EP0638100A1 - Liquid curable resin composition - Google Patents

Liquid curable resin composition

Info

Publication number
EP0638100A1
EP0638100A1 EP93907275A EP93907275A EP0638100A1 EP 0638100 A1 EP0638100 A1 EP 0638100A1 EP 93907275 A EP93907275 A EP 93907275A EP 93907275 A EP93907275 A EP 93907275A EP 0638100 A1 EP0638100 A1 EP 0638100A1
Authority
EP
European Patent Office
Prior art keywords
meth
acrylate
composition
compound
polyols
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP93907275A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0638100A4 (en
Inventor
Tohru Ohtaka
Shinichirou Jsr Apartment 14-101 Iwanaga
Tsuyoshi Watanabe
Katutoshi Jsr Apartment 2-201 Igarashi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Desotech Inc
Original Assignee
DSM Desotech Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DSM Desotech Inc filed Critical DSM Desotech Inc
Publication of EP0638100A4 publication Critical patent/EP0638100A4/en
Publication of EP0638100A1 publication Critical patent/EP0638100A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/82—Coating or impregnation with organic materials
    • C04B41/83—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • C03C17/322—Polyurethanes or polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/104—Coating to obtain optical fibres
    • C03C25/106—Single coatings
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48—Macromolecular compounds
    • C04B41/483—Polyacrylates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/487—Polyethers containing cyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C08G18/673—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen containing two or more acrylate or alkylacrylate ester groups

Definitions

  • compositions in which- these polyether copolymers are used have drawbacks still to be solved. That is, urethane acrylates using these polyether copolymers are insufficient in one or more of the characteristics, including resistance to ultraviolet light, heat resistance, light resistance (resistance against changing its color into yellow under light radiation) , heat resistance (resistance against changing its color into yellow when heated), and flexibility.
  • Such a polyol compound (A) can be prepared by the ring- opening polymerization of ethylene oxide, 1,2-alkylene oxides with 4 or more carbon atoms, e.g, 1,2-butylene oxide, 1,2- hexene oxide, or the like, and one or more compounds selected from polytetramethylene glycol r bisphenol A, and bisphenol F, by a known method.
  • the covered optical fibers were prepared at drawing speeds of 180, 360, and 720 m/min, and subjected to the tests according to the following methods. The results are shown in Table 2.
  • the fibers were dried in a vacuum drier at 50°C for 12 hours, then after standing for one hour at room temperature the final weight (dry weight: Wl) was determined.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Ceramic Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Structural Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
EP93907275A 1992-04-20 1993-03-09 Liquid curable resin composition Withdrawn EP0638100A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP09959692A JP3220221B2 (ja) 1992-04-20 1992-04-20 液状硬化性樹脂組成物
JP99596/92 1992-04-20
PCT/US1993/002037 WO1993021248A1 (en) 1992-04-20 1993-03-09 Liquid curable resin composition

Publications (2)

Publication Number Publication Date
EP0638100A4 EP0638100A4 (en) 1994-12-15
EP0638100A1 true EP0638100A1 (en) 1995-02-15

Family

ID=14251484

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93907275A Withdrawn EP0638100A1 (en) 1992-04-20 1993-03-09 Liquid curable resin composition

Country Status (5)

