EP0542774A1 - Printing member - Google Patents

Printing member

Info

Publication number
EP0542774A1
EP0542774A1 EP19910913356 EP91913356A EP0542774A1 EP 0542774 A1 EP0542774 A1 EP 0542774A1 EP 19910913356 EP19910913356 EP 19910913356 EP 91913356 A EP91913356 A EP 91913356A EP 0542774 A1 EP0542774 A1 EP 0542774A1
Authority
EP
European Patent Office
Prior art keywords
photopolymer
light
sensitive layer
printing member
secondary light
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19910913356
Other languages
German (de)
French (fr)
Inventor
Geoffrey David Clinton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zed Instruments Ltd
Original Assignee
Zed Instruments Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zed Instruments Ltd filed Critical Zed Instruments Ltd
Publication of EP0542774A1 publication Critical patent/EP0542774A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20Exposure; Apparatus therefor
    • G03F7/24Curved surfaces
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/09Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
    • G03F7/095Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having more than one photosensitive layer
    • G03F7/0952Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having more than one photosensitive layer comprising silver halide or silver salt based image forming systems, e.g. for camera speed exposure

Definitions

  • the present invention relates to the preparation of printing cylinders or other printing members, and in particular to printing cylinders incorporating a photopolymer surface.
  • Printing cylinders are commonly prepared by controlled exposure of a photosensitive medium on the cylinder surface.
  • a photosensitive medium For example, in screen printing a screen typically made of a perforated cylindrical nickel sleeve is coated with a photosensitive lacquer covering the entire screen and filling all the perforations. Portions of the photo-sensitive lacquer are then exposed to ultraviolet light through a photographic negative and are subsequently developed. In the development process, where the lacquer has not been exposed to the ultraviolet light it is removed to open the perforations in the screen, producing the required pattern of ink transmitting areas.
  • EP-A-197601 discloses a method of preparing a printing roller in which the photopolymer medium is covered by a light-sensitive intermediate layer. In a first stage, a patterning film is applied to the roller and the intermediate layer is exposed through that film. The intermediate layer is then developed before a subsequent stage in which the photopolymer layer is exposed through the intermediate layer.
  • the intermediate layer in such a system is seamless, and is fixed in register with respect to the photopolymer medium, it potentially offers considerable advantages in preparing cylinders for such uses as the printing of continuous patterns.
  • many of these potential advantages have been obviated by problems associated with the patterning film used to expose the intermediate layer in the first stage.
  • problems associated with the patterning film used to expose the intermediate layer in the first stage As described in the above cited application, if the patterning film is positioned on the cylinder with abutting edges then light tends to be scattered or reflected at the edges, resulting in incomplete light transmission and a resulting discontinuity in the exposed pattern.
  • the film is positioned with its edges overlapping that also changes the effective' density of the negative, and hence the amount of light transmitted in the overlapping region and may also cause physical distortion of the light- sensitive media.
  • a process for preparing a printing member incorporating a photopolymer as the light-sensitive medium comprises providing the photopolymer with a secondary light-sensitive layer, exposing the secondary light-sensitive layer with a digitally modulated light source which is scanned with respect to the member, developing the secondary light- sensitive layer, and subsequently exposing the photopolymer through the developed secondary light layer.
  • directly digitally modulated light sources have previously been used for such purposes as preparing perforated cylindrical nickel printing sleeves, it has not previously been thought possible to use such techniques with photopolymers of the type used for flexographic processes. In general, such media cannot be exposed at the wavelengths and intensities normally available . from directly modulated sources such as lasers.
  • directly modulated sources such as lasers.
  • the present inventors have found that by combining the use of a modulated light source with the provision of an intermediate light-sensitive layer digitally controlled exposure of the photopolymer is possible in a manner which overcomes the disadvantages of the prior art systems requiring the use of a patterning film.
  • exposing the intermediate layer while modulating a scanned light source with appropriate digital data it is possible to generate a perfectly continuous pattern with no discontinuities.
  • the method is therefore particularly advantageous for the production of continuous image rollers for packing, decorative, wall covering and similar products.
