EP0707623A1 - Lubricating oil composition - Google Patents
Lubricating oil compositionInfo
- Publication number
- EP0707623A1 EP0707623A1 EP94918148A EP94918148A EP0707623A1 EP 0707623 A1 EP0707623 A1 EP 0707623A1 EP 94918148 A EP94918148 A EP 94918148A EP 94918148 A EP94918148 A EP 94918148A EP 0707623 A1 EP0707623 A1 EP 0707623A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- carbon atoms
- hydrocarbyl group
- composition
- lubricating oil
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 29
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 28
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 20
- 150000002148 esters Chemical class 0.000 claims abstract description 15
- AVVIDTZRJBSXML-UHFFFAOYSA-L calcium;2-carboxyphenolate;dihydrate Chemical compound O.O.[Ca+2].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O AVVIDTZRJBSXML-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000012990 dithiocarbamate Substances 0.000 claims abstract description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 5
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011733 molybdenum Substances 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 239000003921 oil Substances 0.000 claims description 15
- 239000002199 base oil Substances 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 6
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 229910052717 sulfur Inorganic materials 0.000 claims description 4
- 239000011593 sulfur Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 125000006165 cyclic alkyl group Chemical group 0.000 claims description 3
- -1 phosphorous ester Chemical class 0.000 abstract description 9
- 238000002485 combustion reaction Methods 0.000 description 8
- 230000007935 neutral effect Effects 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 4
- 235000006708 antioxidants Nutrition 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 239000002480 mineral oil Substances 0.000 description 4
- 239000010705 motor oil Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 230000001603 reducing effect Effects 0.000 description 2
- RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 description 1
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical class C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical class C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 150000003939 benzylamines Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- SNCZNSNPXMPCGN-UHFFFAOYSA-N butanediamide Chemical class NC(=O)CCC(N)=O SNCZNSNPXMPCGN-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- KHYKFSXXGRUKRE-UHFFFAOYSA-J molybdenum(4+) tetracarbamodithioate Chemical compound C(N)([S-])=S.[Mo+4].C(N)([S-])=S.C(N)([S-])=S.C(N)([S-])=S KHYKFSXXGRUKRE-UHFFFAOYSA-J 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical class O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
- C10M129/48—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring
- C10M129/54—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring containing hydroxy groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/12—Thio-acids; Thiocyanates; Derivatives thereof
- C10M135/14—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond
- C10M135/18—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond thiocarbamic type, e.g. containing the groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
- C10M137/04—Phosphate esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
- C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
- C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/026—Butene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/024—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings having at least two phenol groups but no condensed ring
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/028—Overbased salts thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C10N2040/28—Rotary engines
Definitions
- the present invention relates to a lubricating oil composi ⁇ tion, in particular, a lubricating oil composition having improved friction reducing properties and suitable for use as a lubricating oil for internal combustion engines, automatic transmissions, suspensions and power steering wheels, particularly as a lubricating oil for internal combustion engines.
- Lubricating oils are usually used for smoothing the working of internal combustion engines, driving mechanisms such as automatic transmissions, suspensions and power stearings, and gears.
- engine oils are effective in lubricating mainly sliding parts such as a piston ring and a cylinder liner, bearings of a crank shaft or a connecting rod, and valve train including cams and valve lifters; in cooling the engine; in cleaning and dispersing combustion products; and in preventing rust formation and corrosion.
- the lubricating oil is used in combination with additives such as a friction modifier (FM) in order to minimize the friction loss and improve the fuel consumption (see, for example, Japanese Patent Publication No. 23595/1991) . Further, since the engine oil for automobiles is used under the various conditions of oil temperature, engine speed and load, more excellent frictional properties under the wide-range conditions of use are necessitated for further improving the fuel consumption.
- FM friction modifier
- the present invention has been completed after investigations made for the purpose of providing a lubricating oil composition having improved friction reducing properties over those of an ordinary lubricating oil containing molybdenum dithiocarbamate and a phosphoric ester, and is suitable for use as a lubricating oil for internal combustion engines, automatic transmissions, suspensions and power steering wheels, particularly as a lubricating oil for internal combustion engines.
