EP0826811A2 - Absorbierender Verbundvliesstoff mit einer weichen Fläche und einer rauhen Fläche und Verfahren zur Herstellung - Google Patents

Absorbierender Verbundvliesstoff mit einer weichen Fläche und einer rauhen Fläche und Verfahren zur Herstellung Download PDF

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Publication number
EP0826811A2
EP0826811A2 EP97420136A EP97420136A EP0826811A2 EP 0826811 A2 EP0826811 A2 EP 0826811A2 EP 97420136 A EP97420136 A EP 97420136A EP 97420136 A EP97420136 A EP 97420136A EP 0826811 A2 EP0826811 A2 EP 0826811A2
Authority
EP
European Patent Office
Prior art keywords
fibers
layer
fibres
material according
layers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP97420136A
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English (en)
French (fr)
Other versions
EP0826811A3 (de
EP0826811B1 (de
Inventor
Didier Bigot
Jacques Escoffier
Clément Heintz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AHLSTROM BRIGNOUD S.A.
Original Assignee
Ahlstrom Lystil SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ahlstrom Lystil SA filed Critical Ahlstrom Lystil SA
Publication of EP0826811A2 publication Critical patent/EP0826811A2/de
Publication of EP0826811A3 publication Critical patent/EP0826811A3/de
Application granted granted Critical
Publication of EP0826811B1 publication Critical patent/EP0826811B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/498—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres entanglement of layered webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/544—Olefin series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/549—Polyamides
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/55—Polyesters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00—Other non-woven fabrics

