EP0714497A1 - Process and device for removing and oxidising organic components from kitchen fumes - Google Patents
Process and device for removing and oxidising organic components from kitchen fumesInfo
- Publication number
- EP0714497A1 EP0714497A1 EP94926872A EP94926872A EP0714497A1 EP 0714497 A1 EP0714497 A1 EP 0714497A1 EP 94926872 A EP94926872 A EP 94926872A EP 94926872 A EP94926872 A EP 94926872A EP 0714497 A1 EP0714497 A1 EP 0714497A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- filter
- catalyst
- exhaust air
- organic components
- heated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 19
- 239000003517 fume Substances 0.000 title claims abstract description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 39
- 230000003197 catalytic effect Effects 0.000 claims description 28
- 238000010438 heat treatment Methods 0.000 claims description 23
- 239000000470 constituent Substances 0.000 claims description 22
- 238000003795 desorption Methods 0.000 claims description 17
- 239000010457 zeolite Substances 0.000 claims description 17
- 230000003647 oxidation Effects 0.000 claims description 15
- 238000007254 oxidation reaction Methods 0.000 claims description 15
- 238000001179 sorption measurement Methods 0.000 claims description 11
- 230000001590 oxidative effect Effects 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 238000006555 catalytic reaction Methods 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 3
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 abstract description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 238000011144 upstream manufacturing Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000019219 chocolate Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C15/00—Details
- F24C15/20—Removing cooking fumes
- F24C15/2042—Devices for removing cooking fumes structurally associated with a cooking range e.g. downdraft
- F24C15/205—Devices for removing cooking fumes structurally associated with a cooking range e.g. downdraft with means for oxidation of cooking fumes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S55/00—Gas separation
- Y10S55/36—Kitchen hoods
Definitions
- the invention relates to a method and a device for removing and oxidizing organic components of kitchen fumes from an exhaust air flow using a fan producing the exhaust air flow in an exhaust air duct, a filter adsorbing the organic components and a catalytic oxidation of the organic components performing heated catalyst.
- a device is known from German Offenlegungsschrift 23 63 820, which has a heated catalyst behind a filter and a fan, through which the exhaust air loaded with organic components is passed immediately after the pre-filtering for catalytic oxidation of the organic components.
- the disadvantage of this device is that the catalytic converter must be continuously heated as long as the fan is in operation and supplies it with polluted exhaust air.
- catalysts In order to To be sam, catalysts generally have a large specific surface, which additionally leads to an energy transfer to the exhaust air flowing through them, in particular in the case of exhaust air mixed with water vapor. The expenditure of energy and the associated costs for keeping the catalytic converter constantly at operating temperature are correspondingly high.
- the organic constituents which are generally only present in a relatively low concentration in the exhaust air flow, can only make an insignificant contribution to the heating of the catalyst due to their exothermic catalytic oxidation due to the high exhaust air volume flow accompanying them.
- the invention is therefore based on the object
- the filter is regenerated by supplying heat and the catalyst is only heated for a limited time and is therefore heated in an energy-saving manner for the catalytic oxidation of the organic constituents.
- This is possible due to the fact that the organic components of the kitchen vapors are not constantly subjected to catalysis as opposed to the state of the art, but are first adsorbed and temporarily stored by the filter and from time to time reacted on the heated catalyst organic components from the filter - if it is in front of the catalyst - are desorbed by heating.
- the desorption phase is carried out at the latest when the filter is saturated with organic components.
- the catalytic oxidation of the organic constituents then also takes place, preferably when the kitchen is shut down, for example at night.
- the catalytic oxidation of the organic constituents previously adsorbed and enriched in a filter takes significantly less time and energy as a result of the more concentrated conversion one which, as in the prior art, is operated continuously during the supply of organic constituents by the exhaust air stream, etc.
- zeolites have a particularly high adsorption capacity, in particular for gaseous substances.