- the present invention provides a lubricating oil composition which comprises a base oil containing (A) from 0.01 to 0.8% by weight, based on the whole composition, of at least one compound selected from the group consisting of (a) phosphoric esters of the general formula:
- R-*-, * 2 and R ⁇ may be the same or different and each represents a hydrogen atom or a hydrocarbyl group having 3 to 23 carbon atoms, with the proviso that at least one of R ⁇ to R 3 is a hydrocarbyl group having 3 to 23 carbon atoms, and
- R ⁇ , R5 and R ⁇ may be the same or different and each represents a hydrogen atom or a hydrocarbyl group having 3 to 23 carbon atoms, with the proviso that at least one of ⁇ to R 6 is a hydrocarbyl group having 3 to 23 carbon atoms;
- the base oil usable as the major component in the lubricating oil composition of the present invention is not particularly limited.
- Base oils are those usually used in ordinary lubricating oils, such as mineral oils and synthetic oils.
- the mineral oils include, for example, 60 neutral oil, 100 neutral oil, 150 neutral oil, 300 neutral oil and 500 neutral oil obtained by solvent refining or hydrorefining; and low-pour point base oils prepared by removing a wax from these base oils so as to improve the low-temperature fluidity. They may be used either singly or in the form of a mixture of two or more of them in a proper ratio.
- the synthetic oils include, for example, poly- ⁇ olefin oligomers, diesters, polyol esters and polyglycol esters. They are usable either singly or in the form of a mixture. They are also usable in the form of a mixture with the above-described mineral oil.
- the blending weight ratio of the synthetic oil to the mineral oil is, for example, 80:20 to 20:80.
- a suitable base oil usable in the composition of the present invention is one having a viscosity in the range of 3 to 20 cSt at 100°C. Particularly preferred are hydrocracked products and/or wax isomerized products containing 3.0% by weight or below of an aromatic component and having a sulfur content of 50 ppm or below and a nitrogen content of 50 ppm below.
- the component (A) is at least one compound selected from the group consisting of a (a) phosphoric ester of the general formula:
- R 1 , R 2 and R 3 are each as defined above, and (b) phosphorous esters of the general formula:
- R ⁇ , R 5 and 6 are each as defined above.
- the groups R 1 , R 2 and R 3 in the above general formula [1] may be the same or different and each represents a hydrogen atom or a hydrocarbyl group having 3 to 23 carbon atoms, with the proviso that at least one of R 1 to R 3 is the hydrocarbyl group having 3 to 23 carbon atoms.
- the hydrocarbyl groups having 3 to 23 carbon atoms include linear, branched and cyclic alkyl and alkenyl groups having 3 to 23 carbon atoms, aryl groups having 6 to 23 carbon atoms, alkylaryl groups having 7 to 23 carbon atoms and arylalkyl groups having 7 to 23 carbon atoms.
- Examples include propyl, butyl, pentyl, hexyl, cyclo- hexyl, octyl, decyl, lauryl, myristyl, palmityl, stearyl, oleyl, eicosyl, phenyl, xylyl, benzyl and phenethyl groups.
- the groups R 4 , R 5 and R 6 in the above general formula [2] for the phosphorous esters may be the same or different and each repre ⁇ sents a hydrogen atom or a hydrocarbyl group having 3 to 23 carbon atoms, with the proviso that at least one of R 4 to R 6 is a hydrocarbyl group having 3 to 23 carbon atoms. Examples include those mentioned above with reference to R 1 , R 2 and R 3 in the above general formula [1].
- composition of the present invention may contain phos ⁇ phoric esters either singly or in combination of two or more of them and/or the phosphorous esters either singly or in combination of two or more of them as the component (A) . Further, a combination of one or more of the phosphoric esters with one or more of the phosphorous esters may be also used.
- the composition of the present invention must contain the phosphoric ester and/or phosphorus ester as the component (A) in an amount of 0.01 to 0.8% by weight, preferably 0.05 to 0.5% by weight, based on the whole composition.
- amount of (A) is below 0.01% by weight, no sufficiently low frictional properties can be obtained and, when it exceeds 0.8% by weight, there is no significant further improvement in frictional properties.
- MoDTC sulfurized oxymolybdenum dithiocarbamates
- the groups R 7 and R 8 in the above general formula [3] each represent a hydrocarbyl group having 8 to 18 carbon atoms.
