EP0589088B1 - Pulvermischung auf Eisenbasis und Verfahren ihrer Herstellung - Google Patents

Pulvermischung auf Eisenbasis und Verfahren ihrer Herstellung Download PDF

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Publication number
EP0589088B1
EP0589088B1 EP92116479A EP92116479A EP0589088B1 EP 0589088 B1 EP0589088 B1 EP 0589088B1 EP 92116479 A EP92116479 A EP 92116479A EP 92116479 A EP92116479 A EP 92116479A EP 0589088 B1 EP0589088 B1 EP 0589088B1
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EP
European Patent Office
Prior art keywords
powder
stearic acid
iron
mixture
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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EP92116479A
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English (en)
French (fr)
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EP0589088A1 (de
Inventor
Kuniaki c/o Technical Research Div. Ogura
Shigeaki c/o Technical Research Div. Takajo
Hiroyuki c/o Technical Research Div. Ishikawa
Akio c/o Chiba Works Sonobe
Yoshiaki c/o Chiba Works Maeda
Toshiyuki c/o Chiba Works Minegishi
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JFE Steel Corp
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Kawasaki Steel Corp
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Priority to EP92116479A priority Critical patent/EP0589088B1/de
Priority to DE69226639T priority patent/DE69226639T2/de
Publication of EP0589088A1 publication Critical patent/EP0589088A1/de
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Publication of EP0589088B1 publication Critical patent/EP0589088B1/de
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • B22F1/103—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material containing an organic binding agent comprising a mixture of, or obtained by reaction of, two or more components other than a solvent or a lubricating agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • B22F1/108—Mixtures obtained by warm mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/02—Compacting only
    • B22F2003/023—Lubricant mixed with the metal powder
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy

Definitions

  • the present invention relates to a method of modifying powder materials used for manufacture of machine parts by powder metallurgy, and more particularly relates to an iron-based powder mixture for powder metallurgy and a manufacturing method thereof, producing an improved powder mixture having stabilized apparent density, less segregation of additives, and superior fluidity characteristics when discharged from a hopper; which method requires less force when ejected from a die in a compacting process; and which material contains no zinc or small amounts of zinc at most.
  • a powder in which graphite was adhered to the surface of the iron-based powder with a binder of zinc stearate was disclosed in the Japanese Patent Laid-Open No. 1-219101. Also, we have proposed a method employing a metal soap and a fatty acid as a binder in Japanese Patent Laid-Open No. 3-162502.
  • all of the above mentioned methods included zinc and other metallic elements in the binders, which caused a major problem since metallic elements in the binders, as oxides, contaminated the inside of the furnace, or varied the composition of the sintered body during sintering.
  • some methods employ binders having no metallic elements, as disclosed in Japanese Patent Publication No. 60-502158 and Japanese Patent Laid-Open No. 2-217403, wherein the binders themselves do not have a lubricating function, and thus zinc stearate was added as the lubricant in the end. Therefore, as described before, zinc in the lubricant contaminated the inside of the furnace as an oxide or varied the composition of the sintered body.
  • an object of the present invention is to provide an iron-based powder mixture for powder metallurgy, and to provide a manufacturing method thereof, wherein the powder mixture has a stabilized apparent density, less segregation, superior characteristics of fluid flow from a hopper, and no zinc or a small amount at most, while maintaining the powder characteristics and the green compact characteristics of the mixture.
  • the mixture may be produced by adhering the alloying powder and the powder for improving machinability to the surface of the iron-based powder as a binder which is made of a melted powder mixture of at least one powder of an organic compound selected from a low melting point group having a melting point of about 69-103°C and consisting of stearic acid, oleic acid, and stearic acid amide, and a high melting point component comprising stearic acid bisamide organic compound powder having a high melting point of about 147°C, and mixing the free powders of a lubricant into the powder mixture at a temperature below the melting point.
