EP0586587A1 - Verbundfilter aus Keramik-Keramik Verbundmaterial. - Google Patents
Verbundfilter aus Keramik-Keramik Verbundmaterial.Info
- Publication number
- EP0586587A1 EP0586587A1 EP92913596A EP92913596A EP0586587A1 EP 0586587 A1 EP0586587 A1 EP 0586587A1 EP 92913596 A EP92913596 A EP 92913596A EP 92913596 A EP92913596 A EP 92913596A EP 0586587 A1 EP0586587 A1 EP 0586587A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ceramic
- filter
- fibers
- layer
- preform
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B18/00—Layered products essentially comprising ceramics, e.g. refractory products
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
- C04B35/571—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide obtained from Si-containing polymer precursors or organosilicon monomers
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/636—Polysaccharides or derivatives thereof
- C04B35/6365—Cellulose or derivatives thereof
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/522—Oxidic
- C04B2235/5224—Alumina or aluminates
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- C04B2235/5228—Silica and alumina, including aluminosilicates, e.g. mullite
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- C04B2235/524—Non-oxidic, e.g. borides, carbides, silicides or nitrides
- C04B2235/5244—Silicon carbide
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- C04B2235/526—Fibers characterised by the length of the fibers
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- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
- C04B2235/6028—Shaping around a core which is removed later
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- C04B2235/614—Gas infiltration of green bodies or pre-forms
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- C04B2235/616—Liquid infiltration of green bodies or pre-forms
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- C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
- C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
- C04B2237/32—Ceramic
- C04B2237/36—Non-oxidic
- C04B2237/365—Silicon carbide
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- C04B2237/38—Fiber or whisker reinforced
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- C04B2237/58—Forming a gradient in composition or in properties across the laminate or the joined articles
- C04B2237/582—Forming a gradient in composition or in properties across the laminate or the joined articles by joining layers or articles of the same composition but having different additives
- C04B2237/584—Forming a gradient in composition or in properties across the laminate or the joined articles by joining layers or articles of the same composition but having different additives the different additives being fibers or whiskers
Definitions
- This invention relates to a ceramic fiber-ceramic matrix composite filter having a porosity which allows the rapid filtration of large quantities of fluids while trapping small particulates therein.
- Ceramic-ceramic matrix composite materials are particularly useful as candle filters or baghouse filters.
- Candle filters are shaped like long tubes, with one open end. Such filters are fastened within an enclosure which is divided into clean and dirty sides such that the fluid to be filtered traverses from the dirty to the clean side by passing through the filter. The fluid flows typically from the outside to the inside of the filter, thus providing dust and particulate-free fluid exiting from the open end thereof.
- U.S. Patent No. 4,092,194 discloses a reinforced ceramic fiber tube taught to be used as a catalyst carrier.
- the tube is comprised of layers of continuous ceramic fiber over which is deposited a non-porous binder comprised of an aqueous slurry of a refractory oxide precursor.
- U.S. Patent No. 4,181,514 discloses a stable filter structure for use in high temperature applications comprised of a stitch knitted high temperature fiber such as glass, ceramic or metallic yarn.
- U.S. Patent No. 4,687,697 discloses a filter of improved structural integrity wherein high temperature- resistant inorganic fibers are interlocked together to form a paper, with an inorganic fiber fabric then disposed on the paper.
- An adhesive is taught to hold the fabric to the paper during the formation of a pleated structure and fitting thereof into a filter frame; the adhesives and any binders that may be present are taught to burn off during use in the high temperature filtration process.
- U.S. Patent No. 4,889,630 discloses a double-layered filter wherein one layer has a coarse porosity and a second layer has a fine-grained porosity.
- the coarse layer is taught to be produced by forming coarse ceramic particles into a molded body followed by firing; the fine-grained layer is formed from very fine particles of ceramic materials optionally mixed with fine diameter short fibers.
- Materials taught to be useful for the formation of both layers include quartz, alumino-silicate, glass, aluminum oxide, silicon carbide, graphite or activated carbon, and metals.
- U.S. Patent No. 4,894,070 describes a tubular porous ceramic filter, taught to be useful for the filtration of particles from hot gases.
