EP0619366A1 - Blocs pour toilettes contenant de l'oxygène actif - Google Patents

Blocs pour toilettes contenant de l'oxygène actif Download PDF

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Publication number
EP0619366A1
EP0619366A1 EP93200961A EP93200961A EP0619366A1 EP 0619366 A1 EP0619366 A1 EP 0619366A1 EP 93200961 A EP93200961 A EP 93200961A EP 93200961 A EP93200961 A EP 93200961A EP 0619366 A1 EP0619366 A1 EP 0619366A1
Authority
EP
European Patent Office
Prior art keywords
lavatory
acid
cleansing block
lavatory cleansing
source
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP93200961A
Other languages
German (de)
English (en)
Inventor
Stefano Scialla
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP93200961A priority Critical patent/EP0619366A1/fr
Priority to CA 2159821 priority patent/CA2159821A1/fr
Priority to PCT/US1994/003163 priority patent/WO1994023002A1/fr
Priority to JP6522178A priority patent/JPH08508769A/ja
Priority to AU64146/94A priority patent/AU6414694A/en
Publication of EP0619366A1 publication Critical patent/EP0619366A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0056—Lavatory cleansing blocks
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2082—Polycarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3942—Inorganic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3945—Organic per-compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers

Definitions

  • the present invention relates to a solid lavatory cleansing block.
  • the blocks are environmentally safe and provide multiple benefits.
  • the object of the present invention is to provide an environmentally safe lavatory cleansing block for use as in-rim and in-cistern type lavatory blocks.
  • the lavatory block should have good bactericidal activity and sanitizing and cleansing performance. Additionally, the block should provide limescale removal and improved odor and stain removal.
  • An advantage of the present invention is that the ingredients remain permanently active in the water of the lavatory bowl in between flushes.
  • the blocks according to the present invention thus provide the unexpected benefit that said blocks prevent the formation of limescale in said lavatory bowl.
  • EP-A-234 626 discloses a solid lavatory cleansing block which contains an oxygen-type bleaching agent as in the present invention, but contains no acid.
  • DE 3407 456 A1 discloses a solid bleaching block for in-cistern use. There is no acid component in this block.
  • EP-A-462 643 discloses a rim-type solid lavatory cleansing block.
  • the preferred water soluble bleaching agent therein is potassium dichloro cyanurate. Potassium dichloro cyanurate is not completely environmentally compatible whereas the sources of active oxygen as in the present invention are completely environmentally safe.
  • the present invention is a solid lavatory cleansing block comprising a source of active oxygen, an acid and a surfactant, whereby said lavatory block provides a permanent aqueous solution having a pH below 7 and comprising from 1ppm to 500ppm active oxygen as said block is progressively dissolved in the lavatory bowl water.
  • the present invention relates to a solid lavatory cleansing block.
  • in-cistern and in-rim type lavatory blocks There are two types of blocks available on the market at present, in-cistern and in-rim type lavatory blocks.
  • the in-rim type blocks are distinct from in-cistern type blocks in that they are designed to be hung from the rim of the lavatory bowl, in a conventional type rim cage.
  • the in-cistern type blocks are designed to be placed in the cistern itself. Depending on the positioning of the block the properties of the active ingredients will vary, depending on the length of time the block is immersed in water.
  • the lavatory blocks of the present invention contained herein are designed to be used as both in-rim and in-cistern type lavatory blocks.
  • the blocks according to the present invention progressively dissolve in water, thereby releasing the ingredients in solution.
  • a permanent aqueous solution is provided in the lavatory bowl which comprises a constant and predetermined amount of various ingredients.
  • the lavatory blocks of the present invention comprise as an essential feature the combination of a source of active oxygen with an acid.
  • the first essential component according to the present invention is a source of active oxygen selected from hydrogen peroxide or a source thereof, preformed peroxyacids, organic peroxides and mixtures thereof and provides 1ppm to 500ppm, preferably from 5ppm to 300ppm, most preferably from 10ppm to 200ppm of active oxygen in said lavatory bowl water.