  • a binder which is made of a melted powder mixture of at least one powder of an organic compound selected from a low melting point group having a melting point of about 69-103°C and consisting of stearic acid, oleic acid, and stearic acid amide, and a high melting point component comprising stearic acid bisamide organic compound powder having a high melting point
  • an object of the present invention is to provide such an advantageous mixture and a manufacturing method for its efficient production.
  • the present invention provides a method for producing an iron-based powder mixture for powder metallurgy, comprising the steps of:
  • inventive method further comprises a step of additional
  • the present invention is further directed to an iron-based powder mixture for powder metallurgy, comprising:
  • the iron-based powder mixture comprises a lubricant containing 0.1 % to 0.5 % by weight of at least one lubricant-free powder selected from the group consisting of stearic acid, oleic acid amide, stearic acid amide, stearic acid bisamide, and a heated mixture of stearic acid amide and stearic acid bisamide, and/or wherein 0.01 % to 0.25 % by weight of a free powder of zinc stearate are mixed without causing adhesion by melting to the surface of the iron-based powder.
  • a lubricant-free powder selected from the group consisting of stearic acid, oleic acid amide, stearic acid amide, stearic acid bisamide, and a heated mixture of stearic acid amide and stearic acid bisamide, and/or wherein 0.01 % to 0.25 % by weight of a free powder of zinc stearate are mixed without causing adhesion by melting to the surface of
  • free powder indicates a powder which is not adhered by melting to the iron-based powder surface, but is simply physically blended in the mixture.
  • heated mixture indicates a powder which can be obtained by heating, melting, mixing, cooling and then crushing a powder of not less than two organic compounds.
  • particle segregation can be prevented by the adhesion, by means of the binder, of the alloying powder and/or the powder for improving machinability to the surface of the iron-based powder.
  • a pure iron powder and/or alloyed iron powder, processed by methods such as pulverization or atomization, may be used as the iron-based powder; a graphite powder or an alloying powder may be used as the powder for an alloy; and talc or metallic sulfide may be used as the powder for improving machinability of the sintered body.
  • the alloying powder and/or the powder for improving machinability and the stearic acid bisamide can be adhered to the surface of the iron-based powder, but also the fluidity of the iron-based powder can be improved by using, as a binder, at least one melted compound of the first group in which the stearic acid (melting point 69°C), oleic acid amide (melting point 76°C), and stearic acid amide (melting point 103°C) having a low melting point are included.
  • the fluidity of the iron-based powder mixture can be improved and the force required for ejection of the product from the die can be significantly reduced.
  • the fluidity of the mixture can be improved and the alloying powder and/or the powder for improving machinability can be adhered to the surface of the iron-based powder, with the beneficial result that the force required for ejection of the iron-based powder from the die can be significantly reduced.
  • the amount of powder of the organic compound, the heated and melted mixture as a binder ranges between 0.1 and 1.0 % by weight.
  • the amount of the powder is less than 0.1 % by weight, a ratio of the amount of graphite contained in the total mixture, which was heated and mixed, to the amount of graphite contained in the powder from 150-74 ⁇ m (100 to 200 mesh) in the mixture (hereinafter defined as the degree of graphite adhesion) is reduced below about 50 %; also the force required for ejecting the product from a die after compacting decreases significantly.
  • the amount of powder is more than 1.0 % by weight, the fluidity of the mixture in flowing from the supply hopper deteriorates.
  • One reason for substantially excluding zinc from the binder is to prevent contamination on the surface of the sintered body during sintering.
  • an alloying powder and/or a powder for improving machinability may be added.
  • the amount of the powder added is less than 0.1 % by weight, no significant advantage is realized because of the small amount applied.
  • the amount of the added powder exceeds 3.0 % by weight, the degree of adhesion of the alloying powder and the powder for improving machinability is reduced to 50 % or less, which reduces the efficiency of the mixture.
  • the iron-based powder mixture of the present invention can be obtained by mixing and then heating the iron-based powder, the alloying powder and/or the powder for improving machinability together with the aforementioned specific organic compounds of the first (low-melting) and second (high-melting) groups.
