EP0844867A1 - Preparations cosmetiques contenant des lactylates acyliques, des hydrolysats proteiques et des condensats d'acide gras proteique - Google Patents

Preparations cosmetiques contenant des lactylates acyliques, des hydrolysats proteiques et des condensats d'acide gras proteique

Info

Publication number
EP0844867A1
EP0844867A1 EP96927707A EP96927707A EP0844867A1 EP 0844867 A1 EP0844867 A1 EP 0844867A1 EP 96927707 A EP96927707 A EP 96927707A EP 96927707 A EP96927707 A EP 96927707A EP 0844867 A1 EP0844867 A1 EP 0844867A1
Authority
EP
European Patent Office
Prior art keywords
protein
acid
hydrolyzates
fatty acid
contain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP96927707A
Other languages
German (de)
English (en)
Inventor
Nagao Totani
Kakushi Dohki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Personal Care and Nutrition GmbH
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0844867A1 publication Critical patent/EP0844867A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/645—Proteins of vegetable origin; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

Definitions

  • the invention relates to cosmetic preparations for washing the skin and hair, which foams strongly after the shampoo application gives a neutral organoleptic impression and thereby causes only a minimum of skin and hair irritation
  • Anionic surfactants such as Alkyl sulfates, alkyl ether sulfates, monoalkyl phosphates, sulfosuccinates, ester sulfonates or soaps are widely used for the production of surfactants for skin and hair cleaning. These compounds are notable for a good cleaning action and foaming, but have an excessively irritating and degreasing effect on the skin or hair, so that the user perceives an uncomfortably dry feeling after using the shampoo and often even causes skin and hair damage. On the other hand, less strongly irritating surfactants only have inadequate foaming and cleaning behavior. Due to the uncomfortable feeling of dryness that the above-mentioned surfactants cause when cleaning the skin, shampoo formulations are usually moisturizing substances such as animal or vegetable extracts, polyols, acyl lactylates or acyl glycolates added
  • composition of this shampoo also includes an anionic surfactant such as lauryl sulfate, since the shampoo based on fatty acid lactylate does not provide satisfactory foam properties.
  • an anionic surfactant such as lauryl sulfate
  • US 4,946,832 describes a basic composition for cosmetics which, in addition to sugar esters and acyl octylates, also contains solvents Prevent the skin from drying out, but in practice it has been shown that a satisfactory feeling on the skin cannot be achieved.
  • mixtures are known from Japanese patent application JP-A2 Hei 6/40850 which, in addition to acyl octylates, can contain additional surfactants such as, for example, acyl isethnicates, alkyl betaines, acyl taurates, ethoxylated fatty acid amides, sulfosuccinates, alkyl phosphates or alkyl polygiucosides.
  • additional surfactants such as, for example, acyl isethnicates, alkyl betaines, acyl taurates, ethoxylated fatty acid amides, sulfosuccinates, alkyl phosphates or alkyl polygiucosides.
  • the creaminess of the foam is not satisfactory.
  • the object of the invention was therefore to provide cosmetic products which, on the one hand, produce a creamy, stable foam and, on the other hand, produce a pleasant feeling on the skin and hair when shampooing.
  • Another object of the invention was to develop preparations which are distinguished by a particularly advantageous dermatological compatibility.
  • the invention relates to cosmetic preparations containing
  • Acyl lactylates are known anionic surfactants which can be obtained by the relevant methods of preparative organic chemistry. One method of producing them is, for example, to allow fatty acid and lactic acid to react in the presence of NaOH or KOH at 140-210 ° C. for a total of 3 to 10 hours and to continuously remove the water of condensation from the equilibrium.
  • the lactylate with free acid content produced in this way can be neutralized as required using various alkaline compounds or amines.
  • the acyl lactylates preferably follow the formula (I)
  • R'CO stands for a linear or branched acyl group 6 with 18 carbon atoms
  • n for numbers from 1 to 3 and M for hydrogen, an alkali and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
  • lactylates derived from fatty acids 6 to 18 and preferably 12 to 14 carbon atoms as there are: caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, isopalmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, Petrose ⁇ linic acid, linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures, which, for example in the pressure splitting of natural fats and oils or in the reduction of aldehydes from Roelen's oxosynthesis. Lactylates based on technical coconut fatty acid cuts are preferably used
  • the protein hydrolyzates to be used as component (b) are also known substances which are usually prepared by alkaline, acidic and / or enzymatic hydrolysis of animal polypeptides such as collagen or keratin.
  • vegetable protein hydrolyzates such as soy protein hydrolyzate, almond protein hydrolyzate, rice protein hydrolyzate and - because of its particularity high dermatological tolerance - wheat protein hydrolyzate used These compounds have a molecular weight in the range from 500 to 5000, preferably 1000 to 2000 daltons and contain amino acids such as glycine, proline, hydroxyproline, glutamic acid or their peptide compounds.
  • Protein fatty acid condensates which form component (c), are reaction products of the protein hydrolysates already mentioned above with fatty acids, which preferably follow formula (II),
  • R 2 CO stands for a linear or branched acyl radical with 6 to 22 carbon atoms.