Definitions

  • the thickness can be of the order of a few tenths of a millimeter when making a "cloth" of wiping to reach a centimeter or even more for "sponge" type items, the grammage can vary from 30 g / m2 to 200 g / m2, or even more.
  • nonwovens we use one of three techniques for obtaining nonwovens, namely the so-called “dry process” technique which consists in making a veil of fibers mechanically or aerodynamics, using conventional textile machines such that openers, carders ..., or the technique called “wet”, technique derived from conventional papermaking, which consists in making a suspension of fibers which are received under form of a sheet, or the so-called “melted” technique consisting of make a web of randomly oriented continuous synthetic filaments relative to each other, and this directly at the outlet of the channels extruding said filaments.
  • dry process which consists in making a veil of fibers mechanically or aerodynamics
  • wet technique derived from conventional papermaking
  • melted so-called “melted” technique consisting of make a web of randomly oriented continuous synthetic filaments relative to each other, and this directly at the outlet of the channels extruding said filaments.
  • the present invention relates to a new type of complex not absorbent woven fabric which has the essential characteristic of having a flexible side, the other side being rough.
  • the respective grammages of the two layers are adapted according to applications, these grammages can range from 15 to 200 g / m2 for the layer intended to form the flexible face and from 10 to 70 g / m2 for the layer intended to form the rough surface.
  • the invention also relates to a method for production of such a product, said process consisting in producing two layers of elementary fibers, the two layers being linked together in downstream of the training area by a jet needling treatment fluid acting at least against the surface of the sheet comprising the hot-melt fibers intended to constitute the "scraping" side of the article complex formed.
  • a conventional machine for obtaining a nonwoven wet for example a machine of the Hydroformer type VOITH company, at the exit of which is arranged a set of tying hydraulic, also of known type, for example a Jet-jet water pressure treatment of the "Jet Lace" type ICBT-PERFOJET company, this machine being adjusted so that the jets preferentially act on the face of the multilayer material constituted by the tablecloth which contains the synthetic fibers hot-melt, which allows the fibers to be redirected in the Z direction of the sheet and somehow "file” them inside this last.
  • a conventional machine for obtaining a nonwoven wet for example a machine of the Hydroformer type VOITH company, at the exit of which is arranged a set of tying hydraulic, also of known type, for example a Jet-jet water pressure treatment of the "Jet Lace" type ICBT-PERFOJET company, this machine being adjusted so that the jets preferentially act on the face of the multilayer material constituted by the
  • the second layer by dry route, the association being made at the end of the formation of this layer relating to its surface, on the side where the action of the jets will be exerted interlacing fluid, the first veil made by wet or by dry process.
  • the two superimposed layers are preferably rewet before submitting them to the action of the jets of entanglement.
  • the nonwoven complex formed is dried and then possibly impregnated with acrylic-based chemical binders (optionally copolymerized), ethylene-vinyl-acetate, polyurethane ..., as well as various adjuvants allowing to reinforce properties specific such as hydrophilicity, flexibility.
  • this machine At the outlet of this machine, there is an installation interlacing by fluid jets sold by the company ICBT-PERFOJET under the name JET-LACE, this machine comprising four rows of injectors allowing the complex to be subjected to the action of jets / needles obtained from water under pressure included between 10 bars and 125 bars.
  • the number of jets / needles per meter of width of each row can vary from 800 to 1700 and is advantageously around 1000, the diameter of each injector orifice being generally between 100 and 140 microns, but possibly reaching a value of 300 microns.
  • the two tablecloths are superimposed so that the tablecloth with polypropylene fibers are at the top and, before drying, the complex is subjected to an entangling action by water jets, the four successive series of jets being obtained from of water under increasing pressure ranging from 23 bars for the first, 27 bars for the second, 55 bars for the third and also 55 bars for the fourth.
  • the action of the water jets changes the initial position of the fibers fuses and stiff which, originally, are located perfectly in the plane of the sheet, said fibers being re-oriented along the Z axis of said sheet and their extremity rising under the effect of the knots of entanglement, or even for the longest fibers forming loops between the tangles.
  • the complex is then dried and subjected to treatment inside a tunnel brought to 400 ° C (the temperature of burner in the case where the fused fibers are of the polypropylene type).
  • This heat treatment causes a partial melting of the fibers of polypropylene visible on the surface of the tablecloth making it abrasive by the formation of droplets at the point of fusion.
  • the effective temperature inside the oven is 190 ° C, i.e. higher than the melting point of polypropylene
  • the passage speed of the sheet inside the oven is such that the fibers only melt partially, other synthetic fibers (excluding any fibers binders) entering the composition of the complex being not affected by this heat treatment, thus making it possible to preserve the flexibility of the article.
  • the speed of passage of the sheet at the interior of the furnace is of the order of 90 m / min, the said furnace having a "effective" length of six meters, the nonwoven being previously preheated to a temperature of 140 ° C.
  • a sheet weighing 40 g / m2 is obtained having a flexible and absorbent face and the other side of which has abrasive properties formed by the visible ends of the fibers polypropylene.
  • this sheet can be used either as is to receive additional treatment online with a binder, in this case a polymer emulsion acrylic / vinyl acetate deposited at a rate of 10 g / m2.
  • thermobonding fibers As indicated above.
  • Such products are particularly suitable for carrying out semi-scouring or very absorbent wiping products, but could also be used in other areas, for example in the food industry, for solvent media, bench tops laboratories ...
  • a complex material according to the invention is produced by combining on the one hand a nonwoven obtained by the wet method, and on the other hand, a nonwoven obtained by dry process.
  • the nonwoven obtained by wet process made on the same machine than the previous example, has only one jet, forming in the final product about 50% of the total mass of the fibers.
  • This first layer is added, before treatment by the set of fluid jets on a card web, constituting 50% of the total weight of fibers, card web made of polyester fibers having a title of 1.7 dtex, curly, and a 38 mm cut.
  • This card veil is preferably slightly tangled with water jets beforehand ensure its cohesion and facilitate its handling.
  • the card web is located below the web produced humid, the whole being rewetted before being subjected to the action of entanglement jets made in the same manner as in Example 1.
  • the product is, as in the previous example, subjected to a heat treatment resulting in a partial melting of polypropylene fibers, making the surface where they are present abrasive.
  • a complex product is obtained, the characteristics of which are grouped in the table below.
  • Such a product which has a flexible face formed by the fibers polyester and a rough side is particularly suitable to be used as a variety of wiping materials in a manner similar to those cited in Example 1, and which have a high flexibility improved.
  • surfactants such as alkyl -sulfonates commonly used in dishwashing liquids, these products being either added alone, or mixed with a binder. It could also be considered to add softeners, degreasers, insecticides, bactericides, flame retardants, solvents.
  • polypropylene is particularly suitable for making the face scratching the article
  • fibers of polyethylene or possibly other fibers such as fibers polyvinyl chloride derivatives whose melting point allows perform heat treatment without deteriorating the characteristics of fibers used in the constitution of the complex.
  • the choice of polypropylene as a material particularly suitable for placing work of the invention is explained by the fact, that at the date of this demand, this is the product with the best ratio price / properties (solvent resistance, stiffness, abrasiveness, skin contact and food).
  • the ply preferably constituting the flexible layer absorbent will consist of fibers selected according to characteristics primarily sought.
  • fibers selected according to characteristics primarily sought.
  • viscose or cotton if you are considering an item with good tear resistance, preferably use fiber polyamide and, if you want to improve the touch, you will use preferably acetate or cellulose fibers (artificial silk).

