EP0831975A1 - Colorants et materiaux d'etancheite penetrants produits a partir de dispersions de polyurethanne - Google Patents

Colorants et materiaux d'etancheite penetrants produits a partir de dispersions de polyurethanne

Info

Publication number
EP0831975A1
EP0831975A1 EP96918261A EP96918261A EP0831975A1 EP 0831975 A1 EP0831975 A1 EP 0831975A1 EP 96918261 A EP96918261 A EP 96918261A EP 96918261 A EP96918261 A EP 96918261A EP 0831975 A1 EP0831975 A1 EP 0831975A1
Authority
EP
European Patent Office
Prior art keywords
active
diisocyanate
hydrogen containing
reaction
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP96918261A
Other languages
German (de)
English (en)
Other versions
EP0831975A4 (fr
Inventor
Revathi Tomko
Barbara J. Varone
Robert A. Martuch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sherwin Williams Co
Original Assignee
Sherwin Williams Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sherwin Williams Co filed Critical Sherwin Williams Co
Publication of EP0831975A1 publication Critical patent/EP0831975A1/fr
Publication of EP0831975A4 publication Critical patent/EP0831975A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48—Macromolecular compounds
    • C04B41/488—Other macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C04B41/4884—Polyurethanes; Polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/285—Nitrogen containing compounds
    • C08G18/2865—Compounds having only one primary or secondary amino group; Ammonia
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/005—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process employing compositions comprising microparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02—Processes; Apparatus
    • B27K3/15—Impregnating involving polymerisation including use of polymer-containing impregnating agents

