EP0828602B1 - Method for making an absorbent structure - Google Patents

Method for making an absorbent structure Download PDF

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Publication number
EP0828602B1
EP0828602B1 EP97919437A EP97919437A EP0828602B1 EP 0828602 B1 EP0828602 B1 EP 0828602B1 EP 97919437 A EP97919437 A EP 97919437A EP 97919437 A EP97919437 A EP 97919437A EP 0828602 B1 EP0828602 B1 EP 0828602B1
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EP
European Patent Office
Prior art keywords
plies
cylinders
cylinder
engraved
play
Prior art date
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Expired - Lifetime
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EP97919437A
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German (de)
French (fr)
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EP0828602A1 (en
Inventor
Rémy Ruppel
Jo[L Hungler
Pierre Laurent
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Essity Operations France SAS
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Fort James France
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F1/00Mechanical deformation without removing material, e.g. in combination with laminating
    • B31F1/07Embossing, i.e. producing impressions formed by locally deep-drawing, e.g. using rolls provided with complementary profiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0707Embossing by tools working continuously
    • B31F2201/0715The tools being rollers
    • B31F2201/0723Characteristics of the rollers
    • B31F2201/0738Cross sectional profile of the embossments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0707Embossing by tools working continuously
    • B31F2201/0715The tools being rollers
    • B31F2201/0741Roller cooperating with a non-even counter roller
    • B31F2201/0743Roller cooperating with a non-even counter roller having a matching profile
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0758Characteristics of the embossed product
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0758Characteristics of the embossed product
    • B31F2201/0761Multi-layered
    • B31F2201/0764Multi-layered the layers being nested
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31FMECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31F2201/00Mechanical deformation of paper or cardboard without removing material
    • B31F2201/07Embossing
    • B31F2201/0771Other aspects of the embossing operations
    • B31F2201/0774Multiple successive embossing operations
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1002Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1007Running or continuous length work
    • Y10T156/1023Surface deformation only [e.g., embossing]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1002Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1025Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina to form undulated to corrugated sheet and securing to base with parts of shaped areas out of contact
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24446Wrinkled, creased, crinkled or creped
    • Y10T428/24455Paper
    • Y10T428/24463Plural paper components
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24562Interlaminar spaces
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24612Composite web or sheet
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628Nonplanar uniform thickness material
    • Y10T428/24669Aligned or parallel nonplanarities
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24826Spot bonds connect components

