EP0696328A1 - Fibres et tissus elastiques et articles fabriques les utilisant - Google Patents

Fibres et tissus elastiques et articles fabriques les utilisant

Info

Publication number
EP0696328A1
EP0696328A1 EP94913373A EP94913373A EP0696328A1 EP 0696328 A1 EP0696328 A1 EP 0696328A1 EP 94913373 A EP94913373 A EP 94913373A EP 94913373 A EP94913373 A EP 94913373A EP 0696328 A1 EP0696328 A1 EP 0696328A1
Authority
EP
European Patent Office
Prior art keywords
fibers
elastic
fiber
percent
usp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP94913373A
Other languages
German (de)
English (en)
Inventor
Rexford A. Maugans
Edward N. Apartment 1207 Knickerbocker
George W. Knight
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=21985228&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0696328(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Priority to EP98106269A priority Critical patent/EP0859073B1/fr
Publication of EP0696328A1 publication Critical patent/EP0696328A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/28—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/30—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising olefins as the major constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

Definitions

  • This invention relates to elastic fibers, fabrics and articles fabricated therefrom (e.g., disposable incontinence garments or diapers).
  • the fibers and fabrics comprise at least one homogeneously branched linear ethylene polymer having specific properties.
  • Fiber is typically classified according to its diameter.
  • Monofilament fiber is generally defined as having an individual fiber diameter greater than about 15 denier, usually greater than about 30 denier per filament.
  • Fine denier fiber generally refers to a fiber having a diameter less than about 15 denier per filament.
  • Microdenier fiber is generally defined as fiber having less than 100 microns diameter. The fiber can also be classified by the process by which it is made, such as monofilament, continuous wound fine filament, staple or short cut fiber, spun bond, and melt blown fiber.
  • thermoplastics such as polypropylene, highly branched low density polyethylene (LDPE) made typically in a high pressure polymerization process, linear heterogeneously branched polyethylene (e.g., linear low density polyethylene made using Ziegler catalysis), blends of polypropylene and linear heterogeneously branched polyethylene, blends of linear heterogeneously branched polyethylene, and ethylene/vinyl alcohol copolymers.
  • LDPE highly branched low density polyethylene
  • linear heterogeneously branched polyethylene e.g., linear low density polyethylene made using Ziegler catalysis
  • blends of polypropylene and linear heterogeneously branched polyethylene e.g., linear low density polyethylene made using Ziegler catalysis
  • blends of polypropylene and linear heterogeneously branched polyethylene e.g., linear low density polyethylene made using Ziegler catalysis
  • blends of polypropylene and linear heterogeneously branched polyethylene e
  • Linear heterogeneously branched polyethylene has been made into monofilament, as described in USP 4,076,698 (Anderson et al.). Linear heterogeneously branched polyethylene has also been successfully made into fine denier fiber, as disclosed in USP 4,644,045 (Fowells), USP 4,830,907 (Sawyer et al.), USP 4,909,975 (Sawyer et al.) and in USP 4,578,414 (Sawyer et al.).
  • Blends of such heterogeneously branched polyethylene have also been successfully made into fine denier fiber and fabrics, as disclosed in USP 4,842,922 (Krupp et al.), USP 4,990,204 (Krupp et al.) and USP 5,112,686 (Krupp et al).
  • USP 5,068,141 also discloses making nonwoven fabrics from continuous heat bonded filaments of certain heterogeneously branched LLDPE having specified heats of fusion.
  • fibers made from all of these types of saturated olefinic polymers are not "elastic" as that term is defined below without incorporating additives or elastomers, thus limiting their use in elastic applications.
  • One attempt to alleviate this problem by incorporating additives into the polymer prior to melt spinning is disclosed in USP 4,663,220 (Wisneski et al.). Wisneski et al. disclose fibrous elastomeric webs comprising at least about 10 percent of a block copolymer and a polyolefin. The resultant webs are said to have elastomeric properties.
  • USP 4,425,393 discloses monofilament fiber made from polymeric material having an elastic modulus from 2,000 to 10,000 psi (13.8 MPa to 68.9 MPa).
  • the polymeric material includes plasticized polyvinyl chloride (PVC), low density polyethylene (LDPE), thermoplastic rubber, ethylene-ethyl acrylate, ethylene-butylene copolymer, polybutylene and copolymers thereof, ethylene-propylene copolymers, chlorinated polypropylene, chlorinated polybutylene or mixtures of those.
  • Elastic fiber and web prepared from a blend of at least one elastomer (i.e., copolymers of an isoolefin and a conjugated polyolefin (e.g., copolymers of isobutylene and isoprene)) and at least one thermoplastic is disclosed in USP 4,874,447 (Hazelton et al.).
