EP0778732A1

EP0778732A1 - Selective herbicides based on aryl uracils

Info

Publication number: EP0778732A1
Application number: EP95931171A
Authority: EP
Inventors: Hans-Joachim Santel; Markus Dollinger; Roland Andree; Mark Wilhelm Drewes
Original assignee: Bayer AG
Current assignee: Bayer AG
Priority date: 1994-09-02
Filing date: 1995-08-21
Publication date: 1997-06-18
Also published as: US5990044A; HK1001276A1; DE4431219A1; AU3471595A; CN1156394A; HK1049094A1; BR9508690A; CA2198742A1; WO1996007323A1; CN1079639C; MX9701553A; JPH10505072A; CN1370406A

Abstract

The invention concerns novel herbicidal synergistic combinations of active substances comprising on the one hand known aryl uracils (such as aryl thiouracils, or isomers of these aryl uracils and aryl thiouracils) and, on the other hand, other known herbicides of other classes of substance, said combinations being particularly effective when used for selectively combating weeds in various crops, in particular corn.

Description

Selective herbicides based on aryluracils

The invention relates to new herbicidal, synergistic active ingredient combinations which consist of known aryluracils (or arylthiouracils - or compounds which are isomeric to these aryluracils or arylthiouracils) on the one hand and other known herbicides which belong to other classes of substances on the other and are particularly successful for selective weed control in various crops, in particular in maize.

Aryluracils (or aryl-thio-uracile) as broadly active herbicides are the subject of a number of patent applications (cf. WO-A 91/00278, US-P 4979982, US-P 5169430, EP-A 408382, EP-A 563384, US-P 5084084, US-P 5127935, US-P 5154755, DE-P 4327743, DE-P 4343451, DE-P 4414326. However, the known aryl uracils (or aryl (thio) uracils) have a number of Efficacy gaps, especially against monocotyledon weeds.

Surprisingly, it has now been found that a number of known herbicidal active compounds from the group of aryluracils (or arylthiouracils - or compounds which are isomeric to these aryluracils or arylthiouracil compounds) when used together with known herbicidal active compounds, for example from the classes of the Alkylanilines, carboxylic acids, carboxamides, diazin (on) e or triazin (on) e, ureas, nitriles, thiocarbamates and triazolinones show pronounced synergistic effects with regard to the action against weeds and are particularly advantageous as broadly effective combination preparations for the selective control of both monocotyledons and of dicotyledon weeds, in the pre-emergence and post-emergence processes, in monocotyledon crops, such as, for example, maize. The invention relates to synergistic herbicidal compositions, characterized by an effective content of an active ingredient combination consisting of

(1) an aryluracil or an arylthiouracil of the general formula (I)

or an isomeric compound of the general formula (Ia)

where in formulas (I) and (Ia), respectively

Q represents oxygen or sulfur,

R represents hydrogen or halogen,

R ^{2 represents} halogen or cyano,

R represents the grouping below,

-A'-A ² -A ³ woπn

A ^{1 represents} a single bond, represents oxygen, sulfur, -SO-, -SO ₂ -, -CO- or the grouping -NA ⁴ -, wherein A ^{4 represents} hydrogen, hydroxy, alkyl, alkoxy, aryl, alkylsulfonyl or arylsulfonyl , or (A ¹ ) represents optionally substituted alkanediyl, alkenediyl, azaalkenediyl, alkindiyl, cycloalkanediyl, cycloalkenediyl or arendiyl,

A ^{2 represents} a single bond, represents oxygen, sulfur, -SO-, -SO ₂ -, -CO- or the grouping -NA ⁴ -, wherein A ^{4 represents} hydrogen, alkyl, aryl, alkylcarbonyl, alkylsulfonyl or arylsulfonyl, or (A ² ) stands for optionally substituted alkanediyl, alkenediyl, aza¬ alkenediyl, alkindiyl, cycloalkanediyl, cycloalkenediyl or arendiyl, and

A ³ for hydrogen, hydroxy, mercapto, amino, cyano, isocyano, thiocyanato, nitro, carboxy, carbamoyl, thiocarbamoyl, sulfo, chlorosulfonyl, halogen or for each optionally substituted alkyl,

Alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino, alkoxycarbonyl, dialkoxy (thio) phosphoryl alkenyl, alkenyloxy, alkenylamino, alkylidenamino, alkenyloxycarbonyl, alkynyl, alkynyloxy, alkynylamino, alkynyloxycarbonyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl, cycloalkyl , Cycloalkylidene amino,

Cycloalkyloxycarbonyl, cycloalkylalkoxycarbonyl, aryl, aryloxy,

Ar lalkyl, arylalkoxy, aryloxycarbonyl, arylalkoxycarbonyl, heterocyclic, heterocyclylalkyl, heterocyclylalkoxy or heterocyclylalkoxycarbonyl,

R ^{4 represents} hydrogen, halogen or optionally substituted alkyl,

R ^{5 represents} hydrogen, halogen or optionally substituted alkyl, and R ^{6 represents} hydrogen, hydroxy, amino or optionally substituted alkyl, alkoxy, alkenyl or alkynyl,

("Active substances of group 1") and

(2) a herbicidal active ingredient from a second group of herbicides (“active ingredients of group 2”) which contains the following classes of compounds (a) to (j):

(a) heteroaryloxyacetamides of the general formula (II)

in which

R ⁷ for each optionally substituted alkyl, alkenyl, alkynyl or

Alkoxy stands,

R ^{8 represents} in each case optionally substituted alkyl, alkenyl, alkynyl or phenyl, and

R ^{9 represents} optionally substituted heteroaryl;

(b) carbamoyltriazolinones of the general formula (III)

in which

R ^{10 represents} hydrogen, hydroxyl, amino or represents optionally substituted alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylamino, alkenylamino, alkynylamino, alkylideneamino, dialkylamino, cycloalkyl, cycloalkylalkyl, aryl or arylalkyl,

R ¹¹ for optionally substituted alkyl, alkenyl, alkynyl,

Alkoxy, alkenyloxy, alkynyloxy, alkylthio, alkenylthio, alkynylthio,

Alkylamino, alkenylamino, alkynylamino, dialkylamino, cycloalkyl,

Cycloalkyloxy, cycloalkylalkyl, aryl, aryloxy, arylthio, arylamino or arylalkyl, and

R ^{12 stands} for optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, arylalkyl, arylalkenyl or arylalkynyl;

(c) alkyl anilines, e.g. N- (l-ethyl-propyl) -3,4-dimethyl-2,6-dinitro-aniline (pendimethalin) or N, N-dipropyl-2,6-dinitro-4-trifluoromethyl-aniline (trifluralin);

(d) carboxylic acids such as e.g. 3,6-dichloropyridine-2-carboxylic acid (clopyralid), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxy-benzoic acid (Dicamba), 4 -Amino-3,5-dichloro-6-fluoropyridin-2-yl-oxyacetic acid (fluroxypyr), 2-amino-4- (hydroxymethylphosphinyl) butanoic acid ammonium salt (glufosinate ammonium), N-phosphonomethyl -glycir. (glyphosate) - (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-lH-imidazol-2-yl) -5-ethyl-pyridine-3-carboxylic acid (imazethapyr) or 2 - (4,5-Dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) -quinoline-3-carboxylic acid (imazaquine);

(e) carboxamides, such as BN- (2-methoxy-l-methyl-ethyl) -N- (2-ethyl-6-methyl-phenyl) -2-chloroacetamide (metolachlor), N-ethoxymethyl-N- (2-ethyl-6-methylphenyl) -2-chloroacetamide (acetochlor), N-methoxy- methyl-N- (2,6-dimethyl-phenyl) -2-chloroacetamide (alachlor), N- (2-methoxy-l-methyl-ethyl) -N- (2,4-dimethyl-3-thienyl) -2-chloroacetamide (dimethenamid), N- (1H-pyrazol-1-ylmethyl) -N- (2,6-dimethylphenyl) - 2-chloroacetamide (metazachlor) or Ni-propyl-N -phenyl-2-chloroacetamide (propachlor);

(f) diazin (on) e, or triazin (on) e, e.g. 2-chloro-4-ethylamino-6-i-propylamino-l, 3,5-triazine (atrazine), 3-i-propyl-lH-2, l, 3-benzothiadiazine-4 (3H) -one- 2,2-dioxide (bentazone), 2-chloro-4-ethylamino-6- (l-cyano-l-methyl-ethylamino) -l, 3,5-triazine (cyanazine), 4-amino-6-t- butyl-4,5-dihydro-3-methylthio-l, 2,4-triazin-5-one (metribuzin), O- (6-

Chloro-3-phenyl-4-pyridazinyl) -S-octyl-thiocarbonate (pyridate); 2-chloro-4,6-bis-ethylamino-l, 3,5-triazine (simazine) or 2-chloro-4-ethylamino-6-t-butylamino-l, 3,5-triazine (terbuthylazine);

(g) ureas, e.g. N- (4,6-Dimethoxy-pyrimidin-2-yl) -N- (3-chloro-4-methoxycarbonyl-1-methyl-pyrazol-5-yl-sulfonyl) urea (Clopyra-sulfurone), N-methoxy -N-methyl-N- [4- (3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1 -benzopyran7-yl-oxy) phenyl] urea (metobenzuron), N- (4,6-Dimethoxy-pyrimidin-2-yl) -N '- (3-dimethylamino-carbonyl-pyridin-2-yl-sulfonyl) urea (nicosulfuron), N- (4,6-bis-difluoromethoxy -pyrimidin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (primisulfuron-methyl), N- (4-methoxy-6-methyl-1, 3, 5 -triazin-2-yl ) -N '- [2- (3, 3, 3-trifluoropropyl) phenylsulfonyl] urea (prosulfuron), N- (4,6-dimethoxypyrimidin-2-yl) -N- (3rd -ethyl-sulfonyl-pyridin-2-yl-sulfonyl) urea (rimsulfüron) or N- (4-methoxy-6-methyl-l, 3,5-triazin-2-yl) -N- (2-methoxycarbonyl- 3-thienylsulfonyl) urea (thifensulfuron-methyl);

(h) nitriles such as 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil) or 3,5-diiodo-4-hydroxy-benzonitrile (ioxynil);

(i) thiocarbamates such as N-di-i-butyl-S-ethyl-thiocarbamate (butylates) or N-dipropyl-S-ethyl-thiocarbamate (EPTC); (j) Active substances from various groups of substances, such as, for example, N-2,6-difluorophenyl-5-methyl- [l, 2,4] triazolo- [l, 5-a] pyrimidine-2-sulfonamide (flumet- sulam), l, -dimethyl-4,4'-bipyridinium chloride (paraquat) or 2- (2-chloro-4-methylsulfonyl-benzoyl) -l, 3-cyclohexanedione (sulcotrione),

with 1 part by weight of active ingredient of group 1 generally in each case

0.001 to 1000 parts by weight of active ingredient of group 2 are eliminated.