Definitions

  • the present invention relates to a method for producing a absorbent structure or sheet with at least two plies, each consisting of at least minus an embossed sheet of crepe absorbent paper.
  • the invention relates in particular to the production of fibrous products, in the form of absorbent paper for sanitary and domestic use.
  • the invention thus relates more particularly to a structure multi-ply absorbent, also called multi-layer structure for products such as toilet paper, handkerchiefs, towels, or wiping cloths.
  • embossing gives bulk to the sheet and it induces a improved absorption of liquids, touch and softness.
  • Attempts have been made to further increase the absorption capacity by creating multilayer structures obtained by combining at least two layers, also called folds each consisting of at least one embossed sheet of crepe absorbent paper.
  • the value of the clearance J is chosen at most equal to the thickness of the sheet to be embossed so as to ensure calendering of the sheet at the tops of the bosses obtained with the association of folds at this level.
  • This floating phenomenon results in the formation of a loop causing a gap between the two folds, and therefore to defects of manufacturing due to the mismatch of the two plies at the time of their association by bonding by the matching cylinder.
  • the object of the present invention is to propose a method which takes advantage of of the advantages of the two methods mentioned above while remedying to the disadvantages which have just been mentioned.
  • the invention proposes a method where the engraved cylinders are distant from each other with a clearance J measured between the vertices of the protrusions of one cylinder and the etching bottom surface of the other cylinder, said clearance J being greater than the sum of the thicknesses of the folds previously shaped, characterized in that this clearance is less than the depth of cylinder engraving.
  • the invention also provides an installation for setting up work of the method according to the invention of the type comprising two cylinders engraved metal with protrusions, rotated by synchronized and with a clearance J between the vertices of the protrusions of a metal cylinder and the surface facing the bottom of the engraving of the other cylinder, greater than the sum of the thicknesses of the folds previously embossed, characterized in that said clearance J is less than the depth of the engraving of cylinders.
  • the invention also provides an absorbent structure with at least two plies produced according to the invention and characterized in that it has an absorption capacity measured according to AFNOR NFQ 03068 standard greater than 10 cm 3 / g, in particular between 11 and 14 cm 3 / g when it is produced from two sheets of crepe absorbent paper each having an absorption capacity of between 4 and 6 cm 3 / g.
  • the fold P1 has bosses B1 obtained by embossing which are spaced from each other and oriented towards the fold P2 which has also, symmetrically, bosses B2 oriented towards the fold P1.
  • the bosses B2 are fitted between the bosses B1 and the spacing between the bosses B1 and B2 is sufficient to provide between them a space 12.
  • Each ply or sheet P1, P2 is a sheet of cellulose wadding, crepe absorbent paper used as sanitary or domestic paper weighing between 10 and 40 g / m 2 .
  • the thickness E1, E2 of each of the plies P1, P2, which can be identical for the two folds, is for example of the order of 0.1 mm.
  • the sheet 10 illustrated in FIG. 1 is produced by means of the installation shown in Figure 2.
  • This installation comprises two embossing units made up each of a pressure cylinder CP1, CP2 coated with flexible material elastomer, cooperating with an engraved steel cylinder CG1, CG2 respectively.
  • the cylinders CG1 and CG2 are engraved so as to present in surface of the elements in relief and / or of the pins R1, R2 distributed as well on the circumference, machine direction, than on the width of each cylinder, cross direction.
  • the metallic cylinders engraved CG1 and CG2 parallel axes are positioned relative to each other so that overlap at the level of their opposite zone, that is to say that the parts in relief R1 of one of the cylinders is inserted between the parts in relief R2 of the other cylinder, the overlap C also called engagement of two cylinders, being however such that there is a clearance J between the cylinders engraved CG1 and CG2 allowing the engagement of folds P1 and P2 between the engraved cylinders.
  • the clearance J measured between the vertices of the protrusions, for example R1, of one of the metallic cylinders CG1 and the surface facing the bottom, for example F2, of the engraving of the other cylinder CG2 is greater than or equal to the sum of the thicknesses E1 and E2 of the folds P1 and P2 when the latter are engaged in the nesting zone mutual fund CG1 and CG2.
  • E1 and E2 are the thicknesses of the folds P1 and P2 in the nesting zone, that is to say of the folds P1 and P2 previously embossed before their simultaneous engagement between the cylinders CG1 and CG2, due to their prior passage in the two embossing units.
  • the installation illustrated in Figure 2 includes a device size 14, known per se, which deposits by an applicator cylinder 16 a adhesive substance A on the tops of the raised protrusions B2 of one of the two folds, here the fold P2, after the embossing of this fold by the CP2 cylinder associated with CG2 cylinder but before the engagement of the fold P2 between the two engraved cylinders CG1 and CG2.
  • the folds are not compressed during their simultaneous engagement between the engraved cylinders CG1, CG2 but they are on the other hand nested in the other and are ready to be bonded by means of a cylinder matchmaker CM which, like the pressure cylinders CP1 and CP2, is a cylinder with flexible coating of elastomeric material which, in the mode of embodiment illustrated in the figures, cooperates with the engraved metal cylinder CG2 to apply the two folds P1 and P2, previously embossed, glued and nested one inside the other, against the CG2 cylinder.
  • CM cylinder matchmaker CM which, like the pressure cylinders CP1 and CP2, is a cylinder with flexible coating of elastomeric material which, in the mode of embodiment illustrated in the figures, cooperates with the engraved metal cylinder CG2 to apply the two folds P1 and P2, previously embossed, glued and nested one inside the other, against the CG2 cylinder.
  • the installation allowing the implementation of the method according to the invention of course has adjustment means (not shown) of the distance between the two engraved cylinders CG1 and CG2 and therefore of adjusting the distance D separating the bottoms F1 and F2 from the engravings of the two cylinders in their mutual nesting area.
  • the method according to the invention makes it possible to produce stronger imprints in each of the two folds P1 and P2 by using, for example, an embossing pressure corresponding substantially to the limit of the flexible material of the cylinders CP1 and CP2 and for example of the order of 14 kg / cm 2 .
  • the method according to the invention makes it possible to produce, from paper reliably, i.e. flawlessly, creped from fibrous products to high absorption capacity and very soft to the touch.
  • the measurements were carried out after aging for 15 min at 125 ° C.
  • the basic sheet or fold, before any embossing has an absorption capacity of between 4 and 6 cm 3 / g.
  • An absorbent structure with two overlapping plies P1 and P2 produced according to the state of the art has an absorption capacity generally between 6 and 10 cm 3 / g and it is, in all cases, less than the limit value 20 d '' about 11 cm 3 / g.
  • the invention is not limited to the process which has just been described. It is in particular possible without departing from the scope of the invention, to apply the adhesive substance A on the vertices of the protrusions B1, B2 of the two folds P1 and P2 prior to their mutual engagement between the cylinders metallic engraved CG1 and CG2.
  • the invention is also not limited to the production of a structure absorbent with two plies, a third ply, previously embossed and arranged between folds P1 and P2, which can be engaged simultaneously between the engraved cylinders CG1 and CG2, the clearance J then being of course greater or equal to the sum of the thicknesses of the three plies previously embossed.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Machines For Manufacturing Corrugated Board In Mechanical Paper-Making Processes (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Paper (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to a manufacturing method for an absorbent structure (10) having at least two plies (P1, P2) each constituted of at least one embossed sheet of creped absorbent paper, wherein the plies (P1, P2) engage between two engraved metal cylinders (CG1, CG2) fitted with protrusions (R1, R2), driven in synchronized rotation, and mutually nesting with a play (J) between the tops of the protrusions (R1, R2) of one metal cylinder (CG1, CG2) and the opposite trough surface (F2, F1) of the engraving of the other cylinder (CG2, CG1), the method being characterized in that the play (J) is less than the depth of the cylinder engravings and larger than the sum of the thicknesses (E1, E2) of the plies (P1, P2) which were previously shaped in such a matching manner that the plies (P1, P2) are not compressed when being engaged between the nested engraved cylinders (CG1, CG2).

