EP0620271A1 - Reinigungsmittel in Form einer Mikroemulsion enthaltend einen Glykolmonoalkylether - Google Patents

Reinigungsmittel in Form einer Mikroemulsion enthaltend einen Glykolmonoalkylether Download PDF

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Publication number
EP0620271A1
EP0620271A1 EP94302639A EP94302639A EP0620271A1 EP 0620271 A1 EP0620271 A1 EP 0620271A1 EP 94302639 A EP94302639 A EP 94302639A EP 94302639 A EP94302639 A EP 94302639A EP 0620271 A1 EP0620271 A1 EP 0620271A1
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Prior art keywords
composition
cosurfactant
carbon atoms
ether
salt
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English (en)
French (fr)
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Steven Taylor Adamy
Barbara Jean Thomas
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Colgate Palmolive Co
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Colgate Palmolive Co
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C11D17/0021—Aqueous microemulsions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • This invention relates to microemulsion cleaning compositions having enhanced degrees of oil uptake and superior cleaning performance and in particular to cleaning compositions that leave lower surface residues following their use.
  • Liquid detergent compositions in emulsion form have been employed as all-purpose detergents for cleaning hard surfaces, such as, painted woodwork, bathtubs, sinks, tile floors, tiled walls, linoleum, paneling and washable wallpaper.
  • microemulsions were developed as a more efficient method of removing lipophilic/materials from substrates. These microemulsions include a lipophile, a surfactant, a cosurfactant and water. They are a thermodynamically stable phase in which the micelles have a particle size of less than 100nm (nanometers), are transparent with no Tyndall scattering and do not separate over long periods of time. Microemulsions can solubilize oil without the use of expensive hydrotropes or vigorous mixing. They show very low interfacial tensions with oil and so will spread on soil surfaces aiding cleaning.
  • Microemulsions have certain disadvantages which make their application to practical problems difficult and often unpredictable. For example, in order to apply this technology to a particular problem, it is necessary to determine the ternary phase diagram for said system. In addition careful consideration must be taken of the surfactant and cosurfactant to be used. Microemulsions are sensitive to electrolytes and the phase behavior of each system must be well understood when diluting it. They are sensitive to oil chain length and foaming at high concentrations of surfactant.
  • the cosurfactants of this reference have substantially no ability to dissolve oily or greasy soil and are selected from the group consisting of, among other entities, water-soluble alkanols have 3 to 4 carbon atoms, polypropylene glycol ethers, and monoalkyl ethers and esters of ethylene glycol or propylene glycol having 1 to 4 carbon atoms.
  • cosurfactants of this reference are selected from the group consisting of, among other compounds, water soluble alkanols, of 2 to 4 carbon atoms, polypropylene glycol of 2 to 18 propoxy units, a monoalkyl ether of a lower glycol of the formula RO(X) n H wherein R is C1 ⁇ 4alkyl and X is CH2CH2O, CH(CH3)CH2O or CH2CH2CH2O and n is from 1 to 4.
  • liquid detergent composition which in liquid crystal form comprises one or more nonionic detergents with lesser amounts of anionic or cationic surfactants, a cosurfactant, such as tripropylene glycol butyl ether, a solvent for the soil, such as, an isoparaffin (9-11 carbons) or methyl cocoate and water as the major component.
  • a cosurfactant such as tripropylene glycol butyl ether
  • a solvent for the soil such as, an isoparaffin (9-11 carbons) or methyl cocoate and water as the major component.
