EP0731853B1 - Device for the accelerated cooling of a fast-moving continuous substrate in a vertical plane - Google Patents

Device for the accelerated cooling of a fast-moving continuous substrate in a vertical plane Download PDF

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Publication number
EP0731853B1
EP0731853B1 EP95932579A EP95932579A EP0731853B1 EP 0731853 B1 EP0731853 B1 EP 0731853B1 EP 95932579 A EP95932579 A EP 95932579A EP 95932579 A EP95932579 A EP 95932579A EP 0731853 B1 EP0731853 B1 EP 0731853B1
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EP
European Patent Office
Prior art keywords
substrate
cooling
cooling fluid
enclosure
tubes
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EP95932579A
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German (de)
French (fr)
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EP0731853A1 (en
Inventor
Benoít DORMAL
Pierre Simon
Stéphan Wilmotte
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Centre de Recherches Metallurgiques CRM ASBL
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Centre de Recherches Metallurgiques CRM ASBL
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/26After-treatment

Definitions

  • the present invention relates to an accelerated cooling device continuous substrate moving rapidly in a vertical plane, plus particularly a coated metal strip, for example a sheet hot dip galvanized.
  • the cooling device object of the present invention, will intentionally described and to facilitate understanding in as part of its use during cooling, after treatment of galvannealing, of a strip of galvanized steel, but this description in no way prejudges that the device of the invention cannot apply in other circumstances requiring conditions similar cooling.
  • the heat treatment called "galvannealing” consists in subjecting a hot-dip galvanized steel sheet after heating, temperature maintenance then cooling.
  • This treatment aims to ensure the diffusion of iron from the sheet through the coating layer, usually zinc or zinc alloy, so to obtain iron contents between 7% and 13% in the layer of the aforementioned coating.
  • This heat treatment operation has for effect of obtaining a coating having better stampability and weldability.
  • the classic galvannealing operation is carried out in an installation where the sheet describes at least two vertical passes namely a pass upward and downward pass.
  • the sheet leaves the bath vertically galvanizing to start its upward phase and enter, directly after the wringing device consisting of air knives, in a heating oven which brings the sheet to a temperature between 460 ° C and 600 ° C; the sheet then circulates in a holding oven at temperature. Above this oven is located at least one device for cooling intended to solidify the coating of the sheet metal, so as not to damage this coating on the rollers return ending the ascending phase and guiding the sheet towards the phase descending.
  • the quality of the coating obtained, after the operation of galvannealing is directly related to the diffusion of iron in the layer of zinc or zinc alloy and that this is favorably influenced by a sufficiently long temperature holding time, for example greater than 10 seconds.
  • the applicant has developed a process in which the heating power as cooling flows to limit the space necessary for these two operations and thereby preserve a sufficient length to obtain a passage time in the furnace of keeping as high a temperature as possible in order to obtain optimal conditions for iron diffusion in the coating layer; the cycle thus produced approaches the ideal cycle called "square".
  • US-A-3,428,023 also describes a device for depositing a coating of zinc on a moving steel strip, and to cool and solidify this coating by means of water spray jets.
  • the present invention relates to an accelerated cooling device of low length, particularly suitable for being used for cooling rapid by means of water / air mist nozzles of a coated substrate after leaving it last out of a temperature maintenance oven and before passing over rollers referral, particularly in the context of galvannealing treatment.
  • said angle is between 35 ° and 40 °.
  • the means for forming one or more fog curtains comprise fog projection ramps, and said projection ramps consist of two tubes whose longitudinal axes are parallel to the plane of said substrate, one of the two tubes encompassing the other and one of the tubes being supplied with water while the other is supplied with air, as well as by sprinklers supplied with water and in air by the two aforementioned tubes so as to form said mist curtains.
  • object of the invention comprises suction and evacuation means coolant outside the closed enclosure of said device cooling and preferably said means are located near of the upper end of the aforementioned device.
  • the aforementioned evacuation means include fume extractor hoods used as cooling fluid.
  • the previous modality provides a very effective solution to the problems techniques posed respectively, on the one hand by the waterfall in the bath of molten zinc and secondly by entrainment of fluid cooling outside the enclosure and bringing it into contact with the upper idler rollers.
  • FIG. 1 shows that the substrate 1 passes through the bath 2 of zinc or zinc alloy contained in the galvanizing tank 3, leaves this last vertically after return around roller 4, goes through a roller guide system 5, spins at device level wringing 6, consisting of air knives intended to adjust the thickness of the coating layer on the substrate. This last then begins a vertical upward trajectory until the second deflection roller 7, follows a horizontal path up to third deflection roller 8, then descends in a trajectory vertical to a later operation.
  • the substrate goes through a short rapid heater 9 and then a short temperature equalization device 10, a device much longer 11 holding temperature and finally in a short rapid cooling device 12 equipped with fog ramps water / air.
  • FIG. 2 illustrates a preferred embodiment of the device 12 for rapidly cooling a coated substrate.
  • the closed enclosure 13 including the rapid cooling device, the substrate to be cooled 1, the inlet 14 with compressed air barriers 141 preventing the coolant go down to the galvanizing bath, outlet 15 with air dams 151 preventing coolant from escaping towards the upper deflection rollers, the projection ramps 16 water / air mist, as well as devices 161, such as deflectors, intended to promote contact between the substrate and the fog and finally the hoods 17 for extracting the fog out of the enclosure defining the cooling device.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)

