EP0706588A1

EP0706588A1 - Fibrous material batts

Info

Publication number: EP0706588A1
Application number: EP94919022A
Authority: EP
Inventors: Lindsay John Newton; Brent Douglas Mantell
Original assignee: NEW WOOL PRODUCTS Ltd
Current assignee: NEW WOOL PRODUCTS Ltd
Priority date: 1993-06-28
Filing date: 1994-06-28
Publication date: 1996-04-17
Anticipated expiration: 2014-06-28
Also published as: DE69421532D1; DK0706588T3; AU7010394A; EP0706588B1; AU683898B2; CA2166185A1; DE69421532T2; ATE186342T1; WO1995000691A1; JPH09501741A

Abstract

Fibrous material batts are produced from a mixture of natural and synthetic fibres. A sliver (10) of the fibres is fed through a lapping device (11) onto a moving conveyor to form a continuous mat. The sliver is sprayed with a bonding agent and other optional substances during lapping. The mat is then compressed to a required thickness before curing the bonding agent, and is then cut to form batts of a low density. Resilience and fire retardance properties may be imparted to the fibrous material by including an octaborate salt among the substances sprayed with the bonding agent.

Description

FT-BROUS MATERIAL BATTS FIELD OF THE INVENTION

This invention relates to the manufacture of fibrous material mats or batts, in particular but not solely to low density batts for thermal insulation or padding. The invention also relates to other properties of these batts, such as fire resistance and resilience to crushing. BACKGROUND OF THE INVENTION

A method of forming resin impregnated fibre batts is disclosed in US Patent No. 4,678,822. The resin is an acrylic self cross-linking polymer containing fire and smoke retardants and a pesticide. The fibres may be natural and/or synthetic in origin and are often waste materials.

The materials are randomly dispersed in a sliver which is sprayed with the resin during a continuous folding process known as lapping. The sliver is lapped up to a required thickness on a moving conveyer, and the resulting mat is cured at around 150°C and cut into batts having a density of around 25 kg/m³.

This method and other similar methods now in use have high production costs due to the quantities of materials required and the conditions under which manufacturing takes place. The relatively high density batts also give an undesirably high thermal conductivity for a given thickness. Lower density products would be cheaper and less conductive but are not yet available from existing sources.

The textile industry incorporates various natural and/or synthetic fibre materials in a wide range of products. These materials are often treated for fire resistance by absorption of inorganic salts such as borates and phosphates from aqueous solution, and/or by spraying with resin compositions which contain these salts or other chemicals such as metal oxides or halogenated organic compounds.

A variety of natural and synthetic resins are available. By themselves most are dangerously flammable until the various salts and other compounds are admixed in solution to form water /resin emulsions. The final compositions may then impart fire, insect, fungus and rodent resistance as well as resilience, cohesion and strength to the fibrous materials. They should also be stable and non-toxic.

Boric acid (H₃B0₃) and sodium tetraborate or borax (Na^O^impart many of the desired properties to the fibres and to the resins with boron being the important component. However, their use has been unsatisfactory to some extent due to problems with high pH and low solubility in water. Generally both the aqueous solutions in which the material is immersed and the resin compositions with which they are sprayed cannot contain sufficient concentrations of boron. They have also been unsatisfactory with regard to stiffness of the treated materials. SUMMARY OF THE INVENTION

It is an object of the present invention to provide for manufacture of fibrous material batts having improved physical properties, or at least to provide the public with a useful choice.

The invention involves several aspects relating to production of the improved batts. A fragile sliver of fibrous material is continuously formed from a mass of natural and/or synthetic fibres such as found in waste wool. The sliver is lapped into a lightweight mat which is carried on a moving conveyor.

A bonding agent and optionally other substances are sprayed onto the sliver in a fine mist as lapping takes place back and forth across the conveyor. Although control may be exerted over the thickness of the mat by varying the lapping and conveying speeds, a further step of compression is normally required before the structure of the mat is fixed by curing.

This enables precise control over the eventual density of batts into which the mat will be cut. It is generally desired that the batts have a density of less than 15 kg/m³, and preferably 8 to 12 kg/m³.