  • Typical examples are condensate products of collagen hydrolyzate keratin hydrolyzate soy protein hydrolyzate almond protein hydrolyzate rice protein hydrolyzate and / or wheat protein hydrolyzate with caproic acid, caprylic acid, 2-ethyluric acid, isoacetic acid, lauric acid, isoacetic acid, acid, palmitic acid, isopalmitic acid, paimoic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and erucic acid as well as their technical mixtures, which are used, for example, in the pressure splitting or natural oil splitting or oil splitting the reduction of aldehydes from Roelen
  • Collagen and wheat protein condensates with technical coconut fatty acids with 12 to 18 carbon atoms are preferably used, which can be present in the form of their alkali and / or alkaline earth metal salts, ammonium, alkylammonium, alkanolammonium and / or glucammonium salts.
  • the concentration of the acyl lactylate in the preparations according to the invention is preferably 1 to 40 and in particular 1 to 20% by weight.
  • the proportion of protein fatty acid condensates can make up 5 to 20, but preferably 7 to 15% by weight of the composition.
  • the concentration of the protein hydrolyzates is usually 2 to 10% by weight, but preferably 3 to 8% by weight of the composition.
  • the weight ratio of condensate to hydrolyzate is in the range from 1: 1 to 3: 1. All information relates to the agents according to the invention and is supplemented with a corresponding amount of water to 100% by weight.
  • the preparations according to the invention can preferably contain, in amounts of 1 to 40% by weight, based on the composition, of further anionic and / or nonionic surfactants.
  • anionic surfactants are alkylbenzenesulfonates, alkanesulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, ⁇ -methyl ester sulfonates, sulfofatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, hydroxymixed ether sulfates, monoglycerosulfate, sulfate amine sulfate amine sulfate, sulfate amate sulfate amate sulfate, monoglyate sulfate, sulfate amine sulfate, monoglyate s
  • anionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • Typical examples of nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, mixed ethers or mixed forms, alk (en) yl oligoglycosides, fatty acid esters, polyol fatty acid ester, polyol ester, polyglycol ester, polyglycol ester, polyglycol ester, polyglycol ester, polyol glycol ester, fatty acid polyol ester, polyol ester, Amine oxides.
  • nonionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • the surfactants mentioned are exclusively known compounds. With regard to the structure and manufacture of these substances, reference is made to relevant reviews, for example J.Falbe (ed.), “Surfactants in Consumer Products", Springer Verlag, Berlin, 1987, pp. 54-124 or J.Falbe (ed.), " Catalysts, surfactants and mineral oil additives ", Thieme Verlag, Stuttgart, 1978, pp. 123-217.
  • the agents according to the invention preferably contain as further side alkyl sulfates, alkyl ether sulfates, sulfosuccinates, alkyl (ether) phosphates and / or alkyl oligoglucosides.
  • the preparations according to the invention can furthermore contain, as further auxiliaries and additives, emulsifiers, superfatting agents, constituents, thickeners, cation polymers, silicone compounds, biogenic agents, film formers, preservatives, colorants and fragrances.
  • Nonionic, ampholytic and / or zwitterionic surface-active compounds which are distinguished by a lipophilic, preferably linear alkyl or alkenyl group and at least one hydrophilic group can be used as emulsifiers or co-emulsifiers.
  • This hydro- The phile group can be either an ionogenic or a nonionic group.
  • Non-ionic emulsifiers contain as a hydrophilic group z.
  • Preferred agents are those which contain nonionic surfactants from at least one of the following groups as O / W emulsifiers:
  • polystyrene resin e.g. Polyglycerol polyricinoleate or polyglycerol poly-12-hydroxystearate Mixtures of compounds from several of these classes of substances are also suitable.
  • the adducts of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters, and sorbitan mono- and diesters with fatty acids or with castor oil are known, commercially available products Homolog mixtures, whose average degree of alkoxylation corresponds to the ratio of the amounts of ethylene oxide and / or propylene oxide and substrate with which the addition reaction is carried out, corresponds to Cme fatty acid monoesters and diesters of addition products of ethylene oxide with glycerol are known from DE-PS 2024 051 as refatting agents for known cosmetic preparations
  • C ⁇ nralkyl mono- and oligoglycosides their preparation and their use as surface-active substances are, for example, from US 3,839,318, US 3,707,535, US 3,547,828, DE-OS 19 43 689, DE-OS 20 36 472 and DE-A1 30 01 064 and EP-A 0 077 167 known They are produced in particular by reacting glucose or oligosaccharides with primary alcohols with 8 to 18 carbon atoms.
  • the glycoside residue both monogiycosides in which a cyclic sugar residue is glycosidically bound to the fatty alcohol and oligomeric glycosides with a degree of oligomerization apply until preferably about 8 are suitable.
  • the degree of oligomerization is a statistical mean value which is based on a homolog distribution customary for such technical products
  • Zwitterionic surfactants can also be used as emulsifiers.
  • Zwitterionic surfactants are surface-active compounds that carry at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the coconut alkyldimethylammonium glycinate N-acylamino propyl-NN-dimethylammonium glycinate, for example the coconut acylaminopropyldimethylammonium glycinate and 2-alkyl-3-carboxylate Hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
  • betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the coconut alkyldimethylammonium glycinate N-acylamino propyl-NN-dimethylammonium glycinate, for example the coconut acylamin
  • fatty acid amide derivative known under the CTFA name Cocamidopropyl Betaine is particularly preferred.
  • suitable emulsifiers are ampholytic surfactants.
  • Ampholytic surfactants are to be understood as meaning those surface-active compounds which, in addition to a C 1-8 alkyl or acyl group, contain at least one free amino group and at least one -COOH or -SOaH group in the molecule and are capable of forming internal salts.
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each with about 8 to 18 carbon atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are the N-coconut alkylaminopropionate, the coconut acylaminoethylaminopropionate and the Cwi ⁇ -acylsarcosine.
  • Substances such as polyethoxylated lanolin derivatives, lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides can be used as superfatting agents, the latter simultaneously serving as foam stabilizers.
  • Suitable consistency agents are primarily fatty alcohols with 12 to 22 and preferably 16 to 18 carbon atoms. A combination of these substances with alkyl oligoglucosides and / or fatty acid N-methyl-glucamides of the same chain length and / or polyglycerol poly-12- is preferred. hydroxystearates.
  • Suitable thickeners are, for example, polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinyl pyrrolidone, surfactants such as, for example Fatty alcohol ethoxyates with a narrow homogeneous distribution or alkyl oligoglucosides as well as electrolytes such as table salt and ammonium chloride.
  • polysaccharides in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinyl pyrrolidon
  • Suitable cationic polymers are, for example, cationic cellulose derivatives, cationic starch, copolymers of diallylammonium salts and acrylamides, quaternized vinylpyrrolidone / inyl imidazole polymers such as e.g. Luviquat® (BASF AG, Ludwigshafen / FRG), condensation products of polyglycols and amines, quaternized collagen polypeptides such as lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat®L, Grünau GmbH), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers such as e.g.
  • Amidomethicone or Dow Corning, Dow Coring Co./US copolymers of adipic acid and dimethylaminohydroxypropyldiethylenetrimamine (Carretein®, Sandoz / CH), polyaminopolyamides such as e.g. described in FR-A 22 52 840 and its crosslinked water-soluble polymers, cationic chitin derivatives such as, for example, quaternized chitano, optionally microcrystalline, cationic guar gum, such as e.g. Jaguar® CBS, Jaguar® C-17, Jaguar® C-16 from Celanese / US, quaternized ammonium salt polymers such as Mirapol® A-15, Mirapol® AD-1, Mirapol® AZ-1 from Miranol / US.
  • Suitable silicone compounds are, for example, dimethylpolysilanes, methylphenylpolysiloxanes, cyclic silicones and amino, fatty acid, alcohol, polyether, epoxy, fluorine and / or alkyl-modified silicone compounds.
  • Biogenic active substances are understood to mean, for example, plant extracts and vitamin complexes.
  • Common film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinylpyrrolidone, vinylpyrrolidone-vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid or its salts and similar compounds.
  • Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid.
  • Suitable pearlizing agents are, for example, glycol distearic acid esters such as ethylene glycol distearate, but also fatty acid monoglycol esters.
  • Suitable dyes are the substances which are approved and suitable for cosmetic purposes used, as compiled, for example, in the publication "Cosmetic Colorants" by the Dye Commission of the German Research Foundation, Verlag Chemie, Weinheim, 1984, pp. 81-106. These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole
  • the total proportion of auxiliaries and additives can be 1 to 50, preferably 5 to 40,% by weight, based on the composition.
  • a body shampoo composition was produced as described in Table 1. Foam formation, creaminess of the foam, degree of perceived moisturizing effect and smoothness were assessed by test subjects.
  • the results of the evaluation of the formulations R1 to R9 according to the invention are also summarized in Table 1
  • the surfactants used relate to 100% by weight of active substance.
  • the amount of water added was dimensioned such that a total value of 100% by weight results. All percentages are understood to be% by weight.
  • Example 2 Analogously to Example 1, a body shampoo with a composition according to Table 2 was produced as a comparative example. The foam height, creaminess of the foam and sensation on the skin after use were evaluated. The results of the comparison formulations R10 to R 16 are summarized in Table 2
  • Example 10 comparative examples V8 to V14
  • formulations containing anionite surfactants with acyl octylates are distinguished from those with ether sulfates by a significantly reduced potential for irritation.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne des nouvelles préparations cosmétiques contenant (a) des lactylates acyliques, (b) des hydrolysats protéiques et (c) des condensats d'acide gras protéique. Ces agents se caractérisent par une tolérance particulièrement bonne sur le plan dermatologique, ainsi que par d'excellentes propriétés moussantes.
EP96927707A 1995-08-18 1996-08-09 Preparations cosmetiques contenant des lactylates acyliques, des hydrolysats proteiques et des condensats d'acide gras proteique Withdrawn EP0844867A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP210492/95 1995-08-18
JP21049295A JPH0959694A (ja) 1995-08-18 1995-08-18 洗浄剤組成物
PCT/EP1996/003522 WO1997006780A1 (fr) 1995-08-18 1996-08-09 Preparations cosmetiques contenant des lactylates acyliques, des hydrolysats proteiques et des condensats d'acide gras proteique

