EP0524242B1 - Membrane separation process for dehydrating a gas or vapour or liquid mixture by pervaporation or vapour permeation - Google Patents
Membrane separation process for dehydrating a gas or vapour or liquid mixture by pervaporation or vapour permeation Download PDFInfo
- Publication number
- EP0524242B1 EP0524242B1 EP91907881A EP91907881A EP0524242B1 EP 0524242 B1 EP0524242 B1 EP 0524242B1 EP 91907881 A EP91907881 A EP 91907881A EP 91907881 A EP91907881 A EP 91907881A EP 0524242 B1 EP0524242 B1 EP 0524242B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- membrane
- brine
- separation process
- membrane separation
- vapour
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
- B01D61/362—Pervaporation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/26—Drying gases or vapours
- B01D53/268—Drying gases or vapours by diffusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
Definitions
- the invention relates to a membrane separation process for dehydrating a gas or vapour or liquid mixture by pervaporation or vapour permeation comprising: passing the mixture along the retentate side of a membrane and generating a driving force in order to transport water through the membrane to the permeate side thereof.
- the separation is usually based on dissolution and diffusion behaviour.
- the gas to be dried should be fed to the retentate side with a high pressure and/or partial vacuum should be applied to the permeate side in order to obtain sufficient driving force for the transport of water through the membrane.
- a disadvantage of this procedure is the usually relatively very high volume of the permeate compartment which is necessary to counteract pressure loss and, consequently, loss of driving force.
- Another important disadvantage is the frequently high loss of gas to be dehydrated, which occurs through permeation together with the water vapour. If gases are dehydrated under increased pressure, the gas separation membranes have to have a high mechanical strength in order to be resistant to this high pressure.
- vapour permeation and pervaporation processes use is made of selective membranes which are frequently composed of a composite of a thick sieve-type base and a very thin compact membrane top layer.
- the driving force is generated by applying a pressure difference across the membrane, which is usually achieved by maintaining a vacuum (for example of less than 10 kPa) at the permeate side.
- the permeated water can be removed by inserting a condenser upstream of the vacuum pump.
- the disadvantage of this method is that, as a consequence of the poor mass transfer in the vacuum and the necessity of counteracting pressure drop, the permeate volume has to be very large.
- a membrane module usually only 1 to 10m2 of membrane surface is installed per m3 of module volume.
- COP coefficient of performance
- the object of the invention is to avoid said disadvantages at least to a significant extent.
- the membrane separation process for dehydrating a gas or vapour or liquid mixture as mentioned in the preamble is therefore characterised in that the driving force is generated in that a highly concentrated solution of one or more hygroscopic salts (brine) is situated at the permeate side of the membrane, and that the hygroscopic capacity of said solution, expressed as a percentage of water vapour pressure reduction with respect to pure water, has a value of over 50%
- the fluid at the retentate side is one selected from benzene, isopropanol, sulphuric acid and ethylene glycol and must be relatively free of the component to be separated, which in case of dehydration is water. Therefore the process of the present invention is excluded.
- GB-A-0495734 discloses a process of dehumidification of gases which comprises contacting the moist gas with a hygroscopic brine.
- a disadvantage is that the gas to be dehumidified may dissolve in the brine, which could lead to considerable losses.
- the salts used in the brines are characterised by combinations of small cations and large anions or of large cations and small anions or of mixtures thereof, which combinations break up water structure.
- the anions and cations may be either inorganic or organic in nature. Owing to the stability at high temperatures, however, combinations of inorganic ions will be chosen in most cases.
- the brine is removed continuously or discontinuously from the permeate side of the membrane, the water taken up by the brine is removed from the brine and the worked-up brine is fed back to the permeate side of the membrane.
- a brine is on the inside of the hollow membranes.
- the invention could be applied to a mixture of azeotropic isopropyl alcohol and water which is dehydrated with the aid of a vapour permeation process, which mixture is passed on the outside of PPO hollow fibre membranes with a brine on the inside of the hollow membranes.
- the brine is a concentrated solution of LiBr or ZnBr2 or CaBr2 or CsF.