Description

La présente invention concerne un procédé de réalisation d'une structure ou feuille absorbante à au moins deux plis, constitués chacun d'au moins une feuille gaufrée de papier absorbant crêpé.The present invention relates to a method for producing a absorbent structure or sheet with at least two plies, each consisting of at least minus an embossed sheet of crepe absorbent paper.

L'invention concerne notamment la réalisation de produits fibreux, sous la forme de papiers absorbants à usage sanitaire et domestique.The invention relates in particular to the production of fibrous products, in the form of absorbent paper for sanitary and domestic use.

L'invention concerne ainsi plus particulièrement une structure absorbante à plusieurs plis, également appelée structure multicouche pour des produits tels que du papier toilette, des mouchoirs, des serviettes, ou des chiffons d'essuyage.The invention thus relates more particularly to a structure multi-ply absorbent, also called multi-layer structure for products such as toilet paper, handkerchiefs, towels, or wiping cloths.

Dans l'industrie du papier sanitaire et domestique, on utilise, pour la réalisation des différents produits, un papier absorbant crêpé de faible poids tel que l'ouate de cellulose ou le tissu ouaté. On profite de la capacité d'allongement de ce matériau, conféré par le crêpage, pour le gaufrer.In the sanitary and domestic paper industry, for the realization of the different products, a low crepe absorbent paper weight such as cellulose wadding or cotton wool. We take advantage of the elongation capacity of this material, conferred by creping, for the emboss.

En effet, le gaufrage donne du bouffant à la feuille et il induit une amélioration de l'absorption des liquides, du toucher et de la douceur. On a cherché à augmenter davantage la capacité d'absorption en créant des structures multicouches obtenues en associant au moins deux couches, aussi appelées plis constitués chacun d'au moins une feuille gaufrée de papier absorbant crêpé.Indeed, the embossing gives bulk to the sheet and it induces a improved absorption of liquids, touch and softness. Attempts have been made to further increase the absorption capacity by creating multilayer structures obtained by combining at least two layers, also called folds each consisting of at least one embossed sheet of crepe absorbent paper.

On a déjà proposé dans la demande de brevet français 93 00366 un procédé de réalisation d'une structure absorbante à au moins deux plis,

  • du type dans lequel on engage les plis entre deux cylindres métalliques gravés pourvus de protubérances, entraínés en rotation de manière synchronisée et s'imbriquant mutuellement avec un jeu J entre les sommets des protubérances d'un cylindre métallique et la surface en vis-à-vis du fond de la gravure de l'autre cylindre,
  • du type dans lequel chaque pli est, préalablement à son engagement entre les deux cylindres gravés, conformé à la surface de celui des cylindres gravés qui lui est associé en appliquant le pli sur ce dernier au moyen d'un cylindre presseur associé à revêtement souple, notamment en matériau élastomère ou en caoutchouc,
  • du type dans lequel on applique une substance adhésive sur les zones en relief d'au moins un pli préalablement à l'engagement des plis entre les cylindres gravés,
French patent application 93 00366 has already proposed a method for producing an absorbent structure with at least two plies,
  • of the type in which the folds are engaged between two engraved metal cylinders provided with protuberances, driven in rotation in a synchronized manner and interlocking with a clearance J between the tops of the protuberances of a metal cylinder and the surface facing screw of the bottom of the engraving of the other cylinder,
  • of the type in which each ply is, prior to its engagement between the two engraved cylinders, conformed to the surface of that of the engraved cylinders which is associated with it by applying the ply to the latter by means of a pressure cylinder associated with flexible coating, especially made of elastomeric material or rubber,
  • of the type in which an adhesive substance is applied to the raised areas of at least one fold prior to the engagement of the folds between the engraved cylinders,

Selon le procédé décrit dans ce document, la valeur du jeu J est choisie au plus égale à l'épaisseur de la feuille à gaufrer de manière à assurer un calandrage de la feuille au niveau des sommets des bossages obtenus avec l'association des plis à ce niveau. Ce procédé présente cependant l'inconvénient de nécessiter l'emploi de cylindres dont les tolérances d'usinage des gravures sont très serrées, ce qui n'est pas simple industriellement.According to the method described in this document, the value of the clearance J is chosen at most equal to the thickness of the sheet to be embossed so as to ensure calendering of the sheet at the tops of the bosses obtained with the association of folds at this level. This process presents however the drawback of requiring the use of cylinders whose machining tolerances of engravings are very tight, which is not easy industrially.

On connait également le procédé couramment désigné dans l'art antérieur par "nested" selon lequel les deux cylindres sont suffisamment distants l'un de l'autre pour que l'un des plis après gaufrage soit décollé du cylindre et appliqué sur le second cylindre gravé portant le deuxième pli de telle sorte que les protubérances du premier pli s'imbriquent entre les protubérances du second pli. Un cylindre marieur à revêtement en caoutchouc plaque le premier pli contre le second de façon à garantir le contact entre les sommets encollés du second pli et le premier pli, et leur association. Cette technique est illustrée par le brevet US 3867225.The process commonly designated in the art is also known. anterior by "nested" according to which the two cylinders are sufficiently distant from each other so that one of the folds after embossing is peeled off from the cylinder and applied to the second engraved cylinder carrying the second fold of so that the protrusions of the first fold overlap between the protrusions of the second fold. A matched cylinder with rubber presses the first fold against the second so as to guarantee the contact between the glued vertices of the second fold and the first fold, and their association. This technique is illustrated by US patent 3,867,225.