  • active oxygen concentration refers to the percentage concentration of elemental oxygen, with an oxidation number zero, that being reduced to water would be stoichiometrically equivalent to a given percentage concentration of a given peroxide compound, when the peroxide functionality of the peroxide compound is completely reduced to oxides.
  • the available oxygen sources according to the present invention increase the ability of the lavatory blocks to remove coloured organic stains.
  • the concentration of available oxygen can be determined by methods known in the art, such as the iodimetric method, the permanganometric method and the cerimetric method. Said methods and the criteria for the choice of the appropriate method are described for example in "Hydrogen Peroxide", W. C. Scumb, C. N. Satterfield and R. L. Wentworth, Reinhold Publishing Corporation, New York, 1955 and "Organic Peroxides", Daniel Swern, Editor Wiley Int. Science, 1970.
  • the active oxygen concentration according to the present invention can be determined by the iodimetric method, whereby the active oxygen solution is added to 50cc of a solution of 1% potassium iodide acidified with 1cc of 1:4 sulphuric acid, preferably in the presence of a trace of ammonium molybdate as a catalyst. After stirring and allowing to stand for 5 minutes, the iodine liberated is titrated with thiosulphate solution, with or without the use of a starch indicator.
  • the active oxygen concentration according to the present invention can also be determined for example by the permanganate method, whereby the active oxygen solution is acidified with sulphuric acid and titrated with a 0.1M potassium permanganate solution.
  • the end point can be determined either visibly or potentiametrically.
  • the active oxygen concentration according to the present invention can also be determined for example by the cerimetric method, whereby the active oxygen solution is acidified with sulphuric acid and titrated with a 0.1M potassium permanganate solution.
  • the end point can be determined potentiometrically or with a redox indicator such as ferrous-1,10-phenanthroline.
  • a hydrogen peroxide source refers to any compound which produces hydrogen peroxide when said compound is in contact with water.
  • Suitable water-soluble sources of hydrogen peroxide for use herein include persulphates, percarbonates, metal oxides and perborates.
  • Suitable preformed peroxyacids for use in the lavatory blocks according to the present invention include diperoxydodecandioic acid DPDA, magnesium perphthalate, perlauric acid, perbenzoic acid, diperoxyazelaic acid and mixtures thereof.
  • the blocks according to the present invention comprise from 0.01% to 30% of said preformed peroxyacids.
  • Suitable organic peroxides for use in the lavatory blocks according to the present invention include diacyl and dialkyl peroxides such as dibenzoyl peroxide, dilauroyl peroxide, dicumyl peroxide and mixtures thereof.
  • the blocks according to the present invention comprise from 0.01% to 30% of said organic peroxides.
  • the lavatory blocks may additionally comprise from 0% to 30%, preferably from 5% to 20% of peracid precursors, i.e. compounds that upon reaction with hydrogen peroxide produce peroxyacids.
  • peracid precursors suitable for use in the present invention can be found among the classes of esters, amides, imides and anhydrides such as acetyl triethyl citrate (ATC) described for instance in EP 91 87 0207, tetra acetyl ethylene diamine (TAED), succinic or maleic anhydrides. All of these bleaching agents are environmentally compatible and odourless.
  • a second essential component of the blocks according to the present invention is an acid.
  • the acid is used to ensure that the pH of the lavatory bowl water is below pH 7, preferably below pH 6.5, more preferably below pH 6.
  • some acids can have the advantage that they can form small concentrations of the corresponding peracids by reaction with hydrogen peroxide in-situ, thus enhancing the overall performance of the lavatory block.
  • These acids can be further selected so as to have chelating and/or building properties.
  • the acids of the present invention that may be used for these purposes can be organic or inorganic acids, preferably organic acids such as citric, maleic, oxalic succinic and tartaric acids, most preferably citric and maleic acids.
  • the third essential ingredient of the lavatory blocks according to the present invention is at least 10% of a surfactant.
  • a surfactant increases the cleansing performance of the lavatory blocks and provides the solid matrix in which all other ingredients can be incorporated.
  • Suitable surfactants for use herein include anionic and nonionic surfactants or mixtures thereof.