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Artificial Filaments (AREA)
  • Laminated Bodies (AREA)
EP19970420136 1996-08-09 1997-07-29 Absorbierender Verbundvliesstoff mit einer weichen Fläche und einer rauhen Fläche und Verfahren zur Herstellung Expired - Lifetime EP0826811B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9610235A FR2752248B1 (fr) 1996-08-09 1996-08-09 Materiau complexe non tisse absorbant comportant une face souple et une face rugueuse, et procede pour son obtention
FR9610235 1996-08-09

Publications (3)

Publication Number Publication Date
EP0826811A2 true EP0826811A2 (de) 1998-03-04
EP0826811A3 EP0826811A3 (de) 1999-12-15
EP0826811B1 EP0826811B1 (de) 2002-10-30

Family

ID=9495076

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19970420136 Expired - Lifetime EP0826811B1 (de) 1996-08-09 1997-07-29 Absorbierender Verbundvliesstoff mit einer weichen Fläche und einer rauhen Fläche und Verfahren zur Herstellung

Country Status (4)

Country Link
EP (1) EP0826811B1 (de)
DE (1) DE69716689T2 (de)
ES (1) ES2183111T3 (de)
FR (1) FR2752248B1 (de)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1009531A0 (fr) * 1996-12-23 1997-03-04 Asota Gmbh Voile aiguillete a deux couches.
EP0865755A1 (de) * 1997-03-21 1998-09-23 Uni-Charm Corporation Wischtuch
EP0888743A1 (de) * 1997-07-02 1999-01-07 Firma Carl Freudenberg Strukturiertes Textilmaterial aus mindestens zwei Basisvliesen und Verfahren zur seiner Herstellung
WO2000076384A1 (fr) * 1999-06-16 2000-12-21 Georgia-Pacific France Produit de coton hydrophile comportant une face douce et une face grattante
EP1264561A1 (de) * 2001-06-06 2002-12-11 Paul Hartmann Aktiengesellschaft Verbundvliesstoffmaterial und Verfahren zu seiner Herstellung
FR2836161A1 (fr) * 2002-02-18 2003-08-22 Jacob Holm France Materiau ou voile en non tisse multicouches possedant une face rugueuse et une face douce
EP1382730A1 (de) * 2002-07-15 2004-01-21 Paul Hartmann AG Kosmetisches Wattepad
WO2004021846A1 (en) * 2002-09-05 2004-03-18 Paolo Alvera A mat
FR2849869A1 (fr) * 2003-01-14 2004-07-16 Ahlstrom Brignoud Procede de fabrication d'un non tisse composite et installation pour la mise en oeuvre dudit procede
WO2004083511A1 (fr) * 2003-02-19 2004-09-30 Jacob Holm Industries France Sas Voile en non tisse possedant une face rugueuse et une face douce et obsorbante
EP1582134A2 (de) * 2004-04-01 2005-10-05 Uni-Charm Corporation Reinigungstuch und Verfahren zu seiner Herstellung
WO2007053204A1 (en) * 2005-11-01 2007-05-10 Kimberly-Clark Worldwide, Inc. Two-sided personal-care appliance for health, hygiene, and/or environmental application(s); and method of making said two-sided personal-care appliance
EP1923496A1 (de) * 2005-09-09 2008-05-21 Sanko Co., Ltd. Reinigungstuch
EP1574208B1 (de) 2004-03-08 2016-08-10 L'Oréal Kosmetische Artikel zum einmaligen Gebrauch

