NZ267724A

NZ267724A - Low density fibrous material batting formed from slivers sprayed and laid on moving multilayered mat

Info

Publication number: NZ267724A
Application number: NZ26772494A
Authority: NZ
Inventors: Lindsay John Newton; Brent Douglas Mantell
Original assignee: New Wool Products Ltd
Priority date: 1993-06-28
Filing date: 1994-06-28
Publication date: 1997-07-27

Description

<div class="application article clearfix" id="description"> New Zealand Nc. 26/724 International No. PCT/NZ94/00067 Priority Dato(s): ... 3S.lk.fa* ao|&./93... Complete Specification Filed: Class: jESJkftJj.*?.:* P.O. Jcurna' No: i*+l& NEW ZEALAND PATENTS ACT 1953 COMPLETE SPECIFICATION Title of Invention: Fibrous material batts Name, address and nationality of applicant(s) as in international application form: M ^ iT6£> NEW WOOL PRODUCTStTB: a New Zealand company of 29 Bullen Street, Nelson, New Zealand -1 - 267724 TXTn • METHOD AND APPARATUS FOR PRODUCING FIBROUS MATERIAL BATTING FIELD OF THE INVENTION This invention relates to the manufacture of fibrous material mats or batting, in 5 particular but not solely to low density batting for thermal insulation or padding. The invention also relates to other properties of batting, such as fire resistance and resilience to crushing. BACKGROUND OF THE INVENTION A method of forming resin impregnated fibre batts is disclosed in US Patent 10 No. 4,678,822. The resin is an acrylic self cross-linking polymer containing fire and smoke retardants and a pesticide. The fibres may be natural and/or synthetic in origin and are often waste materials. The materials are randomly dispersed in a sliver which is sprayed with the resin during a continuous folding process known as lapping. The sliver is lapped up to a 15 required thickness on a moving conveyer, and the resulting mat is cured at around 150°C and cut into batts having a density of ^ound 25 kg/m3. This method and other similar methods now in use have high production costs due to die quantities of materials required and the conditions under which manufacturing takes place. The relatively high density batts also give an undesirably high thermal conductivity 20 for a given thickness. Lower density products would be cheaper and less conductive but are not yet available from existing sources. The textile industry incorporates various natural and/or synthetic fibre materials in a wide range of products. These materials are often treated for fire resistance by absorption of inorganic salts such as borates and phosphates from aqueous solution, 25 and/or by spraying with resin compositions which contain these salts or other chemicals such as metal oxides or halogenated organic compounds. A variety of natural and synthetic resins are available. By themselves most are dangerously flammable until die various salts and other compounds are admixed in solution to form water/resin emulsions. The final compositions may then impart fire, 30 insect, fungus and rodent resistance as weii as resilience, cohcsiuii aiid strength to the fibrous materials. They should also be stable and non-toxic. Boric acid (H3B03) and sodium tetraborate or borax (Na2B407)impart many of the desired properties to the fibres and to the resins with boron being the important component However, their use has been unsatisfactory to some extent due to problems 35 with high pH and low solubility in water. Generally both the aqueous solutions in which the material is immersed and the resin compositions with which they are sprayed cannot f i < - 3 0 MAY 1997 -2- 267724 contain sufficient concentrations of boron. They have also been unsatisfactory with regard to stiffness of the treated materials. SUMMARY OF THE INVENTION It is an object of die present invention to provide for manufacture of fibrous material 5 batting having improved physical properties, or at least to provide the public with a useful choice. The invention involves several aspects relating to production of the improved batting. A fragile sliver of fibrous material is continuously formed from a mass of natural and/or synthetic fibres such as found in waste wool. The sliver is lapped into a 10 lightweight mat which is carried on a moving conveyor. A bonding agent and optionally other substances are sprayed onto die sliver in a fine mist as lapping takes place back and forth across the conveyor. Control may be exerted over the thickness of the mat by varying the lapping and conveying speeds. The structure of the mat is then fixed by curing. IS Spraying takes place on alternate sides of the sliver from a pair of spray booms which preferably oscillate with the sliver. Each boom may be turned off briefly at the point of closest approach of the sliver. This enables precise control over die eventual density of batting into which die mat will be cut. It is generally desired that the batting have a density of less than 15 kg/m3, and preferably 8 to 12 kg/m3. 20 The bonding agent which is sprayed onto the sliver is typically a resin emulsion containing the optional substances in an aqueous solution. Batting being manufactured for thermal insulation must be fire resistant and one of the optional substances should be an octaborate salt having a concentration of up to around 30% by weight. BRIEF DESCRIPTION OF THE DRAWINGS 25 A preferred embodiment will be described as an example of the invention with respect to the drawings of which: Figure 1 schematically shows apparatus for manufacturing fibrous material batting, from one side, Figure 2 shows the apparatus from above with an exaggerated indication of the 30 lapping operation, and Figures 3a and 3b show end views of the spraying operation with the lapper at each turning point of an oscillation. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT Referring to these drawings it will be evident that die invention can be employed 35 when making mats and batts from a range of natural and synthetic materials, including animal or plant fibres and acrylics, polyesters or poly amides. Natural wool is preferred j 3 0 MAY 139? 