- the hydrocarbyl groups having 8 to 18 carbon atoms include linear and branched alkyl and alkenyl groups having 8 to 18 carbon atoms, and cycloalkyl, aryl, alkylaryl and arylalkyl groups having 8 to 18 carbon atoms. Examples include 2-ethylhexyl, n-octyl, nonyl, decyl, lauryl, tridecyl, palmityl, stearyl, oleyl, eicosyl, butylphenyl and nonyl- phenyl groups.
- R 7 and Ry may t, e the same or different from each other, m and n are positive integers such that the sum of m + n is 4.
- the MoDTC used as component (B) may be used singly or as a combination of two or more of them.
- the amount of MoDTC is in the range of 50 to 2,000 ppm, preferably 100 to 1,000 ppm (in terms of molybdenum) based on the whole composition. When the amount of molybdenum is below 50 ppm, no sufficient friction reduction properties can be obtained and when it is above 2,000 ppm, there is no further significant improvement in the frictional properties.
- a calcium salicylate having a total base number of 10 to 100 is used as the component (C) in the composition of the present inven ⁇ tion.
- the calcium salicylate is, for example, one represented by the following general formula:
- the group R ⁇ in the general formula [4] represents a linear, branched or cyclic alkyl group having 8 to 23 carbon atoms, such as an octyl, nonyl, decyl, dodecyl, pentadecyl, octadecyl or eicosyl group.
- the calcium salicylate used as component (C) may be used either singly or in combination of two or more of them.
- the amount of the calcium salicylate is in the range of 0.3 to 2.5% by weight based on the whole composition. When the amount of (C) is below 0.3% by weight, no sufficient low frictional properties can be obtained and, when the amount exceeds 2.5% by weight, the wear resistance is reduced and the ash content is increased unfavorably.
- the lubricating oil composition of the present invention may contain suitable additives usually incorporated into lubricating oils, such as an ashless detergent-dispersant, viscosity index improver, pour point depressant, antioxidant, rust inhibitor, corrosion inhibitor, antifoaming agent and other antiwear agent and friction modifier, so far as the object of the present invention is not dis ⁇ turbed.
- suitable additives usually incorporated into lubricating oils, such as an ashless detergent-dispersant, viscosity index improver, pour point depressant, antioxidant, rust inhibitor, corrosion inhibitor, antifoaming agent and other antiwear agent and friction modifier, so far as the object of the present invention is not dis ⁇ turbed.
- the ashless detergent-dispersants include, for example, succinimides, succinamides, benzylamines, their boron derivatives and esters. They are used in an amount of usually 0.5 to 7% by weight, based on the whole composition.
- the viscosity index improvers include, for example, poly- methacrylates, polyisobutylenes, ethylene/propylene copolymers and hydrogenated styrene/butadiene copolymers. They are used in an amount of from 0.5 to 35% by weight, based on the whole composition.
- the anti-oxidants include, for example, amine antioxidants such as alkylated diphenylamines, phenyl- ⁇ -naphthylamines and alkylated ⁇ -naphthylamines, and phenolic antioxidants such as 2,6-di-t-butyl-4- methyl-phenol and 4,4'-methylenebis(2,6-di-t-butyl-4-methyl-phenol and 4,4'-methylenebis(2,6-di-t-butylphenyl) . They are used in an amount of usually 0.05 to 2% by weight, based on the whole composition.
- the rust inhibitors include, for example, alkenylsuccinic acids and partial esters thereof.
- the corrosion inhibitors include, for example, benzotriazole and benzimidazole.
- the antifoaming agents include, for example, dimethylpolysiloxanes and polyacrylates. They can be suitably incorporated into the oil composition. The following Examples further illustrate the present inven ⁇ tion and do not limit the invention.
- the coefficient of friction was determined by the LFW-1 test under the conditions of 270 rpm, 30 kgf, 120°C and 10 minutes.
- Base oil 150N-1 (having viscosity at 100°C of 5.7 mm 2 /s, aromatic component content of 4.1 wt%, sulfur content of 11.0 ppm and nitrogen content of 89.0 ppm) or 150N-2 (having viscosity at 100°C of 5.5 mm 2 /s, aromatic component content of 0.5 wt%, sulfur content of 0.5 ppm and nitrogen content of 0.1 ppm) was used.
- a lubricating oil containing the combina ⁇ tion of salicylate, MoDTC and phosphoric ester according to the invention provides a significantly lower coefficient of friction over an oil composition containing any two components.