  • the preferable heating temperature ranges from 10°C above the melting point of the selected lower-melting component or the one having the lower melting point when there is more than one component of the first group which has a low melting point (the group comprises stearic acid, oleic acid amide or stearic acid amide which melt at about 69°, 76° and 103°C, respectively) to the melting point of the stearic acid bisamide which has a relatively high melting point of about 147°C.
  • the heating temperature is less than the above, the adhesion of the alloying powder and/or the powder for improving machinability to the surface of the iron-based powder is insufficient.
  • the heating temperature is higher than the melting point of the stearic acid bisamide, the fluidity of the iron-based powder deteriorates and the compounds having the lower melting point degenerate, which increases the cost of the processing facilities and their operation.
  • the heating temperature is higher than the melting points of the lower-melting compounds of the first group, the powders of the compounds of the first (low-melting) group are substantially completely melted. Thus these melted compounds cause adhesion, as a binder, of the alloying powder and/or the powder for improving machinability to the surface of the iron-based powder.
  • the heating temperature is lower than the melting point of the higher-melting stearic acid bisamide it melts only partially if at all and adheres well to the surface of the iron-based powder.
  • the fluidity of the iron-based powder is enhanced and the sintered body may easily be ejected from the die after compacting.
  • the required heating and mixing time ranges from about 30 seconds to about 30 minutes.
  • a heating and mixing time of less than about 30 seconds causes non-uniform adhesion of the alloying powder and/or the powder for improving machinability to the surface of the iron-based powder.
  • a heating and mixing time of more than about 30 minutes causes peeling of the adhered powders.
  • the preferable heating and mixing time ranges from about 5 to 20 minutes.
  • the organic compounds of both groups are, of course, non-metallic; therefore, a compacted body made of the iron-based powder mixture of the present invention does not contaminate the inside of the furnace by generation of dust containing metallic element and/or contaminate the surface of the sintered body by the metallic elements.
  • the kind and amounts of the organic compounds to be used are based upon the kind, shape, and particle-size construction of the iron-based powder and the kind, shape, and added amount of the alloying powder and/or the powder that is added for improving machinability.
  • the iron-based powder mixture according to the present invention can achieve better ejecting force from the die and/or fluidity by adding a lubricant.
  • the added lubricant may comprise a room temperature free powder selected from the group consisting of stearic acid, oleic acid, stearic acid amide, stearic bisamide, and a heated mixture of stearic acid amide and stearic acid bisamide; or a small amount of the free powder of zinc stearate; or a free powder of any of these organic compounds and a small amount of zinc stearate.
  • the organic compounds which separately comprise the heated and melted mixture previously described, and the room temperature powder mixture, are then mixed.
  • the degree of adhesion of the alloying powder and/or the powder for improving machinability is improved by the heated and melted mixture; the ejecting force from the die is reduced by lubricating action of the room temperature powder mixture.
  • the amount of the lubricant powder added to the mixture should not be less than 0.1 % by weight and not more than 0.5 % by weight. When the added amount is less than 0.1 % by weight, the die ejecting force does not improve markedly after compacting. On the other hand, when the added amount of lubricant is more than 0.5 % by weight, the fluidity from the hopper of the mixture decreases.
  • the added amount of zinc stearate lubricant should preferably not be less than 0.01 % by weight nor more than 0.25 % by weight. When the added amount is less than 0.01 % by weight, fluidity of the mixture when fed from the hopper cannot be improved. On the other hand, when the added amount is more than 0.25 % by weight contamination occurs on the surface of the sintered body.
  • the required time for adding these free powders to the iron-based powder and mixing ranges between 30 seconds and 30 minutes at room temperature. Less than 30 seconds results in incomplete mixing, and more than 30 minutes causes deformation of the particles of the free powders which diminishes the effect of reducing the ejecting force exerted on the compacted body from the die. Accordingly, the preferable adding and mixing time ranges from about 5 to 20 minutes.