The bonding agent which is sprayed onto the sliver is typically a resin emulsion containing the optional substances in an aqueous solution. Batts being manufactured for thermal insulation must be fire resistant and one of the optional substances should be an octaborate salt having a concentration of up to around 30% by weight. BRIEF DESCRIPTION OF THE DRAWINGS

A preferred embodiment will be described as an example of the invention with respect to the drawings of which:

Figure 1 schematically shows apparatus for manufacturing fibrous material batts, from one side,

Figure 2 shows the apparatus from above with an exaggerated indication of the lapping operation, and Figure 3 shows an end view of the lapping and spraying operations.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

Referring to these drawings it will be evident that the invention can be employed when making mats and batts from a range of natural and synthetic materials, including animal or plant fibres and acrylics, polyesters or polyamides. Natural wool is preferred due to its ready availability and lofting characteristics. It will also be appreciated that the fibrous material products can be put to a wide range of uses including thermal insulation and stuffing for various objects.

Figure 1 shows sliver 10 of fibrous material passing downwards through a lapping device 11. The sliver is formed continuously from wool or a wool/synthetic mix, preferably at least 50% by weight of wool, which may be scoured or cleaned by a commercial process and possibly pretreated for fire resistance. Processes for treating the bulk material and forming the sliver are well known and will be not be described further. The sliver itself has a fragile structure up to around 1 cm thick and perhaps 2 m in width. The lapping device includes sliver control elements 30 and spray booms 31 which will be described later. The device oscillates back and forth across a moving conveyor 12 onto which the sliver is folded, to create a continuous mat 13 of fibrous material. The fibre bonding agent sprayed onto the sliver from booms 31 thoroughly impregnates the mat, which is typically 10 to 20 cm thick. The conveyor passes through a bath 14 which removes any oversprayed bonding agent. Figure 2 shows mat 13 from above, with an exaggerated zigzag structure caused by the relative motion of the lapping device 11 and conveyor 12. In practice the zigzag is very much finer due to the lapping device moving rather more quickly than the conveyor in the directions indicated. The multilayer structure of the mat has also been considerably exaggerated in Figure 1. As shown in both Figures 1 and 2 the mat 13 is carried from conveyor 12 to a space

15 between parallel conveyors 16 and 17. The space is adjustable, by lowering or raising conveyor 16, so that the mat can be compressed to a greater or lesser degree in obtaining a required thickness. The conveyors contact the mat, still wet from the spraying operation, through a non-sticking mesh surface. Conveyors 16 and 17 carry the mat into an oven 20 which circulates hot air as indicated to dry and cure the bonding agent. A heater /fan 21 blows hot air up through conveyor 17 and out of the oven through an exhaust 22. Heat is exchanged to incoming air which passes down through conveyor 16 from inlet 23. The upwards moving air is typically at a temperature of up to 120°C and preferably heats the mat to a temperature of between 70 and 100°C. The downwards moving air has a temperature of between 50 to 60°C.

The mat 13 is finally cut at a guillotine device 25 after curing and drying. This creates batts of a required thickness and low density according to various parameters which may be varied during the overall manufacturing process. For example, to create batts having a density of 10 kg/m³ from a sliver formed at 50 kg/hr, a i m wide mat may be conveyed at 50 m/hr, and compressed to a thickness of 10 cm. Surprisingly good insulative properties have been obtained from batts having a density less than 15 kg/m³ and preferably between about 8 and 12 kg/m³. This represents an optimum volume ratio of air to fibre. At higher densities fibre and resin consumption are unnecessarily high and the insulation is also reduced. A comparison of one sample with the example in US 4,678,822 is as follows.

Thickness Density Insulation Thermal mm kg/m* "R" value Conductivity m²/°C/W W/m²/°C

90 8.2 1.71 0.052

54 . 25 1.34 0.040

From these results it can be seen that a thickish mat of low density according to the invention gives better insulation than a conventional mat of high density. As the thickness was less than double while the density was less than one third a considerable saving in production materials can be made.

Figure 3 shows the lapper in more detail to have a pair of control booms 30 and a pair of spray booms 31. It moves from side to side as indicated and both sides of the sliver 10 are sprayed with a resin emulsion to hold the structure of the mat, and other substances to provide certain properties of resilience and retardance. The spray booms are alternately switched off for brief periods when the sliver is closest, to obtain economic and even distribution of resin.

Spraying takes place preferably with the resin at a temperature up to about 50°C and generally between about 25 and 40°C. This assists evaporation of moisture prior to curing and avoids need of elaborate radiative or other drying means which have been proposed previously.

Curing takes place in the oven preferably at a temperature less than about 120°C and generally between about 70 and 100°C. Higher curing temperatures are usually of no advantage and may be detrimental to some fibres and resins.

