EP0737624B1 - Method for the manufacture of an easy open lid having an incision located in a sloping region - Google Patents
Method for the manufacture of an easy open lid having an incision located in a sloping region Download PDFInfo
- Publication number
- EP0737624B1 EP0737624B1 EP95420100A EP95420100A EP0737624B1 EP 0737624 B1 EP0737624 B1 EP 0737624B1 EP 95420100 A EP95420100 A EP 95420100A EP 95420100 A EP95420100 A EP 95420100A EP 0737624 B1 EP0737624 B1 EP 0737624B1
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- EP
- European Patent Office
- Prior art keywords
- score line
- strip
- incision
- process according
- angle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 238000002788 crimping Methods 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 238000004080 punching Methods 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 229910000838 Al alloy Inorganic materials 0.000 claims 1
- 238000005260 corrosion Methods 0.000 description 11
- 230000007797 corrosion Effects 0.000 description 11
- 239000000047 product Substances 0.000 description 6
- 238000004806 packaging method and process Methods 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 235000013361 beverage Nutrition 0.000 description 3
- 208000031968 Cadaver Diseases 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 235000015250 liver sausages Nutrition 0.000 description 2
- KRQUFUKTQHISJB-YYADALCUSA-N 2-[(E)-N-[2-(4-chlorophenoxy)propoxy]-C-propylcarbonimidoyl]-3-hydroxy-5-(thian-3-yl)cyclohex-2-en-1-one Chemical compound CCC\C(=N/OCC(C)OC1=CC=C(Cl)C=C1)C1=C(O)CC(CC1=O)C1CCCSC1 KRQUFUKTQHISJB-YYADALCUSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000003416 augmentation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D51/00—Making hollow objects
- B21D51/16—Making hollow objects characterised by the use of the objects
- B21D51/38—Making inlet or outlet arrangements of cans, tins, baths, bottles, or other vessels; Making can ends; Making closures
- B21D51/383—Making inlet or outlet arrangements of cans, tins, baths, bottles, or other vessels; Making can ends; Making closures scoring lines, tear strips or pulling tabs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D17/00—Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions
- B65D17/28—Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions at lines or points of weakness
- B65D17/404—Details of the lines of weakness
Definitions
- the invention relates to the field of containers with opening easy and especially the metal covers to easy opening.
- the easy-opening lids have a generally peripheral incision in the case of containers for food products, as shown in FIGS. 1a to 1c, FIGS. 1a and 1b corresponding to easy-opening lids with bowl, or have a localized incision at a small portion of the cover panel in the case of a cover for a beverage can.
- the incisions are defined by their profile and the residual metal thickness under the incision which is also called the "residual".
- a profile is defined by the angle alpha of the incision and by the calculated width P of the bottom of the incision.
- a typical incision is shown in Figure 2 where the angle alpha is 60 ° and the width P is 40 ⁇ m and is designated by "60P40".
- US patent 4,132,328 is known in which the incision of an easy-opening cover is formed on a strip delimited between two zones formed by two punching stages, so as to increase the compression of said delimited strip and thus facilitate opening the cover.
- Figure 7 shows in section an incision after crimping and sterilization, with cracks at the bottom of the incision characteristics that the present invention proposes otherwise delete entirely, at least reduce very strongly.
- the problem is to find a way to manufacture, so reliable and economical, low residual COF whose bottom incisions is not cracked at the end of manufacture, nor after packaging of the product to be packaged.
- said strip is located on the periphery of the central panel and the skirt inside of the edge to be crimped, and forms an inclined plane between said central panel and said skirt, as illustrated in Figures 3a and 3b, having the shape of a corner cone portion at the top 180 ° -2.beta.
- said cover is a convercle with a peripheral counter-bowl, in which said strip is located at the periphery of the central panel and of said counter-bowl, and forms an inclined plane between said central panel and said counter-bowl, as illustrated in Figures 3c, 3f and 3g, having the shape of a portion of a cone angle at the top 180 ° -2.beta.
- said cover is a partially open lid, for example a lid for a beverage can in which said strip forms a non-zero beta angle inclined plane bordering the part of said panel intended to be opened, as illustrated in Figures 3d and 3rd.
- said strip does not close on itself, as in the previous cases.
- the inclination of said incision strip can be oriented at an angle of +/- beta relative to said mean plane of the central panel, considered as a horizontal plane (see FIGS. 3a and 3b).
- Said beta angle is generally between 5 ° and 45 °. Indeed, for a beta angle less than 5 °, the desired effect (reduction of cracks) obtained is relatively moderate. Furthermore, as the problem posed is solved with a beta angle less than 45 °, there is no technical interest in making an incision on an incision band having a slope greater than 45 °.
- Said beta angle is preferably between 10 and 30 °. As the embodiments and the comparative tests will demonstrate, the means of the invention effectively solve the problem posed.
- Figures 1a to 1c show, in axial section, different shapes of covers with easy opening (1) of the prior art.
- These covers include a central panel (3) on which there is an incision (2) on the incision strip (6) in a horizontal plane, parallel to the mean plane (17) of the panel (3), and a crimping edge ( 4).
- the central panel is provided with a rivet (7) which fixes a ring (8), the spout (9) of which is located in line with the incision (2) so as to ensure the opening by tilting of the ring.
- the crimping edge (4) comprises a skirt (5), strongly inclined, connecting to said central panel, possibly by a bowl (20).
- Figures 1a to 1c are distinguished by the presence of a bowl (20) in the case of FIGS. 1a and 1b, and by the position of the incision (2) located in the plane of said panel central in the case of FIGS. 1a and 1c, and at the bottom of the bowl (20) in the case of FIG. 1b.
- Figure 2 shows in axial section an incision (2).
- a incision (2) is defined, for a thickness E of the layer metallic, by an alpha angle, by a calculated value P of bottom (10) of the incision, by an R value of the thickness residual (11) (also called “residual").
- the sides of the incision were designated by 16a and 16b.
