EP0568336A3 - - Google Patents

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Publication number
EP0568336A3
EP0568336A3 EP19930303310 EP93303310A EP0568336A3 EP 0568336 A3 EP0568336 A3 EP 0568336A3 EP 19930303310 EP19930303310 EP 19930303310 EP 93303310 A EP93303310 A EP 93303310A EP 0568336 A3 EP0568336 A3 EP 0568336A3
Authority
EP
European Patent Office
Prior art keywords
hydrogen peroxide
epoxidized
epoxides
olefins
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19930303310
Other languages
English (en)
Other versions
EP0568336B1 (en
EP0568336A2 (en
Inventor
Guy L. Crocco
John G. Zajacek
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lyondell Chemical Technology LP
Original Assignee
Arco Chemical Technology LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=25368548&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0568336(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Arco Chemical Technology LP filed Critical Arco Chemical Technology LP
Publication of EP0568336A2 publication Critical patent/EP0568336A2/en
Publication of EP0568336A3 publication Critical patent/EP0568336A3/xx
Application granted granted Critical
Publication of EP0568336B1 publication Critical patent/EP0568336B1/en
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP93303310A 1992-04-30 1993-04-28 Epoxidation process using titanium-rich silicalite catalysts Revoked EP0568336B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/876,772 US5262550A (en) 1992-04-30 1992-04-30 Epoxidation process using titanium-rich silicalite catalysts
US876772 1992-04-30

Publications (3)

Publication Number Publication Date
EP0568336A2 EP0568336A2 (en) 1993-11-03
EP0568336A3 true EP0568336A3 (enrdf_load_stackoverflow) 1994-03-16
EP0568336B1 EP0568336B1 (en) 1995-11-02

Family

ID=25368548

Family Applications (1)

Application Number Title Priority Date Filing Date
EP93303310A Revoked EP0568336B1 (en) 1992-04-30 1993-04-28 Epoxidation process using titanium-rich silicalite catalysts

Country Status (6)

Country Link
US (1) US5262550A (enrdf_load_stackoverflow)
EP (1) EP0568336B1 (enrdf_load_stackoverflow)
JP (1) JPH069592A (enrdf_load_stackoverflow)
AT (1) ATE129708T1 (enrdf_load_stackoverflow)
DE (1) DE69300720T2 (enrdf_load_stackoverflow)
ES (1) ES2079236T3 (enrdf_load_stackoverflow)

Families Citing this family (72)