- the membrane is preferably a flat polyvinyl alcohol composite membrane between the permeate side and the retentate side.
- the brines should have an appreciable hygroscopic capacity in order to be able to generate sufficient driving force.
- the required hygroscopic capacity will depend on the water activity of the gas, vapour or liquid mixture to be dehydrated. If said water activity is low, the hygroscopic capacity of the brine whould be high.
- the hygroscopic capacity may be expressed, for example, as the percentage by which a brine lowers the vapour pressure of water at a particular temperature.
- the table below gives the hygroscopic capacity of a number of salt solutions expressed as a percentage of water vapour pressure reduction in saturated solution a 25°C.
- Brines which are suitable for use in the present invention will preferably have a hygroscopic capacity higher than 80%. This means that brines based on, for example, sodium chloride or potassium dichromate will not exhibit the desired effect.
- brines having adequate hygroscopic capacity are, inter alia, LiBr, CsF, KC2H3O2, MgCl2 and mixtures of, for example, LiBr/ZnBr2/CaBr2.
- vapour permeation and pervaporation membranes achieves an appreciable improvement with respect to equipment design (high membrane surface area per m3 of module volume) and procedure.
- the brines reduce the water activities at the permeate side (vapour tensions of less than 1 kPa at a temperature of over 80°C achievable) in a manner such that a large driving force can be established across the membrane.
- the invention can be used in the following membrane designs: tubular membranes (diameters of a few millimetres to a few centimetres), plate-type membranes (plate and frame), spirally wound membranes and hollow membrane fibres (hollow fat fibres: internal diameter greater than 500 ⁇ m and hollow fine fibres: internal diameter between 50 and 200 ⁇ m).
- the permeate volume: membrane surface ratio is usually more than 0.1 m3/m2 in known membrane dehydration processes, a value of less than 0.005 m3/m2, and in most cases of less than 0.0005 m3/m2, can be achieved by application of the invention. The compactness of the equipment can therefore be improved very considerably.
- the brine can be brought to the same liquid pressure as the pressure of the gas or the vapour or liquid to be dehydrated at the retentate side of the membrane.
- the pressure resistance/mechanical strength of the membranes are imposed on the pressure resistance/mechanical strength of the membranes.
- brine offers the possibility of considerably reducing the loss of gas through permeation; for this purpose, use is made of the often limited solubility of the gases to be dehydrated in, in particular, highly concentrated brines.
- the evaporator which is used with the aid of a distillation process for evaporating water out of the brine, may be connected to the apparatus. Evaporating water out of the brine demands less energy than the usual condensation in known membrane separation processes. The equipment is much simpler (no refrigeration technique, no vacuum pump which is susceptible to malfunction).
- the highly concentrated solution of one or more hygroscopic salts being situated inside the hollow fibres (permeate side) (diameter of, for example, 300 ⁇ m).
- a moistened nitrogen having a relative humidity of 75% is passed along an H2O-selective gas separation membrane consisting of a hollow fibre of polyphenylene oxide (PPO). Situated at the permeate side (inside the hollow fibre) is a saturated NaCl solution. It was not possible to detect any marked water permeation (dehydration).
- PPO polyphenylene oxide
- a moistened air having a relative humidity of 75% is dehydrated at a temperature of 25°C with the aid of a gas separation process.
- an H2O-selective hollow gas separation membrane consisting of polyphenylene oxide (PPO) is used.
- Saturated CsF brine is situated inside the hollow fibres. At a gas speed of 1 m/sec along the outside of the fibre, virtually all the water is removed after a fibre length of only 25 cm.
- An azeotropic mixture of isopropyl alcohol and water is dehydrated at a temperature of 90°C with the aid of a vapour permeation system, use being made of PPO hollow fibre membranes. Situated on the inside of the membranes is CsF brine. The permeate flux is approximately 0.3 kg/m2.h.
- An azeotropic mixture of isopropyl alcohol and water is dehydrated at a temperature of 90°C with the aid of a vapour permeation system.
- the equipment comprises PPO hollow fibre membranes, an LiBr/ZnBr2/CaBr2 brine being situated on the inside of the membranes.
