/4" vacuum port connected to a stainless steel tube with a valve between the cell and a vacuum pump and vacuum gauge.
  • Less than one gram of M0I2 catalyst was placed in a ceramic boat inside the vessel. The vapor pressure of the catalyst was estimated to be about 50 millitorr at the operating temperature 210 °C.
  • the hydrogen pressure of about 200 to 250 millitorr was controlled manually by adjusting the supply through the inlet versus the amount pumped away at the outlet where the pressure was monitored in the outlet tube by the vacuum gauge. For each run, the total pressure was made (including the MoI 2 pressue in the case of the experimental run) precisely 250 millitorr.
  • the output power was determined by measuring difference between the cell temperature and the ambient oven temperature and comparing the result to a calibration curve generated by applying power to the inside of the cell with the tungsten filament. Excess power of 0.3 watts was observed from the 40 cc stainless steel reaction vessel containing less than 1 g of MoI 2 when hydrogen was flowed over the hot tungsten wire ( - 2000 °C). However, no excess power was observed when helium was flowed over the hot tungsten wire or when hydrogen was flowed over the hot tungsten wire with no MoI 2 present in the cell.
  • the gaseous contents of the reactor were monitored with a mass spectrometer. At the time that excess energy was produced corresponding to the case wherein hydrogen was flowed over the hot filament, a higher ionizing mass two species was observable; where ⁇ , during the control run wherein hydrogen was flowed over the hot tungsten wire with no MoI 2 present in the cell, a higher ionizing mass two species was not observed.
  • the higher ionizing mass two species is assigned to the dihydrino molecule, 2H 2

Abstract

Methods and apparatus for releasing energy from hydrogen atoms (molecules) by stimulating their electrons to relax to quantized lower energy levels and smaller radii (smaller semimajor and semiminor axes) than the 'ground state' by providing energy sinks or means to remove energy resonant with the hydrogen energy released to stimulate these transitions. An energy sink, energy hole, can be provided by the transfer of at least one electron between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of t electrons from one or more donating species to one or more accepting species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron accepting species equals approximately mX27.21 eV (mX48.6 eV) for atomic (molecular) hydrogen below 'ground state' transitions where m and t are integers. The present invention further comprises a hydrogen spillover catalyst, a multifunctionality material having a functionality which dissociates molecular hydrogen to provide free hydrogen atoms which spill over to a functionality which supports mobile free hydrogen atoms and a functionality which can be a source of the energy holes. The energy reactor includes one of an electrolytic cell, a pressurized hydrogen gas cell, and a hydrogen gas discharge cell. A preferred pressurized hydrogen gas energy reactor comprises a vessel; a source of hydrogen; a means to control the pressure and flow of hydrogen into the vessel; a material to dissociate the molecular hydrogen into atomic hydrogen, and a material which can be a source of energy holes in the gas phase. The gaseous source of energy holes includes those that sublime, boil, and/or are volatile at the elevated operating temperature of the gas energy reactor wherein the exothermic reaction of electronic transitions of hydrogen to lower energy states occurs in the gas phase.

Description

LOWER-ENERGY HYDROGEN METHODS AND STRUCTURES
BACKGROUND OF THE INVENTION
1. Field of the Invention:
This invention relates to methods and apparatus for releasing energy from hydrogen atoms (molecules) as their electrons are stimulated to relax to lower energy levels and smaller radii (smaller semimajor and semiminor axes) than the "ground state" by providing a transition catalyst which acts as an energy sink or means to remove energy resonant with the electronic energy released to stimulate these transitions according to a novel atomic model. The transition catalyst should not be consumed in the reaction. It accepts energy from hydrogen and releases the energy to the surroundings. Thus, the transition catalyst returns to the origin state. Processes that require collisions are common. For example, the exothermic chemical reaction of H + H to form H2 requires a collision with a third body, , to remove the bond energy - H + H + Λ → H2 + . The third body distributes the energy from the exothermic reaction, and the end result is the H2 molecule and an increase in the temperature of the system.
Similarly, the transition from the 77 = 1 state of hydrogen to the n = states of hydrogen is possible via a resonant integer collision, say « = 1 to n = l / 2. In these cases, during the collision the electron(s) couples to another electron transition or electron transfer reaction, for example, which can absorb the exact amount of energy that must be removed from the hydrogen atom (molecule), a resonant energy sink. The end result is a lower-energy state for the hydrogen and increase in temperature of the system. Each of such reactions is hereafter referred to as a shrinkage reaction: each transition is hereafter referred to as a shrinkage transition: each energy sink or means to remove energy resonant with the hydrogen electronic energy released to effect each transition is hereafter referred to as an energy hole, and the electronic energy removed by the energy hole to effect or stimulate the shrinkage transition is hereafter referred to as the resonance shrinkage energy. An energy hole comprising a reactant ion that is spontaneously regenerated following an endothermic electron ionization reaction of energy equal to the resonance shrinkage energy is hereafter referred to as an electrocatalvtic ion. An energy hole comprising two reactants that are spontaneously regenerated following the an endothermic electron transfer reaction between the two species wherein the differences in their ionization energies is equal to the resonance shrinkage energy is hereafter referred to as an electrocatalvtic couple.
The present invention of an electrolytic cell energy reactor, pressurized gas energy reactor, and a gas discharge energy reactor, comprises: a source of hydrogen; one of a solid, molten, liquid, and gaseous source of energy holes; a vessel containing hydrogen and the source of energy holes wherein the shrinkage reaction occurs by contact of the hydrogen with the source of energy holes; and a means for removing the (molecular) lower-energy hydrogen so as to prevent an exothermic shrinkage reaction from coming to equilibrium.
The present invention further comprises methods and structures for repeating this shrinkage reaction to produce shrunken atoms (molecules) to provide new materials with novel properties such as high thermal stability.
2. Description of the Related Art
Existing atomic models and theories are unable to explain certain observed physical phenomena. The Schrδdinger wavefunctions of the hydrogen atom, for example, do not explain the extreme ultraviolet emission spectrum of the interstellar medium or that of the Sun, as well as the phenomenon of anomalous heat release from hydrogen in certain electrolytic cells having a potassium carbonate electrolyte or certain gas energy cells having a hydrogen spillover catalyst comprising potassium nitrate with the production of lower-energy hydrogen atoms and molecules, which is part of the present invention. Thus, advances in energy production and materials have been largely limited to laboratory discoveries having limited or sub-optimal commercial application.
SUMMARY OF THE INVENTION
The present invention comprises methods and apparatuses for releasing heat energy from hydrogen atoms (molecules) by stimulating their electrons to relax to quantized potential energy levels below that of the "ground state" via electron transfer reactions of reactants including electrochemical reactant(s) (electrocatalvtic ion(s) or couple(s)) which remove energy from the hydrogen atoms (molecules) to stimulate these transitions. In addition, this application includes methods and apparatuses to enhance the power output by enhancing the reaction rate- the rate of the formation of the lower-energy hydrogen. The present invention further comprises a hydrogen spillover catalyst, a multifunctionality material having a functionality which dissociates molecular hydrogen to provide free hydrogen atoms which spill over to a functionality which supports mobile free hydrogen atoms and a functionality which can be a source of the energy holes. The energy reactor includes one of an electrolytic cell, a pressurized hydrogen gas cell, and a hydrogen gas discharge cell. A preferred pressurized hydrogen gas energy reactor comprises a vessel; a source of hydrogen; a means to control the pressure and flow of hydrogen into the vessel; a material to dissociate the molecular hydrogen into atomic hydrogen, and a material which can be a source of energy holes in the gas phase. The gaseous source of energy holes includes those that sublime, boil, and/or are volatile at the elevated operating temperature of the gas energy reactor wherein the shrinkage reaction occurs in the gas phase.
The present invention further comprises methods and apparatuses for repeating a shrinkage reaction according to the present invention to cause energy release and to provide shrunken atoms and molecules with novel properties such as high thermal stability, and low reactivity. The lower-energy state atoms and molecules are useful for heat transfer, cryogenic applications, as a buoyant gas. as a medium in an engine such as a Sterling engine or a turbine, as a general replacement for helium, and as a refrigerant by absorbing energy including heat energy as the electrons are excited back to a higher energy level.
Below "Ground State" Transitions of Hydrogen Atoms A novel atomic theory is disclosed in Mills. R., The Grand
Unified Theory of Classical Quantum Mechanics. ( 1995). Technomic Publishing Company, Lancaster, PA provided by HydroCatalysis Power Corporation, Great Valley Corporate Center, 41 Great Valley Parkway, Malvern, PA 19355; The Unification of Spacetime. the Forces. Matter, and Energy. Mills,
R., Technomic Publishing Company, Lancaster, PA, (1992); The Grand Unified Theory. Mills, R. and Farrell, J., Science Press, Ephrata, PA, (1990); Mills, R., Kneizys, S., Fusion Technology, 210, (1991), pp. 65-81 ; Mills, R., Good, W., Shaubach, R., "Dihydrino Molecule Identification", Fusion Technology, 25,
103 (1994); Mills, R., Good, W., "Fractional Quantum Energy Levels of Hydrogen", Fusion Technology, Vol. 28. No. 4, November, ( 1995), pp. 1697-1719, and in my previous U.S. patent applications entitled "Energy/Matter Conversion Methods and Structures", Serial No. 08/467.051 filed on June
6, 1995 which is a continuation-in-part application of Serial No. 08/416,040 filed on April 3, 1995 which is a continuation- in-part application of Serial No. 08/107.357 filed on August 16, 1993, which is a continuation-in-part application of Serial No. 08/075, 102 (Dkt. 99437) filed on June 1 1 , 1993, which is a continuation-in-part application of Serial No. 07/626,496 filed on December 12, 1990 which is a continuation-in-part application of Serial No. 07/345,628 filed April 28, 1989 which is a continuation-in-part application of Serial No. 07/341 ,733 filed April 21 , 1989 which are all incorporated herein by this reference. Fractional Quantum Energy Levels of Hydrogen
A number of experimental observations given in the Experimental Section below lead to the conclusion that atomic hydrogen can exist in fractional quantum states that are at lower energies than the traditional "ground" (n = \ ) state. For example, existence of fractional-quantum-energy-level hydrogen atoms, hereafter called hydrinos . provides an explanation for the soft X-ray emissions of the dark interstellar medium observed by Labov and Bowyer [S. Labov and S. Bowyer, Astrophysical Journal, 371 (1991) 810] and an explanation for the soft X-ray emissions of the Sun [Thomas, R. J., Neupert, W., M., Astrophysical Journal Supplement Series, Vol. 91 , (1994), pp. 461-482; Malinovsky, M., Heroux, L., Astrophysical Journal, Vol. 181 , (1973), pp. 1009-1030; Noyes, R., The Sun. Our Star. Harvard University Press, Cambridge,
MA, (1982), p.172; Phillips, J. H., Guide to the Sun. Cambridge University Press, Cambridge, Great Britain, (1992), pp. 118- 119; 120- 121 ; 144-145].
J. J. Balmer showed in 1885 that the frequencies for some of the lines observed in the emission spectrum of atomic hydrogen could be expressed with a completely empirical relationship. This approach was later extended by J. R. Rydberg, who showed that all of the spectral lines of atomic hydrogen were given by the equation:
where R = 109,677 cm~ nf = 1,2,3,..., H. = 2,3,4,..., and tiι > nf . Niels Bohr, in 1913, developed a theory for atomic hydrogen that gave energy levels in agreement with Rydberg's equation. An identical equation, based on a totally different theory for the hydrogen atom, was developed by E. Schrδdinger, and independently by W. Heisenberg, in 1926.
13.598 eV
E = — (2a) n Sπε..a, n = 1,2,3,... (2b) where aH is the Bohr radius for the hydrogen atom (52.947 pm ), e is the magnitude of the charge of the electron, and ε„ is the vacuum permittivity. Mills' theory predicts that Eq. (2b), should be replaced by Eq. (2c). n = 1,2,3,..., and, n = -,-,-,... (2c)
The quantum number n = \ is routinely used to describe the "ground" electronic state of the hydrogen atom. Mills [Mills, R., The Grand Unified Theory of Classical Quantum Mechanics. (1995), Technomic Publishing Company, Lancaster, PA] in a recent advancement of quantum mechanics has shown that the n = \ state is the "ground" state for "pure" photon transitions (the n = 1 state can absorb a photon and go to an excited electronic state, but it cannot release a photon and go to a lower-energy electronic state). However, an electron transition from the ground state to a lower-energy state is possible by a "resonant collision" mechanism. These lower-energy states have fractional quantum numbers, n = . Processes that occur without photons and that integer require collisions are common. For example, the exothermic chemical reaction of H + H to form H2 does not occur with the emission of a photon. Rather, the reaction requires a collision with a third body, M, to remove the bond energy-
H + H + M → H2 + M. The third body distributes the energy from the exothermic reaction, and the end result is the H2 molecule and an increase in the temperature of the system. Similarly, the n = 1 state of hydrogen and the n = states of integer hydrogen are nonradiative, but a transition between two nonradiative states is possible via a resonant collision, say n = 1 to « = l / 2. In these cases, during the collision the electron couples to another electron transition or electron transfer reaction which can absorb the exact amount of energy that must be removed from the hydrogen atom, a resonant energy sink called an energy hole. The end result is a lower-energy state for the hydrogen and increase in temperature of the system .
Wave Equation Solutions of the Hydrogen Atom Recently, Mills [Mills, R., The Grand Unified Theory of Classical Quantum Mechanics. ( 1995), Technomic Publishing Company, Lancaster, PA] has built on the work generally known as quantum mechanics by deriving a new atomic theory based on first principles. The novel theory hereafter referred to as Mills' theory unifies Maxwell's Equations, Newton's Laws, and Einstein's General and Special Relativity. The central feature of this theory is that all particles (atomic- size and macroscopic particles) obey the same physical laws. Whereas Schrodinger postulated a boundary condition: Ψ → O as r → o, the boundary condition in Mills' theory was derived from Maxwell's equations [Haus, H. A., "On the radiation from point charges", American Journal of Physics, 54, ( 1986), pp. 1 126- 1 129.] :
For non-radiative states, the current-density function must not possess space-time Fourier components that are synchronous with waves traveling at the speed of light.
Application of this boundary condition leads to a physical model of particles, atoms, molecules, and, in the final analysis. cosmology. The closed-form mathematical solutions contain fundamental constants only, and the calculated values for physical quantities agree with experimental observations. In addition, the theory predicts that Eq. (2b), should be replaced by Eq. (2c).
Bound electrons are described by a charge-density (mass-density) function which is the product of a radial delta function ( f(r) = δ(r - rπ)), two angular functions (spherical harmonic functions), and a time harmonic function. Thus, an electron is a spinning, two-dimensional spherical surface, hereafter called an electron orbitsphere. that can exist in a bound state at only specified distances from the nucleus. More explicitly, the orbitsphere comprises a two dimensional spherical shell of moving charge. The corresponding current pattern of the orbitsphere comprises an infinite series of correlated orthogonal great circle current loops. The current pattern (shown in Figure 1.4 of Mills [Mills. R., The Grand Unified Theory of Classical Quantum Mechanics. ( 1995), Technomic Publishing Company, Lancaster, PA]) is generated over the surface by two orthogonal sets of an infinite series of nested rotations of two orthogonal great circle current loops where the coordinate axes rotate with the two orthogonal great circles. Each infinitesimal rotation of the infinite series is about the new x-axis and new y-axis which results from the preceding such rotation. For each of the two sets of nested rotations, the angular sum of the rotations about each rotating x-axis and y-axis totals lπ radians. The current pattern gives rise to the phenomenon corresponding to the spin quantum number. The total function that describes the spinning motion of each electron orbitsphere is composed of two functions. One function, the spin function, is spatially uniform over the orbitsphere, spins with a quantized angular velocity, and gives rise to spin angular momentum. The other function, the modulation function, can be spatially uniform — in which case there is no orbital angular momentum and the magnetic moment of the electron orbitsphere is one Bohr magneton — or not spatially uniform — in which case there is orbital angular momentum. The modulation function also rotates with a quantized angular velocity. Numerical values for the angular velocity, radii of allowed orbitspheres. energies, and associated quantities are calculated by Mills.
Orbitsphere radii are calculated by setting the centripetal force equal to the electric and magnetic forces. The orbitsphere is a resonator cavity which traps photons of discrete frequencies. The radius of an orbitsphere increases with the absorption of electromagnetic energy. The solutions to Maxwell's equations for modes that can be excited in the orbitsphere resonator cavity give rise to four quantum numbers, and the energies of the modes are the experimentally known hydrogen spectrum. Excited states are unstable because the charge-density function of the electron plus photon have a radial doublet function component which corresponds to an electric dipole. The doublet possesses spacetime Fourier components synchronous with waves traveling at the speed of light; thus it is radiative. The charge-density function of the electron plus photon for the n = \ principle quantum state of the hydrogen atom as well as for each of the n = states mathematically integer is purely a radial delta function. The delta function does not possess spacetime Fourier components synchronous with waves traveling at the speed of light; thus, each is nonradiative.
Catalytic Lower-Energy Hydrogen Electronic Transitions Comparing transitions between below "ground"
(fractional quantum) energy states as opposed to transitions between excited (integer quantum) energy states, it can be appreciated that the former are not effected by photons; whereas, the latter are. Transitions are symmetric with respect to time. Current density functions which give rise to photons according to the nonradiative boundary condition of Mills [Mills, R., The Grand Unified Theory of Classical Quantum Mechanics . (1995), Technomic Publishing Company, Lancaster, PA] are created by photons in the reverse process. Excited (integer quantum) energy states correspond to this case. And, current density functions which do not give rise to photons according to the nonradiative boundary condition are not created by photons in the reverse process. Below "ground" (fractional quantum) energy states correspond to this case. But, atomic collisions can cause a stable state to undergo a transition to the next stable state. The transition between two stable nonradiative states effected by a collision with an resonant energy sink is analogous to the reaction of two atoms to form a diatomic molecule vhich requires a third-body collision to remove the bond energy [N. V. Sidgwick, Th e Chemical Elements and Their Compounds. Volume I, Oxford, Clarendon Press, (1950), p.17].
Energy Hole Concept The nonradiative boundary condition of Mills and the relationship between the electron and the photon give the "allowed" hydrogen energy states which are quantized as a function of the parameter n. Each value of n corresponds to an allowed transition effected by a resonant photon which excites the electronic transition. In addition to the traditional integer values (1 , 2. 3,...,) of n, values of fractions are allowed which correspond to transitions with an increase in the central field (charge) and decrease in the size of the hydrogen atom. This occurs, for example, when the electron couples to another electronic transition or electron transfer reaction which can absorb energy, an energy sink. This is the absorption of an energy hole. The absorption of an energy hole destroys the balance between the centrifugal force and the increased central electric force. As a result, the electron undergoes a transition to a lower energy nonradiative state.
From energy conservation, the resonance energy hole of a hydrogen atom which excites resonator modes of radial dimensions — — is
772 + 1 m X 27.2 eV (3) where m = 1,2,3,4,...
After resonant absorption of the energy hole, the radius of the orbitsphere, a„, shrinks to — — and after p cycles of resonant + 1 shrinkage, the radius is — tL— . In other words, the radial ground state field can be mp + 1 considered as the superposition of Fourier components. The removal of negative Fourier components of energy m X 27.2 eV, where rn is an integer increases the positive central electric field inside the spherical shell b rn times the charge of a proton. The resultant electric field is a time-harmonic solution of Laplace's Equations in spherical coordinates. In this case, the radius at which force balance and nonradiation are a. achieved is where m is an integer. In decaying to this
777 + 1 radius from the "ground" state, a total energy of [(m + l)2 - l2]X\3.6 eV is released. The transition between two stable nonradiative states effected by a collision with an energy hole is analogous to the reaction of two atoms to form a diatomic molecule which requires a third body collision to remove the bond energy [N. V. Sidgwick, The Chemical Elements and Their Compounds. Volume I, Oxford, Clarendon Press, (1950), p.17]. The total energy well of the hydrogen atom is shown in FIGURE 1. The exothermic reaction involving transitions from one potential energy level to a lower level is hereafter referred to as HvdroCatalvsis.
A hydrogen atom with its electron in a lower than "ground state" energy level corresponding to a fractional quantum number is hereafter referred to as a hvdrino atom.
The designation for a hydrino atom of radius — where p is an
P integer is H
The size of the electron orbitsphere as a function of potential energy is given in FIGURE 2.
An efficient catalytic system that hinges on the coupling of three resonator cavities involves potassium. For example, the second ionization energy of potassium is 31.63 eV. This energy hole is obviously too high for resonant absorption. However, K+ releases 4.34 eV when it is reduced to K. The combination of K+ to K2+ and K+ to K, then, has a net energy change of 27.28 eV. a.
27.28 eV + K+ + K+ + H → K + K" + H\ + [(p + l - p2]X\3.6 eV
(p + \)
(4)
K + K2+ → K+ + K+ + 27.28 eV (5 ) And, the overall reaction is
H - p2]Xl3.6 eV (6) Note that the energy given off as the atom shrinks is much greater than the energy lost to the energy hole. Also, the energy released is large compared to conventional chemical reactions.
Disproportionation of Energy States
Lower-energy hydrogen atoms, hydrinos. can act as a source of energy holes that can cause resonant shrinkage because the excitation and/or ionization energies are m X 27.2 eV (Eq. (3)). For example, the equation for the absorption of an energy hole of 27.21 eV, m = \ in Eq. (3), during the shrinkage cascade for the third cycle of the hydrogen-type . atom, H with the hydrogen-type atom, H that is ionized as the source of energy holes that cause resonant shrinkage is represented by a a.
27.21 eV + H + HI → H+ + e~ + H + [42 - 32]Z13.6 eV - 27.21 eV
(7)
H+ + e~ → H + 13.6 eV (8)
And, the overall reaction is H + [42 - 32 - 4]X13.6 eV + 13.6 eV (9)
The general equation for the absorption of an energy hole of 27.21 eV, cascade for the pth cycl with the hydrogen-type atom, H that is ionized as the source of m resonant shrinkage is represented by
→ H+ + e~ + H eV- (m'2 -2)X\3.6 eV
( 1 0)
H+ + e~ → H + 13.6 *V ( 1 1 ) And, the overall reacti (12)
H eV + 13.6 eV
Transitions to nonconsecutive energy levels involving the absorption of an energy hole of an integer multiple of 27.21 eV are possible. Lower-energy hydrogen atoms, hydrinos. can act as a source of energy holes that can cause resonant shrinkage with the absorption of an energy hole of mX21.2eV (Eq. (3)). Thus, the shrinkage cascade for the pth cycle of the hydrogen-type atom, H , with the hydrogen- . type atom, H that is ionized as the source of energy holes m that cause resonant shrinkage is represented by
H++e~→H + 13.6eV (14)
And, the overall reaction is a. a.
