EP0651048A2 - Formulation liquide moussante antibactérienne pour le nettoyage de surfaces de cuisine - Google Patents

Formulation liquide moussante antibactérienne pour le nettoyage de surfaces de cuisine Download PDF

Info

Publication number
EP0651048A2
EP0651048A2 EP94203078A EP94203078A EP0651048A2 EP 0651048 A2 EP0651048 A2 EP 0651048A2 EP 94203078 A EP94203078 A EP 94203078A EP 94203078 A EP94203078 A EP 94203078A EP 0651048 A2 EP0651048 A2 EP 0651048A2
Authority
EP
European Patent Office
Prior art keywords
weight percent
nonionic surfactant
formulation
alcohol ethoxylate
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP94203078A
Other languages
German (de)
English (en)
Other versions
EP0651048A3 (fr
Inventor
Janet G. C/O Eastman Kodak Company Gardella
Robert Paul C/O Eastman Kodak Company Manzo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt Benckiser LLC
Original Assignee
Eastman Kodak Co
Reckitt and Colman Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co, Reckitt and Colman Inc filed Critical Eastman Kodak Co
Publication of EP0651048A2 publication Critical patent/EP0651048A2/fr
Publication of EP0651048A3 publication Critical patent/EP0651048A3/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines

Definitions

  • This invention relates to formulations for manually washing dishes.
  • Kitchen surfaces include counter tops, stove tops, dishes and any other hard surface commonly found in kitchen environments.
  • the term “dishes” includes any utensils involved in food preparation or consumption. Kitchen surfaces, particularly dishes, must be washed free of food residues, greases, proteins, starches, gums, dyes, oils and burnt organic residues.
  • anionic synthetic surfactants with or without a nonionic surfactant.
  • Many of such formulations contain a sulphonate-type anionic surfactant, for example, an alkylbenzene sulphonate or an alkane sulfonate, in conjunction with a sulphate or alkyl ether sulphate, or a nonionic surfactant, for example, an alcohol ethoxylate, an alkyl phenol ethoxylate, a mono- or diethanolamide or an amine oxide.
  • the sulphonate material generally predominates.
  • anionic surfactants are incompatible with cationic quaternary antimicrobial surfactants and nonionic surfactants do not normally provide significant foaming capability to liquid formulations. Therefore current dish washing formulations can only mechanically eliminate bacteria from kitchen hard surfaces. They are not effective in killing or controlling the spread of germs throughout the kitchen environment. Thus dish washing liquids combining good foaming and antimicrobial activities are not available to the consumer.
  • the present invention provides an aqueous disinfecting liquid formulation for cleaning hard surfaces, particularly dishes, in a kitchen environment; wherein said formulation is free of anionic surfactants and consisting essentially of:
  • This formulation of this invention will control the presence and spread of bacteria on hard surfaces in the kitchen environment, especially dishes.
  • This invention is a microbiological active quaternary ingredient homogeneously incorporated into a nonionic aqueous surfactant system. Unexpectedly the formulation has good flash foaming and residual foaming capability although no anionic surfactants are included.
  • Optional ingredients can include fragrances, dyes and stabilizers.
  • the purpose of the quaternary ammonium disinfectants is to kill on contact gram positive and gram negative organisms the organisms encountered in kitchen environments.
  • Useful such disinfectants include BTC 8358 which is N- Alkyl (50% C14, 40% C12, and 10% C16) dimethyl benzyl ammonium chloride.
  • quaternary ammonium salt may be any of the well-known class of quaternary ammonium germicides characterized by the formula: wherein at least one of the radicals R1, R2, R3 and R4 is a hydrophobic, aliphatic, aryl aliphatic, or aliphatic aryl radical of from 6 to 26 carbon atoms and the entire cation portion of the molecule has a molecular weight of at least 165.
  • the hydrophobic radicals may be long-chain alkyl, long-chain alkoxy aryl, long-chain alkyl aryl, halogen-substituted long-chain alkyl aryl, long-chain alkyl phenoxy alkyl, aryl alkyl, and so forth, in nature.
  • the remaining radicals on the nitrogen atom other than the hydrophobic radicals are substituents of hydrocarbon structure usually containing a total of no more than 12 carbon atoms.
  • the radical X in the above formula is any salt-forming anionic radical.
  • Suitable quaternary ammonium salts within the above description include the alkyl ammonium halides such as cetyl trimethyl ammonium bromide, alkyl aryl ammonium halides such as octadecyl dimethyl benzyl ammonium bromide, N-alkyl pyridinium halides such as N-cetyl pyridinium bromide, and the like.
  • quaternary ammonium salts include those in which the molecule contains either, amide or ester linkages such as octyl phenoxy ethoxy ethyl dimethyl benzyl ammonium chloride, N-(laurylcocoaminoformylmethyl) - pyridinium chloride, and so forth
  • Other very effective types of quaternary ammonium germicides are those in which the hydrophobic radical is characterized by a substituted aromatic nucleus as in the case of lauryloxyphenyltrimethyl ammonium chloride, cetylaminophenyltrimethyl ammonium methosulfate, dodecylphenyltrimethyl ammonium methosulfate, dodecylbenzyltrimethyl ammonium chloride, chlorinated dodecylbenzyltrimethyl ammonium chloride, and the like.