Description

La présente invention a trait à un dispositif de refroidissement accéléré d'un substrat continu en défilement rapide dans un plan vertical, plus particulièrement une bande métallique revêtue, par exemple une tôle galvanisée à chaud.The present invention relates to an accelerated cooling device continuous substrate moving rapidly in a vertical plane, plus particularly a coated metal strip, for example a sheet hot dip galvanized.

Le dispositif de refroidissement, objet de la présente invention, sera décrit intentionnellement et en vue d'en faciliter la compréhension dans le cadre de son utilisation lors du refroidissement, après traitement thermique de galvannealing, d'une bande d'acier galvanisée, mais cette description ne préjuge en rien que le dispositif de l'invention ne puisse être d'application dans d'autres circonstances requérant des conditions de refroidissement similaires.The cooling device, object of the present invention, will intentionally described and to facilitate understanding in as part of its use during cooling, after treatment of galvannealing, of a strip of galvanized steel, but this description in no way prejudges that the device of the invention cannot apply in other circumstances requiring conditions similar cooling.

Le traitement thermique appelé "galvannealing" consiste à soumettre une tôle d'acier galvanisée à chaud successivement à un chauffage, un maintien à température puis un refroidissement.The heat treatment called "galvannealing" consists in subjecting a hot-dip galvanized steel sheet after heating, temperature maintenance then cooling.

Ce traitement vise à assurer la diffusion du fer de la tôle à travers la couche de revêtement, généralement en zinc ou alliage de zinc, afin d'obtenir des teneurs en fer comprises entre 7 % et 13 % dans la couche de revêtement précitée. Cette opération de traitement thermique a pour effet d'obtenir un revêtement présentant une meilleure emboutissabilité et soudabilité.This treatment aims to ensure the diffusion of iron from the sheet through the coating layer, usually zinc or zinc alloy, so to obtain iron contents between 7% and 13% in the layer of the aforementioned coating. This heat treatment operation has for effect of obtaining a coating having better stampability and weldability.

L'opération classique de galvannealing est effectuée dans une installation où la tôle décrit au moins deux passes verticales à savoir une passe ascendante et une passe descendante.The classic galvannealing operation is carried out in an installation where the sheet describes at least two vertical passes namely a pass upward and downward pass.

De manière schématique, on dira que la tôle quitte verticalement le bain de galvanisation pour amorcer sa phase ascendante et entre, directement après le dispositif d'essorage constitué par des couteaux d'air, dans un four de chauffage qui porte la tôle à une température comprise entre 460°C et 600°C; la tôle circule ensuite dans un four de maintien à température. Au-dessus de ce four est situé au moins un dispositif de refroidissement destiné à assurer la solidification du revêtement de la tôle, de manière à ne pas endommager ce revêtement sur les rouleaux de renvoi terminant la phase ascendante et guidant la tôle vers la phase descendante.Schematically, it will be said that the sheet leaves the bath vertically galvanizing to start its upward phase and enter, directly after the wringing device consisting of air knives, in a heating oven which brings the sheet to a temperature between 460 ° C and 600 ° C; the sheet then circulates in a holding oven at temperature. Above this oven is located at least one device for cooling intended to solidify the coating of the sheet metal, so as not to damage this coating on the rollers return ending the ascending phase and guiding the sheet towards the phase descending.