H ■ →H + H + [2pm + m2 -/77,2]X13.6 gV + 13.6 eV m (p + m)
(15)
Hydrogen is a source of energy holes. The ionization energy of hydrogen is 13.6 eV. Disproportionation can occur between three hydrogen atoms whereby two atoms provide an energy hole of 27.21 eV for the third hydrogen atom. Thus, the shrinkage cascade for the pth cycle of the hydrogen-type with two hydrogen atoms, H\ as the source of energy holes that cause resonant shrinkage is represented by α*
27.21 eV + 2H + H → 2H+ + 2e~ + H a
+ [(p + l)2-p2]Xl3.6eV
(p + \)
(16)
2H++2e"→2H =3- 1 + 27.21 eV (17) And, the overall reaction is
The spectral lines from dark interstellar medium and the majority of the solar power can be attributed to disproportionation reactions as given in the Spectral Data of Hydrinos from the Dark Interstellar Medium and from the Sun Section of Mills [Mills, R., The Grand Unified Theory of Classical Quantum Mechanics. (1995), Technomic Publishing Company, Lancaster, PA]. This assignment resolves the mystery of dark matter, the solar neutrino problem, and the mystery of the cause of sunspots and other solar activity and why the Sun emits X-rays. It also provides the reason for the abrupt change in the speed of sound and transition from "radiation zone" to "convection zone" at a radius of 0.7 the solar radius, 0.1RS as summarized in Example 4 below.
Energy Hole (Atomic Hydrogen
In a preferred embodiment, energy holes, each of approximately 27.21 eV, are provided by electron transfer reactions of reactants including electrochemical reactant(s) (electrocatalytic ion(s) or couple(s)) which cause heat to be released from hydrogen atoms as their electrons are stimulated to relax to quantized potential energy levels below that of the "ground state". The energy removed by an electron transfer reaction, energy hole, is resonant with the hydrogen energy released to stimulate this transition. The source of hydrogen atoms can be the production on the surface of a cathode during electrolysis of water in the case of an electrolytic energy reactor and hydrogen gas or a hydride in the case of a pressurized gas energy reactor or gas discharge energy reactor.
Below "Ground State" Transitions of Hydrogen-Type Molecules and Molecular Ions
Two hydrogen atoms react to form a diatomic molecule, the hydrogen molecule. 2H[aH] → H2[2c' = j2a„] ( 19 where 2c' is the internuclear distance. Also, two hydrino atoms react to form a diatomic molecule, hereafter called a dihydrino molecule.
where p is an integer.
The central force equation for hydrogen-type molecules has orbital solutions which are circular, elliptic, parabolic, or hyperbolic. The former two types of solutions are associated with atomic and molecular orbitals. These solutions are nonradiative if the boundary condition for nonradiation given in the One Electron Atom Section of The Unification of Spacetime. the Forces. Matter, and Energy. Mills, R., Technomic Publishing Company, Lancaster, PA, (1992), is met. The mathematical formulation for zero radiation is that the function that describes the motion of the electron must not possess space-time Fourier components that are synchronous with waves traveling at the speed of light. The boundary condition for the orbitsphere is met when the angular frequencies are ω n =- 2- (21 ) mern As demonstrated in the One Electron Atom Section of Th e Unification of Spacetime. the Forces. Matter, and Energy. Mills, R., Technomic Publishing Company, Lancaster, PA, (1992), this condition is met for the product function of a radial Dirac delta function and a time harmonic function where the angular frequency, ω, is constant and given by Eq. (21). πL , = m n = ^ A (22) where L is the angular momentum and A is the area of the closed geodesic orbit. Consider the solution of the central force equation comprising the product of a two dimensional ellipsoid and a time harmonic function. The spatial part of the product function is the convolution of a radial Dirac delta function with the equation of an ellipsoid. The Fourier transform of the convolution of two functions is the product of the individual Fourier transforms of the functions: thus, the boundary condition is met for an ellipsoidal-time harmonic function wh en πfr h
<yn = = ( 23) meA meab J where the area of an ellipse is
A = πab (24) where 2b is the length of the semiminor axis and 2a is the length of the semimajor axis. The geometry of molecular hydrogen is elliptic with the internuclear axis as the principle axis; thus, the electron orbital is a two dimensional ellipsoidal- time harmonic function. The mass follows geodesies time harmonically as determined by the central field of the protons at the foci. Rotational symmetry about the internuclear axis further determines that the orbital is a prolate spheroid. In general, ellipsoidal orbits of molecular bonding, hereafter referred to as ellipsoidal molecular orbitals (M. O. 's), have the general equation
a' + 4 b' + c~ = 1 (25)
The semiprinciple axes of the ellipsoid are a. b, c.
An ellipsoidal M. O. is equivalent to a charged conductor whose surface is given by Eq. (25). It carries a total charge q, and it's potential is a solution of the Laplacian in ellipsoidal coordinates, Eq. (26).
Excited states of orbitspheres are discussed in the Excited States of the One Electron Atom (Quantization) Section of The Unification of Spacetime. the Forces. Matter, and
Energy. Mills, R., Technomic Publishing Company, Lancaster, PA, (1992). In the case of ellipsoidal M. O. 's, excited electronic states are created when photons of discrete frequencies are trapped in the ellipsoidal resonator cavity of the M. O. The photon changes the effective charge at the M. O. surface where the central field is ellipsoidal. Force balance is achieved at a series of ellipsoidal equipotential two dimensional surfaces confocal with the ground state ellipsoid. The trapped photons are solutions of the Laplacian in ellipsoidal coordinates, Eq. (26).
As is the case with the orbitsphere, higher and lower energy states are equally valid. The photon standing wave in both cases is a solution of the Laplacian in ellipsoidal coordinates. For an ellipsoidal resonator cavity, the relationship between an allowed circumference, 4 E, and the photon standing wavelength, λ, is
AaE = nλ (27 ) where n is an integer and where * = — (28) is used in the elliptic integral E of Eq. (27). Applying Eqs. (27) and (28), the relationship between an allowed angular frequency given by Eq. (23) and the photon standing wave angular frequency, ω, is: —7 = - = ■r = — co] = ωn (29) meA mena,nbχ meanbn n where 77 = 1,2,3,4,...
co, is the allowed angular frequency for 7 = 1 α, and b, are the allowed semimajor and semiminor axes for 77 = 1
From Eq. (29), the magnitude of the elliptic field corresponding to a below "ground state" transition of the hydrogen molecule is an integer. The potential energy equations
y - P , g2 ( 3 1 )
w h ere a = (32)
and where p is an integer. From energy conservation, the resonance energy hole of a hydrogen-type molecule which causes the transition
i s m/?2X 48.6 eV (36) where rn and p are integers. During the transition, the elliptic field is increased from magnitude p to magnitude p + m . The corresponding potential energy change equals the energy absorbed by the energy hole.
Energy hole = -Ve - V = mpl X 48.6 e V (37)
Further energy is released by the hydrogen-type molecule as the internuclear distance "shrinks". The total energy, Eτ, released during the transition is
(38)
A schematic drawing of the total energy well of hydrogen-type molecules and molecular ions is given in FIGURE 3. The exothermic reaction involving transitions from one potential energy level to a lower level below the "ground state" is also hereafter referred to as ΗydroCatalysis .
A hydrogen-type molecule with its electrons in a lower than "ground state" energy level corresponding to a fractional quantum number is hereafter referred to as a dihvdri no molecule . The designation for a dihydrino molecule of F5 internuclear distance, 2c' = °- where p is an integer, is
P
H A schematic drawing of the size of hydrogen- type molecules as a function of total energy is given in FIGURE 4. The magnitude of the elliptic field corresponding to the first below "ground state" hydrogen-type molecule is 2. From energy conservation, the resonance energy hole of a hydrogen molecule which excites the transition of the hydrogen molecule with internuclear distance 2c' = V2α0 to the first below "ground state" with internuclear distance 2c' = -j=a0 is given by
V2
Eqs. (30) and (31) where the elliptic field is increased from magnitude =-67.813 eV (39)
Energy hole = -Ve - Vp = m X 48.6 eV (41 )
In other words, the ellipsoidal "ground state" field of the hydrogen molecule can be considered as the superposition of Fourier components. The removal of negative Fourier components of energy mXA8.6 eV (42 ) where m is an integer, increases the positive electric field inside the ellipsoidal shell by m times the charge of a proton at each focus. The resultant electric field is a time harmonic solution of the Laplacian in ellipsoidal coordinates. The hydrogen molecule with internuclear distance 2c' = -v/2α„ is caused to undergo a transition to a below "ground state" level, and the internuclear distance for which force balance and nonradiation are achieved is 2c' = '-. In decaying to this
1 + m internuclear distance from the " round state", a total energy of is released.
(43) Energy Hole (Molecular Hydrogen)
In a preferred embodiment, energy holes, each of approximately mX48.6 eV\ are provided by electron transfer reactions of reactants including electrochemical reactant(s) (electrocatalytic ion(s) or couple(s)) which cause heat to be released from hydrogen molecules as their electrons are stimulated to relax to quantized potential energy levels below that of the "ground state". The energy removed by an electron transfer reaction, energy hole, is resonant with the hydrogen energy released to stimulate this transition. The source of hydrogen molecules can be the production on the surface of a cathode during electrolysis of water in the case of an electrolytic energy reactor and hydrogen gas or a hydride in the case of a pressurized gas energy reactor or gas discharge energy reactor.
Energy Reactor
The present invention of an electrolytic cell energy reactor, pressurized gas energy reactor, and a gas discharge energy reactor, comprises: a source of hydrogen; one of a solid, molten, liquid, and gaseous source of energy holes; a vessel containing hydrogen and the source of energy holes wherein the shrinkage reaction occurs by contact of the hydrogen with the source of energy holes; and a means for removing the (molecular) lower-energy hydrogen so as to prevent the exothermic shrinkage reaction from coming to equilibrium. The shrinkage reaction rate and let power output are increased by conforming the energy hole to match the resonance shrinkage energy. In general, power output can be optimized by controlling the temperature, pressure of the hydrogen gas, the source of the energy hole including the electrocatalytic ion or couple which provides the energy hole, the counterion of the electrocatalytic ion or couple, and the area of the surface on which the shrinkage reaction occurs. The present invention further comprises a hydrogen spillover catalyst, a multifunctionality material having a functionality which dissociates molecular hydrogen to provide free hydrogen atoms which spill over to a functionality which supports mobile free hydrogen atoms and a functionality which can be a source of the energy holes.
A preferred pressurized hydrogen gas energy reactor comprises a vessel; a source of hydrogen; a means to control the pressure and flow of hydrogen into the vessel; a material to dissociate the molecular hydrogen into atomic hydrogen, and a material which can be a source of energy holes in the gas phase. The gaseous source of energy holes includes those that sublime, boil, and/or are volatile at the elevated operating temperature of the gas energy reactor wherein the shrinkage reaction occurs in the gas phase.
Other objects, features, and characteristics of the present invention, as well as the methods of operation and the functions of the related elements, will become apparent upon consideration of the following description and the appended claims with reference to the accompanying drawings, all of which form a part of this specification, wherein like reference numerals designate corresponding parts in the various figures.
BRIEF DESCRIPTION OF THE DRAWINGS
FIGURE 1 is a schematic drawing of the total energy well of the hydrogen atom;
FIGURE 2 is a schematic drawing of the size of electron orbitspheres as a function of potential energy; FIGURE 3 is a schematic drawing of the total energy wells of the hydrogen molecule, H2[2c' = V2fl0], the hydrogen molecular ion, H2[2c' = 2<3„]+, the dihydrino molecule, H2 2c' = and the dihydrino molecular
V2
FIGURE 4 is a schematic drawing of the size of hydrogen- type molecules, as a function of total energy;
FIGURE 5 is a schematic drawing of an energy reactor in accordance with the invention;
FIGURE 6 is a schematic drawing of an electrolytic cell energy reactor in accordance with the present invention; FIGURE 7 is a schematic drawing of a pressurized gas energy reactor in accordance with the present invention;
FIGURE 8 is a schematic drawing of a gas discharge energy reactor in accordance with the invention; and
FIGURE 9 is a plot of the excess heat release from flowing hydrogen in the presence of nickel oxide powder containing strontium niobium oxide (Nb3+ / Sr2* electrocatalytic couple) by the very accurate and reliable method of heat measurement, thermopile conversion of heat into an electrical output signal.
DETAILED DESCRIPTION OF THE PRESENTLY PREFERRED
EMBODIMENTS
CATALYTIC ENERGY HOLE STRUCTURES FOR ATOMS
Single Electron Excited State
An energy hole is provided by the transition of an electron of a species to an excited state species including a continuum excited state(s) of atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the excited state transition of an electron of one species whereby the transition energy of the accepting species equals approximately mX21.2\ eV where m is an integer. Single Electron Transfer
An energy hole is provided by the transfer of an electron between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of an electron from one species to another species whereby the sum of the ionization energy of the electron donating species minus the ionization energy or electron affinity of the electron accepting species equals approximately mX21.2\ eV where m is an integer.
Single Electron Transfer (Two Species')
An efficient catalytic system that hinges on the coupling of three resonator cavities involves potassium. For example, the second ionization energy of potassium is 31.63 eV. This energy hole is obviously too high for resonant absorption. However, K+ releases 4.34 eV when it is reduced to K. The combination of K+ to K2+ and K* to K, then, has a net energy
l)2 - p2]Xl3.6 eV
(44)
K + K2+ → K+ + K+ + 27.28 eV (45) And, the overall reaction is
Note that the energy given off as the atom shrinks is much greater than the energy lost to the energy hole. And, the energy released is large compared to conventional chemical reactions.
For sodium or sodium ions no electrocatalytic reaction of approximately 27.21 eV is possible. For example, 42.15 eV of energy is absorbed by the reverse of the reaction given in Eq. (45) where Na* replaces K+ :
Na+ + Na+ + A2Λ5 eV → Na + Na2+ (47 )
Other less efficient catalytic systems hinge on the coupling of three resonator cavities. For example, the third ionization energy of palladium is 32.93 eV. This energy hole is obviously too high for resonant absorption. However, Li* releases 5.392 eV when it is reduced to Li. The combination of Pd2+ to Pd3+ and Li+ to Li, then, has a net energy change of 27.54 eV.
(48)
Li + Pd + → Li* + Pd2+ + 27.54 eV (49) And, the overall reaction is
Single Electron Transfer (One Species)
An energy hole is provided by the ionization of an electron from a participating species including an atom, an ion, a molecule, and an ionic or molecular compound to a vacuum energy level. In one embodiment, the energy hole comprises the ionization of an electron from one species to a vacuum energy level whereby the ionization energy of the electron donating species equals approximately mX21.2\ eV where m is an integer.
Titanium is one of the catalysts (electrocatalytic ion) that can cause resonant shrinkage because the third ionization energy is 27.49 eV, m = \ in Eq. (3). Thus, the shrinkage cascade for the pth cycle is represented by α_
27.491 eV + TX + H → 7r+ +e- + H + [(p + \)2 - p2]X\3.6 eV
(P + D
(5 1 )
T?+ + e~ → Ti2+ + 27.491 eV And, the overall reaction is (52)
Rubidium is a so a cata yst (e ectrocatalytic ion). The second ionization energy is 27.28 eV.
27.28 eV + Rb+ + H → Rb + e~ + H + [(P + .Ϋ p2]Xl3.6 eV
(p + ) (54) Rb2+ + e~ → Rb+ +27.28 eV (55)
And, the overall reaction is
H + [(p + lγ - p2]Xl3.6 eV (56)
Other single electron transfer reactions to provide energy holes of approximately mX27.2\ eV where m is an integer appear in my previous U.S. Patent Applications entitled "Energy/Matter Conversion Methods and Structures", Serial No. 08/467,051 filed on June 6, 1995 which is a continuation-in-part application of Serial No. 08/416,040 filed on April 3, 1995 which is a continuation-in-part application of Serial No. 08/107,357 filed on August 16, 1993, which is a continuation-in-part application of Serial No. 08/075,102 (Dkt. 99437) filed on June 11, 1993, which is a continuation-in-part application of Serial No. 07/626,496 filed on December 12, 1990 which is a continuation-in-part application of Serial
No. 07/345,628 filed April 28, 1989 which is a continuation- in-part application of Serial No. 07/341 ,733 filed April 21, 1989, which are incorporated herein by reference.
Multiple Electron Transfer
An energy hole is provided by the transfer of multiple electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximately mX21.2\ eV where m and t are integers.
An energy hole is provided by the transfer of multiple electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of t electrons from one species to another whereby the t consecutive electron affinities and/or ionization energies of the electron donating species minus the t consecutive ionization energies and/or electron affinities of the electron acceptor equals approximately mX21.2\ eV where m and t are integers .
In a preferred embodiment the electron acceptor species is an oxide such as MnOx, AlOx, SiOx. A preferred molecular electron acceptor is oxygen, O2.
Two Electron Transfer (One Species')
In an embodiment, a catalytic system that provides an energy hole hinges on the ionization of two electrons from an atom, ion, or molecule to a vacuum energy level such that the sum of two ionization energies is approximately 27.21 eV. Zinc is one of the catalysts (electrocatalytic atom) that can cause resonant shrinkage because the sum of the first and second ionization energies is 27.358 eV, m = 1 in Eq. (3). Thus, the shrinkage casc
27.358 eV + Zn +
And, the overall reaction is (58 )
Two Electron Transfer (Two Species')
In another embodiment, a catalytic system that provides an energy hole hinges on the transfer of two electrons from an atom, ion, or molecule to another atom or molecule such that the sum of two ionization energies minus the sum of two electron affinities of the participating atoms, ions, and/or molecules is approximately 27.21 eV. A catalytic system that hinges on the transfer of two electrons from an atom to a molecule involves palladium and oxygen. For example, the first and second ionization energies of palladium are 8.34 eV and 19.43 eV, respectively. And, the first and second electron affinities of the oxygen molecule are 0.45 eV and 0.1 1 eV, respectively. The energy hole resulting from a two electron transfer is appropriate for resonant absorption. The combination of Pd to Pd2+ and O2 to O2 ~ , then, has a net energy change of 27.21 eV.
27.21 eV + Pd + Oτ + 3.6 eV
(60)
Pd2* + O → Pd + 02 + 27.21 eV (61 )
And, the overall reaction is - p:]Xl3.6 eV (62)
Additional atoms, molecules, or compounds which could be substituted for O2 are those with first and second electron affinities of approximately 0.45 eV and 0.11 eV, respectively, such as a mixed oxide (MnOx, AlOx, SiOx) containing O to form
Two Electron Transfer (Two Species')
In another embodiment, a catalytic system that provides an energy hole hinges on the transfer of two electrons from an atom, ion, or molecule to another atom, ion, or molecule such that the sum of two ionization energies minus the sum of one ionization energy and one electron affinity of the participating atoms, ions, and/or molecules is approximately 27.21 eV. A catalytic system that hinges on the transfer of two electrons from an atom to an ion involves xenon and lithium. For example, the first and second ionization energies of xenon are 12.13 eV and 21.21 eV, respectively. And, the first ionization energy and the first electron affinity of lithium are 5.39 eV and 0.62 eV, respectively. The energy hole resulting from a two electron transfer is appropriate for resonant absorption. The combination of Xe to Xe2* and Li* to Li', then, has a net energy change of 27.33 eV.
27.33 eV + Xe + U* eV
(63) Xe2* + LX → Xe + Li* + 27.33 eV (64) And, the overall reaction is
H → + [(p + l)2 - p2]Xl3.6 eV (65)
Two Electron Transfer (Two Species')
In another embodiment, a catalytic system that provides an energy hole hinges on the transfer of two electrons from an atom, ion, or molecule to another atom, ion, or molecule such that the sum of two ionization energies minus the sum of two ionization energies of the participating atoms and/or molecules is approximately 27.21 eV. A catalytic system that hinges on the transfer of two electrons from a first ion to a second ion involves silver( Ag*) and silver (Ag2*). For example, the second and third ionization energies of silver are 21.49 eV and 34.83 eV, respectively. And, the second and first ionization energies of silver are 21.49 eV and 7.58 eV, respectively. The energy hole resulting from a two electron transfer is appropriate for resonant absorption. The combination of Ag* to Ag3* and Ag2* to Ag, then, has a net energy change of 27.25 eV.
eV
(66)
Ag3* + Ag → Ag* + Ag-' +27.25 eV (67) And, the overall reaction is
Three Electron Transfer (Two Species) In another embodiment, a catalytic system that provides an energy hole hinges on the transfer of three electrons from an ion to another ion such that the sum of the electron affinity and two ionization energies of the first ion minus the sum of three ionization energies of the second ion is approximately 27.21 eV. A catalytic system that hinges on the transfer of three electrons from an ion to a second ion involves Li' and Cr3*. For example, the electron affinity, first ionization energy, and second ionization energy of lithium are 0.62 eV, 5.392 eV, and 75.638 eV, respectively. And, the third, second, and first ionization energies of Cr3* are 30.96 eV, 1 6.50 eV, and 6.766 eV, respectively. The energy hole resulting from a three electron transfer is appropriate for resonant absorption. The combination of Li' to Li2* and Cr3* to Cr, then, has a net energy change of 27.42 eV.
27.42 eV + LF + CX + H → Li2* + Cr
Li1* + Cr → LF + Cr' 3*+ + 27.42 eV (70)
And, the overall reaction is
Three Electron Transfer (Two Species) In another embodiment, a catalytic system that provides an energy hole hinges on the transfer of three electrons from an atom, ion, or molecule to another atom, ion, or molecule such that the sum of three consecutive ionization energies of the electron donating species minus the sum of three consecutive ionization energies of the electron accepting species is approximately 27.21 eV. A catalytic system that hinges on the transfer of three electrons from an atom to an ion involves Ag and Ce3*. For example, the first, second, and third ionization energies of silver are 7.58 eV, 21.49 eV, and 34.83 eV, respectively. And, the third, second, and first ionization energies of Ce3* are 20.20 eV, 10.85 cV, and 5.47 eV, respectively. The energy hole resulting from a three electron transfer is appropriate for resonant absorption. The combination of Ag to Ag3* and Ce3* to Ce, then, has a net energy change of 27.38 eV. a„
27.38 eV + Ag + Ce3* + H\ → Ag'* + Ce
Ag3* + Ce → Ag And, the overall reaction is α.