- the lubricating oil composition of the present invention has superior low frictional properties to those of ordinary lubricating oils comprising MoDTC and a phosphoric ester, and is suitable for use as a lubricating oil for, for example, internal combustion engines, automatic transmissions, suspensions and power steering wheels, particularly as a lubricating oil for internal combustion engines.
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Abstract
A lubricating oil composition containing from 0.01 to 0.8% by weight, based on the whole composition, of a phosphoric ester and/or a phosphorous ester, from 50 to 2,000 ppm (in terms of molybdenum) of sulfurized oxymolybdenum dithiocarbamate having at least one hydrocarbyl group having 8 to 18 carbon atoms and from 0.3 to 2.5% by weight of a calcium salicylate having a total base number of 10 to 100.
Description
LUBRICATING OIL COMPOSITION
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a lubricating oil composi¬ tion, in particular, a lubricating oil composition having improved friction reducing properties and suitable for use as a lubricating oil for internal combustion engines, automatic transmissions, suspensions and power steering wheels, particularly as a lubricating oil for internal combustion engines.
2. Description of the Related Art
Lubricating oils are usually used for smoothing the working of internal combustion engines, driving mechanisms such as automatic transmissions, suspensions and power stearings, and gears. Particu¬ larly, engine oils are effective in lubricating mainly sliding parts such as a piston ring and a cylinder liner, bearings of a crank shaft or a connecting rod, and valve train including cams and valve lifters; in cooling the engine; in cleaning and dispersing combustion products; and in preventing rust formation and corrosion.
Thus, various functions are required for the engine oils and, recently, even better functions are being demanded as the required performance and engine output become higher and higher and the opera¬ tion conditions more severe. Under these circumstances, additives such as an antiwear agent, metallic detergent, ashless dispersant and antioxidant are incorporated into the engine oil in order to satisfy such requirements.
Since the energy loss in the friction parts in which the lubricating oil participates is high in the engine, the lubricating oil is used in combination with additives such as a friction modifier (FM) in order to minimize the friction loss and improve the fuel consumption (see, for example, Japanese Patent Publication No.
23595/1991) . Further, since the engine oil for automobiles is used under the various conditions of oil temperature, engine speed and load, more excellent frictional properties under the wide-range conditions of use are necessitated for further improving the fuel consumption.
The present invention has been completed after investigations made for the purpose of providing a lubricating oil composition having improved friction reducing properties over those of an ordinary lubricating oil containing molybdenum dithiocarbamate and a phosphoric ester, and is suitable for use as a lubricating oil for internal combustion engines, automatic transmissions, suspensions and power steering wheels, particularly as a lubricating oil for internal combustion engines.
SUMMARY OF THE INVENTION
After intensive investigations made for the purpose of developing a lubricating oil composition having improved friction reduction properties, the inventors have found that the above purpose can be attained with a lubricating oil composition containing a specified phosphoric ester and/or phosphorous ester, sulfurized oxymolybdenum dithiocarbamate and a calcium salicylate in specified proportions. The present invention has been completed on the basis of this finding.
Specifically, the present invention provides a lubricating oil composition which comprises a base oil containing (A) from 0.01 to 0.8% by weight, based on the whole composition, of at least one compound selected from the group consisting of (a) phosphoric esters of the general formula:
Ri-O O
X Pl-O-R33 [1]
I R -0
wherein R-*-, *2 and R^ may be the same or different and each represents a hydrogen atom or a hydrocarbyl group having 3 to 23 carbon atoms, with the proviso that at least one of R^ to R3 is a hydrocarbyl group having 3 to 23 carbon atoms, and
(b) phosphorous esters of the general formula:
R4-θ
\ P-O-R6 [2]
/ R5-0
wherein R^, R5 and R^ may be the same or different and each represents a hydrogen atom or a hydrocarbyl group having 3 to 23 carbon atoms, with the proviso that at least one of ^ to R6 is a hydrocarbyl group having 3 to 23 carbon atoms;
(B) from 50 to 2,000 ppm in terms of molybdenum, of sulfurized oxymolybdenum dithiocarbamate having at least one hydrocarbyl group having 8 to 18 carbon atoms; and
(C) from 0.3 to 2.5% by weight, based on the whole composition of a calcium salicylate having a total base number of 10 to 100.