  • the anionic surfactants which may be used in the present invention include for example alkali metal salts of alkyl substituted benzene sulphonates, alkali metal alkyl sulphonates, alkali metal alkyl sulphates and alkali metal alkyl ether sulphates derived from for example fatty alcohols and alkyl phenols, alkali metal alkane sulphonates, alkali metal olefin sulphonates and alkali metal sulphosuccinates, whereby the sodium salts are preferred. Most preferred are sodium alkyl metal sulphonates and sulphates.
  • nonionic surfactants which may be used can be chosen from any liquid or solid ethoxylated C6-C24 fatty alcohol nonionic surfactant, fatty acid C6-C24 alkanolamides, C6-C20 polyethylglycol ethers, polyethylene glycol with molecular weight 1000 to 80000 and C6-C24 amine oxides.
  • the lavatory blocks of the invention may further comprise 0% to 50%, preferably 5% to 30% fillers of inorganic salts such as sodium sulphate, sodium carbonate, sodium silicate and less preferably phosphorous sodium salts, for example sodium triphosphate, or inert fillers such as clay, urea or calcite.
  • inorganic salts such as sodium sulphate, sodium carbonate, sodium silicate and less preferably phosphorous sodium salts, for example sodium triphosphate, or inert fillers such as clay, urea or calcite.
  • the fillers can be used to adjust the mechanistic properties of the lavatory blocks so that the active ingredients are released in the desired manner.
  • composition differences in the composition of the in-rim and in-cistern type lavatory blocks of the present invention can be exclusively but not necessarily dependant on the type of surfactants, fillers and polymers used therein, which can determine the dissolution rate.
  • the composition differences are well-known in the art.
  • In-cistern type lavatory blocks can preferably contain surfactants with a lower solubilization rate and may be chosen from long chain higher anionics or nonionics with a high degree of ethoxylation.
  • In-cistern type lavatory blocks may also contain specific ingredients to decrease the solubilization rate such as slowly dissolving polymers or oils.
  • the lavatory block of the present invention may also contain a number of optional ingredients.
  • One such ingredient is a chelant system.
  • Said chelant system improves the overall limescale/rust removal performance.
  • the chelant system may improve the stability of the hydrogen peroxide in the formulation.
  • Suitable chelants may be chosen from EDTA, NTA or preferably from biodegradable chelants such as s,s-ethylene diamino disuccinate and dipicolinic acid.
  • the blocks according to the present invention may further comprise from 0% to 20%, preferably 3% to 15% of an enzyme system.
  • the enzyme system assists in the removal of faecal, urine and grease stains which are found in the lavatory bowl.
  • Suitable enzymes that may be used herein include lipases, proteases, cellulases and amylases preferably lipases.
  • perfumes and dyes used to improve the aesthetics of the lavatory block. These perfumes and dyes contained in the lavatory block are selected for their stability in the presence of sources of active oxygen.
  • said blocks comprise a perfume and a dye
  • the lavatory cleansing block is formed by conventional methods well-known in the art as described for instance in EP-A-462 643.
  • the ingredients are mixed to form a dough of suitable consistency which can then be extruded and cut into lengths to form blocks.
  • the extrusion process can be carried out by using simple conventional extrusion equipment such as usually used for manufacturing soap bars.
  • the lavatory blocks may be prepared by compressing all of the ingredients into a block.
  • compositions are made by premixing all of the listed ingredients in the listed proportions except the source of active oxygen which is added to the mixture just prior to the extrusion process.
  • EXAMPLES No. 1,2 1 2 Ingredients Weight % Sodium Dodecyl Benzene Sulphonate 50 55 Lauryl Ether Sulphate - 2 Lutensol AO3O 5 - Sodium Persulphate - 13 Sodium Percarbonate 14 - Sodium Sulphate 13 10 Citric Acid 13 15 Perfume 4 4 Dyes or pigments, water Balance Balance EXAMPLES No.
EP93200961A 1993-04-05 1993-04-05 Blocs pour toilettes contenant de l'oxygène actif Withdrawn EP0619366A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP93200961A EP0619366A1 (fr) 1993-04-05 1993-04-05 Blocs pour toilettes contenant de l'oxygène actif
CA 2159821 CA2159821A1 (fr) 1993-04-05 1994-03-23 Blocs lavabos contenant de l'oxygene actif
PCT/US1994/003163 WO1994023002A1 (fr) 1993-04-05 1994-03-23 Blocs detergents contenant de l'oxygene actif pour cuvette de wc
JP6522178A JPH08508769A (ja) 1993-04-05 1994-03-23 活性酸素を含有したラバトリーブロック
AU64146/94A AU6414694A (en) 1993-04-05 1994-03-23 Lavatory blocks containing active oxygen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP93200961A EP0619366A1 (fr) 1993-04-05 1993-04-05 Blocs pour toilettes contenant de l'oxygène actif