* Cited by examiner, † Cited by third party
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US5214168A (en) * 1992-04-30 1993-05-25 Arco Chemical Technology, L.P. Integrated process for epoxide production
DE4218765A1 (de) 1992-06-06 1993-12-09 Basf Ag Verfahren zur Herstellung von Oxiranen
DE4419195A1 (de) * 1993-07-12 1995-01-19 Degussa Strukturierter Katalysator, bestehend aus mikroporösen Oxiden von Silicium, Aluminium und Titan
US5468885A (en) * 1993-12-20 1995-11-21 Arco Chemical Technology, L.P. Epoxidizer oxygen recovery
US5374747A (en) * 1993-12-23 1994-12-20 Arco Chemical Technology, L.P. Epoxidation process and catalyst therefore
US5453511A (en) * 1993-12-23 1995-09-26 Arco Chemical Technology, L.P. Bis-piperidinium compounds
US5354875A (en) * 1993-12-23 1994-10-11 Uop Epoxidation of olefins using a titania-supported titanosilicate
US5384418A (en) * 1994-01-25 1995-01-24 Arco Chemical Technology, L.P. Integrated process for epoxide production
US5474754A (en) * 1994-08-15 1995-12-12 Arco Chemical Technology, L.P. Preparation of an aluminosilicotitanate isomorphous with zeolite beta
US5463090A (en) * 1994-10-27 1995-10-31 Arco Chemical Technology, L.P. Integrated process for epoxide production
US5646314A (en) * 1994-11-16 1997-07-08 Arco Chemical Technology, L.P. Process for titanium silicalite-catalyzed epoxidation
US5523426A (en) * 1995-01-04 1996-06-04 Arco Chemical Technology, L.P. Integrated process for epoxidation
US5693834A (en) * 1995-03-15 1997-12-02 Arco Chemical Technology, L.P. Integrated process for epoxidation
US5591875A (en) * 1995-08-02 1997-01-07 Chang; Te Epoxidation Process
DE69612349T2 (de) * 1995-10-31 2001-09-06 Nippon Shokubai Co. Ltd., Osaka Verfahren zur Herstellung von Epoxyverbindungen
US5723637A (en) * 1995-12-06 1998-03-03 Sumitomo Chemical Company, Limited Process for producing propylene oxide
DE19600708A1 (de) * 1996-01-11 1997-07-17 Basf Ag Oxidationskatalysator mit einem Gehalt an Lanthanoidmetallen, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators
US5741749A (en) 1996-02-13 1998-04-21 Arco Chemical Technology, L.P. Regeneration of a titanium-containing molecular sieve
DE19607577A1 (de) * 1996-02-29 1997-09-04 Basf Ag Netzkatalysator auf Basis von Titan- oder Vanadiumzeolithen und inerten Netzgeweben zur Beschleunigung von Oxidationsreaktionen
ES2126485B1 (es) * 1996-05-16 1999-12-01 Univ Valencia Politecnica Procedimiento y catalizadores para la obtencion de epoxidos y derivados hidroxilados de acidos y esteres de acidos grasos.
DE19623611A1 (de) * 1996-06-13 1997-12-18 Basf Ag Verfahren zur Herstellung von Epoxiden aus Olefinen und Wasserstoffperoxid
DE19623608A1 (de) * 1996-06-13 1997-12-18 Basf Ag Verfahren zur Herstellung von Epoxiden aus Olefinen und Wasserstoffperoxid oder Hydroperoxiden
BE1010716A3 (fr) * 1996-10-25 1998-12-01 Solvay Procede de regeneration de catalyseurs de type silicalite au titane.
GB9707981D0 (en) * 1997-04-21 1997-06-11 Exxon Chemical Patents Inc Molecular sieve
DE19723751A1 (de) * 1997-06-06 1998-12-10 Basf Ag Formkörper und Verfahren zu dessen Herstellung
FR2764301B1 (fr) * 1997-06-09 1999-07-30 Elf Antar France Composition de carburant comprenant des composes oxygenes pour moteurs diesel
WO1998056780A1 (es) * 1997-06-10 1998-12-17 Universidad Politecnica De Valencia Procedimiento y catalizadores para la obtencion de epoxidos y derivados hidroxilados de acidos y esteres de acidos grasos
US5849938A (en) 1997-09-02 1998-12-15 Arco Chemical Technology, L.P. Separation of methanol and propylene oxide from a reaction mixture
BE1011456A3 (fr) * 1997-09-18 1999-09-07 Solvay Procede de fabrication d'un oxiranne.
BE1011576A3 (fr) * 1997-11-27 1999-11-09 Solvay Produit a base d'epichlorhydrine et procede de fabrication de ce produit.
BE1011577A3 (fr) 1997-11-27 1999-11-09 Solvay Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de catalyseur.
BE1011578A3 (fr) * 1997-11-27 1999-11-09 Solvay Catalyseur d'epoxydation, son utilisation et procede d'epoxydation en presence de ce catalyseur.
US6160138A (en) * 1998-03-26 2000-12-12 Repsol Quimica, S.A. Process for epoxydation of olefinic compounds with hydrogen peroxide
DE19835907A1 (de) * 1998-08-07 2000-02-17 Basf Ag Verfahren zur Umsetzung einer organischen Verbindung mit einem Hydroperoxid