DETAILED DESCRIPTION OF THE INVENTION
The base oil usable as the major component in the lubricating oil composition of the present invention is not particularly limited. Base oils are those usually used in ordinary lubricating oils, such as mineral oils and synthetic oils.
The mineral oils include, for example, 60 neutral oil, 100 neutral oil, 150 neutral oil, 300 neutral oil and 500 neutral oil obtained by solvent refining or hydrorefining; and low-pour point base oils prepared by removing a wax from these base oils so as to improve the low-temperature fluidity. They may be used either singly or in the form of a mixture of two or more of them in a proper ratio.
The synthetic oils include, for example, poly-α olefin oligomers, diesters, polyol esters and polyglycol esters. They are usable either singly or in the form of a mixture. They are also usable in the form of a mixture with the above-described mineral oil. The blending weight ratio of the synthetic oil to the mineral oil is, for example, 80:20 to 20:80.
A suitable base oil usable in the composition of the present invention is one having a viscosity in the range of 3 to 20 cSt at 100°C. Particularly preferred are hydrocracked products and/or wax isomerized products containing 3.0% by weight or below of an aromatic component and having a sulfur content of 50 ppm or below and a nitrogen content of 50 ppm below.
In the composition of the present invention, the component (A) is at least one compound selected from the group consisting of a (a) phosphoric ester of the general formula:
R!-0 O
\ll
P-O-R3 [1]
/ R2-0
wherein R1, R2 and R3 are each as defined above, and (b) phosphorous esters of the general formula:
R4-0
P-O-R6 ( 2 :
R5-0
wherein R^, R5 and 6 are each as defined above.
The groups R1, R2 and R3 in the above general formula [1] may be the same or different and each represents a hydrogen atom or a hydrocarbyl group having 3 to 23 carbon atoms, with the proviso that at least one of R1 to R3 is the hydrocarbyl group having 3 to 23
carbon atoms. The hydrocarbyl groups having 3 to 23 carbon atoms include linear, branched and cyclic alkyl and alkenyl groups having 3 to 23 carbon atoms, aryl groups having 6 to 23 carbon atoms, alkylaryl groups having 7 to 23 carbon atoms and arylalkyl groups having 7 to 23 carbon atoms. Examples include propyl, butyl, pentyl, hexyl, cyclo- hexyl, octyl, decyl, lauryl, myristyl, palmityl, stearyl, oleyl, eicosyl, phenyl, xylyl, benzyl and phenethyl groups.
The groups R4, R5 and R6 in the above general formula [2] for the phosphorous esters may be the same or different and each repre¬ sents a hydrogen atom or a hydrocarbyl group having 3 to 23 carbon atoms, with the proviso that at least one of R4 to R6 is a hydrocarbyl group having 3 to 23 carbon atoms. Examples include those mentioned above with reference to R1, R2 and R3 in the above general formula [1].
The composition of the present invention may contain phos¬ phoric esters either singly or in combination of two or more of them and/or the phosphorous esters either singly or in combination of two or more of them as the component (A) . Further, a combination of one or more of the phosphoric esters with one or more of the phosphorous esters may be also used.
The composition of the present invention must contain the phosphoric ester and/or phosphorus ester as the component (A) in an amount of 0.01 to 0.8% by weight, preferably 0.05 to 0.5% by weight, based on the whole composition. When the amount of (A) is below 0.01% by weight, no sufficiently low frictional properties can be obtained and, when it exceeds 0.8% by weight, there is no significant further improvement in frictional properties.
The sulfurized oxymolybdenum dithiocarbamates (MoDTC) which contain at least one hydrocarbyl group having 8 to 18 carbon atoms are used as component (B). MoDTC has a structure represented by the following general formula:
The groups R7 and R8 in the above general formula [3] each represent a hydrocarbyl group having 8 to 18 carbon atoms. The hydrocarbyl groups having 8 to 18 carbon atoms include linear and branched alkyl and alkenyl groups having 8 to 18 carbon atoms, and cycloalkyl, aryl, alkylaryl and arylalkyl groups having 8 to 18 carbon atoms. Examples include 2-ethylhexyl, n-octyl, nonyl, decyl, lauryl, tridecyl, palmityl, stearyl, oleyl, eicosyl, butylphenyl and nonyl- phenyl groups. R7 and Ry may t,e the same or different from each other, m and n are positive integers such that the sum of m + n is 4.