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE20307343U1 (de) 2003-05-10 2003-07-31 Nölken Hygiene Products GmbH, 53578 Windhagen Gesichtsreinigungstuch
DE102014107725A1 (de) * 2014-06-02 2015-12-03 TRüTZSCHLER GMBH & CO. KG Verfahren zur Herstellung eines strukturierbaren mehrschichtigen Vlieses und mehrschichtiges Vlies
FR3128775A1 (fr) * 2021-10-29 2023-05-05 Sofitec Conduit de diffusion d’air à performances acoustiques élevées, en particulier pour véhicule automobile
DE102021006353A1 (de) 2021-12-27 2023-06-29 Mondi Ascania GmbH Verfahren zur Herstellung eines Nonwovenelements für Hygieneartikel

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0127851A2 (de) * 1983-05-26 1984-12-12 Kuraray Co., Ltd. Nichtgewobene Stoffbahn und Verfahren zur Herstellung derselben
EP0333211A2 (de) * 1988-03-18 1989-09-20 Kimberly-Clark Corporation Nicht elastischer, nicht gewebter, blattartiger Verbundwerkstoff und Verfahren zu dessen Herstellung
EP0540041A1 (de) * 1991-11-01 1993-05-05 Kimberly-Clark Corporation Verfahren zur Herstellung eines hydraulisch genadelten superabsorbierenden Verbundmaterials

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0127851A2 (de) * 1983-05-26 1984-12-12 Kuraray Co., Ltd. Nichtgewobene Stoffbahn und Verfahren zur Herstellung derselben
EP0333211A2 (de) * 1988-03-18 1989-09-20 Kimberly-Clark Corporation Nicht elastischer, nicht gewebter, blattartiger Verbundwerkstoff und Verfahren zu dessen Herstellung
EP0577156A2 (de) * 1988-03-18 1994-01-05 Kimberly-Clark Corporation Verbundvliesstoffmaterial und sein Herstellverfahren
EP0540041A1 (de) * 1991-11-01 1993-05-05 Kimberly-Clark Corporation Verfahren zur Herstellung eines hydraulisch genadelten superabsorbierenden Verbundmaterials

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch, Week 9617 Derwent Publications Ltd., London, GB; Class A97, AN 96-169788 XP002033971 ANONYMOUS: "Impervious absorbent wipe protects user's hands from becoming soiled - obtd. by extrusion-coating film of polyethylene between two absorbent nonwovens" & RESEARCH DISCLOSURE, vol. 382, no. 023, 10 février 1996 (1996-02-10), EMSWORTH, GB *