  • aqueous microemulsion comprising an anionic and/or nonionic synthetic organic detergent, water-insoluble perfume, water and cosurfactant where the cosurfactant adjusts interfacial conformation to reduce interfacial tension between dispersed and continuous phases of said detergents, perfume and water and therefore produces a stable microemulsion.
  • This composition does not contain any solvents for oils and greases other than the perfume.
  • a microemulsion cleaning composition meeting the objects given above has been developed which comprises on a weight basis of the entire composition:
  • composition may additionally contain as optional components such materials as dyes, perfumes, foam controllers, thickeners and the like.
  • perfume is used in its ordinary sense to refer to and include any non water-soluble fragrant substance or mixture of substances including natural (i.e., obtained by extraction of flower, herb, blossom or plant), artificial (i.e., a mixture of natural oils or oil constituents) and synthetic (i.e., a single or mixture of synthetically produced substance) odoriferous substances.
  • perfumes are complex mixtures of blends of various organic compounds, such as, esters, ketones, hydrocarbons, lactones, alcohols. aldehydes, ethers.
  • perfume aromatic compounds and varying amounts of essential oils (e.g., terpenes) such as from 0% to 80%, usually from 10% to 70% by weight, the essential oils themselves being volatile odoriferous compounds and also serving to dissolve the other components of the perfume.
  • essential oils e.g., terpenes
  • the precise composition of the perfume has no particular effect on cleaning performance so long as it meets the criteria of water immiscibility and pleasant odor.
  • perfume is not, per se, a solvent for greasy or oily soil, - even though some perfumes may, in fact, contain as much as 80% of terpenes which are known as good grease solvents - they have the capacity to enhance oil uptake in the compositions of this invention.
  • Another ingredient that may be optionally added to the composition of this invention is an inorganic or organic salt or oxide of a multivalent metal cation, particularly Mg++.
  • the metal or oxide can provide several benefits including improved cleaning performance in dilute usage.
  • Other polyvalent metal ions that can also be used include aluminum, copper, nickel, iron and the like.
  • a foam suppressant in the claimed compositions is desired, minor amounts, i.e., from 0.1% to 2.0%, preferably from 0.25% to 1.0% by weight of the composition of a fatty acid or fatty acid soap having 8 to 22 carbon atoms can be incorporated.
  • the instant compositions do not contain any cationic, nonionic or anionic emulsifier surfactants such as those set forth at Column 8, line 16 to line 61 of U.S. Patent 5,171,475, which is hereby incorporated by reference.
  • the temperatures used to prepare the claimed compositions and to clean products with them is not critical. ambient temperatures being sufficient. For removing oily soils or deposits from surfaces a range of 5 to 50°C is preferred.
  • the range of pH of the composition is not critical and can be 5.0 to 9.0 or even from 2.0 to 13.0.
  • anionic organic surface active agent Although one can use from 1 to 40% of the range of anionic organic surface active agent, it is preferred to use 3 to 20% by weight. This is also the preferred range for nonionic surface active agent, when used.
  • the amount of cosurfactant employed is preferably 1 to 40% with a range of 1 to 15% being even more preferred.
  • the preferred electrolyte is sodium chloride but is not narrowly critical and so other metal salts can also be used.
  • alkali metals including potassium and lithium, alkaline earth metals. including barium, calcium and strontium and polyvalent metals, such as, aluminum, copper, nickel, iron and the like may be used with such anions as halides, sulfates. nitrates, hydroxides, oxides, acetates and the like.
  • the preferred halide is chloride although bromide, iodide or fluoride can be used if desired.