Country Link
EP (1) EP0638100A1 (ja)
JP (1) JP3220221B2 (ja)
AU (1) AU671442B2 (ja)
CA (1) CA2118421A1 (ja)
WO (1) WO1993021248A1 (ja)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5373578A (en) * 1993-12-21 1994-12-13 At&T Corp. Strippable coating for optical fiber
JP3288869B2 (ja) * 1994-10-14 2002-06-04 ジェイエスアール株式会社 液状硬化性樹脂組成物
JPH09143233A (ja) * 1995-11-28 1997-06-03 Japan Synthetic Rubber Co Ltd 光硬化性液状樹脂組成物
JP3756585B2 (ja) * 1996-09-05 2006-03-15 Ｊｓｒ株式会社 光硬化性液状樹脂組成物
JP3634592B2 (ja) * 1997-01-08 2005-03-30 セイコーエプソン株式会社 接着固定物、電子機器および時計
US6023547A (en) * 1997-06-09 2000-02-08 Dsm N.V. Radiation curable composition comprising a urethane oligomer having a polyester backbone
US6085010A (en) * 1997-06-11 2000-07-04 Dsm N.V. Optical glass fiber ribbon assemblies and radiation-curable compositions for use in forming ribbon assemblies
US6048911A (en) * 1997-12-12 2000-04-11 Borden Chemical, Inc. Coated optical fibers
US6391936B1 (en) 1997-12-22 2002-05-21 Dsm N.V. Radiation-curable oligomers radiation-curable compositions, coated optical glass fibers, and ribbon assemblies
JP4141613B2 (ja) 2000-03-09 2008-08-27 富士通株式会社 密閉サイクル冷凍装置および密閉サイクル冷凍装置用乾式蒸発器
JP2003246826A (ja) * 2002-02-19 2003-09-05 Dsm Nv 液状硬化性樹脂組成物
JP2012038499A (ja) * 2010-08-05 2012-02-23 Jsr Corp 電線被覆層形成用放射線硬化性樹脂組成物
JP2013151678A (ja) * 2011-12-29 2013-08-08 Sanyo Chem Ind Ltd 活性エネルギー線硬化性組成物
JP7439761B2 (ja) * 2018-09-10 2024-02-28 株式会社レゾナック エポキシ樹脂、エポキシ樹脂組成物、エポキシ樹脂硬化物及び複合材料

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2910714A1 (de) * 1978-03-30 1979-10-11 Kao Corp Durch bestrahlung haertbare harzueberzugsmasse
JPS62148514A (ja) * 1985-12-24 1987-07-02 Yokohama Rubber Co Ltd:The 紫外線硬化型樹脂組成物
JPS63109699A (ja) * 1986-10-28 1988-05-14 Yokohama Rubber Co Ltd:The 放射線・紫外線硬化型ダンピング材組成物
US4844604A (en) * 1987-11-13 1989-07-04 Desoto, Inc. Optical fiber bundling material and bundled optical fibers
US5093386A (en) * 1989-05-16 1992-03-03 Stamicarbon B.V. Liquid curable plastic composition
WO1992006846A1 (en) * 1990-10-19 1992-04-30 Dsm Desotech, Inc. Curable liquid resin composition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4507458A (en) * 1983-04-14 1985-03-26 Takeda Chemical Industries, Ltd. Urethane acrylate compositions

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2910714A1 (de) * 1978-03-30 1979-10-11 Kao Corp Durch bestrahlung haertbare harzueberzugsmasse
JPS62148514A (ja) * 1985-12-24 1987-07-02 Yokohama Rubber Co Ltd:The 紫外線硬化型樹脂組成物
JPS63109699A (ja) * 1986-10-28 1988-05-14 Yokohama Rubber Co Ltd:The 放射線・紫外線硬化型ダンピング材組成物
US4844604A (en) * 1987-11-13 1989-07-04 Desoto, Inc. Optical fiber bundling material and bundled optical fibers
US5093386A (en) * 1989-05-16 1992-03-03 Stamicarbon B.V. Liquid curable plastic composition
WO1992006846A1 (en) * 1990-10-19 1992-04-30 Dsm Desotech, Inc. Curable liquid resin composition

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 108, no. 4, January 1988, Columbus, Ohio, US; abstract no. 23177a, TAKAHASHI ET AL 'UV-CURABLE POLYURETHANE ACRYLATE RUBBER COMPOSITIONS FOR COATING OPTICAL FIBERS' page 63 ;column 1 ; & JP-A-62 148 514 (YOKOHAMA RUBBER) *
CHEMICAL ABSTRACTS, vol. 110, no. 8, February 1989, Columbus, Ohio, US; abstract no. 59081v, IRII ET AL 'RADIATION- AND ULTRAVIOLET-CURABLE ACRYLIC URETHANE DAMPING COMPOSITIONS' & JP-A-63 109 699 (YOKOHAMA RUBBER) 14 May 1988 *
See also references of WO9321248A1 *

Also Published As

Publication number Publication date
WO1993021248A1 (en) 1993-10-28
AU671442B2 (en) 1996-08-29
EP0638100A4 (en) 1994-12-15
CA2118421A1 (en) 1993-10-28
JPH0680756A (ja) 1994-03-22
AU3793393A (en) 1993-11-18
JP3220221B2 (ja) 2001-10-22

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Inventor name: IGARASHI, KATUTOSHI, JSR APARTMENT 2-201

Inventor name: WATANABE, TSUYOSHI

Inventor name: IWANAGA, SHINICHIROU, JSR APARTMENT 14-101

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