  • USP 4,657,802 discloses composite nonwoven elastic webs and a process for their manufacture.
  • the elastic materials useful for forming the fibrous nonwoven elastic web include polyester elastomeric materials, polyurethane elastomeric materials, and polyamide elastomeric materials.
  • USP 4,833,012 discloses nonwoven entanglement fabrics made from a three dimensional entanglement of elastic fibers, nonshrinkable nonelastic fibers, and shrinkable elastic fibers.
  • the elastic fibers are made from polymer diols, polyur ethanes, polyester elastomers, polyamide elastomers and synthetic rubbers.
  • Composite elastomeric polyether block amide nonwoven webs are disclosed in USP 4,820,572 (Killian et al.). The webs are made using a melt blown process and the elastic fibers are made from a polyether block amide copolymer.
  • elastomeric fibrous web is disclosed in USP 4,803,117 (Daponte).
  • Daponte discloses that the webs are made from elastomeric fibers or microfibers made from copolymers of ethylene and at least one vinyl monomer selected from the group including vinyl ester monomers, unsaturated aliphatic monocarboxylic acids and alkyl esters of these monocarboxylic acids.
  • the amount of the vinyl monomer is said to be "sufficient" to impart elasticity to the melt- blown fibers.
  • Blends of the ethylene /vinyl copolymers with other polymers are also said to form the fibrous webs.
  • Fabricated articles such as incontinence garments, also benefit from use of elastic components.
  • USP 4,940,464 (Van Gompel et al.), USP 4,938,757 (Van Gompel et al.), and USP 4,938,753 (Van Gompel et al.) disclose disposable garments containing elastic gathering means and stretchable side panels.
  • the gathering means and stretchable side panels are made from melt blown or film of block or graft copolymers (e.g., butadiene, isoprene, styrene, ethylene- methyl acrylate, ethylene- vinyl acetate, ethylene-ethyl acrylate or blends thereof).
  • the new elastic fiber has a permanent set of 50 percent or less, or, stated another way, a percent recovery of at least 50 percent. This property is surprisingly different than the response of fibers made from heterogeneously branched linear low density polyethylene where the percent permanent set seems to be generally greater than 50 percent and substantially independent of density.
  • the fiber is made from at least one homogeneously branched linear ethylene polymer having a density less than 0.90 g/cm 3 and a molecular weight distribution, /Mn, of from 1.5 to 2.5.
  • the new elastic fabric comprises such elastic fibers.
  • the homogeneously branched linear ethylene polymers useful herein to make the elastic fibers and fabrics are a known class of polymers which have a linear polymer backbone, no long chain branching and a narrow molecular weight distribution.
  • Such polymers are interpolymers of ethylene and at least one ⁇ -olefin comonomer of from 3 to 20 carbon atoms, and are preferably copolymers of ethylene with a C3-C20 ⁇ -olefin, and are most preferably copolymers of ethylene with 1-butene, 1-hexene, 4-methyl-l-pentene or 1-octene.
  • This class of polymers is disclosed, for example, by Elston in USP 3,645,992 and subsequent processes to produce such polymers using metallocene catalysts have been developed, as shown, for example, in EP 0 129 368, EP 0 260 999, USP 4701432, USP 4937301, USP 4935397, USP 5055438, and WO 90/07526, and others.
  • the polymers can be made by conventional polymerization processes (e.g., gas phase, slurry, solution, and high pressure).
  • the linear ethylene polymers used to form the elastic fibers have homogeneous branching distributions.
  • the terms "homogeneously branching distribution” and “homogeneously branched” means that the comonomer is randomly distributed within a given molecule and that substantially all of the copolymer molecules have the same ethylene/ comonomer ratio.
  • the homogeneity of the branching distribution can be measured variously, including measuring the SCBDI (Short Chain Branch Distribution Index) or CDBI (Composition Distribution Branch Index).
  • SCBDI or CDBI is defined as the weight percent of the polymer molecules having a comonomer content within 50 percent of the median total molar comonomer content.
  • the CDBI of a polymer is readily calculated from data obtained from techniques known in the art, such as, for example, temperature rising elution fractionation (abbreviated herein as "TREF") as described, for example, in Wild et al, Tournal of Polymer Science, Poly. Phys. Ed., Vol. 20, p. 441 (1982), or in U.S. Patent 4,798,081.
  • the SCBDI or CDBI for the homogeneously branched polymers used in the present invention is preferably greater than 30 percent, especially greater than 50 percent.
  • the homogeneously branched linear ethylene polymers used to make the elastic fibers of the present invention have a single melting peak, as measured using differential scanning calorimetry (DSC), in contrast to heterogeneously branched linear ethylene polymers, which have 2 or more melting peaks, due to their broad branching distribution.