H → H + [(p + l)2 - p2]Xl3.6 eV (74)
(P + D
ADDITIONAL CATALYTIC ENERGY HOLE STRUCTURES
Single Electron Transfer
In a further embodiment, an energy hole of energy equal to the total energy released for a below "ground state" electronic transition of the hydrogen atom is provided by the transfer of an electron between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of an electron from one species to another species whereby the sum of the ionization energy of the electron donating species minus the ionization energy or electron affinity of the electron m accepting species equals approximately —27.21 eV; where m is an integer.
For m = 3 corresponding to the 77 = 1 to 77 = 1 / 2 transition, an efficient catalytic system that hinges on the coupling of three resonator cavities involves arsenic and calcium. For example, the third ionization energy of calcium is 50.908 eV. This energy hole is obviously too high for resonant absorption. However, As* releases 9.81 eV when it is reduced to As. The combination of Ca2* to Ca3* and As* to As, then, has a net energy change of 41.1 eV. a„ A eV + As* + Ca2* + H\ → As + Ca' 3*+ + H + [(p + })2 - p2]X\3.6 eV
(p + \)
(75)
As + Ca^* → As* + Ca2* + A\Λ eV (76) And, the overall reaction is
Multiple Electron Transfer An energy hole is provided by the transfer of multiple electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximately —27.21 eV where m and t are integers.
CATALYTIC ENERGY HOLE STRUCTURES FOR MOLECULES
Single Electron Excited State
An energy hole is provided by the transition of an electron of a species to an excited state species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the excited state transition of an electron of one species whereby the transition energy of the accepting species is mp2XA8.6 eV where m and p are integers.
Single Electron Transfer
An energy hole is provided by the transfer of an electron between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of an electron from one species to another species whereby the sum of the ionization energy of the electron donating species minus the ionization energy or electron affinity of the electron accepting species equals approximately mp2XA8.6 eV where m and p are integers.
Single Electron Transfer (Two Species)
An efficient catalytic system that hinges on the coupling of three resonator cavities involves iron and lithium. For example, the fourth ionization energy of iron is 54.8 eV. This energy hole is obviously too high for resonant absorption. However, Li* releases 5.392 eV when it is reduced to Li . The combination of Fe3* to Fe4* and Li* to Li , then, has a net energy change of 49.4 eV .
49.4 eV + Fe3* + Li*.+ H2[2c' = /2O,] → Fe4' + Li + H* n 2c '' + 95.7 eV
(78 )
Li + Fe4* → Li* + Fe3' + 49.4 eV (79) And, the overall reaction is
Note that the energy given off as the molecule shrinks is much greater than the energy lost to the energy hole. And, the energy released is large compared to conventional chemical reactions.
An efficient catalytic system that hinges on the coupling of three resonator cavities involves scandium. For example, the fourth ionization energy of scandium is 73.47 eV. This energy hole is obviously too high for resonant absorption. However, Sc3* releases 2A.76 eV when it is reduced to Sc2*. The combination of Sc3* to Sc4* and Sc3* to Sc2*, then, has a net energy change of 48.7 eV.
48.7 eV + Sc3* + Sc3* + H2[2c' - 2o ,] → Sc4' eV
( 8 1 )
Sc2* + Sc4* → Sc3* + Sc3* + 48.7 eV ( 82) And, the overall reaction is
\2fl„
H2[2c' = V2.70] → H2 * 2c' = + 95.7 eV (83 ) An efficient catalytic system that hinges on the coupling of three resonator cavities involves yttrium. For example, the fourth ionization energy of gallium is 64.00 eV. This energy hole is obviously too high for resonant absorption. However, Pb2* releases 15.03 eV when it is reduced to Pb*. The combination of Ga3* to Ga4* and Pb2* to Pb*, then, has a net energy change of 48.97 eV.
48.97 eV + Ga3* + Pb2* + H2[2c' = ^2a0] → Ga4* + Pb*
Ga4* + Pb* → Ga3* + Pb2* + 48.9 And, the overall reaction is
Single Electron Transfer (One Species)
An energy hole is provided by the ionization of an electron from a participating species including an atom, an ion, a molecule, and an ionic or molecular compound to a vacuum energy level. In one embodiment, the energy hole comprises the ionization of an electron from one species to a vacuum energy level whereby the ionization energy of the electron donating species equals approximately mp2XA8.6 eV where m and p are integers.
Multiple Electron Transfer
An energy hole is provided by the transfer of multiple electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximately mp2XA8.6 eV where m, p, and t are integers. An energy hole is provided by the transfer of multiple electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of t electrons from one species to another whereby the t consecutive electron affinities and/or ionization energies of the electron donating species minus the t consecutive ionization energies and/or electron affinities of the electron acceptor equals approximately mp2XA8.6 eV where m, p, and t are integers.
In a preferred embodiment the electron acceptor species is an oxide such as MnOx, AlOx, SiOx. A preferred molecular electron acceptor is oxygen, O2.
Two Electron Transfer (One Species)
In an embodiment, a catalytic system that provides an energy hole hinges on the ionization of two electrons from an atom, ion, or molecule to a vacuum energy level such that the sum of two ionization energies is approximately mp2XA8.6 eV where m, and p are integers.
Two Electron Transfer (Two Species)
In another embodiment, a catalytic system that provides an energy hole hinges on the transfer of two electrons from an atom, ion, or molecule to another atom or molecule such that the sum of two ionization energies minus the sum of two electron affinities of the participating atoms, ions, and/or molecules is approximately mp2XA8.6 eV where m and p are integers.
Two Electron Transfer (Two Species)
In another embodiment, a catalytic system that provides an energy hole hinges on the transfer of two electrons from an atom, ion, or molecule to another atom, ion, or molecule such that the sum of two ionization energies minus the sum of one ionization energy and one electron affinity of the participating atoms, ions, and/or molecules is approximately mp2XA8.6 eV where m and p are integers.
Other Energy Holes In another embodiment, energy holes, each of approximately
are provided by electron transfer reactions of reactants including electrochemical reactant(s) (electrocatalytic ion(s) or couple(s)) which cause heat to be released from hydrogen molecules as their electrons are stimulated to relax to quantized potential energy levels below that of the "ground state". The energy removed by an electron transfer reaction, energy hole, is resonant with the hydrogen energy released to stimulate this transition. The source of hydrogen molecules is the production on the surface of a cathode during electrolysis of water in the case of an electrolytic energy reactor and hydrogen gas or a hydride in the case of a pressurized gas energy reactor or gas discharge energy reactor.
An energy hole is provided by the transfer of one or more electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximately mX67.8 eV where m and t are integers.
An efficient catalytic system that hinges on the coupling of three resonator cavities involves magnesium and strontium. For example, the third ionization energy of magnesium is 80.143 eV. This energy hole is obviously too high for resonant absorption. However, 5r2+ releases 1 1.03 cV when it is reduced to Sr* . The combination of Mg2* to Mg3* and Sr2* to Sr* , then, has a net energy change of 69.1 eV.
69.1 eV + Mg2* + Sr2* + H2[2c' = 2α„] →
( 88)
Mg3* + Sr* → Mg2* + Sr' + 69.1 eV (89) And, the overall reaction is
H2[2c' = V2αβ] → H 2c = + 95.7 eV (90)
Another efficient catalytic system that hinges on the coupling of three resonator cavities involves magnesium and calcium. In this case, Ca2* releases 11.871 eV when it is reduced to Ca*. The combination of Mg2* to Mg3* and Ca2* to Ca*, then, has a net energy change of 68.2 eV.
68.2 eV + Mg2* + Ca2* + H2[2c' = V2αβ] → Mg3'
(91 )
Mg3* + Ca* → Mg2' + Ca2* + 68.2 eV (92) And, the overall reaction is
H2[2c' = V2α0] → 95.7 eV (93 )
In four other embodiments wherein the theory is given in my previous U. S. patent application. Serial No. 08/107,357 filed on August 16, 1993 which is incorporated herein by this reference, energy holes, each of approximately: nXEτ eV with zero order vibration where Eτ is given by Eq. (38); mX3\.9 eV where 31.94 eV is given by Eq. (222) of the U. S. patent application Serial No. 08/107,357 where n and m are integers,
ED D = E(2H[ Lα„" ]J)- ET 'zero order 2 -^ = -27.21 + 31.94 = 4.73c V (222) an d
95.7 eV (corresponding to m = l in Εq. (43) with zero order vibration which is given by the difference in - Eτ εero order — of Eqs. (254) and (222) of the U. S. patent application Serial No. 08/ 107, 357))
<2„
ED = E(2H ) _ £_ zero order - -^ = -108.8 + 127.66 = 18.86 c ( 254) are provided by electron transfer reactions of reactants including electrochemical reactant(s) (electrocatalytic ion(s) or couple(s)) which cause heat to be released from hydrogen molecules as their electrons are stimulated to relax to quantized potential energy levels below that of the "ground state". The energy removed by an electron transfer reaction, energy hole, is resonant with the hydrogen energy released to stimulate this transition. The source of hydrogen molecules is the production on the surface of a cathode during electrolysis of water in the case of an electrolytic energy reactor and hydrogen gas or a hydride in the case of a pressurized gas energy reactor or gas discharge energy reactor.
An energy hole is provided by the transfer of one or more electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximately mX3\.9A eV (Εq. (222)) where m and t are integers.
An energy hole is provided by the transfer of one or more electrons between participating species including atoms, ions, molecules, and ionic and molecular compounds. In one embodiment, the energy hole comprises the transfer of t electrons from one or more species to one or more species whereby the sum of the ionization energies and/or electron affinities of the electron donating species minus the sum of the ionization energies and/or electron affinities of the electron acceptor species equals approximr ely mX95.1 eV where m and t are integers. ENERGY REACTOR
An energy reactor 50, in accordance with the invention, is shown in FIGURE 5 and comprises a vessel 52 which contains an energy reaction mixture 54, a heat exchanger 60, and a steam generator 62. The heat exchanger 60 absorbs heat released by the shrinkage reaction, when the reaction mixture, comprised of shrinkable material, shrinks. The heat exchanger exchanges heat with the steam generator 62 which absorbs heat from the exchanger 60 and produces steam. The energy reactor 50 further comprises a turbine 70 which receives steam from the steam generator 62 and supplies mechanical power to a power generator 80 which converts the steam energy into electrical energy, which can be received by a load 90 to produce work or for dissipation. The energy reaction mixture 54 comprises an energy releasing material 56 including a source of hydrogen isotope atoms or a source of molecular hydrogen isotope, and a source of energy holes 58 which resonantly remove approximately mX27.2\ eV to cause atomic hydrogen "shrinkage" and approximately m 48.6 eV to cause molecular hydrogen
"shrinkage" where m is an integer wherein the shrinkage reaction occurs by contact of the hydrogen with the source of energy holes. The shrinkage reaction releases heat and shrunken atoms and/or molecules. The source of hydrogen can be hydrogen gas, dissociation of water including thermal dissociation, electrolysis of water, hydrogen from hydrides, or hydrogen from metal-hydrogen solutions. In all embodiments, the source of energy holes can be one or more of an electrochemical, chemical, photochemical, thermal, free radical, sonic, or nuclear reaction(s) or inelastic photon or particle scattering reaction(s). In the latter two cases, the present invention of an energy reactor comprises a particle source 75b and/or photon source 75a to supply the said energy holes. In these cases, the energy hole co responds to stimulated emission by the photon or particle. In preferred embodiments of the pressurized gas energy and gas discharge reactors shown in FIGURES 7 and 8, respectively, a photon source 75a dissociates hydrogen molecules to hydrogen atoms. The photon source producing photons of at least one energy of m approximately mX27.2\ eV, — 27.21 eV, or 40.8 eV causes stimulated emission of energy as the hydrogen atoms undergo the shrinkage reaction. In another preferred embodiment, a photon source 75a producing photons of at least one energy of approximately mXAS.β eV, 95.7 eV, or mX3l.9A eV causes stimulated emission of energy as the hydrogen molecules undergo the shrinkage reaction. In all reaction mixtures, a selected external energy device 75, such as an electrode may be used to supply an electrostatic potential or a current (magnetic field) to decrease the activation energy of the resonant absorption of an energy hole. In another embodiment, the mixture 54, further comprises a surface or material to dissociate and/or absorb atoms and/or molecules of the energy releasing material 56. Such surfaces or materials to dissociate and/or absorb hydrogen, deuterium, or tritium comprise an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite). In a preferred embodiment, a source of energy holes to shrink hydrogen atoms comprises a catalytic energy hole material 58, typically comprising electrocatalytic ions and couples that provide an energy hole of approximately m 27.21 eV plus or minus 1 eV. In a preferred embodiment, a source of energy holes to shrink hydrogen molecules comprises a catalytic energy hole material 58, typically comprising electrocatalytic ions and couple(s) including those that provide an energy hole of approximately 777X48.6 eV plus or minus 5 eV . The electrocatalytic ions and couple(s) include the electrocatalytic ions and couples described in my previous U.S . Patent Applications entitled "Energy/Matter Conversion Methods and Structures", Serial No. 08/467,051 filed on June 6, 1995 which is a continuation-in-part application of Serial No. 08/416,040 filed on April 3, 1995 which is a continuation- in-part application of Serial No. 08/107,357 filed on August 16, 1993, which is a continuation-in-part application of Serial No. 08/075,102 (Dkt. 99437) filed on June 11, 1993, which is a continuation-in-part application of Serial No. 07/626,496 filed on December 12, 1990 which is a continuation-in-part application of Serial No. 07/345,628 filed April 28, 1989 which is a continuation-in-part application of Serial No. 07/341 ,733 filed April 21 , 1989. which are incorporated herein by reference.
A further embodiment is the vessel 52 containing a source of energy holes including an electrocatalytic ion or couple(s) (source of energy holes) in the molten, liquid, gaseous, or solid state and a source of hydrogen including hydrides and gaseous hydrogen. In the case of a reactor which shrinks hydrogen atoms, the embodiment further comprises a means to dissociate the molecular hydrogen into atomic hydrogen including an element, compound, alloy, or mixture of transition elements, inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Lr, Au, Hg, Ce, Pr, Nd. Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated
Cs carbon (graphite) or electromagnetic radiation including UV light provided by photon source 75.
The present invention of an electrolytic cell energy reactor, pressurized gas energy reactor, and a gas discharge energy reactor, comprises: a source of hydrogen; one of a solid, molten, liquid, and gaseous source of energy holes; a vessel containing hydrogen and the source of energy holes wherein the shrinkage reaction occurs by contact of the hydrogen with the source of energy holes; and a means for removing the (molecular) lower-energy hydrogen so as to prevent an exothermic shrinkage reaction from coming to equilibrium. The present energy invention is further described in my previous U.S . Patent Applications entitled "Energy/Matter Conversion Methods and Structures", Serial No. 08/467,051 filed on June 6, 1995 which is a continuation-in-part application of Serial No. 08/416,040 filed on April 3, 1995 which is a continuation-in-part application of Serial No.
08/107,357 filed on August 16, 1993, which is a continuation- in-part application of Serial No. 08/075,102 (Dkt. 99437) filed on June 11 , 1993, which is a continuation-in-part application of Serial No. 07/626,496 filed on December 12,1990 which is a continuation-in-part application of Serial No. 07/345,628 filed April 28, 1989 which is a continuation-in-part application of Serial No. 07/341 ,733 filed April 21 , 1989, and my publications, Mills, R., Kneizys, S., Fusion Technology, 210, (1991 ), pp. 65-81 ; Mills, R., Good, W., Shaubach, R., "Dihydrino Molecule Identification", Fusion Technology, 25, 103 (1994);
Mills, R., Good, W., "Fractional Quantum Energy Levels of Hydrogen", Fusion Technology, Vol. 28, No. 4, November, ( 1995), pp. 1697-1719 which are incorporated herein by reference.
Electrolytic Energy Reactor
An electrolytic energy reactor is described in my previous U.S. patent applications entitled "Energy/Matter Conversion Methods and Structures", Serial No. 08/467,051 filed on June 6, 1995 which is a continuation-in-part application of Serial No. 08/416,040 filed on April 3, 1995 which is a continuation-in-part application of Serial No. 08/107,357 filed on August 16, 1993, which is a continuation- in-part application of Serial No. 08/075, 102 (Dkt. 99437) filed on June 1 1 , 1993, which is a continuation-in-part application of Serial No. 07/626,496 filed on December 12,1990 which is a continuation-in-part application of Serial No. 07/345,628 filed April 28, 1989 which is a continuation-in-part application of Serial No. 07/341 ,733 filed April 21 , 1989 which are incorporated herein by reference. A preferred embodiment of the energy reactor of the present invention comprises an electrolytic cell forming the reaction vessel 52 of FIGURE 5 including a molten electrolytic cell. The electrolytic cell 100 is shown generally in FIGURE 6. An electric current is passed through the electrolytic solution 102 having a electrocatalytic ions or couples providing energy holes equal to the resonance shrinkage energy (including the electrocatalytic ions and couples described in my previous U.S. Patent Applications incorporated herein by reference) by the application of a voltage to an anode 104 and cathode 106 by the power controller 108 powered by the power supply 110. Ultrasonic or mechanical energy may also be imparted to the cathode 106 and electrolytic solution 102 by vibrating means 112. Heat can be supplied to the electrolytic solution 102 by heater 114. The pressure of the electrolytic cell 100 can be controlled by pressure regulator means 1 16 where the cell can be closed. The reactor further comprises a means 101 that removes the (molecular) lower-energy hydrogen such as a selective venting valve to prevent the exothermic shrinkage reaction from coming to equilibrium.
In a preferred embodiment, the electrolytic cell is operated at zero voltage gap by applying an overpressure of hydrogen with hydrogen source 121 where the overpressure can be controlled by pressure control means 122 and 1 16. Water can be reduced to hydrogen and hydroxide at the cathode 106, and the hydrogen can be oxidized to protons at the anode 104. An embodiment of the electrolytic cell energy reactor, comprises a reverse fuel cell geometry which removes the lower-energy hydrogen under vacuum. A preferred cathode 106 of this embodiment has a modified gas diffusion layer and comprises a gas route means including a first Teflon membrane filter and a second carbon paper/Teflon membrane filter composite layer. A further embodiment comprises a reaction vessel that can be closed except for a connection to a condensor 140 on the top of the vessel 100. The cell can be operated at a boil such that the steam evolving from the boiling electrolyte 102 can be condensed in the condensor 140, and the condensed water can be returned to the vessel 100. The lower-energy state hydrogen can be vented through the top of the condensor 140. In one embodiment, the condensor contains a hydrogen/oxygen recombiner 145 that contacts the evolving electrolytic gases. The hydrogen and oxygen are recombined, and the resulting water can be returned to the vessel 100. The heat released from the exothermic reaction whereby the electrons of the electrolytically produced hydrogen atoms (molecules) are induced to undergo transitions to energy levels below the "ground state" and the heat released due to the recombination of the electrolytically generated normal hydrogen and oxygen can be removed by a heat exchanger 60 of FIGURE 5 which can be connected to the condensor 140.
In vacuum, in the absence of external fields, the energy hole to stimulate a hydrogen atom (molecule) to undergo a shrinkage transition is mX27.2\ eV (mXA8.6 eV) where m is an integer. This resonance shrinkage energy can be altered when the atom (molecule) is in a media different from vacuum. An example is a hydrogen atom (molecule) absorbed to the cathode 106 present in the aqueous electrolytic solution 102 having an applied electric field and an intrinsic or applied magnetic field provided by external magnetic field generator 75. Under these conditions the energy hole required can be slightly different from mX27.2\ eV (mXA8.6 eV). Thus, a source of energy holes including electrocatalytic ion and couple reactants can be selected which has a redox (electron transfer) energy resonant with the resonance shrinkage energy when operating under these conditions. In the case where a nickel cathode 106 is used to electrolyze an aqueous solution 102 where the cell is operating within a voltage range of 1.4 to 5 volts, the K+/K+ and Rb+ (Fe3+/Li+ and Sc3+/Sc3+) electrocatalytic ions and couples are preferred embodiments to shrink hydrogen atoms (molecules).
The cathode provides hydrogen atoms (molecules), and the shrinkage reaction occurs at the surface of the cathode where hydrogen atoms (molecules) and the source of energy holes (electrocatalytic ion or couple) are in contact. Thus, the shrinkage reaction can be dependent on the surface area of the cathode. For a constant current density, giving a constant concentration of hydrogen atoms (molecules) per unit area, an increase in surface area increases the reactants available to undergo the shrinkage reaction. Also, an increase in cathode surface area decreases the resistance of the electrolytic cell which improves the electrolysis efficiency. A preferred cathode of the electrolytic cell including a nickel cathode has the properties of a high surface area, a highly stressed and hardened surface such as a cold drawn or cold worked surface, and a large number of grain boundaries.
In a preferred embodiment of the electrolytic cell energy reactor, the source of energy holes can be incorporated into the cathode, mechanically by methods including cold working the source of energy holes into the surface of the cathode; thermally by methods including melting the source of energy holes into the surface of the cathode and evaporation of a solvent of a solution of the source of energy holes in contact with the surface of the cathode, and electrostatically by methods including electrolytic deposition, ion bombardment, and vacuum deposition.
The shrinkage reaction rate can be dependent upon the composition of the cathode 106. Hydrogen atoms (molecules) are reactants to produce energy via the shrinkage reaction. Thus, the cathode must efficiently provide a high concentration of hydrogen atoms (molecules). The cathode
106 can be comprised of any element, compound, alloy, or mixture of a conductor or semiconductor including transition elements and compounds, actinide and lanthanide elements and compounds, and group IIIB and IVB elements and compounds. Transition metals dissociate hydrogen gas into atoms to a more or lesser extent depending on the metal. Nickel and titanium readily dissociate hydrogen molecules and are preferred embodiments for shrinking hydrogen atoms. The cathode can alter the energy of the absorbed hydrogen atoms (molecules) and affect the energy of the shrinkage reaction. A cathode material can be selected which provides resonance between the energy hole and the resonance shrinkage energy. In the case of the K+/K+ electrocatalytic couple with carbonate as the counterion for catalyzing the shrinkage of hydrogen atoms, the relationship of the cathode material to the reaction rate can be: Pt < Pd « Ti,Fe < Ni
This can be the opposite order of the energy released when these materials absorb hydrogen atoms. Thus, for this electrocatalytic couple, the reaction rate can be increased by using a cathode which weakly absorbs the hydrogen atoms with little perturbation of their electronic energies.