  • Preferred quaternary ammonium germicides of the above general types are the long-chain alkyl dimethylbenzyl quaternary ammonium salts, the alkyl phenoxy alkoxy alkyl dimethyl benzyl quaternary ammonium salts, the N-(acylcocoaminoformylmethyl)pyridinium halides, the long-chain alkyl trimethyl ammonium halides, the long-chain alkyl benzyl dimethyl benzyl ammonium halides, and the long-chain alkyl benzyl diethyl ethanol ammonium halides in which the alkyl radical contains from 8-18 carbon atoms.
  • This nonionic system for cleaning standard food and kitchen soils is through emulsification of the soils.
  • Current anionic light duty liquids solubilize most food soils. When soil is emulsified within a system, it will affect the type, density and amount of foam that can be generated. In general, emulsified fatty soils will reduce the amount of foam that can be generated as further cleaning takes place. Since anionic systems solubilize soils, the effect on the foam is not as great as with nonionic systems. Therefore, foam generated from anionic systems is of greater volume and more stable throughout the cleaning process.
  • anionic surfactant systems such as those found in the current light duty liquids are classified as high foamers. Conversely, nonionic surfactant systems are classified as low foamers.
  • the challenge was to achieve disinfection activity while producing consumer acceptable foam using a nonionic and cationic surfactant combination.
  • a surfactant mixture expressed in Example 1, Table 1, that produce consumer acceptable foam comparable to commercial dish washing liquids using anionic detergents.
  • the useful nonionic surfactants have various chain lengths and degrees of ethoxylation that allow the dish washing liquid to be effective on a wide range of food soils while providing good flash foam volume as well as moderate foam stability. This system provides the consumer with effective cleaning on, but not limited to, greasy food soils, fatty food soils, and oily food soils while maintaining disinfection.
  • the unexpected foaming properties of the formulations of the invention are illustrated in this example.
  • the foaming properties are due to the carefully balanced mix of nonionic surfactants.
  • the formulation tested in this example contained the preferred concentration of ingredients listed in Table 1.
  • Table 1 Preferred Range Ammonyx LO (30%) 5.00 0.5-20.0 Mirataine CBS (43%) 5.00 1.0-20.0 Neodol 25-12 5.00 0.5-20.0 Neodol 23-6.5 5.00 0.5-20.0 Mackam DZ (35%) 5.00 1.5-20.0 Mackamide C 5.00 0.5-20.0 BTC 8358 (80%) 1.40 0.5-15.0 Uvinul D-50 0.02 0.0- 0.1 Disodium EDTA 1.00 0.2- 2.0 BHT 0.10 0.0- 0.2 Fragrance 0.35 0.0- 0.5 Liquitint Patent Blue (1%) 0.08 0.0- 0.5 Water, DI 67.05 35.0-85.0
  • the formulation was prepared by adding the water, Ammonyx LO and Mirataine CBS to a beaker and mixing until uniform. Neodol 25-12 and Mackamide C were combined and then added to the beaker and mixed until uniform. Next Neodol 23-6.5 and UvindulD-50 were combined, added to the beaker and mixed until uniform. Finally Mackam DZ, BTC 8358 and EDTA were added to the beaker in sequence and mixed until uniform. The BHT and fragrance are premixed until uniform and then added to the beaker.
  • Deionized water (512g at 120 o F) was mixed with 2g of the Table 1 preferred formulation in a 1500 mL beaker. The mixture was then beaten with a hand held egg beater mix for 50 revolutions or cycles. The foam height was measured at 15 minutes and 30 minutes intervals for the unloaded diluted dish washing liquid.
  • the commercial formulation to which the formulation of this invention was compared was an anionic based dishwashing liquid.
  • the formulation of the invention had a foam height of 25.4mm for the loaded water and 50.8mm for the unloaded water.
  • the commercial liquid had a foam height of 25.4mm for the loaded and 63.5mm for the unloaded.
  • the formulation in example 1 was tested for antimicrobial activity effectiveness against Staphylococcus aureus (ATCC 6538) and Salmonella choleraesuis (ATCC 6538) by AOAC Use Dilution Method as described in AOAC 15th Edition, 1990.
  • the test was carried out at a dilution of 1 part formulation to 256 parts deionized water, at 5 minutes contact time and at different temperatures. This test is used microbiological activity for practical disinfection on hard surface carriers.
  • a carrier is contaminated with test microorganisms through immersion in a broth culture. After the carrier is dried, it is immersed for 10 minutes with the individual formulation to be evaluated. The carrier, in a nutrient medium, is incubated for 48 hours.
  • Table 3 illustrates the disinfection activity of the formulation of example 1 at 5 minutes contact time and 40°C.
  • Examples 1 and 2 show that antibacterial dishwashing liquid formulation of the invention both cleans and kill bacteria present in the kitchen environment. This includes, but is not limited to dishes, counter tops, sink and dishwasher.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)
EP94203078A 1993-11-01 1994-10-22 Formulation liquide moussante antibactérienne pour le nettoyage de surfaces de cuisine. Withdrawn EP0651048A3 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14654493A 1993-11-01 1993-11-01
US146544 1993-11-01

