EP0610197A1 - Compositions pour pneus et courroies - Google Patents
Compositions pour pneus et courroiesInfo
- Publication number
- EP0610197A1 EP0610197A1 EP92909444A EP92909444A EP0610197A1 EP 0610197 A1 EP0610197 A1 EP 0610197A1 EP 92909444 A EP92909444 A EP 92909444A EP 92909444 A EP92909444 A EP 92909444A EP 0610197 A1 EP0610197 A1 EP 0610197A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- phr
- rubber
- mixture
- weight percent
- tire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 97
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 41
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 41
- 239000011593 sulfur Substances 0.000 claims abstract description 41
- 229920001971 elastomer Polymers 0.000 claims abstract description 39
- 239000005060 rubber Substances 0.000 claims abstract description 38
- 229920001194 natural rubber Polymers 0.000 claims abstract description 35
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000006229 carbon black Substances 0.000 claims abstract description 21
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 18
- 239000005062 Polybutadiene Substances 0.000 claims abstract description 18
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 18
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 17
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 17
- 239000012190 activator Substances 0.000 claims abstract description 14
- 239000011787 zinc oxide Substances 0.000 claims abstract description 13
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 4
- 239000010959 steel Substances 0.000 claims abstract description 4
- 239000002245 particle Substances 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229960005349 sulfur Drugs 0.000 claims 4
- 235000001508 sulfur Nutrition 0.000 claims 4
- 238000004073 vulcanization Methods 0.000 abstract description 14
- 238000007596 consolidation process Methods 0.000 abstract 2
- 239000000654 additive Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- 238000005299 abrasion Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 230000032683 aging Effects 0.000 description 5
- 238000005096 rolling process Methods 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 4
- 235000006708 antioxidants Nutrition 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- -1 tackifiers Substances 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001868 cobalt Chemical class 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- OPNUROKCUBTKLF-UHFFFAOYSA-N 1,2-bis(2-methylphenyl)guanidine Chemical compound CC1=CC=CC=C1N\C(N)=N\C1=CC=CC=C1C OPNUROKCUBTKLF-UHFFFAOYSA-N 0.000 description 1
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- LGBYJXBCVZKJBL-UHFFFAOYSA-N 1-[(2-oxoazepan-1-yl)disulfanyl]azepan-2-one Chemical compound O=C1CCCCCN1SSN1C(=O)CCCCC1 LGBYJXBCVZKJBL-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- CPGFMWPQXUXQRX-UHFFFAOYSA-N 3-amino-3-(4-fluorophenyl)propanoic acid Chemical compound OC(=O)CC(N)C1=CC=C(F)C=C1 CPGFMWPQXUXQRX-UHFFFAOYSA-N 0.000 description 1
- MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 1
- HLBZWYXLQJQBKU-UHFFFAOYSA-N 4-(morpholin-4-yldisulfanyl)morpholine Chemical compound C1COCCN1SSN1CCOCC1 HLBZWYXLQJQBKU-UHFFFAOYSA-N 0.000 description 1
- BTTRMCQEPDPCPA-UHFFFAOYSA-N 4-chlorophthalic anhydride Chemical compound ClC1=CC=C2C(=O)OC(=O)C2=C1 BTTRMCQEPDPCPA-UHFFFAOYSA-N 0.000 description 1
- ZOXBWJMCXHTKNU-UHFFFAOYSA-N 5-methyl-2-benzofuran-1,3-dione Chemical compound CC1=CC=C2C(=O)OC(=O)C2=C1 ZOXBWJMCXHTKNU-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- UBUCNCOMADRQHX-UHFFFAOYSA-N N-Nitrosodiphenylamine Chemical compound C=1C=CC=CC=1N(N=O)C1=CC=CC=C1 UBUCNCOMADRQHX-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004614 Process Aid Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- UEZWYKZHXASYJN-UHFFFAOYSA-N cyclohexylthiophthalimide Chemical compound O=C1C2=CC=CC=C2C(=O)N1SC1CCCCC1 UEZWYKZHXASYJN-UHFFFAOYSA-N 0.000 description 1
- PGAXJQVAHDTGBB-UHFFFAOYSA-N dibutylcarbamothioylsulfanyl n,n-dibutylcarbamodithioate Chemical compound CCCCN(CCCC)C(=S)SSC(=S)N(CCCC)CCCC PGAXJQVAHDTGBB-UHFFFAOYSA-N 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- NNYHMCFMPHPHOQ-UHFFFAOYSA-N mellitic anhydride Chemical compound O=C1OC(=O)C2=C1C(C(OC1=O)=O)=C1C1=C2C(=O)OC1=O NNYHMCFMPHPHOQ-UHFFFAOYSA-N 0.000 description 1
- OFHMODDLBXETIK-UHFFFAOYSA-N methyl 2,3-dichloropropanoate Chemical compound COC(=O)C(Cl)CCl OFHMODDLBXETIK-UHFFFAOYSA-N 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- IUJLOAKJZQBENM-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-2-methylpropan-2-amine Chemical compound C1=CC=C2SC(SNC(C)(C)C)=NC2=C1 IUJLOAKJZQBENM-UHFFFAOYSA-N 0.000 description 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 125000001174 sulfone group Chemical group 0.000 description 1
- 150000003579 thiophosphoric acid derivatives Chemical class 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
Definitions
- the present invention relates to tires and belts which have improved properties as compared to standard tire and belt compositions.