  • DSC differential scanning calorimetry
  • the density of the homogeneously branched linear ethylene polymers used to make the elastic fibers of the present invention is measured in accordance with ASTM D-792 and is generally less than 0.90 g/cm 3 , preferably from 0.85 g/cm 3 to 0.90 g/cm 3 , more preferably from 0.85 g/cm 3 to 0.89 g/cm 3 , and especially from 0.85 g/cm 3 to 0.88 g/cm 3 .
  • the molecular weight of the homogeneously branched linear ethylene polymers used to make the elastic fibers of the present invention is conveniently indicated using a melt index measurement according to ASTM D-1238, Condition 190°C/2.16 kg (formally known as "Condition (E)” and also known as I 2 ). Melt index is inversely proportional to the molecular weight of the polymer. Thus, the higher the molecular weight, the lower the melt index, although the relationship is not linear.
  • the melt index for the homogeneously branched linear ethylene polymers used to make the elastic fibers used herein is generally from 0.01 grams/10 minutes (g/10 min) to 1000 g/10 min, preferably from 0.1 g/10 min to 5 g/10 min for monofilament
  • fibers generally above about 15 denier /filament and preferably from 5 g/10 min to 250 g/10 min for fine denier fibers (fibers having a diameter generally less than or equal to 15 denier/filament).
  • melt index measurement Another measurement useful in characterizing the molecular weight of the homogeneously branched linear ethylene polymers used to make the elastic fibers is conveniently indicated using a melt index measurement according to ASTM D-1238, Condition 190°C/10 kg (formerly known as “Condition (N)” and also known as Iio).
  • the ratio of these two melt index terms is the melt flow ratio and is designated as I_o/l2-
  • the I 10 /I2 ratio of the homogeneously branched linear ethylene polymers is 6 or less.
  • antioxidants e.g., hindered phenolics (e.g., Irganox® 1010 made by Ciba-Geigy Corp.), phosphites (e.g., Irgafos® 168 made by Ciba-Geigy Corp.)
  • cling additives e.g., polyisobutylene (PIB)
  • antiblock additives pigments can also be included in the homogeneously branched linear ethylene polymers used to make the elastic fibers, to the extent that they do not interfere with the enhanced fiber and fabric properties discovered by Applicants.
  • the molecular weight distribution (Mw/ n ) of the homogeneously branched ethylene interpolymers are analyzed by gel permeation chromatography (GPC) on a Waters 150C high temperature chromatographic unit equipped with three mixed porosity columns (Polymer Laboratories 10 3 , 10 4 , 10 5 , and 10 6 ), operating at a system temperature of 140°C.
  • the solvent is 1,2,4-trichlorobenzene, from which 0.3 percent by weight solutions of the samples are prepared for injection.
  • the flow rate is 1.0 milliliters/minute and the injection size is 200 microliters.
  • the molecular weight determination is deduced by using narrow molecular weight distribution polystyrene standards (from Polymer Laboratories) in conjunction with their elution volumes.
  • the equivalent polyethylene molecular weights are determined by using appropriate Mark-Houwink coefficients for polyethylene and polystyrene (as described by Williams and Word in Tournal of Polymer Science, Polymer Letters, Vol. 6, (621) 1968, incorporated herein by reference) to derive the following equation:
  • M w R WJ* Mj, where WJ and Mj are the weight fraction and molecular weight, respectively, of the i tn fraction eluting from the GPC column.
  • the M /Mn of the homogeneously branched linear ethylene polymers is generally from 1.5 to 2.5.
  • homogeneously branched linear ethylene polymers does not include, by definition, the traditional heterogeneously branched linear low density polyethylenes of linear high density polyethylenes made using Ziegler polymerization processes (e.g., USP 4,076,698 (Anderson et al.)) or the linear homogeneously branched polymers described by Elston (USP 4,645,992) which have a density of 0.915 g/cm 3 or higher, or the branched high pressure polyethylenes and other high pressure ethylene copolymers (e.g., ethylene /vinyl acetate or ethylene/vinyl alcohol copolymers) which are known to those skilled in the art to have numerous long chain branches. Fibers and /or Fabric
  • the fibers claimed herein are elastic.
  • the term "elastic” means that the fiber will recover at least 50 percent of its stretched length after the first pull and after the fourth pull to 100 percent strain (doubled the length). Elasticity can also be described by the "permanent set" of the fiber. Permanent set is the converse of elasticity. A fiber is stretched to a certain point and subsequently released to the original position before stretch, and then stretched again. The point at which the fiber begins to pull a load is designated as the percent permanent set.