Herbicidal compositions according to the invention are of particular interest

(1) a compound of formula (I) or (Ia) wherein

Q ^{1 represents} oxygen or sulfur,

Q ^{2 represents} oxygen or sulfur,

R ^{1 represents} hydrogen, fluorine, chlorine or bromine,

R ^{2 represents} fluorine, chlorine, bromine, iodine or cyano,

R ^{3 represents} the grouping below,

-A ^J -A ² -A ³

wherein

A ^{1 represents} a single bond, represents oxygen, sulfur, -SO-, -SO ₂ -, -CO- or the grouping -NA ⁴ -, wherein A ^{4 represents} hydrogen, hydroxy, C, -C ₄ alkyl, C _r C ₄ alkoxy, phenyl, C _r C ₄ - alkylsulphonyl or phenylsulphonyl, or (A ¹⁾ represents optionally fluorine-, chlorine- or bromine-substituted C _j -C ₆ - alkanediyl, C ₂ -C ₆ alkene diyl, C ₂ -C ₆ azaalkenediyl, C ₂ -C ₆ . Alkindiyl, C ₃ -C ₆ cycloalkanediyl, C ₃ - C ₆ cycloalkenediyl or phenyl, A ^{2 represents} a single bond, represents oxygen, sulfur, -SO-, -SO ₂ -, -CO- or the grouping -NA ⁴ -, wherein A ^{4 represents} hydrogen, hydroxy, C, -C ₄ alkyl, C _r C ₄ alkoxy, phenyl, C _r C ₄ alkylsulfonyl or phenylsulfonyl, or (A ² ) is in each case optionally substituted by fluorine, chlorine or bromine, C ₆ -C ₆ -alkanediyl, C ₂ -C ₆ -alkenediyl, C ₂ -C ₆ azaalkenediyl, C ₂ -C ₆ _alkindiyl, C ₃ -C ₆ cycloalkanediyl, C ₃ - C ₆ cycloalkenediyl or phenylene,

A ³ for hydrogen, hydroxy, amino, cyano, isocyano, thiocyanato, nitro, carboxy, carυamoyl, thiocarbamoyl, sulfo, chlorosulfonyl, halogen, each optionally with halogen or C _j -, -

Alkoxy-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino, alkoxycarbonyl or dialkoxy- (thio) phosphoryl each having 1 to 6 carbon atoms in the alkyl groups, for alkenyl, alkenyloxy, alkenylamino optionally substituted by halogen, alkylideneamino, alkenyloxy carbonyl, alkynyl, alkynyloxy, alkynylamino or alkinyloxycarbonyl having in each case 2 to 6 carbon atoms in the alkenyl, alkylidene or alkinyl groups, represents in each case optionally halogen-, cyano, carboxy, C _j -C ^ alkyl and / or C _j -C ₄ -alkoxy-carbonyl-substituted cycloalkyl, cycloalkyloxy, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylideneamino, cycloalkyloxycarbonyl or cycloalkylalkoxycarbonyl each having 3 to 6 carbon atoms in the cycloalkyl groups and optionally 1 to 4 carbon atoms in the alkyl groups, or for each optionally by nitro, cyano, carboxy, halogen C _r C ₄ alkyl, C _r C ₄ haloalkyl, C _r C ₄ -Alkyloxy,

C ₁ -C ₄ haloalkyloxy and or C ₁ -C ₄ alkoxy-carbonyl-substituted phenyl, phenyloxy, phenyl-C _r C ₄ -alkyl, phenyl-C _r C ₄ -alkoxy, phenyl-oxycarbonyl or phenyl-C ₁ -C ₄ - alkoxycarbonyl, (in each case fully or partially hydrogenated) pyrrolyl, pyrazolyl, imidazolyl, triazolyl, furyl, thienyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl,

Oxadiazolyl, thiadiazolyl, pyridinyl, pyrimidinyl, triazinyl, pyrazolyl-C _r C ₄ -alkyl, furyl-C _r C ₄ -alkyl, thienyl-C, -C ₄ -alkyl, oxazolyl-C _j -C ^ alkyl, isoxazole-C ₁ -C ₄ -alkyl, thiazole-C _r C ₄ -alkyl, pyridinyl-C _] -C ₄ -alkyl, pyrimidinyl-C, -C ₄ -alkyl, pyrazolylmethoxy, Furylmethoxy, stands for perhydropyranylmethoxy or pyridylmethoxy,

R ^{4 represents} hydrogen, fluorine, chlorine, bromine or alkyl having 1 to 4 carbon atoms which is optionally substituted by fluorine and / or chlorine,

R ^{5 represents} hydrogen, fluorine, chlorine, bromine or alkyl having 1 to 4 carbon atoms which is optionally substituted by fluorine and / or chlorine, and

R ^{6 represents} hydrogen, hydroxy, amino or alkyl, alkoxy, alkenyl or alkynyl, each optionally substituted by fluorine, chlorine or cyano, each having up to 4 carbon atoms, and

(2) an active ingredient from a second group of herbicides, which contains the following classes of compounds (a) to (j):

(a) Heteroaryloxyacetamides of the formula (ü) in which

R ⁷ represents alkyl, alkenyl, alkynyl or alkoxy, each of which is optionally substituted by halogen, cyano or CJ-J alkoxy, each having up to 6 carbon atoms,

R ⁸ represents in each case optionally substituted by halogen, cyano or C _j -C ₄ alkoxy alkyl, alkenyl or alkynyl each of up to 6 carbon atoms or is optionally substituted by halogen, cyano,

C ₁ -C ₄ alkyl, C ₁ -C ₄ haloalkyl, C ₁ -C ₄ -AlkoxyoderC ₁ -C ₄ halo-alkoxy substituted phenyl, and

R ⁹ is optionally substituted by halogen, cyano, C _r C ₄ alkyl, C, - C ₄ haloalkyl, C _j -C ₄ alkoxy or C, -C ₄ -haloalkoxy l substitution iertes heteroaryl from the series 3 -Thiazol-2-yl, l, 2,4-thiadiazol-5-yl, l, 3,4-thiadiazol-2-yl, benzoxazol-2-yl, benzthiazol-2-yl; (b) carbamoyltriazolinones of the formula (III) in which

R ¹⁰ for hydrogen, hydroxyl, amino, for each optionally substituted by halogen or cyano-substituted alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylamino, alkenylamino, alkynylamino, alkylideneamino or dialkylamino, each with up to 6 carbon atoms, each optionally by halogen, cyano or C, -C ₄ - substituted alkyl cycloalkyl, cycloalkylalkyl having in each case 3 to 6 carbon atoms in the cycloalkyl groups and optionally 1 to 4 carbon atoms in the alkyl group, or represents in each case optionally halogen-, cyano, C _j -C ₄ - alkyl or C ₁ -C ₄ alkoxy-substituted phenyl or phenyl-C ₁ -C ₄ alkyl,

R ¹¹ for alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, alkenylthio, alkynylthio, alkylamino, alkenylamino, alkynylamino or dialkylamino, each optionally substituted by halogen, cyano, CC ₄ alkoxy or C, -C ₄ alkylthio each with up to 6 carbon atoms, for each cycloalkyl, cycloalkyloxy or cycloalkylalkyl optionally substituted by halogen, cyano or C 1 -C ₄ -alkyl, each having 3 to 6 carbon atoms in the cycloalkyl groups and optionally 1 to 4 carbon atoms in the alkyl group , or for each if necessary by

Halogen, cyano, C, -C ₄ alkyl or C ₁ -C ₄ alkoxy substituted phenyl, phenoxy, phenylthio, phenylamino or phenyl-C _j -C ₄ alkyl, and

R ¹² for each optionally halogen, cyano, C _j -C ₄ alkoxy, C _j - C ₄ alkylthio, C _r C ₄ alkylsulfonyl, C _r C ₄ alkylsulfonyl, C, -C ₄ alkylamino or Di- (C ₁ -C ₄ -alkyl) -amino-substituted alkyl, alkenyl, alkynyl each having up to 10 carbon atoms, for cycloalkyl or cycloalkylalkyl, each having 3 or optionally substituted by halogen, cyano or C _] -C ₄ -alkyl up to 6 carbon atoms in the cycloalkyl part and optionally 1 to 4 carbon atoms in the alkyl part, for each optionally by halogen, Cyano, C _r C ₄ alkyl or C _j -C ₄ alkoxy substituted phenyl-C _r C ₆ -alkyl, phenyl-C ₂ -C ₆ -alkenyl or phenyl-C ₂ -C ₆ alkynyl;

(d) carboxylic acids such as e.g. 3,6-dichloropyridine-2-carboxylic acid (clopyralid), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxy-benzoic acid (Dicamba), 4 -Amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy-acetic acid (fluroxypyr), 2-amino-4- (hydroxymethyl-phosphinyl l) -butanoic acid- ammonium salt (glufosinate-ammonium), N-

Phosphonomethyl-glycine (glyphosate), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-lH-imidazol-2-yl) -5-ethyl-pyridine-3-carboxylic acid (Ima - zethapyr) or 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) -quinoline-3-carboxylic acid (imazaquine);

(e) carboxamides such as N- (2-methoxy-l-methyl-ethyl) -N- (2-ethyl-

6-methyl-phenyl) -2-chloroacetamide (metolachlor), N-ethoxymethyl-N- (2-ethyl-6-methyl-phenyl) -2-chloroacetamide (acetochlor), N-methoxy-methyl-N - (2,6-dimethyl-phenyl) -2-chloroacetamide (alachlor), N- (2-methoxy-l-methyl-ethyl) -N- (2,4-dimethyl-3-thienyl) -2- chloroacetamide (dimethenamid), N- (lH-pyrazol-l-yl-methyl) -N- (2,6-dimethyl-phenyl) -

2-chloroacetamide (metazachlor) or N-i-propyl-N-phenyl-2-chloroacetamide (propachlor);

(f) diazin (on) e, or triazin (on) e, such as. 2-chloro-4-ethylamino-6-i-propyl-mino-l, 3,5-triazine (atrazine), 3-i-propyl-lH-2J, 3-benzothiadiazine-4 (3H) -one -2,2-dioxide (bentazone), 2-chloro-4-ethylamino-6- (l-cyano-1-methyl-ethylamino) -l, 3,5-triazine (cyanazine), 4-amino-6-t -butyl-4,5-di-hydro-3-methylthio-l, 2,4-triazin-5-one (metribuzin), O- (6-chloro-3-phenyl-4-pyridazinyl) -S- octyl thiocarbonate (pyridate); 2-chloro-4,6-bis-ethylamino-l, 3,5-triazine (simazine) or 2-chloro-4-ethylamino-6-t-butylamino-l, 3,5-triazine (terbuthylazine); (g) ureas, such as N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-chloro-4-methoxycarbonyl-1-methyl-pyrazol-5-yl-sulfonyl) urea ( Clopyra sulfuron), N-methoxy-N-methyl-N '- [4- (3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-l-benzopyran7-yl-oxy) phenyl ] urea (metobenzuron), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-dimethylamino-carbonyl-pyridin-2-yl-sulfonyl) urea ^ icosulfuron) ^ I - (4,6-bis-fluoromethoxy-pyrimidin-2-yl) -N ^, - (2-methoxycarbonyl-phenylsulfonyl) - urea (Primisulfüron-methyl), N- (4-methoxy-6-methyl-l, 3,5-tri-aan-2-yl) -N- [2- (3,3,3-trifluoropropyl) phenylsulfonyl] urea (sulfuron), N- (4,6-dimethoxypyrimidine -2-yl) -N '- (3-ethylsulfonyl-pyridin-2-yl-sulfonyl) urea (rimsulfuron) or N- (4-methoxy-6-memyl-l, 3,5-triazin-2-yl ) -N ^, - (2-methoxycarbonyl-3-thienylsulfonyl) urea (thifensulfuron-methyl);

(i) thiocarbamates such as e.g. N-di-i-butyl-S-ethyl-thiocarbamate (butylate) or N-dipropyl-S-ethyl-thiocarbamate (EPTC);

(j) active substances from various substance groups, e.g. N-2,6-difluorophenyl-5-methyl- [l, 2,4] triazolo- [l, 5-a] pyrimidine-2-sulfonamide (flumet-sulam), l. -DimethyM ^ '- bipyridinium chloride ^ araqua ^ or 2- (2-

Chloro-4-methylsulfonyl-benzoyl) - 1,3-cyclohexanedione (Sulcotrione),

1 to 1 part by weight of active ingredient in group 1 is preferably 0.01 to 100 parts by weight of active ingredient in group 2.

