EP0838288A1 - Verschleissfeste Verbundgussteile - Google Patents
Verschleissfeste Verbundgussteile Download PDFInfo
- Publication number
- EP0838288A1 EP0838288A1 EP96202741A EP96202741A EP0838288A1 EP 0838288 A1 EP0838288 A1 EP 0838288A1 EP 96202741 A EP96202741 A EP 96202741A EP 96202741 A EP96202741 A EP 96202741A EP 0838288 A1 EP0838288 A1 EP 0838288A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- inserts
- ceramic
- wear resistant
- zro2
- al2o3
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C15/00—Disintegrating by milling members in the form of rollers or balls co-operating with rings or discs
- B02C15/004—Shape or construction of rollers or balls
- B02C15/005—Rollers or balls of composite construction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B02—CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
- B02C—CRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
- B02C13/00—Disintegrating by mills having rotary beater elements ; Hammer mills
- B02C13/26—Details
- B02C13/28—Shape or construction of beater elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/02—Casting in, on, or around objects which form part of the product for making reinforced articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/06—Casting in, on, or around objects which form part of the product for manufacturing or repairing tools
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/08—Casting in, on, or around objects which form part of the product for building-up linings or coverings, e.g. of anti-frictional metal
Definitions
- the present invention relates to a composite wear part produced by casting and made up of a metal matrix, the wear surface has inserts with good resistance to wear.
- the invention relates in particular to wearing parts used in crushing, crushing and transport facilities various abrasive materials found in industries such as cement plants, mines, metallurgy, power plants or various careers. These parts are often subjected to high mechanical stresses in the mass and high wear by abrasion to their working surface. It is therefore desirable that these parts have a high resistance to abrasion and a certain ductility to be able to withstand mechanical stresses such as shocks and to possibly be machined.
- the ceramic cake can be formed in pouring into a suitable mold grains of ceramic material and then a liquid glue with good fluidity, for example a resin liquid which, after hardening, retains the grains to form the ceramic structure.
- a liquid glue with good fluidity for example a resin liquid which, after hardening, retains the grains to form the ceramic structure.
- the ceramic material can be made aluminum oxide or zirconium oxide.
- This known technique is however limited to the molding of precision of relatively small parts and where compatibility between the metal matrix and the ceramic structure, especially in terms of thermal behavior, hardly poses any problems since when casting metal the mold and the ceramic structure are preheated and the part does not undergo subsequent heat treatment.
- the technique is, moreover, limited to the production of specific parts with specific requirements determined for hardness and toughness, as well as for parts sold at a very high price because the lost wax molding process is itself very expensive.
- the object of the present invention is to provide a wearing part composite with ceramic inserts meeting, so satisfies the requirements listed above.
- the invention provides a composite wear part produced by conventional or centrifugal casting and consisting of a metal matrix, the wear surface of which includes inserts having good wear resistance, characterized in that the inserts are ceramic parts, themselves composite, consisting of 20 to 80% of Al 2 O 3 and 80 to 20% of ZrO 2 , the percentages being expressed by weight of the constituents.
- the inserts may, in addition, contain other oxides, the proportion by weight does not exceed 3 to 4%.
- the inserts consist of an agglomerate of ceramic grains composites preferably having a particle size included in the range F6 to F20 of the FEPA standard, i.e. a diameter included between approximately 1.5 mm and 5.5 mm. These grains can be made by electrofusion, sintering, thermal spraying or any other process merging the two constituents.
- the invention is based on the observation that aluminum oxide (corundum) and zirconium oxide have different properties, which allows, by a judicious choice in the aforementioned ranges, to adjust the hardness, toughness and the coefficient of thermal expansion of the ceramic composite so as to obtain good hardness and good toughness and to make it compatible with the precise application for which the part is intended, on the one hand, and to obtain, on the other hand, a coefficient of expansion of the ceramic composite which is close to that of the chosen casting metal, that is to say of cast iron or steel having a coefficient of expansion of between 10.10 -6 and 11.10 -6 .
- Zirconium oxide has the advantage of having a coefficient of expansion which is close to that of metal. In addition, it contributes to good toughness, that is to say it reduces the risk of breakage.
- Aluminum oxide on the other hand, contributes to good hardness. These composirts are known to have good toughness.
- the zirconia particles present in alumina make it possible, by well-known mechanisms, to increase the resistance to cracking of the latter and thus to obtain a toughness greater than that of each component considered in isolation, namely ZrO 2 or Al 2 O 3 .