Il s'est avéré que la qualité du revêtement obtenu, après l'opération de galvannealing, est directement en relation avec la diffusion du fer dans la couche de zinc ou d'alliage de zinc et que celle-ci est favorablement influencée par une durée de maintien à température suffisamment longue, par exemple supérieure à 10 secondes.It turned out that the quality of the coating obtained, after the operation of galvannealing, is directly related to the diffusion of iron in the layer of zinc or zinc alloy and that this is favorably influenced by a sufficiently long temperature holding time, for example greater than 10 seconds.

Or, la longueur de la phase ascendante est limitée par des problèmes de construction mécanique et de contrôle des vibrations produites dans la tôle au niveau des couteaux d'air.However, the length of the ascending phase is limited by problems of mechanical construction and vibration control produced in the sheet metal at the level of the air knives.

Pour utiliser au mieux la longueur d'installation dont on dispose pour effectuer les opérations de chauffage, maintien et refroidissement avant passage sur les rouleaux de renvoi sis au-dessus de la phase ascendante, le demandeur a mis au point un procédé dans lequel on augmente tant la puissance de chauffage que les flux de refroidissement afin de limiter l'espace nécessaire à ces deux opérations et préserver de la sorte une longueur suffisante pour obtenir un temps de passage dans le four de maintien à température le plus grand possible en vue d'obtenir des conditions optimales de diffusion du fer dans la couche de revêtement; le cycle ainsi réalisé se rapproche du cycle idéal dit "carré". To make the best use of the installation length available for perform the heating, holding and cooling operations before passage on the deflection rollers located above the ascending phase, the applicant has developed a process in which the heating power as cooling flows to limit the space necessary for these two operations and thereby preserve a sufficient length to obtain a passage time in the furnace of keeping as high a temperature as possible in order to obtain optimal conditions for iron diffusion in the coating layer; the cycle thus produced approaches the ideal cycle called "square".

On connaít déjà, notamment par la publication EP-A-0 395 759, un dispositif à double jet pour produire une bande d'acier revêtu de zinc par immersion, présentant un fleurage minimum, qui comprend une enceinte équipée de gicleurs à brouillard eau/air et présentant un orifice d'entrée et un orifice de sortie pour la bande d'acier.Already known, in particular by publication EP-A-0 395 759, a double device jet to produce a steel strip coated with zinc by immersion, having a minimum flowering, which includes an enclosure equipped with water / air mist nozzles and having an inlet and an outlet for the steel strip.

Le brevet US-A-3.428.023 décrit par ailleurs un dispositif pour déposer un revêtement de zinc sur une bande d'acier en mouvement, et pour refroidir et solidifier ce revêtement au moyen de jets d'eau pulvérisée.US-A-3,428,023 also describes a device for depositing a coating of zinc on a moving steel strip, and to cool and solidify this coating by means of water spray jets.

La présente invention a pour objet un dispositif de refroidissement accéléré de faible longueur, particulièrement apte à être mis en oeuvre pour assurer un refroidissement rapide au moyen de gicleurs à brouillard eau/air d'un substrat revêtu après sortie de ce dernier hors d'un four de maintien à température et avant passage sur des rouleaux de renvoi, notamment dans le cadre du traitement de galvannealing.The present invention relates to an accelerated cooling device of low length, particularly suitable for being used for cooling rapid by means of water / air mist nozzles of a coated substrate after leaving it last out of a temperature maintenance oven and before passing over rollers referral, particularly in the context of galvannealing treatment.