Also, coupling of resonator cavities and enhancement of the transfer of energy between them can be increased when the media is a nonlinear media such as a magnetized ferromagnetic media. Thus, a paramagnetic or ferromagnetic cathode, a nonlinear magnetized media, increases the reaction rate by increasing the coupling of the resonance shrinkage energy of the hydrogen atom and energy hole comprising an electrocatalytic ion or couple. Alternatively, a magnetic field can be applied with the magnetic field generator 75. Magnetic fields at the cathode alter the energy of absorbed hydrogen and concomitantly alter the resonance shrinkage energy. Magnetic fields also perturb the energy of the electrocatalytic reactions (energy hole) by altering the energy levels of the electrons involved in the reactions. The magnetic properties of the cathode are selected as well as the strength of the magnetic field which is applied by magnetic field generator 75 to optimize shrinkage reaction rate-the power output. A preferred ferromagnetic cathode is nickel.
A preferred method to clean the cathode of the electrolytic cell including a nickel cathode is to anodize the cathode in a basic electrolytic solution including approximately 0.57 M X2CO3 (X is the alkali cation of the electrolyte including K+) and to immerse the cathode in a dilute solution of H2O2 such as approximately 3% H2O 2. In a further embodiment of the cleaning method, cyclic voltametry with a second electrode of the same material as the first cathode is performed. The cathode can be then thoroughly rinsed with distilled water. Organic material on the surface of the cathode inhibits the catalytic reaction whereby the electrons of the electrolytically produced hydrogen atoms (molecules) are induced to undergo transitions to energy levels below the "ground state". Cleaning by this method removes the organic material from the cathode surface and adds oxygen atoms onto the cathode surface. Doping the metal surface, including a nickel surface, with oxygen atoms by anodizing the cathode and cleaning the cathode in H2O 2 increases the power output by decreasing hydrogen recombination to molecular hydrogen and by decreasing the bond energy between the metal and the hydrogen atoms (molecules) which conforms the resonance shrinkage energy of the absorbed hydrogen to the energy hole provided by the source of energy holes including the K+/K+ (Sc3+/Sc3+) electrocatalytic couples.
Different anode materials have different overpotentials for the oxidation of water, which can affect ohmic losses. An anode of low overpotential will increase the efficiency. Nickel, platinum, and dimensionally stable anodes including platinized titanium are preferred anodes. In the case of the K+/K+ electrocatalytic couple where carbonate is used as the counterion, nickel is a preferred anode. Nickel is also a preferred anode for use in basic solutions with a nickel cathode. Nickel is inexpensive relative to platinum, and fresh nickel can be electroplated onto the cathode during electrolysis .
A preferred method to clean a dimensionally stable anode including a platinized titanium anode is to place the anode in approximately 3 M HC1 for approximately 5 minutes and then to rinse it with distilled water.
In the case of hydrogen atom shrinkage, hydrogen atoms at the surface of the cathode 106 form hydrogen gas which can form bubbles on the surface of the cathode. These bubbles act as an boundary layer between the hydrogen atoms and the electrocatalytic ion or couple. The boundary can be ameliorated by vibrating the cathode and/or the electrolytic solution 102 or by applying ultrasound with vibrating means 112; and by adding wetting agents to the electrolytic solution 102 to reduce the surface tension of the water and prevent bubble formation. The use of a cathode having a smooth surface or a wire cathode prevents gas adherence. And an intermittent current, provided by an on- off circuit of power controller 108 provides periodic replenishing of hydrogen atoms which are dissipated by hydrogen gas formation followed by diffusion into the solution while preventing excessive hydrogen gas formation which could form a boundary layer.
The shrinkage reaction can be temperature dependent. Most chemical reactions double their rates for each 10 °C rise in temperature. Increasing the temperature increases the collision rate between the hydrogen atoms (molecules) and the electrocatalytic ion or couple which will increase the shrinkage reaction rate. With large temperature excursions from room temperature, the kinetic energy distribution of the reactants can be sufficiently altered to cause the energy hole and the resonance shrinkage energy to conform to a more or lesser extent. The rate can be proportional to the extent of the conformation or resonance of these energies. The temperature can be adjusted to optimize the shrinkage reaction rate-energy production rate. In the case of the K+/K+ electrocatalytic couple, a preferred embodiment can be to run the reaction at a temperature above room temperature by applying heat with heater 114.
The shrinkage reaction can be dependent on the current density. An increase in current density can be equivalent, in some aspects, to an increase in temperature. The collision rate increases, and the energy of the reactants increases with current density. Thus, the rate can be increased by increasing the collision rate of the reactants; however, the rate may be increased or decreased depending on the effect of the increased reactant energies on the conformation of the energy hole and the resonance shrinkar; energy. Also, increased current dissipates more energy jy ohmic heating and may cause hydrogen bubble formation, in the case of the shrinkage of hydrogen atoms. But, a high flow of gas may dislodge bubbles which diminishes any hydrogen gas boundary layer. The current density can be adjusted with power controller 108 to optimize the excess energy production. In a preferred embodiment, the current density can be in the range 1 to 1000 milliamps per square centimeter.
The pH of the aqueous electrolytic solution 102 can affect the shrinkage reaction rate. In the case that the electrocatalytic ion or couple is positively charged, an increase in the pH will reduce the concentration of hydronium at the negative cathode; thus, the concentration of the electrocatalytic ion or couple cations will increase. An increase in reactant concentration increases the reaction rate. In the case of the Rb+ or K+/K+ (Sc3+/Sc +) ion or couple, a preferred pH can be basic (7.1-14).
The counterion of the electrocatalytic ion or couple of the electrolytic solution 102 can affect the shrinkage reaction rate by altering the energy of the transition state. For example, the transition state complex of the K+/K+ electrocatalytic couple with the hydrogen atom has a plus two charge and involves a three body collision which can be unfavorable. A negative two charged oxyanion can bind the two potassium ions; thus, it provides a neutral transition state complex of lower energy whose formation depends on a binary collision which can be greatly favored. The rate can be dependent on the separation distance of the potassium ions as part of the complex with the oxyanion. The greater the separation distance, the less favorable can be the transfer of an electron between them. A close juxtaposition of the potassium ions will increase the rate. The relationship of the reaction rate to the counterion in the case where the K+/K+ couple is used can be :
Thus, a planar negative two charged oxyanion including carbonate with at least two binding sites for K+ which provides close juxtaposition of the K+ ions can be preferred as the counterion of the K+/K+ electro atalytic couple. The carbonate counterion can be also a preferred counterion for the Rb+ electrocatalytic ion.
A power controller 108 comprising an intermittent current, on-off, electrolysis circuit will increase the excess heat by providing optimization of the electric field as a function of time which provides maximum conformation of reactant energies, provides an optimal concentration of hydrogen atoms (molecules) while minimizing ohmic and electrolysis power losses and, in the case of the shrinkage of hydrogen atoms, minimizes the formation of a hydrogen gas boundary layer. The frequency, duty cycle, peak voltage, step waveform, peak current, and offset voltage are adjusted to achieve the optimal shrinkage reaction rate and shrinkage reaction power while minimizing ohmic and electrolysis power losses. In the case where the K+/K+ electrocatalytic couple can be used with carbonate as the counterion; nickel as the cathode; and platinum as the anode, a preferred embodiment can be to use an intermittent square-wave having an offset voltage of approximately 1.4 volts to 2.2 volts; a peak voltage of approximately 1.5 volts to 3.75 volts; a peak current of approximately 1 mA to 100 mA per square centimeter of cathode surface area; approximately a 5 -90% duty cycle; and a frequency in the range of 1 Hz to 1500 Hz.
Further energy can be released by repeating the shrinkage reaction. The atoms (molecules) which have undergone shrinkage diffuse into the cathode lattice. A cathode 106 can be used which will facilitates multiple shrinkage reactions of hydrogen atoms (molecules). One embodiment is to use a cathode which can be fissured and porous to the electrocatalytic ion or couple such that it can contact shrunken atoms (molecules) which have diffused into a lattice, including a metal lattice. A further embodiment is to use a cathode of alternating layers of a material which provides hydrogen atoms (molecules) during electrolysis including a transition metal and an electrocatalytic ion or couple such that shrunken hydrogen atoms (molecules) periodically or repetitively diffuse into contact with the electrocatalytic ion or couple.
The shrinkage reaction can be dependent on the dielectric constant of the media. The dielectric constant of the media alters the electric field at the cathode and concomitantly alters the energy of the reactants. Solvents of different dielectric constants have different solvation energies, and the dielectric constant of the solvent can also lower the overpotential for electrolysis and improve electrolysis efficiency. A solvent, including water, can be selected for the electrolytic solution 102 which optimizes the conformation of the energy hole and resonance shrinkage energy and maximizes the efficiency of electrolysis.
The solubility of hydrogen in the reaction solution can be directly proportional to the pressure of hydrogen above the solution. Increasing the pressure increases the concentration of reactant hydrogen atoms (molecules) at the cathode 106 and thereby increases the rate. But, in the case of the shrinkage of hydrogen atoms this also favors the development of a hydrogen gas boundary layer. The hydrogen pressure can be controlled by pressure regulator means 116 to optimize the shrinkage reaction rate.
In a preferred embodiment, the cathode 106 of the electrolytic cell comprises the catalytic material including a hydrogen spillover catalyst described in the Pressurized Gas
Energy Reactor Section below. In another embodiment, the cathode comprises multiple hollow vessels comprising a thin film conductive shell whereby lower-energy hydrogen diffuses through the thin film and collects inside each vessel and undergoes disproportionation reactions therein.
The heat output can be monitored with thermocouples present in at least the vessel 100 and the condensor 140 of FIGURE 6 and the heat exchanger 60 of FIGURE 5. The output power can be controlled by a computerized monitoring and control system which monitors the thermistors and controls the means to alter the power output. Pressurized Gas Energy Reactor
A pressurized gas energy reactor comprises the first vessel 200 of FIGURE 7 containing a source of hydrogen including hydrogen from metal-hydrogen solutions, hydrogen from hydrides, hydrogen from the dissociation of water including thermal dissociation, hydrogen from the electrolysis of water, or hydrogen gas. In the case of a reactor which shrinks hydrogen atoms, the reactor further comprises a means to dissociate the molecular hydrogen into atomic hydrogen such as a dissociating material including an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite) or electromagnetic radiation including UV light provided by photon source 205 such that the dissociated hydrogen atoms (molecules) contact a source of energy holes including a molten, liquid, gaseous, or solid source of the energy holes including the electrocatalytic ions and couples described in my previous U.S. Patent Applications entitled "Energy/Matter Conversion Methods and Structures", Serial No. 08/467,051 filed on June 6, 1995 which is a continuation-in-part application of Serial No. 08/416,040 filed on April 3, 1995 which is a continuation-in-part application of Serial No. 08/107,357 filed on August 16, 1993, which is a continuation- in-part application of Serial No. 08/075, 102 (Dkt. 99437) filed on June 1 1 , 1993, which is a continuation-in-part application of Serial No. 07/626,496 filed on December 12,1990 which is a continuation-in-part application of Serial No. 07/345,628 filed April 28, 1989 which is a continuation-in-part application of Serial No. 07/341 ,733 filed April 21 , 1989, which are incorporated herein by reference. The pressurized gas energy reactor further comprises a means 201 to remove the
(molecular) lower-energy hydrogen such as a selective venting valve to prevent the exothermic shrinkage reaction from coming to equilibrium. One embodiment comprises heat pipes as heat exchanger 60 of FIGURE 5 which have a lower-energy hydrogen venting valve at a cold spot.
A preferred embodiment of the pressurized gas energy reactor of the present invention comprises a first reaction vessel 200 with inner surface 240 comprised of a material to dissociate the molecular hydrogen into atomic hydrogen including an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite). In a further embodiment, the inner surface 240 can be comprised of a proton conductor. The first reaction vessel 200 can be sealed in a second reaction vessel 220 and receives hydrogen from source 221 under pressure which can be controlled by pressure measurement and control means 222 and 223. In a preferred embodiment the hydrogen pressure can be in the range of 10-3 atmospheres to 100 atmospheres. The wall 250 of the first vessel 200 can be permeable to hydrogen. The outer surface 245 and/or outer vessel 220 has a source of energy holes equal to the resonance shrinkage energy. In one embodiment the source of energy holes can be a mixture or solution containing energy holes in the molten, liquid, or solid state. In another embodiment an electric current can be passed through the material having a source of energy holes. The reactor further comprises a means to control the reaction rate such as current source 225 and heating means 230 which heat the first reaction vessel 200 and the second reaction vessel 220. In a preferred embodiment the outer reaction vessel 220 contains oxygen, the inner surface 240 comprises one or more of a coat of nickel, platinum, or palladium. The outer surface 245 can be coated with one or more of copper, tellurium, arsenic, cesium, platinum, or palladium and an oxide such as CuOx, PtO , PdOx, MnOx, AlOx, SiOx. The electrocatalytic ion or couple can be regenerated spontaneously or via a regeneration means including heating means 230 and current source 225.
In another embodiment, the pressurized gas energy reactor comprises only a single reaction vessel 200 with a hydrogen impermeable wall 250. In the case of a reactor which shrinks hydrogen atoms, one or more of a hydrogen dissociating materials including transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite) are coated on the inner surface 240 with a source of energy holes including one or more of copper, tellurium, arsenic, cesium, platinum, or palladium and an oxide such as
CuOx, PtOx, PdOx, MnOx, AlOx, SiOx. In another embodiment, the source of energy hole can be one of a inelastic photon or particle scattering reaction(s). In a preferred embodiment the photon source 205 supplies the energy holes where the energy hole corresponds to stimulated emission by the photon. In the case of a reactor which shrinks hydrogen atoms the photon source 205 dissociates hydrogen molecules into hydrogen atoms. The photon source producing photons of at least one energy of approximately mX27.2\ eV, — X27.21 eV, or 40.8 eV causes stimulated emission of energy as the hydrogen atoms undergo the shrinkage reaction. In another preferred embodiment, a photon source 205 producing photons of at least one energy of approximately m 48.6 eV , 95.7 eV, or m 31.94 eV causes stimulated emission of energy as the hydrogen molecules undergo the shrinkage reaction.
A preferred inner surface, 240, and outer surface, 245, of the pressurized gas energy reactor including a nickel surface has the properties of a high surface area, a highly stressed and hardened surface such as a cold drawn or cold worked surface, and a large number of grain boundaries. In an embodiment of the pressurized gas energy reactor, the source of energy holes can be incorporated into the inner surface, 240, and outer surface, 245, mechanically by methods including cold working the source of energy holes into the surface material and thermally by methods including melting the source of energy holes into the surface material (fusion). Further methods of incorporation include dry impregnation, evaporation of a solution of the source of energy holes in contact with the surface material (precipitation), ion bombardment, vacuum deposition, impregnation, leaching, and electrostatic incorporation including electrolytic deposition and electroplating. A preferred method to clean the inner surface 240 and the outer surface 245 including a nickel surface is to fill the inner vessel and the outer vessel with a basic electrolytic solution including approximately 0.57 M X2CO3 (X is the alkali cation of the electrolyte including K+) and to fill the inner vessel and the outer vessel with a dilute solution of H2O2. Each of the inner vessel and the outer vessel can be then thoroughly rinsed with distilled water. In one embodiment, at least one of the vessel 200 or the vessel 220 can be then filled with a solution of the energy hole including an approximately 0.57 M K2CO3 solution.
In a further embodiment, textural and/or structural promoters are incorporated with the source of energy holes to increase the shrinkage reaction rate.
In one embodiment of the method of operation of the pressurized gas energy reactor, hydrogen can be introduced inside of the first vessel from source 221 under pressure which can be controlled by pressure control means 222. In the case of a reactor which shrinks hydrogen atoms, the molecular hydrogen can be dissociated into atomic hydrogen by a dissociating material or electromagnetic radiation including UV light provided by photon source 205 such that the dissociated hydrogen atoms contact a source of energy holes including a molten, liquid, gaseous, or solid source of the energy holes. The atomic (molecular) hydrogen releases energy as its electrons are stimulated to undergo transitions to lower energy levels by the energy holes. Alternatively, the hydrogen dissociates on the inner surface 240, diffuses though the wall 250 of the first vessel 200 and contacts a source of energy holes on the outer surface 245 or contact a source of energy holes including a molten, liquid, gaseous, or solid source of the energy holes as hydrogen atoms or recombined hydrogen molecules. The atomic (molecular) hydrogen releases energy as its electrons are stimulated to undergo transitions to lower energy levels by the energy holes. The electrocatalytic ion or couple can be regenerated spontaneously or via a regeneration means including heating means 230 and current source 225. The (molecular) lower- energy hydrogen can be removed from vessel 200 and/or vessel 220 by a means to remove the (molecular) lower- energy hydrogen such as a selective venting valve means 201 which prevents the exothermic shrinkage reaction from coming to equilibrium. To control the reaction rate (the power output), an electric current can be passed through the material having a source of energy holes equal to the resonance shrinkage energy with current source 225, and/or the first reaction vessel 200 and the second reaction vessel 220 are heated by heating means 230. The heat output can be monitored with thermocouples present in at least the first vessel 200, the second vessel 220, and the heat exchanger 60 of FIGURE 5. The output power can be controlled by a computerized monitoring and control system which monitors the thermistors and controls the means to alter the power output. The (molecular) lower-energy hydrogen can be removed by a means 201 to prevent the exothermic shrinkage reaction from coming to equilibrium.
A method of preparation of the catalytic material of the present invention of catalytic systems that hinge on the transfer of an electron from a cation to another capable of producing energy holes for shrinking hydrogen atoms includes the steps of:
• Mixing the oxides of the cations with the hydrogen dissociating material. • Thoroughly mixing by repeatedly sintering and pulverizing.
Example of a Ceramic Catalytic Material: Strontium Niobium Oxide (SrNboO^ on Ni Powder: To prepare the ceramic catalytic material: strontium niobium oxide (SrNb2θ6) on Ni powder, 2.5 kg of SrNb2θ6 are added to 1.5 kg of -300 mesh Ni powder. The materials are mixed to make a homogeneous mixture. The powder can be sintered or calcinated in an oven at 1600°C in atmospheric air for 24 hours. The material can be cooled and ground to remove lumps. The material can be re-sintered at 1600°C in air for another 24 hours. The material can be cooled to room temperature and powderized.
A method of preparation of the catalytic material of the present invention of catalytic systems that hinge on the transfer of an electron from a cation to another capable of producing energy holes for shrinking hydrogen atoms includes the steps of:
• Dissolving ionic salts of the cations into a solvent. In a preferred embodiment, the ionic salts are dissolved in deionized demineralized water to concentration of 0.3 to 0.5 molar.
• Uniformly wetting a dissociation material with the dissolved salt solution. • Draining the excess solution.
• Drying the wetted dissociation material in an oven preferably at a temperature of 220 °C.
• Pulverizing the dried catalytic material into a powder.
Example of a Ionic Catalytic Material: Potassium Carbonate
(K CO3 on Ni Powder:
To prepare the ionic catalytic material: potassium carbonate (K2C03) on Ni powder, a 1 liter solution of 0.5 M K2CO3 in water is poured over 500 grams of -300 mesh Ni powder. The materials are stirred to remove air pockets around the grains of Ni. The excess solution can be drained off. The powder can be dried in an oven at 200°C. If necessary the material can be ground to remove lumps.
Hydrogen Spillover Catalysts In a preferred embodiment, the source of hydrogen atoms for the catalytic shrinkage reaction comprises a hydrogen spillover catalyst.
A hydrogen spillover catalyst according to the present invention comprises: • A hydrogen dissociation material or means which forms free hydrogen atoms or protons;
• A conduit material onto which free hydrogen atoms spill and which supports free, mobile hydrogen atoms and provides a path or conduit for the flow of hydrogen atoms or protons; • A source of energy holes which catalyze the shrinkage reaction, and optionally
• A support material into which the former materials are embedded as a mixture, compound, or solution.
Such hydrogen dissociation materials include surfaces or materials to dissociate hydrogen, deuterium, or tritium, comprise an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu,
Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite). Such conduit materials onto which free hydrogen atoms spill and which supports free, mobile hydrogen atoms and which provides a path or conduit for the flow of hydrogen atoms include nickel, platinum, carbon, tin, iron, aluminum, and copper and their compounds, mixtures, or alloys. In an embodiment, such support materials into which the former materials are embedded as a mixture, compound, or solution includes carbon, silica, nickel, copper, titania, zinc oxide, chromia, magnesia, zirconia, alumina, silica-alumina, and zeolites. In an embodiment, one or more of the other components are deposited on the support material by electroplating. The source of energy holes to cause atomic hydrogen "shrinkage" are preferably of approximately 777X27.21 eV and/or to cause molecular hydrogen "shrinkage" are of approximately rnX48.6 eV where m is an integer including the electrocatalytic ions and couples described in my previous U.S. Patent Applications entitled "Energy/Matter Conversion Methods and Structures", Serial No. 08/467,051 filed on June 6, 1995 which is a continuation-in-part application of Serial No. 08/416,040 filed on April 3, 1995 which is a continuation-in-part application of Serial No.
08/107,357 filed on August 16, 1993, which is a continuation- in-part application of Serial No. 08/075, 102 (Dkt. 99437) filed on June 1 1 , 1993, which is a continuation-in-part application of Serial No. 07/626,496 filed on December 12,1990 which is a continuation-in-part application of Serial No. 07/345,628 filed
April 28, 1989 which is a continuation-in-part application of Serial No. 07/341,733 filed April 21, 1989, which are incorporated herein by reference. The counterion of the energy hole of the spillover catalyst includes those given in the Handbook of Chemistry and Physics, Robert C. Weast,
Editor, 58 th Edition, CRC Press, West Palm Beach, Florida. ( 1974) pp. B61-B 178 which is incorporated by reference herein, organic ions including benzoic acid, phthalate, salicylate, aryl sulfonate, alky sulfate, alkyl sulfonate, and alkyl carboxylate, and the anion of an acid which forms an acid anhydride including sulfite, sulfate, carbonate, bicarbonate, nitrite, nitrate, perchlorate, phosphite, hydrogen phosphite, dihydrogen phosphite, phosphate, hydrogen phosphate, and dihydrogen phosphate. In another embodiment the anion can be in equilibrium with its acid and its acid anhydride.
The functionalities of the hydrogen spillover catalyst are combined with the other functionalities as separate species or as combinations comprising a mixture, solution, compound, or alloy of more than one functionality. For example, in one embodiment, the hydrogen dissociation material and the source of energy holes each comprise homogeneous crystals- each crystal contains one component, and these functionalities are mixed with the conduit material without a support material. Whereas, in another embodiment, the hydrogen dissociation material and the source of energy holes comprise heterogeneous crystals-each crystal contains both of the components, and the heterogeneous crystals are mixed with the conduit material which coats a support material. In a third exemplary embodiment, the source of energy holes can be embedded in the conduit material, and this combined species can be mixed with the hydrogen dissociation material which can be embedded in the same or a different conduit material without a support material.