  • the percent permanent set correlates with the density of the polymer selected. Generally, the lower the density, the lower the permanent set. For fibers made from a homogeneously branched linear ethylene / ⁇ -olefin polymer having a density less than 0.90 g/cm 3 , the percent permanent set is less than or equal to 50 percent (i.e., the recovery is at least 50 percent).
  • homofil fibers can be made from the novel homogeneously branched linear ethylene polymers.
  • Homofil fibers are those fibers which have a single region (domain) and do not have other distinct polymer regions (as do bicomponent fibers).
  • These homofil fibers include staple fibers, spunbond fibers or melt blown fibers (using, e.g., systems as disclosed in USP 4,340,563 (Appel et al.), USP 4,663,220 (Wineski et al.), USP 4,668,566 (Braun), or USP 4,322,027 (Reba)), and gel spun fibers (e.g., the system disclosed in USP 4,413,110, incorporated herein by reference)).
  • Staple fibers can be melt spun (i.e., they can be extruded into the final fiber diameter directly without additional drawing), or they can be melt spun into a higher diameter and subsequently hot or cold drawn to the desired diameter using conventional fiber drawing techniques.
  • the novel elastic staple fibers disclosed herein can also be used as bonding fibers, especially where the novel elastic fibers have a lower melting point than the surrounding matrix fibers.
  • the bonding fiber is typically blended with other matrix fibers and the entire structure is subjected to heat, where the bonding fiber melts and bonds the surrounding matrix fiber.
  • Typical matrix fibers which benefit from use of the novel elastic fibers includes, but is not limited to: poly(ethylene terephthalate) fibers; cotton fibers; nylon fibers; polypropylene fibers; other heterogeneously branched polyethylene fibers; and linear polyethylene homopolymer fibers.
  • the diameter of the matrix fiber can vary depending upon the end use application illustrated.
  • the melt index can be widely varied, with surprisingly little impact upon the fibers' elasticity. This allows more design flexibility for fabrics and finished articles because the strength and retractive force of the fibers and fabrics can be changed independently of the elasticity.
  • the retractive force of a fiber can be changed by changing the polymer melt index (decreasing the melt index increases the retractive force), rather than the fiber diameter, thus permitting a better optimization of fabric "hand" (i.e., feel) with the necessary elastic/strength fabric performance.
  • Bicomponent fibers can also be made from the homogeneously branched linear ethylene polymers.
  • Such bicomponent fibers have the homogeneously branched linear ethylene polymer in at least one portion of the fiber.
  • the homogeneously branched linear ethylene polymer in either the sheath or the core.
  • Different homogeneously branched linear ethylene polymers can also be used independently as the sheath and the core in the same fiber preferably where both components are elastic and especially where the sheath component has a lower melting point than the core component.
  • bicomponent fibers are within the scope of the invention as well, and include such structures as side-by-side fibers (e.g., fibers having separate regions of polymers, wherein the homogeneously branched linear ethylene polymer comprises at least a portion of the fiber's surface).
  • side-by-side fibers e.g., fibers having separate regions of polymers, wherein the homogeneously branched linear ethylene polymer comprises at least a portion of the fiber's surface.
  • the shape of the fiber is not limited.
  • typical fiber have a circular cross sectional shape, but sometimes fibers have different shapes, such as a trilobal shape, or a flat (i.e., "ribbon” like) shape.
  • the elastic fiber disclosed herein is not limited by the shape of the fiber.
  • Fiber diameter can be measured and reported in a variety of fashions. Generally, fiber diameter is measured in denier per filament. Denier is a textile term which is defined as the grams of the fiber per 9000 meters of that fiber's length. Monofilament generally refers to an extruded strand having a denier per filament greater than 15, usually greater than 30. Fine denier fiber generally refers to fiber having a denier of about 15 or less. Microdenier (aka microfiber) generally refers to fiber having a diameter not greater than about 100 micrometers. For the novel elastic fibers disclosed herein, the diameter can be widely varied, with little impact upon the fiber's elasticity.
  • the fiber denier can be adjusted to suit the capabilities of the finished article and as such, would preferably be: from 0.5 to 30 denier /filament for melt blown; from 1 to 30 denier /filament for spunbond; and from 1 to 20,000 denier/filament for continuous wound filament.
  • Fabrics made from such novel fibers include both woven and nonwoven fabrics.
  • Nonwoven fabrics can be made variously, including spunlaced (or hydrodynamically entangled) fabrics as disclosed in USP 3,485,706 (Evans) and USP 4,939,016 (Radwanski et al.); by carding and thermally bonding staple fibers; by spunbonding continuous fibers in one continuous operation; or by melt blowing fibers into fabric and subsequently calandering or thermally bonding the resultant web.