La demanderesse a toutefois pu constater qu'un tel procédé, lorsqu'il est fait appel à des pressions de gaufrage très élevées, aboutit parfois à un phénomène de flottement, en amont de l'engagement entre le cylindre marieur et le cylindre métallique gravé qui lui est associé, de celui des plis qui est décollé de son cylindre métallique de gaufrage pour son parcours dans cette zone en direction du cylindre marieur.The Applicant has however been able to observe that such a process, when is used at very high embossing pressures, sometimes results in a floating phenomenon, upstream of the engagement between the cylinder matchmaker and the engraved metal cylinder associated with it, that of the folds which is peeled off from its metallic embossing cylinder for its course in this area towards the match cylinder.

Ce phénomène de flottement aboutit à la formation d'une boucle entraínant un décalage entre les deux plis, et donc à des défauts de fabrication du fait de la non concordance des deux plis au moment de leur association par collage par le cylindre marieur.This floating phenomenon results in the formation of a loop causing a gap between the two folds, and therefore to defects of manufacturing due to the mismatch of the two plies at the time of their association by bonding by the matching cylinder.

Outre la difficulté de maintenir en synchronisation de déplacement les deux plis avant leur association par collage au moyen du cylindre marieur, cette technique a aussi pour inconvénient de nécessiter une pression suffisamment importante entre le cylindre marieur et l'un des cylindres gravés pour obtenir une bonne association par collage des deux plis préalablement gaufrés.Besides the difficulty of maintaining synchronization of displacement the two folds before their association by gluing by means of the cylinder This technique also has the disadvantage of requiring a match. sufficiently high pressure between the matching cylinder and one of the engraved cylinders to obtain a good association by bonding the two folds previously embossed.

L'utilisation d'une pression relativement importante aboutit alors, en raison de la résilience du cylindre marieur, à un phénomène de gaufrage supplémentaire, ou gaufrage à nouveau, du pli extérieur par rapport au cylindre gravé associé au cylindre marieur qui nuit à l'esthétique du produit ainsi qu'à sa douceur au toucher. The use of a relatively high pressure then results, in because of the resilience of the matching cylinder, to an embossing phenomenon additional, or embossing again, of the outer ply relative to the engraved cylinder associated with the matching cylinder which affects the aesthetics of the product as well as its softness to the touch.

La présente invention a pour but de proposer un procédé tirant partie des avantages des deux procédés mentionnés ci-dessus tout en remédiant aux inconvénients qui viennent d'être évoqués.The object of the present invention is to propose a method which takes advantage of of the advantages of the two methods mentioned above while remedying to the disadvantages which have just been mentioned.

Dans ce but, l'invention propose un procédé où les cylindres gravés sont distants l'un de l'autre avec un jeu J mesuré entre les sommets des protubérances d'un cylindre et la surface du fond de gravure de l'autre cylindre, ledit jeu J étant supérieur à la somme des épaisseurs des plis préalablement conformés, caractérisé en ce que ce jeu est inférieur à la profondeur de la gravure de cylindres.To this end, the invention proposes a method where the engraved cylinders are distant from each other with a clearance J measured between the vertices of the protrusions of one cylinder and the etching bottom surface of the other cylinder, said clearance J being greater than the sum of the thicknesses of the folds previously shaped, characterized in that this clearance is less than the depth of cylinder engraving.

L'invention propose également une installation pour la mise en oeuvre du procédé selon l'invention du type comportant deux cylindres métalliques gravés pourvus de protubérances, entraínés en rotation de manière synchronisée et avec un jeu J entre les sommets des protubérances d'un cylindre métallique et la surface en vis-à-vis du fond de la gravure de l'autre cylindre, supérieur à la somme des épaisseurs des plis préalablement gaufrés, caractérisé en ce que ledit jeu J est inférieur à la profondeur de la gravure des cylindres.The invention also provides an installation for setting up work of the method according to the invention of the type comprising two cylinders engraved metal with protrusions, rotated by synchronized and with a clearance J between the vertices of the protrusions of a metal cylinder and the surface facing the bottom of the engraving of the other cylinder, greater than the sum of the thicknesses of the folds previously embossed, characterized in that said clearance J is less than the depth of the engraving of cylinders.

L'invention propose aussi une structure absorbante à au moins deux plis réalisée selon l'invention et caractérisée en ce qu'elle possède une capacité d'absorption mesurée selon la norme AFNOR NFQ 03068 supérieure à 10 cm3/g, notamment comprise entre 11 et 14 cm3/g lorsqu'elle est réalisée à partir de deux feuilles de papier absorbant crêpé possédant chacune une capacité d'absorption comprise entre 4 et 6 cm3/g.The invention also provides an absorbent structure with at least two plies produced according to the invention and characterized in that it has an absorption capacity measured according to AFNOR NFQ 03068 standard greater than 10 cm 3 / g, in particular between 11 and 14 cm 3 / g when it is produced from two sheets of crepe absorbent paper each having an absorption capacity of between 4 and 6 cm 3 / g.

