EP0799336A1 - Defibrage par rotation de l'asphalte - Google Patents
Defibrage par rotation de l'asphalteInfo
- Publication number
- EP0799336A1 EP0799336A1 EP95939036A EP95939036A EP0799336A1 EP 0799336 A1 EP0799336 A1 EP 0799336A1 EP 95939036 A EP95939036 A EP 95939036A EP 95939036 A EP95939036 A EP 95939036A EP 0799336 A1 EP0799336 A1 EP 0799336A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- asphalt
- fibers
- spinner
- range
- supplying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/18—Formation of filaments, threads, or the like by means of rotating spinnerets
Definitions
- This invention pertains to the manufacture of asphaltic products. More particularly, this invention relates to asphalt products in a fibrous form, and methods for producing fibrous forms of asphalt.
- Asphaltic products have been produced in various forms, with the primary uses of asphalt being in paving and in roofing products.
- the common source of asphalt is the residue or bottoms from the petroleum refining industry. This asphalt must be further refined or processed by air blowing (oxidizing) in order to raise the softening point and increase the stiffness to make useful products for roofing and specialty asphalt products.
- Some asphalt products have improved properties because of the addition of natural or synthetic rubbers or other organic additives. While asphalt itself has many beneficial properties, it lacks inherent tensile strength and integrity. Therefore, many asphalt products are reinforced with such materials as glass fibers or organic fibers such as polymer fibers, and have fillers such as ground limestone.
- asphalt roofing shingles are based on an interior web or carrier of a wet process glass fiber mat, and the asphalt itself contains about 65 percent by weight ground limestone filler.
- Other fillers used in asphalt products include carbon black, finely ground tires, clay, ground glass, and beads of various inorganic or organic materials.
- One of the problems with reinforcing asphalt is that it is often difficult to integrate the reinforcement material into the asphalt matrix, particularly in a uniform manner.
- integrating the asphalt and the reinforcement is accomplished by fixing the reinforcement material into a mat or web, and applying the asphalt in molten form, as is the case in manufacturing asphalt roofing shingles.
- Shingle manufacturing consists of running a continuous wet process glass fiber mat into a bath of molten asphalt to cause a coating on both sides of the mat as well as filling the interstices between the individual glass fibers. This process is limited in that it can only apply a relatively uniform coating, similar to a film.
- Another known method for integrating asphalt with reinforcements is to mix the asphalt with loose or paniculate reinforcement materials. Such mixing requires significant energy and capital equipment, and is not always successful in providing a uniform mix of asphalt and reinforcement. It would be advantageous to be able to uniformly intermix or integrate asphalt with reinforcement materials which are in an unfixed or loose form, rather than bound into a fixed product such as a mat. Also, it would be advantageous to be able to introduce the asphalt itself into various products in forms other than as a liquid.
- reinforcement layers have been used for reinforcing highway systems.
- Such well known reinforcement layers include glass fibers in mat form, either woven or nonwoven, asphalt impregnated mats, mats of organic materials, such as polyester fibers, mats in the form of an open weave or grid, and layers of glass fibers or other reinforcement fibers.
- These reinforcement layers are applied to the roadway beneath subsequently applied bituminous aggregate asphalt layers to reinforce the bituminous aggregate.
- Such reinforcement layers are typically used in locations where the underlying pavement has cracked and the highway system is being repaired.
- Reinforcement layers can also be used on the entire highway for repaying or as original construction.
- reinforcement layers can be used for special applications such as bridge decks. It is well known to use a tack coat on any of these highway reinforcement products to secure the reinforcement product to the roadway prior to applying the paving layer.
- a method for producing asphalt fibers comprising supplying molten asphalt to a rotating asphalt spinner; centrifuging asphalt fibers from the spinner; and collecting the asphalt fibers.
- the asphalt can be modified with one or more organic modifiers from the group consisting of natural rubber, synthetic rubber, elastomers, polymers, resins and other thermoplastic or thermoset materials.
- the modifiers are present in an amount within the range of from about 2 to about 30 percent (weight percent of the total organic composition). Most preferably, the modifiers are present in an amount within the range of from about 4 to about 12 percent.
- the molten asphalt is supplied to the asphalt spinner at a temperature within the range of from about 270°F (132°C) to about 500°F (260°C), as measured at a delivery point just above the spinner.