In the composition of the present invention, the MoDTC used as component (B) may be used singly or as a combination of two or more of them. The amount of MoDTC is in the range of 50 to 2,000 ppm, preferably 100 to 1,000 ppm (in terms of molybdenum) based on the whole composition. When the amount of molybdenum is below 50 ppm, no sufficient friction reduction properties can be obtained and when it is above 2,000 ppm, there is no further significant improvement in the frictional properties.
A calcium salicylate having a total base number of 10 to 100 is used as the component (C) in the composition of the present inven¬ tion. The calcium salicylate is, for example, one represented by the following general formula:
The group R^ in the general formula [4] represents a linear, branched or cyclic alkyl group having 8 to 23 carbon atoms, such as an octyl, nonyl, decyl, dodecyl, pentadecyl, octadecyl or eicosyl group.
The calcium salicylate used as component (C) may be used either singly or in combination of two or more of them. The amount of the calcium salicylate is in the range of 0.3 to 2.5% by weight based on the whole composition. When the amount of (C) is below 0.3% by weight, no sufficient low frictional properties can be obtained and, when the amount exceeds 2.5% by weight, the wear resistance is reduced and the ash content is increased unfavorably.
The lubricating oil composition of the present invention may contain suitable additives usually incorporated into lubricating oils, such as an ashless detergent-dispersant, viscosity index improver, pour point depressant, antioxidant, rust inhibitor, corrosion inhibitor, antifoaming agent and other antiwear agent and friction modifier, so far as the object of the present invention is not dis¬ turbed.
The ashless detergent-dispersants include, for example, succinimides, succinamides, benzylamines, their boron derivatives and esters. They are used in an amount of usually 0.5 to 7% by weight, based on the whole composition.
The viscosity index improvers include, for example, poly- methacrylates, polyisobutylenes, ethylene/propylene copolymers and hydrogenated styrene/butadiene copolymers. They are used in an amount of from 0.5 to 35% by weight, based on the whole composition. The anti-oxidants include, for example, amine antioxidants such as alkylated diphenylamines, phenyl-α-naphthylamines and alkylated α-naphthylamines, and phenolic antioxidants such as 2,6-di-t-butyl-4- methyl-phenol and 4,4'-methylenebis(2,6-di-t-butyl-4-methyl-phenol and 4,4'-methylenebis(2,6-di-t-butylphenyl) . They are used in an amount of usually 0.05 to 2% by weight, based on the whole composition.
The rust inhibitors include, for example, alkenylsuccinic acids and partial esters thereof. The corrosion inhibitors include, for example, benzotriazole and benzimidazole. The antifoaming agents include, for example, dimethylpolysiloxanes and polyacrylates. They can be suitably incorporated into the oil composition.
The following Examples further illustrate the present inven¬ tion and do not limit the invention.
Examples 1 to 8 and Comparative Examples 1 to 5
The coefficient of friction of the lubricating oil composi¬ tion was determined as follows:
(1) Coefficient of friction (μ):
The coefficient of friction was determined by the LFW-1 test under the conditions of 270 rpm, 30 kgf, 120°C and 10 minutes.
Base oil 150N-1 (having viscosity at 100°C of 5.7 mm2/s, aromatic component content of 4.1 wt%, sulfur content of 11.0 ppm and nitrogen content of 89.0 ppm) or 150N-2 (having viscosity at 100°C of 5.5 mm2/s, aromatic component content of 0.5 wt%, sulfur content of 0.5 ppm and nitrogen content of 0.1 ppm) was used.
Each of the lubricating oil compositions listed in Table 1 was prepared from the base oil, and the coefficient of friction (μ) thereof was determined. The results are given in Tables 1-1 and 1-2.
TABLE 1-1
I
<J3 I
Notes: (1) phosphoric ester: R13H27-O O
P-OH
R13H27-0
(2) phosphorous ester: R13H27 °
P-0-C13H27
R13H27 O
TABLE 1-2
o
I
Note: (1) phosphoric ester: R13H27~° °
\l
P-OH
/
As demonstrated by Examples 1-8 in Table 1-1, and comparative Examples 1-5 in Table 1-2, a lubricating oil containing the combina¬ tion of salicylate, MoDTC and phosphoric ester according to the invention provides a significantly lower coefficient of friction over an oil composition containing any two components.