A method of preparation of the hydrogen spillover catalytic material of the present invention includes the steps of:
• Mixing the components of the spillover catalyst by the method of incipient wetness impregnation.
• Thoroughly mixing the components by sintering.
A further method of preparation of the hydrogen spillover catalytic material of the present invention includes the steps of:
• Dissolving or dispersing the components to be mixed in a suitable solvent such as water and drying the solution or mixture. • Removing the solvent by drying, or the wet mixture, suspension, or solution can be frozen and the solvent can be sublimed.
• Thoroughly mixing the components by sintering.
An incipient wetness method of preparation of the hydrogen spillover catalytic material of the present invention comprising a source of energy holes for shrinking hydrogen atoms that hinge on the transfer of an electron from a cation to another includes the steps of:
• Dissolving a desired weight of the ionic salts of the cations into a desired volume of solvent. In a preferred embodiment, the ionic salts are dissolved in deionized demineralized water. • Preparing an incipiently wet conduit-hydrogen dissociation material by uniformly wetting the conduit-hydrogen dissociation material with the dissolved salt solution so that the pores of the material are just filled. The total volume of solvent required can be the desired amount, and the weight percent of the ionic salts of the cations in the final material can be determined by the desired weight of the ionic salts of the cations dissolved in the desired volume of solvent.
• Mechanically mixing the wetted material to insure uniform wetting .
• Drying the incipiently wet conduit-hydrogen dissociation material in an oven preferably at a temperature of 150 °C. In an embodiment the material can be heated until the counterion(s) of the cations chemically decompose to preferably oxides.
• Pulverizing the dried material comprised of the conduit- hydrogen dissociation-source of energy holes material into a powder.
• Optionally, mechanically mixing the dried and powdered material with further hydrogen dissociation material including a powder mixed with a conduit material and a support material .
Example of a Ionic Hydrogen Spillover Catalytic Material: 40% bv Weight Potassium Nitrate (KNO^I on 1 %-Pd-on-Graphitic
Carbon Powder:
To prepare one kilogram of the ionic hydrogen spillover catalytic material: 40% by weight potassium nitrate (KNO3) on 1 %-Pd-on-graphitic carbon powder, 0.40 kg of KNO3 are dissolved in 1 liter of H20. Incipient wetness requires 1 ml of
H20 per gram of -300 mesh graphite powder, and 0.67 grams of KNO3 are required per gram of graphitic carbon powder to achieve a 40% by weight KNO3 content in the final material. The aqueous KNO3 solution can be slowly added to 0.6 kg of l %-Pd-on--300-mesh-graphitic carbon powder as the slurry can be mixed. The slurry can be then placed on an evaporation dish which can be inserted into an oven at 150°C for one hour. Heating causes the water to evaporate from the slurry. The KNO3 coated 1 %-Pd-on-graphitic carbon can be ground into a powder.
Another incipient wetness method of preparation of the hydrogen spillover catalytic material of the present invention comprising a source of energy holes for shrinking hydrogen atoms that hinge on the transfer of an electron from a cation to another includes the steps of:
• Dissolving a desired weight of the ionic salts of the cations into a desired volume of solvent. In a preferred embodiment, the ionic salts are dissolved in deionized demineralized water.
• Preparing an incipiently wet conduit material by uniformly wetting the conduit material with the dissolved salt solution so that the pores of the material are just filled. The total volume of solvent required can be the desired amount, and the weight percent of the ionic salts of the cations in the final material can be determined by the desired weight of the ionic salts of the cations dissolved in the desired volume of solvent.
• Mechanically mixing the wetted material to insure uniform wetting.
• Drying the incipiently wet conduit material in an oven preferably at a temperature of 150 °C. In an embodiment, the material can be heated until the counterion(s) of the cations chemically decompose to preferably oxides. • Pulverizing the dried material comprised of the conduit material and the source of energy holes into a powder.
• Mechanically mixing the dried and powdered material with a hydrogen dissociation material including a powder mixed with a conduit material and a support material.
Example of a Ionic Hydrogen Spillover Catalytic Material: 40% by Weight Potassium Nitrate (KNO J) on Graphitic Carbon Powder with 5% by Weight 1 %-Pd-on-Graphitic Carbon Powder: To prepare one kilogram of the ionic hydrogen spillover catalytic material: 40% by weight potassium nitrate (KNO3) on graphitic carbon powder with 5% by weight 1 %-Pd-on- graphitic carbon powder, 0.67 kg of KNO3 are dissolved in 1 liter of H 0. Incipient wetness requires 1 ml of H 0 per gram of -300 mesh graphite powder, and 0.40 grams of KNO3 are required per gram of graphite powder to achieve a 40% by weight KNO3 content in the final material. The aqueous KNO3 solution can be slowly added to 0.55 kg of graphite powder as the slurry can be mixed. The slurry can be then placed on an evaporation dish which can be inserted into an oven at 150°C for one hour. Heating causes the water to evaporate from the slurry. The KNO3 coated graphite can be ground into a powder. The powder can be weighed. Approximately 50 grams (5% of the weight of the KNO3 coated graphite) of 1 %- Pd-on— 300-mesh graphitic carbon powder can be mixed into the KNO3 coated graphitic carbon powder.
Example of the Mode of Operation of the Exemplary Catalytic Materials:
The catalytic material can be placed into the pressurizable vessel 200. The vessel can be flushed with an inert gas such as He, Ar, or Ne to remove air contaminants in the vessel. The vessel and its contents are heated to the operational temperature, typically 100 °C to 400 °C, before the vessel can be pressurized with hydrogen, typically 20 to 140 PSIG. In an embodiment, the source of energy holes is potassium ions (K+/K+) or rubidium ions (Rb+) intercalated into carbon. In another embodiment, the source of energy holes is an amalgam of the electrocatalytic ion or couple and its reduced metallic form such as rubidium ions (Rb+) and rubidium metal or potassium ions (K+/K+) and potassium metal .
In an embodiment, the source of hydrogen atoms is a hydrogen dissociation means including a hydrogen gas stream blown over a hot filament or grid such as a hot refractory metal including a filament or grid of Ti, Ni, Fe, W, Au, Pt, or Pd at an elevated temperature such as 1800°C. The dissociation means provides hydrogen atoms as well as hydrogen ions, and the momentum of the atoms brings them in contact with the source of energy holes. Or, the hydrogen atoms and ions sputter onto the spillover catalyst. In one preferred embodiment of the pressurized gas reactor, a low pressure can be maintained by pressure regulator means 222 and a pump means 223 to minimize hydrogen atom recombination into molecular hydrogen and remove (molecular) lower-energy hydrogen.
In an embodiment the source of hydrogen atoms is water which dissociates to hydrogen atoms and oxygen on a water dissociation material such as an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y. Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce. Pr, Nd, Pm, Sm, Eu, Gd,
Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite). In a further embodiment, the water dissociation material can be maintained at an elevated temperature by a heat source and temperature control means 230. In an embodiment including one comprising a hydrogen spillover catalyst, the source of hydrogen can be from hydrocarbons including natural gas which can be reformed on a reforming a material such as nickel, cobalt, iron, or a platinum-group metal to hydrogen atoms and carbon dioxide. In a further embodiment, the reforming material can be maintained at an elevated temperature by a heat source and a temperature control means 230. In another embodiment, the source of hydrogen atoms can be from the decomposition of a metal hydride where the decomposition can be controlled by controlling the temperature of the metal hydride with the heat source and temperature control means 230. In another embodiment, the hydride can be coated by methods including electroplating with another material such as the hydrogen dissociation material .
In a preferred embodiment a product of the shrinkage reaction, (molecular) lower-energy hydrogen, can be removed to prevent product inhibition. Thus, the forward energy yielding reaction rate can be increased. One means to remove lower-energy (molecular) hydrogen is to supply the reaction mixture with a scavenger for lower-energy hydrogen. The scavenger absorbs or reacts with the product, lower-energy, hydrogen, and the resulting species can be removed from the reaction mixture. In another embodiment lower-energy hydrogen which is absorbed on the catalysts can be removed via displacement with an inert molecule or atom such as helium that flows through the vessel 200.
Other objects, features, and characteristics of the art of catalysis as well as the methods of preparation, operation and the functions of the related elements, as described by Satterfield [Charles N. Satterfield, Heterogeneous Catalysis in Industrial Practice, Second Edition, McGraw-Hill, Inc., New
York, (1991)] are applied to the present invention and are incorporated by reference herein. Application of the art of catalysis to the present invention of a pressurized gas energy reactor for the release of energy by the catalytic reaction wherein the electrons of hydrogen atoms undergo transitions to lower energy states include the use of an adiabatic reactor, fluidized-bed reactor, transport line reactor, multitube reactor, reverse multitube reactor having the heat exchange means including a fluid in the tubes and the catalytic material surrounding the tubes, and a multitube reactor or reverse multitube reactor comprising a fluidized bed of the catalytic material. Furthermore, in an embodiment comprising a solvated source of energy holes, a suspended hydrogen dissociation material including a hydrogen spillover catalyst, and hydrogen gas, the reactor comprises a trickle-bed reactor, a bubble-column reactor, or a slurry reactor.
For example, in a preferred embodiment, the fluidized bed reactor 200 comprises the hydrogen spillover catalytic material: 40% by weight potassium nitrate (KN03) on graphitic carbon powder with 5% by weight 1 %-Pd-on-graphitic carbon powder. The reacting hydrogen gas can be passed up through a bed of the finely divided solid catalytic material, preferably having a particle size in the range of about 20 to 100 μm , which can be highly agitated and assumes many of the characteristics of a fluid. A cyclone separator 275 returns the fines to the bed. The hydrogen pressure and flow rate are controlled by pressure and flow rate control means 222. Preferably at atmospheric or slightly higher pressures, the corresponding maximum linear velocity can be less than 60 cm/s .
Gaseous Source of Energy Holes
A preferred hydrogen gas energy reactor for the release of energy by an electrocatalytic and/or a disproportination reaction, wherein the electrons of hydrogen atoms undergo transitions to lower energy states in the gas phase, comprises a vessel 200 of FIGURE 7 capable of containing a vacuum or pressures greater than atmospheric; a source of hydrogen 221 ; a means 222 to control the pressure and flow of hydrogen into the vessel; a source of atomic hydrogen in the gas phase, and a source of energy holes in the gas phase. The reaction vessel 200 comprises a vacuum or pressure vessel comprised of a temperature resistance material such as ceramic, stainless steel, tungsten, alumina, Incoloy, and Inconel .
In an embodiment, the source of hydrogen atoms in the gas phase is a hydrogen dissociation means including a hydrogen gas stream blown over a hot filament or grid 280 such as a hot refractory metal including a filament or grid of Ti, Ni, Fe, W, Au, Pt, or Pd at an elevated temperature such as 1800°C. The dissociation means provides hydrogen atoms as well as hydrogen ions, and the momentum of the atoms brings them in contact with the source of energy holes. In a preferred embodiment of the gaseous-source-of-energy-holes gas reactor, a low pressure can be maintained by pressure regulator means 222 and a pressure measurement and pump means 223 to minimize hydrog i atom recombination into molecular hydrogen. The pressure can be measured by measuring the power dissipated in the hot filament or grid which can be operated at constant resistance by a servo loop 285 comprising a voltage and current measurement means, a power supply, and a voltage and current controller where the hydrogen pressure versus power dissipation of the filament or grid at the operating resistance has been calibrated. In another embodiment, the source of atomic hydrogen comprises one or more hydrogen dissociation materials which provide hydrogen atoms by dissociation of molecular hydrogen. Such hydrogen dissociation materials include surfaces or materials to dissociate hydrogen, deuterium, or tritium, including a hydrogen spillover material such as palladium or platinum on carbon and an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W,
Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite). In one embodiment, nonequilibrium conditions of the hydrogen and hydride are maintained by controlling the temperature and hydrogen pressure to provide atomic hydrogen in the gas phase. In another embodiment, the source of atomic hydrogen comprises a tungsten capillary which on the outlet can be heated by electron bombardment to 1800-2000 K such as the atomic hydrogen source described by Bischler [Bischler, U.; Bertel, E., J. Vac. Sci. Technol., A.
( 1993), 1 1 (2), 458-60] which is incorporated herein by reference. In a further embodiment, the tungsten capillary can be heated by the energy released by the hydrogen shrinkage reaction. In another embodiment, the source of atomic hydrogen comprises an inductively coupled plasma flow tube such as that described by Gardner [Gardner, W. L., J. Vac. Sci. Technol., A. (1995), 13(3, Pt. 1), 763-6] which is incorporated herein by reference, and the hydrogen dissociation fraction can be measured with the sensor of Gardner.
The source of energy holes can be placed in a chemically resistant open container such as a ceramic boat 290 inside the reaction vessel. Or, the source of energy holes can be placed in a vessel which has a connection for the passage of the gaseous source of energy holes to the reaction vessel.
The gaseous source of energy holes includes those that sublime, boil, and/or are volatile at the elevated operating temperature of the gas energy reactor wherein the shrinkage reaction occurs in the gas phase. For example, RbNO,and KNO-. are each volatile at a temperature much less than that at which each decomposes [C. J. Hardy, B. 0. Field, J. Chem. Soc, (1963), pp. 5130-5134]. In one embodiment, the ionic hydrogen spillover catalytic material: 40% by weight potassium or rubidium nitrate on graphitic carbon powder with 5% by weight 1 %-Pd-on-graphitic carbon powder can be operated at a temperate at which the potassium or rubidium nitrate can be volatile. Further disproportionation reactions of the product, lower-energy hydrogen atoms, release additional heat energy.
In a preferred embodiment, the source of energy holes is a thermally stable salt of rubidium or potassium such as RbF, RbCl, RbBr, Rbl, Rb2S2, RbOH, Rb2S04, Rb2CO?, Rb,P04, and
KF, KCl, KBr, KI, K2S2, KOH, K2S04. K2CO-<, K,PO .K2GeF4. Further preferred sources of energy holes of approximately mX27.2\ eV to cause atomic hydrogen "shrinkage" and/or approximately mX48.6 eV to cause molecular hydrogen "shrinkage" where m is an integer include the electrocatalytic ions and couples described in my previous U.S. Patent Applications entitled "Energy/Matter Conversion Methods and Structures", Serial No. 08/467,051 filed on June 6, 1995 which is a continuation-in- part application of Serial No. 08/416,040 filed on April 3, 1995 which is a continuation-in-part application of Serial No.
08/107,357 filed on August 16, 1993, which is a continuation- in-part application of Serial No. 08/075.102 (Dkt. 99437) filed on June 1 1 , 1993, which is a continuation-in-part application of Serial No. 07/626,496 filed on December 12, 1990 which is a continuation-in-part application of Serial No. 07/345,628 filed April 28, 1989 which is a continuation-in-part application of Serial No. 07/341 ,733 filed April 21. 1989. which are incorporated herein by reference. The counterion includes those given in the Handbook of Chemistry and Physics. Robert C. Weast, Editor, 58 th Edition, CRC Press, West Palm Beach, Florida, (1974) pp. B61 -B 178 which is incorporated by reference herein. The preferred anion can be stable to hydrogen reduction and thermal decomposition and can be volatile at the operating temperature of the energy reactor.
The following compounds are preferred gaseous sources of energy holes in the gas energy reactor. Higher temperatures result in a higher vapor pressure of the source of energy holes which increases the reaction rate; however, the increase in total pressure increases the recombination rate of hydrogen atoms to hydrogen molecules. In each exemplary case that follows, the operating temperature of the energy reactor can be that which provides an optimal reaction rate.
In an embodiment, the cell temperature can be about 50°C higher than the (highest) melting point of the source of energy holes (in the case that the source of energy holes comprises an electron transfer between two cations—an electrocatalytic couple). The hydrogen pressure can be maintained at about
200 millitorr, and molecular hydrogen can be dissociated with a hot filament or grid 280 of FIGURE 7.
Single Ion Catalysts (Electrocatalytic Ions): Single-ion catalysts (electrocatalytic ions) capable of producing energy holes for shrinking hydrogen atoms. The number following the atomic symbol (n) is the nth ionization energy of the atom. That is for example, Rb+ + 27.28 eV = Rb2+ + e-. (melting point=(MP); boiling point=(BP))
Catalytic Ion n nth ionization energy Mo2+ 3 27.16
MoI2
Ti2 + 3 27.49
TiCl2(MP = subl H2,BP = d 475° vac)
(TiCL I Tιme l) Rb1+ 2 27.28
RbN03 (MP = 310° C, BP = subl)
Rb2S2(MP = 420° C, BP = volat > 850)
RbI(MP = 647° C,BP = \ 300° C)
Two Ion Catalyts (Electrocatalytic Couples):
Two-ion catalysts (electrocatalytic couples) capable of producing energy holes for shrinking hydrogen atoms. The number in the column following the ion, (n), is the nth ionization energy of the atom. That is for example, K+ + 31.63 eV = K2+ + e" and K+ + e" = K + 4.34 eV. (melting point=(MP); boiling point=(BP))
Atom n nth Ion- Atom n nth Ion-
Energy Oxidiz- ization Reduced ization
Hole ed Energy Energy
(ev)
(ev) (ev) Sn4+ 5 72.28 Si 4 + 4 45.14
27.14 S/2α4( P = -33°C,5P = l 14. TC) SiCl4{MP = -70° C,BP = 57.57° )
Pr 3 + 4 38.98 Ca 2 + 2 11.87 27.11
Pr5r,( P = 69rC,5/> = 1547°C) CaBr2(MP = 730° C i d,BP = 806 -812° C)
Sr 2 + 3 43.60 Cr 2 + 2 16.50 27.10
SrCl2{MP = 875°C,BP = 1250° ) Crl2{MP = 856°C.BP = 800 sub vac°C)
Cr 3 + 49.10 Tb 3 + 21.91 27.19 CrF^MP => 1000°C,.5P = 1100- 1200° C subl)
Tbl3 (MP = 946° C, BP > 1300° C)
Sb 3 + 4 44.20 Co 2 + 2 17.06 27.14
SbCl3(MP = 73. A°C,BP = 283° C) 0 (MP = 724° C in HCl gas, BP = 1049° C)
Bi 3 + 4 45.30 Ni 2 + 2 18.1 7 27.1 3
BiCl3(MP = 230 - 232° C, BP = 447° C)
Pd 2 + 3 32.93 In 1 + 1 5.79 27.14
PdF2 (MP = volat) InCl(MP = 225° C, BP = 608° C)
La 3 + 4 49.95 Dy3 + 3 22.80 27.15 LaCl, (MP = 860° C, BP > 1000° C) £>y /3 (MP = 718° C, 5P = 1500° C)
La 3 + 4 49.95 Ho 3 + 3 22.84
27.1 1 LaI3(MP = 772° ) HoI3(MP = 989° C,BP = 1300°C)
K 1 + 2 31 .63 K 1 + 1 4.34
27.28 KN03(MP = 334° , _9P = jiitø) £NO3 (MP = 334° , 5P = subl)
K2S2 (MP = 470° C) /^ (MP = 470° C)
KI(MP = 681° C,BP = \ 330° C) A7(MP = 681° C, 5P = 1330° C)
V 3 + 4 46.71 Pd 2 + 2 19.43
27.28 VF3(MP > 800° C,BP Subl) PbF2(MP = 855°C,.5P = 1290° C)
VOCl(BP = 127° C) PbI2(MP = 402° C, 5P = 954° C) Lu 3 + 4 45.19 Zn 2 + 2 17.96
27.23 LuCl3(MP = 905°C,i9P = subl 750° C) PbCl2(MP = 283° C,BP = 732° C)
As 3 + 4 50.13 Ho 3 + 3 22.84
27.29 AsI3(MP = \A6°C,BP = 403° C) HoI3 (MP = 989° C,BP = 1300°C)
Mo 5+ 6 68.00 Sn4+ 4 40.73 27.27
Møα,(MP = 194°C,.9P = 2680C) SnCl4(MP = -33° C,5P = 114.1°C)
Sb 3 + 4 44.20 Cd 2 + 2 16.91
27.29 5b/3(MP = 170° C,5P = 401°C) CdI2(MP = 387°C,5P = 796°C)
Ag 2 + 3 34.83 Ag 1 + 1 7.58
27.25 AgF2(MP = 690° C, BP = 700° d) AgF(MP = 435° C, BP = 1159° )
La 3+ 4 49.95 Er 3 + 3 22.74
27.21 LalΛMP = 772° C,BP = 1000° C) ErI3(MP = 1020° ,£P = 1280° )
V 4+ 5 65.23 B 3+ 3 37.93
27.30 VCl4 (MP = -28° C,BP = 148.5° C) 5C13(MP = -107.3° C,BP = 12.5° C)
Fe 3+ 4 54.80 Ti 3 + 3 27.49 27.31
FeCl3(MP - 306°C,BP = 3l5°Cd) 71Cl3(MP = AA0°Cd,BP = 660° C)
Co 2+ 3 33.50 TI 1 + 1 6.11
27.39 Co/2 (MP = 515 vac° C, BP = 570° C vac) 77/(MP = 440° C d,BP = 823° C)
CoF2(MP = 1200° C,BP = 1400°C) 77F( P = 327° Cd,BP = 655° C) Bi 3 + 4 45.30 Zn 2 + 2 17.96
27.34 BiBr3 (MP = 218° C, BP = 453° C) ZnBr2 (MP = 394° C d,BP = 650° C)
As 3 + 4 50.13 Dy3+ 3 22.80
27.33 Asl3 (MP = 146°C,BP = 403° C) Dyl3 (MP = 955°Cd,BP = l 320° )
Ho 3+ 4 42.50 Mg 2 + 2 15.03
27.47 HoCl3(MP = 718° C,BP= 1500° C) MgCl2(MP = 714° C,BP = 1412°C)
K 1 + 2 31.63 Rb 1 + 1 4.18 27.45
UT/(MP = 618° C, BP = 1330° C) Rb/(MP = 647° C,BP = 1300° C)
Cr3+ 4 49.10 Pr 3 + 3 21.62
27.48 CrCl3(MP = 1150°C,BP = 1300° Mb/) PrCl3 (MP = 786° C,BP = 1700° C)
Sr 2 + 3 43.60 Fe 2 + 2 16.18
27.42 " SrCl2(MP = 875° C,BP = 1250° C) FeCl2(MP = 670° C,BP subl)
Ni 2 + 3 35.17 Cu 1 + 1 7.73
27.44 NiCl2(MP = 1001° C,BP = 973° C subl) CuCl(MP = 430° C,BP = 1490° C)
Sr 2 + 3 43.60 Mo 2 + 2 16.15
27.45 SrCl2(MP = 875° C, BP = 1250° C) MoCl2
Y 3+ 4 61.80 Zr 4 + 4 34.34
27.46
YCI3(MP = 721° C.BP = 1507° C) ZτCl4(MP = 437° C,BP = 331° C subl) Cd2+ 3 37.48 Ba 2 + 10.00
27.48 Cdl2 (MP = 387° C, BP = 796° C) Bal2 (MP = 740° C)
Ho 3+ 4 42.50 Pb 2 + 2 15.03
27.47 HoI3 (MP = 989° C,BP = 1300° C) Pbl2 (MP = 402° C, BP = 954° C)
Pd2+ 3 32.93 Li 1 + 1 5.39
27.54 PdF2 (MP = volat) LϊF(MP = 845° C,BP = 1676° C)
Eu3+ 4 42.60 Mg 2 + 2 15.03 27.56
EuCl3 (MP = 850° C) MgCl2 (MP = 714° C,BP = 1412° C)
Er3+ 4 42.60 Mg 2 + 2 15.03
27.56 ErCl3(MP = 77A°C,BP = 1500° C) MgCl2(MP = 714° C,BP = 1412° C)
Bi 4 + 5 56.00 Al 3 + 3 28.45
27.55 BiCl4 (MP = 226° C) A Cl3 (MP = 190° C,BP = 177.8° C subl)
Ca2+ 3 50.91 Sm 3 + 3 23.40
27.51 CaBr2 (MP = 730° C si d, BP = 806-812° C) SmBr3 (MP subl > 1000° C)
V 3+ 4 46.71 La 3 + 3 19.18
27.53 VaF3(MP > 800° C, subl) LΆC1(MP = 860° C,BP > 1000°C)
Gd3+ 4 44.00 Cr 2 + 2 16.50 27.50
GdI(MP = 926° C,BP = 1340° C) Crl2(MP = 856° C,BP = 800° C subl vac) Mn 2 + 3 33.67 TI 1 + 1 6.1 1
27.56 Mnl2 (MP = 638° C vac, BP = 500° C subl vac) TIF(MP = 327° C, BP = 655° C)
Yb 3 + 4 43.70 Fe 2 + 2 1 6.1 8
27.52 YbBr3(MP = 956° C, BP = d) FeBr2 (MP = 684° d)
Ni 2 + 3 35.17 Ag 1 + 1 7.58
27.59 NiCl2(MP = 1001° C, BP = 973° C subl) AgCl(MP = 455° C,BP = 1550° C)
Zn 2 + 3 39.72 Yb 2 + 2 12.18
27.54 ZτzC 2 (MP = 283° C, BP = 732° Mb/) 7bC/2 (MP = 702° C,BP = 900° C)
Se 4 + 5 68.30 Sn 4 + 4 40.73 27.57
SeF4(MP = -13.8° C,BP > 100° ) SnCl4(MP = -33° C,BP = 114.1° C)
SnF4(MP = 705° C subl)
Sb 3 + 4 44.20 Bi 2 + 2 16.69
27.51 5W3(ΛfP = 170° C,BP = 401°C) BiI2(MP = 400°C,BP = subl vac)
Eu 3 + 4 42.60 Pb 2 + 2 1 5.03
27.57 EuF3(MP = 1390° C,BP = 2280° ) PbCl2(MP = 501° C,BP = 950° C) In an embodiment wherein the anion can be reduced by hydrogen, the anion is chemically stabilized. For example, the product of the reduction is added to the gas cell to stabilize the anion. In a further embodiment, the anion can be replaced continuously or intermittently. In the case of the nitrate ion, the product ammonia can be removed from the vessel, oxidized to nitrate, and returned to the cell. In one embodiment, the product ammonia can be removed from the vessel by collection in a condensor and can be oxidized to nitrate on a platinum or iridium screen at elevated temperatures such as 912 °C. In a further embodiment, the nitrate ion to ammonia reaction can be minimized by decreasing the hydrogen pressure while optimizing the vapor phase catalytic hydrogen shrinkage reaction. In an embodiment, a low pressure of hydrogen atoms can be generated by dissociation of molecular hydrogen on a hot filament or grid 280 of FIGURE 7. A low pressure of molecular hydrogen can be maintained via the hydrogen supply 221 , the hydrogen flow control means 222, and the hydrogen pressure measurement and vacuum means 223. The hydrogen pressure can be maintained at a low pressure by adjusting the supply through the inlet with flow controller 222 versus the amount pumped away at the outlet by the pressure measurement and pump means 223. The pressure can be adjusted to maximize the output power while minimizing the degradation of nitrate. The optimal hydrogen pressure can be less than about one torr. In an embodiment, the source of hydrogen atoms in the gas phase can be a hydrogen dissociation means including a hydrogen gas stream blown over a hot filament or grid 280 such as a hot refractory metal including a filament or grid of Ti, Ni, Fe, W, Au, Pt, or Pd at an elevated temperature such as 1800°C. The hydrogen molecular source can be directed over the filament or grid and onto the gaseous source of energy holes. The pressure and flow of the hydrogen atoms prohibits the collision of the counterion of the source of energy holes (such as the nitrate ion) from contacting the hot filament or grid. Thus, the thermal decomposition or reduction of the anion on the filament or grid can be prevented. In another embodiment, a negative potential can be maintained as a grid electrode 287 surrounding the filament or grid. The grid electrode permits the passage of hydrogen atoms rom the filament or grid and repels the anion from contacting the hot filament or grid. Thus, the thermal or chemical breakdown of the anion (couterion) can be prevented.