- Figures 3a, 3b and 3c show, in axial section similar to that of FIGS. 1a to 1c, portions of easy opening cover (1) according to the invention having a sloping incision band (6).
- Figures 3a and 3b illustrate the position of the incision (2) on the incision strip (6) forming the bottom of the bowl (20).
- This strip (6) has a slope of angle beta with respect to the plane (17), corresponding to the horizontal mean plane of said central panel (3).
- said strip (6) has a slope of an angle + beta, while the angle is -beta in Figure 3b.
- Figure 3c illustrates the position of the incision (2) on the incision band (6) forming the periphery of the beach central (3), externally limited by the counter-bowl (18).
- This strip (6) has an angle slope + beta by relative to the plan (17).
- FIG. 3f is a top view showing the incision strip (6) in the form of a hatched crown, the incision (2) passing through the center of this strip.
- Figure 3f is an axial section along the axis BB of Figure 3f, showing that said strip (6) has the shape of a cone portion with an angle at the top equal to 180 ° - 2.beta.
- Figures 3d and 3e relate to an opening cover partial beverage can.
- Figure 3d is a top view and Figure 3e is a section along the axis A-A of Figure 3d.
- the incision strip (6) does not form not a band closed on itself, but has the form a horseshoe, the open part of which remains attached to the central panel (3) of the cover.
- the ring (8) is positioned on the side of this open part, and tilting forward just tear the incision (2) and fold inwards the box the tongue delimited by said incision (2).
- Figure 7 similar to Figure 2, shows a section micrographic showing the presence of cracks (12) at the bottom incision (10).
- the invention applies more particularly to covers with easy opening (1) in steel or aluminum or alloy aluminum, alpha angle between 40 and 120 °, thickness between 0.12 and 0.30 mm (nominal thickness of the metal strip intended to form the metal layer of the lid with easy opening), and of residual thickness R at the bottom of an incision greater than 40 ⁇ m.
- the residual thickness value R is generally understood between 60 and 140 ⁇ m, depending on the nature of the metal strip, and according to the value of said nominal thickness.
- the angle alpha is preferably between 40 ° and 60 ° and the width P at the bottom of the incision is between 10 and 40 ⁇ m.
- These preferential values are those which correspond to the best ease of opening.
- the invention also includes a method of manufacturing easy opening covers (1) in which said incision is obtained by punching, using a corner punch alpha, an incision strip (6) of a blank cover, in a vertical direction (19) perpendicular to the plane by means of said central panel (3), said incision strip having a non-zero beta angle slope.
- the angle alpha can be between 40 and 120 °, and the beta angle is generally between 5 and 45 °.
- Said incision strip (6) with a beta angle slope is formed by stamping metal strip in a manner known per se during the formation of the cover blank. Given the high precision of the tools used to manufacture covers, it suffices that said strip has a width of around 1 mm to be sure that said incision (2) will be always well positioned on said sloping strip (6) beta angle.
- Said punch (13) can be oriented at a gamma angle by with respect to said perpendicular direction (19) between two extreme values such as one of these values corresponds to a punch having one of its vertical faces (16a), as shown in Figure 4a, the other value corresponding to a punch having the other of its faces (16b) vertical, as shown in Figure 6a.
- the blank cover not incised is positioned on an appropriately shaped anvil so the incision band (6) is in abutment on said anvil during the action of said punch.
- All of the easy-open lids were made to from 5182 alloy aluminum strip (designation according to Aluminum Association), nominal thickness of 270 ⁇ m, varnished on both sides, and in metallurgical condition H28 corresponding to a strongly hardened state, restored during opening).
- Standard easy-opening covers (1) of 73 mm in diameter were manufactured, with a peripheral incision according to FIG. 3a, incision having a profile of the "60P40" type (alpha angle of 60 ° and a calculated value of dish at the bottom 40 ⁇ m incision).
- the lids obtained were crimped onto boxes which were then sterilized in a standard manner (30 min at 125 ° C). Cuts were made on the covers as manufactured, on the covers after crimping and on the covers after sterilization, so as to be able to carry out observations under the microscope by reflection and to assess the presence and extent of cracks at the bottom of the incision. .
- the residual metal layer under the incision is particularly sensitive to the action of corrosion due to the ingredients of the packaged products (possible presence of acids and / or salts), and the sensitivity to corrosion increases with the presence of cracks, or the presence of cracks of greater length.
- the damage to the incision which can be quantified by the presence of cracks and the length of the cracks, and the resistance to corrosion.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers Opened By Tearing Frangible Portions (AREA)
- Closures For Containers (AREA)
- Shaping Metal By Deep-Drawing, Or The Like (AREA)
- Sewage (AREA)
Description
L'invention concerne le domaine des récipients à ouverture facile et plus spécialement les couvercles métalliques à ouverture facile.The invention relates to the field of containers with opening easy and especially the metal covers to easy opening.
Les couvercles à ouverture facile possèdent une incision
généralement périphérique dans le cas de récipients pour
produits alimentaires, comme représenté sur les figures 1a à
1c, les figures 1a et 1b correspondant à des couvercles à
ouverture facile avec cuvette, ou possèdent une incision
localisée à une faible portion du panneau du couvercle dans le
cas d'un couvercle pour boíte-boisson.
Les incisions sont définies par leur profil et l'épaisseur de
métal résiduelle sous l'incision qui est appelée aussi le
"résiduel".
Un profil est défini par l'angle alpha de l'incision et par la
largeur calculée P du fond de l'incision. Une incision typique
est représentée à la figure 2 où l'angle alpha vaut 60° et la
largeur P vaut 40 µm et elle est désignée par "60P40".