- the asphalt is subjected to an oxidizing process sufficient to give the asphalt a softening point within the range of from about 180°F (82°C) to about 350°F (177°C), and preferably within the range of from about 200°F (93 °C) to about 270°F (132°C), prior to the fiberizing process. All softening points are measured using the ring and ball method.
- the centrifuging step provides acceleration to the molten asphalt sufficient to produce primary asphalt fibers having a diameter within the range of from about 25 (635 10 3 ⁇ m) to about 60 hundred thousandths of an inch (Ht) (1524 K ⁇ m).
- the spinner has a peripheral wall with between 500 and 25,000 orifices tlirough which the asphalt is centrifiiged.
- the asphalt spinner has between 500 and 10,000 orifices.
- asphalt is centrifiiged by the asphalt spinner to form primary asphalt fibers, and the primary asphalt fibers are further attenuated by an annular, downwardly moving gaseous flow from a blower to form a downwardly moving veil of asphalt fibers.
- asphalt fibers having diameters smaller than 250 Ht (6350 10 3 ⁇ m).
- the diameter of the asphalt fibers is within the range of from about 25 (635 10- * ⁇ m) to about 150 Ht (3810 10 ⁇ ⁇ m), with the asphalt having a softening point within the range of from about 180°F (82°C) to about 350°F (177°C), and preferably within a range of from about 200°F (93°C) to about 270°F (132°C), in an unfilled state.
- the diameter of the asphalt fibers is within the range of from about 25 (635 KP ⁇ m) to about 60 Ht (1524 l ( ⁇ m).
- the asphalt fibers can be filled with a filler, and can be reinforced with reinforcement fibers, such as glass fibers.
- a mat of asphalt fibers having diameters within the range of from about 25 (635 10 3 ⁇ m) to about 60 Ht (1524 10-* ⁇ m), and the asphalt having a softening point within the range of from about 180°F (82°C) to about 350°F (177°C).
- the mat can be laminated as a layer to a mat of reinforcement material, such as a wet process glass fiber mat, to make a layered asphalt product.
- Also contemplated within this invention is a method for making an asphalt roofing shingle including the steps of assembling together a layer of asphalt fibers with a mat of reinforcement fibers, coating the assembled mats with asphalt to form an asphalt coated sheet, applying granules to the asphalt coated sheet, and cutting the asphalt coated sheet into roofing shingles.
- the invention also includes the asphalt roofing shingle made by this process.
- a method for integrating asphalt with reinforcement fibers including the steps of establishing a downwardly moving veil of reinforcement fibers of heat-softenable material, such as glass fibers, supplying molten asphalt to a rotating asphalt spinner positioned within the veil of reinforcement fibers, centrifuging asphalt fibers from the asphalt spinner in a manner which directs the asphalt fibers into engagement with the veil to integrate the asphalt with the reinforcement fibers, and collecting the integrated asphalt and reinforcement fibers.
- Another aspect of this invention is the use of the asphalt fibers of the invention as the input product for a carbonizing process. Carbon fibers are prepared by the controlled pyrolysis of an organic precursor in fibrous form.
- Fibers are produced by extrusion or melt blowing. Then the fibers are stabilized by oxidation at temperatures within the range of 200°C to 450°C, usually in air. The oxidation process gives the fiber enough structure at the molecular level to maintain its shape during the carbonization process. Finally, the fiber is carbonized at temperatures exceeding 800°C in an inert atmosphere such as argon. To improve properties the fibers are stretched during the carbonizing step to orient the molecules. Heating to higher temperatures (2500 to 3000°C) also increases the modulus and strength. The resultant carbon fibers have a wide variety of uses.
- Pitch fibers are made from petroleum or coal tar pitch, and are highly aromatic, containing a large proportion of asphaltenes (about 80 to 90 percent, as measured by heptane precipitation by ASTM 3279-78).
- the melting point of pitch is preferred to be near 260°C, with a glass transition temperature of about 85°C.
- Many pitches are not compatible with polymers.
- the asphalt used to make the asphalt fibers of the current invention contains 0 to 35 percent asphaltenes, and typically 15 to 25 percent.