In an embodiment, the source of energy holes is an electrocatalytic ion or electrocatalytic couple comprising cation-anion pairs in the gas phase wherein the cation-anion pairs are dissociated by external source means 75 of FIGURE 5 which includes, for example, a particle source 75b and/or photon source 75a and/or a source of heat, acoustic energy, electric fields, or magnetic fields. In a preferred embodiment, the cation-anion pairs are thermally dissociated by heat source 230 or photodissociated by photon source 205 of FIGURE 7.
In another embodiment of the gas energy reactor having a gaseous source of energy holes, the source of energy holes is atomized with an atomizer means 295 to provide a gaseous source of energy holes. In a preferred embodiment of the atomizer, atoms are boiled, sublimed, or vaporized by a heating means such as the boat heating means 299, and the gaseous atoms are ionized to form a source of energy holes including the electrocatalytic ions or electrocatalytic couples of my previous patent applications incorporated herein by reference. In one embodiment, the atoms are thermally ionized by the heating means 230, by the hydrogen atom source 280 including a hot filament or grid, or by an inductively coupled plasma flow tube. For example, the gas energy cell shown in Figure 7 comprises rubidium or potassium metal in the boat 290 which has a vapor pressure that can be controlled by controlling the temperature of the boat by heating means 230 and or 299. Hydrogen molecules are dissociated to atoms on the hot filament or grid 280. The rubidium (potassium) metal in the gas phase can be ionized to Rb+ (K+) by the same or different hot filament or grid 280. The Rb+ (K+/K+) electrocatalytic ion (couple) serves as a source of energy holes to shrink the hydrogen atoms. In another embodiment, the hot filament c grid 280 comprises a metal(s) or can be electroplated with a metal(s) which boils off as a cation(s) that are a source of energy holes. For example, Mo2 + ions (Mo2+ electrocatalytic ion) enter the gas phase of the energy cell 200 from the hot molybdenum filament or grid 280. The hot molybdenum filament or grid 280 also dissociates hydrogen molecules to hydrogen atoms. For a further example, Ni2+ and Cu+ ions (Ni2+/Cu+ electrocatalytic couple) enter the gas phase of the energy cell 200 from the hot nickel and hot copper or hot nickel-copper alloy filament or grid 280. In another embodiment, the photon source 75a and the particle source 75b of FIGURE 5, including an electron beam, ionize species such as atoms in the gas phase to form the source of energy holes including the electrocatalytic ions or electrocatalytic couples of my previous patent applications incorporated herein by reference. In another embodiment, the atoms or ions are ionized chemically by a volatilized reactant such as an ionic species which oxidizes or reduces the atoms or ions to form a source of energy holes.
The power of the gas energy reactor can be controlled by controlling the amount of the source of energy holes (electrocatalytic ion or couple) in the gas phase and/or by controlling the concentration of atomic or lower-energy hydrogen. The concentration of the gaseous source of energy holes (electrocatalytic ion or couple) can be controlled by controlling the initial amount of the volatile source of energy holes (electrocatalytic ion or couple) present in the reactor, and/or by controlling the temperature of the reactor with temperature control means 230 which determines the vapor pressure of the volatile source of energy holes (electrocatalytic ion or couple). The reactor temperature further controls the power by changing the rate of the catalytic hydrogen shrinkage reaction. The concentration of atomic hydrogen can be controlled by controlling the amount of atomic hydrogen provided by the atomic hydrogen source 280. For example, the amount of hydrogen atoms in the gas phase can be controlled by controlling the flow of hydrogen over or through the hot filament or grid, the tungsten capillary heated by electron bombardment, or the inductively coupled plasma flow tube; by controlling the power dissipated in the inductively coupled plasma flow tube; by controlling the temperature of the hot filament or grid, or the tungsten capillary heated by electron bombardment; by controlling the pressure of the hydrogen and temperature of the hydride maintained under nonequilibrium conditions, and by controlling the rate of removal of recombined hydrogen from the cell by pump means 223. Another means to control the shrinkage reaction rate can be by controlling the pressure of a non reactive gas with non reactive gas source 299, non reactive gas flow control means 232, and pressure measurement and pump means 223. The non reactive gas such as a noble gas competes with collisions between the source of energy holes (electrocatalytic ion or couple) and hydrogen atoms or competes with collisions that yield lower-energy hydrogen disproportionation reactions. Noble gases include He, Ne, and Ar. Further such reaction non reactive " reaction quenching" gases include carbon dioxide and nitrogen.
The hydrogen partial pressure can be further controlled by throttling hydrogen into the cell by a hydrogen value control means 222 while monitoring the pressure with a pressure measurement means 222 and 223. In a preferred embodiment, the hydrogen pressure can be controlled by controlling the temperature with heating means 230 of the gas energy reactor which further comprises a hydrogen storage means such as a metal hydride or other hydride including saline hydrides, titanium hydride, vanadium, niobium, and tantalum hydrides, zirconium and hafnium hydrides, rare earth hydrides, yttrium and scandium hydrides, transition element hydrides, intermetalic hydrides, and their alloys known in the art as given by W. M. Mueller, J. P. Blackledge, and G. G. Libowitz, Metal Hydrides. Academic Press, New York, ( 1968), Hydrogen in Intermetalic Compounds I. Edited by L. Schlapbach, Springer-Verlag, Berlin, and Hydrogen in Intermetalic Compounds II. Edited by L. Schlapbach, Springer- Verlag, Berlin, which are incorporated by reference herein. The temperature of the cell can be controlled by a temperature control and measurement means 230 such that the vapor pressure of the hydrogen in equilibrium with the hydrogen storage material can be the desired pressure. In one embodiment, nonequilibrium conditions of the hydrogen and hydride are maintained by controlling the temperature and hydrogen pressure to provide atomic hydrogen. In several embodiments, the hydrogen storage means can be a rare earth hydride with an operating temperature of about 800 °C; lanthanum hydride with an operating temperature of about 700 °C; gadolinium hydride with an operating temperature of about 750 °C; neodymium hydride with an operating temperature of about 750 °C; yttrium hydride with an operating temperature of about 800 °C; scandium hydride with an operating temperature of about 800 °C; ytterbium hydride with an operating temperature of about 850-900 °C; titanium hydride with an operating temperature of about 450 °C; cerium hydride with an operating temperature of about 950 °C; praseodymium hydride with an operating temperature of about 700 °C; zirconium-titanium (50%/50%) hydride with an operating temperature of about 600 °C; an alkali metal/alkali metal hydride mixture such as Rb/RbH or K/KH with an operating temperature of about 450 °C, and an alkaline earth metal/alkaline earth hydride mixture such as Ba/BaH2 with an operating temperature of about 900- 1000 °C.
The heat output can be monitored with thermocouples present in at least the vessel 200 and the heat exchanger 60 of
FIGURE 5. The rate of the shrinkage reaction rate can be monitored by ultraviolet or electron spectroscopy of the photons or electrons emitted via lower-energy hydrogen transitions, by X-ray photoelectron spectroscopy (XPS) of lower-energy hydrogen, and by mass spectroscopy, Raman or infrared spectroscopy, and gas chromatography of the molecular lower-energy hydrogen (dihydrino). Lower-energy hydrogen atoms and molecules are identified by XPS as higher binding energy species than normal hydrogen. The dihydrino can be identified by mass spectroscopy as a species with a mass to charge ratio of two (m/e=2) that has a higher ionization potential than that of normal hydrogen by recording the ion current as a function of the electron gun energy. The dihydrino can be identified by gas chromatography at low temperature such as gas chromatography with an activated carbon (charcoal) column at liquid nitrogen temperature or with a column that will separate para from ortho hydrogen such as an Rt-Alumina column, or a HayeSep column at liquid nitrogen temperature wherein normal hydrogen can be retained to a greater extent than dihydrino. The dihydrino can be identified by Raman and infrared spectroscopy as a molecule with higher vibrational and rotational energy levels as compared to those of normal hydrogen. The output power can be controlled by a computerized monitoring and control system which monitors the thermistors, spectrometers, and gas chromatograph and controls the means to alter the power output. The (molecular) lower-energy hydrogen can be removed by a means 201 to prevent the exothermic shrinkage reaction from coming to equilibrium.
In another embodiment of the gas energy reactor having a gaseous source of energy holes, hydrogen atoms are produced by a pyrolysis reaction such as the combustion of a hydrocarbon wherein the catalytic source of energy holes can be in the gas phase with the hydrogen atoms. In a preferred mode, the pyrolysis reaction occurs in an internal combustion engine whereby the hydrocarbon or hydrogen containing fuel comprises a source of energy holes that are vaporized (become gaseous) during the combustion. In a preferred mode, the source of energy holes (electrocatalytic ion or couple) is a thermally stable salt of rubidium or potassium such as RbF, RbCl, RbBr, Rbl, Rb2S2, RbOH, Rb2S04, Rb2C03, Rb3P04, and KF, KG, KBr, KI, K2S2, KOH, K S04, K2C03, K3P04,K GeF4.
Additional counterions of the electrocatalytic ion or couple include organic anions including wetting or emulsifying agents. In another embodiment, the hydrocarbon or hydrogen containing fuel further comprises water as a mixture and a solvated source of energy holes including emulsified electrocatalytic ions or couples. During the pyrolysis reaction, water serves as a further source of hydrogen atoms which undergo a shrinkage reaction catalyzed by the source of energy holes wherein the water can be dissociated to hydrogen atoms thermally or catalytically on a surface such as the cylinder or piston head which can be comprised of material which dissociates water to hydrogen and oxygen. The water dissociation material includes an element, compound, alloy, or mixture of transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite).
POWER DENSITY OF GAS ENERGY REACTOR (GAS PHASE HYDROGEN SHRINKAGE REACTION)
The equations numbers which follow referred to those given by Mills [Mills, R., The Grand Unified Theory of Classical Quantum Mechanics. (1995), Technomic Publishing Company, Lancaster, PA]. The rate of the disproportionation reaction, r m.m-.p. t0 cause resonant shrinkage, Eqs. (5.22-5.30), is dependent on the collision rate between the reactants and the efficiency of resonant energy transfer. It is given by the product of the rate constant, km m. p,(Eq. (5.47)), the total number of hydrogen or hydrino atoms, NH , and the efficiency, E (Eq. (6.33)), of the transfer of the resonance shrinkage energy from the donor hydrino atom to the energy hole provided by the
R = (8.8 X 10'25) Jη^φD° κ2 where r is the distance between the donor and the acceptor, J is the overlap integral between the resonance shrinkage energy distribution of the donor hydrino atom and the distribution of the energy hole provided by the acceptor hydrino atom, η is the dielectric constant, and κ2 is a function of the mutual orientation of the donor and acceptor transition moments. Electronic transitions of lower-energy hydrogen atoms occur only by nonradiative energy transfer; thus, the quantum yield of the fluorescence of the donor, ΦD, of Eq.
(6.37) is equal to one. The rate of the disproportionation reaction, rm m. p, to cause resonant shrinkage is
The factor of one half in Eq. (6.38) corrects for double counting of collisions [Levine, I., Physical Chemistry, McGraw-Hill Book Company, New York, (1978), pp. 420-421]. The power, Pm ,p t is given by the product of the rate of the transition, Eq. (6.38), and the energy of the disproportination reaction (Eq. (5.27)).
where V is the volume. For a disproportionation reaction in the gas phase, the energy transfer efficiency is one. The power given by substitution of
E = l, p = 2, m = l, m' = 2, V = 1 m3, N = 3 X 102 T = 675 K (6.40) into Eq. (6.39) is
Pm ,p = GW (l kW / cm3) (6.41 )
In the case that the reaction of hydrogen to lower- energy states occurs by the reaction of a catalytic source of energy holes with hydrogen or hydrino atoms, the reaction rate is dependent on the collision rate between the reactants and the efficiency of resonant energy transfer. The hydrogen- or-hydrino-atom/electrocatalytic-ion collision rate per unit volume, Z a -, , for a gas containing nH hydrogen or
Catalyst hydrino atoms per unit volume, each with radius -^ and
P velocity vH and nc electrocatalytic ions per unit volume, each with radius rCa[alyst and velocity vc is given by Levine [Levine, I.,
Physical Chemistry, McGraw-Hill Book Company, New York,
The average velocity, vavg, can be calculated from the temperature, T, [Bueche, F. J., Introduction to Physics for Scientists and Engineers, McGraw-Hill Book Company, New York, (1986), pp. 261-265].
1 2 3 l (6.43) where k is Boltzmann's constant. Substitution of Eq. (5.44) into Eq. (5.42) gives the collision rate per unit volume, in terms of the temperature. T.
Catalyst p
(6.44)
Catalyst The rate of the catalytic reaction, r , to cause resonant shrinkage is given by the product of the collision rate per unit volume, Z r . , the volume, V, and the efficiency, E, of
Catalyst
P resonant energy transfer given by Eq. (6.37).
The power, Pm p, is given by the product of the rate of the transition, Eq. (6.45), and the energy of the transition, Eq.
+ m2]X2.2X10-ls W
(6.46) In the case of a gas phase catalytic shrinkage reaction wherein the source of energy holes is a single cation having an ionization energy of 27.21 eV with hydrogen or hydrino atoms, the energy transfer efficiency is one. Rubidium ( Rb*) is an electrocatalytic ion with a second ionization energy of 27.28 eV. The power for the reaction given by Eqs. (5.9), (5.10), and
(5.8) with the substitution of
E = 1, p = 1, m - 1, V = 1 m3, NH = 3 X 102' , .Vc = 3 X 1021 ,
(6.47) mc = 1.4 X 10-25 kg, rc = 2.16 X 10-'° m, T = 675 K into Eq. (6.46) is
Pm p = 55 GW (55 kW I cm3) (6.48) In the case that the catalytic reaction of hydrogen to lower- energy states occurs on a surface, the energy transfer efficiency is less than one due to differential surface interactions of the absorbed hydrogen or hydrino atoms and the electrocatalytic ion. The power given by Eqs. (6.46) and (6.47) with
E = 0.001 (6.49) is
Pnι p = 55 MW (55 Wl cm3) (6.50)
Less efficient catalytic systems hinge on the coupling of three resonator cavities. For example, an electron transfer occurs between two cations which comprises an energy hole for a hydrogen or hydrino atom. The reaction rate is dependent on the collision rate between catalytic cations and hydrogen or hydrino atoms and the efficiency of resonant energy transfer with a concomitant electron transfer with each shrinkage reaction. The rate of the catalytic reaction, rm p, to cause resonant shrinkage is given by the product of the collision rate per unit volume, Z , the volume, V, and a L \ Catalyst the efficiency, Ee , of resonant energy transfer given by Εq. (6.37) where r is given by the average distance between cations in the reaction vessel.
The power, Pm p, is given by the product of the rate of the transition, Εq. (6.51). and the energy of the transition, Εq. (5.8).
P m.p = E c [2m + m2]X2.2X10-18 W
(6.52) A catalytic system that hinges on the coupling of three resonator cavities involves potassium. For example, the second ionization energy of potassium is 31.63 eV. This energy hole is obviously too high for resonant absorption. However, K* releases 4.34 eV when it is reduced to K. The combination of K* to K2* and K* to K, then, has a net energy change of 27.28 eV. Consider the case of a gas phase catalytic shrinkage reaction of hydrogen or hydrino atoms by potassium ions as the electrocatalytic couple having an energy hole of 27.28 eV. The energy transfer efficiency is given by Eq. (6.37) where r is given by the average distance between cations in the reaction vessel. When the K* concentration is 3 1022 — K* , r is m approximately 5 X 10"9 m. For J = l, ΦD = 1 , κ2 = 1, τo = 10~13 sec
(based on the vibrational frequency of KH*), and m = 1 in Eq (5.8), the energy transfer efficiency, Ec, is approximately 0.001.