DE19839792A1 (de) * 1998-09-01 2000-03-02 Basf Ag Verfahren zur Herstellung eines Titansilikates mit RUT-Struktur
EP1384506A3 (en) 1999-04-08 2004-02-04 Dow Global Technologies Inc. Titanium containing supports for gold catalysts
KR20000071797A (ko) 1999-04-28 2000-11-25 나까니시 히로유끼 하이드록실화용 촉매 및 방향족 하이드록시 화합물의 제조방법
JP4325045B2 (ja) * 1999-11-09 2009-09-02 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法、該触媒及び該触媒を用いたオキシラン化合物の製造方法
DE19954322A1 (de) 1999-11-10 2001-05-17 Basf Ag Oxid und Verfahren zu dessen Herstellung
EP1122246A1 (de) 2000-02-07 2001-08-08 Degussa AG Verfahren zur Epoxidierung von Olefinen
EP1122248A1 (de) 2000-02-07 2001-08-08 Degussa AG Verfahren zur Epoxidierung von Olefinen
EP1122247A1 (de) 2000-02-07 2001-08-08 Degussa AG Verfahren zur Epoxidierung von Olefinen
FR2806084A1 (fr) * 2000-03-10 2001-09-14 Solvay Procede de fabrication d'un oxiranne
DE10015246A1 (de) * 2000-03-28 2001-10-04 Basf Ag Verfahren zur Umsetzung einer organischen Verbindung mit einem Hydroperoxid
IT1318680B1 (it) * 2000-08-11 2003-08-27 Enichem Spa Processo per la produzione in continuo di ossidi olefinici.
EP1221442B1 (de) 2001-01-08 2010-07-28 Evonik Degussa GmbH Verfahren zur Epoxidierung von Olefinen
US6608219B2 (en) 2001-06-13 2003-08-19 Degussa Ag Process for the epoxidation of olefins
US6600055B2 (en) 2001-06-13 2003-07-29 Degussa Ag Process for the epoxidation of olefins
US6596881B2 (en) 2001-06-13 2003-07-22 Degussa Ag Process for the epoxidation of olefins
US6749668B2 (en) 2001-06-18 2004-06-15 Degussa Ag Process for the recovery of combustible components of a gas stream
JP2004525073A (ja) * 2001-08-13 2004-08-19 ダウ グローバル テクノロジーズ インコーポレイティド オレフィンオキシドの連続製造方法
US6610865B2 (en) 2001-08-15 2003-08-26 Degussa Ag Process for the epoxidation of olefins
US6596883B2 (en) 2001-08-23 2003-07-22 Degussa Ag Process for the epoxidation of olefins
US6720436B2 (en) 2002-03-18 2004-04-13 Degussa Ag Process for the epoxidation of olefins
US7141683B2 (en) 2002-05-02 2006-11-28 Degussa Ag Process for the epoxidation of olefins
US6838572B2 (en) 2002-09-30 2005-01-04 Degussa Ag Process for the epoxidation of olefins
US7722847B2 (en) 2002-09-30 2010-05-25 Evonik Degussa Gmbh Aqueous hydrogen peroxide solutions and method of making same
FR2846964B1 (fr) * 2002-11-12 2006-07-21 Procede de fabrication de 1,2-epoxy-3-chloropropane
US7169945B2 (en) 2002-11-26 2007-01-30 Degussa Ag Process for the epoxidation of olefins
WO2004058737A1 (ja) * 2002-12-24 2004-07-15 Showa Denko K.K. 炭素−炭素二重結合の酸化方法および酸化化合物の製造方法
KR100762862B1 (ko) 2005-06-24 2007-10-04 쇼와 덴코 가부시키가이샤 탄소-탄소 이중결합의 산화방법 및 산화 화합물의 제조방법
US8048402B2 (en) * 2005-08-18 2011-11-01 Exxonmobil Chemical Patents Inc. Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins
CN101570523B (zh) * 2008-04-29 2011-11-02 中国石油化工股份有限公司 一种催化氧化烯丙醇生产环氧丙醇的方法
WO2010101700A1 (en) * 2009-03-05 2010-09-10 Dow Global Technologies Inc. Polyols from hppo and polyurethane products made therefrom
JP2013501070A (ja) * 2009-08-05 2013-01-10 ダウ グローバル テクノロジーズ エルエルシー プロピレンオキサイドの製造方法
BR112012002540A2 (pt) * 2009-08-05 2019-09-24 Dow Global Technologies Inc composição de fase líquida múltipla e processo para preparação de um produto de oxirano a partir de uma olefina e um composto de peróxido
RU2434859C1 (ru) * 2010-03-09 2011-11-27 Государственное образовательное учреждение высшего профессионального образования Нижегородский государственный технический университет им. Р.Е. Алексеева (НГТУ) Способ получения глицидола
US8754246B2 (en) * 2011-02-04 2014-06-17 Dow Global Technologies, Llc Separating phases of a mixture
TWI589567B (zh) * 2012-12-24 2017-07-01 China Petrochemical Development Corporation Taipei (Taiwan) Method of making epoxides
CN103172597B (zh) * 2013-04-03 2017-12-22 北京石油化工学院 钛硅分子筛催化合成环氧脂肪酸甲酯的方法
WO2016153969A1 (en) * 2015-03-20 2016-09-29 Northwestern University Catalysts and related methods for photocatalytc production of h2o2 and thermocatalytic reactant oxidation
CN114426551B (zh) * 2020-10-15 2024-02-02 中国石油化工股份有限公司 一种制备二氧化双环戊二烯dcpddo的方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0568337A2 (en) * 1992-04-30 1993-11-03 ARCO Chemical Technology, L.P. Integrated process for epoxide production involving hydrogen peroxide oxidation on a titanium silicazite catalyst