Definitions

  • the present invention relates to an improvement in the area of polyurethane dispersion resins and an improvement in the penetrating stains/sealants art.
  • the improvement comprises the addition of an active-hydrogen containing composition having only one active-hydrogen and also having a long aliphatic chain, such as an alcohol or a monoamine than contains a C6 or greater aliphatic chain, as part of the prepolymer reaction mixture.
  • This composition reacts with the isocya ate groups during the formation of the prepolymer.
  • the prepolymer has both isocyanate functionality and contains a hydrophobic end group.
  • the prepolymer is neutralized, dispersed in water and chain extended to a composition that penetrates into porous substrates and exhibits excellent water repellency due to the inclusion of the hydrophobic aliphatic end group. Introducing long hydrophobic end groups imparts excellent water resistance and beading characteristics, even to a low molecular weight dispersion polymer. Such low molecular weight polymers would otherwise be expected to show early water sensitivity.
  • Finishes which are useful on porous substrates such as wood, concrete, cement, brick and the like typically fall into two broad classifications: surface coatings and penetrating finishes.
  • Surface coatings can be very high molecular weight, can be highly crosslinked, and characteristically form a continuous film over the substrate. Varnishes and polyurethane clearcoats are typically classified as surface coatings.
  • Penetrating finishes are designed to protect a substrate, and typically change a substrate's color, yet retain the natural textural appearance of the substrate.
  • Penetrating pigmented stains, non-pigmented wood preservatives, and water sealants are typical examples of penetrating finishes.
  • penetrating finishes One key attribute of penetrating finishes is that they are designed so as not to form an appreciable surface film or coating on the wood/substrate. They are typically low in molecular weight and very small particle size. They are durable, well suited for textured, exposed surfaces such as siding, decks, steps and the like, can contain water repellants, and are easily applied.
  • Penetrating finishes can be further subdivided as clear systems or colored systems.
  • the clear systems typically contain a water repellant. When applied to a wood or porous substrate, these compositions serve to protect the substrate from moisture.
  • the colored systems are designed to change the color of the wood or porous surface without hiding the grain or texture of the substrate.
  • This invention is directed to penetrating finishes, particularly, penetrating stains and water sealants.
  • commercial architectural penetrating stains and water sealants have been formulated from oil-based compositions. Many commercially available wood stains still utilize pure linseed oil. Oil-based compositions are relatively inexpensive and provide good spreading characteristics. However, such stains typically lack good abrasion resistance and good drying characteristics. They are, furthermore, typically very high in volatile organic compounds content (VOC).
  • VOC volatile organic compounds content
  • European Patent Application 0 314 378 Al to Adkins discloses a waterborne alkyd deck stain containing a medium-long oil length water-reducible alkyd resin solubilized in water with the use of propylene glycol tertiary butyl ether as a coupling solvent.
  • Adkins claims to have low VOC, good resistance to water, durability to abrasion and the like.
  • U.S. Patent 4,276,329 to Vasishth et al. discloses a composition for treating and protecting wood surfaces comprising a low molecular weight alkyd resin in a cosolvent of water and glycol ether.
  • U.S. Patent 4,432,797 to Vasishth et al. discloses a water based thickened stain containing a film forming resin, pigment, thickener and water. The resin is taught to be either an alkyd, a water based acrylic or a water solution of a modified polysaccharide polymer.
  • UK Patent Application 2 215 732 A to Timperley discloses a water based wood staining composition comprising a water soluble acrylic resin and a pigment.
  • UK Patent 1 589 605 to Gorivaerk disclose a method of preparing a penetrating wood stain of a suspension of finely divided solids in an oil-in-water emulsion.
  • U.S. Patent 5,310,780 relates to previous work of one of the present inventors.
  • the present invention represents a substantial improvement over the '780 patent.
  • the improvement comprises the addition of an active-hydrogen containing composition, containing only one active hydrogen and also containing a long aliphatic chain, such as an alcohol or a monoamine containing a C6 or greater aliphatic chain, as part of the prepolymer reaction mixture.
  • U.S. Patent 5,354,807 to Gasniak discloses anionic water dispersed polyurethane polymers that comprise the reaction product of a poly isocyanate, an active- hydrogen containing compound such as a polyol and a diamine monomer containing a pendant aliphatic.
  • the present invention relates to low VOC, penetrating compositions for staining and protecting porous surfaces such as wood, concrete, cement, brick and die like.
  • this invention relates to stable dispersions of polyurethane-ureas in water which are lower molecular weight, small particle size and which can penetrate into the surface to be coated.
  • the dispersions of this invention are particularly useful as environmentally compliant penetrating stains and water sealants.
  • the present invention relates to an improvement in the area of polyurethane dispersion resins and an improvement in the penetrating stains/sealants art.
  • the improvement comprises the addition of an active-hydrogen containing composition having only one active hydrogen and also having a long aliphatic chain, such as an alcohol or a monoamine containing a