Herbicidal compositions according to the invention are of very particular interest

(1) a compound of formula (I) or (Ia) wherein

Q ^{1 represents} oxygen or sulfur,

Q ^{2 represents} oxygen or sulfur, R ^{1 represents} hydrogen, fluorine, chlorine or bromine,

R ^{2 represents} fluorine, chlorine, bromine, iodine or cyano,

R ^{3 represents} the grouping below,

-A ^] -A ² -A ³

in which

A ^{1 represents} a single bond, represents oxygen, sulfur, -SO-, -SO ₂ -, -CO- or the grouping -NA ⁴ -, wherein A ^{4 represents} hydrogen, hydroxy, methyl, ethyl, n- or i-propyl , Methoxy, ethoxy, n- or i-propoxy, methylsulfonyl or ethylsulfonyl, or (A ¹ ^ is methylene, ethane-1, 1-diyl, ethane-1, 2-diyl, propane-1, 1-diyl, propane - 1,2-diyl, propane-1,3-diyl, ethene-1,2-diyl, propene-1,2-diyl, propene-1,3-diyl, ethyne-1,2-diyl, propyne-1 , 2-diyl or propin-1,3-diyl,

A ^{2 represents} a single bond, represents oxygen, sulfur, -SO-, -SO ₂ -, -CO- or the grouping -NA ⁴ -, wherein A ^{4 represents} hydrogen, hydroxy, methyl, ethyl, n- or i-propyl , Methoxy, ethoxy, n- or i-propoxy, methylsulfonyl, ethylsulfonyl, n- or i-propylsulfonyl or phenylsulfonyl, or (A ^{2) is} methylene, ethane-1,1-diyl, ethane-1,2-diyl, Propane-1,1-diyl, propane-1,2-diyl, propane-l, 3-diyl, ethene-1,2-diyl, propene-1,2-diyl, propene-1,3-diyl, ethyne 1,2-diyl, propyne-1,2-diyl or propyne-1,3-diyl,

A ³ for hydrogen, hydroxy, amino, cyano, nitro, carboxy, carbamoyl, sulfo, fluorine, chlorine, bromine, for each methyl, ethyl, n- or i-propyl optionally substituted by fluorine, chlorine, methoxy or ethoxy , i-, s- or t-butyl, n-, i-, s- or t-pentyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, n- , i-, s- or t-

Pentyloxy, methylthio, ethylthio, n- or i-propylthio, n-, i-, s- or t-butylthio, methyl sulfinyl, ethylsulfinyl, n- or i-propylsulfinyl, methylsulfonyl, ethylsulfonyl, n- or i-propylsulfonyl, methylamino , Ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino, diethylamino, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, dimethoxyphosphoryl, diethoxyphosphoryl, dipropoxyphosphoryl or diisopropoxyphosphoryl, for each in each case

5 propenyl, butenyl, which is also substituted by fluorine or chlorine,

Propenyloxy, butenyloxy, propenylamino, butenylamino, propylidene-amino, butylidene amino, propenyloxycarbonyl, butenyloxycarbonyl, propynyl, butynyl, propynyloxy, butynyloxy, propynylamino, butynylamino, propynyloxycarbonyl or butynyloxycarbonyl, for each

10 cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclopentylmethyl, cyclopentylmethyl, optionally substituted by fluorine, chlorine, cyano, carboxy, methyl, ethyl, n- or i-propyl, methoxycarbonyl or ethoxycarbonyl

15 cyclopropylmethoxy, cyclobutylmethoxy, cyclopentylmethoxy,

Cyclohexylmethoxy, Cyclopentylidenamino, Cyclohexylidenamino, Cyclopentyloxycarbonyl, Cyclohexyloxycarbonyl, Cyclopentylmeth- oxycarbonyl or Cyclohexylmethoxycarbonyl, or for where appropriate by nitro, cyano, carboxy, fluorine, chlorine, bromine, methyl,

20 ethyl, n- or i-propyl, trifluoromethyl, methoxy, ethoxy, n- or i-

Propoxy, di fluoromethoxy, trifluoromethoxy, methoxycarbonyl and / or ethoxycarbonyl substituted phenyl, phenyloxy, benzyl, phenylethyl, benzyloxy, phenyloxycarbonyl, benzyloxycarbonyl, (in each case fully or partially hydrogenated) pyrrolyl,

25 pyrazolyl, imidazolyl, triazolyl, furyl, thienyl, oxazolyl, isoxazolyl,

Thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridinyl, pyrimidinyl, triazinyl, pyrazolylmethyl, furylmethyl, thienylmethyl, oxazolylmethyl, isoxazolmethyl, thiazolmethyl, pyridinylmethyl, pyrimidinylmethyl, pyrazoloxy or pyridylmethoxy, furyl

30 methoxy stands,

R ^{4 represents} hydrogen, fluorine, chlorine or methyl or ethyl which is optionally substituted by fluorine and / or chlorine, R ^{5 stands} for hydrogen, fluorine, chlorine or for methyl or ethyl optionally substituted by fluorine and / or chlorine, and

R ^{6 stands} for hydrogen, hydroxyl, amino or for methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, propenyl or propynyl which is optionally substituted by fluorine, chlorine or cyano, and

(a) Heteroaryloxyacetamides of the formula (ü) in which

R ⁷ for each optionally by fluorine, chlorine, cyano, methoxy or

Ethoxy substituted methyl, ethyl, n- or i-propyl, n-, i- or s-butyl, propenyl, butenyl, propynyl, butinyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy,

R ⁸ represents methyl, ethyl, n- or i-propyl, n-, i-, s- or t-, each of which is optionally substituted by fluorine, chlorine, cyano, methoxy or ethoxy

Butyl, n-, i-, s- or t-pentyl, propenyl, butenyl, propynyl or butynyl, or for phenyl optionally substituted by fluorine, chlorine, bromine, cyano, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, difluoromethoxy or trifluoromethoxy stands, and

R ⁹ for each optionally by fluorine, chlorine, bromine, cyano, methyl,

Ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, trifluoromethyl, dichloromethyl, trichloromethyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s - or t-butoxy, difluoromethoxy or trifluoromethoxy substituted heteroaryl from the series l, 3-thiazol-2-yl, l, 2,4-thiadiazol-5-yl, l, 3,4-thiadiazol-2-yl, Benzoxazol-2-yl, benzothiazol-2-yl;

(b) carbamoyltriazolinones of the formula (III) in which R ¹⁰ for hydrogen, hydroxy, amino, for methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, butenyl, propynyl or butynyl, each optionally substituted by fluorine, chlorine or cyano , Methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, propenyloxy, butenyloxy, propynyloxy or butynyloxy, methylamino,

Ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, propenylamino, butenylamino, propinylamino or butinylamino, ethylidenamino, propylidenamino, butylidenamino, dimethylamino or diethylamino, each optionally with fluorine, chlorine, bromine, Cyano, methyl, ethyl, n- or i-propyl substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl or cyclohexylmethyl, or for each optionally by fluorine, chlorine, bromine, cyano, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, methoxy or ethoxy substituted phenyl or benzyl,

R ¹¹ for each methyl, ethyl, n- or i-propyl, n-, i-, substituted by fluorine, chlorine, cyano, methoxy, ethoxy, n- or i-propoxy, methylthio, ethylthio, n- or i-propylthio , s- or t-butyl, propenyl, butenyl, propynyl, butynyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, propenyloxy, butenyloxy, propynyloxy, butynyloxy, Methylthio, ethylthio, n- or i-propylthio, n-, i-, s- or t-butylthio, propenylthio, butenylthio, propinylthio, butinylthio, methylamino, ethylamino, n- or i-propylamino, n-, i-, s - or t-butylamino, propenylamino, butenylamino, propynylamino, butynylamino, dimethylamino or diethylamino, for each cyclopropyl, cyclobutyl, cyclobutyl, which is optionally substituted by fluorine, chlorine, bromine, cyano, methyl, ethyl, n- or i-propyl , Cyclopentyl, Cyclo¬ hexyl, Cyclopropyloxy, Cyclobutyloxy, Cyclopentyloxy, Cyclohexyloxy, Cyclo-propylmethyl, Cyclobutylmethyl, Cyclopentylmethyl or Cyclohexylmethyl, or for jewe ils optionally by fluorine, chlorine,

Bromine, cyano, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, methoxy or ethoxy substituted phenyl, phenoxy, phenylthio, phenylamino or benzyl, and R ¹² for each optionally by fluorine, cyano, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, methylthio, ethylthio, n- or i-propylthio, n-, i- , s- or t-butylthio, methylsulfinyl, ethylsulfinyl, methylsulfonyl, ethylsulfonyl, methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino, diethylamino, dipropylamino or dibutylamino substituted Methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, butenyl, pentenyl, hexenyl, propynyl, butynyl, pentynyl or hexynyl, each optionally by fluorine, chlorine, Bromine, cyano, methyl, ethyl, n- or i-propyl substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, cyclohexylethyl or cyclohexylpropyl, or for each optionally by fluorine, chlorine, bromine, cyano, Methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, methoxy or ethoxy substituted benzyl, phenyleth yl, phenylpropyl, phenylbutyl, phenylethenyl, phenylpropenyl, phenylbutenyl, phenylethynyl, phenylpropynyl or phenylbutinyl,