  • the preferred quantitative limits for the electrolytes is 0 to 5% with 0 to 1% being particularly preferred.
  • Suitable organic surface active agents include water-soluble, non-soap, anionic detergents as well as mixtures of said anionic detergents with water-soluble nonionic and polar nonionic detergents.
  • Exemplary anionic detergents include those compounds which contain an organic hydrophobic group containing 8 to 22 carbon atoms and preferably 10 to 18 carbon atoms in their molecular structure and at least one water-solubilizing group, such as. sulfonate, sulfate or carboxylate. Usually, the hydrophobic group, will comprise a 8-22 carbon alkyl, alkenyl or acyl group.
  • These detergents are employed in the form of water-soluble salts and the salt-forming cation is usually sodium, potassium, ammonium. magnesium, 2-3 carbon mono-, di- or tralkanolammonium cations.
  • anionic sulfate detergents are the 8-18 carbon alkyl sulfate salts and alkyl ether polyethenoxy sulfate salts having the formula R(OC2H4) n OSO3M wherein R is an alkyl group having 8-18 carbon atoms, n is 1 to 12 and M is a solubilizing cation, e.g., sodium, potassium, ammonium, magnesium and mono-, di- and triethanol ammonium ions.
  • the alkyl sulfate salts may be obtained by reducing glycerides of coconut oil or tallow and neutralizing the product with bases derived from metals in Groups I, II or III of the Deming Periodic Table.
  • alkyl ether polyethenoxy sulfates are obtained by sulfating the condensation product of ethylene oxide with an 8-18 carbon alkanol and neutralizing the product.
  • Preferred alkyl sulfates and alkyl ether polyethenoxy sulfates contain 10 to 16 carbon atoms in the alkyl moiety.
  • Particularly preferred alkyl sulfates are sodium lauryl sulfate and sodium myristyl sulfate.
  • the water-soluble nonionic surfactants that are employed are the condensation product of an organic aliphatic or alkyl aromatic hydrophobic compound having a carboxy, hydroxy, amido or amino group with a free hydrogen attached to the nitrogen atom can be condensed with ethylene oxide or with the polyhydration product thereof, polyethylene glycol, to form a nonionic detergent.
  • the length of the polyethenoxy chain can be adjusted to achieve the desired balance between the hydrophobic and hydrophilic elements (HLB) and such balances may be measured by HLB numbers.
  • Suitable nonionic surfactants are the condensation products of a higher alcohol containing 8 to 18 carbon atoms in a straight or branched chain configuration condensed with 0.5 to 30 moles of ethylene oxide.
  • Preferred compounds are a 9 to 11 carbon alkanol ethoxylate (5EO) and a 12 to 15 carbon alkanol ethoxylate (7EO). These preferred compounds are commercially available from Shell Chemical Co. under the tradenames, Dobanol 91-5 and Neodol 25-7.
  • Another group of suitable nonionic surfactants sold under the tradename Pluronics. are condensation products of ethylene with the condensation products of propylene oxide and propylene glycol.
  • surfactants are the polycondensation products of ethylene oxide and alkyl phenols, like nonyl phenol.
  • cosurfactants in this invention having the structure RO(X)nH where R, X and n are as defined above which are particularly useful over temperatures of 5C and 43C wherein x is an alkylene or dialkylene group having 1 to 4 carbon atoms, more preferably 2 to 3 carbon atoms.
  • Useful cosurfactants are: ethylene glycol monohexyl ether, ethylene glycol monoheptyl ether. ethylene glycol monooctyl ether, ethylene glycol monononyl ether.
  • diethylene glycol monohexyl ether diethylene glycol monoheptyl ether, diethylene glycol monooctyl ether, triethylene glycol monohexyl ether, propylene glycol monohexyl ether, isopropropylene glycol monohexyl ether and the like.
  • These surfactants may be synthesized by condensing an alkanol having 6 to 9 carbon atoms with ethylene oxide, 1,2-propylene glycol, or 1,3-propylene glycol respectively.