- the filter contains ceramic fibers, such as alumina, aluminosilicate, and mixtures thereof, together with a binder or colloidal oxide hydrosol.
- the tubes are formed by vacuum filtration of an aqueous slurry of the ceramic fibers through a wire mesh.
- U.S. Patent No. 4,917,941 discloses a ceramic composite comprised of a layer of continuous ceramic filaments surrounded by a mixture of chopped fibers, whiskers and/or particulates, which is infiltrated with a ceramic to form a matrix phase.
- the matrix forming material, or infiltrant is taught to be a "meltable ceramic" (with a melting point range from about -1400°C to about 2000°C) , which is comprised of alkaline earth silicates or alkaline earth alumino-silicates.
- the filtering surface can then be prepared by winding ceramic fibers in a sufficient pattern to assure an appropriate pore size or by deposition of a ceramic fiber felt on the support surface. Silicon carbide is then coated onto the surface, typically by chemical vapor deposition. In this way a filter having excellent strength and toughness is obtained.
- the filter is light in weight, a feature providing excellent economy since such filters are typically supported by steel framing.
- a ceramic-ceramic composite filter comprised of a base or support of texturized continuous ceramic fibers fashioned into a desired shape, an optionally felt layer comprised of inorganic chopped fibers and whiskers which bridge the pores in the fibrous base, a carbonaceous layer, and a silicon carbide overlayer.
- the filter surface exhibits a fine porosity sufficient to filter small particles from fluids, such as hot gases, i.e., on the order of 1 to 50 micrometers, but exhibits a small pressure drop across the filter such that large quantities of fluid may be filtered rapidly, due to the support having pore diameters of greater than 100 micrometers.
- bundles of ceramic fibers are first typically texturized by a conventional textile process which causes very fine filaments to extend from the surface of the tows, which are in essence broken- fibers. Such filaments are desirable, although not absolutely necessary as they are thought to assist in locking neighboring yarns together.
- the tows are then (1) braided or woven into the desired shape, or (2) woven into a cloth and then formed into the desired shape, or (3) formed into the desired shape by filament winding.
- This ceramic fiber preform is then rigidized by the application of a phenolic resin thereto.
- the rigid member can be overcoated with a layer of chopped ceramic fiber, or felt, if desired, dried, and then overcoated and infiltrated with a layer of silicon carbide.
- the shape typically tubular, is closed at one end, providing the look of a large test tube. Such tubes are fastened at the exit port of hot gas exhaust in order to filter particles therefrom.
- the filter can be manufactured into various sizes and shapes as desired.
- the tube can be formed into various styles of weave or braid. It can be fashioned by traditional weaving or braiding methods, or preferably formed by a method known as filament winding, a technique well known in the textile art. In some cases, a very open weave, with very large spaces (i.e.
- a preferred ceramic fiber for use herein is commercially available under the NEXTELTM brand from the 3M Company, which is comprised of aluminoborosilicate. Fibers of this type are disclosed in U.S. Patent Nos. 3,795,524 and 4,047,965.
- the workpiece In order to effectively coat the ceramic fiber preform in a chemical vapor deposition (CVD) furnace, the workpiece must be rigidized, typically by applying a phenolic resin to the fibers followed by curing of the workpiece in an oven. This phenolic resin becomes pyrolyzed to form a carbonaceous layer, which must support the weight of the fiber preform during the early stages of the chemical vapor deposition process such that same does not stretch. This tendency to stretch may be further minimized by having some of the tows of ceramic fiber oriented along the long axis of the preform.
- CVD chemical vapor deposition
- this carbonaceous layer assists in preventing extremely good bonding between the ceramic fiber preform and the silicon carbide overcoat. Such is important because the fusion of such layers would result in a material exhibiting non-composite behavior, i.e., it would tend to be brittle and potentially exhibit catastrophic failure.
- One way to measure the properties of a composite is to examine same after fracture for fiber "pull-out", also known as a brushy fracture surface. Such a surface is desirable, because it indicates that the fibers have not fused together or fused to the matrix material.