  • a pattern formed from multiple repeat units may be formed from a single digital original, removing the need for step and repeat photographic methods.
  • the cylinder can be produced more quickly using a single integrated process with fewer handling steps.
  • the secondary light-sensitive layer is a photographic emulsion or a photo-resist. More preferably the layer is a lithographic photographic emulsion for bright light or yellow light working.
  • Figure 1 is a cross section through a printing cylinder
  • Figure 2 is a diagram showing the cylinder installed in an exposing unit
  • Figures 3A to 3G are diagrams illustrating schematically the different steps of one example of the process.
  • the printing cylinder comprises a metal cylinder 1 coated uniformly on its surface with a photopolymer 2.
  • the photopolymer may, for example, be that manufactured by Dupont as CYREL type HLS.
  • the photopolymer may be applied in a conventional fashion using apparatus such as that commercially available from Stork Limited and sold under the trade name SEAMEX SLEEVES.
  • the cylinder is subsequently coated with a secondary photosensitive layer 3 which, in this first example, is a photographic emulsion of the rapid access type designed for lithography arid which is suitable for either bright light work or yellow light working.
  • the exposing unit is generally similar to the rotary colour output scanners widely used in the industry and commercially available from manufacturers such as Hell or Dai Nippon.
  • the exposing head incorporates a low power light source 5.
  • the output of the light source 5 is modulated via a digitally controlled electro-optic or acousto-optic modulator to produce the desired image on the photographic emulsion.
  • multiple exposure heads may be used.
  • the cylinder is removed and processed in a modified photopolymer exposure unit.
  • the modifications by comparison with a conventional photopolymer processor, consist of the addition of an in-line photographic processor which develops, fixes, hardens and dries the image in the photosensitive layer 3 on the surface of the photopolymer.
  • Subsequent stages in the exposure and processing of the cylinder are then carried out conventionally, using an ultraviolet light source to expose the photopolymer through " the developed secondary photosensitive layer 3.
  • the unexposed areas of the photopolymer are then washed out and the cylinder dried.
  • the emulsion which as in the embodiment discussed above, is a lithographic photographic emulsion for bright light or yellow light working, is not applied directly to the photopolymer but instead is applied to a transparent substrate which, in this example, is a tube 6 of clear plastics material such as polyvinylidene chloride.
  • the tube of plastic is pre-stressed in manufacture to enable it to shrink on the application of heat.
  • the cylinder is subsequently removed from the bath and the emulsion coated on the substrate dried in a forced air flow.
  • the cylinder is then mounted in an exposing unit 4' and exposed in the same manner as described above in relation to Figure 2.
  • the exposed cylinder is then placed in a secondary development station 8 to develop and fix the photographic emulsion as shown in Figure 3E.
  • the photopolymer 2 is exposed through the developed photographic emulsion.
  • the plastics substrate 6 bearing the emulsion is then cut away from the cylinder and the cylinder with the exposed photopolymer placed in a photopolymer development and fixing station 10 for processing in a conventional fashion.
  • the plastics tube should be shrink-fitted" to the cylinder prior to the application of the photographic emulsion
  • the emulsion may be applied to the plastics tube before it is fitted to the cylinder.
  • the secondary photosensitive layer is a photo-resist of the type commonly used with gravure cylinders.
  • the photo-resist is coated on the photopolymer 2 using techniques such as ring coating, or bar coating, or any of a number of other techniques commonly used in applying photo-resist to gravure cylinders.
  • the coated cylinder is then exposed in a similar process to that described above, but using a higher power light source such as an Ar ion laser.
  • the exposing machine may incorporate a digitally modulated - laser exposure head. A suitable head would be similar to that produced by "Think Laboratories" for their Laser Stream product.
  • the secondary photosensitive layer is then developed, and the photopolymer exposed, as described above.
  • the chemistry of the development process is modified as appropriate to the particular photo-resist used.
  • the present invention may be used, for example, for flexographic printing processes. Such processes commonly use photopolymers produced by BASF, DUPONT, and others. However hitherto it has not been possible to produce images in continuous form.
  • the invention may also be used for gravure processes which at present use photopolymer in sheet form.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)
  • Manufacture Or Reproduction Of Printing Formes (AREA)
  • Printing Plates And Materials Therefor (AREA)