- the inventors have found that tire and belt compositions having a reduced heat buildup exhibit improved properties, especially when subjected to environments which lead to ageing of the rubber compositions.
- European Patent application 0314271 discloses the use of an improved processing aid to improve handling, durability and rolling resistance of tires, as well as reducing heat buildup.
- European Patent application 0451 603 relates to the use of an anionic polymerization initiator for curing elastomers to improve their hysteresis. Improved hysteresis leads to tires having a lower rolling resistance. One aspect of hysteresis is heat buildup.
- PCT patent application WO 91/05821 discloses a tire sidewall composition comprising a particular polymer which leads to sidewalls having a desirable reduced internal heat buildup and improved adhesion to adjacent rubber carcass and tread portions of the tire.
- publication, "Natural Rubber Compounds for Truck Tires," NR Technology, Vol. 16, Part 1 (1985) suggests the use of additional stearic acid activator in order to reduce the heat generation, among other properties, in truck tires.
- the present invention relates, in one aspect to a tire wherein at least one of the tread, steel-cord skim stock, sidewall and carcass portions contains a rubber composition formed by curing a blend of at least: 50-100 weight percent of natural rubber, polyisoprene or a mixture thereof,
- the present invention relates to a belt which contains a rubber composition formed by curing a blend of at least:
- the low heat buildup rubber compositions of the present invention can be used in tire treads for truck tires and off-the-road tires, in particular, for sidewalls, for tire carcasses and for steel-cord skim stocks.
- the rubber compositions of the present invention are particularly useful for conveyor belts and V-belts which are subjected to high loading and abrasion in service.
- a typical truck tire tread composition in accordance with the present invention comprises the cured product of a blend containing:
- truck tire treads may contain other conventional additives such as 0-20 phr silica, 2-10 phr tackifier, 5-50 phr of processing oil, 1-5 phr waxes, 1-5 phr antioxidant and 1-5 phr antiozonants.
- Important properties for truck tire treads include abrasion resistance, rolling resistance, resistance to cracking, thermal and oxidative stability and durability.
- a typical steel-cord skim stock composition in accordance with the present invention is the cured product of a blend comprising:
- These steel-cord skim stocks may also contain 0-20 phr silica, 0-2.0 phr of a cobalt salt and 1-3 phr of antidegradants. Adhesion to steel is an important property for this portion of the tire.
- a typical carcass portion of a tire in accordance with the present invention is the cured product of a blend comprising: 50-80 weight percent of natural rubber, polyisoprene or a mixture thereof,
- carcass portions may also contain 1-3 phr antioxidant and 2-8 phr processing oil, if desired. Important properties for the carcass portion are the thermal resistance and the rebound resilience.
- a typical sidewall portion of a tire in accordance with the present invention is the cured product of a blend comprising:
- a typical off-the-road tire tread in accordance with the present invention is the cured product of a blend which comprises:
- Off-the-road tire treads may also include 5-50 phr of processing oil, 0-5 phr of resin, 0-2 phr wax, 1-4 phr antiozonants and 0.5-2.0 phr antioxidants.
- Important properties for off-the-road tire treads are tread wear, cutting and chipping resistance and hysteresis.
- a typical conveyor belt in accordance with the present invention is the cured product of a blend comprising:
- a typical V-belt in accordance with the present invention is the cured product of a blend comprising:
- V-belts are fatigue resistance and service life.
- sulfur examples include various types of sulfur such as powdered sulfur, precipitated sulfur and insoluble sulfur.