  • Figure 1a is a ternary phase diagram showing dodecane uptake in a system containing ethylene glycol monohexyl ether (C6E1) as cosurfactant.
  • C6E1 ethylene glycol monohexyl ether
  • Figure 1b is a ternary phase diagram showing dodecane uptake in a system containing diethylene glycol monohexyl ether (C6E2) as cosurfactant.
  • C6E2 diethylene glycol monohexyl ether
  • Figure 2a is a ternary phase diagram showing dodecane uptake in a system containing ethylene glycol monobutyl ether (C4E1) as cosurfactant.
  • C4E1 ethylene glycol monobutyl ether
  • Figure 2b is a ternary phase diagram showing dodecane uptake in a system containing diethylene glycol monobutyl ether (C4E2) as cosurfactant.
  • C4E2 diethylene glycol monobutyl ether
  • Figure 3 is a two dimensional graph showing dodecane uptake in a system containing either diethylene glycol monohexyl (C6E2) or monobutyl ether (C4E2) as cosurfactant with a mixture of anionic and nonionic surfactants.
  • C6E2 diethylene glycol monohexyl
  • C4E2 monobutyl ether
  • Figure 4 is a two dimensional graph showing triolein uptake as a function of the amount of dodecane solubilized in an ethylene glycol monohexyl ether (C6E1) system.
  • Figure 5 is a two dimensional graph showing triolein uptake as a function of the amount of dodecane solubilized in a diethylene glycol monohexyl ether (C6E2) system.
  • Figure 6 is a two dimensional graph showing neat grease cleaning of two prototype microemulsions.
  • Figure 7 is a two dimensional graph showing grease cleaning with diluted microemulsions.
  • solubilizing power of systems employing ethylene glycol monohexyl ether (available as Hexyl Cellosoive from Union Carbide Chemicals and Plastics Co. Inc.) and diethylene glycol monohexyl ether (available as Hexyl Carbitol from Union Carbide Chemicals Co. Inc.) as cosurfactants were compared with systems employing ethylene glycol monobutyl ether (available as Butyl Cellosolve from Union Carbide Chemicals and Plastics Co. Inc.) and diethylene glycol monobutyl ether (available as Butyl Carbitol from Union Carbide Chemicals and Plastics Co. Inc.) using n-dodecane as the material being solubilized.
  • ethylene glycol monohexyl ether available as Hexyl Cellosoive from Union Carbide Chemicals and Plastics Co. Inc.
  • diethylene glycol monohexyl ether available as Hexyl Carbitol from Union Carbide Chemicals Co. Inc
  • Solubilization capacities for n-dodecane i.e., the amount of n-dodecane which can be solubilized in a microemulsion so that the dispersion remains homogeneous. transparent and stable. were plotted in Figures 1a-b and 2a-b.
  • the systems described are composed of 0.15M NaCl (aqueous) brine, sodium lauryl sulfate (as the surfactant SLS) and either ethylene glycol monohexyl ether (1a), diethylene glycol monohexyl ether (1b), ethylene glycol monobutyl ether (2a) or diethylene glycol monobutyl ether (2b).
  • n-dodecane solubilization capacities are shown in the form of contours of equal oil uptake plotted on the brine/SLS/cosurfactant triangular phase diagram.
  • Figures 1a-b and 2a-b represent partial phase diagrams. only going up to 50% SLS and 50% cosurfactant.
  • the 2.5% contour lies on a composition point of 85% brine, 11% SLS and 4% ethylene glycol monohexyl ether (C6E1). This means that in 100g of an 85% brine, 11% SLS, 4% C6E1, 2.5g of dodecane may be solubilized before the mixture separates into two liquid phases.
  • Figure 1a shows that a composition of 90% brine, 5.0% SLS, and 5% ethylene glycol monohexyl ether can solubilize 5% dodecane; a composition with diethylene glycol monohexyl ether instead can solubilize 1% dodecane.
  • ethylene glycol monobutyl ether nor diethylene glycol monobutyl ether systems in like compositions were able to solubilize any significant amounts of dodecane.
  • the ethylene glycol monohexyl ether system can solubilize 6% dodecane.
  • Like systems with ethylene glycol monobutyl ether and diethylene glycol monobutyl ether are able to solubilize only 2% and 1% dodecane, respectively.