D'autres caractéristiques et avantages de l'invention apparaítront à la lecture de la description détaillée qui suit pour la compréhension de laquelle on se reportera aux dessins annexés dans lesquels :

  • la figure 1 représente en coupe transversale une structure absorbante à deux plis ;
  • la figure 2 est un schéma illustrant la conception d'une installation pour la mise en oeuvre du procédé de fabrication conforme aux enseignements de l'invention ;
  • la figure 3 est une vue schématique en coupe selon la ligne 3-3 de la figure ; et
  • la figure 4 est un diagramme permettant d'illustrer les performances d'une feuille multicouches absorbante réalisée conformément aux enseignements de l'invention.
Other characteristics and advantages of the invention will appear on reading the detailed description which follows for the understanding of which reference will be made to the appended drawings in which:
  • Figure 1 shows in cross section an absorbent structure with two plies;
  • Figure 2 is a diagram illustrating the design of an installation for the implementation of the manufacturing process according to the teachings of the invention;
  • Figure 3 is a schematic sectional view along line 3-3 of the figure; and
  • FIG. 4 is a diagram making it possible to illustrate the performance of an absorbent multilayer sheet produced in accordance with the teachings of the invention.

On a représenté à la figure 1, en coupe transversale, une feuille ou structure 10 à deux plis P1 et P2 emboítés l'un dans l'autre. There is shown in Figure 1, in cross section, a sheet or structure 10 with two plies P1 and P2 nested one inside the other.

Le pli P1 comporte des bossages B1 obtenus par gaufrage qui sont espacés les uns des autres et orientés en direction du pli P2 qui comporte également, de manière symétrique, des bossages B2 orientés vers le pli P1.The fold P1 has bosses B1 obtained by embossing which are spaced from each other and oriented towards the fold P2 which has also, symmetrically, bosses B2 oriented towards the fold P1.

Les bossages B2 sont emboítés entre les bossages B1 et l'écartement entre les bossages B1 et B2 est suffisant pour ménager entre eux un espace 12.The bosses B2 are fitted between the bosses B1 and the spacing between the bosses B1 and B2 is sufficient to provide between them a space 12.

Chaque pli ou feuille P1, P2 est une feuille d'ouate de cellulose, papier crêpé absorbant utilisé comme papier sanitaire ou domestique de poids compris entre 10 et 40 g/m2.Each ply or sheet P1, P2 is a sheet of cellulose wadding, crepe absorbent paper used as sanitary or domestic paper weighing between 10 and 40 g / m 2 .

L'épaisseur E1, E2 de chacun des plis P1, P2, qui peut être identique pour les deux plis, est par exemple de l'ordre de 0,1 mm.The thickness E1, E2 of each of the plies P1, P2, which can be identical for the two folds, is for example of the order of 0.1 mm.

La feuille 10 illustrée à la figure 1 est réalisée au moyen de l'installation représentée à la figure 2.The sheet 10 illustrated in FIG. 1 is produced by means of the installation shown in Figure 2.

Cette installation comporte deux unités de gaufrage constituées chacune d'un cylindre presseur CP1, CP2 à revêtement en matériau souple élastomère, coopérant avec un cylindre en acier gravé CG1, CG2 respectivement.This installation comprises two embossing units made up each of a pressure cylinder CP1, CP2 coated with flexible material elastomer, cooperating with an engraved steel cylinder CG1, CG2 respectively.

Les cylindres CG1 et CG2 sont gravés de façon à présenter en surface des éléments en relief et/ou des picots R1, R2 répartis aussi bien sur la circonférence, sens machine, que sur la largeur de chaque cylindre, sens travers.The cylinders CG1 and CG2 are engraved so as to present in surface of the elements in relief and / or of the pins R1, R2 distributed as well on the circumference, machine direction, than on the width of each cylinder, cross direction.

Conformément aux enseignements de l'invention, et comme on peut le voir aux figures 2 et 3, les cylindres métalliques gravés CG1 et CG2 d'axes parallèles sont positionnés l'un par rapport à l'autre de manière à s'imbriquer au niveau de leur zone en vis-à-vis, c'est-à-dire que les parties en relief R1 de l'un des cylindres s'intercalent entre les parties en relief R2 de l'autre cylindre, le chevauchement C également appelé engagement des deux cylindres, étant toutefois tel qu'il existe un jeu J entre les cylindres gravés CG1 et CG2 permettant l'engagement des plis P1 et P2 entre les cylindres gravés.In accordance with the teachings of the invention, and as can be see it in figures 2 and 3, the metallic cylinders engraved CG1 and CG2 parallel axes are positioned relative to each other so that overlap at the level of their opposite zone, that is to say that the parts in relief R1 of one of the cylinders is inserted between the parts in relief R2 of the other cylinder, the overlap C also called engagement of two cylinders, being however such that there is a clearance J between the cylinders engraved CG1 and CG2 allowing the engagement of folds P1 and P2 between the engraved cylinders.