The resin emulsion normally includes various fire and smoke retardants, pesticides, fungicides and the like in the form of an aqueous solution. A surfactant such as sold by Eastman Chemicals Ltd of the United States, under the trade mark TEXANOL, may also be added. Resins suitable for the low temperature curing are preferably acrylic polymer emulsion types with low film forming properties during spraying and high self cross- linking properties during curing. One especially advantageous addition to the fibre bonding agents has been found in a range of inorganic octaborate salts, particularly sodium octaborate

A sodium octaborate product (tetrahydrate) is marketed by United States Borax and

Chemical Corporation under the trade marks TIMBOR and F-BOR. These have been used exclusively for preservation of timber in the past.

A suitable resin is marketed by A C Hatrick (NZ) Limited under the trade mark ACROCRYL. It has not been used successfully with boric acid or borax in the past and compositions of this kind have been disregarded due to the unfavourable chemical reactions which occur. Other salts and resins may also be suitable but those mentioned are the most cheaply and widely available at present.

A composition of TIMBOR dissolved in water and ACROCRYL forms an emulsion which gives surprisingly good fire resistance and resilience to treated materials. There are no problems with pH or low solubility as occurs with other well known boron chemicals which have been tried in the past. It also covers and adheres to fibre surfaces particularly well, and has a marked shelf life stability so need not be used immediately after preparation. The resin is an acrylic cross-linked variety which is cured at around 70 to 100°C once applied.

Preferred mixtures for spraying onto a fibrous material sliver during lapping have been found to comprise a resin emulsion with up to 30% by weight of resin solids and up to 30% by weight of an octaborate salt. Most preferably 15 to 25% by weight of resin solids and 10 to 25% of sodium octaborate tetrahydrate.

A comparison of technical data on boric acid, borax and sodium octaborate indicates rather better water solubility characteristics for octaborate compounds (1/19, 1/16 and 1/11 g/ml respectively). Further, the pH of an octaborate solution drops to near neutral as concentration increases and no unfavourable reactions occur with the materials or resins. This allows a high concentration of boron in purely aqueous solutions for immersion of materials, and in resin emulsions which may be sprayed onto the materials.

Outstanding results have been achieved in experiments conducted to date using resin compositions on woollen webs or blocks for insulation. An emulsion comprising 20% ACROCRYL, 18% TIMBOR and the balance water by weight was sprayed onto woollen fibres which were then lofted and cured. The resulting webs were effectively fire resistant with desirable qualities of high stiffness and low toxicity with fungicidal and insecticidal properties also.

Claims

CLAIMS:

1. A method of manufacturing fibrous material batts comprising: forming a sliver of dispersed fibrous material, lapping the sliver into a moving multilayer mat, spraying the sliver with a fibre bonding agent during lapping, compressing the moving mat to a required thickness, curing the bonding agent while maintaining the required thickness, and cutting the mat to form batts of required dimensions and density.

2. A method according to claim 1 wherein the fibrous material comprises at least 50% by weight of wool.

3. A method according to claim 1 wherein the batts have a density of less than 15 kg/m³.

4. A method according to claim 1 wherein the batts have a density of between 8 and 12 kg/m³.

5. A method according to claim 1 wherein the fibre bonding agent comprises a resin emulsion having less than 30% by weight of resin solids.

6. A method according to claim 1 wherein the fibre bonding agent comprises a resin emulsion having from 15 to 25% by weight of resin solids.

7. A method according to claim 1 wherein the fibre bonding agent comprises an aqueous resin emulsion or solution having less than 30% by weight of an octaborate salt.

8. A method according to claim 1 wherein the fibre bonding agent comprises an aqueous resin emulsion or solution having from 10 to 25% by weight of sodium octaborate tetrahydrate.

9. A method according to claim 1 wherein the spraying takes place with the fibre bonding agent at a temperature of less than 50°C.

10. A method according to claim 1 wherein the spraying takes place with the fibre bonding agent at a temperature of from 25 to 40°C.

11. A method according to claim 1 wherein the curing takes place at a temperature of less than 120°C.

12. A method according to claim 1 wherein the curing takes place at a temperature of from 70 to 100°C.

13. A method of manufacturing low density fibrous material from a sliver of natural and/or synthetic fibres comprising spraying, lapping and curing the sliver with a fibre bonding agent to form a matt having a density of less than 15 kg/m³.

14. A fibrous material mat or batt having a density of less than 15 kg/m³.

15. A method of manufacturing a fibrous material from a sliver of natural and/or synthetic fibres comprising sprayin the sliver with an aqueous solution or a resin composition containing an appreciable concentration of an octaborate salt.

16. A fibrous material mat or batt incorporating an octaborate salt.