Par ailleurs, on connait le brevet US 4,132,328 dans lequel
l'incision d'un couvercle à ouverture facile est formée sur une
bande délimitée entre deux zones formées par deux étapes de
poinçonnage, de manière à augmenter la compression de ladite
bande délimitée et ainsi faciliter l'ouverture du couvercle.The easy-opening lids have a generally peripheral incision in the case of containers for food products, as shown in FIGS. 1a to 1c, FIGS. 1a and 1b corresponding to easy-opening lids with bowl, or have a localized incision at a small portion of the cover panel in the case of a cover for a beverage can.
The incisions are defined by their profile and the residual metal thickness under the incision which is also called the "residual".
A profile is defined by the angle alpha of the incision and by the calculated width P of the bottom of the incision. A typical incision is shown in Figure 2 where the angle alpha is 60 ° and the width P is 40 µm and is designated by "60P40".
Furthermore, US patent 4,132,328 is known in which the incision of an easy-opening cover is formed on a strip delimited between two zones formed by two punching stages, so as to increase the compression of said delimited strip and thus facilitate opening the cover.
Il y a une demande toujours plus grande pour des couvercles à
ouverture facile présentant simultanément une plus grande
facilité d'ouverture et une plus grande sécurité de
fabrication et d'usage. Mais ces exigences sont à ce jour en
grande partie contradictoires dans la mesure où la plus grande
facilité d'ouverture est généralement obtenue par diminution
du résiduel, diminution qui entraíne une sécurité de
fabrication bien moindre (précision des outils plus grande,
marge de sécurité plus faible), et surtout des risques très
importants d'apparition de fissures en fond d'incision, qui
conduisent à des fuites, soit directemnent, soit par action de
la pression pendant le conditionnement, typiquement avec
stérilisation, soit après conditionnement par action corrosive
du produit conditionné.
En outre, la présence de fissures rend les couvercles plus
sensibles aux perforations par chocs lors des manutentions du
produit conditionné, et cela depuis le conditionnement du
produit jusqu'à son utilisation finale chez le consommateur.There is an ever-increasing demand for easy-opening covers which simultaneously present greater ease of opening and greater safety in manufacture and use. But these requirements are to date largely contradictory to the extent that the greatest ease of opening is generally obtained by reducing the residual, a decrease which results in a much lower manufacturing safety (greater precision of tools, greater safety margin low), and above all very significant risks of the appearance of cracks at the bottom of the incision, which lead to leaks, either directly, or by the action of pressure during conditioning, typically with sterilization, or after conditioning by the corrosive action of conditioned product.
In addition, the presence of cracks makes the covers more sensitive to impact punctures during handling of the packaged product, and this from the packaging of the product to its final use by the consumer.
La figure 7 représente en coupe une incision après sertisage et stérilisation, présentant, en fond d'incision, des fissures caractéristiques que la présente invention se propose sinon de supprimer en totalité, du moins de réduire très fortement.Figure 7 shows in section an incision after crimping and sterilization, with cracks at the bottom of the incision characteristics that the present invention proposes otherwise delete entirely, at least reduce very strongly.
Le problème est de trouver un moyen pour fabriquer, de manière fiable et économique, des COF à faible résiduel dont le fond des incisions ne soit pas fissuré en sortie de fabrication, ni après conditionnement du produit à emballer.The problem is to find a way to manufacture, so reliable and economical, low residual COF whose bottom incisions is not cracked at the end of manufacture, nor after packaging of the product to be packaged.
Ce problème est résolu par le procédé selon la revendication 1.This problem is solved by the method according to claim 1.
Selon une première modalité préférée de l'invention, ladite bande est située à la périphérie du panneau central et de la jupe intérieure du bord à sertir, et forme un plan incliné entre ledit panneau central et ladite jupe, comme illustré aux figures 3a et 3b, ayant la forme d'une portion de cône d'angle au sommet 180°-2.beta. According to a first preferred embodiment of the invention, said strip is located on the periphery of the central panel and the skirt inside of the edge to be crimped, and forms an inclined plane between said central panel and said skirt, as illustrated in Figures 3a and 3b, having the shape of a corner cone portion at the top 180 ° -2.beta.
Selon une seconde modalité de l'invention, ledit couvercle est un convercle avec une contre-cuvette périphérique, dans lequel ladite bande est située à la périphérie du panneau central et de ladite contre-cuvette, et forme un plan incliné entre ledit panneau central et ladite contre-cuvette, comme illustré aux figures 3c, 3f et 3g, ayant la forme d'une portion de cône d'angle au sommet 180°-2.beta.According to a second embodiment of the invention, said cover is a convercle with a peripheral counter-bowl, in which said strip is located at the periphery of the central panel and of said counter-bowl, and forms an inclined plane between said central panel and said counter-bowl, as illustrated in Figures 3c, 3f and 3g, having the shape of a portion of a cone angle at the top 180 ° -2.beta.
Selon une troisième modalité de l'invention, ledit couvercle est un couvercle à ouverture partielle, par exemple un couvercle pour boíte-boisson dans lequel ladite bande forme un plan incliné d'angle beta non nul bordant la partie dudit panneau destinée à être ouverte, comme illustré aux figures 3d et 3e. Dans ce cas, ladite bande ne se referme pas sur elle-même, comme dans les cas précédents.According to a third embodiment of the invention, said cover is a partially open lid, for example a lid for a beverage can in which said strip forms a non-zero beta angle inclined plane bordering the part of said panel intended to be opened, as illustrated in Figures 3d and 3rd. In this case, said strip does not close on itself, as in the previous cases.
L'inclinaison de ladite bande d'incision peut être orientée
selon un angle de +/- beta par rapport audit plan moyen du
panneau central, considéré comme plan horizontal (voir les
figures 3a et 3b).
Ledit angle beta est généralement compris entre 5° et 45°. En
effet, pour un angle beta inférieur à 5°, l'effet recherché
(diminution de fissures) obtenu est relativement modéré. Par
ailleurs, comme le problème posé est résolu avec un angle beta
inférieur à 45°, il n'y a pas d'intérêt technique à réaliser
une incision sur une bande d'incision ayant une pente
supérieure à 45°.
Ledit angle beta est de préférence compris entre 10 et 30°.