Abstract

Un élément d'imprimerie tel qu'un cylindre métallique (1) comporte un photopolymère (2) comme moyen photosensible. Selon un procédé de préparation de l'élément d'imprimerie, on recouvre le photopolymère (2) d'une couche photosensible (3) secondaire. Dans un exemple, il s'agit d'une émulsion photographique d'un type utilisé fréquemment en lithographie. La couche photosensible secondaire est exposée à une source lumineuse à modulation numérique. On explore la source lumineuse par rapport à l'élément d'imprimerie. Ensuite, on développe la couche photosensible secondaire et on expose le photopolymère à travers la couche photosensible secondaire développée.A printing element such as a metal cylinder (1) comprises a photopolymer (2) as a photosensitive means. According to a process for preparing the printing element, the photopolymer (2) is covered with a secondary photosensitive layer (3). In one example, it is a photographic emulsion of a type frequently used in lithography. The secondary photosensitive layer is exposed to a digitally modulated light source. The light source is explored in relation to the printing element. Next, the secondary photosensitive layer is developed and the photopolymer is exposed through the developed secondary photosensitive layer.

Description

PRINTING MEMBER
BACKGROUND TO THE INVENTION The present invention relates to the preparation of printing cylinders or other printing members, and in particular to printing cylinders incorporating a photopolymer surface.
Printing cylinders are commonly prepared by controlled exposure of a photosensitive medium on the cylinder surface. For example, in screen printing a screen typically made of a perforated cylindrical nickel sleeve is coated with a photosensitive lacquer covering the entire screen and filling all the perforations. Portions of the photo-sensitive lacquer are then exposed to ultraviolet light through a photographic negative and are subsequently developed. In the development process, where the lacquer has not been exposed to the ultraviolet light it is removed to open the perforations in the screen, producing the required pattern of ink transmitting areas.
It is known, particularly where the cylinder is to be used for flexographic or gravure processes, to use a photopolymer as the photosensitive medium. EP-A-197601 discloses a method of preparing a printing roller in which the photopolymer medium is covered by a light-sensitive intermediate layer. In a first stage, a patterning film is applied to the roller and the intermediate layer is exposed through that film. The intermediate layer is then developed before a subsequent stage in which the photopolymer layer is exposed through the intermediate layer.
Since the intermediate layer in such a system is seamless, and is fixed in register with respect to the photopolymer medium, it potentially offers considerable advantages in preparing cylinders for such uses as the printing of continuous patterns. However, in practice, many of these potential advantages have been obviated by problems associated with the patterning film used to expose the intermediate layer in the first stage. As described in the above cited application, if the patterning film is positioned on the cylinder with abutting edges then light tends to be scattered or reflected at the edges, resulting in incomplete light transmission and a resulting discontinuity in the exposed pattern. On the other hand, if the film is positioned with its edges overlapping that also changes the effective' density of the negative, and hence the amount of light transmitted in the overlapping region and may also cause physical distortion of the light- sensitive media.
SUMMARY OF THE INVENTION According the present invention, a process for preparing a printing member incorporating a photopolymer as the light-sensitive medium, comprises providing the photopolymer with a secondary light-sensitive layer, exposing the secondary light-sensitive layer with a digitally modulated light source which is scanned with respect to the member, developing the secondary light- sensitive layer, and subsequently exposing the photopolymer through the developed secondary light layer.
Although directly digitally modulated light sources have previously been used for such purposes as preparing perforated cylindrical nickel printing sleeves, it has not previously been thought possible to use such techniques with photopolymers of the type used for flexographic processes. In general, such media cannot be exposed at the wavelengths and intensities normally available . from directly modulated sources such as lasers. However the present inventors have found that by combining the use of a modulated light source with the provision of an intermediate light-sensitive layer digitally controlled exposure of the photopolymer is possible in a manner which overcomes the disadvantages of the prior art systems requiring the use of a patterning film. Thus by exposing the intermediate layer while modulating a scanned light source with appropriate digital data it is possible to generate a perfectly continuous pattern with no discontinuities. The method is therefore particularly advantageous for the production of continuous image rollers for packing, decorative, wall covering and similar products. For such purposes, a pattern formed from multiple repeat units may be formed from a single digital original, removing the need for step and repeat photographic methods. Moreover, by contrast with the prior art processes requiring the use of a separate patterning film, the cylinder can be produced more quickly using a single integrated process with fewer handling steps.
Preferably the secondary light-sensitive layer is a photographic emulsion or a photo-resist. More preferably the layer is a lithographic photographic emulsion for bright light or yellow light working.
