EP0737995A2 - Combinaison de matériaux pour dispositifs intégrés de getter et d'apport de mercure et dispositif émisé obtenus - Google Patents

Combinaison de matériaux pour dispositifs intégrés de getter et d'apport de mercure et dispositif émisé obtenus Download PDF

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Publication number
EP0737995A2
EP0737995A2 EP96830202A EP96830202A EP0737995A2 EP 0737995 A2 EP0737995 A2 EP 0737995A2 EP 96830202 A EP96830202 A EP 96830202A EP 96830202 A EP96830202 A EP 96830202A EP 0737995 A2 EP0737995 A2 EP 0737995A2
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EP
European Patent Office
Prior art keywords
mercury
dispensing
materials
dispensing device
combination
Prior art date
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Granted
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EP96830202A
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German (de)
English (en)
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EP0737995B1 (fr
EP0737995A3 (fr
Inventor
Antonio Schiabel
Stefano Giorgi
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SAES Getters SpA
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SAES Getters SpA
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Publication of EP0737995A3 publication Critical patent/EP0737995A3/fr
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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00—Gas-discharge or vapour-discharge lamps
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00—Gas-discharge or vapour-discharge lamps
    • H01J61/02—Details
    • H01J61/24—Means for obtaining or maintaining the desired pressure within the vessel
    • H01J61/26—Means for absorbing or adsorbing gas, e.g. by gettering; Means for preventing blackening of the envelope
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J7/00—Details not provided for in the preceding groups and common to two or more basic types of discharge tubes or lamps
    • H01J7/14—Means for obtaining or maintaining the desired pressure within the vessel
    • H01J7/18—Means for absorbing or adsorbing gas, e.g. by gettering
    • H01J7/183—Composition or manufacture of getters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J7/00—Details not provided for in the preceding groups and common to two or more basic types of discharge tubes or lamps
    • H01J7/14—Means for obtaining or maintaining the desired pressure within the vessel
    • H01J7/20—Means for producing, introducing, or replenishing gas or vapour during operation of the tube or lamp