(d) carboxylic acids such as e.g. 3,6-dichloropyridine-2-carboxylic acid (clopyralid), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxybenzoic acid (dicamba), 4-amino -3,5-dichloro-6-fluoropyridine-2-yl-oxy-acetic acid (fluroxypyr), 2-amino-4- (hydroxymethyl-phosphinyl) butanoic acid ammonium salt (glufosinate ammonium), N-

Phosphonomethyl-glycine (glyphosate), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1 H-imidazol-2-yl) -5-ethyl-pyridine-3-carboxylic acid ( Imaz-ethapyr) or 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) -quinoline-3-carboxylic acid (imazaquine);

(e) carboxamides such as N- (2-methoxy-l-methyl-ethyl) -N- (2-ethyl-

6-methyl-phenyl) -2-chloroacetamide (metolachlor), N-ethoxymethyl-N- (2-ethyl-6-methyl-phenyl) -2-chloroacetamide (acetochlor), N-methoxy- methyl-N- (2,6-dimethyl-phenyl) -2-chloroacetamide (alachlor), N- (2-methoxy-1-methyl-ethyl) -N- (2,4-dimethyl-3-thienyl) -2-chloroacetamide (dimethenamid), N- (1H-pyrazol-1-ylmethyl) -N- (2,6-dimethylphenyl) - 2-chloroacetamide (metazachlor) or Ni-propyl-N -phenyl-2-chloroacetamide (propachlor);

(f) diazin (on) e, or triazin (on) e, e.g. 2-chloro-4-ethylamino-6-i-propylamino-l, 3,5-triazine (atrazine), 3-i-propyl-lH-2, l, 3-benzothia-diazin-4 (3H) -one- 2,2-dioxide (bentazone), 2-chloro-4-ethylamino-6- (l-cyano-l-methyl-ethylamino) -l, 3,5-triazine (cyanazine), 4-amino-6-t- butyl-4,5-c hydro-3-methylthio-l, 2,4-triazin-5-one (metribuzin), O- (6-

Chloro-3-phenyl-4-pyridazinyl) -S-octyl-thiocarbonate (pyridate); 2-chloro-4,6-bis-ethylamino-1,3,5-triazine (simazine) or 2-chloro-4-ethylamino-6-t-butylamino-1,3,5-triazine (terbuthylazine);

(g) ureas, such as N- (4,6-dimethoxy-pyrimidin-2-yl) -N- (3-chloro-4-methoxycarbonyl-l-methyl-pyrazol-5-yl-sulfonyl) -haπιstoff (Clopyra - sulfüron), N-methoxy-N-methyl-N- [4- (3,4-dihydro-2-methoxy-2,4,4-trimethy 1-2H-1 -benzopyran7-yl-oxy) phenyl] urea (metobenz uron), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-dimethylamino-carbonyl-pyridin-2-yl-sulfonyl) urea (nicosulfuron), N- (4,6-bis-difluoromethoxy-pyrimidin-2-yl) -N ^, - (2-methoxycarbonyl-phenyl-sulfonyl) -harp substance (Primisulfuron-methyl), N- (4-methoxy-6-methyl-1, 3 , 5-triazin-2-yl) -N '- [2- (3, 3, 3-trifluoropropyl) phenylsulfonyl] urea (prosulfuron), N- (4,6-dimethoxy-pyrimidin-2 -yl) -N '- (3-ethyl-sulfonyl-pyridin-2-yl-sulfonyl) -urea (rimsulfuron) or N- (4-methoxy-6-methyl-l, 3,5-triazin-2-yl ) -N- (2-methoxycarbonyl-3-thienylsulfonyl) urea (thifensulfuron-methyl);

(i) thiocarbamates such as N-di-i-butyl-S-ethyl-thiocarbamate (butylates) or N-dipropyl-S-ethyl-thiocarbamate (EPTC); (j) Active substances from various groups of substances, such as, for example, N-2,6-difluorophenyl-5-methyl- [1, 2,4] -triazolo- [1, 5-a] -pyrimidine-2-sulfonamide (flumet- sulam), l, -dimethyl-4,4'-bipyridinium chloride (paraquat) or 2- (2-chloro-4-methylsulfonyl-benzoyl) - 1, 3 -cyclohexanedione (sulcotrione),

0.1 to 10 parts by weight of active compound of the general formula (II) are preferably used per 1 part by weight of active compound of the general formula (I).

Examples of the compounds of the formula (I) to be used as mixing partners according to the invention are: 1- (4-chloro-3-methylsulfonylamino-phenyl) -3,6-dihydro-2,6-dioxo-3- methyl-4-trifluoromethyl-1 (2H) -pyrimidine, 1 - (4-chloro-3-methylsulfonylamino-phenyl) -3,6-dihydro-2,6-dioxo-3-amino-4-trifluoromethyl -l (2H) -pyrimidine, l- (4-cyano-3-methylsulfonylamino-phenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-l (2H) -pyrimidine , l- (4-Chloro-3-ethylsulfonylamino-phenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1 (2H) -pyrimidine, 1 - (4-chloro -3-ethylsulfonylamino-phenyl) - 3,6-dihydro-2,6-dioxo-3-amino-4-trifluoromethyl-1 (2H) -pyrimidine, 1 - (4-cy ano-3-ethylsulfonylamino-phenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-l (2H) -pyrimidine, l- (4-chloro-3-n-propylsulfonylamino-phenyl) -3,6-dihydro- 2,6-dioxo-3-methyl-4-trifluoromethyl-1 (2H) -pyrimidine, 1 - (4-chloro-3-n-propylsulfonylaminophenyl) -3,6-dihydro-2,6-dioxo-3 -amino-4-trifluoπnethyl - 1 (2H) -pyrimidine, 1- (4-cyano-3-n-propylsulfonylaminophenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1 (2H) -pyrimidine, 1 - (4-chloro-3-i-propylsulfonylamino-phenyl) -3, 6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-l (2H) -pyrimidine, l- ( 4-chloro-3-i-propylsulfonylamino-phenyl) -3,6-dihydro-2,6-dioxo-3-amino-4-trifluoromethyl-l (2H) -pyrimidine, 1 - (4-cyano-3 -i-propylsulfonylamino-phenyl) -3, 6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1 (2H) -pyrimidine, 1 - (4-chloro-5-methylsulfonylamino-2 ~ fluorine) phenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-l (2H) -pyrimidine, 1- (4-chloro-5-methylsulfonylamino-2-fluorophenyl) -3, 6-dihydro-2,6-dioxo-3-amino-4-trifluoromethyl-l (2H) -pyrimidine, l- (4-cyano-5-methylsulfonylamino-2-fluorophenyl) -3,6-dihydro -2,6-dioxo-3-methyl-4-trifluoromethyl-l (2H) -pyrimidine, l- (4-chloro-5-ethylsulfonylamino-2-fluorophenyl) -3,6-dihydro-2,6- dioxo-3-methyl-4-trifluoromethyl-l (2H) -pyrimidine, l- (4-chloro-5-ethylsulfonylamino-2-fluorophenyl) -3,6-dihydro-2,6-diox o-3-amino-4-trifluoromethyl-l (2H) -pyrimidine, l- (4-cyano-5-ethylsulfonylamino-2-fluorophenyl) -3,6-dihydro-2,6-dioxo-3 -methyl-4-trifluoromethyl-l (2H) -pyri- midin, 1 - (4-chloro-5-n-propylsulfonylamino-2-fluorophenyl) -3, 6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-l (2H) -pyrimidine, l - (4-Chloro-5-n-propylsulfonylamino-2-fluoro-phenyl) -3,6-dihydro-2,6-dioxo-3-amino-4-trifluoromethyl-l (2H) -pyrimidine, 1- (4th -Cyano-5-n-propylsulfonylamino-2-fluorophenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1 (2H) -pyrimidine, 1 - (4-chloro 5-i-propylsulfonylamino-2-fluorophenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-l (2H) -pyrimidine, l- (4-chloro-5-i -propylsulfonylamino-2-fluorophenyl) -3,6-dihydro-2,6-dioxo-3-amino-4-trifluoromethyl-1 (2H) -pyrimidine, 1 - (4-cyano-5-i- propylsulfonylamino-2-fluorophenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-trifluoromethyl-1 (2H) -pyrimidine, 1 - (4-cyano-5-n-butylsulfonylamino-2 -fluorophenyl) -3,6-dihydro-2,6-dioxo-3-methyl-4-4-trifluoromethyl-1 (2H) -pyrimidine.

Examples of the compounds of the formula (II) to be used as mixture partners according to the invention are: N-methyl-N-phenyl-α- (5-trifluoromethyl-l, 3,4-thiadiazol-2-yl-oxy ) -acetamide, N-ethyl-N-phenyl-α- (5-trifluoromethyl-l, 3,4-thiadiazol-2-yl-oxy) -acetamide, Nn-propyl-N-phenyl-α- (5th -trifluoromethyl-1, 3, 4-thiadiazol-2-yl-oxy) -acetamide, Ni-propyl-N-phenyl-α- (5-trifluoromethyl-1, 3, 4-thiadiazol-2-yl-oxy) - acetamide, N-methyl-N- (4-fluoro-phenyl) -α- (5-trifluoromethyl-l, 3,4-thiadiazol-2-yl-oxy) -acetamide, N-ethyl-N- (4-fluoro -phenyl) -α- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide, Nn-propyl-N- (4-fluorophenyl) -α- (5-trifluoromethyl - 1, 3, 4-thiadiazol-2-yl-oxy) -acetamide, ni-propyl-N- (4-fluorophenyl) -α- (5-trifluo-memyl-l, 3,4-thiadiazole- 2-yl-oxy) -acetamide, N-methyl-N- (4-chlorophenyl) -α- (5-trifluoromethyl-1,3, 4-thiadiazol-2-yl-oxy) -acetamide, N -Ethyl-N- (4-chlorophenyl) -α- (5-trifluoromethyl-1, 3, 4-thiadiazol-2-yl-oxy) - acetamide, Nn- propyl-N- (4-chlorophenyl) -α- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide and Ni-propyl-N- (4-chlorophenyl) - α- (5-trifluoromethyl-l, 3,4-thia-diazol-2-yl-oxy) acetamide.