  • spunlaced (or hydrodynamically entangled) fabrics as disclosed in USP 3,485,706 (Evans) and USP 4,939,016 (Radwanski et al.)
  • carding and thermally bonding staple fibers by spunbonding continuous fibers in one continuous operation; or by melt blowing fibers into fabric and subsequently calandering or thermally bonding the resultant web.
  • the term "consisting essentially of” means that both the homogeneously branched linear ethylene/ ⁇ -olefin polymers used to make the fibers and fabrics can have additional materials which do not materially affect the elasticity of the fibers or fabric.
  • useful nonlimiting additive materials include pigments, antioxidants, stabilizers, surfactants (e.g., as disclosed in USP 4,486,552 (Niemann), USP 4,578,414 (Sawyer et al.) or USP 4,835,194 (Bright et al.)).
  • Fabricated articles which can be made using the novel elastic fibers and fabrics disclosed herein include composite fabric articles (e.g., diapers) that desire elastic portions.
  • elastic portions are desired in diaper waist band portions to prevent the diaper from falling and leg band portions to prevent leakage (as shown in USP 4381,781 (Sciaraffa)).
  • the elastic portions promote better form fitting and /or fastening systems for a good combination of comfort and reliability.
  • the novel elastic fibers and fabrics disclosed herein can also produce structures which combine elasticity with breathability.
  • novel elastic fibers and fabrics disclosed herein can also be used in various structures as described in USP 2,957,512
  • layer 50 of the structure described in USP '512 i.e, the elastic component
  • layer 50 of the structure described in USP '512 can be replaced with the novel elastic fibers and fabrics, especially where flat, pleated, creped, etc., non-elastic materials are made into elastic structures.
  • Attachment of the novel elastic fibers and/or fabric to non-elastic fibers, fabrics or other structures can be done with melt bonding or with adhesives. Gathered or shirred elastic structures can be produced from the new elastic fibers and/or fabrics and non-elastic components by pleating the non-elastic component (as described in USP '512) prior to attachment, prestretching the elastic component prior to attachment, or heat shrinking the elastic component after attachment.
  • novel elastic fibers described herein also can be used in a spunlaced (or hydrodynamically entangled) process to make novel structures.
  • USP 4,801,482 (Goggans) discloses an elastic sheet (12) which can now be made with the novel elastic fibers /fabric described herein.
  • Continuous elastic filaments as described herein could also be used in woven applications where high resilience is desired.
  • the novel elastic fibers and fabrics disclosed herein also have adjustable tenacity and retractive force, which enables design flexibility for variable retractive force in the same garment, if needed, as described for example in USP 5,196,000 (Clear et al.).
  • USP 5,037,416 (Allen et al.) describes the advantages of a form fitting top sheet by using elastic ribbons (see member 19 of USP' 416).
  • the novel elastic fibers could serve the function of member 19 of USP '416, or could be used in fabric form to provide the desired elasticity.
  • the novel elastic fibers have a low melting point (with the melting point of the polymer essentially linearly related to the polymer density), such that in a blend of novel elastic fibers and very high molecular weight polyethylene fibers (e.g., SpectraTM fibers made by Allied Chemical) as described in USP 4,584,347 (Harpell et al.), the lower melting elastic fibers bond the high molecular weight polyethylene fibers without melting the high molecular weight fibers, thus preserving the high strength and integrity of the high molecular weight fiber.
  • the novel elastic fibers and/or fabrics disclosed herein can be substituted for elastic sheet 122, which forms a composite elastic material including a reversibly necked material.
  • the new elastic fibers can also be a melt blown elastic component, as described in reference 6 of the drawings of USP
  • USP '170 generally describes elastic coform material and manufacturing processes.
  • Elastic panels can also be made from the novel elastic fibers and fabrics disclosed herein, and can be used, for example, as members 18, 20, 14, and/or 26 of USP 4,940,464 (Van Gompel).
  • the novel elastic fibers and fabrics described herein can also be used as elastic components of composite side panels (e.g., layer 86 of USP '464).
  • Fibers were produced by extruding the polymer using a one inch (2.54 cm) diameter extruder which feeds a gear pump.
  • the gear pump pushed the material through a spin pack containing a 40 micrometer (average pore size) sintered flat metal filter and a 34 hole spinneret.
  • the spinneret holes had a diameter of 400 micrometers and a land length (i.e, length/diameter or L/D) of 4/1.