  • the prepolymer reaction mixture reacts with the isocyanate groups during the formation of the prepolymer.
  • the prepolymer has both isocyanate functionality and contains some hydrophobic end groups.
  • the prepolymer is neutralized, dispersed in water and chain extended to a composition that penetrates into porous substrates and exhibits excellent water repellency due in part to the inclusion of the hydrophobic aliphatic end group.
  • the present invention relates to low VOC stable, small particle size dispersions of polyurethane-ureas in an aqueous solvent which are especially suitable as penetrating stains and water sealants.
  • the dispersions of this invention have excellent abrasion resistance, shelf stability, penetration into porous surfaces and UV light stability. These dispersions are particularly suited for use, either alone or with additional ingredients such as pigments, waxes and the like, as penetrating stains and water sealants.
  • the polyurethane-ureas of this invention are very low in molecular weight yet are not water sensitive.
  • the compositions of this invention are different from surface coatings and paints in that they do not form an appreciable film when applied over a porous substrate such as wood, concrete, cement, brick and the like.
  • compositions of this invention are penetrating stains and water sealants which comprise low VOC, stable dispersions of small particle size polyurethane-ureas in an aqueous media.
  • the particle size of the polyurethane-urea molecules is less than about 0.4 micron, and most preferably in the range of about 0.1 to about 0.3 micron.
  • the polyurethane-ureas are low in molecular weight. Prior to dispersion in water, the polyurethane-urea intermediates have a weight average molecular weight generally less than about 10,000. When dispersed in an aqueous media, the polyurethane-ureas have a theoretical free isocyanate functionality of zero and a weight average molecular weight generally less than about 50,000.
  • compositions of this invention are produced by first reacting two active- hydrogen containing compositions with a diisocyanate-functional material.
  • One of the active-hydrogen containing compositions is preferably difunctional with respect to isocyanate groups.
  • the other active-hydrogen containing composition is monofunctional with respect to isocyanate groups and must also contain an aliphatic chain of C6 or greater.
  • the difunctional active-hydrogen containing composition is preferably selected from the group consisting of diols such as
  • polyester diols formed from the reaction of saturated and unsaturated
  • polyhydric alcohols such as ethylene glycol, propylene glycol, neopentyl glycol, 1,4-butanediol, 1,4-butenediol, 1,6-hexanediol, furan dimethanol, and cyclohexane dimethanol, with saturated and unsaturated polycar- boxylic acids and derivatives thereof such as maleic acid, fumaric acid, itaconic acid, succinic acid, glutaric acid, adipic acid, isophthalic acid, terephthalic acid, phthalic anhydride, dimethyl terephthalate, dimer acids and the like;
  • polyesters formed by the reaction of lactones, such as caprolactone, with a diol 1) polyesters formed by the reaction of lactones, such as caprolactone, with a diol;
  • polyether diols such as the products of the polymerization of a cyclic oxide such as ethylene oxide, propylene oxide or tetrahydrofuran; 4) polyether diols formed by the addition of one or more cyclic oxides to water, ethylene glycol, propylene glycol, diethylene glycol, cyclohexane dimethanol, glycerol, or Bisphenol A;
  • polycarbonate diols such as the reaction product of 1,3-propanediol, 1,4- butanediol, 1,6-hexanediol, diethylene glycol or tetraethylene glycol with diary 1 carbonates such as diphenyl carbonate or phosgene;
  • polyacetal diols such as the reaction product of a glycol such as diethylene glycol, triethylene glycol or hexanediol with formaldehyde;
  • low molecular weight diols such as dihydroxyalkanoic acids including dimethylolpropionic acid; and mixtures thereof.
  • Other difunctional active hydrogen containing compositions are also suitable for use herein.
  • active hydrogens include hydrogen atoms attached to oxygen, nitrogen or sulfur, and thus, in addition to the polyols disclosed above, compounds such as diamines, aminoalcohols, and mercapto-terminated derivatives thereof, are also useful.
  • Representative materials include the difunctional materials disclosed in U.S. Patent 5,354,807 which is incorporated herein by reference. To the extent that U.S. Patent 5,354,807 teaches materials having functionality greater than two, those materials are not preferred herein as they create a crosslinked, non ⁇ linear polymer which is not preferred for use as a penetrating stain, water repellent or preservative.
  • the diisocyanate-functional material is selected from the group of aromatic, cycloaliphatic or aliphatic diisocyanates, preferably selected from the group consisting of tetramethylene diisocyanate, hexamethylene diisocyanate, 2,4-toluene diisocyanate, 2,6-toluene diisocyanate, 4,4'-diphenylmethane diisocyanate, isophorone diisocyanates, Desmodur WTM (a 4,4'-dicyclohexylmethane diisocyanate available from Mobay), benzene 1,3-bis (l-isocyanato-l-me ⁇ hyle ⁇ hyl)[m-TMXD ⁇ ], and mixtures thereof.
  • aromatic, cycloaliphatic or aliphatic diisocyanates preferably selected from the group consisting of tetramethylene diisocyanate, hexamethylene diisocyanate, 2,4-toluene
  • an active-hydrogen containing composition that is monofunctional with resepect to isocyanates and which contains a long aliphatic chain, preferably a C6 or greater aliphatic chain, more preferably a C 12 to C22 aliphatic chain.
  • the amount of such material should be such that from about 1 % to about 50% of the total active-hydrogen functionality is contributed by the monofunctional composition.