- the choice of the proportions of the constituents of the ceramic insert composite can, of course, also take into account the composition of the casting metal in view of the properties required the application for which the part is intended. Similarly, the choice of composition of the casting metal can be adapted to the nature of the composite insert.
- Example 1 manufacture of an axis crusher ejector vertical.
- a mixture of 75% Al 2 O 3 and 25% ZrO 2 is formed, the two constituents of which are fused by electrofusion to form grains with a particle size included in categories F6 to F20 of the FEPA standard. These grains are then poured into a mold of suitable shape with a liquid resin which, after hardening, retains the grains together to form the ceramic wafer which must constitute the insert of the wear part. These inserts are placed in a suitable mold into which a liquid metal is poured comprising 3% carbon, 26% chromium and other traditional elements in small proportion which are always encountered in alloys of this type. A wear part is thus produced with ceramic inserts with a hardness of the order of 1600 Hv with a coefficient of expansion close to 8.10 -6 , maintained in a cast iron matrix with a hardness close to 750 Hv.
- Example 2 manufacture of a crusher rotor.
- An insert is prepared as in Example 1 but by choosing, this time, a ceramic composition which favors the coefficient of expansion at the expense of hardness, more precisely 40% of ZrO 2 and 60% of Al 2 O 3 . This produces an insert with a hardness of around 1,350 Hv with a coefficient of expansion close to 9.10 -6 .
- the goal here is to reduce the risk of cracks in the room because of the high impact level to which this type of part is subjected.
- the metallic matrix will consist of a manganese steel with a composition of 1% carbon, 14% manganese and 1.5% molybdenum.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Food Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Compositions Of Oxide Ceramics (AREA)
Priority Applications (28)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96202741A EP0838288A1 (de) | 1996-10-01 | 1996-10-01 | Verschleissfeste Verbundgussteile |
CN97198472A CN1114513C (zh) | 1996-10-01 | 1997-08-27 | 复合耐磨部件 |
ES97943824T ES2150278T3 (es) | 1996-10-01 | 1997-08-27 | Pieza de desgaste compuesta. |
JP51711098A JP2001504036A (ja) | 1996-10-01 | 1997-08-27 | 複合耐摩耗部品 |
UA99031803A UA46124C2 (uk) | 1996-10-01 | 1997-08-27 | Зносостійка деталь із композитного матеріалу (варіанти) |
US09/269,723 US6399176B1 (en) | 1996-10-01 | 1997-08-27 | Composite wear component |
EEP199900139A EE9900139A (et) | 1996-10-01 | 1997-08-27 | Komposiitmaterjalist kulumiskindel detail |
PCT/EP1997/004762 WO1998015373A1 (fr) | 1996-10-01 | 1997-08-27 | Piece d'usure composite |
EP97943824A EP0930948B1 (de) | 1996-10-01 | 1997-08-27 | Verschleissfester verbundkörper |
PT97943824T PT930948E (pt) | 1996-10-01 | 1997-08-27 | Peca de desgaste composita |
SK402-99A SK284900B6 (sk) | 1996-10-01 | 1997-08-27 | Oteruvzdorný diel z kompozitného materiálu |
DE69702988T DE69702988T2 (de) | 1996-10-01 | 1997-08-27 | Verschleissfester verbundkörper |
AT97943824T ATE195895T1 (de) | 1996-10-01 | 1997-08-27 | Verschleissfester verbundkörper |
US10/448,004 USRE39998E1 (en) | 1996-10-01 | 1997-08-27 | Composite wear component |
KR1019997002798A KR100691295B1 (ko) | 1996-10-01 | 1997-08-27 | 복합 마모 부품 |
TR1999/00645T TR199900645T2 (xx) | 1996-10-01 | 1997-08-27 | Bile�ik a��nma par�as�. |