- zeolites When filtering exhaust air containing kitchen vapors, zeolites are advantageously suitable which have hydrophobic properties and therefore selectively adsorb the organic components of the kitchen vapors, but not water vapor adhering to the kitchen vapors.
- Zeolites can be in the form of a powder bed, a bed of granules or a monolithic body.
- Granulate beds are preferably used because they have better flow-through properties than the powder bed and are cheaper to produce than the monolithic body.
- a special property of the Zeo- lithe is their reversible adsorption capacity, ie they release the previously adsorbed organic components when the temperature rises.
- the desorption temperature depends on the one hand on the characteristic properties of the zeolite, in particular on its optionally modified surface properties and on the nature of the adsorbed organic constituents themselves. Suitable desorption temperatures are in the range from 150 ° C. to 300 ° C., a higher temperature leading to an advantageously high desorption rate, but the upper limit of the desorption temperature has to be limited in order to avoid undesired carburization, which increases the regeneration capacity of the zeolite and would affect the filter.
- Zeolites or filters which, as described above, desorb the organic constituents when heat is added are referred to below as “desorbing zeolites” or “desorbing filters”.
- zeolites has the advantage, compared to the adsorption filters made of activated carbon or non-woven mat, which are difficult to desorb, which are otherwise used in kitchens, that they can be subjected to higher thermal loads.
- ERSA ⁇ ZBLA ⁇ T (RULE 26)
- zeolites catalytically active substances which oxidize the organic constituents with the addition of oxygen, in particular with noble metal salts.
- the catalytic effect of the zeolite and thus of the filter is activated by the application of heat.
- the organic constituents are catalytically oxidized in the presence of oxygen without first being desorbed.
- the previously adsorbing zeolite is expediently operated as a catalyst at temperatures of 200 ° C. to 900 ° C. Preferably in the range of 200 ° C to 450 ° C.
- Filters and zeolites which catalytically oxidize the previously absorbed organic constituents with the addition of heat are hereinafter referred to as "oxidizing zeolites" or "oxidizing filters”.
- the filter can be heated in many ways.
- the filter can be heated directly, in particular by means of an electrical heating device.
- the filter itself can also be designed as a heat exchanger, for example according to the cross-flow principle, in order to be able to use any waste heat that may be used to heat the filter.
- the filter can be heated indirectly by, for example, connecting a heating device upstream of it, which heats the exhaust air flow before it enters the filter.
- the heating device device can, for example, in turn be operated electrically or be designed as a heat exchanger.
- inventive method according to claim 1 and the inventive device according to claim 9 are characterized in that a "desorbable filter", in particular a zeolite, is used as the filter and the catalytic oxidation is carried out in a separate but fluidically connected and heated catalyst.
- a "desorbable filter” in particular a zeolite
- the conditions for the catalytic oxidation of the organic constituents are the same as for the oxidizing filter.
- the filter is at the same time catalyst, as previously described for the "oxidizing zeolite". This reduces the number of components and the device can be made more compact overall.
- the advantage of the device according to claim 9, with the catalyst separated from the "desorbing filter”, is that the catalyst can be assigned, for example, to several filters during which the desorption phases are shifted simultaneously or at different times. This would be particularly advantageous for canteen kitchens or large systems with several suction points for organically contaminated vapors.
- a catalyst separated from the filter can be arranged in a branch line which is not flowed through in the adsorption phase, so that the catalyst is not loaded in the adsorption phase, in particular not with water vapor.
- the catalytic converter arranged downstream of the desorbing filter can be heated directly or indirectly via a heating device, the type of heating preferably being electric.
- Heating devices of the "desorbing filter” and the downstream catalytic converter according to claim 9 and the “oxidizing filter” according to claim 10 of the present invention can be switched by switching devices assigned to them independently of the fan assigned to them and generating the exhaust air flow, so that they can be actuated earlier when the filter reaches saturation or as required.