- the asphaltene content is kept low to insure compatibility with polymers added.
- the glass transition temperature of the asphalt is within the range of from about -15°C to about -5°C.
- the melting point of the asphalt is typically within the range of from about 93 °C to about 116°C.
- An additional aspect of the invention is a method for making highway reinforcement products including establishing a downwardly moving veil of reinforcement fibers of heat-softenable material, supplying molten asphalt to a rotating asphalt spinner positioned within the veil of reinforcement fibers, centrifuging asphalt fibers from the asphalt spinner, thereby directing the asphalt fibers into engagement with the veil to integrate the asphalt with the reinforcement fibers, feeding a reinforcement mat beneath the asphalt spinner, and collecting the integrated asphalt and reinforcement fibers on top of the reinforcement fibers to form a highway reinforcement product.
- the invention also includes the highway reinforcement product produced by this method.
- the process of making highway reinforcement products is less time consuming and costly.
- the asphalt layers in such products can be more accurately metered out, and the asphalt and the reinforcement fibers can be easily integrated.
- the use of asphalt fibers in highway reinforcement products enables products of higher strength without having to increase the materials used. Also, since it is not necessary to dip the reinforcement mat into a bath of molten asphalt, the highway reinforcement can be made without the expense and hazards of an open asphalt bath.
- Figure 1 is a schematic sectional view in elevation of apparatus for centrifuging asphalt fibers according to the method of the invention.
- Figure 2 is a schematic sectional view in elevation of apparatus for cofiberizing asphalt fibers and glass fibers according to the method of the invention.
- Figure 3 is a schematic view in elevation of apparatus for alternately commingling veils of asphalt fibers with veils of glass fibers.
- Figure 4 is a perspective view of an asphalt fiber mat of the invention.
- Figure 5 is a schematic cross-sectional view in elevation of a laminated mat containing an asphalt fiber mat and a reinforcing mat.
- Figure 6 is a schematic view in elevation of a process of making asphalt roofing shingles according to the invention.
- Figure 7 is a schematic plan view of an asphalt roofing shingle of the invention.
- Figure 8 is a schematic view in elevation of a process for making a highway reinforcement product according to the invention.
- Figure 9 is a schematic cross-sectional view in elevation of a highway reinforcement product according to the invention.
- asphalts which can be employed in this invention can be either a naturally occurring asphalt or a manufactured asphalt produced by refining petroleum, and may include straight-run fractional-derived asphalts, cracked asphalts, asphalts derived from processing such as asphalt oxidizing, propane deasphalting, steam distilling, chemically modifying, and the like. In one of its preferred embodiments, the invention is applicable to asphalts for roofing shingle production.
- the asphalt can be either modified or unmodified.
- the apparatus for producing asphalt fibers from a rotary process includes rotatably mounted asphalt spinner 10 which is comprised generally of spinner bottom wall 12 and spinner peripheral wall 14.
- the asphalt spinner can be cast from nickle/cobalt/chromium alloy as used for the production of glass fibers, or can be any other suitable spinner such as one from welded stainless steel.
- the spinner peripheral wall has numerous orifices 16 for the centrifugation of asphalt fibers, and preferably has between about 500 and about 25,000 orifices.
- Molten asphalt is dropped into the rotating asphalt spinner as stream 20.
- the molten asphalt is driven radially outwardly and up the peripheral wall where centrifugal force centrifuges the asphalt through the orifices as asphalt streams or primary asphalt fibers 22.
- the primary asphalt fibers 22 are directed downwardly by annular blower 24 to form a downwardly moving flow or veil 25 of asphalt fibers. Any means can be used for turning the fibers from a generally radially outward path to a path directed toward a collection surface.
- centrifugal attenuation by the rotation of the asphalt spinner is sufficient to produce asphalt fibers of the desired fiber diameter, and no further attenuation is needed.
- the centrifuging process provides acceleration to the molten asphalt sufficient to produce primary asphalt fibers having a diameter below about 250 Ht (6350 10- * ⁇ m), preferably within the range of from about 25 (635 K ⁇ m) to about 150 Ht (3810 10-* ⁇ m), and most preferably within the range of from about 25 (635 lCP ⁇ m) to about 60 Ht (1524 10 3 ⁇ m).