A BRIEF DESCRIPTION OF THE DRAWINGS A process in accordance with the present invention will now be described in detail with reference to the accompanying drawings in which:
Figure 1 is a cross section through a printing cylinder; Figure 2 is a diagram showing the cylinder installed in an exposing unit; and
Figures 3A to 3G are diagrams illustrating schematically the different steps of one example of the process.
DETAILED DESCRIPTION OF EXAMPLES
The printing cylinder comprises a metal cylinder 1 coated uniformly on its surface with a photopolymer 2. The photopolymer may, for example, be that manufactured by Dupont as CYREL type HLS. The photopolymer may be applied in a conventional fashion using apparatus such as that commercially available from Stork Limited and sold under the trade name SEAMEX SLEEVES. The cylinder is subsequently coated with a secondary photosensitive layer 3 which, in this first example, is a photographic emulsion of the rapid access type designed for lithography arid which is suitable for either bright light work or yellow light working. Once the emulsion coated on the photopolymer has dried the cylinder is mounted in an exposing machine 4. In construction the exposing unit is generally similar to the rotary colour output scanners widely used in the industry and commercially available from manufacturers such as Hell or Dai Nippon. The exposing head incorporates a low power light source 5. The output of the light source 5 is modulated via a digitally controlled electro-optic or acousto-optic modulator to produce the desired image on the photographic emulsion. To reduce the time taken for exposure, multiple exposure heads may be used.
Once the photographic emulsion has been exposed, the cylinder is removed and processed in a modified photopolymer exposure unit. The modifications, by comparison with a conventional photopolymer processor, consist of the addition of an in-line photographic processor which develops, fixes, hardens and dries the image in the photosensitive layer 3 on the surface of the photopolymer. Subsequent stages in the exposure and processing of the cylinder are then carried out conventionally, using an ultraviolet light source to expose the photopolymer through "the developed secondary photosensitive layer 3. The unexposed areas of the photopolymer are then washed out and the cylinder dried. In an alternative embodiment using a photographic emulsion, the emulsion, which as in the embodiment discussed above, is a lithographic photographic emulsion for bright light or yellow light working, is not applied directly to the photopolymer but instead is applied to a transparent substrate which, in this example, is a tube 6 of clear plastics material such as polyvinylidene chloride. The tube of plastic is pre-stressed in manufacture to enable it to shrink on the application of heat.
- The process of this embodiment is illustrated schematically in Figures 3A to 3G. After the clear plastics tube 6 has been fitted over the photopolymer coated cylinder 1 it is heated using hot air from a source 9 to shrink the tube. As seen in Figure 3B, more shrinking occurs away from the cylinder. In this and the other figures the separation of the substrate from the cylinder is exaggerated for the sake of clarity: in reality after shrinking the tube makes a close fit with the surface of the cylinder. After the substrate has been fitted to the cylinder it is coated with the photographic emulsion 7 using a dip bath as shown in Figure 3C. Other methods may be used to apply the emulsion, including spraying or spreading. The cylinder is subsequently removed from the bath and the emulsion coated on the substrate dried in a forced air flow. The cylinder is then mounted in an exposing unit 4' and exposed in the same manner as described above in relation to Figure 2. The exposed cylinder is then placed in a secondary development station 8 to develop and fix the photographic emulsion as shown in Figure 3E. In the next stage, the photopolymer 2 is exposed through the developed photographic emulsion. The plastics substrate 6 bearing the emulsion is then cut away from the cylinder and the cylinder with the exposed photopolymer placed in a photopolymer development and fixing station 10 for processing in a conventional fashion.
Although it is preferred that the plastics tube should be shrink-fitted" to the cylinder prior to the application of the photographic emulsion, alternatively the emulsion may be applied to the plastics tube before it is fitted to the cylinder.
In an alternative embodiment, the secondary photosensitive layer is a photo-resist of the type commonly used with gravure cylinders. The photo-resist is coated on the photopolymer 2 using techniques such as ring coating, or bar coating, or any of a number of other techniques commonly used in applying photo-resist to gravure cylinders. The coated cylinder is then exposed in a similar process to that described above, but using a higher power light source such as an Ar ion laser. The exposing machine may incorporate a digitally modulated - laser exposure head. A suitable head would be similar to that produced by "Think Laboratories" for their Laser Stream product. After exposure, the secondary photosensitive layer is then developed, and the photopolymer exposed, as described above. The chemistry of the development process is modified as appropriate to the particular photo-resist used. The present invention may be used, for example, for flexographic printing processes. Such processes commonly use photopolymers produced by BASF, DUPONT, and others. However hitherto it has not been possible to produce images in continuous form. The invention may also be used for gravure processes which at present use photopolymer in sheet form.
Although described above in relation to sleeves and cylinders the present invention is also applicable to flat plates for flexographic and gravure processes of the type discussed above.