  • Representative monofunctional compositions include the alcohols, mercaptans and monoamines having C6 or greater aliphatic chains such as hexyl, soya, tallow, hydrogenated tallow, stearyl, coco, lauryl, and oleyl alcohol, mercaptan, amine and mixtures thereof.
  • a catalyst such as di-butyl tin dilaurate, tin octoate and the like.
  • the preferred ratio of total active- hydrogen containing materials to diisocyanate should be such that there is an excess of isocyanate functionality over active-hydrogen functionality.
  • the ratio of equivalents of NCO to total active-hydrogen should be between about 1.01:1 to about 2.0:1; preferably between about 1.01:1 to about 1.5:1.
  • the active-hydrogen containing materials from about 1 % to about 50% (of the equivalents of materials reactive with NCO) should be contributed by the monofunctional composition.
  • a percentage of the total polymer weight solids preferably between about 1 % and about 10%, is contributed by active-hydrogen containing compositions having the ability to contribute ionic or hydrophilic groups to the polyure ⁇ thane-urea.
  • active-hydrogen containing compositions having the ability to contribute ionic or hydrophilic groups to the polyure ⁇ thane-urea.
  • diols, amines and/or epoxies containing carboxylic acid groups, sulfonic acid groups, phosphoric acid groups, ammonium salts, phosphonium salts or sulfonium salts are examples of active-hydrogen containing compositions having the ability to contribute ionic or hydrophilic groups.
  • the prepolymer preparation reaction is typically carried out by charging the difunctional active-hydrogen containing composition with the catalyst to a reaction ves ⁇ sel, heating the contents to a temperature of between about 85°C and about 100°C, and adding, via continuous or stepwise addition over a period of time, preferably between about 1/2 hour to about 1.5 hours, the diisocyanate-functional materials.
  • a solvent such as n-methyl pyrolidinone, dimethyl formamide, methyl ethyl ketone, toluene, and mixtures thereof in an amount ranging up to about 20% by weight based upon the total weight of the materials present in the reaction vessel.
  • the reaction vessel temperature is main- tained between about 90° and 100°C for approximately 3 to 4.5 hours. Residual isocyanate percentage can be measured by any means well known in the art.
  • the monofunctional active-hydrogen containing composition is then added at 80 o C over a 15 minute period.
  • the reaction mixture is held at 90°C to 100°C for another 1/2 to 1.5 hours.
  • the prepolymer is then poured into water containing a weak base neutralization agent, such as triethylamine, trimethylamine, triisopropyl amine, tributyl amine, triethylene diamine (e.g.
  • DABCOTM commercially available from Air Products Co.
  • N,N-dimethyl-cyclohexyl amine N,N-dimethylstearyl amine, N,N-dimethyl aniline, N-methylmorpholine, N-ethylmorpholine, N-methylpiperazine, N-mefhylpyrolidine, N- methylpiperidine, N,N-dimethyl-e ⁇ hanol amine, N,N-diethyl-ethanol amine, triethanol amine, N-methyldiethanol amine, dimethylaminopropanol, 2-methoxyethyldimethyl amine, N-hydroxyethylpiperazine, 2-(2-dimethylaminoethoxy)-ethanol and 5-diethyl- amino-2-pentanone and mixtures thereof, and dispersed.
  • the amount of weak base added should be sufficient to neutralize at least about 80% of the ionic groups present in solution.
  • the weak base is added in an amount sufficient to neutralize 100% of the ionic groups.
  • the weak base can be added in excess, that is, an amount greater than that necessary to neutralize the ionic groups.
  • the intermediate at this point has a weight average molecular weight less than about 10,000.
  • the monofunctional active-hydrogen containing composition has endcapped many of the NCO groups so that the prepolymer also has some long chain aliphatic hydrophobic endcaps.
  • the percentage of solids in the water or aqueous solvent can range from between about 20% by weight to about 60% by weight, preferably between about 30% to 50% by weight.
  • a difunctional amine compound such as ethylene diamine, propylene diamine, butylene diamine, hexamethylene diamine, cyclohexylene diamine, piperazine, hydrazine, mixtures thereof, equivalents thereof and the like in an amount sufficient to react with up to about 90% of the theoretical amount of residual NCO functionality can optionally be included in the dispersing media for chain extension of the polyurethane.
  • Chain extenders having a functionality greater than two should not be included in any appreciable amount due to their tendency to cause unacceptably high levels of branching, whereby the composition then acts as a film-forming polymer rather than a penetrating composition when applied to wood or another porous substrate.
  • most of the active-hydrogen containing ingredients are either - difunctional or monofunctional with respect to isocyanates.
  • a minor amount of the total number of equivalents can be contributed by higher-functional materials such as trimethylolpropane; however, an appreciable percentage of such materials is not desired as this results in an intermediate, and thus a final polymer, which exhibits high molecular weight and extensive branching.
  • the most preferred difunctional active-hydrogen containing starting materials are a combination of 1) the polyester diols formed from the reaction of saturated and unsaturated dihydric alcohols such as ethylene glycol, propylene glycol, neopentyl glycol, 1,4-butanediol, 1,4-butenediol, 1,6-hexanediol, furan dimethanol, and cyclohex ⁇ ane dimethanol with saturated and unsaturated polycarboxylic acids such as maleic acid, fumaric acid, itaconic acid, succinic acid, glutaric acid, adipic acid, isophthalic acid, terephthalic acid, phthalic anhydride, dimethyl terephthalate, dimer acids and the like; and 2) a diol containing hydrophilic groups.