- secondary attenuation is used to further attenuate the primary fibers.
- the blower is supplied with sufficient air pressure to pull the primary fibers and further attenuate them into the desired final asphalt fiber diameter. As shown in Figure 1, the blower attenuates the primary fibers into final fibers 26, which are collected as asphalt fiber web 28 on any suitable collection surface, such as conveyor 30.
- the asphalt fiber web 28 can be transported through any further processing steps, such as oven 32, to result in the final asphalt product, such as mat 34, which is also shown in Figure 4. Further processing steps could also include laminating the asphalt fiber mat or layer with a reinforcement layer, such as a glass fiber mat.
- the asphalt fiber mat is porous, having a porosity within the range of from about 20 (9.4 lO ' W/s) to about 50 CuFt./min. (23.6 lO'mVs) on a 1-inch square (0.645 10 '3 m 2 ) sample with a one-half inch water pressure (0.93 mm of Hg) drop.
- the asphalt fiber mat has a porosity within the range of from about 30
- the mat has a density within the range of from about 2 (32 kg/m 3 ) to about 10 pounds per cubic feet (pcf) (160 kg/m 3 ), and preferably within the range of from about 3 (48 kg m 3 ) to about 5 pcf (80 kg m 3 ).
- the mat has a high degree of flexibility and conformability (ability to be molded or shaped around sharp corners) when compared to an asphalt film of the same density or thickness.
- An optional feature of the invention is the use of a heating means, such as induction heater 35, to heat either the asphalt spinner, or the primary asphalt fibers, or both, to facilitate the asphalt fiber attenuation.
- a heating means such as induction heater 35
- induction heater 35 to heat either the asphalt spinner, or the primary asphalt fibers, or both, to facilitate the asphalt fiber attenuation.
- an auxiliary heat source can be used to maintain the temperature of the asphalt spinner at the level for optimum centrifugation of the asphalt into fibers.
- Other heating means for the asphalt spinner can be employed, such as electric resistance heating.
- the temperature of the asphalt spinner should be within the range of from about 270°F (132°C) to about 500°F (260°C), and preferably within the range of from about 330°F (165°C) to about 420°F (216°C).
- the asphalt spinner had a diameter of 15 inches (381 mm) and was rotated at 2300 RPM.
- the spinner peripheral wall was adapted with 854 orifices, each being 0.034 inches (0.86 mm) in diameter. There was no external heating from a burner and no secondary attenuation from a blower.
- the asphalt fibers were collected as a porous mat.
- Example II The oxidized Lagovan flux of Example I was further modified with 4 percent Kraton 1184.
- the polymer was incorporated into the asphalt by mixing in a Ross shear mixer at 400°F (204°C) for about 60 minutes.
- the resulting modified asphalt had a viscosity at 350°F ( 177°C) of 110,000 cps ( 110 Pa-s), a softening point of 285°F (141 °C), and a penetration of 14 dmm at 25°C.
- the asphalt was delivered at a temperature of 400°F (204°C) to the asphalt spinner of Example I rotating at 1700 RPM, and asphalt fibers were centrifiiged. These fibers were noticeably longer, stronger, and less tacky than the fibers from Example I.
- Example HI The oxidized Lagovan flux of Example I was further modified with 4 percent Kraton 1184.
- the polymer was incorporated into the asphalt by mixing in a Ross shear mixer at 400°F (204°C) for about 60
- the resulting asphalt had a softening point of 244°F (118°C), a penetration of 20 dmm at 25°C, and a viscosity at 350°F (177°C) of 11,250 cps (11.25 Pa « s).
- the asphalt was further processed by heat conditioning at 330°F (166°C) for 2 hours to raise the viscosity, resulting in an asphalt having a softening point of 245°F (118°C), and a viscosity at 350°F (177°C) of 26,900 cps (26.9 Pa « s).
- the asphalt was delivered at a temperature of 360°F (182°C) to the asphalt spinner of Example I rotating at 1356 RPM.
- the resulting asphalt fibers were an open-type web.
- the oxidized Lagovan flux of Example I was modified by mixing it with 10 percent Himont Profax 6301 polypropylene in a shear mixer.
- the resulting asphalt had a softening point of 302°F (150°C), a penetration of 7 dmm at 25°C, and a viscosity at 350°F (177°C) of 110,000 cps (110 Pa « s).