  • the gear pump was operated such that about 0.39 grams of polymer were extruded through each hole of the spinneret per minute.
  • Melt temperature of the polymer was typically about 204°C, but varied depending upon the molecular weight of the polymer being spun. Generally the higher the molecular weight, the higher the melt temperature.
  • Quench air (slightly above room temperature (about 25°C) was used to help the melt spun fibers cool.
  • the quench air was located just below the spinneret and blew air across the fiber line as it was extruded.
  • the quench air flow rate was low enough so that it could barely be felt by hand in the fiber area below the spinneret.
  • the fibers were collected on a godet roll having a diameter of about 6 inches (15.24 cm).
  • the godet roll speed was adjustable, but for the experiments demonstrated herein, the godet speed was about 1500 revolutions /minute.
  • the godet roll was located about 3 meters below the spinneret die.
  • Fibers were tested on an Instron tensile testing device equipped with a small plastic jaw on the cross-head (the jaw has a weight of about six gms) and a 500 gram load cell.
  • the jaws were set 1 inch (2.54 cm) apart.
  • the cross head speed was set at 5 inches/minute (12.7 cm/minute).
  • a single fiber was loaded into the Instron jaws for testing.
  • the fiber was then stretched to 100 percent of strain (i.e., it was stretched another 1 inch (2.54 cm)), where the tenacity was recorded.
  • the fiber was allowed to return to the original Instron setting (where the jaws were again 1 inch (2.54 cm) apart) and the fiber was again pulled.
  • the strain was recorded and the percent permanent set was calculated.
  • a fiber pulled for the second time did not provide stress resistance (i.e., pull a load) until it had traveled 0.1 inches (0.25 cm).
  • the percent permanent set was calculated as 10 percent, i.e., the percent of strain at which the fiber begins to provide stress resistance.
  • the numerical difference between the percent permanent set and 100 percent is known as the percent elastic recovery.
  • a fiber having a permanent set of 10 percent will have a 90 percent elastic recovery.
  • the fiber was pulled to 100 percent strain and the tenacity recorded. The fiber pulling process was repeated several times, with the percent permanent set recorded each time and the 100 percent strain tenacity recorded as well. Finally, the fiber was pulled to its breaking point and the ultimate breaking tenacity and elongation were recorded.
  • Example 1 was made from a homogeneously branched ethylene /butene copolymer trademarked TAFMERTM A20090, which is made by Mitsui Petrochemical.
  • Example 2 was made from a homogeneously branched ethylene/butene copolymer trademarked EXACTTM 4023, which is made by Exxon Chemical Corporation.
  • Table 1 summarizes percent permanent set data for melt spun (i.e., no further mechanical drawing) fiber for Examples 1 and 2.
  • Examples 1 and 2 were easily made into fiber and had less permanent set (more resiliency) than comparable examples 3-7.
  • the lower density example 2 had elastic properties rivaling that of comparative examples 8-11, which are currently used commercially, either alone or in combination with traditional non-elastic polymers (e.g., polypropylene or heterogeneously branched linear ethylene polymers).
  • Comparative Examples 3-7 are fibers melt spun from conventional heterogeneously branched ethylene/1-octene polymers (such as DOWLEX® polyethylene and ASPUN® Fiber Grade Resins, both made by The Dow Chemical Company).
  • conventional heterogeneously branched ethylene/1-octene polymers such as DOWLEX® polyethylene and ASPUN® Fiber Grade Resins, both made by The Dow Chemical Company.
  • Comparative Example 8 is a set of rubber fibers/strips made by JPS Corp.
  • Comparative example 9 is LycraTM fiber (made by DuPont).
  • Comparative examples 10, 11 and 12 are elastic components from HuggiesTM Pull Ups diapers (made by Kimberly Clark Corp.). After the polypropylene fabric was stripped off of the elastic side panel, a set of thin strips were cut from the elastic side panels of the diapers and tested as comparable example 10 to simulate performance of individual fibers.
  • the elastic fibers from the waist band of the diapers were identified as polyurethane (by infrared) and were tested as comparative example 11.
  • Fabric cut from the stripped elastic side panel is designated comparative example 12 and had a basis weight of about 0.64-0.69 grams/square inch.
  • Comparative example 12 was tested in accordance with the method used for testing the fibers (but by using a one inch (2.54 cm) by one inch (2.54 cm) square piece of fabric) and had a percent permanent set of about 2 percent after the first pull and a percent permanent set of about 3 percent after the fourth pull.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Nonwoven Fabrics (AREA)
  • Artificial Filaments (AREA)
  • Woven Fabrics (AREA)
  • Multicomponent Fibers (AREA)
  • Absorbent Articles And Supports Therefor (AREA)