- the vaporisation of the permeated water takes place at approximately 180°C in an evaporating element.
- the process is carried out continuously and stably for approximately 100 hours.
- the permeate flux is approximately 0.4 kg/m2.h.
- An azeotropic mixture of butanol and water is dehydrated at a temperature of 60°C with the aid of a pervaporation system.
- the equipment comprises a flat polyvinyl alcohol composite membrane. Situated at the permeate side is an LiBr/ZnBr2/CaBr2 brine. Permeation of water takes place with a flux of approximately 0.5 kg/m2.h. The permeation of alcohol cannot be detected. It was not possible to detect any leakage of brine.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
- The invention relates to a membrane separation process for dehydrating a gas or vapour or liquid mixture by pervaporation or vapour permeation comprising: passing the mixture along the retentate side of a membrane and generating a driving force in order to transport water through the membrane to the permeate side thereof.
- Such a membrane separation process is disclosed in GB-B-1440963.
- In drying gases by water-selective vapour permeation membranes, the separation is usually based on dissolution and diffusion behaviour. The gas to be dried should be fed to the retentate side with a high pressure and/or partial vacuum should be applied to the permeate side in order to obtain sufficient driving force for the transport of water through the membrane. A disadvantage of this procedure is the usually relatively very high volume of the permeate compartment which is necessary to counteract pressure loss and, consequently, loss of driving force. Another important disadvantage is the frequently high loss of gas to be dehydrated, which occurs through permeation together with the water vapour. If gases are dehydrated under increased pressure, the gas separation membranes have to have a high mechanical strength in order to be resistant to this high pressure.
- In vapour permeation and pervaporation processes, use is made of selective membranes which are frequently composed of a composite of a thick sieve-type base and a very thin compact membrane top layer. The driving force is generated by applying a pressure difference across the membrane, which is usually achieved by maintaining a vacuum (for example of less than 10 kPa) at the permeate side. The permeated water can be removed by inserting a condenser upstream of the vacuum pump. The disadvantage of this method is that, as a consequence of the poor mass transfer in the vacuum and the necessity of counteracting pressure drop, the permeate volume has to be very large. In a membrane module, usually only 1 to 10m² of membrane surface is installed per m³ of module volume. The proportion taken up by the equipment in the costs of a vapour permeation and pervaporation process is consequently relatively high (compare the compactness of a membrane module in reverse osmosis and gas separation processes: 100 to 500m² of membrane surface per m³ of module volume). This disadvantage of an unduly large membrane module exists even if a flushing gas such as nitrogen is passed along the permeate side of the membrane, which nitrogen is fed to a condenser in order to remove the water therefrom.
- Another important disadvantage of the abovementioned processes is the relatively unfavourable coefficient of performance (COP), which is a measure of the energy efficiency of the water removal by means of a condenser. This is primarily due to the low energy efficiency in the cooling. Finally, the acquisition and maintenance costs of the equipment are high and the vacuum equipment is in general susceptible to malfunction.
- The object of the invention is to avoid said disadvantages at least to a significant extent.
- According to the invention the membrane separation process for dehydrating a gas or vapour or liquid mixture as mentioned in the preamble is therefore characterised in that the driving force is generated in that a highly concentrated solution of one or more hygroscopic salts (brine) is situated at the permeate side of the membrane, and that the hygroscopic capacity of said solution, expressed as a percentage of water vapour pressure reduction with respect to pure water, has a value of over 50%
- According to the claims of GB-B-1440963 the fluid at the retentate side is one selected from benzene, isopropanol, sulphuric acid and ethylene glycol and must be relatively free of the component to be separated, which in case of dehydration is water. Therefore the process of the present invention is excluded.
- Further GB-A-0495734 discloses a process of dehumidification of gases which comprises contacting the moist gas with a hygroscopic brine. A disadvantage is that the gas to be dehumidified may dissolve in the brine, which could lead to considerable losses.