- the asphalt was delivered at a temperature of 409°F (209°C) to the asphalt spinner of Example I rotating at 1229 RPM.
- the resulting asphalt fibers were drier, less tacky, and more lofty than any of the asphalt fiber samples from Examples I through HI.
- Example V The diameter of asphalt fibers produced in Examples I through IV was measured by first preparing a sample by fixing a 1-inch (25.4-mm) by 1.5-inch (38.1-mm) thin asphalt fiber mat specimen on a microscope slide with a cover slip.
- the microscope was equipped with 200X capability, a video camera, and a monitor. Transmitted light was used for all measurements in a bright field mode.
- a pair of dial calipers capable of measuring to 0.1 mm and a calibration slide with divisions of at least 10 microns and a total length of at least 100 microns was used. The calibration slide was placed on the stage, and 100 microns was measured off the video monitor using the dial calipers.
- PET polyethyleneterphthalate
- Table I fiber diameters from a dried bottle grade polyethyleneterphthalate (PET) sample made by a similar rotary fiberizing process are included as a control in Table I.
- the PET material used was Eastman Kodapet dried at 230°C overnight.
- the PET fibers were made by centrifuging molten PET delivered at 600°F (316°C) to a 15-inch (318-mm) diameter spinner with 2400 holes having a diameter of 0.016 inch (0.406 mm). The spinner was rotated at 1600 RPM.
- the PET fibers exhibited some fusing and entangling. Some of the PET fibers were twinned, and the fibers exhibited brashiness (lack of slipperiness when rubbing one fiber against another).
- Example VI The asphalt of Example II was enhanced by the addition of clay filler to make up 10 percent of the total composition by weight.
- the fibers were stiffer than the fibers produced in Example ⁇ , and were also drier and shorter.
- the amount of filler is within the range of from about 2 to about 30 percent by weight of the total weight of asphalt and filler.
- the process for fiberizing asphalt with a rotating asphalt spinner can be used in combination with a rotary glass fiber forming process to integrate asphalt with glass fibers.
- the asphalt spinner 10 is positioned beneath a conventional glass spinner 40 of the type well known for producing glass fibers.
- the asphalt spinner is preferably mounted beneath the glass spinner bottom wall for coaxial rotation with the glass spinner on axis 42.
- Molten asphalt stream 20 drops through hollow quill 44 which rotatably supports the glass spinner. Attenuation of the glass fibers can be facilitated by annular blower 46 and annular burner 36, in a manner well known in the art of making glass fibers.
- Molten glass is dropped as stream 50 into the spinner, is centrifiiged as glass fibers 52 and turned downwardly as a flow of fibers and gases, or veil 54.
- An additive apparatus such as binder nozzle 56, can be positioned either within the veil or outside the veil, for applying any binder or other coatings or particles desired, or for supplying liquids for cooling the asphalt fibers.
- the asphalt fibers are distributed radially outwardly from the asphalt spinner, and they intermingle with the glass fibers in the veil and are collected on the conveyor as an intermingled mass 58 of asphalt fibers and glass fibers. Since the glass fiber forming process necessarily operates at temperatures above the softening point of glass, the area surrounding and immediately below the glass spinner is very hot.
- asphalt fibers will be entrained in some of the hot gases flowing with the veil of fibers, and thereby experience temperatures sufficient to soften or melt the asphalt fibers.
- some of the asphalt material may attach itself to some of the glass fibers to form asphalt particles on the fibers.
- the asphalt may also be in the form of a coating on some of the fibers. Care must be taken not to introduce the asphalt into a region with temperatures so hot as to ignite the asphalt.
- the mass of intermingled asphalt and glass fibers can be transported to any suitable processing station, such as oven 32, before becoming asphalt/glass fiber product 60.
- Example VII The asphalt sample of Example IV was cofiberized with glass fibers with apparatus similar to that shown in Figure 2.
- the resulting mass of intermingled asphalt and glass fibers was collected as an insulation product, which looked like black fiberglass insulation.
- the asphalt/glass fiber insulation product had between 60 and 65 percent by weight organic components, although the weight percent of the organic components can be within the range of from about 20 to about 80 percent of the asphalt/glass fiber commingled product.