The lubricating oil composition of the present invention has superior low frictional properties to those of ordinary lubricating oils comprising MoDTC and a phosphoric ester, and is suitable for use as a lubricating oil for, for example, internal combustion engines, automatic transmissions, suspensions and power steering wheels, particularly as a lubricating oil for internal combustion engines.
Claims
1. A lubricating oil composition which comprises a base oil containing:
(A) from 0.01 to 0.8 wt%, based on the whole composition, of at least one compound selected from the group consisting of:
(a) phosphoric esters of the general formula
wherein R1, R2 and R3 may be the same or different and each represents a hydrogen atom or a hydrocarbyl group having 3 to 23 carbon atoms, with the proviso that at least one of R1 to R3 is a hydrocarbyl group having 3 to 23 carbon atoms, and
(b) phosphorous esters of the general formula:
wherein R4, R5 and R6 may be the same or different and each represents a hydrogen atom or a hydrocarbyl group having 3 to 23 carbon atoms, with the proviso that at least one of R4 to R6 is a hydrocarbyl group having 3 to 23 carbon atoms;
(B) from 50 to 2,000 ppm in terms of molybdenum, based on the whole composition of sulfurized oxymolybdenum dithiocarbamate having at least one hydrocarbyl group having 8 to 18 carbon atoms, and (C) from 0.3 to 2.5% by weight, based on the whole composition, of a calcium salicylate having a total base number of 10 to 100.
2. The oil composition of claim 1 wherein the base oil is a hydrocracked product and/or a wax isomerized product containing 3.0% by weight based on base oil or below of an aromatic component and having a sulfur content of 50 ppm or below and a nitrogen content of 50 ppm or below.
3. The oil composition of claim 1 wherein the amount of component (A) is from 0.05 to 0.5% by weight, based on whole composition.
4. The oil composition of claim 1 wherein the sulfurized oxymolybdenum dithiocarbamate has the formula:
where R7 and R8 are each independently a hydrocarbyl group having 8 to 18 carbon atoms and the sum of m + n is 4.
5. The oil composition of claim 1 wherein the calcium salicylate has the formula:
where R9 is a linear, branched or cyclic alkyl group having 8 to 23 carbon atoms.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5148669A JPH06336593A (en) | 1993-05-27 | 1993-05-27 | Lubricant composition |
| JP148669/93 | 1993-05-27 | ||
| PCT/US1994/006001 WO1994028094A1 (en) | 1993-05-27 | 1994-05-27 | Lubricating oil composition |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0707623A1 true EP0707623A1 (en) | 1996-04-24 |
| EP0707623A4 EP0707623A4 (en) | 1996-09-18 |
| EP0707623B1 EP0707623B1 (en) | 1998-07-22 |
Family
ID=15457975
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94918148A Expired - Lifetime EP0707623B1 (en) | 1993-05-27 | 1994-05-27 | Lubricating oil composition |
Country Status (7)
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|---|---|
| EP (1) | EP0707623B1 (en) |
| JP (1) | JPH06336593A (en) |
| AU (1) | AU696014B2 (en) |
| CA (1) | CA2163207C (en) |
| DE (1) | DE69411922T2 (en) |
| NO (1) | NO312680B1 (en) |
| WO (1) | WO1994028094A1 (en) |
Cited By (1)
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| US8444936B2 (en) | 2009-03-27 | 2013-05-21 | Hitachi High-Technologies Corporation | Autoanalyzer and pipetting nozzle for autoanalyzer |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH07197064A (en) * | 1993-12-30 | 1995-08-01 | Cosmo Oil Co Ltd | Power steering fluid composition |
| JP3454593B2 (en) * | 1994-12-27 | 2003-10-06 | 旭電化工業株式会社 | Lubricating oil composition |
| CA2199393A1 (en) * | 1995-07-20 | 1997-02-06 | Idemitsu Kosan Co., Ltd. | Lubricating oil composition |