- The salts used in the brines are characterised by combinations of small cations and large anions or of large cations and small anions or of mixtures thereof, which combinations break up water structure. The anions and cations may be either inorganic or organic in nature. Owing to the stability at high temperatures, however, combinations of inorganic ions will be chosen in most cases.
- The brine is removed continuously or discontinuously from the permeate side of the membrane, the water taken up by the brine is removed from the brine and the worked-up brine is fed back to the permeate side of the membrane.
- Better results can be obtained if the mixture to be dehydrated is under increased pressure often and the brine is at essentially the same pressure.
- If the process is continuous the permeated water is evaporated.
- Preferably use is made of hollow fibre membranes and the highly concentrated solution of one or more hygroscopic salts is situated inside or outside the hollow fibres membranes.
- If a moisture containing gas is passed in the outside of hollow H₂O-selective PPO gas separation fibre membranes, a brine is on the inside of the hollow membranes.
- The invention could be applied to a mixture of azeotropic isopropyl alcohol and water which is dehydrated with the aid of a vapour permeation process, which mixture is passed on the outside of PPO hollow fibre membranes with a brine on the inside of the hollow membranes.
- Preferably the brine is a concentrated solution of LiBr or ZnBr₂ or CaBr₂ or CsF.
- If a liquid mixture of azeotropic butanol and water is dehydrated with the aid of a pervaporation process, the membrane is preferably a flat polyvinyl alcohol composite membrane between the permeate side and the retentate side.
- The brines should have an appreciable hygroscopic capacity in order to be able to generate sufficient driving force. The required hygroscopic capacity will depend on the water activity of the gas, vapour or liquid mixture to be dehydrated. If said water activity is low, the hygroscopic capacity of the brine whould be high. The hygroscopic capacity may be expressed, for example, as the percentage by which a brine lowers the vapour pressure of water at a particular temperature. The table below gives the hygroscopic capacity of a number of salt solutions expressed as a percentage of water vapour pressure reduction in saturated solution a 25°C.
Brine Hygroscopic capacity (%) K₂Cr₂O₇ 2 BaCl₂.2H₂O 10 KCl 16 KBr 19 NaCl 25 NH₄NO₃ 38 MgCl₂.6H₂O 67 Kc₂H₃O₂.1.5 H₂O 78 LiCl.H₂O 89 NaOH.H₂O 93 LiBr.2H₂O 92 CsF > 95 LiBr/ZnBr₂/CaBr₂ 98 - Brines which are suitable for use in the present invention will preferably have a hygroscopic capacity higher than 80%. This means that brines based on, for example, sodium chloride or potassium dichromate will not exhibit the desired effect.
- Examples of brines having adequate hygroscopic capacity to be used in the membrane processes according to the invention are, inter alia, LiBr, CsF, KC₂H₃O₂, MgCl₂ and mixtures of, for example, LiBr/ZnBr₂/CaBr₂.
- Making use of a highly concentrated solution of hygroscopic salts at the permeate side of gas separation, vapour permeation and pervaporation membranes achieves an appreciable improvement with respect to equipment design (high membrane surface area per m³ of module volume) and procedure. The brines reduce the water activities at the permeate side (vapour tensions of less than 1 kPa at a temperature of over 80°C achievable) in a manner such that a large driving force can be established across the membrane.
- It is of importance that, during the dehydration of a gas and the dehydration of a vapour, the brine cannot come into contact with the gas or the vapour, respectively. In the event of direct contact, brine in the gas could be entrained by aerosol formation in the dehydrated gas or vapour, and this is extremely disadvantageous. This is an additional advantage of using a membrane which otherwise primarily has the aim of achieving the desired selectivity (sharpness of separation). In addition, the flexibility of the process increases sharply as a result of this: the flows of gas or vapour or of absorption liquid respectively may be varied independently over a wide range.
- The invention can be used in the following membrane designs: tubular membranes (diameters of a few millimetres to a few centimetres), plate-type membranes (plate and frame), spirally wound membranes and hollow membrane fibres (hollow fat fibres: internal diameter greater than 500 µm and hollow fine fibres: internal diameter between 50 and 200 µm).