Abstract

Fibres et tissus élastiques constitués de polymères d'éthylène linéaires, à ramification homogène, qui peuvent être utilisés pour produire des structures pouvant présenter une compatibilité de recyclage entre les composants élastiques et non élastiques. Les fibres de la présente invention ont une mémoire élastique d'au moins 50 % pour un allongement de 100 %. Ces fibres et tissus sont particulièrement utiles pour produire des articles et des composants desdits articles (par exemple des couches jetables).
EP94913373A 1993-04-27 1994-04-06 Fibres et tissus elastiques et articles fabriques les utilisant Withdrawn EP0696328A1 (fr)

Priority Applications (1)

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EP98106269A EP0859073B1 (fr) 1993-04-27 1994-04-06 Fibres bicomposants avec au moins un composant élastique, tissus et articles les utilisant

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US5358093A 1993-04-27 1993-04-27
US53580 1993-04-27
PCT/US1994/003789 WO1994025648A1 (fr) 1993-04-27 1994-04-06 Fibres et tissus elastiques et articles fabriques les utilisant

Related Child Applications (1)

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EP98106269A Division EP0859073B1 (fr) 1993-04-27 1994-04-06 Fibres bicomposants avec au moins un composant élastique, tissus et articles les utilisant

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EP0696328A1 true EP0696328A1 (fr) 1996-02-14

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EP98106269A Expired - Lifetime EP0859073B1 (fr) 1993-04-27 1994-04-06 Fibres bicomposants avec au moins un composant élastique, tissus et articles les utilisant

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EP (2) EP0696328A1 (fr)
JP (1) JPH08509784A (fr)
CA (1) CA2161429A1 (fr)
DE (2) DE696328T1 (fr)
DK (1) DK0859073T3 (fr)
ES (2) ES2210610T3 (fr)
FI (1) FI955107A0 (fr)
WO (1) WO1994025648A1 (fr)