  • Figure 1a shows that at high levels of surfactant, cosurfactant and dodecane, liquid crystals are formed.
  • Figure 3 shows the dodecane uptake capacity of a system containing diethylene glycol monohexyl ether compared with a system containing diethylene glycol monobutyl ether.
  • a mixture of Mg lauryl sulfate and Neodol 25-7 (a straight chain nonionic surfactant with 12-15 carbon atoms and 7 ethoxy groups, available from Shell Chemical Co.) was used at a total concentration of 6%.
  • the weight fraction of the Neodol 25-7 was varied from 0 to 1.
  • the cosurfactant, diethylene glycol monohexyl ether or diethylene glycol monobutyl ether was kept constant at 3%. Perfume was added at a level of 0.8% in order to form the microemulsion.
  • Neodol 25-7 Except at very high weight fractions of Neodol 25-7, the dodecane uptake was significantly higher for diethylene glycol monohexyl ether as cosurfactant than for diethylene glycol monobutyl ether, the oil solubility being nearly doubled.
  • triolein is the oil to be solubilized.
  • microemulsions were preformed with dodecane as a solubilized hydrocarbon and uptake capacities of triolein in these systems measured.
  • triolein uptake in systems without dodecane has also been measured.
  • Figures 4 and 5 show triolein uptake in two example ethylene glycol monohexyl ether systems as a function of the amount of dodecane solubilized.
  • the amount of dodecane is represented as a percentage calculated by equation (1) given above.
  • Figure 4 shows that in a composition of 5% of SLS, 5% ethylene glycol monohexyl ether, 90% brine with 1.4% dodecane solubilized (as defined in Equation1), 0.14% triolein (as defined by Equation2) may be solubilized.
  • Figure 5 shows that triolein uptake in the diethylene glycol monohexyl ether system, where a composition of 12.5% SLS, 12.5% diethylene glycol monohexyl ether, 75% brine can solubilize a maximum of 1.55% triolein when 3.6% dodecane is presolubilized.
  • compositions A & B In order to test grease cleaning performance, two prototype all-purpose cleaner formulations were prepared and are shown below in Table 1 as compositions A & B.
  • Table 1 Composition of Formulas Tested Material A B Mg Lauryl Sulfate 3.0 3.0 Neodol 25-7 3.0 3.0 Diethylene glycol mono butyl ether 3.0 Diethylene glycol mono hexyl ether 3.0 Perfume 0.8 0.8 Water q.s. q.s.
  • Figures 6 and 7 show a comparison of the grease cleaning ability of formulae A and B when used neat (undiluted) and diluted.
  • Formula B containing diethylene glycol monohexyl ether, cleans significantly faster than formula A.
  • both formulae perform equally well.
  • diethylene glycol monohexyl ether shows enhanced grease cleaning on neat application and equal cleaning upon dilution when compared with diethylene glycol monobutyl ether.
  • a mixture of 50% hard tallow and 50% soft tallow dyed with D&C Red #17 was applied to new Formica tiles (15cm x 15cm) by spraying a chloroform solution with an air brush.
  • a 10% solution of the grease was used while for dilute, a 2% solution was used. In both cases, a 0.01% solution of the dye was used.
  • For Neat cleaning 1.0% of each formula was applied to sponges which were previously saturated with tap water and wrung out.
  • sponges were saturated with 1.2% solutions of the formulae in tap water. The sponges were placed in holders and placed on a sled of a Gardner Abrader apparatus. Each sponge holder contained 270 g of lead shot.
  • the abrader was allowed to operate for the desired number of strokes and the percent reflectance of the tile was measured. For neat,. the operation was continued stopping after 1, 3, 5, 10, 20, 35 and 50 strokes. For dilute, the sponges and holders were removed after every 15 strokes so that the sponges could be wrung out and replenished with solution.
  • the % cleaning was calculated according to the following ratio: Cleaned tile reflectance-soiled tile reflectance Unsoiled tile reflectance-soiled tile reflectance x 100