| JP4354014B2 (en) * | 1995-10-05 | 2009-10-28 | 出光興産株式会社 | Lubricating oil composition for continuously variable transmission |
| CA2213075C (en) * | 1995-12-22 | 2001-10-09 | Japan Energy Corporation | Lubricating oil for internal combustion engines |
| US7625847B2 (en) | 2002-08-05 | 2009-12-01 | Nippon Oil Corporation | Lubricating oil compositions |
| US7563752B2 (en) | 2002-08-05 | 2009-07-21 | Nippon Oil Corporation | Lubricating oil compositions |
| CN100462424C (en) * | 2002-08-05 | 2009-02-18 | 新日本石油株式会社 | Lubricating oil compositions |
| JP4373650B2 (en) * | 2002-08-05 | 2009-11-25 | 新日本石油株式会社 | Lubricating oil composition |
| US20070117726A1 (en) * | 2005-11-18 | 2007-05-24 | Cartwright Stanley J | Enhanced deposit control for lubricating oils used under sustained high load conditions |
| JP5105557B2 (en) * | 2010-04-26 | 2012-12-26 | 東燃ゼネラル石油株式会社 | Lubricating oil composition for internal combustion engines |
| JP2010189657A (en) * | 2010-04-26 | 2010-09-02 | Tonengeneral Sekiyu Kk | Lubricating oil composition for internal combustion engine |
| JP2013209569A (en) | 2012-03-30 | 2013-10-10 | Jx Nippon Oil & Energy Corp | Lubricating oil composition |
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| EP0418860A1 (en) * | 1989-09-20 | 1991-03-27 | Nippon Oil Co., Ltd. | Lubricating composition for internal combustion engine |
| WO1992019703A1 (en) * | 1991-05-01 | 1992-11-12 | The Lubrizol Corporation | Thermally stable compositions and lubricants and functional fluids containing the same |
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| US4171558A (en) * | 1976-09-20 | 1979-10-23 | Idemitsu Kosan Co., Ltd. | Cutting oil composition for processing cemented carbide skiving hob |
| JPS5975995A (en) * | 1982-10-25 | 1984-04-28 | Showa Shell Sekiyu Kk | Lubricating composition excellent in resistance to wear and extreme pressure and friction properties |
| JPH0662983B2 (en) * | 1986-03-17 | 1994-08-17 | 株式会社豊田中央研究所 | Lubricating oil composition |
| US4849123A (en) * | 1986-05-29 | 1989-07-18 | The Lubrizol Corporation | Drive train fluids comprising oil-soluble transition metal compounds |
| US4832867A (en) * | 1987-10-22 | 1989-05-23 | Idemitsu Kosan Co., Ltd. | Lubricating oil composition |
| US5281347A (en) * | 1989-09-20 | 1994-01-25 | Nippon Oil Co., Ltd. | Lubricating composition for internal combustion engine |
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- 1993-05-27 JP JP5148669A patent/JPH06336593A/en active Pending
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- 1994-05-27 EP EP94918148A patent/EP0707623B1/en not_active Expired - Lifetime
- 1994-05-27 CA CA002163207A patent/CA2163207C/en not_active Expired - Fee Related
- 1994-05-27 DE DE69411922T patent/DE69411922T2/en not_active Expired - Fee Related
- 1994-05-27 AU AU69594/94A patent/AU696014B2/en not_active Ceased
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| EP0418860A1 (en) * | 1989-09-20 | 1991-03-27 | Nippon Oil Co., Ltd. | Lubricating composition for internal combustion engine |
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|---|---|---|---|---|
| US8444936B2 (en) | 2009-03-27 | 2013-05-21 | Hitachi High-Technologies Corporation | Autoanalyzer and pipetting nozzle for autoanalyzer |
Also Published As
| Publication number | Publication date |
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| NO954708L (en) | 1995-11-21 |
| DE69411922D1 (en) | 1998-08-27 |
| CA2163207C (en) | 2002-11-26 |
| AU696014B2 (en) | 1998-08-27 |
| WO1994028094A1 (en) | 1994-12-08 |
| AU6959494A (en) | 1994-12-20 |
| EP0707623A4 (en) | 1996-09-18 |
| NO312680B1 (en) | 2002-06-17 |
| JPH06336593A (en) | 1994-12-06 |
| CA2163207A1 (en) | 1994-12-08 |
| NO954708D0 (en) | 1995-11-21 |
| DE69411922T2 (en) | 1998-12-17 |
| EP0707623B1 (en) | 1998-07-22 |
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