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IT1152296B (it) * 1982-07-28 1986-12-31 Anic Spa Procedimento per la sintesi di monometileteri dei glicoli
IT1152299B (it) * 1982-07-28 1986-12-31 Anic Spa Procedimento per l'espossidazione di composti olefinici
IT1184316B (it) * 1985-02-05 1987-10-28 Enichem Sintesi Procedimento per la monoepossidazione di composti contenenti due doppi legami
IT1187661B (it) * 1985-04-23 1987-12-23 Enichem Sintesi Catalizzatore a base di silicio e titanio ad elevata resistenza meccanica
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Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
EP0568337A2 (en) * 1992-04-30 1993-11-03 ARCO Chemical Technology, L.P. Integrated process for epoxide production involving hydrogen peroxide oxidation on a titanium silicazite catalyst

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
A. THANGARAJ ET AL.: "Catalytic Properties of Crystalline Titanium Silicalites. I. Synthesis and Characterization of Titanium-Rich Zeolites with MFI Structure", JOURNAL OF CATALYSIS, vol. 130, 1991, NEW-YORK (USA), pages 1 - 8 *
A. THANGARAJ ET AL.: "Catalytic Properties of Crystalline Titanium Silicalites. II. Hydroxylation of Phenol with Hydrogen Peroxide over TS-1 Zeolites", JOURNAL OF CATALYSIS, vol. 131, 1991, NEW-YORK (USA), pages 294 - 297 *
A. THANGARAJ ET AL.: "Catalytic Properties of Crystalline Titanium Silicalites. III. Ammoximation of Cyclohexanone", JOURNAL OF CATALYSIS, vol. 131, 1991, NEW-YORK (USA), pages 394 - 400, XP002926482, DOI: doi:10.1016/0021-9517(91)90274-8 *
U. ROMANO ET AL.: "Selective oxidation with Ti-silicalite", LA CHIMICA & L'INDUSTRIA, vol. 72, no. 7, 1990, MILAN (IT), pages 610 - 616, XP008064647 *

Also Published As

Publication number Publication date
JPH069592A (ja) 1994-01-18
DE69300720D1 (de) 1995-12-07
EP0568336B1 (en) 1995-11-02
ES2079236T3 (es) 1996-01-01
ATE129708T1 (de) 1995-11-15
DE69300720T2 (de) 1996-04-11
EP0568336A2 (en) 1993-11-03
US5262550A (en) 1993-11-16

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