Plus précisément, le jeu J mesuré entre les sommets des protubérances, par exemple R1, de l'un des cylindres métalliques CG1 et la surface en vis-à-vis du fond, par exemple F2, de la gravure de l'autre cylindre CG2 est supérieur ou égal à la somme des épaisseurs E1 et E2 des plis P1 et P2 lorsque ces derniers sont engagés dans la zone d'imbrication mutuelle des cylindres CG1 et CG2.More precisely, the clearance J measured between the vertices of the protrusions, for example R1, of one of the metallic cylinders CG1 and the surface facing the bottom, for example F2, of the engraving of the other cylinder CG2 is greater than or equal to the sum of the thicknesses E1 and E2 of the folds P1 and P2 when the latter are engaged in the nesting zone mutual fund CG1 and CG2.

On a ainsi la relation J > E1 + E2.
E1 et E2 sont les épaisseurs des plis P1 et P2 dans la zone d'imbrication, c'est-à-dire des plis P1 et P2 préalablement gaufrés avant leur engagement simultané entre les cylindres CG1 et CG2, du fait de leur passage préalable dans les deux unités de gaufrage.
We thus have the relation J> E1 + E2.
E1 and E2 are the thicknesses of the folds P1 and P2 in the nesting zone, that is to say of the folds P1 and P2 previously embossed before their simultaneous engagement between the cylinders CG1 and CG2, due to their prior passage in the two embossing units.

L'installation illustrée à la figure 2 comporte un dispositif d'encollage 14, connu en soi, qui dépose par un cylindre applicateur 16 une substance adhésive A sur les sommets des protubérances en relief B2 de l'un des deux plis, ici le pli P2, postérieurement au gaufrage de ce pli par le cylindre CP2 associé au cylindre CG2 mais préalablement avant l'engagement du pli P2 entre les deux cylindres gravés CG1 et CG2.The installation illustrated in Figure 2 includes a device size 14, known per se, which deposits by an applicator cylinder 16 a adhesive substance A on the tops of the raised protrusions B2 of one of the two folds, here the fold P2, after the embossing of this fold by the CP2 cylinder associated with CG2 cylinder but before the engagement of the fold P2 between the two engraved cylinders CG1 and CG2.

Grâce à la caractéristique de l'invention selon laquelle le jeu J est supérieur à la somme des épaisseurs E1, E2 des plis P1 et P2 préalablement gaufrés, les plis ne sont pas comprimés lors de leur engagement simultané entre les cylindres gravés CG1, CG2 mais ils sont par contre imbriqués l'un dans l'autre et sont prêts à être associés par collage au moyen d'un cylindre marieur CM qui, comme les cylindres presseurs CP1 et CP2, est un cylindre à revêtement souple en matériau élastomère qui, dans le mode de réalisation illustré sur les figures, coopère avec le cylindre métallique gravé CG2 pour appliquer les deux plis P1 et P2, préalablement gaufrés, encollés et imbriqués l'un dans l'autre, contre le cylindre CG2.Thanks to the characteristic of the invention according to which the clearance J is greater than the sum of the thicknesses E1, E2 of the folds P1 and P2 beforehand embossed, the folds are not compressed during their simultaneous engagement between the engraved cylinders CG1, CG2 but they are on the other hand nested in the other and are ready to be bonded by means of a cylinder matchmaker CM which, like the pressure cylinders CP1 and CP2, is a cylinder with flexible coating of elastomeric material which, in the mode of embodiment illustrated in the figures, cooperates with the engraved metal cylinder CG2 to apply the two folds P1 and P2, previously embossed, glued and nested one inside the other, against the CG2 cylinder.

Grâce à l'imbrication des deux plis assurée durant leur phase d'engagement mutuel entre les deux cylindres CG1 et CG2, il n'existe aucun risque de décalage relatif des deux plis entre le moment où ils quittent leur zone d'engagement mutuel entre les cylindres gravés CGI et CG2 et le moment où les deux plis imbriqués s'engagent entre le cylindre marieur CM et le cylindre gravé CG2.Thanks to the nesting of the two folds ensured during their phase mutual engagement between the two cylinders CG1 and CG2, there is no risk of relative offset of the two folds between the time they leave their mutual engagement zone between the engraved cylinders CGI and CG2 and the moment when the two overlapping folds engage between the matching cylinder CM and the engraved cylinder CG2.

De plus, du fait de l'imbrication intime préalable des deux plis P1 et P2, mais sans pression, la pression assurée par le cylindre marieur CM contre le cylindre métallique gravé CG2 peut être réduite évitant ainsi le phénomène de "gravure à nouveau" du pli P1 par les parties en relief R2 du cylindre métallique gravé CG2.In addition, due to the prior intimate nesting of the two folds P1 and P2, but without pressure, the pressure provided by the matching cylinder CM against the engraved metal cylinder CG2 can be reduced thus avoiding phenomenon of "etching again" of the fold P1 by the raised portions R2 of the metallic cylinder engraved CG2.

L'installation permettant la mise en oeuvre du procédé selon l'invention possède bien entendu des moyens de réglage (non représentés) de l'entraxe des deux cylindres gravés CG1 et CG2 et donc de réglage de la distance D séparant les fonds F1 et F2 des gravures des deux cylindres dans leur zone d'imbrication mutuelle.The installation allowing the implementation of the method according to the invention of course has adjustment means (not shown) of the distance between the two engraved cylinders CG1 and CG2 and therefore of adjusting the distance D separating the bottoms F1 and F2 from the engravings of the two cylinders in their mutual nesting area.