267724 due to its ready availability and lofting charac.wristics. It will also be appreciated that the fibrous material products can be put to a wide range of uses including thermal insulation and stuffing for various objects. Figure 1 shows sliver 10 of fibrous material passing downwards through a lapping device 11. The sliver is formed continuously from wool or a wool/synthetic mix, preferably at least 50% by weight of wool, which may be scoured or cleaned by a commercial process and possibly pretreated for fire resistance. Processes for treating the bulk material and forming the sliver are well known and will be not be described further. The sliver itself has a fragile structure up to around 1 cm thick and perhaps 2 m in width. The lapping device includes sliver control elements 30 and spray booms 31 which will be described later. The device oscillates back and forth across a moving conveyor 12 onto which the sliver is folded, to create a continuous mat 13 of fibrous material. The fibre bonding agent sprayed onto the sliver from booms 31 thoroughly impregnates the mat, which is typically 10 to 20 cm thick. The conveyor passes through a bath 14 which removes any oversprayed bonding agent. Figure 2 shows mat 13 from above, with an exaggerated zigzag structure caused by the relative motion of the lapping device 11 and conveyor 12. In practice the zigzag is very much finer due to the lapping device moving rather more quickly than the conveyor in the directions indicated. The multilayer structure of the mat has also been considerably exaggerated in Figure 1. As shown in both Figures 1 and 2 the mat 13 is carried from conveyor 12 to a space 15 between parallel conveyors 16 and 17. The space is adjustable, by lowering or raising conveyor 16, so that the mat can be compressed to a greater or lesser degree in obtaining a required thickness. The conveyors contact both sides of the mat, which is still wet from the spraying operation, through a non-sticking mesh surface. This also holds the mat in place during air blowing. Conveyors 16 and 17 carry the mat into an oven 20 which circulates hot air as indicated to dry and cure the bonding agent. A heater/fan 21 blows hot air up through conveyor 17 and out of the oven through an exhaust 22. Heat is exchanged to incoming air which passes down through conveyor 16 from inlet 23. The upwards moving air is typically at a temperature of up to 120°C and preferably heats the mat to a temperature of between 70 and 100 °C. The downwards moving air has a temperature of between 50 to 60°C. The mat 13 is finally cut at a guillotine device 25 after curing and drying. This creates batting of a required thickness and low density according to various parameters which may be varied during the overall manufacturing process. For example, to create 3 0 MAY 199? 267724 batting having a density of 10 kg/m3 from a sliver formed at 50 kg/hr, aim wide mat may be conveyed at 50 m/hr, and compressed to a thickness of 10 cm. Surprisingly good insulative properties have been obtained from batting having a density less than 15 kg/m3 and preferably between about 8 and 12 kg/m3. This represents 5 an optimum volume ratio of air to fibre. At higher densities fibre and resin consumption are unnecessarily high and the insulation is also reduced. A comparison of one sample with the example in US 4,678,822 is as follows. 10 Thickness mm Density kg/m Insulation "R" value m2oC/W Thermal Conductivity W/m/°C 90 8.2 1.71 0.052 54 25 1.34 0.040 From these results it can be seen that a thickish mat of low density according to the 15 invention gives better insulation than a conventional mat of high density. As the thickness was less than double while the density was less than one third a considerable saving in production materials can be made. Figures 3a and 3b show the lapper in more detail to have a pair of control booms 30 and a pair of spray booms 31. It moves from side to side as indicated and the sides of the 20 sliver 10 are finely and alternately sprayed with a resin emulsion to hold the structure of the mat, and other substances to provide certain properties of resilience and retardance. The spray booms are alternately switched off for brief periods when the sliver is closest, to obtain economic and even distribution of resin. Spraying takes place preferably with die resin at a temperature up to about 50°C and 25 generally between about 25 and 40°C. This assists evaporation of moisture prior to curing and avoids need of elaborate radiative or other drying means which have been proposed previously. Curing takes place in the oven preferably at a temperature less than about 120°C and generally between about 70 and 100°C. Higher curing temperatures are usually of no 30 advantage and may be detrimental to some fibres and resins. The resin emulsion normally includes various fire and smoke retardants, pesticides, fungicides and the like in the form of an aqueous solution. A surfactant such as sold by Eastman Chemicals Ltd of the United States, under the trade mark TEXANOL, may also be added. Resins suitable for the low temperature curing are preferably acrylic polymer 3 0 HAY 199? RECEIVES -5- 267724 emulsion types with low film forming properties during spraying and high self cross-linking properties during curing. One especially advantageous addition to the fibre bonding agents has been found in a range of inorganic octaborate salts, particui<uly sodium octaborate (NajBgOu). 5 A sodium octaborate product (tetrahydrate) is marketed by United States Borax and Chemical Corporation under the trade marks TIMBOR and F-BOR. These have been used exclusively for preservation of timber in the past. A suitable resin is marketed by A C Hatrick (NZ) Limited under the trade mark ACROCRYL. It has not been used successfully with boric acid or borax in the past and 10 compositions of this kind have been disregarded due to the unfavourable chemical reactions which occur. Other salts and resins may also be suitable but those mentioned are the most cheaply and widely available at present. A composition of TIMBOR dissolved in water and ACROCRYL forms an emulsion which gives surprisingly good fire resistance and resilience to treated materials. There are 15 no problems with pH or low solubility as occurs with other well known boron chemicals which have been tried in the past It also covers and adheres to fibre surfaces particularly well, and has a marked shelf life stability so need not be used immediately after preparation. The resin is an acrylic cross-linked variety which is cured at around 70 to 100°C once applied. 20 Preferred mixtures for spraying onto a fibrous material sliver during lapping have been found to comprise a resin emulsion with up to 30% by weight of resin solids and up to 30% by weight of an octaborate salt. Most preferably 15 to 25% by weight of resin solids and 10 to 25% of sodium octaborate tetrahydrate. A comparison of technical data on boric acid, borax and sodium octaborate indicates 25 rather better water solubility characteristics for octaborate compounds (1/19, 1/16 and 1/11 g/ml respectively). Further, the pH of an octaborate solution drops to near neutral as concentration increases and no unfavourable reactions occur with the materials or resins. This allows a high concentration of boron in purely aqueous solutions for immersion of materials, and in resin emulsions which may be sprayed onto the materials. 30 Outstanding results have been achieved in experiments conducted to date using resin compositions on woollen webs or blocks for insulation. An emulsion comprising 20% ACROCRYL, 18% TIMBOR and the balance water by weight was sprayed onto woollen fibres which were then lofted and cured. The resulting webs were effectively fire resistant with desirable qualities of high stiffness and low toxicity with fungicidal and insecticidal 35 properties also. 3 0 MAY 199? FieoEfVLli 267724 </div>