Publications (1)

Publication Number Publication Date
EP0619366A1 true EP0619366A1 (fr) 1994-10-12

Family

ID=8213739

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93200961A Withdrawn EP0619366A1 (fr) 1993-04-05 1993-04-05 Blocs pour toilettes contenant de l'oxygène actif

Country Status (5)

Country Link
EP (1) EP0619366A1 (fr)
JP (1) JPH08508769A (fr)
AU (1) AU6414694A (fr)
CA (1) CA2159821A1 (fr)
WO (1) WO1994023002A1 (fr)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996017921A1 (fr) * 1994-12-09 1996-06-13 The Procter & Gamble Company Composition pour le lavage automatique de la vaisselle contenant des particules de peroxydes de diacyle
WO1996033259A1 (fr) * 1995-04-17 1996-10-24 The Procter & Gamble Company Preparation et utilisation de particules composites contenant du peroxyde de diacyle
WO1997024424A1 (fr) * 1995-12-28 1997-07-10 Rhone-Poulenc Surfactants & Specialties, L.P. Procedes pour produire des compositions solides de tensioactifs se dissolvant plus lentement
WO2000078911A1 (fr) * 1999-06-22 2000-12-28 Deoflor S.P.A. Composition detergente et desinfectante pour appareils sanitaires
EP1095663A1 (fr) * 1999-10-27 2001-05-02 Sogeval S.A. Composition désinfectante potentialisée et stabilisée ayant une activité bactéricide et virucide
WO2004053048A1 (fr) * 2002-12-06 2004-06-24 Ecolab Inc. Solides acides
WO2008125425A1 (fr) * 2007-04-16 2008-10-23 Unilever N.V. Bloc de nettoyage pour surface dure auto-adhésif
WO2010108834A1 (fr) * 2009-03-25 2010-09-30 Henkel Ag & Co. Kgaa Système composé d'un produit de nettoyage et d'un dispositif de distribution
WO2011092325A3 (fr) * 2010-01-29 2011-09-29 Ecolife B.V. Composition pour la prévention ou l'élimination de dépôts de sels insolubles
US8076278B2 (en) 2007-04-16 2011-12-13 Conopco, Inc. Self adhesive hard surface cleaning composition
DE102010030021A1 (de) 2010-06-14 2011-12-15 Henkel Ag & Co. Kgaa Maschinelles Reinigungsverfahren
WO2014190130A1 (fr) * 2013-05-24 2014-11-27 The Procter & Gamble Company Composition de tensioactifs concentrée
EP2876154A1 (fr) * 2013-11-26 2015-05-27 Bolton Manitoba SpA Composition détergente et/ou parfumante adhésive
US9267095B2 (en) 2013-05-24 2016-02-23 The Procter & Gamble Company Low pH detergent composition comprising nonionic surfactants
US10519400B2 (en) 2013-05-24 2019-12-31 The Procter & Gamble Company Low PH detergent composition