CA002266475A CA2266475A1 (fr) | 1996-10-01 | 1997-08-27 | Piece d'usure composite |
BR9712188-6A BR9712188A (pt) | 1996-10-01 | 1997-08-27 | Peça de desgaste composta. |
HU9904505A HU224208B1 (hu) | 1996-10-01 | 1997-08-27 | Összetett anyagú kopásálló alkatrész |
KR1020067001837A KR20060013699A (ko) | 1996-10-01 | 1997-08-27 | 복합 마모 부품 |
RU99108736A RU2177389C2 (ru) | 1996-10-01 | 1997-08-27 | Износостойкая деталь из композитного материала |
AU45529/97A AU723329B2 (en) | 1996-10-01 | 1997-08-27 | Composite wear component |
PL97332578A PL189446B1 (pl) | 1996-10-01 | 1997-08-27 | Zespolony element roboczy |
CZ19991116A CZ294041B6 (cs) | 1996-10-01 | 1997-08-27 | Otěruvzdorný díl z kompozitního materiálu |
ZA978672A ZA978672B (en) | 1996-10-01 | 1997-09-26 | Composite wear component |
MYPI97004643A MY128314A (en) | 1996-10-01 | 1997-10-03 | Composite wear component |
ID973347A ID17782A (id) | 1996-10-01 | 1997-10-03 | Komponen komposit tahan pakai |
US10/152,569 US6520241B2 (en) | 1996-10-01 | 2002-05-23 | Composite wear component |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96202741A EP0838288A1 (de) | 1996-10-01 | 1996-10-01 | Verschleissfeste Verbundgussteile |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0838288A1 true EP0838288A1 (de) | 1998-04-29 |
Family
ID=8224453
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96202741A Withdrawn EP0838288A1 (de) | 1996-10-01 | 1996-10-01 | Verschleissfeste Verbundgussteile |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP0838288A1 (de) |
ZA (1) | ZA978672B (de) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6030344A (en) * | 1996-12-04 | 2000-02-29 | Acuson Corporation | Methods and apparatus for ultrasound image quantification |
US6086539A (en) * | 1996-12-04 | 2000-07-11 | Acuson Corporation | Methods and apparatus for ultrasound image quantification |
USRE39998E1 (en) | 1996-10-01 | 2008-01-08 | Magotteaux International S.A. | Composite wear component |
US7513295B2 (en) | 2001-12-04 | 2009-04-07 | Magotteaux International Sa | Cast parts with enhanced wear resistance |
US8147980B2 (en) | 2006-11-01 | 2012-04-03 | Aia Engineering, Ltd. | Wear-resistant metal matrix ceramic composite parts and methods of manufacturing thereof |
CN108745508A (zh) * | 2018-07-09 | 2018-11-06 | 徐州鑫华耐磨材料有限公司 | 陶瓷金属复合锤头及其制造方法 |
CN113524393A (zh) * | 2021-07-02 | 2021-10-22 | 红云红河烟草(集团)有限责任公司 | 一种切丝机专用陶瓷刀片及制造方法 |
CN113981290A (zh) * | 2021-09-18 | 2022-01-28 | 湖北秦鸿新材料股份有限公司 | 陶瓷颗粒及其制备方法和应用 |
CN115821096A (zh) * | 2022-11-30 | 2023-03-21 | 山东硕源工业机械设备有限公司 | 一种陶瓷高铬合金基耐磨复合材料的制备方法 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE702385C (de) * | 1935-10-08 | 1941-02-06 | Nikolaus Graf V Ballestrem Auf | Rohrleitung fuer Spuel- oder Blasversatz |
US3181939A (en) * | 1961-01-27 | 1965-05-04 | Norton Co | Fused alumina-zirconia abrasives |
JPS60127067A (ja) * | 1983-12-14 | 1985-07-06 | Kubota Ltd | セラミツクス・金属複合体の製造法 |
JPS62286661A (ja) * | 1986-06-04 | 1987-12-12 | Kawasaki Heavy Ind Ltd | 高硬度粒子の鋳包み方法 |
EP0476496A1 (de) * | 1990-09-20 | 1992-03-25 | Magotteaux International | Verfahren zur Herstellung eines bimetallischen Gussstückes und Verschleissteil nach diesem Verfahren |
JPH05200526A (ja) * | 1992-01-24 | 1993-08-10 | Mitsubishi Heavy Ind Ltd | 耐摩耗複合材の製造方法 |
EP0575685A1 (de) * | 1992-06-23 | 1993-12-29 | Sulzer Innotec Ag | Feinguss mit Verschleissflächen |
-
1996
- 1996-10-01 EP EP96202741A patent/EP0838288A1/de not_active Withdrawn
-
1997