- Four individual samples were prepared, with the results shown in Table II.
- FIG 2 alternate commingling of veils of asphalt fibers and glass fibers can also be used, as shown in Figure 3.
- the asphalt fibers can be integrated with the glass fibers by centrifuging glass fibers from one or more rotary glass spinners 40 which are supplied with molten glass by any suitable delivery means, such as forehearth 66, to establish one or more downwardly moving veils 54 of glass fibers.
- the glass fiber veils are positioned above collecting surface 30, and the veils of glass fibers are aligned generally along the length of the collecting surface.
- Asphalt fibers are centrifiiged by one or more rotary asphalt spinners 10 to establish one or more downwardly moving veils 25 of asphalt fibers also positioned above the collecting surface.
- the asphalt material can be supplied in molten form from a common source, such as asphalt supply conduit 68.
- the veils of asphalt fibers are aligned along the length of the collecting surface, generally colinearly with the veils of glass fibers, in an alternating fashion with the veils of glass fibers. The result is that the asphalt fibers and glass fibers intermingle and are collected as integrated asphalt fibers and glass fibers. Subsequently, the integrated asphalt and glass fibers can be further processed into the desired asphalt/glass fiber product.
- a single asphalt spinner is positioned between a pair of glass spinners.
- the asphalt fiber mat 34 of the invention shown in Figure 4, can be incorporated into numerous applications, particularly in the construction industry.
- Possible uses include glass mat thermoplastics, filtration, sound absorption, gasketing, sorbents, adhesives, mat binders, moisture resistant layers, corrosion resistant layers, insulation, polymer placement for shingle modification, application of a conforming layer without the need for heating or a solvent, impact absorbing layers, and highway resurfacing.
- the integrated glass fibers and asphalt can be subjected to a compressing or consolidation step which forms a more dense product.
- a compressing or consolidation step which forms a more dense product.
- the integrated glass fibers and asphalt Prior to consolidation the integrated glass fibers and asphalt preferably have a density within the range of from about 2 (32 kg/m 3 ) to about 15 pcf (240 kg/m 3 ), while after consolidation the integrated glass fiber and asphalt product preferably has a density within the range of from about 65 (1041 kg/m 3 ) to about 120 pcf (1922 kg/m 3 ).
- the consolidated product will have uses in various products including vibration damping material, molding material, insulation, and floor tile substrates.
- the asphalt fiber mat When the asphalt fiber mat is used in highway construction and repair, the asphalt fiber mat can be laminated with reinforcement mats, such as a wet process glass fiber mat, to form a reinforcement layer.
- the reinforcement layer is useful in various other construction applications as well as highway construction.
- a laminated mat 70 can be formed by laminating together asphalt mat 34 and a reinforcement layer, such as continuous glass fiber mat 72.
- the laminated mat can be used as a stress-absorbing membrane interlayer in various construction applications, such as highways.
- FIG. 6 The use of the asphalt fiber mat in a shingle process is shown in Figure 6, in which wet process shingle mat 76 and asphalt fiber layer 34 are laminated together to form laminated mat 70.
- the laminated mat is fed into asphalt coater 78, and granules are applied to the coated asphalt sheet by granule applicator 80.
- the granules are pressed into the sheet in any suitable manner, such as granule press 82, and are cut into individual shingles 84 by cutting cylinder 86.
- An individual shingle is shown in Figure 7. After the discrete shingles are formed, they can be processed with commonly used apparatus for handling such shingles, such as shingle stacker 88 to form stacks 90 of shingles, and bundle packager 92 to form shingle bundles 94.
- a layer of asphalt fibers in the construction of a shingle or other roofing product enables the selective positioning of a layer having specific properties. For example, if the asphalt fibers in the layer are modified with a polymer to provide high flexibility or elasticity, the use of the layer enables placement of high elasticity asphalt at the top portion of the shingle (where elasticity is needed) without requiring all of the coating asphalt to be modified. This construction would give a better performing shingle without much additional cost.
- Example Vm Asphalt roofing shingles were made by laminating an asphalt fiber layer made as in Example II above with a wet process shingle mat. The laminated mat was then coated with filled coating asphalt to make a shingle. The Elmendorf tear strength of the resulting shingle was 1953 grams. This is about 9 percent higher than the typical tear strength for conventional shingles.