Comme le démontreront les exemples de réalisation et les
essais comparatifs, les moyens de l'invention résolvent
effectivement le problème posé.The inclination of said incision strip can be oriented at an angle of +/- beta relative to said mean plane of the central panel, considered as a horizontal plane (see FIGS. 3a and 3b).
Said beta angle is generally between 5 ° and 45 °. Indeed, for a beta angle less than 5 °, the desired effect (reduction of cracks) obtained is relatively moderate. Furthermore, as the problem posed is solved with a beta angle less than 45 °, there is no technical interest in making an incision on an incision band having a slope greater than 45 °.
Said beta angle is preferably between 10 and 30 °.
As the embodiments and the comparative tests will demonstrate, the means of the invention effectively solve the problem posed.
Les figures 1a à 1c représentent, en coupe axiale, différentes
formes de couvercles à ouverture facile (1) de l'art
antérieur.
Ces couvercles comprennent un panneau central (3) sur lequel
se trouve une incision (2) sur bande d'incision (6) dans un
plan horizontal, parallèle au plan moyen (17) du panneau (3),
et un bord à sertir (4).
Le panneau central est muni d'un rivet (7) qui fixe un anneau
(8) dont le bec (9) est situé au droit de l'incision (2) de
manière à assurer l'ouverture par basculement de l'anneau.
Le bord à sertir (4) comprend une jupe (5), fortement
inclinée, se raccordant audit panneau central, éventuellement
par une cuvette (20).Figures 1a to 1c show, in axial section, different shapes of covers with easy opening (1) of the prior art.
These covers include a central panel (3) on which there is an incision (2) on the incision strip (6) in a horizontal plane, parallel to the mean plane (17) of the panel (3), and a crimping edge ( 4).
The central panel is provided with a rivet (7) which fixes a ring (8), the spout (9) of which is located in line with the incision (2) so as to ensure the opening by tilting of the ring.
The crimping edge (4) comprises a skirt (5), strongly inclined, connecting to said central panel, possibly by a bowl (20).
Les figures 1a à 1c se distinguent par la présence d'une cuvette (20) dans le cas des figures 1a et 1b, et par la position de l'incision (2) située dans le plan dudit panneau central dans le cas des figures 1a et 1c, et au fond de la cuvette (20) dans le cas de la figure 1b.Figures 1a to 1c are distinguished by the presence of a bowl (20) in the case of FIGS. 1a and 1b, and by the position of the incision (2) located in the plane of said panel central in the case of FIGS. 1a and 1c, and at the bottom of the bowl (20) in the case of FIG. 1b.
La figure 2 représente en coupe axiale une incision (2). Une incision (2) se définit, pour une épaisseur E de la couche métallique, par un angle alpha, par une valeur calculée P du fond (10) de l'incision, par une valeur R de l'épaisseur résiduelle (11) (appelé aussi "résiduel"). Les côtés de l'incision ont été désignés par 16a et 16b.Figure 2 shows in axial section an incision (2). A incision (2) is defined, for a thickness E of the layer metallic, by an alpha angle, by a calculated value P of bottom (10) of the incision, by an R value of the thickness residual (11) (also called "residual"). The sides of the incision were designated by 16a and 16b.
Les figures 3a, 3b et 3c représentent, en coupe axiale analogue à celle des figures 1a à 1c, des portions de couvercle à ouverture facile (1) selon l'invention présentant une bande d'incision (6) en pente.Figures 3a, 3b and 3c show, in axial section similar to that of FIGS. 1a to 1c, portions of easy opening cover (1) according to the invention having a sloping incision band (6).
Les figures 3a et 3b illustrent la position de l'incision (2)
sur la bande d'incision (6) formant le fond de la cuvette
(20). Cette bande (6) présente une pente d'angle beta par
rapport au plan (17), correspondant au plan moyen horizontal
dudit panneau central (3).
Sur la figure 3a, ladite bande (6) présente une pente d'un
angle +beta, alors que l'angle est de -beta sur la figure 3b. Figures 3a and 3b illustrate the position of the incision (2) on the incision strip (6) forming the bottom of the bowl (20). This strip (6) has a slope of angle beta with respect to the plane (17), corresponding to the horizontal mean plane of said central panel (3).
In Figure 3a, said strip (6) has a slope of an angle + beta, while the angle is -beta in Figure 3b.
La figure 3c illustre la position de l'incision (2) sur la bande d'incision (6) formant la périphérie de la plage centrale (3), limitée extérieurement par la contre-cuvette (18). Cette bande (6) présente une pente d'angle +beta par rapport au plan (17).Figure 3c illustrates the position of the incision (2) on the incision band (6) forming the periphery of the beach central (3), externally limited by the counter-bowl (18). This strip (6) has an angle slope + beta by relative to the plan (17).
Les figures 3f et 3g sont relatives au couvercle de la figure
3c. La figure 3f est une vue de dessus montrant la bande
d'incision (6) sous forme d'une couronne hachurée, l'incision
(2) passant au centre de cette bande.
La figure 3f est une coupe axiale selon l'axe B-B de la figure
3f, montrant que ladite bande (6) a la forme d'une portion de
cône d'angle au sommet égal à 180°- 2.beta.Figures 3f and 3g relate to the cover of Figure 3c. FIG. 3f is a top view showing the incision strip (6) in the form of a hatched crown, the incision (2) passing through the center of this strip.
Figure 3f is an axial section along the axis BB of Figure 3f, showing that said strip (6) has the shape of a cone portion with an angle at the top equal to 180 ° - 2.beta.