Publications (1)

Publication Number Publication Date
EP0844867A1 true EP0844867A1 (fr) 1998-06-03

Family

ID=16590254

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96927707A Withdrawn EP0844867A1 (fr) 1995-08-18 1996-08-09 Preparations cosmetiques contenant des lactylates acyliques, des hydrolysats proteiques et des condensats d'acide gras proteique

Country Status (3)

Country Link
EP (1) EP0844867A1 (fr)
JP (1) JPH0959694A (fr)
WO (1) WO1997006780A1 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9711685D0 (en) * 1997-06-05 1997-08-06 Procter & Gamble Cosmetic compositions
DE19730649C1 (de) 1997-07-17 1998-09-24 Henkel Kgaa Detergensgemische
FR2825925B1 (fr) * 2001-06-19 2005-01-28 Silab Sa Procede de preparation d'un principe actif a partir de riz, principe actif obtenu et compositions adaptees
DE102005063062A1 (de) * 2005-12-29 2007-07-05 Henkel Kgaa Synergistische Proteinhydrolysat-Kombinationen zur Behandlung reifer Haut
EP1998735A4 (fr) * 2006-02-27 2012-11-28 Stepan Co Compositions à base de lactylate d'acyle pour des applications avec rinçage et sans rinçage pour la peau et les cheveux
DE102007029061A1 (de) * 2007-06-21 2009-03-12 Henkel Ag & Co. Kgaa Haut- und Haarbehandlungsmittel mit einem Extrakt eines Süßgrases
US20100093599A1 (en) * 2008-10-10 2010-04-15 Jeffrey Wu Shine control cleanser
DE102010001193A1 (de) * 2010-01-25 2011-07-28 Dahms, Gerd, 47138 Neue Tensidzusammensetzungen
DOP2019000173A (es) 2019-06-21 2019-09-30 Maria Portillo Rosado Rosa Composicion limpiadora multiusos a base de colageno.
CN111072471B (zh) * 2019-12-13 2022-07-29 中国日用化学研究院有限公司 一种脂肪酰乳酸或其盐的制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3670569D1 (de) * 1985-03-01 1990-05-31 Procter & Gamble Milder reinigungsschaum.
EP0224796B1 (fr) * 1985-11-28 1991-10-16 Kao Corporation Composition détergente
GB9204175D0 (en) * 1992-02-27 1992-04-08 Unilever Plc Cleansing composition
DE4207046A1 (de) * 1992-03-06 1993-09-09 Goldwell Ag Haarwaschmittel

Non-Patent Citations (1)

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Title
See references of WO9706780A1 *

Also Published As

Publication number Publication date
WO1997006780A1 (fr) 1997-02-27
JPH0959694A (ja) 1997-03-04

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