Examples of the compounds of the formula (III) to be used as mixture partners according to the invention are:

4-amino-5-methyl-2- (1, 1-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-1, 2,4-tri-azol-3-one, 4-amino-5- ethyl-2- (1J-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino-5-n-propyl-2- (1, 1 -dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-l, 2,4-triazol-3-one, 4-amino-5-i-propyl-2- (lJ-dimethyl-ethyl-aminocar- bonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino-5-methoxy-2- (1, 1-dimethylethyl-aminocarbonyl) -2,4-dihydro -3H- 1, 2,4-triazol-3-one, 4-amino-5-ethoxy-2- (1, 1 - dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-1, 2.4 -triazol-3-one, 4-amino-5-methyl-2- (2-fluoro-1J-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-l, 2,4-triazol-3 -one , 4-amino-5-ethyl-2- (2-fluoro-1, 1-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino -5-n-propyl-2- (2-fluoro-1, 1-dimethyl-ethylamino-carbonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino -5-i-propyl-2- (2-fluoro-1, 1-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino -5-meth-oxy-2- (2-fluoro-1, 1-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino-5 -ethoxy-2- (2-fluoro-1, 1-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino-5-methyl-2 - (2-chloro-1, 1-dimethyl-ethyl-amino-carbonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino-5-ethyl-2- ( 2-chlo r- 1, 1-dimethyl-aminocarbonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino-5-n-propyl-2- (2- chloro-1, 1-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino-5-i-propyl-2- (2-chloro lJ-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-l, 2,4-triazol-3-one, 4-amino-5-methoxy-2- (2-chloro-l, l-dimethyl- ethyl aminocarbonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino-5-ethoxy-2- (2-chloro-1, 1-dimethyl-ethyl- aminocarbonyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, 4-amino-5-i-propyl-2-i-propyl-aminocarbonyl-2,4-dihydro-3H-1 , 2,4-triazol-3-one, 4-amino-5-dimethylamino-2- (1, 1-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-1, 2,4-triazole -3-on, 4-

Amino-5-dimethylamino-2- (2-fluoro-1, 1-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-l, 2,4-triazol-3-one, 4-amino-5- dimethylamino-2- (2-chloro-1J-dimethyl-ethylaminocarbonyl) -2,4-dihydro-3H-l, 2,4-triazol-3-one and 4-methyl-5-methoxy-2- (l , l-dimethyl-ethyl-aminocarbonyl) -2,4-dihydro-3H-l, 2,4-triazol-3-one.

The compounds of formula (I) are described in the above-mentioned patent applications and patents.

The compounds of the formula (II) are known and / or can be prepared by known processes (cf. EP-A 5501, EP-A 18497, EP-A 29171, EP-A 94514, EP-A 100044, EP-A 100045 , EP-A 161602, EP-A 195237, EP-A 348734, EP-A 348737). The compounds of the formula (III) are likewise known and / or can be prepared by known processes (cf. EP-A 294666, EP-A 370293, EP-A 391187, EP-A 398096, EP-A 399294, EP -A 415196, EP-A 477646).

It has now surprisingly been found that the active substance combinations defined above from the aryluracils (or arylthiouracils) of the formula (I) and the active substances mentioned above under Group 2 have a particularly high herbicidal activity and in different crops, in particular in maize , but can also be used in soy, sunflowers, wheat, barley and sugar cane for selective weed control.

Surprisingly, the herbicidal activity of the active compound combinations according to the invention is considerably higher than the sum of the effects of the individual active compounds.

There is therefore an unforeseeable true synergistic effect and not just an addition to the effect. The new drug combinations are available in a number of cultures, e.g. in maize, soybeans and sugar cane, well tolerated, whereby the new active ingredient combinations also cover weeds that are otherwise difficult to control. The new active ingredient combinations thus represent a valuable addition to the selective herbicides, especially the herbicides that can be used in maize.

Examples of weeds which can be controlled well by the active compound combinations according to the invention are:

Dicotyledon weeds of the genera Sinapis, Lepidium, Galium, Stellaria, Matricaria, Anthemis, Galinsoga, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, Solanor, Cirsium, Cardu Rotala, Lindernia, Lamiu, Veronica, Abutilon, Emex, Sida, Datura, Viola, Galeopsis, Papaver, Centaurea, Trifolium, Ranunculus, Taraxum.

Monocotyledonous weeds of the genera Echinochloa, Setaria, Panicum, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Avena, Cyperus, Sorhum, Agropyron, Cynodon, Monochoria, Fimbristylis, Sagittaria, Eleocharis, Scirpus, Papalum, Ischaemum, Sphenoclea, Dactylocenium, Agrostis, Alopecurus, Apera.

However, the use of the active compound combinations according to the invention is in no way limited to these genera, but extends in the same way to other plants.

As already stated, the active compound combinations according to the invention have an excellent action against weeds and grasses, while being well tolerated by maize crops. Their use as selective herbicides in maize should therefore be particularly emphasized.

The synergistic effect of the active compound combinations according to the invention is particularly pronounced at certain concentration ratios. However, the weight ratios of the active ingredients in the active ingredient combinations can be varied within relatively large ranges. In general, 1 part by weight of group 1 active ingredient accounts for 0.001 to 1000 parts by weight, preferably 0.01 to 100 parts by weight, particularly preferably 0.1 to 10 parts by weight of group 2 active ingredient.

The active ingredients can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension emulsion concentrates, active ingredient-impregnated natural and synthetic substances and very fine encapsulations in polymers Fabrics.

These formulations are prepared in a known manner, e.g. B. by mixing the active ingredients with extenders, that is liquid solvents and / or solid carriers, if appropriate using surface-active agents, ie emulsifiers and / or dispersants and / or foam-generating agents.

If water is used as an extender, organic solvents can, for example, also be used as auxiliary solvents. The following are essentially suitable as liquid solvents: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylene or methylene chloride, aliphatic hydrocarbons, - 24 -

such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol as well as their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.

Possible solid carriers are e.g. Ammonium salts and natural rock powders such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders such as highly disperse silica, aluminum oxide and silicates are suitable as solid carriers for granules: e.g. broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours and granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stems; as emulsifying and / or foaming agents are possible: e.g. nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates; Possible dispersants are: e.g. Lignin sulfite liquor and methyl cellulose.

Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids can be used in the formulations. Other additives can be mineral and vegetable oils.

Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.

The formulations generally contain between 0J and 95 percent by weight of active compound, preferably between 0.5 and 90%.

The active compound combinations according to the invention are generally used in the form of finished formulations. The one in the drug combinations Active ingredients contained can also be mixed in individual formulations when used, ie applied in the form of tank mixtures.

The new active ingredient combinations, as such or in their formulations, can furthermore also be used in a mixture with other known maize herbicides for weed control, ready-to-use formulations or tank mixes being possible. A mixture with other known active compounds, such as fungicides, insecticides, acaricides, nematicides, bird repellants, growth agents, plant nutrients and agents which improve soil structure, is also possible. For certain applications, especially in the post-emergence process, it may also be advantageous to add mineral or vegetable oils (e.g. the commercially available "Oleo Dupont 11E") or ammonium salts, such as e.g. Include ammonium sulfate or ammonium rhodanide.

The active compound combinations according to the invention can be used as such, in the form of their formulations or in the use forms prepared therefrom by further dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules. They are used in the usual way, e.g. by watering, spraying, spraying or sprinkling.

The active compound combinations according to the invention can be applied both before and after emergence of the plants. They can also be worked into the soil before sowing.

The active compound combinations according to the invention can (a) in conventional cultivation of maize ("conventional tillage") both in advance! on-procedure as well in the post-emergence process or (b) in the gentle cultivation of maize ("preplant bumdown").

As suitable mixing partners for conventional cultivation, the following well-known active ingredients - "common names" or alternatively known code names - are given:

Acetochlor, alachlor, atrazine, bentazone, butylates, clopyralide, cyanazine, 2,4-D, dimethenamid, EPTC, flumetsulam, fluroxypyr, clopyrasulfüron, imazethapyr, imaza- quin, ioxynil, metazachlor, metobenzuron, metolachinon, metolachinlor, m Pendimethalin, Primisulfurron, Propachlor, Prosulfüron, Pyridate, Rimsulfuron, Simazin, Sulcotrione, Terbutylaän, Thifensulfuron, Trifluralin.

The following known active ingredients are particularly worth mentioning as suitable mixing partners for soil-protecting cultivation:

Bentazon, Bromoxynil, Dicamba, 2,4-D, Glyphosate, Metribuzin, Paraquat, Diquat, Glufosinate.

The application rates of the active compound combinations according to the invention can be varied within a substantial range. They essentially depend on the type of effect desired. In general, the application rates are between 10 g and 10 kg of active ingredient combination per hectare of soil, preferably between 50 g and 5 kg per ha, in particular between 100 g and 2 kg per ha.

While the individual active compounds have weaknesses in the herbicidal action, the combinations according to the invention consistently show very good and broadly effective control of the weeds, which occur predominantly in maize, which goes beyond a pure addition of action.

Herbicides always have a synergistic effect if the herbicidal activity of the active ingredient combination is greater than that of the individual active ingredients applied. The expected effect for a given combination of two herbicides can be calculated as follows (cf. Colby, S. R; "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, pages 20-22, 1967):

If X =% damage from herbicide A (active ingredient of group 1) at p kg ha application rate and

Y =% damage by herbicide B (active ingredient of group 2) at q kg / ha application rate and

E = the expected damage from herbicides A and B at p and q kg ha application rate,

then E = X + Y - (X * Y / 100).

If the actual damage is greater than calculated, the effect of the combination is super-additive, i.e. it shows a synergistic effect.

The application tests for the active compound combinations according to the invention show that the herbicidal activity of the active compound combinations according to the invention is greater than the calculated, i.e. that the new drug combinations work synergistically.

Claims

claims

1. Herbicidal agents, characterized by an effective content of an active ingredient combination consisting of

(1) an aryluracil or an arylthiouracil of the general formula (I)

or an isomeric compound of the general formula (Ia)

where in formulas (I) and (Ia), respectively

Q represents oxygen or sulfur,

Q2 represents oxygen or sulfur,

R ^{1 represents} hydrogen or halogen,

R represents halogen or cyano, R ^{3 represents} the grouping below,

-A ¹ -A ² -A ³

woπn

A ^{1 represents} a single bond, represents oxygen, sulfur, -SO-, -SO ₂ -, -CO- or the grouping -NA ⁴ -, wherein A ^{4 represents}

Is hydrogen, hydroxyl, alkyl, alkoxy, aryl, alkylsulfonyl or arylsulfonyl, or (A ¹ ) is in each case optionally substituted alkanediyl, alkenediyl, azaalkenediyl, alkynediyl, cycloalkanediyl, cycloalkenediyl or arendiyl,

A ² for a single bond, for oxygen, sulfur, -SO-, -SO ₂ -

, -CO- or the grouping -NA ⁴ -, wherein A ^{4 is} hydrogen, alkyl, aryl, alkylcarbonyl, alkylsulfonyl or arylsulfonyl, or (A ² ) is in each case optionally substituted alkanediyl, alkenediyl, azaalkenediyl, alkynediyl, cycloalkanediyl , Cycloalkendiyl or Arendiyl stands, and

A ³ for hydrogen, hydroxy, mercapto, amino, cyano, isocyano, thiocyanato, nitro, carboxy, carbamoyl, thiocarbamoyl, sulfo, chlorosulfonyl, halogen or for optionally substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, dialkylamino , Alkoxycarbonyl, di-alkoxy (thio) phosphoryl, alkenyl, alkenyloxy, alkenylamino, alkylidenamino, alkenyloxycarbonyl, alkynyl, alkynyloxy, alkynylamino, alkynyloxycarbonyl, cycloalkyl, cycloalkyloxy, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylidenamino, cycloalkyloxyyloxy aryl, cycloalkyloxyyloxyalkyl, , Arylalkoxy, aryloxycarbonyl, arylalkoxycarbonyl, heterocyclyl, heterocyclylalkyl, heterocyclylalkoxy or heterocyclylalkoxycarbonyl, R ^{4 represents} hydrogen, halogen or optionally substituted alkyl,