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
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  • Detergent Compositions (AREA)
EP94302639A 1993-04-14 1994-04-13 Reinigungsmittel in Form einer Mikroemulsion enthaltend einen Glykolmonoalkylether Withdrawn EP0620271A1 (de)

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US4853893A 1993-04-14 1993-04-14
US48538 1993-04-14
US19169794A 1994-02-04 1994-02-04
US191697 1998-11-13

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EP0620271A1 true EP0620271A1 (de) 1994-10-19

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EP (1) EP0620271A1 (de)
JP (1) JPH06330098A (de)
CN (1) CN1093743A (de)
AU (1) AU675500B2 (de)
BR (1) BR9401481A (de)
CA (1) CA2117274A1 (de)
HU (1) HUT66866A (de)
MY (1) MY110708A (de)
NZ (1) NZ260307A (de)
PT (1) PT101489B (de)
TR (1) TR27650A (de)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2297926A (en) * 1995-02-17 1996-08-21 Hats Ltd Diagnostic test-tube
WO1998022569A2 (en) * 1996-11-21 1998-05-28 Colgate-Palmolive Company Microemulsion all purpose liquid cleaning compositions
WO1998026655A1 (en) * 1996-12-18 1998-06-25 S. C. Johnson & Son, Inc. Microemulsion insect control compositions
WO1998055587A1 (en) * 1997-06-06 1998-12-10 Colgate-Palmolive Company Microemulsion all purpose liquid cleaning compositions
WO2008077641A1 (en) * 2006-12-22 2008-07-03 Biofrontera Bioscience Gmbh Nanoemulsion
US20110250239A1 (en) * 2010-04-09 2011-10-13 Biofrontera Bioscience Gmbh Pharmaceutical and/or cosmetic composition for treating the skin
CN109354368A (zh) * 2018-11-22 2019-02-19 国网天津市电力公司电力科学研究院 一种变电站事故油池含油污泥处理方法

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AU675833B2 (en) * 1994-03-23 1997-02-20 Amway Corporation Concentrated all-purpose light duty liquid cleaning composition and method of use
US6593279B2 (en) * 1999-12-10 2003-07-15 Integrity Industries, Inc. Acid based micro-emulsions
WO2011037229A1 (ja) * 2009-09-28 2011-03-31 株式会社 資生堂 可溶化剤及びそれを含む可溶化組成物
CN105296179A (zh) * 2015-11-19 2016-02-03 吴庆春 一种皂基环保洗衣液

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US5076954A (en) * 1986-05-21 1991-12-31 Colgate-Palmolive Company Stable microemulsion cleaning composition

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2297926A (en) * 1995-02-17 1996-08-21 Hats Ltd Diagnostic test-tube
WO1998022569A2 (en) * 1996-11-21 1998-05-28 Colgate-Palmolive Company Microemulsion all purpose liquid cleaning compositions
WO1998022569A3 (en) * 1996-11-21 1998-08-13 Colgate Palmolive Co Microemulsion all purpose liquid cleaning compositions
WO1998026655A1 (en) * 1996-12-18 1998-06-25 S. C. Johnson & Son, Inc. Microemulsion insect control compositions
US6028117A (en) * 1996-12-18 2000-02-22 S. C. Johnson & Son, Inc. Microemulsion insect control compositions
WO1998055587A1 (en) * 1997-06-06 1998-12-10 Colgate-Palmolive Company Microemulsion all purpose liquid cleaning compositions
WO2008077641A1 (en) * 2006-12-22 2008-07-03 Biofrontera Bioscience Gmbh Nanoemulsion
AU2007338323B2 (en) * 2006-12-22 2013-07-11 Biofrontera Bioscience Gmbh Nanoemulsion
US11540981B2 (en) 2006-12-22 2023-01-03 Biofrontera Bioscience Gmbh Nanoemulsion formulation with improved stability and cell penetration
US20110250239A1 (en) * 2010-04-09 2011-10-13 Biofrontera Bioscience Gmbh Pharmaceutical and/or cosmetic composition for treating the skin
CN109354368A (zh) * 2018-11-22 2019-02-19 国网天津市电力公司电力科学研究院 一种变电站事故油池含油污泥处理方法

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CA2117274A1 (en) 1994-10-15
PT101489B (pt) 2000-11-30
CN1093743A (zh) 1994-10-19
JPH06330098A (ja) 1994-11-29
AU675500B2 (en) 1997-02-06
AU5948094A (en) 1994-10-20
NZ260307A (en) 1995-03-28
BR9401481A (pt) 1994-10-18
HUT66866A (en) 1995-01-30
TR27650A (tr) 1995-06-14
HU9401062D0 (en) 1994-07-28
PT101489A (pt) 1995-05-04

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