EP0726974A1 - Process for manufacturing cellulose moulded bodies - Google Patents
Process for manufacturing cellulose moulded bodiesInfo
- Publication number
- EP0726974A1 EP0726974A1 EP95928881A EP95928881A EP0726974A1 EP 0726974 A1 EP0726974 A1 EP 0726974A1 EP 95928881 A EP95928881 A EP 95928881A EP 95928881 A EP95928881 A EP 95928881A EP 0726974 A1 EP0726974 A1 EP 0726974A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- amine oxide
- tertiary amine
- cellulose
- fibers
- aqueous solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 19
- 229920002678 cellulose Polymers 0.000 title claims abstract description 17
- 239000001913 cellulose Substances 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 8
- 150000003512 tertiary amines Chemical class 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003125 aqueous solvent Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 5
- 238000007493 shaping process Methods 0.000 claims abstract 2
- 239000002904 solvent Substances 0.000 claims abstract 2
- 238000001556 precipitation Methods 0.000 claims description 5
- 229920000151 polyglycol Polymers 0.000 claims description 4
- 239000010695 polyglycol Substances 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
- -1 glycol ethers Chemical class 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- 206010061592 cardiac fibrillation Diseases 0.000 abstract description 18
- 230000002600 fibrillogenic effect Effects 0.000 abstract description 17
- 230000001172 regenerating effect Effects 0.000 abstract 2
- 239000000835 fiber Substances 0.000 description 29
- 238000009987 spinning Methods 0.000 description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 8
- 239000000126 substance Substances 0.000 description 6
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 229920000433 Lyocell Polymers 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 238000001891 gel spinning Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
Definitions
- the invention relates to a process for the production of cellulosic shaped articles, e.g. Fibers according to the preamble of claim 1.
- NMMO N-methyl-moipholin-N-oxide
- EP-A 553 070 Processes for producing cellulosic shaped articles from a solution of cellulose in a mixture of NMMO and water are e.g. in U.S. Patent 4,246,221. The fibers produced in this way are distinguished by a high fiber strength in the conditioned and in the wet state, a high wet modulus and a high loop strength.
- a special property of these fibers is their high tendency to fibrillation, especially under stress when wet, e.g. during a washing process. While this property is desirable for certain applications of the fibers and gives interesting effects, the usability for other purposes, e.g. Textiles that are said to be wash-resistant are reduced.
- REPLACEMENT BLA ⁇ (RULE 26) According to EP-A-538 977, the fibers, which can be freshly spun or have already been dried, are treated with an aqueous system which contains a chemical reagent with 2 to 6 functional groups which can react with cellulose.
- cellulosic fibers are spun from a solution in a tertiary amine oxide into an aqueous coagulation bath.
- SU-1 224362 A describes a process for the production of cellulose fibers with a spinning bath, which is characterized in that it has the aim of increasing the elongation at break, reducing the shrinkage at elevated temperatures and maintaining the elongation in the wet state contains, inter alia, isopropanol or isobutanol or mixtures of the two with 5-40% NMMO and 0.8-10% water.
- isoamyl alcohol is also given in an example.
- REPLACEMENT BLA ⁇ (RULE 26) Kuuchikhin VG, Khim. Volokna (1989) No. 4, p. 33 and Romanov VV and Sokira AN, Khim. Volokna (1988) No. 1, p. 27 describe the use of isopropanol and isobutanol in the spinning bath.
- the fibrillation behavior of the spun fibers improves significantly if substances are used in the spinning bath which have a higher molecular weight than the amine oxide used.
- the spinning bath essentially consists of these substances, i.e. that small amounts of additives may also be present in the spinning bath. It is also possible to add small amounts of up to 10% of tertiary amine oxide or water to the spin bath without restricting the effect according to the invention of using non-aqueous solvents for the amine oxide.
- glycols, glycol ethers, polyglycols and polyglycol ethers are outstandingly suitable as substances used for the process according to the invention.
- the process according to the invention can be used in a particularly advantageous manner if the tertiary amine oxide used is N-methylmorpholine-N-oxide.