Conformément à la présente invention, un dispositif de refroidissement accéléré d'un substrat continu en défilement rapide dans un plan vertical, formé par une enceinte close comportant un orifice inférieur d'entrée et un orifice supérieur de sortie pour le passage dudit substrat, dans lequel ladite enceinte comprend une zone de refroidissement, dite principale, dotée de moyens d'introduction du fluide de refroidissement sous la forme de rideaux de brouillard eau-air de part et d'autre dudit substrat, une zone de refroidissement, dite secondaire, dotée de moyens favorisant le contact entre le fluide de refroidissement et le substrat, et une zone d'extraction du fluide de refroidissement, et dans lequel lesdits orifices d'entrée et de sortie sont dotés de moyens de retenue du fluide de refroidissement à l'intérieur de l'enceinte, est caractérisé en ce que lesdits rideaux de brouillard sont disposés dans l'espace en formant un angle compris entre 30° et 60° par rapport au sens de mouvement dudit substrat, et en ce que lesdits moyens de retenue du fluide de refroidissement sont constitués par des jets d'air comprimé disposés de part et d'autre dudit substrat et dirigés vers celui-ci, pour empêcher toute sortie de fluide de refroidissement hors de ladite enceinte.According to the present invention, an accelerated cooling device of a continuous substrate moving rapidly in a vertical plane, formed by an enclosure close with a lower inlet and an upper outlet for the passage of said substrate, in which said enclosure comprises a zone of so-called main cooling, provided with means for introducing the cooling in the form of water-air mist curtains on either side of said substrate, a so-called secondary cooling zone provided with means favoring the contact between the coolant and the substrate, and an extraction zone of the coolant, and wherein said inlet and outlet ports are provided means for retaining the coolant inside the enclosure, is characterized in that said fog curtains are arranged in space in forming an angle between 30 ° and 60 ° relative to the direction of movement of said substrate, and in that said means for retaining the coolant are consisting of compressed air jets arranged on either side of said substrate and directed towards it, to prevent any coolant from escaping from said enclosure.

Suivant une réalisation préférentielle du dispositif de refroidissement, ledit angle est compris entre 35° et 40°.According to a preferred embodiment of the cooling device, said angle is between 35 ° and 40 °.

Suivant une autre modalité de réalisation préférentielle du dispositif de refroidissement de l'invention, les moyens pour former un ou plusieurs rideaux de brouillard comprennent des rampes de projection de brouillard, et lesdites rampes de projection sont constituées par deux tubes dont les axes longitudinaux sont parallèles au plan dudit substrat, l'un des deux tubes englobant l'autre et l'un des tubes étant alimenté en eau tandis que l'autre est alimenté en air, ainsi que par des gicleurs alimentés en eau et en air par les deux tubes précités de manière à former lesdits rideaux de brouillard. According to another preferred embodiment of the cooling device of the invention, the means for forming one or more fog curtains comprise fog projection ramps, and said projection ramps consist of two tubes whose longitudinal axes are parallel to the plane of said substrate, one of the two tubes encompassing the other and one of the tubes being supplied with water while the other is supplied with air, as well as by sprinklers supplied with water and in air by the two aforementioned tubes so as to form said mist curtains.

Suivant une autre réalisation préférentielle du dispositif, objet de l'invention, celui-ci comporte des moyens d'aspiration et d'évacuation du fluide de refroidissement hors de l'enceinte close dudit dispositif de refroidissement et préférentiellement lesdits moyens sont situés près de l'extrémité supérieure du dispositif précité.According to another preferred embodiment of the device, object of the invention, it comprises suction and evacuation means coolant outside the closed enclosure of said device cooling and preferably said means are located near of the upper end of the aforementioned device.

Suivant encore une autre modalité de réalisation préférentielle du dispositif de l'invention, les moyens d'évacuation précités comprennent des hottes d'aspiration du brouillard utilisé comme fluide de refroidissement.According to yet another preferred embodiment of the device of the invention, the aforementioned evacuation means include fume extractor hoods used as cooling fluid.

La modalité précédente apporte une solution très efficace aux problèmes techniques posés respectivement, d'une part par la chute d'eau dans le bain de zinc fondu et d'autre part par l'entraínement de fluide de refroidissement hors de l'enceinte et sa mise en contact avec les rouleaux de renvoi supérieurs.The previous modality provides a very effective solution to the problems techniques posed respectively, on the one hand by the waterfall in the bath of molten zinc and secondly by entrainment of fluid cooling outside the enclosure and bringing it into contact with the upper idler rollers.