- the phenolic resin can be applied by a variety of techniques. For example, it can be applied by individual fiber tows during the filament winding process or before they are woven into cloth. Alternatively, the resin can be sprayed onto a completed workpiece, or same can be dipped into the resin following the winding or weaving process. The resin-coated preform is then cured in an oven typically at 190°C for one hour, which causes the rigidization thereof.
- a layer of chopped ceramic fibers may be deposited over the surface of the rigid preform by forming a slurry of such chopped fibers in a slightly viscous aqueous mixture.
- the open end of the preform may then be attached to a vacuum system, the preform lowered into a tank containing the suspension of chopped fibers, and vacuum applied.
- the liquid component of the slurry will flow through the preform with the small fibers deposited on the outside surface thereof.
- the preform is then removed from the tank, air dried by pulling air through same, and then dried in an oven at about 90°C. Additional phenolic resin may be applied over this felt or chopped fiber layer such that the resin is distributed throughout same, which provides additional stability to the workpiece for application of the CVD coating.
- the resin is then cured by placing the preform in an oven typically at 190°C for one hour.
- Commercially available fibers which can be used in the felt layer include chopped NEXTELTM 312 and NEXTELTM 440 fibers available from the 3M Company, alumina fibers comprising approximately 96% to 97% alumina and 3% to 4% silica and having a use temperature of about 1600°C sold under the tradena e Saffill available from ICI, and silicon carbide fibers comprising about 54% silicon, 12% oxygen and 30% carbon and having a use temperature of about 1200° C available AS Nicalon from Nippon Carbon.
- the resultant rigidized form is placed in a CVD chamber, well known in the art, and heated resistively or by induction under vacuum.
- Placement in the reactor is such that gas flows from the inside to the outside while the heat source is from the outside.
- Such is known as a "forced flow” process which will lead to a more rapid CVD than will occur if gases pass through the preforms driven by diffusion only.
- hydrogen gas and methyltrichlorosilane (MTS) are introduced to the CVD reactor, providing silicon carbide deposition on the preform and hydrogen chloride formation as a reaction product.
- Byproduct and unreacted hydrogen and MTS are removed from the reactor via vacuum pumping and scrubbing mechanisms.
- Typical process conditions for the CVD operation are pressures of 5 to 50 torr, flow rates of from 6 to 12 standard liters per minute of MTS and hydrogen gas, and temperatures of from 1000 to 1100°C. Coating times range from 15 to 17 hours. Under such conditions, the preforms received about 160 to about 200 weight percent of silicon carbide.
- the fibers in the resultant composite are coated on all sides with silicon carbide, providing a high degree of infiltration of silicon carbide into the fibrous structure, essential for maximizing strength and toughness.
- the resultant ceramic-ceramic composite tube is a rigid, permeable composite capable of withstanding temperatures up to about 1000°C for indefinite periods.
- This Example describes a composite made from ceramic fiber tows which had texturized, or roughened surfaces, with no additional felt layer applied to it.
- the ceramic fiber preform was constructed of three filament wound plys.
- the yarn was passed through a trough containing phenolic resin (UCAR Phenolic Dispersion BKUA-2370, available from the Union Carbide Corporation) and then filament wound (while still wet with resin) over a mandrel. It was important to agitate the suspension of resin during the coating process. This was achieved by using a small peristaltic action pump to circulate the resin through the trough. Coating with the resin added about 5% of the fiber weight.
- UAR Phenolic Dispersion BKUA-2370 available from the Union Carbide Corporation
- the first ply was NEXTELTM 312 1/2 1800 1.5 Z yarn (trade designation of an aluminoborosilicate fiber, available from the 3M Company) .
- the yarn was wound to form an angle of 11.78 degrees to the axis of the mandrel; the spacing between yarns was 0.159 cm (0.0625 in). This ply was comprised of 100 revolutions.
- the second ply was of the same yarn except that it had been texturized by exposing the finished yarn to pressurized air.
- the yarn formed an angle of 31.27 degrees to the axis of the mandrel; the spacing between the yarns was 0.159 cm. This ply was comprised of 86 revolutions.
- a third ply of the same yarn as the second ply made an angle of nearly 90 degrees with the axis of the mandrel. (This is known as a circular wrap.) Spacing between these yarns was 0.095 cm (0.0375 in).