R ^{5 represents} hydrogen, halogen or optionally substituted alkyl, and

R ^{6 represents} hydrogen, hydroxy, amino or optionally substituted alkyl, alkoxy, alkenyl or alkynyl,

("Active substances of group 1") and

(2) a herbicidal active ingredient from a second group of herbicides (“active ingredients of group 2”) which contains the compound classes (a) to (j) mentioned below:

(a) heteroaryloxyacetamides of the general formula (II)

in which

R ⁷ represents optionally substituted alkyl, alkenyl, alkynyl or alkoxy,

R ^{9 represents} optionally substituted heteroaryl;

(b) carbamoyltriazolinones of the general formula (III) in which

10 represents hydrogen, hydroxyl, amino or optionally substituted alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylamino, alkenylamino, alkynylamino, alkylideneamino, dialkylamino, cycloalkyl, cycloalkylalkyl, aryl or arylalkyl,

11 for optionally substituted alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, alkenylthio, alkynylthio, alkylamino, alkenylamino, alkynylamino,

Dialkylamino, cycloalkyl, cycloalkyloxy, cycloalkylalkyl, aryl, aryloxy, arylthio, arylamino or arylalkyl, and

(d) carboxylic acids such as e.g. 3,6-dichloropyridine-2-carboxylic acid (clopyralid), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6-

Dichloro-2-methoxy-benzoic acid (dicamba), 4-amino-3,5-dichloro-6-fluoropyridin-2-yl-oxyacetic acid (fluroxypyr), 2-amino-4- (hydroxymethylphosphinyl) butanoic acid - Ammonium salt (glufosinate-ammonium), N-phosphonomethyl-glycine (glyphosate), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-lH-imidazol-2-yl) - 5-ethyl-pyridine-3-carboxylic acid (imazethapyr) odeß- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) -quinolin-3-carboxylic acid (imazaquine);

(e) carboxamides such as e.g. N- (2-methoxy-1-methyl-ethyl) -N- (2-ethyl-6-methyl-phenyl) -2-chloroacetamide (metolachlor), N-

5 ethoxymethyl-N- (2-ethyl-6-methylphenyl) -2-chloroacetamide

(Acetochlor), N-methoxymethyl-N- (2,6-dimethyl-phenyl) -2-chloroacetamide (alachlor), N- (2-methoxy-l-methyl-ethyl) -N- (2,4- dimethyl-3-thienyl) -2-chloroacetamide (dimethenamid), N- (1H-pyrazole-1 -yl-methyl) -N- (2,6-dimethyl-phenyl) -2-chloroacetate-

10 amide (metazachlor) or N-i-propyl-N-phenyl-2-chloroacetamide

(Propachlor);

(f) diazin (on) e, or triazin (on) e, e.g. 2-chloro-4-ethylamino-6-i-propylamino-l, 3,5-triazine (atrazine), 3-i-propyl-lH-2J, 3-benzothiadiazin-4 (3H) -one-2,2- dioxide (bentazone), 2-chloro-4-

15 ethylamino-6- (l-cyano-1-methyl-ethylamino) -1,3,5-triazine

(Cyanazine), 4-amino-6-t-butyl-4,5-dihydro-3-methylthio-1, 2,4-triazin-5-one (metribuzin), O- (6-chloro-3-phenyl- 4-pyridazinyl) - S-octyl thiocarbonate (pyridate); 2-chloro-4,6-bis-ethylamino-1,3,5-triazine (simazine) or 2-chloro-4-ethylamino-6-t-butyl-

20 amino-1,3,5-triazine (terbuthylazine);

(g) ureas, e.g. N- (4,6-dimethoxy-pyrimidin-2-yl) -N'- (3-chloro-4-methoxycarbonyl-1-methyl-pyrazol-5-yl-sulfonyl) - hara (clopyrasulfuron), N-methoxy- N-methyl-N '- [4- (3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1 -benzopyran7-yl-

25 oxy) phenyl] urea (metobenzuron), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-dimethylaminocarbonyl-pyridin-2-yl-sulfonyl) urea (nicosulfuron), N- (4,6-bis-difluoro-methoxy-pyrimidin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (Primisulfuron-methyl), N- (4-methoxy-6-

30 methyl-1, 3, 5-triazin-2-yl) -N '- [2- (3, 3, 3-trifluoropropyl) phenylsulfonyl] urea (prosulfuron), N- (4,6 -Dimethoxy-pyrimidin-2-yl) -N '- (3-ethylsulfonyl-pyridin-2-yl-sulfonyl) - urea (rimsulfuron) or N- (4-methoxy-6-methyl-l, 3,5-triazin-2-yl) -N '- (2-methoxycarbonyl-3-thienylsulfonyl) urea (thifensulfuron- methyl);

(j) active substances from various substance groups, e.g. N-2,6-difluorophenyl-5-methyl- [1, 2,4] -triazolo- [1,5-a] -pyrimidine-2-sulfonamide (flumetsulam), l, -dimethyl-4,4 ' -bipyridinium chloride (paraquat) or 2- (2-chloro-4-methylsulfonyl-benzoyl) -l, 3-cyclohexanedione (sulcotrione).

2. Herbicidal composition according to claim 1, characterized by a content of an active ingredient combination consisting of

(1) a compound of formula (I) or (Ia) wherein

Q ^{1 represents} oxygen or sulfur,

Q ^{2 represents} oxygen or sulfur,

R ^{1 represents} hydrogen, fluorine, chlorine or bromine,

R ^{2 represents} fluorine, chlorine, bromine, iodine or cyano,

R ^{3 represents} the grouping below,

-A'-A ² -A ³

woπn A ^{1 represents} a single bond, represents oxygen, sulfur, -SO-, -SO ₂ -, -CO- or the grouping -NA ⁴ -, wherein A ^{4 represents} hydrogen, hydroxy, C ₁ -C ₄ alkyl, C _r C ₄ alkoxy, phenyl, C ₁ -C ₄ alkylsulfonyl or phenylsulfonyl, or (A ¹ ) is 5 each C ₁ -C ₆ alkanediyl, C ₂ -C ₆ - optionally substituted by fluorine, chlorine or bromine Alkenediyl, C ₂ -C ₆ - azaalkenediyl, C ₂ -C ₆ . Alkindiyl, C ₃ -C ₆ -cycloalkanediyl, C ₃ -C ₆ -cycloalkenediyl or phenylene,

A ^{2 stands} for a single bond, for oxygen, sulfur, -SO-, -SO ₂ - 10, -CO- or the grouping -NA ⁴ -, wherein A ^{4 stands} for

Is hydrogen, hydroxy, C, -C ₄ alkyl, C _r C ₄ alkoxy, phenyl, C ₁ -C ₄ alkylsulfonyl or phenylsulfonyl group, or (A ²⁾ for each case optionally substituted by fluorine, chlorine or bromine substitu¬ iertes C , -C ₆ - alkanediyl, C ₂ -C ₆ -alkenediyl, C ₂ -C ₆ -azaalkenediyl, 15 ^ -C _ß . Alkindiyl, C ₃ -C ₆ -cycloalkanediyl, C ₃ -C ₆ -cycloalkenediyl or phenylene,

A ³ for hydrogen, hydroxy, amino, cyano, isocyano, thio cyanato, nitro, carboxy, carbamoyl, thiocarbamoyl, sulfo, chlorosulfonyl, halogen, each for if appropriate

20 halogen or C _j - ^ alkoxy substituted alkyl, alkoxy,

Alkylthio, alkylsulfmyl, alkylsulfonyl, alkylamino, dialkylamino, alkoxycarbonyl or dialkoxy (thio) phosphoryl each having 1 to 6 carbon atoms in the alkyl groups, for alkenyl optionally substituted by halogen,

25 alkenyloxy, alkenylamino, alkylidene amino, alkenyloxycarbonyl, alkynyl, alkynyloxy, alkynylamino or alkynyloxycarbonyl, each with 2 to 6 carbon atoms in the alkenyl, alkylidene or alkynyl groups, for where appropriate by halogen, cyano, carboxy, C ^ Alkyl

30 and / or C, -C ₄ -alkoxy-carbonyl substituted cycloalkyl,

Cycloalkyloxy, cycloalkylalkyl, cycloalkylalkoxy, cycloalkylideneamino, cycloalkyloxycarbonyl or cycloalkylalkoxycarbonyl each having 3 to 6 carbon atoms in the Cycloalkyl groups and optionally 1 to 4 carbon atoms in the alkyl groups, or for each optionally by nitro, cyano, carboxy, halogen C _j -C ₄ alkyl, C _j -C ₄ haloalkyl, C _j -C ^ alkyloxy, C _j -C ₄ -haloalkyloxy and / or C ₁ -C ₄ -alkoxy-carbonyl-substituted phenyl, phenyloxy, phenyl-C _] -C ₄ -alkyl, phenyl-C, -C ₄ -alkoxy, phenyloxycarbonyl or phenyl- C ₁ -C ₄ alkoxycarbonyl, (in each case fully or partially hydrogenated) pyrrolyl, pyrazolyl, imidazolyl, triazolyl, furyl, thienyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridinyl,

Pyrimidinyl, triazinyl, pyrazolyl-C _j - _j alkyl, furyl C _r C ₄ alkyl, thienyl C _r C ₄ alkyl, oxazolyl C, -C ₄ alkyl, isoxazole C _j - C ₄ alkyl , Thiazole-C _r C ₄ -alkyl, pyridinyl-C _r C ₄ -alkyl, pyrimidinyl-C ₁ -C ₄ -alkyl, pyrazolylmethoxy, furylmethoxy, represents perhydropyranylmethoxy or pyridylmethoxy,

R ^{4 represents} hydrogen, fluorine, chlorine, bromine or alkyl having 1 to 4 carbon atoms which is optionally substituted by fluorine and or chlorine,

R ^{5 represents} hydrogen, fluorine, chlorine, bromine or alkyl which is optionally substituted by fluorine and / or chlorine and has 1 to 4

Carbon atoms, and

R ^{6 stands} for hydrogen, hydroxy, amino or for alkyl, alkoxy, alkenyl or alkynyl, each optionally substituted by fluorine, chlorine or cyano, each having up to 4 carbon atoms, and

(2) an active ingredient from a second group of herbicides which contains the compound classes (a) to (j) mentioned below:

(a) Heteroaryloxyacetamides of the formula (II) in which R ⁷ represents alkyl, alkenyl, alkynyl or alkoxy, each optionally substituted by halogen, cyano or C 1 -C ₄ -alkoxy, each having up to 6 carbon atoms,