La description qui suit a trait à une réalisation particulière et sera explicitée en faisant référence aux dessins annexés, dans lesquels

la figure 1
illustre le principe du traitement thermique de galvannealing;
la figure 2
représente une vue globale du dispositif de refroidissement de l'invention.
The description which follows relates to a particular embodiment and will be explained with reference to the appended drawings, in which
figure 1
illustrates the principle of galvannealing heat treatment;
figure 2
shows an overall view of the cooling device of the invention.

Les figures précitées constituent des représentations schématiques dans lesquelles on n'a reproduit que les éléments nécessaires à la bonne compréhension de l'invention.The above figures constitute schematic representations in which we have reproduced only the elements necessary for the proper understanding of the invention.

La figure 1 montre que le substrat 1 passe dans le bain 2 de zinc ou alliage de zinc contenu dans la cuve 3 de galvanisation, quitte cette dernière verticalement après renvoi autour du rouleau 4, passe par un système de guidage à rouleaux 5, subit un essorage au niveau du dispositif d'essorage 6, constitué par des couteaux d'air ayant pour objet de régler l'épaisseur de la couche de revêtement sur le substrat. Ce dernier commence alors une trajectoire ascendante verticale jusqu'au deuxième rouleau de renvoi 7, poursuit une trajectoire horizontale jusqu'au troisième rouleau de renvoi 8, puis redescend en une trajectoire verticale vers une opération ultérieure.FIG. 1 shows that the substrate 1 passes through the bath 2 of zinc or zinc alloy contained in the galvanizing tank 3, leaves this last vertically after return around roller 4, goes through a roller guide system 5, spins at device level wringing 6, consisting of air knives intended to adjust the thickness of the coating layer on the substrate. This last then begins a vertical upward trajectory until the second deflection roller 7, follows a horizontal path up to third deflection roller 8, then descends in a trajectory vertical to a later operation.

Au cours de la trajectoire ascendante entre les rouleaux 4 et 7, le substrat passe dans un court dispositif de chauffage rapide 9, puis un court dispositif 10 d'égalisation de la température, un dispositif beaucoup plus long 11 de maintien à température et enfin dans un court dispositif 12 de refroidissement rapide équipé de rampes à brouillard eau/air.During the upward path between the rollers 4 and 7, the substrate goes through a short rapid heater 9 and then a short temperature equalization device 10, a device much longer 11 holding temperature and finally in a short rapid cooling device 12 equipped with fog ramps water / air.

La figure 2 illustre une modalité de réalisation préférentielle du dispositif 12 de refroidissement rapide d'un substrat revêtu.FIG. 2 illustrates a preferred embodiment of the device 12 for rapidly cooling a coated substrate.

On distingue sur cette figure 2, l'enceinte close 13 englobant le dispositif de refroidissement rapide, le substrat à refroidir 1, l'entrée 14 dotée de barrages 141 d'air comprimé empêchant le fluide de refroidissement de descendre vers le bain de galvanisation, la sortie 15 dotée de barrages 151 à air comprimé empêchant la sortie du fluide de refroidissement vers les rouleaux de renvoi supérieurs, les rampes 16 de projection de brouillard eau/air, ainsi que les dispositifs 161, tels que des déflecteurs, destinés à favoriser le contact entre le substrat et le brouillard et enfin les hottes 17 d'extraction du brouillard hors de l'enceinte définissant le dispositif de refroidissement.We distinguish in this figure 2, the closed enclosure 13 including the rapid cooling device, the substrate to be cooled 1, the inlet 14 with compressed air barriers 141 preventing the coolant go down to the galvanizing bath, outlet 15 with air dams 151 preventing coolant from escaping towards the upper deflection rollers, the projection ramps 16 water / air mist, as well as devices 161, such as deflectors, intended to promote contact between the substrate and the fog and finally the hoods 17 for extracting the fog out of the enclosure defining the cooling device.

Il va de soi que la description ci-dessus est volontairement limitée à un domaine particulier tel que le galvannealing, mais il n'en reste pas moins vrai que la présente demande de brevet vise à couvrir toute mise en oeuvre du dispositif de refroidissement revendiqué et ce indépendamment de modalités d'application, comme par exemple la nature du fluide de refroidissement utilisé.It goes without saying that the above description is voluntarily limited to a particular field such as galvannealing, but there is none left less true that the present patent application aims to cover any stake using the claimed cooling device independently application methods, such as the nature of the fluid used.