Les figures 3d et 3e sont relatives à un couvercle à ouverture partielle de boíte boisson. La figure 3d est une vue de dessus et la figure 3e est une coupe selon l'axe A-A de la figure 3d. Avec ce type de couvercle, la bande d'incision (6) ne forme pas une bande fermée sur elle-même, mais présente la forme d'un fer à cheval, dont la partie ouverte reste rattachée au panneau central (3) du couvercle. L'anneau (8) est positionné du côté de cette partie ouverte, et en basculant vers l'avant vient déchirer l'incision (2) et rabattre vers l'intérieur de la boíte la languette délimitée par ladite incision (2).Figures 3d and 3e relate to an opening cover partial beverage can. Figure 3d is a top view and Figure 3e is a section along the axis A-A of Figure 3d. With this type of cover, the incision strip (6) does not form not a band closed on itself, but has the form a horseshoe, the open part of which remains attached to the central panel (3) of the cover. The ring (8) is positioned on the side of this open part, and tilting forward just tear the incision (2) and fold inwards the box the tongue delimited by said incision (2).
Les figures 4a, 5a et 6a sont des coupes partielles
axiales de poinçons (13) destinés à former des incisions (2)
selon l'invention, les deux côtés (14a, 14b) du poinçon
formant un angle alpha et se raccordant par une extrémité
(15). Les poinçons se déplacent selon la direction verticale
(19) pour former les incisions (2) correspondantes
représentées aux figures 4b, 5b et 6b.
Ces figures montrent les limites de l'inclinaison du poinçon
d'un angle gamma par rapport à la verticale:
- à la figure 4a, une limite de l'angle gamma est atteinte car
le
côté 14a du poinçon est vertical, - à la figure 6a, l'autre limite de l'angle gamma est atteinte
car l'autre
côté 14b du poinçon est vertical, - la figure 5a représente un cas intermédiaire où l'angle gamma vaut zero.
These figures show the limits of the inclination of the punch at a gamma angle relative to the vertical:
- in FIG. 4a, a limit of the gamma angle is reached because the
side 14a of the punch is vertical, - in FIG. 6a, the other limit of the gamma angle is reached because the
other side 14b of the punch is vertical, - FIG. 5a represents an intermediate case where the gamma angle is zero.
La figure 7, analogue à la figure 2, représente une coupe micrographique montrant la présence de fissures (12) en fond d'incision (10).Figure 7, similar to Figure 2, shows a section micrographic showing the presence of cracks (12) at the bottom incision (10).
L'invention s'applique plus particulièrement aux couvercles à ouverture facile (1) en acier ou en aluminium ou alliage d'aluminium, d'angle alpha compris entre 40 et 120°, d'épaisseur comprise entre 0,12 et 0,30 mm (épaisseur nominale de la bande métallique destinée à former la couche métallique du couvercle à ouverture facile), et d'épaisseur résiduelle R en fond d'incision supérieure à 40 µm.The invention applies more particularly to covers with easy opening (1) in steel or aluminum or alloy aluminum, alpha angle between 40 and 120 °, thickness between 0.12 and 0.30 mm (nominal thickness of the metal strip intended to form the metal layer of the lid with easy opening), and of residual thickness R at the bottom of an incision greater than 40 µm.
La valeur d'épaisseur résiduelle R est généralement comprise entre 60 et 140 µm, selon la nature de la bande métallique, et selon la valeur de ladite épaisseur nominale.The residual thickness value R is generally understood between 60 and 140 µm, depending on the nature of the metal strip, and according to the value of said nominal thickness.
Selon l'invention, l'angle alpha est de préférence compris
entre 40° et 60° et la largeur P à fond d'incision est
comprise entre 10 et 40 µm.
Ces valeurs préférentielles sont celles qui correspondent à la
meilleure facilité d'ouverture.According to the invention, the angle alpha is preferably between 40 ° and 60 ° and the width P at the bottom of the incision is between 10 and 40 μm.
These preferential values are those which correspond to the best ease of opening.
L'invention comprend aussi un procédé de fabrication de couvercles à ouverture facile (1) dans lequel ladite incision est obtenue par poinçonnage, à l'aide d'un poinçon d'angle alpha, d'une bande d'incision (6) d'une ébauche de couvercle, dans une direction verticale (19) perpendiculaire au plan moyen dudit panneau central (3), ladite bande d'incision ayant une pente d'angle beta non nul. The invention also includes a method of manufacturing easy opening covers (1) in which said incision is obtained by punching, using a corner punch alpha, an incision strip (6) of a blank cover, in a vertical direction (19) perpendicular to the plane by means of said central panel (3), said incision strip having a non-zero beta angle slope.
Comme déjà indiqué à propos de l'incision elle-même, l'angle alpha peut être comprise entre 40 et 120°, et l'angle beta est généralement compris entre 5 et 45°.As already stated about the incision itself, the angle alpha can be between 40 and 120 °, and the beta angle is generally between 5 and 45 °.
Ladite bande d'incision (6) en pente d'angle beta est formée par emboutissage de bande de métal de manière connue en soi lors de la formation de l'ébauche de couvercle. Compte tenu de la grande précision des outillages de fabrication des couvercles, il suffit que ladite bande ait une largeur de l'ordre de 1 mm pour être assuré que ladite incision (2) sera toujours bien positionnée sur ladite bande (6) en pente d'angle beta.Said incision strip (6) with a beta angle slope is formed by stamping metal strip in a manner known per se during the formation of the cover blank. Given the high precision of the tools used to manufacture covers, it suffices that said strip has a width of around 1 mm to be sure that said incision (2) will be always well positioned on said sloping strip (6) beta angle.
Ledit poinçon (13) peut être orienté selon un angle gamma par rapport à ladite direction perpendiculaire (19) compris entre deux valeurs extrèmes telles que l'une de ces valeurs correspond à un poinçon ayant l'une de ses faces verticale (16a), comme représenté à la figure 4a, l'autre valeur correpondant à un poinçon ayant l'autre de ses faces (16b) verticale, comme représenté à la figure 6a.Said punch (13) can be oriented at a gamma angle by with respect to said perpendicular direction (19) between two extreme values such as one of these values corresponds to a punch having one of its vertical faces (16a), as shown in Figure 4a, the other value corresponding to a punch having the other of its faces (16b) vertical, as shown in Figure 6a.