  • Stearic acid or oleic acid amide or stearic acid amide of the first group, and stearic acid bisamide of the second group, as a binder, were added in amounts shown in Table 1, into an atomizing iron powder for powder metallurgy.
  • the powder had an average particle diameter of 78 ⁇ m.
  • Reduced iron powder instead of atomized iron powder, with an average particle diameter of 78 ⁇ m was used in Sample No. 10.
  • the atomized iron powder was the same powder used in the practical example 1 of the present invention.
  • Each organic chemical powder of the first and second groups was the only powder added as a binder.
  • zinc stearate used for a conventional lubricant was employed by mixing at a room temperature without heating as sample No. 5 of a comparative example.
  • the degree of graphite (C) adhesion in the powder is represented by the ratio of the amount of C in the powder of particle size ranging from 150-74 ⁇ m (100 to 200 mesh) of this mixture to the amount of C of the total mixture which was heated, melted, and mixed.
  • the degree of carbon adhesion is indicated as the ratio of (C analysis value in 150-74 ⁇ m (100-200 mesh))/(C analysis value in the total mixture) x 100(%).
  • the degree of talc adhesion was measured by the same method as the one used for the carbon.
  • the fluidity characteristics of the powder are represented by the fluidity time of a 100 g mixture from a 5.1 mm diameter orifice provided at the bottom center of a container which is 40 mm in diameter and 100 mm high, to which a 100 g mixture of powder mixture at room temperature was added.
  • the powder mixture for the powder metallurgy in comparison with the conventional comparative example, had a high degree of graphite adhesion, and achieved less segregation and less ejecting force and superior fluidity.
  • samples No. 1 to No. 3 of the comparison example to which only the lower melting point organic compound was added, had deteriorated fluidity.
  • sample No. 4 of the comparison example to which only the high melting point organic compound was added, had reduced ejecting force but deteriorated degree of graphite adhesion.
  • Sample No. 5 of comparative example, to which zinc stearate powder was added by conventional room temperature mixing has the deteriorated ejecting force and degree of graphite adhesion.
  • the lubricants were mixed into the above obtained iron-based powder mixture for 10 minutes at room temperature.
  • Added free powders as the above mentioned lubricants were stearic acid, oleic acid, stearic acid amide, stearic acid bisamide, and a heated mixture of stearic acid amide and stearic acid bisamide.
  • the identical iron powder, binder, and alloying powder as in practical example 1 were used, and the added amount of each of these is shown in the Table 3.
  • the identical copper powder of practical example 1 was used as the alloying powder.
  • the identical talc of practical example 1 was used as the alloying powder.
  • the iron powder, binder, and alloying powder were mixed with heating and melting for 10 minutes at 115°C, then cooled and mixed with zinc stearate as a lubricant for 10 minutes at room temperature.
  • the identical atomized iron powder of the practical example were used, and zinc stearate in an amount exceeding the appropriate range was added as a lubricant.
  • the degree of C adhesion, fluidity, and ejecting force of the obtained mixture were measured in the same manner as that of practical example 1. The result of the measurements is shown in Table 3.
  • the identical iron powders, binders, and alloying powders of practical example 1 were used and the added amounts are shown in table 4.
  • the identical copper powder of practical example 1 was used as an alloying powder.
  • the heating temperature and time were the same as practical example 3.
  • the free powders of stearic acid, oleic acid amide, stearic acid amide, stearic acid bisamide, the heated mixture of stearic acid amide and stearic acid bisamide, and zinc stearate were added as lubricants. These lubricants were added into the above mentioned iron-based powder mixture and mixed for 10 minutes at room temperature.
  • the identical atomized iron powder of the practical example was used, and the lubricants were added as shown in Table 4.
  • the degree of C adhesion, fluidity, and ejecting force of the obtained mixture were measured in the same manner as practical example 1.
  • the result of the measurement is shown in Table 4.
  • the degree of C adhesion, fluidity, ejecting force, and the surface condition of the sintered body of the practical example 4 of the present invention showed superior characteristics against the comparison examples in which the fluidity and the surface condition of the sintered body, in particular, were inferior due to an excessive amount of the room temperature mixture excepting zinc stearate and the zinc stearate.