  • saturated and unsaturated dihydric alcohols such as ethylene glycol, propylene glycol, neopentyl glycol, 1,4-butanediol, 1,4-
  • One such preferred polyester diol is RucoflexTM 1015-120 (a mixture of polyester diols based on neopentyl glycol, hexanediol and adipic acid, commercially available from Ruco Polymer Corporation).
  • a particularly preferred diol containing hydrophilic groups is dimethylolpropionic acid. When used, these two diols are preferably present in percentages such that the Rucoflex material contributes between about 40% to about 70% of the OH functionality of the total materials.
  • a preferred embodiment comprises Rucoflex 1015-120, trimethylolpropane, dimethylolproprionic acid and cyclohexane dimethanol.
  • the isocyanate-functional materials are most preferably exclusively diisocyanates selected from the group consisting of Desmodur WTM (4,4'-dicyclohexylmethane diisocyanate), m-TMXDI (benzene 1,3-bis (1-isocyanato-l-methylethyl)), IPDI (isophorone diisocyanates) and mixtures thereof. Most preferred is a combination of Desmodur WTM and m-TMXDI.
  • the isocyanate-functional materials can have a functionality greater than two, however, for the same reasons, an appreciable percentage of such isocyanate ingredients is not acceptable due to the effect on molecular weight and chain branching of both the intermediate and the final product.
  • the ratio of NCO equivalents contributed by the individual isocyanates is not critical.
  • the dispersing media is preferably water. Preferred is water with a small percentage of diamine present or added for chain extension with the residual NCO.
  • the amount of dispersing media should be between about 40% and about 80% by weight of total reaction ingredients. More preferably, the percentage of dispersing media is between about 50% and 80% by weight.
  • a chain extension agent When a chain extension agent is used, it should preferably be present or added in an amount sufficient to react with up to about 90% of the residual NCO functionality.
  • the final, chain-extended dispersion should have a weight average molecular weight less than about 50,000.
  • the composition can be modified with other standard ingredients commonly used to formulate penetrating stains, wood preservatives and water sealants.
  • the dispersions of this invention can be combined with other ingredients such as pigments, colorants, paraffins, waxes, UV light stabilizers, rheology modifiers, mildewcides, biocides, fungicides, and other conventional additives to form excellent penetrating stains, preservatives and/or sealants for wood, concrete, cement, brick and other porous architectural surfaces.
  • Colorants and pigment dispersions, when used, are typically added in amounts up to about 15% by volume of the total composition.
  • Paraffin and ethylene waxes, used to impart water resistance to penetrating finishes, when used, are typically added in amounts up to about
  • a surface tension modifying ingredient can be added to the composition to lower the surface tension of the carrier. It has been found that such a surface tension modifying ingredient can enable the composition to more easily penetrate into the porous substrate to which it is applied.
  • Suitable solvents for use as surface tension modifying ingredients include the 2,2,4-trimethyl-alkyl diol monoisobutyrate solvents available from Eastman Chemical marketed under the TexanolTM brand name, glycols such as ethylene glycol, propylene glycol, dipropylene glycol, and the like, glycol ethers such as 2-butoxy ethanol (Butyl CellosolveTM), diethylene glycol monobutyl ether (Butyl CarbitolTM), and the like, and alcohols such as methanol, ethanol, propanol and the like; and mixtures thereof.
  • the surface tension modifying agent should be included in an amount sufficient to lower the surface tension of the carrier to a level where the composition will achieve the desired penetration into the porous substrate.
  • the amount of surface tension modifying agent required is from between about 0.25% to about 5.0% by volume based upon the total volume of the composition.
  • many standard stain and sealant additives are commercially available in a media which imparts some surface tension modifying activity.
  • many commercially available rheology modifiers are sold in glycol and glycol ether media.
  • the media may contribute some surface tension modifying properties.
  • the RheolateTM materials are commercially available in a butyl carbitol media.
  • mildewcides and fungicides are commercially available in petroleum distillate media. These media additionally may impart some surface tension modifying characteristics. In general, media which would be expected to impart surface tension modifying activity and which are present in an appreciable amount should be included when calculating the total percentage of surface tension modifying agents.
  • EXAMPLE I--PREPARATION OF THE DISPERSION Charge 120.0g of n-methyl pyrolidinone, 496.56g of Rucoflex 1015-120 (1.09 eq of OH), 80.0g of dimethylolpropionic acid (1.19 eq of OH), 15.0g of trimethylolpropane (0.33 eq of OH), 20.0g of 1,4-cyclohexane dimethanol (0.27 eq of OH) and 3.0g of dibutyl tin dilaurate (10% solution in n-methyl pyrolidinone) to a reaction vessel equipped with a nitrogen blanket. Begin stirring and increase temperature to about 85.5°C. Begin a 30-40 minute addition of 647.13g of m-TMXDI
  • the above dispersion has approximate M n of 3338, M w of 22,813 and M z of
  • Dispersions prepared according to the above generally have the following characteristics:
  • EXAMPLE III-WATER SEALANT The following represents a typical, non-pigmented water sealant composition using the polyurethane dispersion of Example I.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