Definitions

  • the present invention relates to a combination of materials for the production of devices combining the getter and mercury-dispensing functions, to the devices thus produced and to a process for the introduction of mercury inside electron tubes.
  • a precise dosage of mercury inside these devices is extremely important for the quality of the devices and most of all for ecological reasons.
  • the high toxicity of this element implies serious problems of environmental pollution upon end-life disposal of the devices containing it, or in case of accidental break-up of the devices.
  • These problems of ecological nature impose the use of amounts of mercury as small as possible, compatibly with the functionality of the tubes.
  • These considerations have been lately included also in the legislative sphere, and the trend of the recent international regulations is to establish top limits for the amount of mercury which can be introduced into the devices: for example, for standard fluorescent lamps the use of a total amount of Hg not greater than 10 mg per lamp has been suggested.
  • US patent no.4.808.136 and the European patent application EP-568.317 disclose the use of tablets or small spheres of porous material soaked with mercury which is then released by heating once the lamp is closed. However, also these methods require complicated operations for the loading of mercury into the tablets, and the released amount of mercury is difficult to be reproduced.
  • amalgams of mercury for example with indium, bismuth or zinc
  • these amalgams generally have the drawback of a low melting temperature and a high mercury vapor pressure already at temperatures not very high.
  • the zinc amalgams described in the commercial bulletins of the APL Engineered Materials Inc. have a vapor pressure at 43°C which is about 90% of that of liquid mercury. Consequently, these amalgams badly withstand the thermal treatments for the production of the lamps in which they are introduced.
  • These compounds have a temperature of mercury-release start variable according to the specific compound, however they are all stable up to about 500°C both in the atmosphere and in evacuated volumes, thus resulting compatible with the operations for the assembly of the electron tubes, during which the mercury-dispensing devices may reach temperatures of about 500°C.
  • the mercury is released from the above-cited compounds by an activation operation, which is usually carried out by heating the material between 750°C and 900°C for about 30 seconds. This heating may be accomplished by laser radiation, or by induction heating of the metallic support of the Hg-dispensing compound.
  • the processes for the production of mercury-containing electron tubes include a tube-closing operation performed by glass fusion (e.g. the sealing of fluorescent lamps) or by frit sealing, i.e. welding two pre-shaped glass members by means of a paste of low-melting glass.
  • the mercury-dispensing device may undergo an indirect heating up to about 600°C. In this step the device is exposed to gases and vapors emitted by the melted glass and, in almost all industrial processes, to air.
  • the mercury-dispensing material undergoes a surface oxidation, whose final result is a yield lower than about 40% of the total mercury content during the activation process.
  • the mercury-dispensing material undergoes an indirect heating up to about 500°C. In this case the mercury yield during the activation process drops as low as about 20% of the total mercury content of the device.
  • the mercury not released during the activation operation is then slowly released during the life of the electron tube.
  • patent application EP-A-091.297 suggests the addition of Ni or Cu powders to the Ti 3 Hg or Zr 3 Hg compounds.
  • the addition of Ni and Cu to the mercury-dispensing compounds causes the melting of the combination of materials thus obtained, favouring the release of almost all the mercury in few seconds.
  • the melting takes place at the eutectic temperatures of the systems Ni-Ti, Ni-Zr, Cu-Ti and Cu-Zr, ranging from about 880°C for the Cu 66% - Ti 34% composition to 1280°C for the Ni81% - Ti 19% composition (atomic percent), though the document erroneously gives a melting temperature of 770°C for the Ni 4% - Ti 96% composition.
  • the object of the present invention is to provide an improved combination of materials for dispensing mercury in the electron tubes, which allows to overcomes one or more drawbacks of the prior art.
  • the object of the present invention is first of all to provide an improved combination of materials for dispensing mercury which is capable of releasing amounts of mercury higher than 60% during the activation step, even after partial oxidation, so as to be able to reduce the total amount of employed mercury.
  • Another object of the present invention is to provide a combination of materials whose residue, after the activation operation for releasing mercury, has a getter activity.
  • Another object of the present invention is to provide mercury-dispensing devices containing the combination of materials of the invention.
  • Still another object is to provide a process for introducing mercury by means of the devices of the invention into the electron tubes which require said element.
  • Component A of the combination of the present invention is an intermetallic compound corresponding to formula Ti x Zr y Hg z , as disclosed in the cited US patent no.3.657.589, to which reference is made for further details.
  • Zr 3 Hg and, particularly, Ti 3 Hg are preferred.
  • Component B of the combination of the present invention has the function of favouring the release of mercury from component A, and hereafter will also be defined promoter.
  • This component is a metallic alloy or an intermetallic compound including copper, tin and a metal selected among the rare earths or a mixture of rare earths.