- This resin-coated preform was then dried in an oven at 190°C for one hour, resulting in a tube with an inside diameter of 5.08 cm (2 inches) and an outside diameter of about 5.4 cm (2.15 inches).
- a set of four preforms was then placed in a CVD apparatus, comprising a quartz vacuum envelope, a graphite reactor, and an induction-heated coil, in such a way that gas flow was forced to go from the inside of the preform, through the preform wall, and finally through the outside surface.
- MTS and hydrogen gases were fed into the reactor and silicon carbide deposited on the preform. Unreacted MTS, hydrogen and hydrogen chloride, a byproduct of this reaction, exited through the scrubbing system.
- Hydrogen flow rate 12 standard liters/minute
- Low pressure was utilized during the initial stages of coating in order to insure infiltration of the preform and the deposition of silicon carbide over the surfaces of all filaments and fibers.
- Lower pressure enhances "throwing power", the ability to penetrate into the interior of the structure.
- Approximately 15 hours of CVD were needed to achieve a weight ratio of matrix/support of about 1.7 - 2.
- Example 2 This example describes a composite wherein ceramic fiber felt is applied over a texturized ceramic fiber preform.
- the ceramic fiber preform was constructed of three filament wound plys. First, the yarn was treated with phenolic resin as per Example 1. Then, the plys were formed as per Example 1 with the same materials, the only exception being that the spacing between the yarns in the outer layer was 0.159 cm (0.0625 in).
- Chopped ceramic fibers were then deposited on the filament wound substrate.
- a 50/50 weight percent Nicalon (chopped, 3 mm length, 15 to 20 micrometer diameter, silicon carbide fiber) /Saffil (commercially available chopped alumina fiber, RF grade) suspension was formed by slurrying the fibers in a mixture of Methocell A4M (available from Dow Chemical and comprised of a mixture of cellulose ethers having a molecular weight of about 70,000) and water.
- Methocell A4M available from Dow Chemical and comprised of a mixture of cellulose ethers having a molecular weight of about 70,000
- the Methocell aids in increasing the viscosity of the slurry, thus better holding the fibers in suspension and making deposition more uniform along the length of the preform.
- the viscosity was measured at 50 centipoise by a Brookfield viscometer.
- the slurry concentration was 0.00092 g fiber/cc.
- the slurry was poured into a 1.905 m x 38.1 cm x 25.4 (75 in x 15 in x 10 in) rectangular tank.
- the rigid preform was attached to a vacuum source at the open end, and lowered into the tank. Vacuum, about 17 inches of mercury, was applied suddenly, which caused the water/Methocell mixture to flow through the preform, depositing the ceramic fibers on the outside of the tube.
- the preform was quickly raised from the tank, and air dried by drawing air through it. This partially dried the layer of chopped fibers and helped them adhere to the preform until air dried for 24 hours and dried in an oven at 95°C for one hour. Additional phenolic resin was then applied by spraying. This was then further cured at 190°C for one hour.
- the weight of the resin was about 5% of the weight of the chopped fiber. After this preparation, the preform was placed in the CVD apparatus of Example 1 using the same conditions.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Filtering Materials (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US69880491A | 1991-05-13 | 1991-05-13 | |
US698804 | 1991-05-13 | ||
PCT/US1992/003260 WO1992020638A1 (en) | 1991-05-13 | 1992-04-22 | Ceramic-ceramic composite filter |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0586587A1 true EP0586587A1 (de) | 1994-03-16 |