Les compositions décrites à faible teneur en composés organiques volatils sont utiles pour colorer et pour protéger des substrats poreux tels que le bois, le béton, le ciment, les briques et similaires, et contiennent des dispersions aqueuses de polyuréthanne-urées.
EP96918261A 1995-06-07 1996-06-06 Colorants et materiaux d'etancheite penetrants produits a partir de dispersions de polyurethanne Withdrawn EP0831975A4 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US48158695A 1995-06-07 1995-06-07
US481586 1995-06-07
PCT/US1996/009310 WO1996040447A1 (fr) 1995-06-07 1996-06-06 Colorants et materiaux d'etancheite penetrants produits a partir de dispersions de polyurethanne

Publications (2)

Publication Number Publication Date
EP0831975A1 true EP0831975A1 (fr) 1998-04-01
EP0831975A4 EP0831975A4 (fr) 1998-08-12

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP96918261A Withdrawn EP0831975A4 (fr) 1995-06-07 1996-06-06 Colorants et materiaux d'etancheite penetrants produits a partir de dispersions de polyurethanne

Country Status (5)

Country Link
EP (1) EP0831975A4 (fr)
JP (1) JPH11507403A (fr)
AU (1) AU6096096A (fr)
BR (1) BR9608714A (fr)
WO (1) WO1996040447A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5290525B2 (ja) * 2007-01-23 2013-09-18 東邦化学工業株式会社 一液型止水剤

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03139582A (ja) * 1989-10-24 1991-06-13 Dainippon Ink & Chem Inc 意匠性塗料組成物とその塗装物
WO1992018558A1 (fr) * 1991-04-12 1992-10-29 Robert M. Evans Associates, Inc. Revetement et materiau d'etancheite contenant du polyurethane
EP0682049A1 (fr) * 1994-05-09 1995-11-15 Hoechst Aktiengesellschaft Polyuréthane-polyurés et leur utilisation comme dispersant pour des résines synthétiques

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5023309A (en) * 1987-09-18 1991-06-11 Rheox, Inc. Water dispersible, modified polyurethane thickener with improved high shear viscosity in aqueous systems
US5310780A (en) * 1990-08-21 1994-05-10 The Sherwin-Williams Company Penetrating stains and sealants from polyurethane dispensions

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03139582A (ja) * 1989-10-24 1991-06-13 Dainippon Ink & Chem Inc 意匠性塗料組成物とその塗装物
WO1992018558A1 (fr) * 1991-04-12 1992-10-29 Robert M. Evans Associates, Inc. Revetement et materiau d'etancheite contenant du polyurethane
EP0682049A1 (fr) * 1994-05-09 1995-11-15 Hoechst Aktiengesellschaft Polyuréthane-polyurés et leur utilisation comme dispersant pour des résines synthétiques

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 015, no. 353 (C-0865), 6 September 1991 & JP 03 139582 A (DAINIPPON INK & CHEM INC), 13 June 1991, *
See also references of WO9640447A1 *

Also Published As

Publication number Publication date
JPH11507403A (ja) 1999-06-29
BR9608714A (pt) 1999-06-29
WO1996040447A1 (fr) 1996-12-19
EP0831975A4 (fr) 1998-08-12
AU6096096A (en) 1996-12-30

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