- the process for making highway reinforcement products shown in Figure 8 includes glass spinner 100 mounted for coaxial rotation with first asphalt spinner 102. Molten glass 104 supplied to the spinner is centrifiiged from the glass spinner in the form of glass fibers 106. Molten asphalt 108 supplied to the first asphalt spinner is centrifiiged into asphalt fibers 110 by the first asphalt spinner.
- the asphalt fibers preferably have a diameter within the range of from about 25 (635 KP ⁇ m) to about 60 Ht (1524 lO-' ⁇ m). This cofiberizing of the glass fibers and the asphalt fibers commingles the two materials and integrates them with each other.
- the glass fibers and the asphalt fibers can be turned downwardly by annular blowers, not shown.
- the glass spinner and first asphalt spinner are positioned above a collecting surface, such as conveyor 112.
- a reinforcement mat such as open weave glass grid 114, can be fed onto the conveyor and directed beneath the flow of integrated asphalt and glass fibers.
- the reinforcement mat can be any type suitable for reinforcing pavement layers, either woven or nonwoven, of organic or inorganic materials, and preferably in the form of an open weave or grid.
- the integrated asphalt and glass fibers are collected on top of the glass grid to produce highway reinforcement product 116.
- the integrated asphalt and glass fibers are consolidated by calendering roll 117.
- tack coating material 118 can be applied to the top of the highway reinforcement product from any suitable source, such as tack coat spray applicator 120.
- the tack coat can be any suitable adhesive for bonding the highway reinforcement product to the roadway, such as an asphalt adhesive.
- the tack coat is tacky at a temperature of 25°C, as measured by ASTM rolling ball test D-2131, according to which values above about 40 mm are considered not tacky.
- a second layer of asphalt fibers 126 produced by second asphalt spinner 128 can be laid down on top of the highway reinforcement product.
- the second asphalt spinner is in general alignment with the first asphalt spinner along the length of the collecting surface.
- the asphalt stream 130 being supplied to the second asphalt spinner is of a composition which will create tacky fibers. This can be accomplished in several ways, such as by using an asphalt with a high penetration ratio.
- the tacky asphalt fibers have a diameter within the range of from about 25 (635 10 ⁇ m) to about 60 Ht (1524 lCP ⁇ m).
- the spray applied tack coat 118 is usually not necessary.
- the tacky asphalt fibers are tacky at a temperature of 25°C.
- the highway reinforcement product 116 has reinforcement mat or glass grid 114 as its top layer, since as applied to the highway the product is inverted from the orientation shown in Figure 8.
- layer 122 which is the integrated glass fibers 106 and asphalt fibers 110.
- the bottom layer is tack coat 118.
- the highway reinforcement product can contain release paper 124 to facilitate unwinding the product at the highway paving site.
- the invention can be usefiil in the manufacture of reinforcement products of asphalt and glass fibers, and in the manufacture of asphalt roofing shingles.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Road Paving Structures (AREA)
- Laminated Bodies (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Working-Up Tar And Pitch (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US36234294A | 1994-12-22 | 1994-12-22 | |
US362342 | 1994-12-22 | ||
PCT/US1995/014236 WO1996019600A1 (fr) | 1994-12-22 | 1995-10-31 | Defibrage par rotation de l'asphalte |
Publications (2)
Publication Number | Publication Date |