Le procédé selon l'invention permet de réaliser des empreintes plus fortes dans chacun des deux plis P1 et P2 en utilisant par exemple une pression de gaufrage correspondant sensiblement à la limite du matériau souple des cylindres CP1 et CP2 et par exemple de l'ordre de 14 kg/cm2. The method according to the invention makes it possible to produce stronger imprints in each of the two folds P1 and P2 by using, for example, an embossing pressure corresponding substantially to the limit of the flexible material of the cylinders CP1 and CP2 and for example of the order of 14 kg / cm 2 .

Le procédé selon l'invention permet de réaliser, à partir de papier crêpé, de manière fiable, c'est-à-dire sans défaut, des produits fibreux à haute capacité d'absorption et présentant une grande douceur au toucher.The method according to the invention makes it possible to produce, from paper reliably, i.e. flawlessly, creped from fibrous products to high absorption capacity and very soft to the touch.

Le diagramme de la figure 4 permet d'illustrer ces performances.
Sur ce diagramme, on a indiqué en ordonnée la capacité d'absorption d'une structure absorbante mesurée selon la norme AFNOR NFQ 03068 et qui est exprimée en cm3/g.
The diagram in Figure 4 illustrates these performances.
On this diagram, the absorption capacity of an absorbent structure measured according to AFNOR standard NFQ 03068 and which is expressed in cm 3 / g has been indicated on the ordinate.

En abscisse, on a fait figurer la résistance transverse humide exprimée en cN pour 15 mm.On the abscissa, we have shown the transverse wet resistance expressed in cN for 15 mm.

Les mesures ont été effectuées après un vieillissement de 15 min à 125°C.The measurements were carried out after aging for 15 min at 125 ° C.

Comme on peut le voir sur le diagramme, la feuille ou pli de base, avant tout gaufrage, présente une capacité d'absorption comprise entre 4 et 6 cm3/g.As can be seen in the diagram, the basic sheet or fold, before any embossing, has an absorption capacity of between 4 and 6 cm 3 / g.

Une structure absorbante à deux plis imbriqués P1 et P2 réalisée selon l'état de la technique présente une capacité d'absorption généralement comprise entre 6 et 10 cm3/g et elle est, dans tous les cas, inférieure à la valeur limite 20 d'environ 11 cm3/g.An absorbent structure with two overlapping plies P1 and P2 produced according to the state of the art has an absorption capacity generally between 6 and 10 cm 3 / g and it is, in all cases, less than the limit value 20 d '' about 11 cm 3 / g.

Au contraire, lorsque la structure absorbante multicouches est réalisée conformément au procédé selon l'invention, on obtient des valeurs ponctuelles, indiquées à la partie gauche de la courbe 18 de la figure 4 qui sont au-dessus de la valeur limite 20 et qui sont notamment comprises entre 12 et 14 cm3/g.On the contrary, when the multilayer absorbent structure is produced in accordance with the method according to the invention, one obtains point values, indicated on the left part of curve 18 of FIG. 4 which are above the limit value 20 and which are in particular between 12 and 14 cm 3 / g.

L'invention n'est pas limitée au procédé qui vient d'être décrit. Il est notamment possible sans sortir du cadre de l'invention, d'appliquer la substance adhésive A sur les sommets des protubérances B1, B2 des deux plis P1 et P2 préalablement à leur engagement mutuel entre les cylindres métalliques gravés CG1 et CG2.The invention is not limited to the process which has just been described. It is in particular possible without departing from the scope of the invention, to apply the adhesive substance A on the vertices of the protrusions B1, B2 of the two folds P1 and P2 prior to their mutual engagement between the cylinders metallic engraved CG1 and CG2.

L'invention n'est pas non plus limitée à la réalisation d'une structure absorbante à deux plis, un troisième pli, préalablement gaufré et agencé entre les plis P1 et P2, pouvant être engagé simultanément entre les cylindres gravés CG1 et CG2, le jeu J étant alors bien entendu supérieur ou égal à la somme des épaisseurs des trois plis préalablement gaufrés.The invention is also not limited to the production of a structure absorbent with two plies, a third ply, previously embossed and arranged between folds P1 and P2, which can be engaged simultaneously between the engraved cylinders CG1 and CG2, the clearance J then being of course greater or equal to the sum of the thicknesses of the three plies previously embossed.