The power for the reaction given by Eqs. (5.13), (5.14), and (5.8) with the substitution of
E = 0.001, p = l, m = l, V = l m3, NH = 3 X 1022, Nc = 3 X 1021,
(6 31 mc = 6.5 10"26 kg, rc = 1.38 X 10"10 m, T= 675 K into Eq. (6.52) is Pm p = 300 MW (300 W I cm3) (6.54
Gas Discharge Energy Reactor
A gas discharge energy reactor comprises a hydrogen isotope gas filled glow discharge vacuum chamber 300 of FIGURE 8 including an ozonizer-type capacitor, a hydrogen source 322 which supplies hydrogen to the chamber 300 through control valve 325, and a voltage and current source 330 to cause current to pass between a cathode 305 and an anode 320. In one embodiment comprising an ozonizer-type capacitor gas discharge cell, one of the electrodes can be shielded by a dielectric barrier such as glass or a ceramic moiety. In a preferred embodiment, the cathode further comprises a source of energy holes of approximately mX27.21 eV to cause atomic hydrogen "shrinkage" and/or approximately mX48.6 eV to cause molecular hydrogen
"shrinkage" where m is an integer (including the electrocatalytic ions and couples described in my previous U.S. patent applications entitled "Energy/Matter Conversion Methods and Structures", Serial No. 08/467,051 filed on June 6, 1995 which is a continuation-in-part application of Serial No. 08/416,040 filed on April 3, 1995 which is a continuation- in-part application of Serial No. 08/107,357 filed on August 16, 1993, which is a continuation-in-part application of Serial No. 08/075,102 (Dkt. 99437) filed on June 1 1 , 1993, which is a continuation-in-part application of Serial No. 07/626,496 filed on December 12, 1990 which is a continuation-in-part application of Serial No. 07/345,628 filed April 28, 1989 which is a continuation-in-part application of Serial No. 07/341 ,733 filed April 21 , 1989 which are incorporated by reference). A preferred cathode 305 for shrinking hydrogen atoms is a palladium cathode whereby a resonant energy hole can be provided by the ionization of electrons from palladium to the discharge current. A second preferred cathode 305 for shrinking hydrogen atoms comprises a source of energy holes via electron transfer to the discharge current including at least one of beryllium, copper, platinum, zinc, and tellurium and a hydrogen dissociating means such as a source of electromagnetic radiation including UV light provided by photon source 350 or a hydrogen dissociating material including the transition elements and inner transition elements, iron, platinum, palladium, zirconium, vanadium, nickel, titanium, Sc, Cr, Mn, Co, Cu, Zn, Y, Nb, Mo. Tc, Ru, Rh, Ag, Cd, La, Hf, Ta, W, Re, Os, Ir, Au, Hg, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Vb, Lu, Th, Pa, U, activated charcoal (carbon), and intercalated Cs carbon (graphite). The reactor further comprises a means to control the energy dissipated in the discharge current when electrons are transferred from an electron donating species to provide an energy hole for hydrogen atoms (molecules) including pressure controller means 325 and current (voltage) source 330. The gas discharge energy reactor further comprises a means 301 to remove the (molecular) lower-energy hydrogen such as a selective venting valve to prevent the exothermic shrinkage reaction from coming to equilibrium. In another embodiment of the gas discharge energy reactor, the source of energy hole can be one of a inelastic photon or particle scattering reaction(s). In a preferred embodiment the photon source 350 supplies the energy holes where the energy hole corresponds to stimulated emission by the photon. In the case of a reactor which shrinks hydrogen atoms, the photon source 350 dissociates hydrogen molecules into hydrogen atoms. The photon source producing photons of at least one energy of approximately mX27.21 eV, — X27.21 eV, or
40.8 eV causes stimulated emission of energy as the hydrogen atoms undergo the shrinkage reaction. In another preferred embodiment, a photon source 350 producing photons of at least one energy of approximately mXA8.6 eV , 95.7 eV , or mX31.94 eV causes stimulated emission of energy as the hydrogen molecules undergo the shrinkage reaction.
In another embodiment, a magnetic field can be applied by magnetic field generator 75 of FIGURE 5 to produce a magnetized plasma of the gaseous ions which can be a nonlinear media. Coupling of resonator cavities and enhancement of the transfer of energy between them can be increased when the media is nonlinear. Thus, the reaction rate (transfer of the resonance shrinkage energy of the hydrogen atoms to the energy holes, the electrocatalytic ions or couples) can be increased and controlled by providing and adjusting the applied magnetic field strength.
In one embodiment of the method of operation of the gas discharge energy reactor, hydrogen from source 322 can be introduced inside of the chamber 300 through control valve
325. A current source 330 causes current to pass between a cathode 305 and an anode 320. The hydrogen contacts the cathode which comprises a source of energy holes of approximately mX27.21 eV to cause atomic hydrogen "shrinkage" and approximately mX48.6 eV to cause molecular hydrogen "shrinkage" where m is an integer. In a preferred embodiment, electrons are transferred from an electron donating species present on the cathode 305 to the discharge current to provide energy holes for hydrogen atoms (molecules). In the case of a reactor which shrinks hydrogen atoms, the molecular hydrogen can be dissociated into atomic hydrogen by a dissociating material on the cathode 305 or by a source of electromagnetic radiation including UV light provided by photon source 350 such that the dissociated hydrogen atoms contact a source of energy holes including a molten, liquid, gaseous, or solid source of the energy holes. The atomic (molecular) hydrogen releases energy as its electrons are stimulated to undergo transitions to lower energy levels by the energy holes. The energy dissipated in the discharge current when electrons are transferred from an electron donating species can be controlled to provide an energy hole equal to the resonance shrinkage energy for hydrogen atoms (molecules) by controlling the gas pressure from source 322 with pressure controller means 325 and the voltage with the current (voltage) source 330. The heat output can be monitored with thermocouples present in at least the cathode 305, the anode 320, and the heat exchanger 60 of FIGURE 5. The output power can be controlled by a computerized monitoring and control system which monitors the thermistors and controls the means to alter the power output. The (molecular) lower-energy hydrogen can be removed by a means 301 to prevent the exothermic shrinkage reaction from coming to equilibrium.
In another embodiment of the gas discharge energy reactor, a preferred cathode 305 comprises the catalytic material including a spillover catalyst described in the
Pressurized Gas Energy Reactor Section.
Another embodiment of the gas discharge energy reactor comprises a gaseous source of energy holes wherein the shrinkage reaction occurs in the gas phase, and the gaseous hydrogen atoms are provided by a discharge of molecular hydrogen gas. In a further embodiment the gaseous source of energy holes can be provided by a discharge current which produces the gaseous source of energy holes (electrocatalytic ion or couple) such as a discharge in potassium metal to form K+/K+, rubidium metal to form Rb+, or titanium metal to form Ti2+. The embodiment comprises a hydrogen isotope gas filled glow discharge chamber 300. The glow discharge cell can be operated at an elevated temperature such this the source of energy holes (electrocatalytic ion or couple) can be sublimed, boiled, or volatilized into the gas phase. In an embodiment, the counterion of the source of energy holes (electrocatalytic ion or couple) can be the hydride anion ( H~) such as rubidium hydride (Rb+ electrocatalytic ion) and/or potassium hydride (K+/K+ electrocatalytic couple).
In an embodiment, the source of energy holes can be an electrocatalytic ion or electrocatalytic couple comprising cation-anion pairs in the gas phase wherein the cation-anion pairs are dissociated by external source means 75 of FIGURE 5 which includes, for example, a particle source 75b and/or photon source 75a and/or a source of heat, acoustic energy, electric fields, or magnetic fields. In a preferred embodiment, the cation-anion pairs are thermally dissociated by heat source 75 of FIGURE 5 or photodissociated by photon source 350 of FIGURE 8.
Refrigeration Means A further embodiment of the present invention comprises a refrigeration means which comprises the electrolytic cell of FIGURE 6, the pressurized hydrogen gas cell of FIGURE 7, and the hydrogen gas discharge cell of FIGURE 8 of the present invention wherein a source of lower-energy atomic (molecular) hydrogen is supplied rather than a source of normal hydrogen. The lower-energy hydrogen atoms are reacted to a higher energy state with the absorption of heat energy according to the reverse of the catalytic shrinkage reaction such as those given by Eqs. (4-6); (7-9); ( 10- 12); (13- 15); ( 16- 18); (48-50); (51 -53); (54-56); (57-59); (60-62), (63-
65), (66-68), (69-71 ), (72-74), and (75-77). The lower-energy hydrogen molecules are reacted to a higher energy state with the absorption of heat energy according to the reverse of the catalytic shrinkage reaction such as that given by Eqs. (78-80); (81 -83); (84-86); (88-90), and (91 -93). In this embodiment, means 101 , 201 and 301 of FIGURES 6, 7, and 8, respectively, serve to remove the normal hydrogen such as a selective venting valves to prevent the endothermic reaction from coming to equilibrium.
Compositions of Matter Comprising at Least Lower-Energy Hydrogen Atom(s) and/or Lower-Energy Hydrogen MoleculeCs
The present invention further comprises molecules containing lower-energy hydrogen atoms. Lower-energy hydrogen can be reacted with any atom of the periodic chart or known organic or inorganic molecule or compound or metal, nonmetal, or semiconductor to form an organic or inorganic molecule or compound or metal, nonmetal, or semiconductor containing lower-energy hydrogen atoms and molecules. The reactants with lower-energy hydrogen include neutral atoms, negatively or positively charged atomic and molecular ions, and free radicals. For example, lower-energy hydrogen can be reacted with water or oxygen to form a molecule containing lower-energy hydrogen and oxygen, and lower-energy hydrogen can be reacted with singly ionized helium to form a molecule containing helium and lower-energy hydrogen.
Lower-energy hydrogen can be also reacted with metals. In one embodiment of the electrolytic cell energy reactor, lower- energy hydrogen produced during operation at the cathode can be incorporated into the cathode by reacting with it; thus, a metal-lower-energy hydrogen material can be produced. In all such reactions, the reaction rate and product yield are increased by applying heat, and/or pressure.
Lower-energy hydrogen molecules (dihydrinos) are purified from hydrogen gas by combustion of the normal hydrogen. Oxygen can be mixed with the sample to be purified, and the sample can be ignited. In a second embodiment of the method of dihydrino purification, the sample can be flowed over a hydrogen recombiner which reacts with the normal hydrogen in the gas stream to form water. In a third embodiment, lower-energy hydrogen molecules (dihydrinos) are collected in a cathode of an electrolytic energy reactor of the present invention such as a metal cathode including a nickel cathode or a carbon cathode. The cathode can be heated in a vessel to a first temperature which causes normal hydrogen to preferentially off gas by external heating or by flowing a current through the cathode. The normal hydrogen can be pumped off, then the cathode can be heated to a second higher temperature at which dihydrino gas can be released and collected. In a fourth embodiment, the gas sample is purified by cryofiltration including gas chromatography at low temperature such as gas chromatography with an activated carbon (charcoal) column at liquid nitrogen temperature and with a column which will separate para from ortho hydrogen such as an Rt-Alumina column, or a HayeSep column at liquid nitrogen temperature wherein normal hydrogen can be retained to a greater extent than dihydrino. In a fifth embodiment, the gas sample is purified by cryodistillation wherein normal hydrogen can be liquefied and separated from gaseous lower-energy hydrogen (dihydrino). The dihydrino can be concentrated by liquefaction in liquid helium.
EXPERIMENTAL VERIFICATION OF THE PRESENT THEORY
Example 1 .
The article by Mills and Good [Mills, R., Good, W., "Fractional Quantum Energy Levels of Hydrogen", Fusion
Technology, Vol. 28, No. 4, November, (1995), pp. 1697-1719] describes the determination of excess heat release during the electrolysis of aqueous potassium carbonate by the very accurate and reliable method of heat measurement, flow calorimetry; describes the experimental identification of hydrogen atoms in fractional quantum energy levels — hydrinos — by X-ray Photoelectron Spectroscopy (XPS); describes the experimental identification of hydrogen atoms in fractional quantum energy levels — hydrinos — by emissions of soft x-rays from dark matter; describes the experimental identification of hydrogen molecules in fractional quantum energy levels — dihydrino molecules by high resolution magnetic sector mass spectroscopy with ionization energy determination, and gives a summary.
In summary: The complete theory which predicts fractional quantum energy levels of hydrogen and the exothermic reaction whereby lower-energy hydrogen is produced is given elsewhere [Mills, R., The Grand Unified Theory of Classical Quantum Mechanics. (1995), Technomic Publishing Company, Lancaster, PA provided by HydroCatalysis Power Corporation, Great Valley Corporate Center, 41 Great Valley Parkway, Malvern, PA 19355, R. Mills; Unification of Spacetime. the Forces. Matter, and Energy (Technomic Publishing Company, Lancaster, PA, 1992)]. Excess power and heat were observed during the electrolysis of aqueous potassium carbonate. Flow calorimetry of pulsed current electrolysis of aqueous potassium carbonate at a nickel cathode was performed in a single-cell dewar. The average power out of 24.6 watts exceeded the average input power (voltage times current) of 4.73 watts by a factor greater than 5. The total input energy (integration of voltage times current) over the entire duration of the experiment was 5.72 MJ; whereas, the total output energy was 29.8 MJ. No excess heat was observed when the electrolyte was changed from potassium carbonate to sodium carbonate. The source of heat is assigned to the electrocatalytic, exothermic reaction whereby the electrons of hydrogen atoms are induced to undergo transitions to quantized energy levels below the conventional "ground state". These lower energy states correspond to fractional quantum numbers: n = 1/2, 1/3, 1/4,
... . Transitions to these lower energy states are stimulated in the presence of pairs of potassium ions (K+/K+ electrocatalytic couple) which provide 27.2 eV energy sinks.
The identification of the n = 1/2 hydrogen atom , H(n = 1/2) is reported. Samples of the nickel cathodes of aqueous potassium carbonate electrolytic cells and aqueous sodium carbonate electrolytic cells were analyzed by XPS. A broad peak centered at 54.6 eV was present only in the cases of the potassium carbonate cells. The binding energy (in vacuum) of H(n = 1/2) is 54.4 eV. Thus, the theoretical and measured binding energies for H(n = 1/2) are in excellent agreement. Further experimental identification of hydrinos — down to
H(n = 1/8) — can be found in the alternative explanation by Mills et al. for the soft X-ray emissions of the dark interstellar medium observed by Labov and Bowyer [S. Labov and S. Bowyer, Astrophysical Journal, 371 (1991) 810] of the Extreme UV Center of the University of California, Berkeley. The agreement between the experimental spectrum and the energy values predicted for the proposed transitions is remarkable .
The reaction product of two H(n=l/2) atoms, the dihydrino molecule, was identified by mass spectroscopy
(Shrader Analytical & Consulting Laboratories). The mass spectrum of the cryofiltered gases evolved during the electrolysis of a light water K2C03 electrolyte with a nickel cathode demonstrated that the dihydrino molecule, H2(n = 1/2), has a higher ionization energy, about 63 eV, than normal molecular hydrogen, H2(n = 1), 15.46 eV. The high resolution (0.001 AMU) magnetic sector mass spectroscopic analysis of the postcombustion gases indicated the presence of two peaks of nominal mass two at 70 eV and one peak at 25 eV. The same analysis of molecular hydrogen indicates only one peak at 25 eV and one peak at 70 eV. In the case of the postcombustion sample at 70 eV, one peak was assigned as the hydrogen molecular ion peak, H2 (n = 1 ), and one peak was assigned as the . dihydrino molecular peak, H2 (n = 1/2) which has a slightly larger magnetic moment.
Example 2.
In the January 1994 edition of Fusion Technology, [Mills, R., Good, W., Shaubach, R., "Dihydrino Molecule Identification", Fusion Technology, 25, 103 (1 .94)] Mills et al. review and present three sets of data of heat production and "ash" identification including the work of HydroCatalysis Power Corporation (Experiments #l-#3) and Thermacore, Inc. (Experiments # 4-#14).
In summary:
Mills et al. report the experimental evidence supporting the Mills theory that an exothermic reaction occurs wherein the electrons of hydrogen atoms and deuterium atoms are stimulated to relax to quantized potential energy levels below that of the "ground state" via electrochemical reactants K+ and K+; Pd2+ and Li+, or Pd and 0 of redox energy resonant with the energy hole which stimulates this transition. Calorimetry of pulsed current and continuous electrolysis of aqueous potassium carbonate (K+/K+ electrocatalytic couple) at a nickel cathode was performed. The excess power out of 41 watts exceeded the total input power given by the product of the electrolysis voltage and current by a factor greater than 8. The "ash" of the exothermic reaction is atoms having electrons of energy below the "ground state" which are predicted to form molecules. The predicted molecules were identified by lack of reactivity with oxygen, by separation from molecular deuterium by cryofiltration, and by mass spectroscopic analysis.
The combustion of the gases evolved during the electrolysis of a light water K2C03 electrolyte (K+/K+ electrocatalytic couple) with a nickel cathode was incomplete. The mass spectroscopic analysis (Air Products & Chemicals, Inc.) of uncombusted gases demonstrated that the species predominantly giving rise to the m/e = 2 peak must have a different m/e = 1 to m/e = 2 production efficiency than hydrogen. And, the further mass spectroscopic analysis of the m/e = 2 peak of the uncombusted gas demonstrated that the dihydrino molecule, H2(n = 1/2), has a higher ionization energy than H2. According to the analysis 1 / Mills et al. of the raw data,
Miles of the China Lake Naval Air Warfare Center Weapons Division observed the dideutrino molecule as a species with a mass to charge ratio of four and having a higher ionization potential than normal molecular deuterium. Miles was using mass spectroscopy to analyze the cryofiltered gases evolved from excess power producing electrolysis cells (palladium cathode and a LiOD/D 0 electrolyte; an electrocatalytic couple of 27.54 eV). [B. F. BUSH, J. J. LAGOWSKI, M. H. MILES, and G. S. OSTROM, "Helium Production During the Electrolysis of D 0 in Cold Fusion Experiments", J. Electroanal. Chem., 304, 271 (1991); M. H. MILES, B. F. BUSH, G. S. OSTROM, and J. J. LAGOWSKI, "Heat and Helium Production in Cold Fusion
Experiments", Proc. Conf. The Science of Cold Fusion , Como, Italy, June 29-July 4, 1991 , p. 363, T. BRESSANI, E. DEL GIUDICE, and G. PREPARATA, Eds., SIF (1991); M. H. MILES, R. A. HOLLINS, B. F. BUSH, J. J. LAGOWSKI, and R. E. J. MILES, "Correlation of Excess Power and Helium Production During
D 0 and H20 Electrolysis Using Palladium Cathodes", J. Electroanal. Chem., 346, 99 (1993); M. H. MILES and B. F. BUSH, "Search for Anomalous Effects Involving Excess Power and Helium During D20 Electrolysis Using Palladium Cathodes," Proc. 3rd Int. Conf. Cold Fusion, Nagoya, Japan, October 21-25,
1992, p. 189].
Palladium sheets coated on one side with a hydrogen impermeant gold layer and coated on the other surface with an oxide coat (MnO , A10x, SiOx) were deuterium or hydrogen loaded at NTT Laboratories. Heat was observed from light and heavy hydrogen only when the mixed oxide coat was present (Pd/0 electrocatalytic couple). The high resolution (.001 AMU) quadrapole mass spectroscopic analysis of the gases released when a current was applied to a deuterium (99.9%) loaded MnOx coated palladium sheet indicate the presence of a large shoulder on the D2 peak which Mills et al. assign to the dideutrino molecule, D2(n = 1/2). [E. YAMAGUCHI and T. NISHIOKA, "Direct Evidence for Nuclear Fusion Reactions in Deuterated Palladium," Proc. 3rd Int. Conf. Cold Fusion,, Nagoya, Japan, October 21-25, 1992, p. 179; E. YAMAGUCHI and T. NISHIOKA, "Helium-4 Production from Deuterated Palladium at Low Energies," NTT Basic Research Laboratories and IMRA Europe S. A., Personal Communication (1992)].
Example 3. Pennsylvania State University has determined excess heat release from flowing hydrogen in the presence of nickel oxide powder containing strontium niobium oxide (Nb3+/Sr2 + electrocatalytic couple) by the very accurate and reliable method of heat measurement, thermopile conversion of heat into an electrical output signal [Phillips, J., "A Calorimetric Investigation of the Reaction of Hydrogen with Sample PSU #1 ", September 1 1 , 1994, A Confidential Report submitted to HydroCatalysis Power Corporation provided by HydroCatalysis Power Corporation, Great Valley Corporate Center, 41 Great Valley Parkway, Malvern, PA 19355]. Excess power and heat were observed with flowing hydrogen over the catalyst which increased with increasing flow rate. However, no excess power was observed with flowing helium over the catalyst/nickel oxide mixture or flowing hydrogen over nickel oxide alone. As shown in FIGURE 9, approximately 10 cc of nickel oxide powder containing strontium niobium oxide immediately produced 0.55 W of steady state output power at 523 °K. When the gas was switched from hydrogen to helium, the power immediately dropped. The switch back to hydrogen restored the excess power output which continued to increase until the hydrogen source cylinder emptied at about the 40,000 second time point. With no hydrogen flow the output power fell to zero.
The source of heat is assigned to the electrocatalytic, exothermic reaction whereby the electrons of hydrogen atoms are induced to undergo transitions to quantized energy levels below the conventional "ground state". These lower energy states correspond to fractional quantum numbers: n = 1/2, 1/3, 1/4, ... . Transitions to these lower energy states are stimulated in the presence of pairs of niobium and strontium ions (Nb3+/Sr2+ electrocatalytic couple) which provide 27.2 eV energy sinks. Example 4 .
The article in the Spectral Data of Hydrinos from the Dark Interstellar Medium and from the Sun Section of Mills [Mills, R., The Grand Unified Theory of Classical Quantum
Mechanics. (1995), Technomic Publishing Company, Lancaster, PA] describes the experimental identification of hydrogen atoms in fractional quantum energy levels — hydrinos — by emissions of soft X-rays from dark matter and the Sun; provides a resolution to the Solar Neutrino Problem, the
Temperature of the Solar Corona Problem, the Broadening of the Hydrogen 911.8A Line Problem, the Temperature of the Transition from "Radiation Zone" to "Convection Zone" Problem, the Cool Carbon Monoxide Clouds Problem, the Stellar Age Problem, the Solar Rotation Problem, the Solar Flare Problem, and the problem of the ionizing energy source of hydrogen planets, and describes the experimental identification of hydrogen atoms in fractional quantum energy levels — hydrinos — by spin/nuclear hyperfine structure transition energies obtained by COBE for which no other satisfactory assignment exists.
In summary:
As shown in Table 1 Mills [Mills, R., The Grand Unified Theory of Classical Quantum Mechanics. (1995), Technomic
Publishing Company, Lancaster, PA], hydrogen transitions to electronic energy levels below the "ground" state corresponding to fractional quantum numbers predicted by Mills' theory match the spectral lines of the extreme ultraviolet background of interstellar space. And, hydrogen disproportionation reactions yield ionized hydrogen, energetic electrons, and hydrogen ionizing radiation. This assignment resolves the paradox of the identity of dark matter and accounts for many celestial observations such as: diffuse Hoc emission is ubiquitous throughout the Galaxy, and widespread sources of flux shortward of 912 A are required [Labov, S., Bowyer, S., "Spectral observations of the extreme ultraviolet background", The Astrophysical Journal, 371 , ( 1991 ), pp. 810- 819] .
Further experimental identification of hydrinos — down to H(n = 1/8) — can be found in the alternative explanation by Mills for the soft X-ray emissions of the dark interstellar medium observed by Labov and Bowyer [S. Labov and S. Bowyer, Astrophysical Journal, 371 (1991 ) 810] of the Extreme UV Center of the University of California, Berkeley. The agreement between the experimental spectrum and the energy values predicted for the proposed transitions is remarkable .