  • the use of a mixture of rare earths is preferred over the use of single elements in that, since these metals have a similar chemistry, the separation of the single elements is a difficult and expensive operation; on the other hand, by using a mixture of rare earths it is possible to obtain, in this application, essentially the same results obtained with the single elements.
  • the mixtures of rare earths are known in the art by the name "misch metal"; this denomination, and its short form MM, will be used hereafter in the rest of the specification and in the claims.
  • the weight ratio between copper, tin and MM can vary within a wide range, but advantageous results have been obtained with compositions which, in a ternary diagram of percentage compositions on a weight basis (fig.4), fall within a polygon defined by points:
  • compositions which, in a ternary diagram of percentage compositions on a weight basis (fig.4), fall within a polygon defined by points:
  • a particularly preferred alloy has the percentage composition Cu 40% - Sn 30% - MM 30%, corresponding to point i) in the composition ternary diagram of fig.4.
  • the weight ratio between components A and B of the combination of the invention may vary within a wide range, but it is generally included between 20:1 and 1:20, and preferably between 10:1 and 1:5.
  • Components A and B of the combination of the invention may be employed in various physical forms, not necessarily the same for the two components.
  • component B may be present in the form of a coating of the metallic support, and component A as a powder adhered to component B by rolling.
  • both components are in the form of a fine powder, having a particle size lower than 250 ⁇ m and preferably between 10 and 125 ⁇ m.
  • the present invention in a second aspect thereof, relates to the mercury-dispensing devices which use the above-described combinations of A and B materials.
  • the mercury-dispensing devices of the present invention can be manufactured with the most different geometric shapes, and materials A and B of the combination can be employed without support or on a support, usually metallic.
  • Some classes of electron tubes for which the mercury dispensers are intended further require, for their correct operation, the presence of a getter material which removes traces of gases such as CO, CO 2 , H 2 , O 2 or water vapor: it is the case, for example, of fluorescent lamps.
  • a getter material which removes traces of gases such as CO, CO 2 , H 2 , O 2 or water vapor: it is the case, for example, of fluorescent lamps.
  • getter material C is lower than that required in prior art devices used in the same application.
  • getter materials include, among the others, metals such as titanium, zirconium, tantalum, niobium, vanadium and mixtures thereof, or alloys thereof with other metals such as nickel, iron, aluminum, like the alloy having a weight percentage composition Zr 84% - Al 16%, manufactured and sold by the Applicant under the name St101, or the intermetallic compounds Zr 2 Fe and Zr 2 Ni, manufactured and sold by the Applicant respectively under the name St198 and St199.
  • the getter material is activated during the same heat treatment by which mercury is released inside the tube.
  • the getter material C may be present in various physical forms, but it is preferably employed in the form of a fine powder, having a particle size lower than 250 ⁇ m and preferably between 10 and 125 ⁇ m.
  • the ratio between the overall weight of the A and B materials and that of the getter material C may generally range from about 10:1 to 1:10, and preferably between 5:1 and 1:2.
  • the devices of the invention can simply consist of a tablet 10 made up of compressed and unsupported powders of the A and B (and possibly C) materials, which for ease of production generally has a cylindrical or parallelepipedal shape; this latter possibility is shown in fig.1.
  • the device may have the shape of a ring 20 as shown in fig.2, which represents a top plan view of the device, and in fig.2a which represents a cross-section along II-II of device 20.
  • the device is made up of a support 21 having the shape of a toroidal channel containing the A and B (and possibly C) materials.
  • the support is generally metallic, and preferably of nickel-plated steel.
  • the device may be made in the shape of a strip 30 as shown in fig.3, which represents a top plan view of the device, and in figs.3a and 3b wherein a section along III-III of device 30 is depicted.
  • support 31 consists of a strip, preferably made of nickel-plated steel, onto which the A and B (and possibly C) materials are adhered by cold compression (rolling).
  • materials A, B and C may be mixed together and rolled on one or both faces of the strip (fig.3a), or materials A and B are rolled on one surface of the strip and material C on the opposite surface, as shown in fig.3b.
  • the invention in a further aspect thereof, relates to a method for introducing mercury into the electron tubes by using the above-described devices.
  • the method includes the step of introducing inside the tube the above-described mercury-dispensing combination of materials and preferably in one of the above-described devices 10, 20 or 30, and then the combination heating step to get mercury free.
  • the heating step may be carried out with any suitable means such as, for example, by radiation, by high-frequency induction heating or by having a current flow through the support when the latter is made of a material having a high electric resistivity.
  • the heating is effected at a temperature which causes the release of mercury from the mercury-dispensing combination, comprised between 600 and 900°C for a time of about 10 seconds to one minute.
  • Examples 1 to 3 concern the preparation of the mercury-dispensing and promoting materials
  • examples 4 to 9 concern the tests for the mercury release after the heat treatment simulating the sealing operation