- sulfur donors may be used in place of, or in addition to sulfur in order to provide the required level of sulfur during the vulcanization process.
- sulfur donors include, but are not limited to, tetramethylthiuram disulfide, tetraethylthiuram disulfide, tetrabutylthiuram disulfide, dipentamethylene thiuram hexasulfide, dipentamethylene thiuram tetrasulfide, dithiodimorpholine, caprolactam disulfide and mixtures thereof.
- references to sulfur shall include sulfur donors and mixtures of sulfur and sulfur donors. Further, references to the quantity of sulfur employed in the vulcanization, when appl ied to sulfur donors, refer to a quantity of sulfur donor which is required to provide the equivalent amount of sulfur that is specified.
- a vulcanization accelerator in the rubber compound.
- Conventional , known vulcanization accelerators may be employed.
- the preferred vulcanization accelerators include mercaptobenzothiazole, 2,2'-mercaptobenzothiazole disulfide, sulfenamide accelerators including
- 2-(morpholinothio)benzothiazole 2-(morpholinothio)benzothiazole; thiophosphoric acid derivative accelerators, thiurams, dithiocarbamates, diphenyl guanidine, diorthotolyl guanidine, dithiocarbamyl sulfenamides, xanthates, triazine accelerators and mixtures thereof.
- Other rubber additives may also be employed in their usual amounts.
- reinforcing agents such as carbon black, silica, clay, whiting and other mineral fillers, as wel l as mixtures of fillers, may be included in the rubber composition.
- scorch retarders such as phthalic anhydride, pyromellitic anhydride, benzene hexacarboxylic trianhydride, 4-methylphthalic anhydride, trimellitic anhydride, 4-chlorophthalic anhydride, N- cyclohexyl-thiophthalimide, salicylic acid, benzoic acid, maleic anhydride and N-nitrosodiphenylamine may also be included in the rubber composition in conventional, known amounts.
- steel-cord adhesion promoters such as cobalt salts and dithiosulfates in conventional, known quantities.
- the process of curing the blends of the present invention is preferably carried out at a temperature of 110-220°C over a period of up to 24 hours. More preferably, the process is carried out at a temperature of 120-190°C over a period of up to 8 hours. All of the additives mentioned above with respect to the rubber composition may also be present during the vulcanization process. In a more preferred embodiment of the vulcanization process, the vulcanization is carried out at a temperature of 120-190°C over a period of up to 8 hours and in the presence of at least one vulcanization accelerator. The best heat buildup in accordance with the present invention is found when vulcanization is carried out at a temperature above 160°C and/or for a period exceeding t 90 .
- the tire and belt products of the present invention have reduced heat buildup. With respect to the tire products, they exhibit a heat buildup of 20-35°C whereas the belt products exhibit a heat buildup of from 10-35°C.
- Heat buildup for the purposes of the present specification, was measured using ASTM 623 A at a starting temperature of 100°C. The actual heat buildup is the temperature rise from 100°C to the temperature at which equilibrium was reached. Equilibrium temperature is when the temperature stabilizes and does not rise any further. Note that for some prior art products, the temperature never stabilizes.
- One way to produce products in accordance with the present invention is to carry out the curing of the blend in the presence of 0.1-5.0 parts by weight of a coagent represented by the general formula A:
- Ql-D-(Q 2 )n (A); wherein D, optionally containing one or more heteroatoms or groups selected from nitrogen, oxygen, silicon, phosphorus, boron, sulphone and sulphoxy, is a monomeric or oligomeric divalent, trivalent or tetravalent group, n is an integer selected from 1, 2 or 3, Q 1 and Q 2 are independently selected from the formulas I and II:
- R 1 , R 2 and R 3 are i ndependently selected from hydrogen, C 1 -C 18 al kyl groups, C 3 -C 18 cycloal kyl groups, C 6 -C 18 aryl groups, C 7 -C 30 aral kyl groups and C 7 -C 30 al karyl groups and R 2 and R 3 may combine to form a ring when R 1 is hydrogen; B and B 1 are independently selected from the fol lowing hetero atoms: oxygen and sulfur.
- These imides are, in general, known compounds and may be prepared by the methods disclosed in, "The synthesis of Biscitraconimides and Polybiscitraconimides," Galanti, A.V. and Scola, D.A., Journ. of Poly.