- the heating devices of the "desorbing filter” and the downstream catalytic converter according to claim 9 can also be designed as a common heating device or have a common switching device, since the desorption and the catalytic oxidation take place almost simultaneously in the catalyst downstream of the filter . Certain circuitry precautions can be taken to ensure that the catalytic converter is heated to its operating temperature immediately before the filter is heated and the desorption is started.
- the catalyst of the device according to the invention according to claim 9 is not heated state during the adsorption phase with condensed water, it is only in the heated state, preferably only in the desorption phase, exposed to the exhaust air stream leaving the filter.
- This is advantageously achieved by the fact that the catalyst is bypassed by a bypass and shut-off devices in the bypass and / or through the bypass to the bridging portion of the Abluft ⁇ channel, .with the catalyst are provided, and are examples of playing designed as controllable valves.
- the heat stored in the gaseous carrier medium after the catalytic oxidation of the organic constituents can at least partially be supplied to the desorption process or the catalysis. This can be done, for example, in such a way that the heated exhaust air is fed to the filter, which may be designed as a cross-flow heat exchanger, or to a heat exchanger which is connected upstream of the filter and which is intended to heat the exhaust air supplied to the filter. It is also possible that part of the exhaust air exiting and heated from the catalytic converter is mixed with the colder exhaust air entering the filter in order to heat it up, but a minimum oxygen content in the exhaust air supplied to the filter must not be undercut, since otherwise the following
- FIG. 1 shows the block diagram of a device for removing and oxidizing organic constituents 1 of kitchen vapors in the adsorption phase
- FIG. 2 shows the block diagram of the device from FIG. 1 in the phase of desorption and catalysis
- FIG. 3 shows the block diagram of the device from FIG. 1 at the end of the desorption phase.
- the device consists of a filter 2, a catalytic converter 3 and a fan 4, which generates an exhaust air flow 5, the filter 2, the catalytic converter 3 and the fan 4 being arranged downstream in terms of flow and connected via the exhaust air duct.
- the exhaust air duct 6 branches upstream of the catalytic converter 3 into a bypass 7,
- a first controllable shut-off device 8 is arranged in the bypass 7. In the part of the exhaust air duct 6 bridged by the bypass 7, a second controllable shut-off device 9 is provided in front of the catalytic converter 3.
- a heating device 10 or 11 is integrated in the filter 2 or the catalyst 3 and can be switched independently of one another and independently of the fan 4. In the adsorption phase (FIG. 1), the shut-off device 8 is open and the shut-off device 9 is closed, so that the exhaust air stream 5 is directed past the catalyst 3.
- the heating devices 10 and 11 are switched off and the filter 2 and the catalytic converter 3 are at a low temperature T Q , where T Q is less than 100 ° C.
- the organic components 1 located in the exhaust air stream 5 adsorb in the filter 2.
- the exhaust air cleaned in this way is drawn off via the bypass.
- the catalyst 3 is heated to its operating temperature T 1 (for example 350 ° C.) by means of the second electrical heating device 11. As soon as it reaches this temperature, the second shut-off device
- the first heating device 10 and the second heating device 11 are switched off again, the first shut-off device 8 is opened again and the second shut-off device 9 is closed again .