Claims (3)

  1. Accelerated cooling device for a continuous quick-running substrate in a vertical plane, formed with a closed enclosure comprising a lower inlet orifice and an upper outlet orifice for the passage of said substrate, wherein said enclosure comprises a so-called primary cooling zone provided with cooling fluid introducing means as water-air mist curtains on either side of said substrate, a so-called secundary cooling zone provided with means favoring a contact between the cooling fluid and the substrate, and a cooling fluid extracting zone, and wherein said inlet and outlet orifices are provided with cooling fluid retaining means inside the enclosure, characterized in that said mist curtains are spatially arranged by forming an angle comprised between 30° and 60° with respect to the movement direction of said substrate, and in that said cooling fluid retaining means are formed by pressurized air jets arranged on either side of said substrate and oriented towards it, to prevent any output of cooling fluid out of said enclosure.
  2. Cooling device according to claim 1, characterized in that said angle is comprised between 35° and 40°.
  3. Cooling device according to claim 1 or 2, characterized in that the means to form one or more mist curtains comprise mist-projecting ramps and in that said projecting ramps are formed by two tubes the longitudinal axes of which are parallel to the plane of said substrate, one of the two tubes enclosing the other one and one of the tubes being fed with water, whereas the other one is fed with air, as well as by nozzles fed with water and air by both above-mentioned tubes so as to form, said mist curtains.
EP95932579A 1994-10-26 1995-09-27 Device for the accelerated cooling of a fast-moving continuous substrate in a vertical plane Expired - Lifetime EP0731853B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
BE9400973A BE1008792A6 (en) 1994-10-26 1994-10-26 Accelerated cooling device substrate scroll continuous fast in a vertical plane.
BE9400973 1994-10-26
PCT/BE1995/000089 WO1996013619A1 (en) 1994-10-26 1995-09-27 Device for the accelerated cooling of a fast-moving continuous substrate in a vertical plane

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EP0731853A1 EP0731853A1 (en) 1996-09-18
EP0731853B1 true EP0731853B1 (en) 1999-08-11

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EP (1) EP0731853B1 (en)
JP (1) JPH09507533A (en)
BE (1) BE1008792A6 (en)
DE (1) DE69511372T2 (en)
WO (1) WO1996013619A1 (en)

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Publication number Priority date Publication date Assignee Title
US20100266783A1 (en) * 2009-04-15 2010-10-21 Hot Dip Solutions, Llc Method of coating a substrate

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3428023A (en) * 1964-07-02 1969-02-18 Dominion Foundries & Steel Quenching zinc metal coatings with atomised water spray
US3782326A (en) * 1971-03-16 1974-01-01 Australian Wire Ind Pty Primary water quench
US3853306A (en) * 1971-12-28 1974-12-10 Bethlehem Steel Corp Apparatus for quenching molten coatings
JPS5856029B2 (en) * 1979-12-11 1983-12-13 新日本製鐵株式会社 strip cooling system
US4367597A (en) * 1979-12-13 1983-01-11 Nippon Steel Corporation Gas-liquid cooling apparatus
US4407487A (en) * 1980-01-15 1983-10-04 Heurtey Metallurgie Device for cooling metal articles
US4361448A (en) * 1981-05-27 1982-11-30 Ra-Shipping Ltd. Oy Method for producing dual-phase and zinc-aluminum coated steels from plain low carbon steels
JPS5967323A (en) * 1982-10-07 1984-04-17 Nippon Steel Corp Cooler of steel strip
CA1328166C (en) * 1988-09-29 1994-04-05 Hidekazu Kawano Two-fluid injection apparatus and a manufacturing apparatus including such injecting apparatus for manufacturing minimized spangle molten plated steel plate

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DE69511372D1 (en) 1999-09-16
BE1008792A6 (en) 1996-08-06
WO1996013619A1 (en) 1996-05-09
JPH09507533A (en) 1997-07-29
US5843367A (en) 1998-12-01
DE69511372T2 (en) 2000-05-11
EP0731853A1 (en) 1996-09-18

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