EP0586587B1 EP0586587B1 (de) | 1997-03-26 |
Family
ID=24806725
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92913596A Expired - Lifetime EP0586587B1 (de) | 1991-05-13 | 1992-04-22 | Verbundfilter aus Keramik-Keramik Verbundmaterial |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP0586587B1 (de) |
JP (1) | JPH06507878A (de) |
KR (1) | KR100198016B1 (de) |
AU (1) | AU2183792A (de) |
BR (1) | BR9205991A (de) |
CA (1) | CA2109089A1 (de) |
CZ (1) | CZ241993A3 (de) |
DE (1) | DE69218593T2 (de) |
ES (1) | ES2099267T3 (de) |
FI (1) | FI935021A (de) |
HU (1) | HU9303213D0 (de) |
WO (1) | WO1992020638A1 (de) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5411763A (en) * | 1993-01-11 | 1995-05-02 | Martin Marietta Energy Systems, Inc. | Method of making a modified ceramic-ceramic composite |
DE19713068A1 (de) * | 1997-03-27 | 1998-10-01 | Ecm Ingenieur Unternehmen Fuer | Verfahren zur Herstellung von Heißgasfilter-Elementen sowie die Verwendung des Filters zur Heißgasfiltration von Rauchgasen |
DE102005018874B4 (de) * | 2005-04-23 | 2010-12-30 | Ceramat, S. Coop., Asteasu | Verfahren zur Herstellung einer Fasermatte und Fasermatte |
KR100836059B1 (ko) * | 2006-03-31 | 2008-06-09 | 주식회사 엘지화학 | 점토를 포함하는 세라믹 필터 및 그 제조 방법 |
KR101237349B1 (ko) | 2007-01-09 | 2013-02-28 | (주)엘지하우시스 | 내충격성이 뛰어난 플러깅된 탄화규소 필터의 제조방법 |
CN102718494B (zh) * | 2012-06-21 | 2014-03-19 | 海南大学 | 一种复合碳化硅陶瓷过滤膜材料的制备方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4397901A (en) * | 1979-07-31 | 1983-08-09 | Warren James W | Composite article and method of making same |
DE3213951C2 (de) * | 1982-04-16 | 1989-08-10 | KERFA GmbH Industriebeheizungen, 5820 Gevelsberg | Verfahren zur Herstellung eines Keramikfaserisolierstoffkörpers |
US4500328A (en) * | 1983-02-22 | 1985-02-19 | Gilbert W. Brassell | Bonded carbon or ceramic fiber composite filter vent for radioactive waste |
EP0322932B1 (de) * | 1987-12-23 | 1994-03-30 | Hi-Tech Ceramics, Inc. | Mit Fasern gefüllte retikulierte Keramik, verwendet zur Auskleidung von Ofen |
US5075160A (en) * | 1988-06-13 | 1991-12-24 | Martin Marietta Energy Systems, Inc. | Ceramic fiber reinforced filter |
-
1992
- 1992-04-22 ES ES92913596T patent/ES2099267T3/es not_active Expired - Lifetime
- 1992-04-22 WO PCT/US1992/003260 patent/WO1992020638A1/en active IP Right Grant
- 1992-04-22 CZ CS932419A patent/CZ241993A3/cs unknown
- 1992-04-22 CA CA002109089A patent/CA2109089A1/en not_active Abandoned
- 1992-04-22 KR KR1019930703397A patent/KR100198016B1/ko not_active IP Right Cessation
- 1992-04-22 DE DE69218593T patent/DE69218593T2/de not_active Expired - Fee Related
- 1992-04-22 BR BR9205991A patent/BR9205991A/pt not_active Application Discontinuation
- 1992-04-22 EP EP92913596A patent/EP0586587B1/de not_active Expired - Lifetime
- 1992-04-22 JP JP5500041A patent/JPH06507878A/ja active Pending
- 1992-04-22 AU AU21837/92A patent/AU2183792A/en not_active Abandoned
-
1993
- 1993-11-12 HU HU9303213A patent/HU9303213D0/hu unknown
- 1993-11-12 FI FI935021A patent/FI935021A/fi unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9220638A1 * |
Also Published As
Publication number | Publication date |
---|---|
FI935021A0 (fi) | 1993-11-12 |
DE69218593T2 (de) | 1997-09-18 |
CA2109089A1 (en) | 1992-11-14 |
DE69218593D1 (de) | 1997-04-30 |
JPH06507878A (ja) | 1994-09-08 |
BR9205991A (pt) | 1994-08-02 |
FI935021A (fi) | 1993-11-12 |
CZ241993A3 (en) | 1994-04-13 |
AU2183792A (en) | 1992-12-30 |
HU9303213D0 (en) | 1994-03-28 |
WO1992020638A1 (en) | 1992-11-26 |
EP0586587B1 (de) | 1997-03-26 |
KR100198016B1 (ko) | 1999-06-15 |
ES2099267T3 (es) | 1997-05-16 |
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