  • Examples 10 to 14 concern the tests for the functionality as getter materials of the residues remaining after the mercury release. All the metals used for the preparation of alloys and compounds for the following tests have a minimum pureness of 99,5%. In the compositions of the examples all percentages are on a weight basis if not differently specified.
  • This example illustrates the synthesis of the mercury-dispensing material Ti 3 Hg.
  • 143,7 g of titanium are placed in a steel cradle and degassed by a furnace treatment at a temperature of about 700°C and a pressure of 10 -6 mbar for 30 minutes. After cooling the titanium powder in an inert atmosphere, 200,6 g of mercury are introduced in the cradle by means of a quartz tube. The cradle is then closed and heated at about 750°C for 3 hours. After cooling, the product is ground until a powder passing through a 120 ⁇ m mesh-size standard sieve is obtained.
  • the resulting material essentially consists of Ti 3 Hg, as confirmed by a diffractometric test carried out on the powder.
  • This example concerns the preparation of a promoting alloy which makes part of the combinations of the invention.
  • misch metal used contains about 50% by weight of cerium, 30% of lanthanum, 15% of neodymium and the rest are other rare earths.
  • the mixture is heated at a temperature of about 900°C, kept at that temperature for 5 minutes to encourage the homogeneity thereof, and finally cast into a steel ingot-mould.
  • Each ingot is ground in a blade mill and the powder is sieved like in example 1.
  • the composition of the obtained alloy is Cu 40% - Sn 30% - MM 30%, and corresponds to point i) in the diagram of fig.4.
  • This example concerns the preparation of a promoting alloy which makes part of the combinations of the invention.
  • the procedure of example 2 is repeated using 60 g of Cu, 30 g of Sn and 10 g of MM in powder form.
  • the composition of the obtained alloy is Cu 60% - Sn 30% - MM 10%, and corresponds to point I) in the diagram of fig.4.
  • Examples 4 to 9 concern the tests for the mercury release after a heat treatment in air which simulates the frit conditions to which the device is subjected during the tube closing (hereafter generally referred to as sealing).
  • Examples 4 to 7 are comparative examples which show the release after frit sealing respectively by the dispensing component alone (ex.4) and by the same mixed only with copper, tin and the above-cited getter alloy St101 (ex.5-7); a similar comparative test on a mixture of Ti 3 Hg and MM powders was not possible due to the excessive reactivity of this mixture.
  • Table 1 shows the mercury-dispensing compound A, the promoting material B (letters (i) or (I) in examples 8 and 9 refer to the composition of the Cu-Sn-MM alloy as shown in the diagram of fig.4), the weight ratio between components A and B and the mercury yield as a percentage of released mercury on the total content of the device.
  • the comparative examples are marked by a star.
  • Examples 10 to 14 concern the tests for the functionality as getter materials of the residues remaining after the mercury release by the combinations of the invention and by some comparative combinations.
  • the mercury release tests have been carried out after simulation of the frit sealing on the samples.
  • the fritted samples have been introduced inside a vacuum chamber having a volume of 1 liter, and heated under vacuum at 850°C for 10 seconds and kept at said temperature for 20 seconds.
  • the capacity of the residue to work as a getter is measured after the activation; this measurement is performed by introducing in the chamber an amount of hydrogen such as to bring the pressure to 0.1 mbar at a temperature of 30°C, and by measuring the time required for the pressure in the chamber to decrease to 0.01 mbar.
  • the measure of the pressure is taken by means of a capacitive manometer.
  • Table 2 shows the composition of the sample and the hydrogen absorption velocity at 30°C.
  • the "SAMPLE COMPOSITION" column gives the weight percentages of the component materials. The comparative combinations are marked by a star.
  • the residue remaining after the mercury release has a getter activity: in fact, while the residue remaining after the mercury release by the Ti 3 Hg compound alone has no getter activity, the sample of example 13 to which no getter has been added exhibits a significant hydrogen absorption velocity. Moreover, sample 12 has a hydrogen absorption velocity comparable to that of the sample of example 11, which is a combination of a mercury dispenser with a getter, widely used by lamp manufacturers.
  • the combinations with promoter of the present invention offer another important advantage, consisting in the possibility of carrying out the activation operation at temperatures or with times lower than those allowed by prior art materials.
  • Ti 3 Hg alone requires an activation temperature of about 900°C
  • the present combinations allow the reduction of the operation time and of the size of the lines for the production of the lamps; in both cases a double advantage is achieved of causing less pollution inside the tube due to the outgassing of all the materials present therein and of reducing the amount of energy required for the activation.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Discharge Lamp (AREA)
  • Common Detailed Techniques For Electron Tubes Or Discharge Tubes (AREA)
  • Vessels, Lead-In Wires, Accessory Apparatuses For Cathode-Ray Tubes (AREA)
  • Gas Separation By Absorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
EP96830202A 1995-04-10 1996-04-09 Combinaison de matériaux pour dispositifs intégrés de getter et d'apport de mercure et dispositif émisé obtenus Expired - Lifetime EP0737995B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI950734A IT1273531B (it) 1995-04-10 1995-04-10 Combinazioni di materiali per dispositivi integrati getter ed erogatori di mercurio e dispositivi cosi' ottenuti
ITMI950734 1995-04-10