- Although the permeate volume: membrane surface ratio is usually more than 0.1 m³/m² in known membrane dehydration processes, a value of less than 0.005 m³/m², and in most cases of less than 0.0005 m³/m², can be achieved by application of the invention. The compactness of the equipment can therefore be improved very considerably.
- As a result of using the brine, a negligible pressure loss occurs at the permeate side, even if the permeate compartment is formed by the lumen of "hollow fine fibres". Apart from a high compactness, this guarantees maintenance of driving force and, consequently, of the permeate flux. This also implies that the permeate pressure (the driving force) can be very easily adjusted by regulating the water content of the brine. As a consequence of this, one particular design of an apparatus can be used in very many different applications. In order to use apparatuses according to the state of the art for various applications, the permeate circuit would have to be altered by intervention in order to guarantee optimum process conditions.
- In principle, the brine can be brought to the same liquid pressure as the pressure of the gas or the vapour or liquid to be dehydrated at the retentate side of the membrane. As a result of this lower requirements are imposed on the pressure resistance/mechanical strength of the membranes.
- Especially in regard to the use for dehydrating gases, the use of brine offers the possibility of considerably reducing the loss of gas through permeation; for this purpose, use is made of the often limited solubility of the gases to be dehydrated in, in particular, highly concentrated brines.
- The evaporator, which is used with the aid of a distillation process for evaporating water out of the brine, may be connected to the apparatus. Evaporating water out of the brine demands less energy than the usual condensation in known membrane separation processes. The equipment is much simpler (no refrigeration technique, no vacuum pump which is susceptible to malfunction).
- Because the volume of the permeate space can be considerably reduced, it has proved possible to conduct said processes satisfactorily using hollow fibres, the highly concentrated solution of one or more hygroscopic salts being situated inside the hollow fibres (permeate side) (diameter of, for example, 300 µm).
- The invention will now be explained in more detail with reference to some examples.
- A moistened nitrogen having a relative humidity of 75% is passed along an H₂O-selective gas separation membrane consisting of a hollow fibre of polyphenylene oxide (PPO). Situated at the permeate side (inside the hollow fibre) is a saturated NaCl solution. It was not possible to detect any marked water permeation (dehydration).
- A moistened air having a relative humidity of 75% is dehydrated at a temperature of 25°C with the aid of a gas separation process. In this process, an H₂O-selective hollow gas separation membrane consisting of polyphenylene oxide (PPO) is used. Saturated CsF brine is situated inside the hollow fibres. At a gas speed of 1 m/sec along the outside of the fibre, virtually all the water is removed after a fibre length of only 25 cm.
- An azeotropic mixture of isopropyl alcohol and water is dehydrated at a temperature of 90°C with the aid of a vapour permeation system, use being made of PPO hollow fibre membranes. Situated on the inside of the membranes is CsF brine. The permeate flux is approximately 0.3 kg/m².h.
- An azeotropic mixture of isopropyl alcohol and water is dehydrated at a temperature of 90°C with the aid of a vapour permeation system. The equipment comprises PPO hollow fibre membranes, an LiBr/ZnBr₂/CaBr₂ brine being situated on the inside of the membranes. The vaporisation of the permeated water takes place at approximately 180°C in an evaporating element. The process is carried out continuously and stably for approximately 100 hours. The permeate flux is approximately 0.4 kg/m².h.
- An azeotropic mixture of butanol and water is dehydrated at a temperature of 60°C with the aid of a pervaporation system. The equipment comprises a flat polyvinyl alcohol composite membrane. Situated at the permeate side is an LiBr/ZnBr₂/CaBr₂ brine. Permeation of water takes place with a flux of approximately 0.5 kg/m².h. The permeation of alcohol cannot be detected. It was not possible to detect any leakage of brine.
Claims (11)
- Membrane separation process for dehydrating a gas or vapour or liquid mixture by pervaporation or vapour permeation comprising: passing the mixture along the retentate side of a membrane and generating a driving force in order to transport water through the membrane to the permeate side thereof characterised in that the driving force is generated in that a highly concentrated solution of one or more hygroscopic salts (brine) is situated at the permeate side of the membrane, and that the hygroscopic capacity of said solution, expressed as a percentage of water vapour pressure reduction with respect to pure water, has a value of over 50%.