- Base compounds were mixed in a Farrel Bridge BR 1.6 liter Banbury type internal mixer (preheating at 50°C, rotor speed 77 rpm, mixing time 6 min with full cooling).
- Optimum cure time (t 90 ) is the time to 90% of delta torque above minimum
- reversion time (t r 2) is the time to 2% of delta torque below maximum torque
- Final torque (Tf) is the torque measured after the overcure time.
- Sheets and test specimens were vulcanized by compression molding in a Fontyne TP-400 press.
- Compression set was determined after 24 h at 70°C or 72 h at 23°C according to ASTM D 395-89.
- Heat build-up temperature rise and compression set after dynamic loading were determined using a Goodrich Flexometer (load 1 MPa, stroke 0.445 cm, frequency 30 Hz, start temperature 100°C, running time 30 min; ASTM D 623-78). Blow out time was determined according to ASTM D 623-78 (load 2 MPa, stroke 0.645 cm, frequency 30 Hz, start temperature 100°C).
- Abrasion was determined using a Zwick abrasion tester as volume loss per 40 m path travelled (DIN 53516).
- Examples 1-3 and Comparative Example A are formulations for truck tire treads.
- the components of each formulation are given in Table 1 and the physical and mechanical properties for different curing conditions are given in Tables 2a-2d.
- the heat buildup and permanent set are given for different curing conditions in Tables 3a-3b.
- Example 4 and Comparative Example B are also formulations for truck tire treads.
- the components of each formulation are given in Table 4 and the physical and mechanical properties for different curing conditions are given in Tables 5a-5b.
- the heat buildup and permanent set are given for different curing conditions in Tables 6a-6b.
- Examples 5-7 and Comparative Examples C-D are formulations for off- the-road tire treads.
- the components of each formulation are given in Table 7 and the physical and mechanical properties for different curing conditions are given in Tables 8a-8d.
- the heat buildup and permanent set are given for different curing conditions in Tables 9-10.
- Example 8 and Comparative Examples E-F are formulations for conveyor belts.
- the components of each formulation are given in Table 11 and the physical and mechanical properties for different curing conditions are given in Tables 12a-12b.
- the heat buildup and permanent set are given for different curing conditions in Table 13.
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Abstract
La présente invention concerne un pneu dans lequel au minimum une des parties de la bande de roulement de la couche armée de fils d'acier, des flancs et de la carcasse contient une composition caoutchouteuse formée par la vulcanisation d'un mélange de: a. caoutchouc naturel, polyisoprène ou leur mélange, b. caoutchouc butadiène, caoutchouc styrène-butadiène ou leur mélange, c. noir de carbone, d. activeur, e. oxyde de zinc, f. soufre ou donneur de soufre, et g. accélérateur de vulcanisation. L'invention est caractérisée par le fait que ladite composition caoutchouteuse possède une température de consolidation de 20 à 35 °C. Ces pneus présentent une ou plusieurs améliorations d'une grande variété de propriétés. La présente invention concerne aussi une courroie qui contient une telle composition caoutchouteuse, caractérisée par le fait que ladite composition caoutchouteuse possède une température de consolidation de 10 à 25 °C. Ces courroies présentent également une ou plusieurs améliorations de différentes propriétés.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
WOPCT/EP91/02048 | 1991-10-29 | ||
PCT/EP1991/002048 WO1992007904A1 (fr) | 1990-10-29 | 1991-10-29 | Coagents antireversion utilises dans la vulcanisation du caoutchouc |
PCT/EP1992/001030 WO1993009178A1 (fr) | 1991-10-29 | 1992-05-07 | Compositions pour pneus et courroies |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0610197A1 true EP0610197A1 (fr) | 1994-08-17 |
