EP0755429A4 - Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system - Google Patents

Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system

Info

Publication number
EP0755429A4
EP0755429A4 EP95915004A EP95915004A EP0755429A4 EP 0755429 A4 EP0755429 A4 EP 0755429A4 EP 95915004 A EP95915004 A EP 95915004A EP 95915004 A EP95915004 A EP 95915004A EP 0755429 A4 EP0755429 A4 EP 0755429A4
Authority
EP
European Patent Office
Prior art keywords
heavy metal
peroxyacid bleach
delayed release
release
bleach system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP95915004A
Other languages
German (de)
French (fr)
Other versions
EP0755429B1 (en
EP0755429A1 (en
Inventor
Gerard Marcel Baillely
Janice Jeffrey
John Scott Park
Barry Stoddart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of EP0755429A1 publication Critical patent/EP0755429A1/en
Publication of EP0755429A4 publication Critical patent/EP0755429A4/en
Application granted granted Critical
Publication of EP0755429B1 publication Critical patent/EP0755429B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/046Insoluble free body dispenser
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039Coated compositions or coated components in the compositions, (micro)capsules
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/08Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/32Amides; Substituted amides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/36Organic compounds containing phosphorus
    • C11D3/364Organic compounds containing phosphorus containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3902Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905Bleach activators or bleach catalysts
    • C11D3/3907Organic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3902Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905Bleach activators or bleach catalysts
    • C11D3/3932Inorganic compounds or complexes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3942Inorganic per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3945Organic per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/12Soft surfaces, e.g. textile

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

There is a provided a detergent composition containing: (a) a heavy metal ion sequestrant; and (b) an organic peroxyacid bleaching system wherein a means is provided for delaying the release to a wash solution of said peroxyacid bleach relative to the release of said heavy metal ion sequestrant. Preferably said composition additionally contains (c) a water soluble builder wherein a means is provided for delaying the release to a wash solution of said peroxyacid bleach relative to the release of said water soluble builder. A pretreat wash method is also provided.
EP95915004A 1994-04-13 1995-04-03 Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system Expired - Lifetime EP0755429B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9407535A GB9407535D0 (en) 1994-04-13 1994-04-13 Detergent compositions
GB9407535 1994-04-13
PCT/US1995/004085 WO1995028464A1 (en) 1994-04-13 1995-04-03 Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system

Publications (3)

Publication Number Publication Date
EP0755429A1 EP0755429A1 (en) 1997-01-29
EP0755429A4 true EP0755429A4 (en) 1998-07-29
EP0755429B1 EP0755429B1 (en) 2004-02-11

Family

ID=10753619

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95915004A Expired - Lifetime EP0755429B1 (en) 1994-04-13 1995-04-03 Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system

Country Status (13)