De manière connue en soi pour former ladite incision (2) par action dudit poinçon (13), l'ébauche de couvercle non-incisée est positionnée sur une enclume de forme appropriée de manière à ce que la bande d'incision (6) soit en appui sur ladite enclume lors de l'action dudit poinçon.In a manner known per se to form said incision (2) by action of said punch (13), the blank cover not incised is positioned on an appropriately shaped anvil so the incision band (6) is in abutment on said anvil during the action of said punch.
Tous les couvercles à ouverture facile ont été fabriqués à partir de bande d'aluminium en alliage 5182 (désignation selon l'Aluminum Association), d'épaisseur nominale de 270 µm, vernie sur ses deux faces, et à l'état métallurgique H28 correspondant à un état fortement écroui, restauré lors du vernissage). All of the easy-open lids were made to from 5182 alloy aluminum strip (designation according to Aluminum Association), nominal thickness of 270 µm, varnished on both sides, and in metallurgical condition H28 corresponding to a strongly hardened state, restored during opening).
On a fabriqué des couvercles standard à ouverture facile (1)
de 73 mm de diamètre, avec une incision périphérique selon la
figure 3a, incision ayant un profil de type "60P40" (angle
alpha de 60° et une valeur calculée de plat en fond d'incision
de 40 µm).
Le poinçon faisait donc un angle alpha de 60°, sa bissectrice
était orientée selon la verticale (angle gamma = 0).Standard easy-opening covers (1) of 73 mm in diameter were manufactured, with a peripheral incision according to FIG. 3a, incision having a profile of the "60P40" type (alpha angle of 60 ° and a calculated value of dish at the bottom 40 µm incision).
The punch therefore made an alpha angle of 60 °, its bisector was oriented vertically (gamma angle = 0).
Les essais ont consisté à faire varier l'épaisseur résiduelle
R d'une part (résiduel de 50 µm / 60 µm / 70µm / 95 µm), et à
faire varier la pente beta de la bande d'incision (6) de
l'ébauche de couvercle à inciser.
Les résultats de deux essais comparatifs, parmi les différents
essais réalisés, sont décrits en détail ci-après, avec:
- un angle beta de 0° selon l'état de la technique,
- un angle beta de 15° selon l'invention.
The results of two comparative tests, among the various tests carried out, are described in detail below, with:
- a beta angle of 0 ° according to the state of the art,
- a beta angle of 15 ° according to the invention.
Pour chaque couple de valeurs de R et d'angle beta de la bande d'incision (6), 200 couvercles à ouverture facile ont été fabriqués.For each pair of values of R and beta angle of the band incision (6), 200 easy-opening covers were manufactured.
Les couvercles obtenus ont été sertis sur des boítes qui ont
été ensuite stérilisées de manière standard (30 min à 125°C).
Des coupes ont été réalisées sur les couvercles tels que
fabriqués, sur les couvercles après sertissage et sur les
couvercles après stérilisation, de manière à pouvoir réaliser
des observations au microscope par réflexion et évaluer la
présence et l'importance de fissures en fond d'incision.The lids obtained were crimped onto boxes which were then sterilized in a standard manner (30 min at 125 ° C).
Cuts were made on the covers as manufactured, on the covers after crimping and on the covers after sterilization, so as to be able to carry out observations under the microscope by reflection and to assess the presence and extent of cracks at the bottom of the incision. .
Cotation des fissures par leur fréquence et leur longueur:
- a) présence de fissures :
- Oui = plus de 1
cas sur 10
Rares = de 1cas sur 10 à 1 sur 100
Non = moins de 1 cas sur 100 - b) longueur des fissures:
- < 2 µm-5µm (amorces)
fissures au-delà de 5 µm
- a) presence of cracks:
- Yes = more than 1 in 10 cases
Rare = 1 in 10 to 1 in 100
No = less than 1 in 100 cases - b) length of the cracks:
- <2 µm-5µm (primers)
cracks beyond 5 µm
Résultats obtenus sur couvercles tels que fabriqués :
Les résultats obtenus après sertissage et après stérilisation
vont dans le même sens avec une tendance à l'augmentation du
nombre et/ou de la profondeur des fissures.
Par ailleurs, les essais d'ouverture manuelle ont conduit à
des résultats comparables pour une même valeur de résiduel R.The results obtained after crimping and after sterilization go in the same direction with a tendency to increase the number and / or the depth of the cracks.
In addition, the manual opening tests led to comparable results for the same residual value R.
Ces résultats montrent de manière claire l'influence de l'angle beta sur l'apparition de fissures en fond d'incision.These results clearly show the influence of the beta angle on the appearance of cracks at the bottom of the incision.
Ces résultats sont d'une grande importance pratique.
En effet, selon les études de tenue à la corrosion menées par
la demanderesse, la couche métallique résiduelle sous
l'incision est particulièrement sensible à l'action de la
corrosion due aux ingrédients des produits conditionnés
(présence éventuelle d'acides et/ou de sels), et la
sensibilité à la corrosion augmente avec la présence de
fissures, ou la présence de fissures de plus grande longueur.
Selon une approche qualitative, il y a donc une corrélation
entre l'endommagement de l'incision, que l'on peut quantifier
par la présence de fissures et la longueur des fissures, et la
tenue à la corrosion. These results are of great practical importance.
In fact, according to the corrosion resistance studies carried out by the applicant, the residual metal layer under the incision is particularly sensitive to the action of corrosion due to the ingredients of the packaged products (possible presence of acids and / or salts), and the sensitivity to corrosion increases with the presence of cracks, or the presence of cracks of greater length.
According to a qualitative approach, there is therefore a correlation between the damage to the incision, which can be quantified by the presence of cracks and the length of the cracks, and the resistance to corrosion.