The paradox of the paucity of solar neutrinos to account for the solar energy output by the pp chain is resolved by assigning a major portion of the solar output to lower-energy hydrogen transitions. The photosphere of the Sun is 6000 K; whereas, the temperature of the corona based on the assignment of the emitted X-rays to highly ionized heavy elements is in excess of 106 K. No satisfactory power transfer mechanism is known which explains the excessive temperature of the corona relative to that of the photosphere.
The paradox is resolved by the existence of a power source associated with the corona. The energy which maintains the corona at a temperature in excess of 106 K is that released by disproportionation reactions of lower-energy hydrogen as given by Eqs. ( 13-15). In Table 2 of Mills, the energy released by the transition of the hydrino atom with the initial lower- energy state quantum number p and radius — - to the state
P with lower-energy state quantum number (p + m) and radius - — catalyzed by a hydrino atom with the initial lower-
(p + m) energy state quantum number rri , initial radius -JL , and final m' radius aH are given in consecutive order of energy from the 1 → 1 / 2 H transition to the 1 / 9 → 1 / 10 H transition. The agreement between the calculated and the experimental values is remarkable. Furthermore, many of the lines of Table 2 had no previous assignment, or the assignment was unsatisfactory [Thomas, R. J., Neupert. W., M., Astrophysical Journal Supplement Series, Vol. 91 , H 994), pp. 461 -482; Malinovsky, M., Heroux, L., Astrophysical Journal, Vol. 181 , (1973), pp. 1009-1030; Noyes. R., The Sun. Our Star. Harvard University Press, Cambridge, MA, (1982), p.172; Phillips, J. H., Guide to the Sun. Cambridge University Press, Cambridge, Great Britain, (1992), pp. 1 18-1 19; 120- 121 ; 144-145] . The calculated power of 4 X 1026 W matches the observed power output of 4 X 1026 W . The broadening of the solar H I 911.8 A line
( 911.8.4 rσ = 600 A ) is six times that, predicted based on the thermal electron energy at the surface of the photosphere ( T = 6,000 K) where the H I 911.8 A continuum originates, and based on the relative width of the helium continuum lines, He I 504.3 A ( He I 504.3 A to = 530 A) and He Η 227.9 A
( He II 227.9 A to = 225 ) [Thomas, R. J.. Neupert, W., M., Astrophysical Journal Supplement Series, Vol. 91 , (1994), pp. 461-482; Stix, M., The Sun. Springer- Verlag, Berlin, (1991 ), pp. 351-356; Malinovsky, M., Ηeroux, L.. Astrophysical Journal, Vol. 181 , (1973), pp. 1009-1030; Noyes, R., The Sun. Our Star. Harvard University Press, Cambridge. MA, (1982), ρ.172; Phillips, J. H., Guide to the Sun. Cambridge University Press, Cambridge, Great Britain, (1992), pp. 1 18-119; 120-121 ; 144- 145]. The latter lines are proportionally much narrower; yet, the corresponding temperatures of origin must be higher because the transitions are more energetic. Furthermore, the H 911.8 ,4 continuum line of the spectrum of a prominence is about one half the width of the same line of the quiet Sun spectrum. Yet, the temperature rises to greater than 10,000 K in a prominence. The problem of the anomalous spectral feature of the excessive broadening of the continuum line of hydrogen to higher energies can be resolved by assignment of the broadening mechanism to energetic disproportionation reactions involving hydrogen atoms as reactants. The reaction product, lower-energy hydrogen, can be reionized as it is diffuses towards the center of the Sun. The abrupt change in the speed of sound and transition from "radiation zone" to "convection zone" at a radius of 0.7 the solar radius, 0.7R5, with a temperature of 2 X 106 Λ' matches the ionization temperature of lower-energy hydrogen.
Another spectroscopic mystery concerns an infrared absorption band of the chromosphere at a wavelength of 4.7 μm which was previously assigned to carbon monoxide despite the implausibility of its existence in the observed region which has a temperature above that at which carbon monoxide would break up into its constituent carbon and oxygen atoms. This problem can be resolved by assignment of the broad 4.7 μm feature to a temperature broadened rotational transition of a molecular ion of lower-energy hydrogen. The assignment of the 4.7 μm absorption line to the 7 = 0 to 7 = 1 transition rotational transition of H*[2c' = 3α0]+ provides a resolution of the problem of cool carbon monoxide clouds.
Modeling how stars evolve leads to age estimates for some stars that are greater than the age of the universe. Mills' theory predicts that presently, stars exist which are older than the elapsed time of the present expansion as stellar evolution occurred during the contraction phase.
General Relativity provides a resolution to the problem of the loss of angular momentum of the core which is in agreement with the current Solar models and helioseismology data. The photon transfer of momentum to expanding spacetime mechanism provides a resolution to the solar rotation problem of the slowly rotating Solar core.
Further stellar evidence of disproportionation reactions is the emission of extreme ultraviolet radiation by young stars called A stars. They appear to have energetic, ultraviolet- emitting upper atmospheres, or coronas, even though astronomers believe such stars lack the ability to heat these regions.
Numerous late-type stars, particularly dM stars, are known to flare from time to time at visible and X-ray wavelengths. An extremely pronounced flare was observed by the Extreme Ultraviolet Explorer (EUVE) Deep Survey telescope on the star AU Microscopii at a count of 20 times greater than that at quiescence [Bowyer, S., Science, Vol. 263, ( 1994), pp. 55-59] . Emission lines in the extreme ultraviolet were observed for which there is no satisfactory assignment. These spectral lines match hydrogen transitions to electronic energy levels below the "ground" state corresponding to fractional quantum numbers as shown in Table 3 of Mills. The lines assigned to lower-energy hydrogen transitions increased significantly in intensity during the flare event. The data is consistent with disproportionation reactions of lower-energy hydrogen as the mechanism of solar flare activity.
Planetary evidence of disproportionation reactions is the emission of energy by Jupiter, Saturn, and Uranus in excess of that absorbed from the Sun. Jupiter is gigantic ball of gaseous hydrogen. Saturn and Uranus are also largely comprised of hydrogen. H3 + is detected from all three planets by infrared emission spectroscopy [J. Tennyson, Physics World, July, ( 1995), pp. 33-36] . Disproportionation reactions of hydrogen yield ionizing electrons, energy, and ionized hydrogen atoms. Ionizing electrons and protons can both react with molecular hydrogen to produce H3 .
The spin/nuclear hyperfine structure transition energies of lower-energy hydrogen match closely certain spectral lines obtained by COBE [E. L. Wright, et. al., The Astrophysical Journal, 381 , (1991 ), pp. 200-209; J. C. Mather, et. al., The
Astrophysical Journal, 420, (1994), pp. 439-444] for which no other satisfactory assignment exists.
Example 5. Pennsylvania State University has determined excess heat release from flowing hydrogen in the presence of ionic hydrogen spillover catalytic material: 40% by weight potassium nitrate (KNO3) on graphitic carbon powder with 5% by weight 1 %-Pd-on-graphitic carbon (K+/K+ electrocatalytic couple) by the very accurate and reliable method of heat measurement, thermopile conversion of heat into an electrical output signal [Phillips, J., Shim, Η., "Additional Calorimetric Examples of Anomalous Heat from Physical Mixtures of K/Carbon and Pd/Carbon", January 1 , 1996, A Confidential Report submitted to HydroCatalysis Power Corporation provided by HydroCatalysis Power Corporation, Great Valley Corporate Center, 41 Great Valley Parkway, Malvern, PA 19355]. Excess power and heat were observed with flowing hydrogen over the catalyst. However, no excess power was observed with flowing helium over the catalyst mixture. Rates of heat production were reproducibly observed which were higher than that expected from the conversion of all the hydrogen entering the cell to water, and the total energy observed was over four times larger than that expected if all the catalytic material in the cell were converted to the lowest energy state by "known" chemical reactions. Thus, "anomalous" heat, heat of a magnitude and duration which could not be explained by conventional chemistry, was reproducibly observed.
Example 6. Excess heat from a pressurized gas energy cell having a gaseous source of energy holes has been observed by HydroCatalysis Power Corporation [manuscript in progress] with low pressure hydrogen in the presence of molybdenum iodide (MoI ) (Mo2+ electrocatalytic ion) which was volatilized at the operating temperature of the cell, 210 °C. The calorimeter was placed inside a large convection oven that maintained the ambient temperature of the cell at the operating temperature. The cell comprised a 40 cc stainless steel pressure vessel that was surrounded by a 2 inch thick molded ceramic thermal insulator. The cell was sealed with a vacuum tight flange that had a two hole Buffalo gland for a tungsten wire to dissociate molecular hydrogen, a perforation for a Type K thermocouple, a 1/16 inch inlet for hydrogen which was connected to a 1/4 inch stainless steel tube which connected to the hydrogen supply. The flange was sealed with a copper gasket. The bottom of the vessel had a 1/4" vacuum port connected to a stainless steel tube with a valve between the cell and a vacuum pump and vacuum gauge. Less than one gram of M0I2 catalyst was placed in a ceramic boat inside the vessel. The vapor pressure of the catalyst was estimated to be about 50 millitorr at the operating temperature 210 °C. The hydrogen pressure of about 200 to 250 millitorr was controlled manually by adjusting the supply through the inlet versus the amount pumped away at the outlet where the pressure was monitored in the outlet tube by the vacuum gauge. For each run, the total pressure was made (including the MoI2 pressue in the case of the experimental run) precisely 250 millitorr.
The output power was determined by measuring difference between the cell temperature and the ambient oven temperature and comparing the result to a calibration curve generated by applying power to the inside of the cell with the tungsten filament. Excess power of 0.3 watts was observed from the 40 cc stainless steel reaction vessel containing less than 1 g of MoI2 when hydrogen was flowed over the hot tungsten wire ( - 2000 °C). However, no excess power was observed when helium was flowed over the hot tungsten wire or when hydrogen was flowed over the hot tungsten wire with no MoI2 present in the cell. Rates of heat production were reproducibly observed which were higher than that expected from the conversion of all the hydrogen inside the cell to water, and the total energy observed was over 30 times larger than that expected if all the catalytic material in the cell were converted to the lowest energy state by "known" chemical reactions. Thus, "anomalous" heat, heat of a magnitude and duration which could not be explained by conventional chemistry, was reproducibly observed.
The gaseous contents of the reactor were monitored with a mass spectrometer. At the time that excess energy was produced corresponding to the case wherein hydrogen was flowed over the hot filament, a higher ionizing mass two species was observable; whereε , during the control run wherein hydrogen was flowed over the hot tungsten wire with no MoI2 present in the cell, a higher ionizing mass two species was not observed. The higher ionizing mass two species is assigned to the dihydrino molecule, 2H 2
→ H 2c' =

Claims

Claims :
1. A cell comprising: a vessel capable of containing a vacuum or pressures greater than atmospheric; an effective amount of a material for forming a gaseous transition catalyst for catalyzing the transition of a hydrogen atom to an energy state lower than n=l, where n is the energy state of an electron in said free hydrogen atom; a source of hydrogen atoms in the gas phase,* means for forming said gaseous transition catalyst from said material; and means for contacting said gaseous transition catalyst with said hydrogen atoms in said vessel under conditions whereby said hydrogen atoms undergo a transition to an energy state lower than n=l and releases energy.
2. A cell according to claim 1, wherein said gaseous transition catalyst is adapted to absorb a multiple of about 27 eV from said hydrogen atom when said hydrogen atom undergoes said transition to a lower energy state.
3. A cell according to claim 1, wherein said gaseous transition catalyst is adapted to have a resonant absorption with the energy released by said hydrogen atom when said hydrogen atom undergoes said transition to a lower energy state.
4. A cell according to claim 1, wherein said source of hydrogen atoms comprises a hydrogen containing gas and means for disassociating said hydrogen containing gas.
5. A cell according to claim 4, wherein said source of hydrogen atoms comprises at least one of a hot filament and a hydrogen containing gas stream, a hot grid and a hydrogen containing gas stream, a tungsten capillary heated by electron bombardment to 1800-2000 K and a hydrogen gas containing stream, a hydride maintained under nonequilibrium conditions, and an inductively coupled plasma flow tube and a hydrogen gas containing stream.
6. A cell according to claim 1, wherein said source of hydrogen atoms comprises a hydrogen containing gas stream and a second catalyst for disassociating said hydrogen containing gas stream into free hydrogen atoms.
7. A cell according to claim 6, wherein said hydrogen disassociation catalyst comprises at least one element selected from the group of the transition elements, lanthanides, and activated charcoal.
8. A cell according to claim 1, further comprising means for absorbing energy from said hydrogen atom undergoing said transitions.
9. A cell according to claim 1, further comprising means for removing molecular hydrogen having an energy state lower than n=l.
10. A cell according to claim 1, further comprising a boat or container for containing said material, and means for connecting said boat or container to said vessel.
11. A cell according to claim 10, wherein said boat or container further comprises means for heating said material contained therein.
12. A cell according to claim 1, wherein said gaseous transition catalyst is an ionic compound which is resistant to hydrogen reduction.
13. A cell according to claim 1, wherein said material is adapted to sublime, boil, or become volatile when heated.
14. A cell according to claim 1, wherein said material comprises a salt of rubidium or potassium.
15. A cell according to claim 1, wherein said material comprises a salt of rubidium which is selected from the group consisting of RbF, RbCl, RbBr, Rbl, Rb2S2, RbOH, Rb2S04, Rb2C03/ and R b3P04.
16. The cell according to claim 1, wherein said material comprises a salt of potassium which is selected from the group consisting of KF, KC1, KBr, KI, K2S2, KOH, K2S04, K2C03, K2P04, and K2GeF4.
17. The cell according to claim 1, wherein said material is adapted to provide a vapor pressure greater than 0 of a cation selected from the group consisting of (Rb+) , (Mo +) , and (Ti2+) , when said material is heated.
18. The cell according to claim 1, wherein said material is adapted to provide a pair of cations having a vapor pressure greater than 0 when said material is heated, said pair of cations being selected from the group consisting of: (Sn4+, Si4+) , (Pr3+, Ca2+) , (Sr2+, Cr2+) , (Cr3+, Tb3+) , (Sb3+, Co2+) , (Bi3+,
Ni2+) Pd2+, In+) , (La3+, Dy3+) , (La3+, Ho3+) , (K+, K+) , (V3+, Pd2+) , (Lu3+, Zn2+) , (As3+, Ho3+) , (Mo5+ Sn4+) , (Sb3+, Cd2+) , (Ag2+, Ag+) , (La3+, Er3+) (V4+, B3+) , (Fe3\ Ti3+) , (Co2+, Ti+) , (Bi3+ Zn2+) , (As3+, Dy3+) , (Ho3+, . Mg2+) , (K\ Rb+) , (Cr3+, Pr3+) , (Sr2+, Fe2+) (Ni2 Cu+) (Sr2+ Mo2+) , (Y3+, Zr4*) , (Cd2+, Ba2+) , (Ho 3 + Pb2+) (Pd 2* Li*) , (Eu3\ Mg2+) (Er3+, Mg2+) , (Bi + Al3+) , (Ca2\ Sm3+) , (V3 La3+) , (Gd3+, Cr2+) (Mn2 Ti+) , (Yb3+, Fe2+) , Ni2 Ag+) , (Zn2+ Yb2+) , (Se4+, Sn4+) , (Sb3 Bi2+) , and (Eu3+ Pb +) .
19. A cell according to claim 1, wherein said material comprises a salt which can be vaporized or volatized into ions.
20. A cell according to claim 19, wherein said salt comprises one or more cations and at least one anion selected from the group consisting of halides, sulfates, phosphates, carbonates, hydroxide, and sulfides .
21. A cell according to claim 1, wherein said means for forming said gaseous transition catalyst from said material comprises at least one of heat, electron-beam energy, photon energy, acoustic energy, electric field, or magnetic field.
22. A cell according to claim 1, wherein said material is adapted to provide gaseous atoms, said means for forming said transition catalyst further comprising means for ionizing said gaseous atoms to form said gaseous transition catalyst.
23. A cell according to claim 1, further comprising means for heating said material, wherein said material is adapted to provide gaseous atom when said material is heated, and said means for forming said transition catalyst comprising means for ionizing said gaseous atoms.
24. A cell according to claim 1, wherein said material comprises a filament which when active forms said gaseous transition catalyst .
25. A cell according to claim 1, wherein said means for forming said gaseous transition catalyst comprises a filament and said material is coated on said filament.
26. A cell according to claim 11, wherein said material is adapted to provide gaseous atoms when heated, and said means for forming said transition catalyst comprising means for ionizing said gaseous atoms.
27. A cell according to claim 10, wherein said material comprises a salt which can be vaporized or volatized into ions.
28. A cell according to claim 1, further comprising a nonreactive gas wherein the power is controlled by controlling the amount of said nonreactive gas.
29. A cell according to claim 1, wherein said source of hydrogen atoms comprises a means for pyrolysis of hydrocarbons or water.
30. A cell according to claim 29, wherein said cell comprises an internal combustion engine cylinder.
31. A cell according to claim 1, further comprising a means for controlling a power output of said cell, said power output controlling means comprising means for controlling the amount of said gaseous transition catalyst or said hydrogen atoms.
32. A cell according to claim 31, wherein said means for controlling the amount of said gaseous transition catalyst comprises means for controlling the temperature of said cell, wherein said material is adapted to have a vapor pressure dependent upon the temperature of said cell.
33. A cell according to claim 10, further comprising means for controlling a power output of said cell, said power output controlling means comprising means for controlling the temperature in said boat or container, wherein said material is adapted to have a vapor pressure dependent upon the temperature of said boat or container.
34. A cell according to claim 31, wherein the amount of said hydrogen atoms is controlled by controlling the flow of hydrogen atoms from said hydrogen atom source.
35. A cell according to claim 5, further comprising a means for controlling a power output of said cell, said power output controlling means comprising means: for controlling the flow of said hydrogen containing gas over at least one of said hot filament, said tungsten capillary heated by electron bombardment, or said inductively coupled plasma flow tube; or for controlling the power dissipated in said inductively coupled plasma flow tube; or for controlling a temperature of said hot filament or said tungsten capillary heated by electron bombardment; or for controlling the pressure of hydrogen and temperature of said hydride maintained under nonequilibrium conditions.
36. A cell according to claim 1, further comprising means for controlling a power output of said cell, said power output controlling means comprising means for monitoring the quantity of said released energy.
37. A cell according to claim 1, further comprising means for controlling a power output of said cell, said power output controlling means comprising a computerized monitoring and control system which monitors at least one of a thermistor, spectrometer, or gas chromatograph.
38. A method of extracting energy from hydrogen atoms comprising the steps of: volatizing a material to form a gaseous transition catalyst; providing hydrogen atoms; and contacting said gaseous transition catalyst with said hydrogen atoms under conditions whereby said hydrogen atoms undergo a transition to an energy state lower than n=l and energy is released from said hydrogen atoms, wherein n is the energy state of an electron in a free hydrogen atom and said gaseous transition catalyst is a catalyst for catalyzing the transition of hydrogen to an energy state lower than n=l.
39. A method according to claim 38, wherein said step of providing hydrogen atoms comprises the step of disassociating a hydrogen containing gas into hydrogen atoms.
40. A method according to claim 38, wherein said step of providing hydrogen atoms comprises at least one of passing a hydrogen containing gas over a hot filament, passing a hydrogen containing gas over a hot grid, passing a hydrogen containing gas through a tungsten capillary heated by electron bombardment to 1800-2000 K, or maintaining a hydride under nonequilibrium conditions, or passing a hydrogen containing gas through an inductively coupled plasma flow tube.
41. A method according to claim 38, wherein said step of providing hydrogen atoms comprises contacting a hydrogen containing gas with a second catalyst for disassociating said hydrogen containing gas stream into free hydrogen atoms.
42. A method according to claim 38, wherein said gaseous transition catalyst absorbs a multiple of about 27 eV from said hydrogen when said hydrogen atoms undergo said transition to a lower energy state.
43. A method according to claim 38, wherein said gaseous transition catalyst is adapted to have a resonant absorption with the energy- released by said hydrogen atoms when said hydrogen atoms undergo said transition to a lower energy state.
44. A method according to claim 38, further comprising the steps of conducting said method in a cell comprising a vessel having the capability of containing a vacuum or pressure greater than atmospheric.
45. A method according to claim 38, further comprising the step of controlling a power output of said cell.
46. A method according to claim 45, wherein said step of controlling a power output of said cell includes controlling a flow of hydrogen atoms into said cell.
47. A method according to claim 38, further comprising the step of absorbing said released energy.
48. A method according to claim 38, further comprising the step of removing molecular hydrogen having an energy state lower than n=l.
49. A method according to claim 38, wherein the step of volatizing a material to form a gaseous transition catalyst comprises the steps of volatizing said material to form gaseous atoms and ionizing said gaseous atoms .
50. A method of making hydrinos comprising the steps of : volatizing a material to form a gaseous transition catalyst; forming hydrogen atoms; and contacting said gaseous transition catalyst with said hydrogen atoms under conditions whereby said hydrogen atoms undergo a transition to an energy state lower than n=l and energy is released from said hydrogen atoms to thereby form said hydrinos, wherein n is the energy state of an electron in a free hydrogen atom and said gaseous transition catalyst is a catalyst for catalyzing the transition of hydrogen to an energy state lower than n=l .
51. A method according to claim 50, further comprising the steps of collecting and purifying said hydrinos.
EP96919010A 1995-06-06 1996-05-31 Lower-energy hydrogen methods and structures Withdrawn EP0858662A4 (en)

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US46705195A 1995-06-06 1995-06-06
US467051 1995-06-06
US59271296A 1996-01-26 1996-01-26
US592712 1996-01-26
PCT/US1996/007949 WO1996042085A2 (en) 1995-06-06 1996-05-31 Lower-energy hydrogen methods and structures

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AU6146596A (en) 1997-01-09
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AU705379B2 (en) 1999-05-20
RU2180458C2 (en) 2002-03-10
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CN1187146A (en) 1998-07-08
BR9608924A (en) 2000-11-21
PL324187A1 (en) 1998-05-11
KR19990022396A (en) 1999-03-25
MX9709701A (en) 1998-07-31
HUP9901773A2 (en) 1999-09-28
CA2218895A1 (en) 1996-12-27
CN1099305C (en) 2003-01-22
CA2218895C (en) 2001-08-28
PL186102B1 (en) 2003-10-31
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WO1996042085A2 (en) 1996-12-27
EP0858662A4 (en) 2001-04-18

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