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA991306B (en) * 1998-07-23 1999-08-20 Magdelena Christiana Cor Stols "A cleaning composition".
JP4605680B2 (ja) * 2000-10-25 2011-01-05 四国化成工業株式会社 水中で活性酸素を放出しうる錠剤
PL3681988T3 (pl) * 2017-09-14 2023-05-08 Unilever Ip Holdings B.V. Kształtowana kostka do czyszczenia toalet
GB2605639A (en) * 2021-04-08 2022-10-12 Wizso Ltd Methods for reducing water consumption, carbon emissions and chemical usage

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1257813A (fr) * 1967-12-26 1971-12-22
EP0014979A1 (fr) * 1979-02-23 1980-09-03 Henkel Kommanditgesellschaft auf Aktien Procédé de fabrication de blocs de rinçage pour l'hygiène des toilettes
EP0171494A1 (fr) * 1984-02-29 1986-02-19 Werner & Mertz GmbH Agent combiné de nettoyage/de blanchissement pour le traitement de l'eau de chasse dans des réservoirs de la chasse et son application
EP0184416A2 (fr) * 1984-11-30 1986-06-11 JEYES GROUP plc Nettoyage pour cabinets d'aisance
JPS61197697A (ja) * 1985-02-28 1986-09-01 花王株式会社 水洗便器用清浄剤組成物
EP0234626A1 (fr) * 1986-02-12 1987-09-02 Unilever N.V. Bloc de blanchiment solide
JPH01240600A (ja) * 1988-03-18 1989-09-26 Seiwa Kogyo Kk トイレ用洗浄剤
JPH02147699A (ja) * 1988-11-30 1990-06-06 Nippon Soda Co Ltd 芳香性尿石防止剤

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4229410A (en) * 1978-02-13 1980-10-21 Kosti Carl M Bacteriostatic deodorant water coloring toilet element
US4460490A (en) * 1980-12-18 1984-07-17 Jeyes Group Limited Lavatory cleansing blocks
DE3225292A1 (de) * 1982-07-07 1984-01-12 Henkel KGaA, 4000 Düsseldorf Reinigungs- und desinfektionsmitteltablette fuer den wasserkasten von spueltoiletten
US4536368A (en) * 1983-12-09 1985-08-20 The Hilton-Davis Chemical Co. Method for sanitizing toilets
GB8626080D0 (en) * 1986-10-31 1986-12-03 Unilever Plc Detergent composition
US5188755A (en) * 1991-10-10 1993-02-23 Block Drug Company Surface erodible controlled releasing, free standing cleansing block and cleaning method for the domestic water closet

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1257813A (fr) * 1967-12-26 1971-12-22
EP0014979A1 (fr) * 1979-02-23 1980-09-03 Henkel Kommanditgesellschaft auf Aktien Procédé de fabrication de blocs de rinçage pour l'hygiène des toilettes
EP0171494A1 (fr) * 1984-02-29 1986-02-19 Werner & Mertz GmbH Agent combiné de nettoyage/de blanchissement pour le traitement de l'eau de chasse dans des réservoirs de la chasse et son application
EP0184416A2 (fr) * 1984-11-30 1986-06-11 JEYES GROUP plc Nettoyage pour cabinets d'aisance
JPS61197697A (ja) * 1985-02-28 1986-09-01 花王株式会社 水洗便器用清浄剤組成物
EP0234626A1 (fr) * 1986-02-12 1987-09-02 Unilever N.V. Bloc de blanchiment solide
JPH01240600A (ja) * 1988-03-18 1989-09-26 Seiwa Kogyo Kk トイレ用洗浄剤
JPH02147699A (ja) * 1988-11-30 1990-06-06 Nippon Soda Co Ltd 芳香性尿石防止剤

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 198641, Derwent World Patents Index; AN 1986-269641 *
DATABASE WPI Week 199029, Derwent World Patents Index; AN 1990-219881 *
PATENT ABSTRACTS OF JAPAN vol. 013, no. 575 (C - 667) 19 December 1989 (1989-12-19) *