Publications (2)

Publication Number Publication Date
EP0651048A2 true EP0651048A2 (fr) 1995-05-03
EP0651048A3 EP0651048A3 (fr) 1995-10-11

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EP94203078A Withdrawn EP0651048A3 (fr) 1993-11-01 1994-10-22 Formulation liquide moussante antibactérienne pour le nettoyage de surfaces de cuisine.

Country Status (2)

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EP (1) EP0651048A3 (fr)
CA (1) CA2132274A1 (fr)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997006230A1 (fr) * 1995-08-04 1997-02-20 Reckitt & Colman Inc. Compositions de nettoyage et/ou de desinfection a effet d'opalescence pour surfaces dures
EP0691397A3 (fr) * 1994-07-07 1997-03-05 Clorox Co Produit de nettoyage antimicrobien pour surface dure
WO1997039094A1 (fr) * 1996-04-15 1997-10-23 Stepan Company Composition detergente a haut pouvoir moussant a base d'agents tensioactifs non ioniques
US5728672A (en) * 1995-08-04 1998-03-17 Reckitt & Colman Inc. Pine oil hard surface cleaning compositions
WO1998014060A1 (fr) * 1996-09-30 1998-04-09 Albemarle Corporation Compositions herbicides et regulatrices de la croissance des vegetaux et utilisation correspondante
WO1999013036A1 (fr) * 1997-09-10 1999-03-18 Albemarle Corporation Substance permettant de nettoyer les surfaces dures sans frotter
WO1999016854A1 (fr) * 1997-09-30 1999-04-08 Reckitt Benckiser Inc. Compositions acides epaissies pour le nettoyage et la desinfection
WO1999019438A1 (fr) * 1997-10-15 1999-04-22 Stepan Company Composition de detergent a fort moussage presentant une base de tensioactifs non ioniques
WO1999031216A1 (fr) * 1997-12-12 1999-06-24 Colgate-Palmolive Company Microemulsion antimicrobienne multifonction renfermant un tensio-actif cationique
US6017860A (en) * 1996-04-15 2000-01-25 Stepan Company Cleaning, conditioning and styling hair care compositions
EP1092763A2 (fr) * 1999-10-12 2001-04-18 Inui Corporation Composition détergente anti microbienne
WO2001053442A2 (fr) * 2000-01-24 2001-07-26 Colgate-Palmolive Company Composition de nettoyage antimicrobienne contenant un tensioactif cationique
US6284723B1 (en) 1995-07-26 2001-09-04 Boli Zhou Antimicrobial hard surface cleaner
US6339057B1 (en) 1997-04-14 2002-01-15 Stepan Company High foaming detergent composition having a non-ionic surfactant base
WO2002076207A1 (fr) * 2001-03-27 2002-10-03 The Dial Corporation Compositions antibacteriennes
WO2004009754A1 (fr) * 2002-07-24 2004-01-29 Reckitt Benckiser Inc Nettoyants pour surfaces dures
US7163783B2 (en) * 2001-08-23 2007-01-16 Fuji Photo Film Co., Ltd. Rinse-processing composition for processing silver halide color photographic material, processing apparatus and processing method
US7229956B2 (en) * 2000-09-25 2007-06-12 Reckitt Benckiser (Uk) Limited Anti-static cleaning wipes
WO2007079022A2 (fr) * 2005-12-30 2007-07-12 The Dial Corporation Compositions antibactériennes comprenant des germicides à base d'ammonium quaternaire et des oxydes d'alcamines et ayant un potentiel d'irritation réduit
GB2504377A (en) * 2012-05-25 2014-01-29 Rhodia Operations Surfactant composition and method of unloading a liquid from a hydrocarbon reservoir
JP2018529822A (ja) * 2015-09-28 2018-10-11 エコラボ ユーエスエー インコーポレイティド 硬水使用のためのｄｅａを含まない深鍋および平鍋用の洗浄剤