Claims (4)

  1. Process for making an absorbent sheet (10) with at least two plies (P1, P2), each consisting of at least one embossed sheet of absorbent crepe paper,
    of the type in which the plies (P1, P2) are threaded between two engraved metal cylinders (CG1, CG2) provided with protuberances (R1, R2), driven in rotation in a synchronized manner, a play J being provided between the tops of the protuberances (R1, R2) of one metal cylinder (CG1, CG2) and the opposite surface of the bottom (F2, Fl) of the engraving of the other cylinder (CG2, CG1),
    of the type in which each ply (P1, P2), prior to it being threaded between two engraved cylinders (CG1, CG2), is made to conform totally or partially to the surface of the engraved cylinders with which it is associated by applying the ply (P1, P2) onto the latter (CG1, CG2) by means of a pressure cylinder (CP1, CP2) associated with a flexible covering, in particular made of elastomeric material or rubber,
    of the type in which an adhesive substance (A) is applied to the zones in relief (B2) of at least one ply (P2) prior to the plies (P1, P2) being threaded between the engraved cylinders (CG1, CG2),
    and of the type in which the two plies (P1, P2) are associated by gluing, subsequent to the plies being threaded between the engraved cylinders (CG1; CG2), by applying the two nested plies (P1, P2) onto one (CG2) of the two engraved cylinders by means of a marrying cylinder (CM) with a flexible covering, made in particular of an elastomeric material or of rubber, the said play (J) being greater than the sum of the thicknesses (E1, E2) of the previously formed plies (P1, P2), characterized in that the said play J is less than the depth of the engraving of the cylinders.
  2. Process according to claim 1, characterized in that the adhesive substance (A) is applied on the zones in relief on one of the two plies (P1, P2), prior to the plies being threaded between the engraved cylinders.
  3. Installation for implementing the process according to one of the preceding claims 1 or 2, of the type comprising two engraved metal cylinders (CG1, CG2) provided with protuberances (R1, R2), driven in rotation in a synchronized manner with a play (J) between the tops of the protuberances (R1, R2) of one metal cylinder and the facing surface of the bottom (F2, F1) of the engraving of the other cylinder, greater than the sum of the thicknesses (E1, E2) of the previously embossed plies, characterized in that the play J is less than the depth of the engravings of the cylinders.
  4. Absorbent structure (10) with at least two plies (P1, P2), each consisting of at least one embossed sheet of absorbent crepe paper, characterized in that it is made by a process according to one of claims 1 or 2, and in that its absorptive capacity, measured according to AFNOR standard NFQ 03068 lies between 11 and 14 cm3/g when it is made from two sheets of absorbent crepe paper each possessing an absorptive capacity of between 4 and 6 cm3/g.
EP97919437A 1996-03-27 1997-03-27 Method for making an absorbent structure Expired - Lifetime EP0828602B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9603779 1996-03-27
FR9603779A FR2746702B1 (en) 1996-03-27 1996-03-27 PROCESS FOR PRODUCING AN ABSORBENT SHEET
PCT/FR1997/000562 WO1997035712A1 (en) 1996-03-27 1997-03-27 Method for making an absorbent structure

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EP0828602A1 EP0828602A1 (en) 1998-03-18
EP0828602B1 true EP0828602B1 (en) 2000-04-12

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DE69929965T2 (en) * 1998-08-10 2006-11-23 Hunt Technology Ltd. IMPROVEMENTS RELATING TO METHOD FOR THERMAL LAMINATION
IT1308298B1 (en) * 1999-09-28 2001-12-10 Perini Fabio Spa EMBOSSER-LAMINATOR DEVICE WITH COUPLING OF ZONE SAILS, RELATIVE METHOD AND PRODUCT OBTAINED
EP1270196B1 (en) * 2001-06-29 2006-03-29 Georgia-Pacific France Method of making embossed tissue paper and embossing cylinder
US6832546B2 (en) * 2001-12-18 2004-12-21 Sca Hygiene Products Gmbh Embossing device
US6802937B2 (en) * 2002-06-07 2004-10-12 Kimberly-Clark Worldwide, Inc. Embossed uncreped throughdried tissues
US20080264275A1 (en) * 2007-04-30 2008-10-30 Lee Delson Wilhelm Embossing apparatus
DE102009025821B4 (en) * 2009-05-18 2011-03-31 Thyssenkrupp Steel Europe Ag Method for producing a metal component

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US3867225A (en) * 1969-01-23 1975-02-18 Paper Converting Machine Co Method for producing laminated embossed webs
US3708366A (en) * 1970-11-25 1973-01-02 Kimberly Clark Co Method of producing absorbent paper toweling material
US4093765A (en) * 1976-02-13 1978-06-06 Scott Paper Company Soft absorbent fibrous web and disposable diaper including same
US4483728A (en) * 1980-07-14 1984-11-20 Kimberly-Clark Corporation Relieved patterned marrying roll
US4543142A (en) * 1984-04-16 1985-09-24 Kimberly-Clark Corporation Process for making nested paper towels
FR2700496B1 (en) * 1993-01-15 1995-02-17 Kaysersberg Sa Method of embossing a sheet with one or more plies, sheet of embossed paper.
US5693406A (en) * 1995-08-25 1997-12-02 The Procter & Gamble Company Multi-ply paper product
EP0900301B1 (en) * 1996-05-23 2003-10-22 The Procter & Gamble Company Multiple ply tissue paper with continuous network regions

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US6306482B1 (en) 2001-10-23
GR3033905T3 (en) 2000-11-30
PT828602E (en) 2000-09-29
FR2746702B1 (en) 1998-05-29
DE69701661T2 (en) 2000-08-31
DK0828602T3 (en) 2000-07-17
ATE191677T1 (en) 2000-04-15
DE69701661D1 (en) 2000-05-18
ES2145599T3 (en) 2000-07-01
WO1997035712A1 (en) 1997-10-02
EP0828602A1 (en) 1998-03-18
TR199701442T1 (en) 1998-06-22

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