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EP0799336A1 true EP0799336A1 (fr) | 1997-10-08 |
EP0799336B1 EP0799336B1 (fr) | 2000-08-02 |
Family
ID=23425710
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95939036A Expired - Lifetime EP0799336B1 (fr) | 1994-12-22 | 1995-10-31 | Defibrage par rotation de l'asphalte |
Country Status (10)
Country | Link |
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EP (1) | EP0799336B1 (fr) |
JP (1) | JPH10510890A (fr) |
CN (1) | CN1173209A (fr) |
AU (1) | AU700729B2 (fr) |
BR (1) | BR9510479A (fr) |
CA (1) | CA2208034A1 (fr) |
DE (1) | DE69518255T2 (fr) |
ES (1) | ES2148580T3 (fr) |
TW (1) | TW440606B (fr) |
WO (1) | WO1996019600A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101542025B (zh) * | 2006-11-24 | 2011-04-27 | 松下电器产业株式会社 | 纳米纤维和高分子网状物的制造方法和装置 |
WO2010131062A1 (fr) * | 2009-05-13 | 2010-11-18 | Litwin | Matériel pour débiter un boudin de brai en granulés de brai ou similaires, comprenant des moyens de guidage de l'écoulement du boudin de brai |
TWI497024B (zh) * | 2012-06-05 | 2015-08-21 | Nat Inst Chung Shan Science & Technology | A rotary asphalt heat treatment device |
CN102704042B (zh) * | 2012-07-09 | 2013-11-27 | 遇秉武 | 一种沥青基碳纤维的制备方法 |
CN109234818B (zh) * | 2018-11-28 | 2022-03-08 | 青岛科技大学 | 一种环气流辅助静电纺丝装置及方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1356567A (en) * | 1970-09-08 | 1974-06-12 | Coal Industry Patents Ltd | Manufacture of carbon fibres |
JPS591725A (ja) * | 1982-06-28 | 1984-01-07 | Kawasaki Heavy Ind Ltd | 炭素繊維の製造方法 |
JPH0823088B2 (ja) * | 1985-06-28 | 1996-03-06 | 呉羽化学工業株式会社 | 炭素繊維マツトの製造方法及び装置 |
US4820078A (en) * | 1986-12-29 | 1989-04-11 | Brocious George D | Apparatus for road surface repair with fiber-reinforced asphalt |
CA1302934C (fr) * | 1987-06-18 | 1992-06-09 | Masatoshi Tsuchitani | Mode de preparation de brais mesophases |
JP2513500B2 (ja) * | 1988-10-03 | 1996-07-03 | 株式会社ブリヂストン | 自動車用内装材 |
US5458822A (en) * | 1993-06-21 | 1995-10-17 | Owens-Corning Fiberglas Technology, Inc. | Method for manufacturing a mineral fiber product |
JPH07316929A (ja) * | 1994-05-19 | 1995-12-05 | Nippon Muki Co Ltd | 石油アスファルト繊維及び石油アスファルト繊維成型品並びにそれらの製造方法 |
US5468546A (en) * | 1994-12-22 | 1995-11-21 | Owens-Corning Fiberglas Technology, Inc. | Method of making a highway reinforcement product |
-
1995
- 1995-10-30 TW TW84111474A patent/TW440606B/zh not_active IP Right Cessation
- 1995-10-31 BR BR9510479A patent/BR9510479A/pt active Search and Examination
- 1995-10-31 DE DE69518255T patent/DE69518255T2/de not_active Expired - Fee Related
- 1995-10-31 CA CA 2208034 patent/CA2208034A1/fr not_active Abandoned
- 1995-10-31 EP EP95939036A patent/EP0799336B1/fr not_active Expired - Lifetime
- 1995-10-31 WO PCT/US1995/014236 patent/WO1996019600A1/fr not_active Application Discontinuation
- 1995-10-31 CN CN 95197458 patent/CN1173209A/zh active Pending
- 1995-10-31 AU AU41004/96A patent/AU700729B2/en not_active Ceased
- 1995-10-31 ES ES95939036T patent/ES2148580T3/es not_active Expired - Lifetime
- 1995-10-31 JP JP8519784A patent/JPH10510890A/ja not_active Ceased
Non-Patent Citations (1)
Title |
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See references of WO9619600A1 * |
Also Published As
Publication number | Publication date |
---|---|
MX9704613A (es) | 1997-10-31 |
JPH10510890A (ja) | 1998-10-20 |
CN1173209A (zh) | 1998-02-11 |
ES2148580T3 (es) | 2000-10-16 |
EP0799336B1 (fr) | 2000-08-02 |
DE69518255D1 (de) | 2000-09-07 |
AU4100496A (en) | 1996-07-10 |
DE69518255T2 (de) | 2000-11-30 |
AU700729B2 (en) | 1999-01-14 |
TW440606B (en) | 2001-06-16 |
CA2208034A1 (fr) | 1996-06-27 |
BR9510479A (pt) | 1998-06-02 |
WO1996019600A1 (fr) | 1996-06-27 |
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