- REPLACEMENT BLA ⁇ (RULE 26) All known compositions are suitable as spinning solutions for the process according to the invention.
- the pulp concentration in the dope can vary between 5 and 25. However, cellulose contents between 10 and 18% are preferred.
- the device consists of a heated, temperature-controlled cylinder into which the spinning mass is filled. By means of a piston, the propulsion of which is controlled by a motor, the spinning mass is extruded through the spinneret attached to the underside of the cylinder.
- a dry-wet spinning process that is to say the filament is immersed in a spinning bath (20 cm bath length in water) after the air gap given in the examples and is drawn off using a godet .
- the friction of the fibers against one another during washing processes or during finishing processes in the wet state was simulated by the following text: 8 fibers were placed in a 20 ml sample vial with 4 ml water and in a laboratory shaker type RO-1 from Gerhardt for 9 hours, Bonn (FRG) shaken at level 12. The fibrillation behavior of the fibers was then assessed under the microscope by counting the number of fibrils per 0.276 mm fiber length and is given in a splice rating from 0 (no fibrils) to 6 (strong fibrillation).
- the output has no significant influence on the fibrillation behavior of the fibers.
- this makes it possible to produce low-fibrillation fibers even at higher ejection rates (e.g. 0.1 g / hole / min), which enables a more economical process.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT1695/94 | 1994-09-05 | ||
AT0169594A AT401063B (en) | 1994-09-05 | 1994-09-05 | METHOD FOR PRODUCING CELLULOSIC SHAPED BODIES |
PCT/AT1995/000174 WO1996007779A1 (en) | 1994-09-05 | 1995-09-04 | Process for manufacturing cellulose moulded bodies |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0726974A1 true EP0726974A1 (en) | 1996-08-21 |
EP0726974B1 EP0726974B1 (en) | 1998-06-17 |
Family
ID=3518999
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95928881A Expired - Lifetime EP0726974B1 (en) | 1994-09-05 | 1995-09-04 | Process for manufacturing cellulose moulded bodies |
Country Status (12)
Country | Link |
---|---|
US (1) | US5827463A (en) |
EP (1) | EP0726974B1 (en) |
JP (1) | JPH09505120A (en) |
CN (1) | CN1135242A (en) |
AT (2) | AT401063B (en) |
AU (1) | AU693589B2 (en) |
BR (1) | BR9506355A (en) |
CA (1) | CA2175462A1 (en) |
DE (1) | DE59502591D1 (en) |
FI (1) | FI961903A (en) |
NO (1) | NO961782D0 (en) |
WO (1) | WO1996007779A1 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4446491C2 (en) * | 1994-12-23 | 2000-06-15 | Fraunhofer Ges Forschung | Process for the production of cellulose fibers and cellulose fibers with reduced tendency to fibrillate |
AT404032B (en) * | 1996-03-04 | 1998-07-27 | Chemiefaser Lenzing Ag | METHOD FOR PRODUCING CELLULOSIC FIBERS |
SE509894C2 (en) | 1996-08-27 | 1999-03-15 | Akzo Nobel Surface Chem | Use of a Linear Synthetic Polymer to Improve the Properties of a Cellulose Form Body Made by a Tertiary Amine Oxide Process |
EP0853146A3 (en) * | 1997-01-09 | 1999-03-24 | Akzo Nobel N.V. | Method of producing cellulosic fibres and cellulosic fibres |
DE10019660B4 (en) * | 2000-04-20 | 2004-04-29 | Zimmer Ag | Process for spinning a spinning solution and spinning head |
AT410319B (en) * | 2001-07-25 | 2003-03-25 | Chemiefaser Lenzing Ag | CELLULOSE SPONGE AND METHOD FOR THE PRODUCTION THEREOF |
DE10137171A1 (en) * | 2001-07-31 | 2003-02-13 | Stockhausen Chem Fab Gmbh | Preparation of celluosic shaped bodies having superabsorber properties useful for production of disposable diapers, tampons, bandages, incontinence articles, moisture absorbers, clothing, filters, and packaging materials |
AT502743B1 (en) * | 2005-08-26 | 2008-06-15 | Chemiefaser Lenzing Ag | CELLULOSIC FORM BODY, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF |
DE102006022009B3 (en) * | 2006-05-10 | 2007-12-06 | Thüringisches Institut für Textil- und Kunststoff-Forschung e.V. | Process for producing cellulosic multicomponent fibers |
TWI667378B (en) | 2014-01-03 | 2019-08-01 | 奧地利商蘭精股份有限公司 | Cellulosic fibre |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT134893B (en) * | 1931-11-07 | 1933-10-10 | Warszawska Spolka Akcyjna Budo | Crankless motor compressor with two counter-rotating free-flight pistons. |
US4246221A (en) * | 1979-03-02 | 1981-01-20 | Akzona Incorporated | Process for shaped cellulose article prepared from a solution containing cellulose dissolved in a tertiary amine N-oxide solvent |
IT1194603B (en) * | 1979-12-21 | 1988-09-22 | Snia Viscosa | PROCEDURE FOR THE PREPARATION OF BODIES FORMED OF CELLULOSE REGENERATED FROM SOLUTIONS OF CELLULOSE DERIVATIVES IN ORGANIC SOLVENTS |
DD218121A1 (en) * | 1983-10-17 | 1985-01-30 | Chemiefaser Komb Schwarza Wilh | PROCESS FOR PREPARING FORM BODIES FROM CELLULOSE SOLUTIONS |
SU1224362A1 (en) * | 1984-06-29 | 1986-04-15 | Предприятие П/Я А-3844 | Method of producing cellulose fibres |
GB9022175D0 (en) * | 1990-10-12 | 1990-11-28 | Courtaulds Plc | Treatment of fibres |
GB9122318D0 (en) * | 1991-10-21 | 1991-12-04 | Courtaulds Plc | Treatment of elongate members |
AT396930B (en) * | 1992-01-23 | 1993-12-27 | Chemiefaser Lenzing Ag | AMINOXIDE |
GB9222059D0 (en) * | 1992-10-21 | 1992-12-02 | Courtaulds Plc | Fibre treatment |
GB9304887D0 (en) * | 1993-03-10 | 1993-04-28 | Courtaulds Plc | Fibre treatment |
-
1994
- 1994-09-05 AT AT0169594A patent/AT401063B/en not_active IP Right Cessation
-
1995
- 1995-09-04 WO PCT/AT1995/000174 patent/WO1996007779A1/en active IP Right Grant
- 1995-09-04 JP JP8509026A patent/JPH09505120A/en active Pending
- 1995-09-04 AT AT95928881T patent/ATE167533T1/en not_active IP Right Cessation
- 1995-09-04 DE DE59502591T patent/DE59502591D1/en not_active Expired - Fee Related
- 1995-09-04 AU AU32462/95A patent/AU693589B2/en not_active Ceased
- 1995-09-04 CA CA002175462A patent/CA2175462A1/en not_active Abandoned
- 1995-09-04 CN CN95190855.3A patent/CN1135242A/en active Pending
- 1995-09-04 EP EP95928881A patent/EP0726974B1/en not_active Expired - Lifetime
- 1995-09-04 US US08/633,754 patent/US5827463A/en not_active Expired - Fee Related
- 1995-09-04 BR BR9506355A patent/BR9506355A/en not_active Application Discontinuation
-
1996
- 1996-05-02 NO NO961782A patent/NO961782D0/en unknown
- 1996-05-03 FI FI961903A patent/FI961903A/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9607779A1 * |
Also Published As
Publication number | Publication date |
---|---|
BR9506355A (en) | 1997-09-16 |
EP0726974B1 (en) | 1998-06-17 |
NO961782L (en) | 1996-05-02 |
FI961903A0 (en) | 1996-05-03 |
FI961903A (en) | 1996-05-03 |
WO1996007779A1 (en) | 1996-03-14 |
US5827463A (en) | 1998-10-27 |
AT401063B (en) | 1996-06-25 |
CA2175462A1 (en) | 1996-03-14 |
JPH09505120A (en) | 1997-05-20 |
DE59502591D1 (en) | 1998-07-23 |
CN1135242A (en) | 1996-11-06 |
ATE167533T1 (en) | 1998-07-15 |
NO961782D0 (en) | 1996-05-02 |
ATA169594A (en) | 1995-10-15 |
AU3246295A (en) | 1996-03-27 |
AU693589B2 (en) | 1998-07-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE69723582T2 (en) | REGENERATED CELLULOSE FIBERS AND METHOD FOR THEIR PRODUCTION | |
AT514474B1 (en) | Polysaccharide fiber and process for its preparation | |
EP0659219B1 (en) | Cellulose fibres | |
EP3011085B1 (en) | Polysaccharide fibres and method for producing same | |
DE4444140A1 (en) | Solvent-spun cellulosic filaments | |
EP0494852A2 (en) | Process for the production of cellulosic articles | |
AT401393B (en) | METHOD FOR PRODUCING CELLULOSE FIBERS | |
EP0686712B1 (en) | Flexible cellulosic fibers with reduced modulus and NMR-characteristics and process for their production | |
EP0823945B1 (en) | Process for the manufacture of cellulose fibres | |