Publications (3)

Publication Number Publication Date
EP0737995A2 true EP0737995A2 (fr) 1996-10-16
EP0737995A3 EP0737995A3 (fr) 1998-07-01
EP0737995B1 EP0737995B1 (fr) 2000-06-28

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EP96830202A Expired - Lifetime EP0737995B1 (fr) 1995-04-10 1996-04-09 Combinaison de matériaux pour dispositifs intégrés de getter et d'apport de mercure et dispositif émisé obtenus

Country Status (9)

Country Link
EP (1) EP0737995B1 (fr)
JP (1) JP2858646B2 (fr)
KR (1) KR100239823B1 (fr)
CN (1) CN1086504C (fr)
CA (1) CA2172686A1 (fr)
DE (1) DE69608996T2 (fr)
HU (1) HU221281B1 (fr)
IT (1) IT1273531B (fr)
RU (1) RU2113031C1 (fr)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1248285A2 (fr) * 2001-04-06 2002-10-09 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Lampe à décharge à basse pression
US6680571B1 (en) 1997-05-22 2004-01-20 Saes Getters S.P.A. Device for introducing small amounts of mercury into fluorescent lamps
US6679745B2 (en) 2000-03-06 2004-01-20 Saes Getters S.P.A. Method for the manufacture of mercury dispenser devices to be used in fluorescent lamps
WO2006008771A1 (fr) * 2004-07-23 2006-01-26 Saes Getters S.P.A. Compositions de distribution de mercure et procede de fabrication de ces compositions
WO2006106551A1 (fr) * 2005-04-06 2006-10-12 Saes Getters S.P.A. Distributeur de mercure soude a un ecran de cathode de lampes fluorescentes
WO2006106550A1 (fr) * 2005-04-06 2006-10-12 Saes Getters S.P.A. Distributeur de mercure pour lampes fluorescentes, monte mecaniquement sur un ecran de cathode
WO2009080569A1 (fr) 2007-12-21 2009-07-02 Saes Getters S.P.A. Dispositifs de diffusion de mercure à perte de particules réduite
ITMI20082187A1 (it) * 2008-12-11 2010-06-12 Getters Spa Sistema dispensatore di mercurio per lampade a fluorescenza
WO2011006811A1 (fr) 2009-07-15 2011-01-20 Saes Getters S.P.A. Support pour éléments filiformes contenant une substance active
WO2011104145A1 (fr) 2010-02-23 2011-09-01 Saes Getters S.P.A. Procédé et système pour la distribution contrôlée de mercure et dispositifs fabriqués par l'intermédiaire de ce procédé
ITMI20131658A1 (it) * 2013-10-08 2015-04-09 Getters Spa Combinazione di materiali per dispositivi di rilascio di mercurio e dispositivi contenenti detta combinazione di materiali

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100641301B1 (ko) * 2004-09-15 2006-11-02 주식회사 세종소재 겟터 겸용 수은 보충재
ITMI20050044A1 (it) * 2005-01-17 2006-07-18 Getters Spa Composizioni per il rilascio di mercurio
KR100870990B1 (ko) * 2007-11-13 2008-12-01 희성소재 (주) Ｂｌｕ용 형광램프에 수은을 도입시키기 위한 게터조성물및 그 장치
KR100899601B1 (ko) * 2009-02-06 2009-05-27 희성소재 (주) 램프용 고효율 수은방출 게터 조성물
US8253331B2 (en) 2010-04-28 2012-08-28 General Electric Company Mercury dosing method for fluorescent lamps
CN102664133A (zh) * 2012-05-10 2012-09-12 张文知 强化光合作用的无极灯灯管

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3657589A (en) * 1969-10-20 1972-04-18 Getters Spa Mercury generation
JPS526071A (en) * 1975-07-04 1977-01-18 Japan Radio Co Ltd Mercury emission getter material
US4464133A (en) * 1982-04-05 1984-08-07 Gte Laboratories Incorporated Method of charging a vessel with mercury
EP0669639A1 (fr) * 1994-02-24 1995-08-30 Saes Getters S.P.A. Combinaison de matériaux pour dispositifs dispensateurs de mercure, méthode de préparation et dispositifs ainsi obtenus

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3657589A (en) * 1969-10-20 1972-04-18 Getters Spa Mercury generation
JPS526071A (en) * 1975-07-04 1977-01-18 Japan Radio Co Ltd Mercury emission getter material
US4464133A (en) * 1982-04-05 1984-08-07 Gte Laboratories Incorporated Method of charging a vessel with mercury
EP0669639A1 (fr) * 1994-02-24 1995-08-30 Saes Getters S.P.A. Combinaison de matériaux pour dispositifs dispensateurs de mercure, méthode de préparation et dispositifs ainsi obtenus