Country Link
EP (1) EP0755429B1 (en)
JP (1) JP4393582B2 (en)
CN (2) CN1094514C (en)
AT (1) ATE259412T1 (en)
AU (1) AU2204895A (en)
BR (1) BR9507379A (en)
CA (1) CA2187438C (en)
DE (1) DE69532559T2 (en)
ES (1) ES2216011T3 (en)
GB (1) GB9407535D0 (en)
MA (1) MA23505A1 (en)
PE (1) PE50595A1 (en)
WO (1) WO1995028464A1 (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19609953A1 (en) * 1996-03-14 1997-09-18 Basf Ag Solid composition of heterocyclic compounds and / or oxime esters and inert porous support materials and their use as a stable bleach activator component in detergents, bleaches and cleaners
GB2311541A (en) * 1996-03-29 1997-10-01 Procter & Gamble Oxygen-releasing bleach composition
GB2311535A (en) * 1996-03-29 1997-10-01 Procter & Gamble Detergent compositions
GB2311536A (en) * 1996-03-29 1997-10-01 Procter & Gamble Dishwashing and laundry detergents
GB2311542A (en) * 1996-03-29 1997-10-01 Procter & Gamble Percarbonate bleach composition
GB2311538A (en) * 1996-03-29 1997-10-01 Procter & Gamble Detergent compositions
DE19704634A1 (en) 1997-02-07 1998-08-27 Henkel Kgaa pH-controlled release of detergent components
GB2329188A (en) * 1997-09-11 1999-03-17 Procter & Gamble Detergent composition containing a stabilised percarboxylic bleaching system
JPH11217590A (en) * 1998-02-04 1999-08-10 Kao Corp Breaching and detergent composition
GB0004988D0 (en) 2000-03-01 2000-04-19 Unilever Plc Composition and method for bleaching a substrate
JP5206166B2 (en) * 2008-07-03 2013-06-12 コニカミノルタIj株式会社 Ink jet ink and method for forming liquid crystal alignment film
GB0902959D0 (en) * 2009-02-23 2009-04-08 Reckitt Benckiser Nv Composition
EP3050952A1 (en) * 2015-02-02 2016-08-03 The Procter and Gamble Company Method of dishwashing
EP3050951A1 (en) * 2015-02-02 2016-08-03 The Procter and Gamble Company Method of dishwashing
ES2714130T3 (en) 2015-02-02 2019-05-27 Procter & Gamble Detergent composition
US10280386B2 (en) 2015-04-03 2019-05-07 Ecolab Usa Inc. Enhanced peroxygen stability in multi-dispense TAED-containing peroxygen solid
US9783766B2 (en) 2015-04-03 2017-10-10 Ecolab Usa Inc. Enhanced peroxygen stability using anionic surfactant in TAED-containing peroxygen solid
EP3184601A1 (en) * 2015-12-23 2017-06-28 Agrana Beteiligungs- Aktiengesellschaft Process fluid comprising environmentally compatible bio-stabilizers
JP6943961B2 (en) * 2016-09-07 2021-10-06 エコラボ ユーエスエー インコーポレイティド Detergent composition containing an enzyme stabilized by phosphonate
WO2019027629A1 (en) 2017-07-31 2019-02-07 Dow Global Technologies Llc Detergent additive
US11162056B2 (en) * 2017-07-31 2021-11-02 Dow Global Technologies Llc Encapsulation method
WO2019027631A1 (en) * 2017-07-31 2019-02-07 Dow Global Technologies Llc Detergent additive
EP3810743B1 (en) 2018-06-15 2024-03-13 Ecolab USA Inc. Enhanced peroxygen stability using fatty acid in bleach activating agent containing peroxygen solid
EP3693450A1 (en) * 2019-02-08 2020-08-12 The Procter & Gamble Company Method of treating fabrics with automated pre-treatment of water

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4378300A (en) * 1981-12-10 1983-03-29 Colgate-Palmolive Company Peroxygen bleaching composition
FR2528447A1 (en) * 1982-06-10 1983-12-16 Kao Corp DETERGENT AND LAUNCHING COMPOSITION AND METHOD FOR PREPARING THE SAME
JPS59194000A (en) * 1983-04-18 1984-11-02 花王株式会社 Bleaching detergent composition

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES8400768A1 (en) * 1980-11-06 1983-11-01 Procter & Gamble Bleach activator compositions, preparation thereof and use in granular detergent compositions.
US4421664A (en) * 1982-06-18 1983-12-20 Economics Laboratory, Inc. Compatible enzyme and oxidant bleaches containing cleaning composition
US5130044A (en) * 1987-10-30 1992-07-14 The Clorox Company Delayed onset active oxygen bleach composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4378300A (en) * 1981-12-10 1983-03-29 Colgate-Palmolive Company Peroxygen bleaching composition
FR2528447A1 (en) * 1982-06-10 1983-12-16 Kao Corp DETERGENT AND LAUNCHING COMPOSITION AND METHOD FOR PREPARING THE SAME
JPS59194000A (en) * 1983-04-18 1984-11-02 花王株式会社 Bleaching detergent composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 8450, Derwent World Patents Index; Class D25, AN 84-309801, XP002064829 *