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996017921A1 (fr) * 1994-12-09 1996-06-13 The Procter & Gamble Company Composition pour le lavage automatique de la vaisselle contenant des particules de peroxydes de diacyle
US5710115A (en) * 1994-12-09 1998-01-20 The Procter & Gamble Company Automatic dishwashing composition containing particles of diacyl peroxides
WO1996033259A1 (fr) * 1995-04-17 1996-10-24 The Procter & Gamble Company Preparation et utilisation de particules composites contenant du peroxyde de diacyle
US5763378A (en) * 1995-04-17 1998-06-09 The Procter & Gamble Company Preparation of composite particulates containing diacyl peroxide for use in dishwashing detergent compositions
AU713659B2 (en) * 1995-04-17 1999-12-09 Procter & Gamble Company, The Preparation and use of composite particles containing diacyl peroxide
WO1997024424A1 (fr) * 1995-12-28 1997-07-10 Rhone-Poulenc Surfactants & Specialties, L.P. Procedes pour produire des compositions solides de tensioactifs se dissolvant plus lentement
WO2000078911A1 (fr) * 1999-06-22 2000-12-28 Deoflor S.P.A. Composition detergente et desinfectante pour appareils sanitaires
EP1095663A1 (fr) * 1999-10-27 2001-05-02 Sogeval S.A. Composition désinfectante potentialisée et stabilisée ayant une activité bactéricide et virucide
FR2800281A1 (fr) * 1999-10-27 2001-05-04 So Ge Val Sa Composition desinfectante potentialisee et stabilisee en solution aqueuse ayant une activite bactericide et virucide marquee
WO2004053048A1 (fr) * 2002-12-06 2004-06-24 Ecolab Inc. Solides acides
WO2008125425A1 (fr) * 2007-04-16 2008-10-23 Unilever N.V. Bloc de nettoyage pour surface dure auto-adhésif
EA020185B1 (ru) * 2007-04-16 2014-09-30 Юнилевер Н.В. Чистящий блок, самоклеящийся на твердые поверхности
US8076278B2 (en) 2007-04-16 2011-12-13 Conopco, Inc. Self adhesive hard surface cleaning composition
WO2010108834A1 (fr) * 2009-03-25 2010-09-30 Henkel Ag & Co. Kgaa Système composé d'un produit de nettoyage et d'un dispositif de distribution
WO2011092325A3 (fr) * 2010-01-29 2011-09-29 Ecolife B.V. Composition pour la prévention ou l'élimination de dépôts de sels insolubles
US8415285B2 (en) 2010-01-29 2013-04-09 Ecover Coordination Center N.V. Composition for the prevention or removal of insoluble salt deposits
WO2011157630A1 (fr) 2010-06-14 2011-12-22 Henkel Ag & Co. Kgaa Procédé de lavage en machine
DE102010030021A1 (de) 2010-06-14 2011-12-15 Henkel Ag & Co. Kgaa Maschinelles Reinigungsverfahren
WO2014190130A1 (fr) * 2013-05-24 2014-11-27 The Procter & Gamble Company Composition de tensioactifs concentrée
CN105283530A (zh) * 2013-05-24 2016-01-27 宝洁公司 浓缩型表面活性剂组合物
US9267095B2 (en) 2013-05-24 2016-02-23 The Procter & Gamble Company Low pH detergent composition comprising nonionic surfactants
US9840681B2 (en) 2013-05-24 2017-12-12 The Procter & Gamble Company Concentrated surfactant composition
US10519400B2 (en) 2013-05-24 2019-12-31 The Procter & Gamble Company Low PH detergent composition
EP2876154A1 (fr) * 2013-11-26 2015-05-27 Bolton Manitoba SpA Composition détergente et/ou parfumante adhésive
ITMI20131972A1 (it) * 2013-11-26 2015-05-27 Bolton Manitoba S P A Composizione adesiva detergente e/o profumante

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WO1994023002A1 (fr) 1994-10-13
JPH08508769A (ja) 1996-09-17
AU6414694A (en) 1994-10-24
CA2159821A1 (fr) 1994-10-13

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