  • an iron-based powder mixture for powder metallurgy has advantageous characteristics.
  • the iron-based powder mixture has a stable level of powder metallurgy product and improved machinability due to reduced segregation of the alloying powder and the powder for improving machinability. It has a stabilized filling condition in the die due to superior fluidity of the powder mixture in flowing from the hopper. There is less damage to the molded body, thanks to the reduced force of ejection from the die. There is less and less contamination in the sintering furnace and surface of sintered body because of the use of reduced amounts of metallic elements such as binders and lubricants.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Powder Metallurgy (AREA)

Claims (8)

  1. Verfahren zum Herstellen eines Pulvergemisches auf Eisenbasis für Pulvermetallurgie, mit den Schritten:
    Mischen von
    (A) 0,1 Gew.-% bis 1,0 Gew.-% eines Pulvers von mindestens einer organischen Verbindung, ausgewählt aus der aus Stearinsäure, Oleinsäure-Amid und Stearinsäure-Amid bestehenden Gruppe,
    (B) 0,1 Gew.-% bis 1,0 Gew.-% eines Pulvers aus Stearinsäure-Bisamid,
    (C) 0,1 Gew.-% bis 3,0 Gew.-% eines Legierungszusatz-Pulvers, ausgewählt aus der aus Kupfer, Nickel, Graphit und Phosphor bestehenden Gruppe, und/oder eines Pulvers zum Verbessern der Bearbeitbarkeit, ausgewählt aus der aus Talkum oder Metallsulfid bestehenden Gruppe,
    (D) wobei der Rest ein Pulver auf Eisenbasis ist; danach Erwärmen des resultierenden Eisenbasis-Pulvergemisches während 30 Sekunden bis 30 Minuten in einem Temperaturbereich, der von 10°C über dem niedrigsten Schmelzpunkt der organischen Verbindung (A) bis zum Schmelzpunkt des Stearin-Bisamides (B) reicht, und
    darauffolgendes Abkühlen des Gemisches.
  2. Verfahren nach Anspruch 1, das die weiteren Schritte enthält:
    zusätzliches Mischen von 0,1 Gew.-% bis 0,5 Gew.-% von mindestens einem freien Schmierstoffpulver, ausgewählt aus der aus Stearinsäure, Oleinsäure-Amid, Stearinsäure-Amid bestehenden Gruppe und einem mit dem Pulvergemisch auf Eisenbasis während 30 s bis 30 min bei einer Temperatur unter den Schmelzpunkten der Bestandteile erwärmten Gemisch von Stearinsäure-Amid und Stearinsäure-Bisamid.
  3. Verfahren nach Anspruch 1 mit den weiteren Schritten:
    zusätzliches Mischen von 0,01 Gew.-% bis 0,25 Gew.-% eines freien Pulvers von Zinkstearat zu dem Pulvergemisch auf Eisenbasis während 30 s bis 30 min bei einer Temperatur unter den Schmelzpunkten der Bestandteile.
  4. Verfahren nach Anspruch 1 mit den weiteren Schritten:
    zusätzliches Mischen von 0,01 Gew.-% bis 0,25 Gew.-% eines freien Pulvers von Zinkstearat und 0,1 Gew.-% bis 0,5 Gew.-% von mindestens einem freien Schmierstoffpulver, ausgewählt aus der aus Stearinsäure, Oleinsäure-Amid, Stearinsäure-Amid, Stearinsäure-Bisamid bestehenden Gruppe und eines während 30 s bis 30 min bei einer Temperatur unter den Schmelzpunkten der Bestandteile erwärmten Gemisches von Stearinsäure-Amid und Stearinsäure-Bisamid mit dem Pulvergemisch auf Eisenbasis.