R ⁸ for alkyl, alkenyl or alkynyl, each optionally substituted by halogen, cyano or C _j -C ₄ alkoxy, each having up to 6 carbon atoms or for optionally halogen, cyano, C _r C ₄ alkyl, C _r C ₄ haloalkyl , C _r C ₄ alkoxy or C ₁ -C ₄ haloalkoxy substituted phenyl, and

R ⁹ for each optionally by halogen, cyano, C _j -C ₄ -

Alkyl, C, -C ₄ -haloalkyl, C _r C ₄ alkoxy or C _r C ₄ - haloalkoxy substituted heteroaryl from the series 1,3-thiazol-2-yl, l, 2,4-thiadiazol-5-yl, l, 3,4-thiadiazol-2-yl, benzoxazol-2-yl, benzthiazol-2-yl;

(b) carbamoyltriazolinones of the formula (IQ) in which

R ¹⁰ for hydrogen, hydroxy, amino, for each optionally substituted by halogen or cyano-substituted alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylamino, alkenylamino, alkynylamino, alkylideneamino or dialkylamino each having up to 6 carbon atoms, for each ge ¬ be substituted by halogen, cyano or C _j -C ₄ alkyl substitu¬ iertes cycloalkyl, cycloalkylalkyl having in each case 3 to 6 Kohlen¬ atoms in the cycloalkyl groups and optionally 1 to 4 carbon atoms in the alkyl group, or represents in each case optionally halogen-, cyano, C, -C ₄ alkyl or C _λ -

C ₄ alkoxy-substituted phenyl or phenyl-C, -C ₄ -alkyl,

R ¹¹ for each optionally by halogen, cyano, C, -C ₄ -

Alkoxy or C _j -C ₄ alkylthio substituted alkyl, alkenyl,

Alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, alkenylthio, alkynylthio, alkylamino, alkenylamino, alkynylamino or dialkylamino, each having up to 6 carbon atoms, for cycloalkyl, cycloalkyloxy or cycloalkylalkyl, each of which is optionally substituted by halogen, cyano or C 1-4 alkyl, each having 3 to 6 carbon atoms in the cycloalkyl groups and optionally 1 to 4 carbon atoms in the alkyl group , or represents in each case optionally halogen-, cyano, C _j -C ₄ alkyl or C, -C ₄ - alkoxy-substituted phenyl, phenoxy, phenylthio, phenylamino or phenyl-C ₁ -C ₄ - alkyl, and

R ¹² for each optionally by halogen, cyano, C _j -C ₄ -

Alkoxy, C _r C ₄ -alkylthio, C _j -C ^ alkylsulfmyl, C _r C ₄ -alkyl-sulfonyl, C _j -C ₄ -alkylamino or di- (C _r C ₄ -alkyl) -amino substituted alkyl, alkenyl, alkynyl, each having up to 10 carbon atoms, represents in each case optionally halogen-, cyano or C _j -C ₄ - alkylalkyl alkyl moiety substituted cycloalkyl or Cyclo¬ each having 3 to 6 carbon atoms in the cyclo and optionally 1 to 4 carbon atoms in the alkyl moiety, for phenyl-C _j- C ₈ -alkyl, phenyl-C ₂ -C ₆ -alkenyl or phenyl-C ₂ -C optionally substituted by halogen, cyano, C _j -C ₄ alkyl or C _j -C ₄ alkoxy ₆ .alkynyl;

(c) alkyl anilines, e.g. N- (l-ethyl-propyl) -3, 4-dimethyl-2,6-di-nitro-aniline (pendimethalin) or N, N-dipropyl-2,6-dinitro-4-trifluoromethyl-aniline (trifluralin);

(d) carboxylic acids, such as 3,6-dichloropyridine-2-carboxylic acid (clopyralide), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxy-benzoic acid (Dicamba), 4-amino-3,5-dichloro-6-fluoropyridin-2-yl-oxyacetic acid (fluroxypyr), 2-amino-4- (hydroxymethylphosphinyl) butanoic acid ammonium salt (glufosinate ammonium ), N-phosphonomethyl-glycine (glyphosate), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) -5-ethyl-pyridin-3 -carboxylic acid (imazethapyr) odefi- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1 H -imidazol-2-yl) -quinolin-3-carboxylic acid (imazaquine);

(e) carboxamides, e.g. N- (2-methoxy-1-methyl-ethyl) -N- (2-ethyl-6-methyl-phenyl) -2-chloroacetamide (metolachlor), N-ethoxymethyl-N- (2-ethyl-6- methyl-phenyl) -2-chloroacetamide

(Acetochlor), N-methoxymethyl-N- (2,6-dimethyl-phenyl) -2-chloroacetamide (alachlor), N- (2-methoxy-l-methyl-ethyl) -N- (2,4- dimethyl-3-thienyl) -2-chloroacetamide (dimethenamid), N- (lH-pyrazol-l-yl-methyl) -N- (2,6-dimethyl-phenyl) -2-chloroacetamide ( Metazachlor) or N-i-propyl-N-phenyl-2-chloroacetamide

(Propachlor);

(f) diazin (on) e, or triazin (on) e, e.g. 2-chloro-4-ethylamino-6-i-propylamino-l, 3,5-triazine (atrazine), 3-i-propyl-lH-2, l, 3-benzothiadiazin-4 (3H) -on-2, 2-dioxide (bentazone), 2-chloro-4-ethylamino-6- (1-cyano-1-methyl-ethylamino) -l, 3,5-triazine

(Cyanazine), 4-amino-6-t-butyl-4,5-dihydro-3-methylthio-l, 2,4-triazin-5-one (metribuzin), O- (6-chloro-3-phenyl- 4-pyridazinyl) - S-octyl thiocarbonate (pyridate); 2-chloro-4,6-bis-ethylamino-1,3,5-triazine (simazine) or 2-chloro-4-ethylamino-6-t-butylamino-l, 3,5-triazine (terbuthylaena);

(g) ureas, e.g. N- (4,6-Dimethoxy-pyrimidin-2-yl) -N '- (3-chloro-4-methoxycarbonyl-1-methyl-pyrazol-5-yl-sulfonyl) -haπι- substance (clopyrasulfuron), N- Methoxy-N-methyl-N- [4- (3,4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran7-yl-oxy) phenyl] urea (metobenzuron ), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-dimethylaminocarbonyl-pyridin-2-yl-sulfonyl) urea (nicosulfuron), N- (4,6-bis-difluoromethoxy - pyrimidin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (primisulfuron-methyl), N- (4-methoxy-6-methyl-l, 3,5-triazine-2 -yl) -N '- [2- (3,3,3-trifluoropropyl) phenylsulfonyl] urea

(Prosulfuron), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (3-ethyl-sulfonyl-pyridin-2-yl-sulfonyl) urea (rimsulfuron) or N- (4-methoxy-6-methyl-l, 3,5-triazin-2-yl) -N '- (2-methoxy-carb ony 1 -3 -thienyl-sulfony 1) -urea thifensulfuron-methyl 1);

(i) thiocarbamates such as e.g. N-di-i-butyl-S-ethyl-thiocarbamate

(Butylates) or N-dipropyl-S-ethyl-thiocarbamate (EPTC);

(j) active substances from various substance groups, e.g. N-2,6-difluorophenyl-5-methyl- [1, 2,4] triazolo- [1, 5-a] pyrimidine-2-sulfonamide

(Flumetsulam), 1, -dimethyl-4,4'-bipyridinium chloride (paraquat) or 2- (2-chloro-4-methylsulfonyl-benzoyl) -l, 3-cyclohexanedione (sulcotrione).

3. Herbicidal composition according to claim 1, characterized by a content of an active ingredient combination consisting of

(1) a compound of formula (I) or (Ia) wherein

Q ^{1 represents} oxygen or sulfur,

Q ^{2 represents} oxygen or sulfur,

R ^{1 represents} hydrogen, fluorine, chlorine or bromine,

R ^{2 represents} fluorine, chlorine, bromine, iodine or cyano,

R ^{3 represents} the grouping below,

-A ^! -A ² -A ³

in which A ¹ for a single bond, for oxygen, sulfur, -SO-, -SO ₂ -

, -CO- or the grouping -NA ⁴ -, where A ^{4 is}

Hydrogen, hydroxy, methyl, ethyl, n- or i-propyl,

Methoxy, ethoxy, n- or i-propoxy, methylsulfonyl or ethylsulfonyl, or (A is methylene, ethane-1,1-diyl,

Ethane-1,2-diyl, propane-1,1-diyl, propane-1,2-diyl, propane-1,3-diyl, ethene-1,2-diyl, propene-1,2-diyl, propene- 1,3-diyl, ethine-1,2-diyl, propyne-1,2-diyl or propyne-1,3-diyl,

A ^{2 represents} a single bond, represents oxygen, sulfur, -SO-, -SO ₂ -, -CO- or the grouping -NA ⁴ -, wherein A ^{4 represents}

Is hydrogen, hydroxy, methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, methylsulfonyl, ethyl sulfonyl, n- or i-propylsulfonyl or phenylsulfonyl, or (A ^{2) is} methylene, Ethane-1,1-diyl, ethane-1,2-diyl, propane-1,1-diyl, propane-1,2-diyl, propane-1,3-diyl, ethene-1,2-diyl,

Propene-1,2-diyl, propene-1,3-diyl, ethyne-1,2-diyl, propyne-1,2-diyl or propyne-1,3-diyl,

A ³ for hydrogen, hydroxy, amino, cyano, nitro, carboxy, carbamoyl, sulfo, fluorine, chlorine, bromine, for any substituted by fluorine, chlorine, methoxy or ethoxy

Methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, n-, i-, s- or t-pentyl, methoxy, ethoxy, n- or i-propoxy, n- , i-, s- or t-butoxy, n-, i-, s- or t-pentyloxy, methylthio, ethyl thio, n- or i-propylthio, n-, i-, s- or t-butylthio, Methylsulfinyl, ethylsulfinyl, n- or i-propylsulfinyl, methyl sulfonyl, ethylsulfonyl, n- or i-propylsulfonyl, methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butyl ¬ amino, dimethylamino, diethylamino, methoxycarbonyl, ethoxycarbonyl, n- or i-propoxycarbonyl, dimethoxyphosphoryl, diethoxyphosphoryl, dipropoxyphosphoryl or

Diisopropoxyphosphoryl, for propenyl, butenyl, propenyloxy, butenyloxy, propenylamino, butenylamino, propylidene, which are each optionally substituted by fluorine or chlorine. amino, butylideneamino, propenyloxycarbonyl, butenyloxycarbonyl, propynyl, butynyl, propynyloxy, butynyloxy, propynylamino, butynylamino, propynyloxycarbonyl or butynyloxycarbonyl, each optionally with fluorine, chlorine, cyano, carboxy, methyl, ethyl, n- or i-propyl,