- Membrane separation process according to claim 1, characterised in that the brine salts contain combinations of small cations and large anions or of large cations and small anions or of mixtures thereof.
- Membrane separation process according to one of the preceding claims, characterised in that the brines are inorganic in nature.
- Membrane separation process according to one of the preceding claims, characterised in that the brine is removed continuously or discontinuously from the permeate side of the membrane, that the water taken up by the brine is removed from the brine and in that the worked-up brine is fed back to the permeate side of the membrane.
- Membrane separation process according to one of the preceding claims, characterised in that the mixture to be dehydrated is under increased pressure and the brine is at essentially the same pressure.
- Membrane separation process according to claim 4 or 5, characterised in that the process is continuous and in that the permeated water is evaporated.
- Membrane separation process according to one of the preceding claims, characterised in that use is made of hollow fibre membranes and the highly concentrated solution of one or more hygroscopic salts is situated inside or outside the hollow fibres membranes.
- Membrane separation process according to claim 7, characterised in that moisture-containing gas is passed on the outside of hollow H₂O-selective PPO gas separation fibre membranes with a brine on the inside of the hollow membranes.
- Membrane separation process according to claim 5, characterised in that a mixture of azeotropic isopropyl alcohol and water is dehydrated with the aid of a vapour permeation process, which mixture is passed on the outside of PPO hollow fibre membranes with a brine on the inside of the hollow membranes.
- Membrane separation process according to one of the preceding claims, characterised in that the brine is a concentrated solution of LiBr or ZnBr₂ or CaBr₂ or CsF.
- Membrane separation process according to one of claims 1 to 3 inclusive, characterised in that a liquid mixture of azeotropic butanol and water is dehydrated with the aid of a pervaporation process, the membrane being a flat polyvinyl alcohol composite membrane between the permeate side and the retentate side.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL9000783A NL9000783A (en) | 1990-04-03 | 1990-04-03 | MEMBRANE SEPARATION PROCESS FOR DEWATERING A GAS, VAPOR OR LIQUID MIXTURE BY PERVAPORATION, VAPOR PERMEATION OR GAS SEPARATION. |
NL9000783 | 1990-04-03 | ||
PCT/NL1991/000054 WO1991015284A1 (en) | 1990-04-03 | 1991-04-02 | Membrane separation process for dehydrating a gas or vapour or liquid mixture by pervaporation, vapour permeation or gas separation |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0524242A1 EP0524242A1 (en) | 1993-01-27 |
EP0524242B1 true EP0524242B1 (en) | 1994-12-21 |
Family
ID=19856858
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91907881A Expired - Lifetime EP0524242B1 (en) | 1990-04-03 | 1991-04-02 | Membrane separation process for dehydrating a gas or vapour or liquid mixture by pervaporation or vapour permeation |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0524242B1 (en) |
AT (1) | ATE115887T1 (en) |
DE (1) | DE69106128T2 (en) |
DK (1) | DK0524242T3 (en) |
NL (1) | NL9000783A (en) |
WO (1) | WO1991015284A1 (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2682613B1 (en) * | 1991-10-22 | 1994-06-03 | Cogia | METHOD FOR AT LEAST PARTIAL DEHYDRATION OF AN AQUEOUS COMPOSITION AND DEVICES FOR CARRYING OUT THE METHOD. |
NL9201226A (en) * | 1992-07-08 | 1994-02-01 | Tno | METHOD AND APPARATUS FOR REGULATING THE HUMIDITY OF A GAS FLOW AND PURIFYING IT AT THE SAME TIME FROM UNWANTED ACID OR BASIC GASES. |
US5399188A (en) * | 1993-12-01 | 1995-03-21 | Gas Research Institute | Organic emissions elimination apparatus and process for same |
NL9401233A (en) * | 1994-03-25 | 1995-11-01 | Tno | Membrane gas absorption method. |
NL9400483A (en) * | 1994-03-25 | 1995-11-01 | Tno | Method for absorbing gas/liquid with the aid of hollow fibre membranes |
US5575835A (en) * | 1995-08-11 | 1996-11-19 | W. L. Gore & Associates, Inc. | Apparatus for removing moisture from an environment |
