EP0662506B1 - Verfahren und Vorrichtung zur Kühlung von Partialoxidationsrohgas - Google Patents
Verfahren und Vorrichtung zur Kühlung von Partialoxidationsrohgas Download PDFInfo
- Publication number
- EP0662506B1 EP0662506B1 EP94114403A EP94114403A EP0662506B1 EP 0662506 B1 EP0662506 B1 EP 0662506B1 EP 94114403 A EP94114403 A EP 94114403A EP 94114403 A EP94114403 A EP 94114403A EP 0662506 B1 EP0662506 B1 EP 0662506B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- crude gas
- cooling fluid
- quenching space
- space
- gas duct
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 16
- 230000003647 oxidation Effects 0.000 title claims description 11
- 238000007254 oxidation reaction Methods 0.000 title claims description 11
- 238000001816 cooling Methods 0.000 title claims description 8
- 239000007789 gas Substances 0.000 claims description 100
- 238000010791 quenching Methods 0.000 claims description 91
- 239000012809 cooling fluid Substances 0.000 claims description 23
- 230000000171 quenching effect Effects 0.000 claims description 23
- 239000002893 slag Substances 0.000 claims description 18
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 239000000446 fuel Substances 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
- 238000002309 gasification Methods 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/466—Entrained flow processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/52—Ash-removing devices
- C10J3/526—Ash-removing devices for entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/78—High-pressure apparatus
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
- C10J3/845—Quench rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28C—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
- F28C3/00—Other direct-contact heat-exchange apparatus
- F28C3/02—Other direct-contact heat-exchange apparatus the heat-exchange media both being gases or vapours
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
- C10J2300/0979—Water as supercritical steam
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0075—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for syngas or cracked gas cooling systems
Definitions
- the invention relates to a method for cooling raw gas, by partial oxidation from fine-grained to dusty Fuels in an entrained-flow gasifier in the presence of oxygen and / or air and water vapor Pressures up to 100 bar and temperatures above the Slag melting point is obtained, the raw gas in a vertical raw gas duct with a gaseous or vaporous one Quenching cooling fluid, which is in an annular, vertically downward flow in the Area of the raw gas duct near the wall is introduced into the raw gas duct becomes.
- the invention also relates to a raw gas duct to carry out the procedure.
- the gasification temperatures are in the range from approx. 1500 ° C to approx. 2000 ° C.
- the generated Partial oxidation raw gas flows through the so-called raw gas channel. it cools down through chemical reactions as well by dissipating heat to the cooled walls of the Raw gas channel. This is usually used as the raw gas duct designated that area. the one from the reactor shaft located above the burner level the gasification reactor and the itself immediately following, usually as Radiation cooler pipe section exists, Depending on the height and cooling of the raw gas duct stand behind this temperature of the partial oxidation raw gas between 800 and 1600 ° C on.
- the gas is then used for further cooling to the raw gas duct in a convection cooler or a combined radiation-convection heat exchanger initiated.
- That in the gasification reactor generated partial oxidation raw gas contains however constituent parts that result from the sinking
- caking or deposits can form from sticky or molten ash or slag particles consist. Because of these caking or deposits, that with conventional means only very much gas flow are difficult to remove and impaired heat dissipation from the gas or even completely prevented under certain circumstances.
- the hot one Raw gas flow in the area of the raw gas channel behind the gasification reactor with a lower one Gaseous or vaporous temperature Mix cooling fluid.
- This process which in referred to as quenching by experts with returned cold product gas, another, the desired gas composition is not negatively influencing gas or with water vapor be performed.
- the cooling fluid has an annular channel from top to bottom and occurs in the area where the raw gas channel to the Carburetor connects into the raw gas duct.
- the cooling fluid then flows as a ring flow near the wall in direct current the raw gas to be cooled upwards, the cooling fluid contact of sticky particles of the raw gas with the wall surface prevent the raw gas channel.
- the cooling effect of the quench gas in the known flow control is through indirect cooling supports the wall surface of the raw gas duct.
- the invention is therefore based on the object of a method with the characteristics described above to further develop that, on the one hand, malfunctions due to the formation of deposits is avoided as far as possible be and that on the other hand to carry out the process a raw gas duct that is as simple as possible without disruptive Internals can be used.
