EP0838288A1 - Verschleissfeste Verbundgussteile - Google Patents

Verschleissfeste Verbundgussteile Download PDF

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Publication number
EP0838288A1
EP0838288A1 EP96202741A EP96202741A EP0838288A1 EP 0838288 A1 EP0838288 A1 EP 0838288A1 EP 96202741 A EP96202741 A EP 96202741A EP 96202741 A EP96202741 A EP 96202741A EP 0838288 A1 EP0838288 A1 EP 0838288A1
Authority
EP
European Patent Office
Prior art keywords
inserts
ceramic
wear resistant
zro2
al2o3
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP96202741A
Other languages
English (en)
French (fr)
Inventor
Hubert Francois
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to EP96202741A priority Critical patent/EP0838288A1/de
Priority to US10/448,004 priority patent/USRE39998E1/en
Priority to US09/269,723 priority patent/US6399176B1/en
Priority to TR1999/00645T priority patent/TR199900645T2/xx
Priority to UA99031803A priority patent/UA46124C2/uk
Priority to CA002266475A priority patent/CA2266475A1/fr
Priority to EEP199900139A priority patent/EE9900139A/xx
Priority to PCT/EP1997/004762 priority patent/WO1998015373A1/fr
Priority to EP97943824A priority patent/EP0930948B1/de
Priority to PT97943824T priority patent/PT930948E/pt
Priority to SK402-99A priority patent/SK284900B6/sk
Priority to DE69702988T priority patent/DE69702988T2/de
Priority to BR9712188-6A priority patent/BR9712188A/pt
Priority to CN97198472A priority patent/CN1114513C/zh
Priority to KR1019997002798A priority patent/KR100691295B1/ko
Priority to JP51711098A priority patent/JP2001504036A/ja
Priority to ES97943824T priority patent/ES2150278T3/es
Priority to AT97943824T priority patent/ATE195895T1/de
Priority to HU9904505A priority patent/HU224208B1/hu
Priority to KR1020067001837A priority patent/KR20060013699A/ko
Priority to RU99108736A priority patent/RU2177389C2/ru
Priority to AU45529/97A priority patent/AU723329B2/en
Priority to PL97332578A priority patent/PL189446B1/pl
Priority to CZ19991116A priority patent/CZ294041B6/cs
Priority to ZA978672A priority patent/ZA978672B/xx
Priority to MYPI97004643A priority patent/MY128314A/en
Priority to ID973347A priority patent/ID17782A/id
Publication of EP0838288A1 publication Critical patent/EP0838288A1/de
Priority to US10/152,569 priority patent/US6520241B2/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C15/00Disintegrating by milling members in the form of rollers or balls co-operating with rings or discs
    • B02C15/004Shape or construction of rollers or balls
    • B02C15/005Rollers or balls of composite construction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C13/00Disintegrating by mills having rotary beater elements ; Hammer mills
    • B02C13/26Details
    • B02C13/28Shape or construction of beater elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product
    • B22D19/02Casting in, on, or around objects which form part of the product for making reinforced articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product
    • B22D19/06Casting in, on, or around objects which form part of the product for manufacturing or repairing tools
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product
    • B22D19/08Casting in, on, or around objects which form part of the product for building-up linings or coverings, e.g. of anti-frictional metal