US6747930B1 (en) | 1996-12-24 | 2004-06-08 | Hide & Seek Technologies, Inc. | Data protection on an optical disk |
NL1006013C2 (en) | 1997-05-09 | 1998-11-10 | Tno | Apparatus and method for performing membrane gas / liquid absorption at elevated pressure. |
US6531262B1 (en) | 1998-06-25 | 2003-03-11 | Spectradisc Corporation | Methods and apparatus for rendering an optically encoded medium unreadable and tamper-resistant |
US6338933B1 (en) * | 1998-06-25 | 2002-01-15 | Spectradisc Corporation | Methods and apparatus for rendering an optically encoded medium unreadable |
US6926829B2 (en) | 2000-03-06 | 2005-08-09 | Kvaerner Process Systems A.S. | Apparatus and method for separating fluids through a membrane |
DE10117140A1 (en) * | 2001-04-05 | 2002-10-17 | Geesthacht Gkss Forschung | Separating liquid or gaseous material mixtures comprises using membrane separation unit to separate material into retentate and permeate, and contacting permeate with absorbent |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3751879A (en) * | 1971-04-26 | 1973-08-14 | Instrumentation Specialties Co | Apparatus for reducing the dissolved gas concentration in a liquid |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE673772C (en) * | 1933-04-21 | 1939-03-29 | Julius Pintsch Kom Ges | Device for the regeneration of concentrated salt solutions serving as a drying liquid for gases |
GB495734A (en) * | 1937-09-06 | 1938-11-18 | Dow Chemical Co | Improvements in the dehumidification of gases and in compositions for absorbing water vapour |
GB1207704A (en) * | 1968-01-11 | 1970-10-07 | Exxon Research Engineering Co | Separation of gas mixtures by diffusion through porous barriers |
GB1440963A (en) * | 1973-04-30 | 1976-06-30 | Skarstrom C W | Process for separating a component from a fluid mixture |
US4174374A (en) * | 1977-06-22 | 1979-11-13 | General Electric Company | Maintaining the separation efficiency of immobilized liquid membranes in gas separation methods and apparatus |
NL7904388A (en) * | 1978-06-15 | 1979-12-18 | Mitsubishi Rayon Co | METHOD AND DEVICE FOR TRANSFER OF GASES. |
US4516984A (en) * | 1983-11-08 | 1985-05-14 | Emory University | Degassing process and apparatus for removal of oxygen |
DE3610011A1 (en) * | 1986-03-25 | 1987-10-08 | Geesthacht Gkss Forschung | METHOD FOR SEPARATING THE COMPONENTS OF A LIQUID MIXTURE |
NL8702150A (en) * | 1987-09-09 | 1989-04-03 | Tno | METHOD AND MEMBRANE FOR REMOVING WATER VAPOR BY VAPOR PERMEATION FROM A GAS-VAPOR MIXTURE. |
-
1990
- 1990-04-03 NL NL9000783A patent/NL9000783A/en not_active Application Discontinuation
-
1991
- 1991-04-02 AT AT91907881T patent/ATE115887T1/en active
- 1991-04-02 EP EP91907881A patent/EP0524242B1/en not_active Expired - Lifetime
- 1991-04-02 WO PCT/NL1991/000054 patent/WO1991015284A1/en active IP Right Grant
- 1991-04-02 DE DE69106128T patent/DE69106128T2/en not_active Expired - Fee Related
- 1991-04-02 DK DK91907881.6T patent/DK0524242T3/en active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3751879A (en) * | 1971-04-26 | 1973-08-14 | Instrumentation Specialties Co | Apparatus for reducing the dissolved gas concentration in a liquid |
Non-Patent Citations (1)
Title |
---|
THE CHEMICAL ENGINEER, PERVAPORATION HEADING FOR NEW HORIZONS, FEBRUARY 1990, PAGES 46-49 * |
Also Published As
Publication number | Publication date |
---|---|
DE69106128T2 (en) | 1995-05-04 |
WO1991015284A1 (en) | 1991-10-17 |
EP0524242A1 (en) | 1993-01-27 |
DK0524242T3 (en) | 1995-03-20 |
ATE115887T1 (en) | 1995-01-15 |
NL9000783A (en) | 1991-11-01 |
DE69106128D1 (en) | 1995-02-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0524242B1 (en) | Membrane separation process for dehydrating a gas or vapour or liquid mixture by pervaporation or vapour permeation | |
US4875908A (en) | Process for selectively separating gaseous mixtures containing water vapor | |
US5259869A (en) | Use of membrane separation to dry gas streams containing water vapor | |
US5681433A (en) | Membrane dehydration of vaporous feeds by countercurrent condensable sweep | |
US5044166A (en) | Refrigeration process with purge and recovery of refrigerant | |