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1009531A0 (fr) * 1996-12-23 1997-03-04 Asota Gmbh Voile aiguillete a deux couches.
BE1009531B3 (fr) * 1996-12-23 1999-04-06 Asota Gmbh Voile aiguillete a deux couches.
EP0865755A1 (de) * 1997-03-21 1998-09-23 Uni-Charm Corporation Wischtuch
US6013349A (en) * 1997-03-21 2000-01-11 Uni-Charm Corporation Wiping sheet
EP0888743A1 (de) * 1997-07-02 1999-01-07 Firma Carl Freudenberg Strukturiertes Textilmaterial aus mindestens zwei Basisvliesen und Verfahren zur seiner Herstellung
WO2000076384A1 (fr) * 1999-06-16 2000-12-21 Georgia-Pacific France Produit de coton hydrophile comportant une face douce et une face grattante
FR2795100A1 (fr) * 1999-06-16 2000-12-22 Fort James France Produit de coton hydrophile comportant une face douce et une face grattante
EP1264561A1 (de) * 2001-06-06 2002-12-11 Paul Hartmann Aktiengesellschaft Verbundvliesstoffmaterial und Verfahren zu seiner Herstellung
DE10127514A1 (de) * 2001-06-06 2003-01-30 Hartmann Paul Ag Verbundvliesstoffmaterial und Verfahren zu seiner Herstellung
FR2836161A1 (fr) * 2002-02-18 2003-08-22 Jacob Holm France Materiau ou voile en non tisse multicouches possedant une face rugueuse et une face douce
WO2004007824A3 (de) * 2002-07-15 2004-03-25 Hartmann Paul Ag Kosmetisches wattepad
EP1382730A1 (de) * 2002-07-15 2004-01-21 Paul Hartmann AG Kosmetisches Wattepad
WO2004021846A1 (en) * 2002-09-05 2004-03-18 Paolo Alvera A mat
US7484276B2 (en) 2003-01-14 2009-02-03 Ahlstrom Corporation Process for manufacturing a composite nonwoven and installation for carrying out the process
FR2849869A1 (fr) * 2003-01-14 2004-07-16 Ahlstrom Brignoud Procede de fabrication d'un non tisse composite et installation pour la mise en oeuvre dudit procede
WO2004063451A1 (en) * 2003-01-14 2004-07-29 Ahlstrom Brignoud Manufacturing process of a composite nonwoven and installation for carrying out said process
CN100457997C (zh) * 2003-01-14 2009-02-04 阿尔斯特罗姆公司 复合非织造物的制造方法及实施该方法的设备
WO2004083511A1 (fr) * 2003-02-19 2004-09-30 Jacob Holm Industries France Sas Voile en non tisse possedant une face rugueuse et une face douce et obsorbante
EP1574208B1 (de) 2004-03-08 2016-08-10 L'Oréal Kosmetische Artikel zum einmaligen Gebrauch
EP1582134A3 (de) * 2004-04-01 2007-05-02 Uni-Charm Corporation Reinigungstuch und Verfahren zu seiner Herstellung
US7820277B2 (en) 2004-04-01 2010-10-26 Uni-Charm Corporation Wiper and method for manufacturing the same
EP1582134A2 (de) * 2004-04-01 2005-10-05 Uni-Charm Corporation Reinigungstuch und Verfahren zu seiner Herstellung
EP1923496A4 (de) * 2005-09-09 2009-01-14 Sanko Co Ltd Reinigungstuch
EP1923496A1 (de) * 2005-09-09 2008-05-21 Sanko Co., Ltd. Reinigungstuch
WO2007053204A1 (en) * 2005-11-01 2007-05-10 Kimberly-Clark Worldwide, Inc. Two-sided personal-care appliance for health, hygiene, and/or environmental application(s); and method of making said two-sided personal-care appliance

Also Published As

Publication number Publication date
DE69716689T2 (de) 2003-03-20
EP0826811A3 (de) 1999-12-15
FR2752248B1 (fr) 1998-09-25
DE69716689D1 (de) 2002-12-05
FR2752248A1 (fr) 1998-02-13
EP0826811B1 (de) 2002-10-30
ES2183111T3 (es) 2003-03-16

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