Definitions

  • the present invention relates to a composite wear part produced by casting and made up of a metal matrix, the wear surface has inserts with good resistance to wear.
  • the invention relates in particular to wearing parts used in crushing, crushing and transport facilities various abrasive materials found in industries such as cement plants, mines, metallurgy, power plants or various careers. These parts are often subjected to high mechanical stresses in the mass and high wear by abrasion to their working surface. It is therefore desirable that these parts have a high resistance to abrasion and a certain ductility to be able to withstand mechanical stresses such as shocks and to possibly be machined.
  • the ceramic cake can be formed in pouring into a suitable mold grains of ceramic material and then a liquid glue with good fluidity, for example a resin liquid which, after hardening, retains the grains to form the ceramic structure.
  • a liquid glue with good fluidity for example a resin liquid which, after hardening, retains the grains to form the ceramic structure.
  • the ceramic material can be made aluminum oxide or zirconium oxide.
  • This known technique is however limited to the molding of precision of relatively small parts and where compatibility between the metal matrix and the ceramic structure, especially in terms of thermal behavior, hardly poses any problems since when casting metal the mold and the ceramic structure are preheated and the part does not undergo subsequent heat treatment.
  • the technique is, moreover, limited to the production of specific parts with specific requirements determined for hardness and toughness, as well as for parts sold at a very high price because the lost wax molding process is itself very expensive.
  • the object of the present invention is to provide a wearing part composite with ceramic inserts meeting, so satisfies the requirements listed above.
  • the invention provides a composite wear part produced by conventional or centrifugal casting and consisting of a metal matrix, the wear surface of which includes inserts having good wear resistance, characterized in that the inserts are ceramic parts, themselves composite, consisting of 20 to 80% of Al 2 O 3 and 80 to 20% of ZrO 2 , the percentages being expressed by weight of the constituents.
  • the inserts may, in addition, contain other oxides, the proportion by weight does not exceed 3 to 4%.
  • the inserts consist of an agglomerate of ceramic grains composites preferably having a particle size included in the range F6 to F20 of the FEPA standard, i.e. a diameter included between approximately 1.5 mm and 5.5 mm. These grains can be made by electrofusion, sintering, thermal spraying or any other process merging the two constituents.
  • the invention is based on the observation that aluminum oxide (corundum) and zirconium oxide have different properties, which allows, by a judicious choice in the aforementioned ranges, to adjust the hardness, toughness and the coefficient of thermal expansion of the ceramic composite so as to obtain good hardness and good toughness and to make it compatible with the precise application for which the part is intended, on the one hand, and to obtain, on the other hand, a coefficient of expansion of the ceramic composite which is close to that of the chosen casting metal, that is to say of cast iron or steel having a coefficient of expansion of between 10.10 -6 and 11.10 -6 .
  • Zirconium oxide has the advantage of having a coefficient of expansion which is close to that of metal. In addition, it contributes to good toughness, that is to say it reduces the risk of breakage.
  • Aluminum oxide on the other hand, contributes to good hardness. These composirts are known to have good toughness.
  • the zirconia particles present in alumina make it possible, by well-known mechanisms, to increase the resistance to cracking of the latter and thus to obtain a toughness greater than that of each component considered in isolation, namely ZrO 2 or Al 2 O 3 .
  • the choice of the proportions of the constituents of the ceramic insert composite can, of course, also take into account the composition of the casting metal in view of the properties required the application for which the part is intended. Similarly, the choice of composition of the casting metal can be adapted to the nature of the composite insert.
  • Example 1 manufacture of an axis crusher ejector vertical.
  • a mixture of 75% Al 2 O 3 and 25% ZrO 2 is formed, the two constituents of which are fused by electrofusion to form grains with a particle size included in categories F6 to F20 of the FEPA standard. These grains are then poured into a mold of suitable shape with a liquid resin which, after hardening, retains the grains together to form the ceramic wafer which must constitute the insert of the wear part. These inserts are placed in a suitable mold into which a liquid metal is poured comprising 3% carbon, 26% chromium and other traditional elements in small proportion which are always encountered in alloys of this type. A wear part is thus produced with ceramic inserts with a hardness of the order of 1600 Hv with a coefficient of expansion close to 8.10 -6 , maintained in a cast iron matrix with a hardness close to 750 Hv.
  • Example 2 manufacture of a crusher rotor.
  • An insert is prepared as in Example 1 but by choosing, this time, a ceramic composition which favors the coefficient of expansion at the expense of hardness, more precisely 40% of ZrO 2 and 60% of Al 2 O 3 . This produces an insert with a hardness of around 1,350 Hv with a coefficient of expansion close to 9.10 -6 .
  • the goal here is to reduce the risk of cracks in the room because of the high impact level to which this type of part is subjected.
  • the metallic matrix will consist of a manganese steel with a composition of 1% carbon, 14% manganese and 1.5% molybdenum.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Food Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Compositions Of Oxide Ceramics (AREA)
EP96202741A 1996-10-01 1996-10-01 Verschleissfeste Verbundgussteile Withdrawn EP0838288A1 (de)

Priority Applications (28)