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WO2007142919A2 (fr) 2006-05-30 2007-12-13 The Dial Corporation Compositions ayant une efficacité antivirale élevée
CA2654079A1 (fr) 2006-06-02 2008-03-27 The Dial Corporation Methode destinee a inhiber la transmission du virus influenza
US8648027B2 (en) 2012-07-06 2014-02-11 The Clorox Company Low-VOC cleaning substrates and compositions comprising a cationic biocide
US9096821B1 (en) 2014-07-31 2015-08-04 The Clorox Company Preloaded dual purpose cleaning and sanitizing wipe
US10982177B2 (en) 2017-09-18 2021-04-20 The Clorox Company Cleaning wipes with particular lotion retention and efficacy characteristics
US10973385B2 (en) 2017-09-18 2021-04-13 The Clorox Company Cleaning wipes having particular pore volume distribution characteristics
US10975341B2 (en) 2017-09-18 2021-04-13 The Clorox Company Cleaning wipes having particular MABDF characteristics
US10973386B2 (en) 2017-09-18 2021-04-13 The Clorox Company Cleaning wipes system having particular performance characteristics
US11273625B2 (en) 2018-12-21 2022-03-15 The Clorox Company Process for manufacturing multi-layer substrates comprising sandwich layers and polyethylene

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GB1115300A (en) * 1964-10-06 1968-05-29 Procter & Gamble Detergent compositions
US3983079A (en) * 1973-09-04 1976-09-28 The Procter & Gamble Company Dishwashing composition
EP0004121A1 (fr) * 1978-03-13 1979-09-19 THE PROCTER & GAMBLE COMPANY Compositions détergentes pour le linge à faible teneur en phosphate
GB2075043A (en) * 1980-04-23 1981-11-11 Flanagan J J Surfactant System
EP0107118A1 (fr) * 1982-10-04 1984-05-02 Richardson-Vicks, Inc. Shampooing pour le conditionnement des cheveux
EP0152194A2 (fr) * 1984-01-25 1985-08-21 The Procter & Gamble Company Compositions de shampooing
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GB1115300A (en) * 1964-10-06 1968-05-29 Procter & Gamble Detergent compositions
US3983079A (en) * 1973-09-04 1976-09-28 The Procter & Gamble Company Dishwashing composition
EP0004121A1 (fr) * 1978-03-13 1979-09-19 THE PROCTER & GAMBLE COMPANY Compositions détergentes pour le linge à faible teneur en phosphate
GB2075043A (en) * 1980-04-23 1981-11-11 Flanagan J J Surfactant System
EP0107118A1 (fr) * 1982-10-04 1984-05-02 Richardson-Vicks, Inc. Shampooing pour le conditionnement des cheveux
EP0152194A2 (fr) * 1984-01-25 1985-08-21 The Procter & Gamble Company Compositions de shampooing
JPH02184609A (ja) * 1989-01-10 1990-07-19 Sanyo Chem Ind Ltd 殺菌剤組成物