Claims

1. A process for preparing a printing member (1) incorporating a photopolymer (2) as the light-sensitive medium, comprising providing the photopolymer with a secondary light-sensitive layer (3) , exposing the secondary light-sensitive layer (3) with a digitally modulated light source which is scanned with respect to the member, developing the secondary ϊight-sensitive layer (3) and subsequently exposing the photopolymer (2) through the secondary light-sensitive layer.
2. A process according to claim 1, in which the printing member (1) is a cylindrical printing member or sleeve.
3. A process according to claim 1 or 2, in which the secondary light-sensitive layer (2) is a photographic emulsion or photographic resist.
4. A process according to claim 3, in which the secondary light-sensitive layer (2) is a lithographic photographic emulsion for bright light or yellow light working.
5. A process according to any one of the preceding claims, in which the secondary light-sensitive layer is provided on a transparent substrate (6) fitted to the printing member (1) over the photopolymer.
6. A process according to claim 5 when directly or indirectly dependent on claim 2, in which the transparent substrate (6) is a pre-stressed plastics tube which is placed over the sleeve or cylinder and heated, thereby shrinking the tube to fit the cylinder or sleeve (1) .
7. A process according to claim 5 or 6, in which the secondary light-sensitive layer (3) is coated on the transparent substrate (6) after the substrate is fitted to the printing member.
8. A process according to any one of claims 5 to 7, in which the substrate (6) is removed from the printing member (1) after the exposure of the photopolymer (2) , the photopolymer subsequently being developed.
9. A system for preparing printing members comprising a printing member (1) carrying a light-sensitive photopolymer (2), and a secondary light-sensitive layer (3) adjacent the photopolymer, and means (4, 5) for exposing the secondary light- sensitive layer comprising a light source, means to modulate the light source in response to digital printing data and means to scan the light source with respect to the printing member.
10. A system according to claim 9, in which the secondary light-sensitive layer (3) is formed on a transparent substrate (6) which is fitted to the printing member (1) over the photopolymer.
11. A system according to claim 10, in which the printing member (1) is a cylinder or sleeve and the transparent substrate (6) is a plastics tube shrink-fitted to the printing member.
EP19910913356 1990-07-27 1991-07-23 Printing member Withdrawn EP0542774A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9016488 1990-07-27
GB909016488A GB9016488D0 (en) 1990-07-27 1990-07-27 Printing cylinder