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6680571B1 (en) 1997-05-22 2004-01-20 Saes Getters S.P.A. Device for introducing small amounts of mercury into fluorescent lamps
US6679745B2 (en) 2000-03-06 2004-01-20 Saes Getters S.P.A. Method for the manufacture of mercury dispenser devices to be used in fluorescent lamps
EP1248285A3 (fr) * 2001-04-06 2006-04-05 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Lampe à décharge à basse pression
EP1248285A2 (fr) * 2001-04-06 2002-10-09 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH Lampe à décharge à basse pression
US7976776B2 (en) 2004-07-23 2011-07-12 Saes Getters S.P.A. Mercury dispensing compositions and manufacturing process thereof
WO2006008771A1 (fr) * 2004-07-23 2006-01-26 Saes Getters S.P.A. Compositions de distribution de mercure et procede de fabrication de ces compositions
EP1953800A1 (fr) * 2004-07-23 2008-08-06 Saes Getters S.P.A. Compositions fournissant du mercure
US7674428B2 (en) 2004-07-23 2010-03-09 Saes Getters S.P.A. Mercury dispensing compositions and manufacturing process thereof
WO2006106551A1 (fr) * 2005-04-06 2006-10-12 Saes Getters S.P.A. Distributeur de mercure soude a un ecran de cathode de lampes fluorescentes
WO2006106550A1 (fr) * 2005-04-06 2006-10-12 Saes Getters S.P.A. Distributeur de mercure pour lampes fluorescentes, monte mecaniquement sur un ecran de cathode
WO2009080569A1 (fr) 2007-12-21 2009-07-02 Saes Getters S.P.A. Dispositifs de diffusion de mercure à perte de particules réduite
US7982383B2 (en) 2007-12-21 2011-07-19 Saes Getters S.P.A. Mercury dispensing devices with a reduced particle loss
ITMI20082187A1 (it) * 2008-12-11 2010-06-12 Getters Spa Sistema dispensatore di mercurio per lampade a fluorescenza
WO2010066611A1 (fr) * 2008-12-11 2010-06-17 Saes Getters S.P.A. Système de distribution de mercure pour des lampes à fluorescence
US8076848B2 (en) 2008-12-11 2011-12-13 Saes Getters S.P.A. Mercury dispensing system for fluorescent lamps
WO2011006811A1 (fr) 2009-07-15 2011-01-20 Saes Getters S.P.A. Support pour éléments filiformes contenant une substance active
US8427051B2 (en) 2009-07-15 2013-04-23 Saes Getters S.P.A. Support for filiform elements containing an active material
WO2011104145A1 (fr) 2010-02-23 2011-09-01 Saes Getters S.P.A. Procédé et système pour la distribution contrôlée de mercure et dispositifs fabriqués par l'intermédiaire de ce procédé
US8453892B2 (en) 2010-02-23 2013-06-04 Saes Getters S.P.A. Method and system for the controlled dispensing of mercury and devices manufactured through this method
ITMI20131658A1 (it) * 2013-10-08 2015-04-09 Getters Spa Combinazione di materiali per dispositivi di rilascio di mercurio e dispositivi contenenti detta combinazione di materiali
WO2015052604A1 (fr) * 2013-10-08 2015-04-16 Saes Getters S.P.A. Combinaison de matériaux pour des dispositifs de distribution de mercure et dispositifs contenant ladite combinaison de matériaux
US9406476B2 (en) 2013-10-08 2016-08-02 Saes Getters S.P.A. Combination of materials for mercury-dispensing devices and devices containing said combination of materials

Also Published As

Publication number Publication date
EP0737995B1 (fr) 2000-06-28
CA2172686A1 (fr) 1996-10-11
IT1273531B (it) 1997-07-08
ITMI950734A1 (it) 1996-10-10
CN1086504C (zh) 2002-06-19
KR100239823B1 (ko) 2000-01-15
ITMI950734A0 (it) 1995-04-10
HUP9600835A3 (en) 1999-09-28
CN1138209A (zh) 1996-12-18
JPH08287822A (ja) 1996-11-01
EP0737995A3 (fr) 1998-07-01
HU9600835D0 (en) 1996-05-28
HU221281B1 (en) 2002-09-28
KR960039099A (ko) 1996-11-21
JP2858646B2 (ja) 1999-02-17
HUP9600835A2 (en) 1997-05-28
DE69608996T2 (de) 2000-11-02
DE69608996D1 (de) 2000-08-03
RU2113031C1 (ru) 1998-06-10

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