- the filter 2 is now in a regenerated form and, after cooling to T Q, can again adsorb new organic constituents 1 from the exhaust air stream 5.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4328405 | 1993-08-24 | ||
DE4328405A DE4328405A1 (en) | 1993-08-24 | 1993-08-24 | Method and device for removing and oxidizing organic components from kitchen fumes |
PCT/EP1994/002796 WO1995006227A1 (en) | 1993-08-24 | 1994-08-24 | Process and device for removing and oxidising organic components from kitchen fumes |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0714497A1 true EP0714497A1 (en) | 1996-06-05 |
EP0714497B1 EP0714497B1 (en) | 1999-07-28 |
Family
ID=6495873
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94926872A Expired - Lifetime EP0714497B1 (en) | 1993-08-24 | 1994-08-24 | Use of a hydrophobic filter in a process for removing and oxidising organic components from kitchen fumes |
Country Status (4)
Country | Link |
---|---|
US (1) | US5858316A (en) |
EP (1) | EP0714497B1 (en) |
DE (2) | DE4328405A1 (en) |
WO (1) | WO1995006227A1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19730292C1 (en) * | 1997-07-15 | 1999-03-11 | Daimler Benz Ag | Plant for the removal of gaseous organic substances from the air |
US7094388B2 (en) * | 2000-04-21 | 2006-08-22 | Dte Energy Technologies, Inc. | Volatile organic compound abatement through a fuel cell |
FR2886869B1 (en) * | 2005-06-14 | 2007-08-31 | Saint Gobain Ct Recherches | STRUCTURE AND CATALYTIC FILTER FOR FILTERING GAS COMPRISING HYDROPHOBIC OR OLEOPHOBIC CEMENT |
EP2893967A1 (en) * | 2014-01-10 | 2015-07-15 | Berbel Ablufttechnik Gmbh | Device and method for elimination of odours |
CN104728893A (en) * | 2015-03-30 | 2015-06-24 | 宁波博业环保科技有限公司 | Oil fume treating system for kitchen |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2658742A (en) * | 1950-01-09 | 1953-11-10 | Harold R Suter | Catalytic fume incineration |
GB1206829A (en) * | 1968-01-26 | 1970-09-30 | Carr Fastener Co Ltd | Means for cleaning air or gases in domestic cooking ovens |
DE2363820C3 (en) * | 1973-12-21 | 1980-02-21 | Licentia-Patent-Verwaltungs-Gmbh, 6000 Frankfurt | Kitchen vapor filter device |
JPS5096178A (en) * | 1973-12-24 | 1975-07-31 | ||
US4235220A (en) * | 1979-06-07 | 1980-11-25 | Hepner Robert J | Cooking stove exhaust air filtration system |
DE3447481A1 (en) * | 1984-12-27 | 1986-07-03 | Küppersbusch AG, 4650 Gelsenkirchen | Roasting oven with automatic removal of odorous and dirtying particles in the roasting oven air |
DE3636250A1 (en) * | 1986-10-24 | 1988-04-28 | Josef Dr Muschawek | Process and apparatus for eliminating gaseous impurities from a crude gas |
DE3715598A1 (en) * | 1987-05-09 | 1988-11-24 | Licentia Gmbh | Cooking stove with heat self-cleaning - has main and auxiliary fume flues with shutter and afterburner |
JPH0615016B2 (en) * | 1988-09-09 | 1994-03-02 | トヨタ自動車株式会社 | Automotive exhaust gas purification device |
JPH03141816A (en) * | 1989-10-27 | 1991-06-17 | Toyota Motor Corp | Exhaust gas purifier |
DE4142336A1 (en) * | 1991-12-20 | 1993-06-24 | Bosch Siemens Hausgeraete | Vapour duct for domestic oven with catalytic afterburner - which allows burning of combustible vapours and neutralisation of odours at entrance to fume extn. chimney |
-
1993
- 1993-08-24 DE DE4328405A patent/DE4328405A1/en not_active Withdrawn
-
1994
- 1994-08-24 US US08/596,377 patent/US5858316A/en not_active Expired - Lifetime
- 1994-08-24 DE DE59408549T patent/DE59408549D1/en not_active Expired - Lifetime
- 1994-08-24 EP EP94926872A patent/EP0714497B1/en not_active Expired - Lifetime
- 1994-08-24 WO PCT/EP1994/002796 patent/WO1995006227A1/en active IP Right Grant
Non-Patent Citations (1)
Title |
---|
See references of WO9506227A1 * |
Also Published As
Publication number | Publication date |
---|---|
US5858316A (en) | 1999-01-12 |
WO1995006227A1 (en) | 1995-03-02 |
DE4328405A1 (en) | 1995-03-02 |
EP0714497B1 (en) | 1999-07-28 |
DE59408549D1 (en) | 1999-09-02 |
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