EP0546237A1 - Méthode pour lubrifier et assurer l'étanchéité des bouchons en liège à l'aide de compositions à base de silicone et de paraffine ou à base de silicone de paraffine et de plastifiant - Google Patents

Méthode pour lubrifier et assurer l'étanchéité des bouchons en liège à l'aide de compositions à base de silicone et de paraffine ou à base de silicone de paraffine et de plastifiant Download PDF

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Publication number
EP0546237A1
EP0546237A1 EP92103933A EP92103933A EP0546237A1 EP 0546237 A1 EP0546237 A1 EP 0546237A1 EP 92103933 A EP92103933 A EP 92103933A EP 92103933 A EP92103933 A EP 92103933A EP 0546237 A1 EP0546237 A1 EP 0546237A1
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EP
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Prior art keywords
paraffin
silicone
fact
fluid
food grade
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP92103933A
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German (de)
English (en)
Inventor
Ugo Mestrallet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
La Tecnochimica Sas Di Ugo Mestrallet & C
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La Tecnochimica Sas Di Ugo Mestrallet & C
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Publication of EP0546237A1 publication Critical patent/EP0546237A1/fr
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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    • C10M107/00Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/50Lubricating compositions characterised by the base-material being a macromolecular compound containing silicon
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    • C10M109/00Lubricating compositions characterised by the base-material being a compound of unknown or incompletely defined constitution
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    • C10M125/00Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/10Metal oxides, hydroxides, carbonates or bicarbonates
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    • C10M125/26Compounds containing silicon or boron, e.g. silica, sand
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    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/16Ethers
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    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26Carboxylic acids; Salts thereof
    • C10M129/28Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/38Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/40Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
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    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/68Esters
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    • C10M147/02Monomer containing carbon, hydrogen and halogen only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67BAPPLYING CLOSURE MEMBERS TO BOTTLES JARS, OR SIMILAR CONTAINERS; OPENING CLOSED CONTAINERS
    • B67B1/00Closing bottles, jars or similar containers by applying stoppers
    • B67B1/03Pretreatment of stoppers, e.g. cleaning, steaming, heating, impregnating or coating; Applying resilient rings to stoppers
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
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    • C10M2229/04Siloxanes with specific structure
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    • C10M2229/04Siloxanes with specific structure
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    • C10M2229/0455Siloxanes with specific structure containing silicon-to-hydroxyl bonds used as base material
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    • C10M2229/04Siloxanes with specific structure
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    • C10M2229/0465Siloxanes with specific structure containing silicon-oxygen-carbon bonds used as base material
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    • C10M2229/04Siloxanes with specific structure
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    • C10M2229/04Siloxanes with specific structure
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    • C10M2229/04Siloxanes with specific structure
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    • C10M2229/04Siloxanes with specific structure
    • C10M2229/05Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/051Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing halogen
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/05Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/052Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen
    • C10M2229/0525Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen used as base material
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/05Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/053Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing sulfur
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    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04Siloxanes with specific structure
    • C10M2229/05Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
    • C10M2229/054Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing phosphorus
    • C10M2229/0545Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing phosphorus used as base material
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    • C10N2010/02Groups 1 or 11
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    • C10N2010/04Groups 2 or 12
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    • C10N2040/30Refrigerators lubricants or compressors lubricants
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    • C10N2040/32Wires, ropes or cables lubricants
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    • C10N2040/34Lubricating-sealants
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    • C10N2040/36Release agents or mold release agents
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    • C10N2040/38Conveyors or chain belts
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/40Generators or electric motors in oil or gas winning field
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    • C10N2040/42Flashing oils or marking oils
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    • C10N2040/44Super vacuum or supercritical use
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    • C10N2040/50Medical uses

Definitions

  • This invention covers a method for lubrication and sealing of cork stoppers and for the organoleptic preservation of the contents of these containers.
  • cork stoppers were coated with hydrocarbon based lubricating agents such as paraffin and vaselin to facilitate stoppering and later removal of the corks and to guarantee perfect sealing and organoleptic preservation of the product.
  • this invention has the aim further to improve on known techniques by a new method based upon a peculiar association of products and their preparation.
  • paraffins were used for cork stopper lubrication, but these paraffins cannot be used for pasteurization purposes because of their low melting point.
  • paraffins have proved to be excellent and harmless lubricants and sealants for cork stoppers, so that this invention has the aim to ensure their re-utilization by batching them with suitable other products in order to create a thermostable product having good lubrication and sealing characteristics.
  • Stabilization of the two main constituents in the batch i.e. silicone fluid and paraffin, which are chemically incompatible since they are mutually insoluble, non emulsifiable in absence of solvents and are having completely different melting points, is achieved by adding pyrolitic silica gel acting as a thickener of the silicone fluid and a mix of finely homogenized, thermal and physically stable constituents.
  • the paraffin is oxystabilized, for instance, by adding butyloxyanisole or a synergic mixture of butyloxyanisole and dodecylgallate.
  • Metal stearates like lithium, magnesium, sodium, calcium etc. will also be added as anti stick-slip agents to ensure dynamic and static balancing of the friction coefficient of the cork stopper at a rational average value.
  • the dynamic component has indeed the aim to provide for smooth stoppering and unstoppering of the bottles, whereas the static component shall provide for a perfect seal and prevent the liquid from seeping along the cork surface into the bottle when no proper steps are taken to keep the bottles in upright position for at least 24 hours after stoppering to allow for re-expansion of the cork stoppers.
  • pigments such as titanium bioxide and iron oxides may be added, to dye the processed corks in various shades, according to specific requirements.
  • plastic polymers like tetrafluorethylene (TFE) suitable for foodstuffs may also be added.
  • TFE tetrafluorethylene
  • Preparation of the compound subject matter of this invention can be by hot or cold processing.
  • the hot process is sequenced as follows:
  • paraffin may be substituted by F.U. viscous Vaseline or soft white vaseline which requires no powdering.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
EP92103933A 1991-12-12 1992-03-07 Méthode pour lubrifier et assurer l'étanchéité des bouchons en liège à l'aide de compositions à base de silicone et de paraffine ou à base de silicone de paraffine et de plastifiant Withdrawn EP0546237A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITGE910166A IT1253568B (it) 1991-12-12 1991-12-12 Metodo di lubrificazione e sigillatura dei tappi con composti silico- paraffinici e plasto-silico-paraffinici
ITGE910166 1991-12-12