EP0683827B1 (en) | Process for producing shaped cellulose bodies | |
DE102013002833B4 (en) | A process for the production of regenerated cellulose fibers and the use of regenerated cellulose fibers produced by the process | |
DE202013011959U1 (en) | Direct-spun cellulose fibers, their preparation and use | |
EP0726974B1 (en) | Process for manufacturing cellulose moulded bodies | |
EP3414374A1 (en) | Method for producing carbon fibres from cellulose fibres treated with sulphonic acid salts | |
EP0918894B1 (en) | Method for producing cellulose fibres | |
EP0918798B1 (en) | Method for the production of cellulosic shaped bodies | |
EP0984084B1 (en) | Process for manufacturing cellulosic fibres | |
EP0918893B1 (en) | Cellulose microfibre | |
EP1299583B1 (en) | Method for producing cellulose fibres |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19960502 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE |
|
AX | Request for extension of the european patent |
Free format text: LT PAYMENT 960429;LV PAYMENT 960429;SI PAYMENT 960429 |
|
RAX | Requested extension states of the european patent have changed |
Free format text: LT PAYMENT 960429;LV PAYMENT 960429;SI PAYMENT 960429 |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
17Q | First examination report despatched |
Effective date: 19970825 |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE |
|
AX | Request for extension of the european patent |
Free format text: LT PAYMENT 960429;LV PAYMENT 960429;SI PAYMENT 960429 |
|
LTIE | Lt: invalidation of european patent or patent extension | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 19980617 Ref country code: ES Free format text: THE PATENT HAS BEEN ANNULLED BY A DECISION OF A NATIONAL AUTHORITY Effective date: 19980617 |
|
REF | Corresponds to: |
Ref document number: 167533 Country of ref document: AT Date of ref document: 19980715 Kind code of ref document: T |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REF | Corresponds to: |
Ref document number: 59502591 Country of ref document: DE Date of ref document: 19980723 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 19980807 Year of fee payment: 4 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 19980821 Year of fee payment: 4 Ref country code: DE Payment date: 19980821 Year of fee payment: 4 |
|
ITF | It: translation for a ep patent filed | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19980904 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 19980908 Year of fee payment: 4 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 19980917 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 19980917 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 19980917 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: GERMAN |
|
GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 19980911 |
|
ET | Fr: translation filed | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19990219 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FD4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19990331 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19990904 Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19990904 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19990930 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19990930 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19990930 |
|
BERE | Be: lapsed |
Owner name: LENZING A.G. Effective date: 19990930 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000401 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 19990904 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000531 |
|
NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee |
Effective date: 20000401 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000701 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED. Effective date: 20050904 |