Application Number Priority Date Filing Date Title
EP96202741A EP0838288A1 (de) 1996-10-01 1996-10-01 Verschleissfeste Verbundgussteile
CN97198472A CN1114513C (zh) 1996-10-01 1997-08-27 复合耐磨部件
ES97943824T ES2150278T3 (es) 1996-10-01 1997-08-27 Pieza de desgaste compuesta.
JP51711098A JP2001504036A (ja) 1996-10-01 1997-08-27 複合耐摩耗部品
UA99031803A UA46124C2 (uk) 1996-10-01 1997-08-27 Зносостійка деталь із композитного матеріалу (варіанти)
US09/269,723 US6399176B1 (en) 1996-10-01 1997-08-27 Composite wear component
EEP199900139A EE9900139A (et) 1996-10-01 1997-08-27 Komposiitmaterjalist kulumiskindel detail
PCT/EP1997/004762 WO1998015373A1 (fr) 1996-10-01 1997-08-27 Piece d'usure composite
EP97943824A EP0930948B1 (de) 1996-10-01 1997-08-27 Verschleissfester verbundkörper
PT97943824T PT930948E (pt) 1996-10-01 1997-08-27 Peca de desgaste composita
SK402-99A SK284900B6 (sk) 1996-10-01 1997-08-27 Oteruvzdorný diel z kompozitného materiálu
DE69702988T DE69702988T2 (de) 1996-10-01 1997-08-27 Verschleissfester verbundkörper
AT97943824T ATE195895T1 (de) 1996-10-01 1997-08-27 Verschleissfester verbundkörper
US10/448,004 USRE39998E1 (en) 1996-10-01 1997-08-27 Composite wear component
KR1019997002798A KR100691295B1 (ko) 1996-10-01 1997-08-27 복합 마모 부품
TR1999/00645T TR199900645T2 (xx) 1996-10-01 1997-08-27 Bile�ik a��nma par�as�.
CA002266475A CA2266475A1 (fr) 1996-10-01 1997-08-27 Piece d'usure composite
BR9712188-6A BR9712188A (pt) 1996-10-01 1997-08-27 Peça de desgaste composta.
HU9904505A HU224208B1 (hu) 1996-10-01 1997-08-27 Összetett anyagú kopásálló alkatrész
KR1020067001837A KR20060013699A (ko) 1996-10-01 1997-08-27 복합 마모 부품
RU99108736A RU2177389C2 (ru) 1996-10-01 1997-08-27 Износостойкая деталь из композитного материала
AU45529/97A AU723329B2 (en) 1996-10-01 1997-08-27 Composite wear component
PL97332578A PL189446B1 (pl) 1996-10-01 1997-08-27 Zespolony element roboczy
CZ19991116A CZ294041B6 (cs) 1996-10-01 1997-08-27 Otěruvzdorný díl z kompozitního materiálu
ZA978672A ZA978672B (en) 1996-10-01 1997-09-26 Composite wear component
MYPI97004643A MY128314A (en) 1996-10-01 1997-10-03 Composite wear component
ID973347A ID17782A (id) 1996-10-01 1997-10-03 Komponen komposit tahan pakai
US10/152,569 US6520241B2 (en) 1996-10-01 2002-05-23 Composite wear component

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96202741A EP0838288A1 (de) 1996-10-01 1996-10-01 Verschleissfeste Verbundgussteile

Publications (1)

Publication Number Publication Date
EP0838288A1 true EP0838288A1 (de) 1998-04-29

Family

ID=8224453

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96202741A Withdrawn EP0838288A1 (de) 1996-10-01 1996-10-01 Verschleissfeste Verbundgussteile

Country Status (2)

Country Link
EP (1) EP0838288A1 (de)
ZA (1) ZA978672B (de)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6030344A (en) * 1996-12-04 2000-02-29 Acuson Corporation Methods and apparatus for ultrasound image quantification
US6086539A (en) * 1996-12-04 2000-07-11 Acuson Corporation Methods and apparatus for ultrasound image quantification
USRE39998E1 (en) 1996-10-01 2008-01-08 Magotteaux International S.A. Composite wear component
US7513295B2 (en) 2001-12-04 2009-04-07 Magotteaux International Sa Cast parts with enhanced wear resistance
US8147980B2 (en) 2006-11-01 2012-04-03 Aia Engineering, Ltd. Wear-resistant metal matrix ceramic composite parts and methods of manufacturing thereof
CN108745508A (zh) * 2018-07-09 2018-11-06 徐州鑫华耐磨材料有限公司 陶瓷金属复合锤头及其制造方法
CN113524393A (zh) * 2021-07-02 2021-10-22 红云红河烟草(集团)有限责任公司 一种切丝机专用陶瓷刀片及制造方法
CN113981290A (zh) * 2021-09-18 2022-01-28 湖北秦鸿新材料股份有限公司 陶瓷颗粒及其制备方法和应用
CN115821096A (zh) * 2022-11-30 2023-03-21 山东硕源工业机械设备有限公司 一种陶瓷高铬合金基耐磨复合材料的制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE702385C (de) * 1935-10-08 1941-02-06 Nikolaus Graf V Ballestrem Auf Rohrleitung fuer Spuel- oder Blasversatz
US3181939A (en) * 1961-01-27 1965-05-04 Norton Co Fused alumina-zirconia abrasives
JPS60127067A (ja) * 1983-12-14 1985-07-06 Kubota Ltd セラミツクス・金属複合体の製造法
JPS62286661A (ja) * 1986-06-04 1987-12-12 Kawasaki Heavy Ind Ltd 高硬度粒子の鋳包み方法
EP0476496A1 (de) * 1990-09-20 1992-03-25 Magotteaux International Verfahren zur Herstellung eines bimetallischen Gussstückes und Verschleissteil nach diesem Verfahren
JPH05200526A (ja) * 1992-01-24 1993-08-10 Mitsubishi Heavy Ind Ltd 耐摩耗複合材の製造方法
EP0575685A1 (de) * 1992-06-23 1993-12-29 Sulzer Innotec Ag Feinguss mit Verschleissflächen