Les conséquences positives d'une amélioration de la tenue à la corrosion des couvercles à ouverture facile sont de plusieurs ordres:
- d'une part, pour le fabricant de couvercles, il est
important de disposer d'une plage de sécurité en ce qui
concerne la valeur de l'épaisseur résiduelle de métal. Dans le
cas présent, toutes les valeurs testées pour R, de 50 à 95 µm
conviennent. En effet, une fabrication est d'autant plus
coûteuse en outillage, en contrôle et en rebus qu'elle doit
satisfaire à une plage étroite de valeurs pour un paramètre
donné tel que l'épaisseur résiduelle de métal.
Par ailleurs, l'amélioration de la tenue à la corrosion peut aussi permettre une diminution de l'épaisseur de la couche de vernis intérieur. - d'autre part, l'amélioration de la tenue à la corrosion se traduit par une augmentation de la durée de vie des produits conditionnés, et par la diminution corrélative des risques de perforation des emballages, avec tous les risques de contamination et de salissures associés.
Enfin, la possibilité de diminuer, dans une large plage de valeurs, la valeur de l'épaisseur résiduelle de métal permet de moduler et de diminuer comme souhaité l'effort d'ouverture des couvercles à ouverture facile, alors que les couvercles de l'art antérieur nécessitaient, pour une même tenue à la corrosion, une valeur d'épaisseur résiduelle nettement supérieure, et donc impliquaient un effort d'ouverture supérieur.
Ce sont là des avantages importants dans le métier de l'emballage utilisant des couvercles à ouverture facile.The positive consequences of an improvement in the corrosion resistance of easy-opening covers are of several types:
- on the one hand, for the manufacturer of covers, it is important to have a safety range with regard to the value of the residual thickness of metal. In the present case, all the values tested for R, from 50 to 95 μm are suitable. Indeed, a manufacturing is all the more expensive in tooling, in control and in scrap as it must satisfy a narrow range of values for a given parameter such as the residual thickness of metal.
Furthermore, improving the corrosion resistance can also allow a reduction in the thickness of the interior varnish layer. - on the other hand, the improvement in corrosion resistance results in an increase in the service life of the packaged products, and in the corresponding reduction in the risks of perforation of the packaging, with all the risks of contamination and associated soiling .
Finally, the possibility of decreasing, over a wide range of values, the value of the residual thickness of metal makes it possible to modulate and decrease as desired the opening force of the lids with easy opening, while the lids of the prior art required, for the same corrosion resistance, a significantly higher residual thickness value, and therefore involved a greater opening force.
These are important advantages in the packaging business using easy-open lids.
Claims (9)
- Manufacturing process for easy opening metal covers (1) with central panel (3) and crimping edge (4) comprising a sore line (2) on a score line strip (6), part of the said panel on which the said score line is formed, and a ring (8) for perforation of the said score line and the said opening, in which the said score line (2) is made by punching with a punch (13) with an angle alpha and along a vertical direction (19) perpendicular to the average plane of the said central panel (3), a cover blank with a score line strip (6) placed on an anvil, characterized in that:a) the said score line strip (6) with a constant thickness E has a non-zero slope with an angle beta with respect to the average plane (17) of the said panel (3),b) the said anvil is an appropriate shape such that the said score line strip (6) is supported on the said anvil during the said punching operation.
- Process according to claim 1 in which the said punch (13) is oriented at an angle gamma with respect to the said perpendicular direction (19) between two extreme values such that one of these values corresponds to a punch with one of its faces vertical (16a), the other value corresponding to a punch with the other of its faces (16b) vertical.
- Process according to claim 2, in which the said score line strip (6) is located at the periphery of the said central panel (3) and the internal skirt (5) of
- Process according to claim 2 in which the said cover (1) has a peripheral counter-sink (18) and in which the said score line strip (6) is located at the periphery of the central panel (3) and the said counter-sink (18), and forms an inclined plane between the said central panel and the said counter-sink.
- Process according to claim 2, in which the said cover (1) opens partially, and in which the said score line strip (6) forms an inclined plane at the edge of the part of the said panel designed to be opened.
- Process according to any one of claims 1 to 5, in which the said angle beta is between 5° and 45°.
- Process according to claim 6 in which the said angle beta is preferably between 10 and 30°.
- Process according to any one of claims 1 to 7 in which the said cover (1) is made of steel or aluminum or aluminum alloy with a score line with angle alpha between 40 and 120° and between 0.12 and 0.30 mm thick, its thickness being the nominal thickness of the metal strip for the cover, and the score line having a thickness at the bottom of the score line exceeding 40 µm.
- Process according to any one of claims 1 to 8, in which the angle alpha is preferably between 40° and 60°, and the width P at the bottom of this score line is between 10 and 40 µm.