- the raw gas channel consists of the one above the burner level of the gasification reactor Reactor shaft 1, to which immediately the lower one above the gasification reactor Quench room 2 connects.
- the lower quench room merges into the upper quench room 3, whose However, the diameter is smaller than the diameter of the lower quench chamber 2.
- the introduction of the quench gas serving as the cooling fluid via the ring channel 4 in the area near the wall upper quench chamber 3.
- To the upper quench chamber 3 closes the radiation cooler Pipe section 5 through which the raw gas channel with the downstream one, in the figure not shown convection cooler or one combined cooler-heat exchanger in connection stands.
- the device When operating the device according to the invention flows through the ring channel 4 introduced Quench gas initially in the area near the wall the upper quench chamber 3 vertically downwards and thus gets into the lower one Quench chamber 2, the diameter of which is larger than the diameter of the upper quench chamber 3.
- the Enlargement of the diameter in the quench chamber 2 is chosen so that thereby under Influence of the upward flowing partial oxidation raw gas the downward flow of the quench gas reversed and thus penetration of quench gas in the reactor shaft 1 is avoided. Rather, the quench gas arrives together with that from the reactor shaft 1 emerging and upward flowing partial oxidation raw gas in the pipe section 5, in which both Gases mixed together and continuing at the same time be cooled.
- the direction of flow of the gases is marked by the arrows in the illustration.
- Quench gas prevents the slag layer 6 out of the lower quench chamber 2 can grow into the upper quench chamber 3.
- the slag layer 6 can still be parallel to Downward flow of quench gas grow and thus form a cone-shaped deposit 7. This However growth is interrupted at the point at which the speed of the downward flowing Quench gas too small and its temperature become too high to melt the die cone-shaped deposit forming slag prevent. Because under certain operating conditions, namely relatively low gasification temperature and high ash melting point of the used Coal, the temperature in the lower quench room 2 may be too low to be cone-shaped Deposits 7 melt and their growth to prevent it in these circumstances expedient if the quench gas supply via the Ring channel 4 periodically interrupted for a short time becomes.
- the quench gas supply can either be completely interrupted or the quench gas is wholly or partly via special induction facilities, the ones in the illustration are not closer are shown. in a preferably oblique downward flow in the upper Quench room 3 initiated. This possibility is in the figure indicated by the arrows 8. In principle, it is of course also possible in this Trap the quench gas inlet in a horizontal or diagonally upward flow to make.
- the quench gas with a digestion that is, with a speed component in the circumferential direction
- the required swirl of the Quench gas can be achieved in this way, for example be that the quench gas contrary to the illustration not from above in the illustration, but is introduced tangentially into the ring channel 4.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Industrial Gases (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4340156A DE4340156A1 (de) | 1993-11-25 | 1993-11-25 | Verfahren und Vorrichtung zur Kühlung von Partialoxidationsrohgas |
DE4340156 | 1993-11-25 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0662506A1 EP0662506A1 (de) | 1995-07-12 |
EP0662506B1 true EP0662506B1 (de) | 1999-02-24 |
Family
ID=6503405
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP94114403A Expired - Lifetime EP0662506B1 (de) | 1993-11-25 | 1994-09-14 | Verfahren und Vorrichtung zur Kühlung von Partialoxidationsrohgas |
Country Status (4)
Country | Link |
---|---|
US (1) | US5571295A (es) |
EP (1) | EP0662506B1 (es) |
DE (2) | DE4340156A1 (es) |