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE702385C (de) * 1935-10-08 1941-02-06 Nikolaus Graf V Ballestrem Auf Rohrleitung fuer Spuel- oder Blasversatz
US3181939A (en) * 1961-01-27 1965-05-04 Norton Co Fused alumina-zirconia abrasives
JPS60127067A (ja) * 1983-12-14 1985-07-06 Kubota Ltd セラミツクス・金属複合体の製造法
JPS62286661A (ja) * 1986-06-04 1987-12-12 Kawasaki Heavy Ind Ltd 高硬度粒子の鋳包み方法
EP0476496A1 (de) * 1990-09-20 1992-03-25 Magotteaux International Verfahren zur Herstellung eines bimetallischen Gussstückes und Verschleissteil nach diesem Verfahren
JPH05200526A (ja) * 1992-01-24 1993-08-10 Mitsubishi Heavy Ind Ltd 耐摩耗複合材の製造方法
EP0575685A1 (de) * 1992-06-23 1993-12-29 Sulzer Innotec Ag Feinguss mit Verschleissflächen

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
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PATENT ABSTRACTS OF JAPAN vol. 009, no. 286 (M - 429) 13 November 1985 (1985-11-13) *
PATENT ABSTRACTS OF JAPAN vol. 012, no. 171 (M - 700) 21 May 1988 (1988-05-21) *
PATENT ABSTRACTS OF JAPAN vol. 017, no. 635 (M - 1514) 25 November 1993 (1993-11-25) *
W. GERHARTZ ET AL.: "Ullmann's Encyclopedia of Industrial Chemistry", 1985, VCH VERLAGSGESELLSCHAFT, WEINHEIM, DE, FIFTH EDITION, XP002023826 *

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE39998E1 (en) 1996-10-01 2008-01-08 Magotteaux International S.A. Composite wear component
US6193664B1 (en) 1996-12-04 2001-02-27 Acuson Corporation Method and apparatus for ultrasound image quantification
US6241677B1 (en) 1996-12-04 2001-06-05 Acuson Corporation Method and apparatus for ultrasound image quantification
US6110118A (en) * 1996-12-04 2000-08-29 Acuson Corporation Method and apparatus for ultrasound image quantification
US6030344A (en) * 1996-12-04 2000-02-29 Acuson Corporation Methods and apparatus for ultrasound image quantification
US6086539A (en) * 1996-12-04 2000-07-11 Acuson Corporation Methods and apparatus for ultrasound image quantification
US6322511B1 (en) 1996-12-04 2001-11-27 Acuson Corporation Methods and apparatus for ultrasound image quantification
US6093149A (en) * 1996-12-04 2000-07-25 Acuson Corporation Method and apparatus for setting the integration interval for time integrated surface integral in an ultrasound imaging system
US6464640B1 (en) 1996-12-04 2002-10-15 Acuson Corporation Methods and apparatus for ultrasound imaging with automatic color image positioning
US7513295B2 (en) 2001-12-04 2009-04-07 Magotteaux International Sa Cast parts with enhanced wear resistance
US7935431B2 (en) 2001-12-04 2011-05-03 Magotteaux International Sa Cast parts with enhanced wear resistance
US8147980B2 (en) 2006-11-01 2012-04-03 Aia Engineering, Ltd. Wear-resistant metal matrix ceramic composite parts and methods of manufacturing thereof
CN108745508A (zh) * 2018-07-09 2018-11-06 徐州鑫华耐磨材料有限公司 陶瓷金属复合锤头及其制造方法
CN113524393A (zh) * 2021-07-02 2021-10-22 红云红河烟草(集团)有限责任公司 一种切丝机专用陶瓷刀片及制造方法
CN113981290A (zh) * 2021-09-18 2022-01-28 湖北秦鸿新材料股份有限公司 陶瓷颗粒及其制备方法和应用
CN115821096A (zh) * 2022-11-30 2023-03-21 山东硕源工业机械设备有限公司 一种陶瓷高铬合金基耐磨复合材料的制备方法
CN115821096B (zh) * 2022-11-30 2023-08-18 山东硕源工业机械设备有限公司 一种陶瓷高铬合金基耐磨复合材料的制备方法

Also Published As

Publication number Publication date
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