Methoxycarbonyl or ethoxycarbonyl substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, cyclo-propylmethoxy, cyclobutylmethoxy, cyclo butyl methoxy, cyclo butyl Cyclopentyloxycarbonyl, cyclohexyloxycarbonyl, cyclopentylmethoxycarbonyl or cyclohexylmethoxycarbonyl, or for each optionally by nitro, cyano, carboxy, fluorine, chlorine, bromine, methyl, ethyl, n- or i-

Propyl, trifluoromethyl, methoxy, ethoxy, n- or i-propoxy, difluoromethoxy, trifluoromethoxy, methoxycarbonyl and / or ethoxycarbonyl substituted phenyl, phenyloxy, benzyl, phenylethyl, benzyloxy, phenyloxycarbonyl, benzyloxycarbonyl, (each optionally fully or partially hydrogenated) pyrrolyl , Pyrazolyl, imidazolyl, triazolyl, furyl, thienyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, pyridinyl, pyrimidinyl, triazinyl, pyrazolylmethyl, furylmethyl, thienylmethyl, isoxazidylmethylmethyl, oxazolylethylmethyl, oxazolylmethylmethyl, oxazolylmethylmethyl, oxazolylethylmethyl , Furylmethoxy or pyridylmethoxy,

R ^{4 represents} hydrogen, fluorine, chlorine or methyl or ethyl which is optionally substituted by fluorine and / or chlorine,

R ^{5 stands} for hydrogen, fluorine, chlorine or for methyl or ethyl optionally substituted by fluorine and / or chlorine, and R ^{6 stands} for hydrogen, hydroxyl, amino or for methyl, ethyl, n- or i-propyl, methoxy, ethoxy, n- or i-propoxy, propenyl or propinyl, which is optionally substituted by fluorine, chlorine or cyano, and

(2) an active ingredient from a second group of herbicides, which contains the compound classes (a) to Q) mentioned below:

(a) Heteroaryloxyacetamides of the formula (II) in which

R ⁷ for each optionally by fluorine, chlorine, cyano,

Methoxy or ethoxy substituted methyl, ethyl, n- or i-propyl, n-, i- or s-butyl, propenyl, butenyl, propynyl,

Butinyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy,

R ⁸ for each optionally by fluorine, chlorine, cyano,

Methoxy or ethoxy substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, n-, i-, s- or t-pentyl, propenyl,

Butenyl, propynyl or butynyl, or phenyl optionally substituted by fluorine, chlorine, bromine, cyano, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, difluoromethoxy or trifluoromethoxy, and

R ⁹ for each optionally by fluorine, chlorine, bromine, cyano,

Methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, difluoromethyl, trifluoromethyl, dichloromethyl, trichloromethyl, methoxy, ethoxy, n- or i-propoxy, n-, i - H, s- or t-butoxy, difluoromethoxy or trifluoromethoxy substituted heteroaryl from the series l, 3-thiazol-2-yl, l, 2,4-thiadiazol-5-yl, 1,3,4-

Thiadiazol-2-yl, benzoxazol-2-yl, benzthiazol-2-yl;

(b) carbamoyltriazolinones of the formula (III) in which R ^{10 represents} hydrogen, hydroxyl, amino, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, butenyl, each substituted by fluorine, chlorine or cyano,

Propynyl or butynyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, propenyloxy, butenyloxy, propynyloxy or butynyloxy, methylamino, ethylamino, n- or i-propyl¬ amino, n -, i-, s- or t-butylamino, propenylamino, butenylamino, propynylamino or butynylamino, ethylidene amino, propylidenamino, butylidene amino, dimethylamino or diethylamino, each optionally by fluorine, chlorine,

Bromine, cyano, methyl, ethyl, n- or i-propyl substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl or cyclohexylmethyl, or for each optionally by fluorine, chlorine, bromine, cyano, methyl, ethyl, n- or i-propyl, n-

, i-, s- or t-butyl, methoxy or ethoxy substituted phenyl or benzyl,

R ¹¹ for each methyl, ethyl, n- or i-propyl, n-, i-, substituted by fluorine, chlorine, cyano, methoxy, ethoxy, n- or i-propoxy, methylthio, ethylthio, n- or i-propylthio , s- or t-butyl, propenyl, butenyl, propynyl, butynyl, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, propenyloxy, butenyloxy, propynyloxy, butynyloxy, methyl¬ thio, ethylthio, n- or i-propylthio, n-, i-, s- or t-butylthio, propenylthio, butenylthio, propinylthio, butinylthio, methyl amino, ethylamino, n- or i-propylamino, n-, i- , s- or t-butylamino, propenylamino, butenylamino, propynylamino, butynylamino, dimethylamino or diethylamino, for cyclopropyl, cyclobutyl, each substituted by fluorine, chlorine, bromine, cyano, methyl, ethyl, n- or i-propyl,

Cyclobutyl, cyclopentyl, cyclohexyl, cyclopropyloxy, cyclobutyloxy, cyclopentyloxy, cyclohexyloxy, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl or cyclohexylmethyl, or for each optionally by fluorine, Chlorine, bromine, cyano, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, methoxy or ethoxy substituted phenyl, phenoxy, phenylthio, phenylamino or benzyl, and

R 12 for each optionally by fluorine, cyano, methoxy, ethoxy, n- or i-propoxy, n-, i-, s- or t-butoxy, methylthio,

Ethylthio, n- or i-propylthio, n-, i-, s- or t-butylthio, methylsulfinyl, ethylsulfinyl, methylsulfonyl, ethylsulfonyl, methylamino, ethylamino, n- or i-propylamino, n-, i-, s- or t-butylamino, dimethylamino, diethylamino, dipropylamino or dibutylamino substituted methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, propenyl, butenyl, pentenyl, hexenyl, propynyl, butynyl, Pentinyl or hexinyl, for each cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, cyclohexylethyl or cyclohexylpropyl optionally substituted by fluorine, chlorine, bromine, cyano, methyl, ethyl, n- or i-propyl , or for benzyl, phenylethyl, phenylpropyl optionally substituted by fluorine, chlorine, bromine, cyano, methyl, ethyl, n- or i-propyl, n-, i-, s- or t-butyl, methoxy or ethoxy, Phenylbutyl, phenylethenyl, phenylpropenyl, phenylpropenyl, phenylbutenyl, phenylethinyl, phenylpropinyl or he is phenyl butynyl,

(c) alkyl anilines, e.g. N- (l-ethyl-propyl) -3,4-dimethyl-2,6-di-nitro-aniline (pendimethalin) or N, N-dipropyl-2,6-dinitro-4-trifluoromethyl-aniline (trifluralin);

(d) carboxylic acids, such as 3,6-dichloropyridine-2-carboxylic acid (clopyralide), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxy-benzoic acid (Dicamba), 4-amino-3,5-dichloro-6-fluoropyridin-2-yl-oxyacetic acid (fluroxypyr), 2-amino-4- (hydroxymethylphosphinyl) butanoic acid ammonium salt (glucosinate ammonium ), N-phosphonomethyl-glycine (glyphosate), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-lH-imide- azol-2-yl) -5-ethyl-pyridine-3-carboxylic acid (imazethapyr) or 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl ) - quinoline-3-carboxylic acid (imazaquin);

(e) carboxamides such as e.g. N- (2-methoxy-l-methyl-ethyl) -N- (2-ethyl-6-methyl-phenyl) -2-chloroacetamide (metolachlor), N-

Ethoxymethyl-N- (2-ethyl-6-methyl-phenyl) -2-chloroacetamide (acetochlor), N-methoxymethyl-N- (2,6-dimethyl-phenyl) -2-chloroacetamide (alachlor), N- (2-methoxy-l-methyl-ethyl) -N- (2,4-dimethyl-3-thienyl) -2-chloroacetamide (dimethenamid), N- (1 H-pyrazole-1 -yl- methyl) -N- (2,6-dimethyl-phenyl 2-chloroacetamide (MetazacMor) or N-i-propyl-N-phenyl-2-cMoracetamide (propachlor);

(f) diazin (on) e, or triazin (on) e, e.g. 2-chloro-4-ethylamino-6-i-propylamino-l, 3,5-triazine (atrazine), 3-i-propyl-lH-2J, 3-benzothiadiazin-4 (3H) -on-2,2- dioxide (bentazone), 2-chloro-4-ethylamino-6- (1-cyano-1-methyl-ethylamino) - 1, 3, 5-triazine (cy anazine), 4-amino-6-t-butyl-4 , 5 -dihy dro-3 -methylthi o- 1, 2,4-triazin-5-one (metribuzin), O- (6-chloro-3-phenyl-4-pyridazinyl) - S-octyl-thiocarbonate (pyridate) ; 2-chloro-4,6-bis-ethylamino-1,3,5-triazine (simazine) or 2-chloro-4-ethylamino-6-t-butylamino-l, 3,5-triazine (terbuthylazine);

(g) ureas, such as N- (4,6-dimethoxy-pyrimidin-2-yl) - - (3-chloro-4-methoxycarbonyl-1-methyl-pyrazol-5-yl-sulfonyl) urea ( Clopyrasulfuron), N-methoxy-N-methyl-N '- [4- (3,4-di-hydro-2-methoxy-2,4,4-trimethyl-2H-l-benzopyran7-yl-oxy) phenyl ] urea (metobenzuron), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-dimethylaminocarbonyl-pyridin-2-yl-sulfonyl) urea (nicosulfuron), N- (4, 6-bis-difluoromethoxy-pyrimidin-2-yl) -N- (2-methoxycarbonyl-phenylsulfonyl) urea (primisulfuron-methyl), N- (4-methoxy-6-methyl-1, 3,5-tri azin-2-yl) -N '- [2- (3,3,3-trifluoropropyl) phenylsulfonyl] urea (prosulfuron), N- (4,6-dimethoxy-pyrimidin-2-yl) - N '- (3-ethyl sulfonyl-pyridin-2-yl-sulfonyl) urea (rimsulfuron) or N- (4-methoxy-6-methyl-l, 3,5-triazin-2-yl) -N '- (2-methoxy-caιbonyl-3 -thienyl-sulfonyl) -urea (thifensulfüron-methyl);

4. Herbicidal composition according to claim 1, characterized in that in the active ingredient combination the weight ratio of (1) aryluracil or arylthiouracil of the general formula (I) or one isomeric thereto

Compound of general formula (Ia) to a herbicidal active ingredient from a second group of herbicides of the compound classes (a) to (j) mentioned in claim 1 is between 1: 0.001 and 1: 1000.

5. A method of combating weeds, characterized in that an active ingredient combination according to claims 1 to 4 is allowed to act on weeds and / or their habitat.

6. A method for controlling weeds according to claim 5, characterized in that the combinations of effects according to claims 1 to 4 are applied to weeds in maize crops.

7. Use of active ingredient combinations according to claims 1 to 4 for

Weed control. Process for the preparation of herbicidal compositions, characterized in that the active compound combination according to Claims 1 to 4 is mixed with extenders and / or surface-active agents.

A process for the preparation of herbicidal compositions according to claim 8, characterized in that the formulations contain between 0J and 95% by weight of active ingredient.