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP95420100A EP0737624B1 (en) | 1995-04-14 | 1995-04-14 | Method for the manufacture of an easy open lid having an incision located in a sloping region |
US08/930,431 US6004089A (en) | 1995-04-14 | 1996-04-15 | Method for making easy-open lids with improved scoring |
ES96913590T ES2144238T3 (en) | 1995-04-14 | 1996-04-15 | MANUFACTURING PROCEDURE FOR EASY OPENING COVERS WITH IMPROVED INCISION. |
AU56525/96A AU5652596A (en) | 1995-04-14 | 1996-04-15 | Method for making easy-open lids with improved scoring |
EP96913590A EP0820409B1 (en) | 1995-04-14 | 1996-04-15 | Method for making easy-open lids with improved scoring |
DE69607337T DE69607337T2 (en) | 1995-04-14 | 1996-04-15 | METHOD FOR PRODUCING EASILY OPENING LIDS WITH IMPROVED NOTES |
PCT/FR1996/000571 WO1996032334A1 (en) | 1995-04-14 | 1996-04-15 | Method for making easy-open lids with improved scoring |
HU9802582A HU226349B1 (en) | 1995-04-14 | 1996-04-15 | Method for making easy-open lids with improved scoring |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP95420100A EP0737624B1 (en) | 1995-04-14 | 1995-04-14 | Method for the manufacture of an easy open lid having an incision located in a sloping region |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0737624A2 EP0737624A2 (en) | 1996-10-16 |
EP0737624A3 EP0737624A3 (en) | 1996-10-30 |
EP0737624B1 true EP0737624B1 (en) | 1999-10-13 |
Family
ID=8221571
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95420100A Expired - Lifetime EP0737624B1 (en) | 1995-04-14 | 1995-04-14 | Method for the manufacture of an easy open lid having an incision located in a sloping region |
EP96913590A Expired - Lifetime EP0820409B1 (en) | 1995-04-14 | 1996-04-15 | Method for making easy-open lids with improved scoring |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96913590A Expired - Lifetime EP0820409B1 (en) | 1995-04-14 | 1996-04-15 | Method for making easy-open lids with improved scoring |
Country Status (7)
Country | Link |
---|---|
US (1) | US6004089A (en) |
EP (2) | EP0737624B1 (en) |
AU (1) | AU5652596A (en) |
DE (1) | DE69607337T2 (en) |
ES (1) | ES2144238T3 (en) |
HU (1) | HU226349B1 (en) |
WO (1) | WO1996032334A1 (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9717241D0 (en) * | 1997-08-15 | 1997-10-22 | Metal Box Plc | Easy open can ends |
JPH11105867A (en) * | 1997-09-30 | 1999-04-20 | Nippon Steel Corp | Highly corrosion-resistant, easily openable resin-coated metal can lid requiring no repairs at obverse and reverse |
ES2207971T3 (en) | 1998-10-08 | 2004-06-01 | Ball Packaging Europe Gmbh | TEMPORARY LOCK OF THE REVENTON IN A PLATE COVER. |
EP1308226A1 (en) * | 2001-11-06 | 2003-05-07 | Impress B.V. | Easy opening closure, container provided with such closure, and apparatus for producing such closure |
MY138331A (en) * | 2004-12-09 | 2009-05-29 | Crown Packaging Technology Inc | Method of and apparatus for forming a closure |
US8939308B2 (en) | 2009-09-04 | 2015-01-27 | Crown Packaging Technology, Inc. | Full aperture beverage end |
US9550604B2 (en) | 2010-10-18 | 2017-01-24 | Silgan Containers Llc | Can end with strengthening bead configuration |
USD653109S1 (en) | 2010-10-18 | 2012-01-31 | Stolle Machinery Company, Llc | Can end |
US9714114B2 (en) | 2013-11-08 | 2017-07-25 | Crown Packaging Technology, Inc. | Full aperture can end |
US20160354832A1 (en) * | 2015-06-08 | 2016-12-08 | Novelis Inc. | Beverage can end score tooling |
KR101635800B1 (en) * | 2015-09-15 | 2016-07-04 | 주식회사 도루코 | Snap-off double edge blade |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3338199A (en) * | 1965-03-17 | 1967-08-29 | American Can Co | Scoring apparatus and method |
US3650006A (en) * | 1968-12-11 | 1972-03-21 | American Can Co | Score manufacture |
US3688718A (en) * | 1969-10-23 | 1972-09-05 | Aluminum Co Of America | Method and apparatus for scoring metal container ends |
CH530829A (en) * | 1970-02-06 | 1972-11-30 | Rasselstein Ag | Method and tool for producing an embossed notch in a metal sheet |
US3946683A (en) * | 1972-12-26 | 1976-03-30 | Aluminum Company Of America | Tabless container opening device and method and tools for forming the same |
US3977341A (en) * | 1974-06-06 | 1976-08-31 | Aluminum Company Of America | Easy opening container component |
US3964414A (en) * | 1974-06-11 | 1976-06-22 | Kaiser Aluminum & Chemical Corporation | Easy open end method and apparatus |
US4039100A (en) * | 1976-07-28 | 1977-08-02 | Wells Robert A | Container having non-removable opening member with attached opening lever |
US4149479A (en) * | 1977-04-20 | 1979-04-17 | National Can Corporation | Method for forming opening means in panel |
US4202287A (en) * | 1977-04-20 | 1980-05-13 | National Can Corporation | Method of attaching tab to end panel |
JPS60204452A (en) * | 1984-03-30 | 1985-10-16 | 谷内 啓二 | Vessel cover with safe opening edge |
US5252019A (en) * | 1992-01-21 | 1993-10-12 | Weirton Steel Corporation | Convenience-feature non-circular end closure with interrupted panel profiling |
-
1995
- 1995-04-14 EP EP95420100A patent/EP0737624B1/en not_active Expired - Lifetime
-
1996
- 1996-04-15 ES ES96913590T patent/ES2144238T3/en not_active Expired - Lifetime
- 1996-04-15 WO PCT/FR1996/000571 patent/WO1996032334A1/en active IP Right Grant
- 1996-04-15 EP EP96913590A patent/EP0820409B1/en not_active Expired - Lifetime
- 1996-04-15 AU AU56525/96A patent/AU5652596A/en not_active Abandoned
- 1996-04-15 US US08/930,431 patent/US6004089A/en not_active Expired - Lifetime
- 1996-04-15 DE DE69607337T patent/DE69607337T2/en not_active Expired - Lifetime
- 1996-04-15 HU HU9802582A patent/HU226349B1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
HUP9802582A3 (en) | 2000-05-29 |
WO1996032334A1 (en) | 1996-10-17 |
AU5652596A (en) | 1996-10-30 |
EP0820409B1 (en) | 2000-03-22 |
EP0737624A3 (en) | 1996-10-30 |
US6004089A (en) | 1999-12-21 |
ES2144238T3 (en) | 2000-06-01 |
EP0737624A2 (en) | 1996-10-16 |
HU226349B1 (en) | 2008-09-29 |
HUP9802582A2 (en) | 1999-02-01 |
DE69607337D1 (en) | 2000-04-27 |
EP0820409A1 (en) | 1998-01-28 |
DE69607337T2 (en) | 2000-08-24 |
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