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US5698480A (en) * 1994-08-09 1997-12-16 Hercules Incorporated Textile structures containing linear low density polyethylene binder fibers
US6117546A (en) * 1996-03-03 2000-09-12 Hercules Incorporated Yarns containing linear low density polyethylene fibers
DE19609419C2 (de) * 1996-03-11 2003-01-30 Inst Polymerforschung Dresden Schmelzgesponnene vernetzte elastische Fäden aus Polyethylen, Verfahren zu ihrer Herstellung und deren Verwendung
ES2194192T3 (es) 1996-03-29 2003-11-16 Fibervisions L P Fibras de polipropileno y articulos producidos a partir de ellas.
US5985193A (en) * 1996-03-29 1999-11-16 Fiberco., Inc. Process of making polypropylene fibers
US7338698B1 (en) 1997-02-28 2008-03-04 Columbia Insurance Company Homogeneously branched ethylene polymer carpet, carpet backing and method for making same
US20030211280A1 (en) 1997-02-28 2003-11-13 Shaw Industries, Inc. Carpet, carpet backings and methods
AR018359A1 (es) * 1998-05-18 2001-11-14 Dow Global Technologies Inc Articulo resistente al calor , configurado, irradiado y reticulado, libre de un agente de reticulacion de silano
ATE339482T1 (de) 1998-06-01 2006-10-15 Dow Global Technologies Inc Verfahren zur herstellung von waschbaren, trocknenden und elastischen gegenständen
US6225243B1 (en) * 1998-08-03 2001-05-01 Bba Nonwovens Simpsonville, Inc. Elastic nonwoven fabric prepared from bi-component filaments
FR2801612B1 (fr) * 1999-11-29 2002-08-30 Aplix Sa Fibre a ame elastique et tissu non tisse elastique
AU2002320481B2 (en) * 2001-07-17 2007-02-15 Dow Global Technologies Inc. Elastic, heat and moisture resistant bicomponent and biconstituent fibers
WO2003008680A1 (fr) * 2001-07-17 2003-01-30 Dow Global Technologies Inc. Fibres elastiques a deux composants et a deux constituants et procede pour produire des structures cellulosiques a partir de celles-ci
JP4155042B2 (ja) 2002-02-20 2008-09-24 チッソ株式会社 弾性長繊維不織布及びこれを用いた繊維製品
US20040260034A1 (en) 2003-06-19 2004-12-23 Haile William Alston Water-dispersible fibers and fibrous articles
US8513147B2 (en) 2003-06-19 2013-08-20 Eastman Chemical Company Nonwovens produced from multicomponent fibers
US7892993B2 (en) 2003-06-19 2011-02-22 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
US7910208B2 (en) 2004-03-03 2011-03-22 Kraton Polymers U.S. Llc Elastomeric bicomponent fibers comprising block copolymers having high flow
US7101623B2 (en) 2004-03-19 2006-09-05 Dow Global Technologies Inc. Extensible and elastic conjugate fibers and webs having a nontacky feel
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US9273417B2 (en) 2010-10-21 2016-03-01 Eastman Chemical Company Wet-Laid process to produce a bound nonwoven article
US8840758B2 (en) 2012-01-31 2014-09-23 Eastman Chemical Company Processes to produce short cut microfibers
US9617685B2 (en) 2013-04-19 2017-04-11 Eastman Chemical Company Process for making paper and nonwoven articles comprising synthetic microfiber binders
US9598802B2 (en) 2013-12-17 2017-03-21 Eastman Chemical Company Ultrafiltration process for producing a sulfopolyester concentrate
US9605126B2 (en) 2013-12-17 2017-03-28 Eastman Chemical Company Ultrafiltration process for the recovery of concentrated sulfopolyester dispersion
JPWO2022181590A1 (fr) * 2021-02-26 2022-09-01
WO2022181591A1 (fr) * 2021-02-26 2022-09-01 東レ株式会社 Non-tissé filé-lié, et fibres conjuguées type à âme enrobée

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Also Published As

Publication number Publication date
DK0859073T3 (da) 2004-03-29
ES2210610T3 (es) 2004-07-01
CA2161429A1 (fr) 1994-11-10
EP0859073A1 (fr) 1998-08-19
FI955107A (fi) 1995-10-26
JPH08509784A (ja) 1996-10-15
WO1994025648A1 (fr) 1994-11-10
DE69433344T2 (de) 2004-04-15
ES2083345T1 (es) 1996-04-16
DE69433344D1 (de) 2003-12-24
FI955107A0 (fi) 1995-10-26
DE696328T1 (de) 1996-10-10
EP0859073B1 (fr) 2003-11-19

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