ES (1) | ES2128476T3 (es) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8960651B2 (en) | 2008-12-04 | 2015-02-24 | Shell Oil Company | Vessel for cooling syngas |
US9051522B2 (en) | 2006-12-01 | 2015-06-09 | Shell Oil Company | Gasification reactor |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10330512B4 (de) * | 2003-07-05 | 2006-11-23 | Sustec Schwarze Pumpe Gmbh | Verfahren und Vorrichtung zur Verhinderung von Ablagerungen in Rohgasdurchführungen |
CA2606846C (en) | 2005-05-02 | 2013-12-10 | Shell Internationale Research Maatschappij B.V. | Method and system for producing synthesis gas |
CN101200650B (zh) | 2006-11-01 | 2012-01-18 | 国际壳牌研究有限公司 | 将固体含碳供给料处理成液体的方法 |
DE102007027601A1 (de) * | 2007-06-12 | 2008-12-18 | Uhde Gmbh | Herstellung und Kühlung von gasförmigen Kohlevergasungsprodukten |
WO2009065841A1 (en) | 2007-11-20 | 2009-05-28 | Shell Internationale Research Maatschappij B.V. | Process for producing a purified synthesis gas stream |
CN101348735B (zh) * | 2008-08-26 | 2012-07-25 | 浙江大学 | 流化床裂解煤气净化和焦油回收系统及方法 |
WO2010040764A2 (en) | 2008-10-08 | 2010-04-15 | Shell Internationale Research Maatschappij B.V. | Process to prepare a gas mixture of hydrogen and carbon monoxide |
CN102264679B (zh) | 2008-12-22 | 2014-07-23 | 国际壳牌研究有限公司 | 制备甲醇和/或二甲醚的方法 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2971830A (en) * | 1958-06-18 | 1961-02-14 | Sumitomo Chemical Co | Method of gasifying pulverized coal in vortex flow |
NL178134C (nl) * | 1974-06-17 | 1986-02-03 | Shell Int Research | Werkwijze en inrichting voor het behandelen van een heet produktgas. |
DE2504060A1 (de) * | 1975-01-31 | 1976-08-05 | Otto & Co Gmbh Dr C | Unter druck arbeitender schlackenbadgenerator |
DE2710154C2 (de) * | 1977-03-09 | 1982-09-23 | Dr. C. Otto & Comp. Gmbh, 4630 Bochum | Unter Druck und hoher Temperatur arbeitender Gaserzeuger |
US4279622A (en) * | 1979-07-13 | 1981-07-21 | Texaco Inc. | Gas-gas quench cooling and solids separation process |
US4466808A (en) * | 1982-04-12 | 1984-08-21 | Texaco Development Corporation | Method of cooling product gases of incomplete combustion containing ash and char which pass through a viscous, sticky phase |
GB8312103D0 (en) * | 1983-05-04 | 1983-06-08 | Shell Int Research | Cooling and purifying hot gas |
US4494963A (en) * | 1983-06-23 | 1985-01-22 | Texaco Development Corporation | Synthesis gas generation apparatus |
US4581899A (en) * | 1984-07-09 | 1986-04-15 | Texaco Inc. | Synthesis gas generation with prevention of deposit formation in exit lines |
DE3427088C2 (de) * | 1984-07-18 | 1987-05-07 | Korf Engineering GmbH, 4000 Düsseldorf | Vorrichtung zum Abkühlen eines heißen Produktgases |
DE3808729A1 (de) * | 1988-03-16 | 1989-10-05 | Krupp Koppers Gmbh | Verfahren und vorrichtung zur abkuehlung des aus einem vergasungsreaktor austretenden heissen produktgases |
DE3809313A1 (de) * | 1988-03-19 | 1989-10-05 | Krupp Koppers Gmbh | Verfahren und vorrichtung zum kuehlen von partialoxidationsgas |
DE3816340A1 (de) * | 1988-05-13 | 1989-11-23 | Krupp Koppers Gmbh | Verfahren und vorrichtung zum kuehlen eines heissen produktgases, das klebrige bzw. schmelzfluessige partikel enthaelt |
-
1993
- 1993-11-25 DE DE4340156A patent/DE4340156A1/de not_active Withdrawn
-
1994
- 1994-09-14 EP EP94114403A patent/EP0662506B1/de not_active Expired - Lifetime
- 1994-09-14 DE DE59407843T patent/DE59407843D1/de not_active Expired - Fee Related
- 1994-09-14 ES ES94114403T patent/ES2128476T3/es not_active Expired - Lifetime
- 1994-11-22 US US08/343,105 patent/US5571295A/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9051522B2 (en) | 2006-12-01 | 2015-06-09 | Shell Oil Company | Gasification reactor |
US8960651B2 (en) | 2008-12-04 | 2015-02-24 | Shell Oil Company | Vessel for cooling syngas |
Also Published As
Publication number | Publication date |
---|---|
ES2128476T3 (es) | 1999-05-16 |
DE4340156A1 (de) | 1995-06-01 |
DE59407843D1 (de) | 1999-04-01 |
US5571295A (en) | 1996-11-05 |
EP0662506A1 (de) | 1995-07-12 |
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