  5. Pulvergemisch auf Eisenbasis für Pulvermetallurgie, das umfaßt:
    ein geschmolzenes Bindergemisch, welches 0,1 Gew.-% bis 1,0 Gew.-% eines Pulvers von mindestens einer organischen Verbindung umfaßt, ausgewählt aus einer niedriger schmelzenden Gruppe, die im wesentlichen aus Stearinsäure, Oleinsäure-Amid und Stearinsäure-Amid besteht, und 0,1 Gew.-% bis 1,0 Gew.-% eines Pulvers einer organischen Verbindung einer höher schmelzenden Gruppe, die Stearinsäure-Bisamid umfaßt; und
    der Rest des Gemisches ein Pulver auf Eisenbasis umfaßt, an dessen Oberfläche 0,1 Gew.-% bis 3,0 Gew.-% eines Legierungszusatz-Pulvers angehängt ist, das ausgewählt ist aus der aus Kupfer, Nickel, Graphit und Phosphor bestehenden Gruppe, und/oder ein Pulver zum Verbessern der Bearbeitbarkeit, ausgewählt aus der aus Talkum oder einem Metallsulfid bestehenden Gruppe.
  6. Pulvergemisch auf Eisenbasis für Pulvermetallurgie nach Anspruch 5, bei dem 0,1 Gew.-% bis 0,5 Gew.-% mindestens eines freien Schmierstoffpulvers, das ausgewählt ist aus der aus Stearinsäure, Oleinsäure-Amid, Stearinsäure-Amid, Stearinsäure-Bisamid bestehenden Gruppe und ein erwärmtes Gemisch aus Stearinsäure-Amid und Stearinsäure-Bisamid gemischt wird, ohne Schmelzadhäsion an der Oberfläche des Pulvers auf Eisenbasis zu verursachen.
  7. Pulvergemisch auf Eisenbasis für Pulvermetallurgie nach Anspruch 5, bei dem 0,01 Gew.-% bis 0,25 Gew.-% eines freien Pulvers von Zinkstearat gemischt wird, ohne Schmelzadhäsion an der Oberfläche des auf Eisen basierenden Pulvers zu verursachen.
  8. Pulvergemisch auf Eisenbasis für Pulvermetallurgie gemäß Anspruch 5, bei dem 0,1 Gew.-% bis 0,5 Gew.-% mindestens eines freien Pulvers, ausgewählt aus der aus Stearinsäure, Oleinsäure-Amid, Stearinsäure-Amid, Stearinsäure-Bisamid bestehenden Gruppe und ein erwärmtes Gemisch aus Stearinsäure-Amid und Stearinsäure-Bisamid und bei dem 0,01 Gew.-% bis 0,25 Gew.-% eines freien Pulvers aus Zinkstearat zugemischt werden, ohne Schmelzadhäsion an der Oberfläche des Pulvers auf Eisenbasis zu verursachen.
EP92116479A 1992-09-25 1992-09-25 Pulvermischung auf Eisenbasis und Verfahren ihrer Herstellung Expired - Lifetime EP0589088B1 (de)

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EP92116479A EP0589088B1 (de) 1992-09-25 1992-09-25 Pulvermischung auf Eisenbasis und Verfahren ihrer Herstellung
DE69226639T DE69226639T2 (de) 1992-09-25 1992-09-25 Pulvermischung auf Eisenbasis und Verfahren ihrer Herstellung

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EP0589088B1 true EP0589088B1 (de) 1998-08-12

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CHEMICAL ABSTRACTS, vol. 114 Columbus, Ohio, US; abstract no. 47404, OKABE, RITSUO ET AL. 'Iron-base powder for powder metallurgy' & JP-A-2 057 602 (KAWASAKI STEEL CORP.) 27 February 1990 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10235413A1 (de) * 2002-08-02 2004-03-04 H.C. Starck Gmbh Herstellung Presshilfsmittel-haltiger Pulver
CN101022903B (zh) * 2004-09-17 2010-11-10 霍加纳斯股份有限公司 包含仲酰胺作为润滑剂和/或粘结剂的粉末金属组合物

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