Family
ID=8165618
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92909444A Withdrawn EP0610197A1 (fr) | 1991-10-29 | 1992-05-07 | Compositions pour pneus et courroies |
Country Status (8)
Country | Link |
---|---|
EP (1) | EP0610197A1 (fr) |
JP (1) | JPH07500616A (fr) |
BR (1) | BR9206688A (fr) |
CA (1) | CA2122347A1 (fr) |
CZ (1) | CZ104794A3 (fr) |
FI (1) | FI941968A0 (fr) |
SK (1) | SK49694A3 (fr) |
WO (1) | WO1993009178A1 (fr) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5503940A (en) * | 1994-10-24 | 1996-04-02 | The Goodyear Tire & Rubber Company | Elastomeric laminates containing a solventless elastomeric adhesive composition |
US6186202B1 (en) | 1996-02-20 | 2001-02-13 | The Goodyear Tire & Rubber Company | Silica reinforced solventless elastomeric adhesive compositions |
US5728757A (en) * | 1996-08-09 | 1998-03-17 | The Goodyear Tire & Rubber Company | Zinc salts of citraconamic acid and rubber compounds containing such salts |
US5696188A (en) * | 1996-08-09 | 1997-12-09 | The Goodyear Tire & Rubber Company | Rubber compounds containing aryl bis citraconamic acids |
US6079468A (en) | 1996-08-09 | 2000-06-27 | The Goodyear Tire & Rubber Company | Rubber article containing a bismaleimide and a bis benzothiazolydithio end capped compound |
JP4678909B2 (ja) * | 2000-02-01 | 2011-04-27 | 住友ゴム工業株式会社 | ランフラットタイヤ |
JP2001288298A (ja) * | 2000-02-04 | 2001-10-16 | Bridgestone Corp | ゴム組成物及びそれを用いた空気入りタイヤ |
KR20030095079A (ko) * | 2002-06-11 | 2003-12-18 | 금호타이어 주식회사 | 내피로 특성이 향상된 타이어용 고무조성물 |
KR20030095080A (ko) * | 2002-06-11 | 2003-12-18 | 금호타이어 주식회사 | 내피로 특성이 향상된 타이어용 고무조성물 |
US20060111498A1 (en) * | 2004-11-23 | 2006-05-25 | The Goodyear Tire & Rubber Company | Rubber compound with hydrotalcite having increased blow-out resistance |
JP2007169431A (ja) | 2005-12-21 | 2007-07-05 | Sumitomo Rubber Ind Ltd | サイドウォール用ゴム組成物 |
US20070144644A1 (en) * | 2005-12-22 | 2007-06-28 | David John Zanzig | Pneumatic tire |
EP2584217A4 (fr) * | 2010-06-15 | 2017-12-13 | Bando Chemical Industries, Ltd. | Courroie de transmission |
US9879131B2 (en) | 2012-08-31 | 2018-01-30 | Soucy Techno Inc. | Rubber compositions and uses thereof |
CN102911412A (zh) * | 2012-11-01 | 2013-02-06 | 中国化工橡胶桂林有限公司 | 全钢子午胎胎侧胶 |
WO2015054779A1 (fr) | 2013-10-18 | 2015-04-23 | Soucy Techno Inc. | Compositions de caoutchouc et leurs utilisations |
WO2015089647A1 (fr) | 2013-12-19 | 2015-06-25 | Soucy Techno Inc. | Compositions de caoutchouc et leurs utilisations |
JP6897144B2 (ja) * | 2017-02-22 | 2021-06-30 | 横浜ゴム株式会社 | コンベアベルト用ゴム組成物、コンベアベルト及びベルトコンベア |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4071496A (en) * | 1976-04-30 | 1978-01-31 | Phillips Petroleum Company | Carbon black for low-hysteresis rubber compositions |
JPS5986641A (ja) * | 1982-11-10 | 1984-05-18 | Tokai Carbon Co Ltd | ゴム組成物 |
-
1992
- 1992-05-07 WO PCT/EP1992/001030 patent/WO1993009178A1/fr not_active Application Discontinuation
- 1992-05-07 EP EP92909444A patent/EP0610197A1/fr not_active Withdrawn
- 1992-05-07 SK SK496-94A patent/SK49694A3/sk unknown
- 1992-05-07 CA CA002122347A patent/CA2122347A1/fr not_active Abandoned
- 1992-05-07 CZ CZ941047A patent/CZ104794A3/cs unknown
- 1992-05-07 BR BR9206688A patent/BR9206688A/pt not_active Application Discontinuation
- 1992-05-07 JP JP4508553A patent/JPH07500616A/ja active Pending
-
1994
- 1994-04-28 FI FI941968A patent/FI941968A0/fi unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9309178A1 * |
Also Published As
Publication number | Publication date |
---|---|
JPH07500616A (ja) | 1995-01-19 |
WO1993009178A1 (fr) | 1993-05-13 |
FI941968A (fi) | 1994-04-28 |
CA2122347A1 (fr) | 1993-05-13 |
BR9206688A (pt) | 1995-10-24 |
CZ104794A3 (en) | 1994-11-16 |
SK49694A3 (en) | 1994-11-09 |
FI941968A0 (fi) | 1994-04-28 |
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