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Cited By (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0691397A3 (fr) * 1994-07-07 1997-03-05 Clorox Co Produit de nettoyage antimicrobien pour surface dure
US6284723B1 (en) 1995-07-26 2001-09-04 Boli Zhou Antimicrobial hard surface cleaner
CN1087770C (zh) * 1995-08-04 2002-07-17 雷基特-科尔曼公司 起霜型的硬表面清洁和/或消毒组合物
WO1997006230A1 (fr) * 1995-08-04 1997-02-20 Reckitt & Colman Inc. Compositions de nettoyage et/ou de desinfection a effet d'opalescence pour surfaces dures
US5728672A (en) * 1995-08-04 1998-03-17 Reckitt & Colman Inc. Pine oil hard surface cleaning compositions
AU700516B2 (en) * 1995-08-04 1999-01-07 Reckitt Benckiser Inc. Blooming type, hard surface cleaning and/or disinfecting compositions
AU748069B2 (en) * 1996-04-15 2002-05-30 Stepan Company High foaming detergent composition having a non-ionic surfactant base
US6017860A (en) * 1996-04-15 2000-01-25 Stepan Company Cleaning, conditioning and styling hair care compositions
US6218346B1 (en) 1996-04-15 2001-04-17 Stepan Company Methods for cleaning, conditioning and styling hair
WO1997039094A1 (fr) * 1996-04-15 1997-10-23 Stepan Company Composition detergente a haut pouvoir moussant a base d'agents tensioactifs non ioniques
WO1998014060A1 (fr) * 1996-09-30 1998-04-09 Albemarle Corporation Compositions herbicides et regulatrices de la croissance des vegetaux et utilisation correspondante
US6339057B1 (en) 1997-04-14 2002-01-15 Stepan Company High foaming detergent composition having a non-ionic surfactant base
WO1999013036A1 (fr) * 1997-09-10 1999-03-18 Albemarle Corporation Substance permettant de nettoyer les surfaces dures sans frotter
WO1999016854A1 (fr) * 1997-09-30 1999-04-08 Reckitt Benckiser Inc. Compositions acides epaissies pour le nettoyage et la desinfection
US6239092B1 (en) 1997-09-30 2001-05-29 Reckitt Benckiser Inc. Thickened acidic, hard surface cleaning and disinfecting compositions particularly useful for ceramic surfaces
WO1999019438A1 (fr) * 1997-10-15 1999-04-22 Stepan Company Composition de detergent a fort moussage presentant une base de tensioactifs non ioniques
WO1999031216A1 (fr) * 1997-12-12 1999-06-24 Colgate-Palmolive Company Microemulsion antimicrobienne multifonction renfermant un tensio-actif cationique
EP1092763A3 (fr) * 1999-10-12 2003-02-12 Inui Corporation Composition détergente anti microbienne
EP1092763A2 (fr) * 1999-10-12 2001-04-18 Inui Corporation Composition détergente anti microbienne
WO2001053442A3 (fr) * 2000-01-24 2001-12-20 Colgate Palmolive Co Composition de nettoyage antimicrobienne contenant un tensioactif cationique
WO2001053442A2 (fr) * 2000-01-24 2001-07-26 Colgate-Palmolive Company Composition de nettoyage antimicrobienne contenant un tensioactif cationique
US7229956B2 (en) * 2000-09-25 2007-06-12 Reckitt Benckiser (Uk) Limited Anti-static cleaning wipes
WO2002076207A1 (fr) * 2001-03-27 2002-10-03 The Dial Corporation Compositions antibacteriennes
US6616922B2 (en) 2001-03-27 2003-09-09 The Dial Corporation Antibacterial compositions
US7163783B2 (en) * 2001-08-23 2007-01-16 Fuji Photo Film Co., Ltd. Rinse-processing composition for processing silver halide color photographic material, processing apparatus and processing method
WO2004009754A1 (fr) * 2002-07-24 2004-01-29 Reckitt Benckiser Inc Nettoyants pour surfaces dures
AU2003281521B2 (en) * 2002-07-24 2009-05-21 Reckitt Benckiser Llc Acidic hard surface cleaners
WO2007079022A2 (fr) * 2005-12-30 2007-07-12 The Dial Corporation Compositions antibactériennes comprenant des germicides à base d'ammonium quaternaire et des oxydes d'alcamines et ayant un potentiel d'irritation réduit
WO2007079022A3 (fr) * 2005-12-30 2007-08-23 Dial Corp Compositions antibactériennes comprenant des germicides à base d'ammonium quaternaire et des oxydes d'alcamines et ayant un potentiel d'irritation réduit
GB2504377A (en) * 2012-05-25 2014-01-29 Rhodia Operations Surfactant composition and method of unloading a liquid from a hydrocarbon reservoir
JP2018529822A (ja) * 2015-09-28 2018-10-11 エコラボ ユーエスエー インコーポレイティド 硬水使用のためのｄｅａを含まない深鍋および平鍋用の洗浄剤
US10689599B2 (en) 2015-09-28 2020-06-23 Ecolab Usa Inc. DEA-free pot and pan cleaner for hard water use

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CA2132274A1 (fr) 1995-05-02
EP0651048A3 (fr) 1995-10-11

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