Publications (1)

Publication Number Publication Date
EP0546237A1 true EP0546237A1 (fr) 1993-06-16

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EP92103933A Withdrawn EP0546237A1 (fr) 1991-12-12 1992-03-07 Méthode pour lubrifier et assurer l'étanchéité des bouchons en liège à l'aide de compositions à base de silicone et de paraffine ou à base de silicone de paraffine et de plastifiant

Country Status (2)

Country Link
EP (1) EP0546237A1 (fr)
IT (1) IT1253568B (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0773090A1 (fr) * 1995-11-07 1997-05-14 Christopher David Aberdein Méthode pour la fabrication d'un bouchon à liège
WO2003029130A1 (fr) * 2001-09-27 2003-04-10 Wacker-Chemie Gmbh Procede pour impregner des bouchons de bouteille
EP1640031A2 (fr) * 2004-09-28 2006-03-29 Nipro Corporation Seringue couverte avec un lubrifiant contenant de l'huile de silicone et du silice

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2336841A1 (de) * 1973-07-19 1975-02-06 Geb Gueltig Renate Woerz Verfahren zum ueberziehen von flaschenkorken mit kunststoff
DE2424451A1 (de) * 1974-05-20 1975-12-11 Staedtler Fa J S Plastische masse fuer modellierzwecke
EP0167202A1 (fr) * 1984-06-29 1986-01-08 The Procter & Gamble Company Procédé de chloration en position alpha, employant des anti-oxydants pour produits alimentaires, de l'oxygène ou des cyanoquinones
EP0277603A2 (fr) * 1987-02-05 1988-08-10 LA TECNOCHIMICA S.A.S. DI UGO MESTRALLET & C. Emulsion siliconée pour la lubrification de bouchons de liège, la fermeture de bouteilles et de boîtes de conserve à longue conservation pour boissons et aliments
EP0351503A1 (fr) * 1988-05-23 1990-01-24 LA TECNOCHIMICA S.A.S. DI UGO MESTRALLET & C. Préparation à base de silicones pour le blanchiment non toxique de bouchons en liège
EP0465830A2 (fr) * 1990-07-11 1992-01-15 LA TECNOCHIMICA S.r.l. Revêtement inerte et non-toxique pour bouchons en liège ayant un effet de lubrification et de plastification

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2336841A1 (de) * 1973-07-19 1975-02-06 Geb Gueltig Renate Woerz Verfahren zum ueberziehen von flaschenkorken mit kunststoff
DE2424451A1 (de) * 1974-05-20 1975-12-11 Staedtler Fa J S Plastische masse fuer modellierzwecke
EP0167202A1 (fr) * 1984-06-29 1986-01-08 The Procter & Gamble Company Procédé de chloration en position alpha, employant des anti-oxydants pour produits alimentaires, de l'oxygène ou des cyanoquinones
EP0277603A2 (fr) * 1987-02-05 1988-08-10 LA TECNOCHIMICA S.A.S. DI UGO MESTRALLET & C. Emulsion siliconée pour la lubrification de bouchons de liège, la fermeture de bouteilles et de boîtes de conserve à longue conservation pour boissons et aliments
EP0351503A1 (fr) * 1988-05-23 1990-01-24 LA TECNOCHIMICA S.A.S. DI UGO MESTRALLET & C. Préparation à base de silicones pour le blanchiment non toxique de bouchons en liège
EP0465830A2 (fr) * 1990-07-11 1992-01-15 LA TECNOCHIMICA S.r.l. Revêtement inerte et non-toxique pour bouchons en liège ayant un effet de lubrification et de plastification

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 7551, Derwent Publications Ltd., London, GB; AN 75-83340W [51] & DE-A-2 424 451 (FA STAEDLER) 11 December 1975 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0773090A1 (fr) * 1995-11-07 1997-05-14 Christopher David Aberdein Méthode pour la fabrication d'un bouchon à liège
US6216898B1 (en) 1995-11-07 2001-04-17 Portocork Internacional, S.A. Method of manufacturing a stopper
WO2003029130A1 (fr) * 2001-09-27 2003-04-10 Wacker-Chemie Gmbh Procede pour impregner des bouchons de bouteille
AU2002338678B2 (en) * 2001-09-27 2005-09-22 Wacker-Chemie Gmbh Method for impregnating bottle corks
EP1640031A2 (fr) * 2004-09-28 2006-03-29 Nipro Corporation Seringue couverte avec un lubrifiant contenant de l'huile de silicone et du silice
EP1640031A3 (fr) * 2004-09-28 2006-06-07 Nipro Corporation Seringue couverte avec un lubrifiant contenant de l'huile de silicone et du silice
US7648487B2 (en) 2004-09-28 2010-01-19 Nipro Corporation Syringe

Also Published As

Publication number Publication date
ITGE910166A0 (it) 1991-12-12
ITGE910166A1 (it) 1993-06-12
IT1253568B (it) 1995-08-08

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