Claims

<div class="application article clearfix printTableText" id="claims"> CLAIMS: I. A method of manufacturing low density fibrous material batting comprising: forming a sliver of dispersed fibrous material, lapping the sliver onto a moving multilayer mat, 5 spraying the sliver with a fibre bonding agent during lapping, to produce an even distribution of the bonding agent in the mat, curing the bonding agent on the moving mat, and cutting the mat to form batting of required dimensions and density, wherein alternate sides of the sliver are sprayed during lapping, by a pair of spray booms which oscillate with the sliver. 10 2. A method according to claim 1 further comprising compressing the moving mat to a required thickness during curing. 3. A method according to claim 1 wherein the spray booms direct spray in generally opposed directions towards the sliver. 4. A method according to claim 1 wherein heated air is blown upward through the mat IS to cause curing. 5. A method according to claim 1 wherein the fibrous material comprises at least 50% by weight of wool. 6. A method according to claim 1 wherein the batts have a density of less than 15 kg/m3. 20 7. A method according to claim 1 wherein the batts have a density of between 8 and 12 kg/m3. 8. A method according to claim 1 wherein the fibre bonding agent comprises a resin containing an octaborate salt. 9. A method according to claim 1 wherein the fibre bonding agent comprises a resin 25 having from 10 to 25% by weight of sodium octaborate tetrahydrate. 10. Apparatus for manufacturing low density fibrous material batting comprising: lapping means which forms a sliver of fibrous material into a moving multilayer mat, spraying means which delivers a fibre bonding agent to alternate sides of the sliver during lapping, to produce an even distribution of resin in die mat, curing means which heats the 30 bonding agent on the moving mat after lapping of the sliver, and cutting means which severs the mat into batting of required dimensions and density. II. Apparatus according to claim 10 further comprising compressing means which together with the curing means reduces the moving mat to a required thickness. 12. Apparatus according to claim 10 wherein the spraying means comprise spray booms 35 on either side of the sliver which direct the bonding agent generally toward the sliver before the sliver is lapped onto die mat. 3 0 MAY 1997, -7- 267724 13. Apparatus according to claim 10 wherein the curing means blow heated air upwards through the moving mat. 14. A method of manufacturing low density fibrous material batting substantially as hereinbefore described with reference to the accompanying drawings. 15. An apparatus for manufacturing low density fibrous material batting substantially as hereinbefore described with reference to the accompanying drawings. END OF CLAIMS AGENTS FOR THE APPLICANTS </div>