Also Published As

Publication number Publication date
CN1094514C (en) 2002-11-20
ATE259412T1 (en) 2004-02-15
DE69532559T2 (en) 2004-12-16
BR9507379A (en) 1997-09-16
CA2187438C (en) 2000-10-31
CN1206334C (en) 2005-06-15
CA2187438A1 (en) 1995-10-26
EP0755429B1 (en) 2004-02-11
JPH09512049A (en) 1997-12-02
WO1995028464A1 (en) 1995-10-26
AU2204895A (en) 1995-11-10
DE69532559D1 (en) 2004-03-18
GB9407535D0 (en) 1994-06-08
CN1373180A (en) 2002-10-09
ES2216011T3 (en) 2004-10-16
MA23505A1 (en) 1995-12-31
EP0755429A1 (en) 1997-01-29
JP4393582B2 (en) 2010-01-06
CN1150451A (en) 1997-05-21
PE50595A1 (en) 1996-02-13

Similar Documents

Publication Publication Date Title
EP0755429A4 (en) Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system
MY108663A (en) Liquid detergent compositions containing a suspended peroxygen bleach
EP0396287A3 (en) Method and product for enhanced bleaching with in situ peracid formation
EP0342177A3 (en) Heavy duty liquid laundry detergents containing anionic and nonionic surfactant, builder and proteolytic enzyme
GB2209342B (en) Hot water wash cycle built nonaqueous liquid nonionic laundry detergent composition containing amphoteric surfactant
CA2213633A1 (en) Laundry pretreatment with peroxide bleaches containing chelators for iron, copper or manganese for reduced fabric damage
ATE170555T1 (en) CONCENTRATED PHOSPHATE FREE LIQUID ENZYME CONTAINING MACHINE DISHWASHING DETERGENT
DE59802351D1 (en) BLEACH SYSTEM
EP0755434A4 (en) Detergents containing a builder and a delayed release enzyme
AU597711B2 (en) Nonaqueous liquid nonionic laundry detergent composition & method of use
HUP9902766A2 (en) Detergent composition
MY105995A (en) Detergent additive granulate and detergent.
CA2243965A1 (en) Laundry additive compositions including dispersible polyolefin and method for using same
MY102166A (en) Liquid non aqueous or substantive non aqucous laundry detergent composition
CA2187436A1 (en) Detergents Containing a Surfactant and a Delayed Release Peroxyacid Bleach Source
MX9604788A (en) Detergents containing a heavy metal sequestrant and a delayed release peroxyacid bleach system.
CA2187306A1 (en) Detergents Containing a Surfactant and a Delayed Release Enzyme
MX9604780A (en) Detergents containing a builder and a delayed release peroxyacid bleach source.
MX9604782A (en) Detergent compositions.
MX9604829A (en) Detergents containing a surfactant and a delayed release peroxyacid bleach source.
MX9604781A (en) Detergents containing an enzyme and a delayed release peroxyacid bleaching system.
EP0861315A4 (en) Detergents delivering a stronger organic peroxyacid bleach to a wash first followed by delivering a weaker peroxyacid
MX9604814A (en) Detergents containing a builder and a delayed release enzyme.
MX9604824A (en) Detergents containing a surfactant and a delayed release enzyme.
ES2002545A6 (en) Laundry detergent composition

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19961010

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU NL PT SE

A4 Supplementary search report drawn up and despatched

Effective date: 19980615

AK Designated contracting states

Kind code of ref document: A4

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU NL PT SE

17Q First examination report despatched

Effective date: 20020118

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU NL PT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040211

Ref country code: CH

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040211

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040211

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040211

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 69532559

Country of ref document: DE

Date of ref document: 20040318

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20040403

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20040405

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040511

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040511

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040511

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2216011

Country of ref document: ES

Kind code of ref document: T3

ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

26N No opposition filed

Effective date: 20041112

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20060430

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20070315

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20070420

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20040711

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20070404

Year of fee payment: 13

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20081101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20081101

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20081231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080430

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20080404

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080404

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20090430

Year of fee payment: 15

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070403

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101103

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20140325

Year of fee payment: 20

REG Reference to a national code

Ref country code: GB

Ref legal event code: PE20

Expiry date: 20150402

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20150402