CA2375252C (en) | Method for the purification of a liquid by membrane distillation, in particular for the production of desalinated water from seawater or brackish water or process water | |
EP0192893B1 (en) | Potable water from internal combustion engines | |
US3950247A (en) | Separation procedure | |
US4466202A (en) | Energy-efficient evaporation process with means for vapor recovery | |
US4944882A (en) | Hybrid membrane separation systems | |
KR950007913B1 (en) | High facilitated membrane for selective separation and process for the use thereof | |
EP0548281B1 (en) | Membrane module | |
EP2599539B1 (en) | Steam permselective membrane, and method using same for separating steam from mixed gas | |
US5611842A (en) | Organic and inorganic vapor permeation by countercurrent condensable sweep | |
US4067805A (en) | Process for separating aqueous formaldehyde mixtures | |
US20140157985A1 (en) | Dehumidification Systems and Methods Thereof | |
CA2046332A1 (en) | Composite membrane for separating water from fluids containing organic compounds by pervaporation | |
EP2331241A1 (en) | Process for separating liquid mixtures | |
US4199445A (en) | Process for separating aqueous mineral acid mixtures | |
US5427687A (en) | Bubble reaction using vapor permeation | |
EP0308002A1 (en) | Method and membrane for the removal of water vapour from a gas/vapour mixture by means of vapour permeation | |
US4877533A (en) | Separation of water from organic fluids | |
JPH02261521A (en) | Concentration method for water/ketone | |
GOODING et al. | Membrane-aided distillation of azeotropic solutions | |
JPS63258601A (en) | Concentration of aqueous organic solution |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19920928 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK FR GB IT LI LU NL SE |
|
17Q | First examination report despatched |
Effective date: 19930609 |
|
ITF | It: translation for a ep patent filed |
Owner name: STUDIO MASSARI S.R.L. |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE DK FR GB IT LI LU NL SE |
|
REF | Corresponds to: |
Ref document number: 115887 Country of ref document: AT Date of ref document: 19950115 Kind code of ref document: T |
|
EAL | Se: european patent in force in sweden |
Ref document number: 91907881.6 |
|
REF | Corresponds to: |
Ref document number: 69106128 Country of ref document: DE Date of ref document: 19950202 |
|
ET | Fr: translation filed | ||
REG | Reference to a national code |
Ref country code: DK Ref legal event code: T3 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19950430 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 19990506 Year of fee payment: 9 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 19990510 Year of fee payment: 9 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 19990511 Year of fee payment: 9 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 19990512 Year of fee payment: 9 Ref country code: DK Payment date: 19990512 Year of fee payment: 9 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000402 Ref country code: DK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000402 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000403 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000430 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000430 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20000430 |
|
BERE | Be: lapsed |
Owner name: NEDERLANDSE ORGANISATIE VOOR TOEGEPAST-NATUURWETEN Effective date: 20000430 |
|
EUG | Se: european patent has lapsed |
Ref document number: 91907881.6 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: EBP |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20030326 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20030331 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20030408 Year of fee payment: 13 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20040402 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20041103 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20041231 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050402 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20100413 Year of fee payment: 20 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: V4 Effective date: 20110402 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20110402 |