- 1997-09-26 ZA ZA978672A patent/ZA978672B/xx unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE702385C (de) * | 1935-10-08 | 1941-02-06 | Nikolaus Graf V Ballestrem Auf | Rohrleitung fuer Spuel- oder Blasversatz |
US3181939A (en) * | 1961-01-27 | 1965-05-04 | Norton Co | Fused alumina-zirconia abrasives |
JPS60127067A (ja) * | 1983-12-14 | 1985-07-06 | Kubota Ltd | セラミツクス・金属複合体の製造法 |
JPS62286661A (ja) * | 1986-06-04 | 1987-12-12 | Kawasaki Heavy Ind Ltd | 高硬度粒子の鋳包み方法 |
EP0476496A1 (de) * | 1990-09-20 | 1992-03-25 | Magotteaux International | Verfahren zur Herstellung eines bimetallischen Gussstückes und Verschleissteil nach diesem Verfahren |
JPH05200526A (ja) * | 1992-01-24 | 1993-08-10 | Mitsubishi Heavy Ind Ltd | 耐摩耗複合材の製造方法 |
EP0575685A1 (de) * | 1992-06-23 | 1993-12-29 | Sulzer Innotec Ag | Feinguss mit Verschleissflächen |
Non-Patent Citations (4)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 009, no. 286 (M - 429) 13 November 1985 (1985-11-13) * |
PATENT ABSTRACTS OF JAPAN vol. 012, no. 171 (M - 700) 21 May 1988 (1988-05-21) * |
PATENT ABSTRACTS OF JAPAN vol. 017, no. 635 (M - 1514) 25 November 1993 (1993-11-25) * |
W. GERHARTZ ET AL.: "Ullmann's Encyclopedia of Industrial Chemistry", 1985, VCH VERLAGSGESELLSCHAFT, WEINHEIM, DE, FIFTH EDITION, XP002023826 * |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE39998E1 (en) | 1996-10-01 | 2008-01-08 | Magotteaux International S.A. | Composite wear component |
US6193664B1 (en) | 1996-12-04 | 2001-02-27 | Acuson Corporation | Method and apparatus for ultrasound image quantification |
US6241677B1 (en) | 1996-12-04 | 2001-06-05 | Acuson Corporation | Method and apparatus for ultrasound image quantification |
US6110118A (en) * | 1996-12-04 | 2000-08-29 | Acuson Corporation | Method and apparatus for ultrasound image quantification |
US6030344A (en) * | 1996-12-04 | 2000-02-29 | Acuson Corporation | Methods and apparatus for ultrasound image quantification |
US6086539A (en) * | 1996-12-04 | 2000-07-11 | Acuson Corporation | Methods and apparatus for ultrasound image quantification |
US6322511B1 (en) | 1996-12-04 | 2001-11-27 | Acuson Corporation | Methods and apparatus for ultrasound image quantification |
US6093149A (en) * | 1996-12-04 | 2000-07-25 | Acuson Corporation | Method and apparatus for setting the integration interval for time integrated surface integral in an ultrasound imaging system |
US6464640B1 (en) | 1996-12-04 | 2002-10-15 | Acuson Corporation | Methods and apparatus for ultrasound imaging with automatic color image positioning |
US7513295B2 (en) | 2001-12-04 | 2009-04-07 | Magotteaux International Sa | Cast parts with enhanced wear resistance |
US7935431B2 (en) | 2001-12-04 | 2011-05-03 | Magotteaux International Sa | Cast parts with enhanced wear resistance |
US8147980B2 (en) | 2006-11-01 | 2012-04-03 | Aia Engineering, Ltd. | Wear-resistant metal matrix ceramic composite parts and methods of manufacturing thereof |
CN108745508A (zh) * | 2018-07-09 | 2018-11-06 | 徐州鑫华耐磨材料有限公司 | 陶瓷金属复合锤头及其制造方法 |
CN113524393A (zh) * | 2021-07-02 | 2021-10-22 | 红云红河烟草(集团)有限责任公司 | 一种切丝机专用陶瓷刀片及制造方法 |
CN113981290A (zh) * | 2021-09-18 | 2022-01-28 | 湖北秦鸿新材料股份有限公司 | 陶瓷颗粒及其制备方法和应用 |
CN115821096A (zh) * | 2022-11-30 | 2023-03-21 | 山东硕源工业机械设备有限公司 | 一种陶瓷高铬合金基耐磨复合材料的制备方法 |
CN115821096B (zh) * | 2022-11-30 | 2023-08-18 | 山东硕源工业机械设备有限公司 | 一种陶瓷高铬合金基耐磨复合材料的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
ZA978672B (en) | 1999-01-08 |
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