Publications (1)

Publication Number Publication Date
EP0542774A1 true EP0542774A1 (en) 1993-05-26

Family

ID=10679741

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19910913356 Withdrawn EP0542774A1 (en) 1990-07-27 1991-07-23 Printing member

Country Status (4)

Country Link
EP (1) EP0542774A1 (en)
JP (1) JPH05509177A (en)
GB (1) GB9016488D0 (en)
WO (1) WO1992002859A1 (en)

Families Citing this family (11)

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Publication number Priority date Publication date Assignee Title
NL9402239A (en) * 1994-12-29 1996-08-01 Raytech Sprl Method for applying a pattern to a surface of a non- planar, in particular cylindrical substrate
US5654125A (en) * 1995-05-01 1997-08-05 E. I. Du Pont De Nemours And Company Laser apparatus and process of use
DE19536805A1 (en) * 1995-10-02 1997-04-03 Basf Lacke & Farben Multi-layer recording element suitable for the production of flexographic printing plates by digital information transmission
EP0785474A1 (en) * 1996-01-16 1997-07-23 Schablonentechnik Kufstein Aktiengesellschaft Process and apparatus for the fabrication of flexographic printing plates
US6312872B1 (en) * 1997-10-24 2001-11-06 Macdermid Graphic Arts Composite relief image printing plates
US5846691A (en) 1996-07-08 1998-12-08 Polyfibron Technologies, Inc. Composite relief image printing plates and methods for preparing same
FR2763888B1 (en) * 1997-05-28 1999-07-16 Rollin Sa IMPROVED SLEEVE FOR A CYLINDER OF A PRINTING MACHINE OR THE LIKE AND METHOD FOR FITTING THEREOF
NL1013626C2 (en) * 1999-11-19 2001-05-22 Av Flexologic Bv Embossing of gravure printing plate, comprises using a photocopier machine to apply an opaque layer in the regions of the photocurable polymer plate needing embossing
JP2002023348A (en) * 2000-07-11 2002-01-23 Asahi Kasei Corp Method for producing sleeve type photosensitive resin printing plate
US20050170287A1 (en) * 2004-01-30 2005-08-04 Kanga Rustom S. Photosensitive printing sleeves and method of forming the same
WO2015120195A1 (en) * 2014-02-05 2015-08-13 Hps Technologies Inc. Perforated flexographic printing plates and methods for making and using them

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DE2726329A1 (en) * 1976-06-11 1977-12-22 Zed Instr Ltd COPY PROCEDURE
GB1529590A (en) * 1977-10-07 1978-10-25 Leathley Publications Ltd Manufacture of printing rollers
JPS56117241A (en) * 1980-02-22 1981-09-14 Fuji Photo Film Co Ltd Photosensitive lithographic printing plate
US4705729A (en) * 1984-11-19 1987-11-10 Hewlett-Packard Company Method for photochemically enhancing resolution in photolithography processes
NL8500992A (en) * 1985-04-03 1986-11-03 Stork Screens Bv PROCESS FOR FORMING A PATTERNED PHOTOPOLYMER COATING ON A PRINTING ROLLER AND PRINTING ROLLER WITH PATTERNED PHOTOPOLYMER COATING.
DE3621376A1 (en) * 1986-06-26 1988-01-07 Hoechst Ag RADIATION-SENSITIVE RECORDING MATERIAL
NL8802928A (en) * 1988-11-28 1990-06-18 Stork Screens Bv A METHOD AND APPARATUS FOR FORMING A RESISTANT PATTERN ON A CYLINDRICAL ART AND A METAL CYLINDER CREATED BY THE USE OF SUCH A RESISTANCE PATTERN.

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Also Published As

Publication number Publication date
GB9016488D0 (en) 1990-09-12
WO1992002859A1 (en) 1992-02-20
JPH05509177A (en) 1993-12-16

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