EP0510403B1 - Label - Google Patents

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Publication number
EP0510403B1
EP0510403B1 EP92105700A EP92105700A EP0510403B1 EP 0510403 B1 EP0510403 B1 EP 0510403B1 EP 92105700 A EP92105700 A EP 92105700A EP 92105700 A EP92105700 A EP 92105700A EP 0510403 B1 EP0510403 B1 EP 0510403B1
Authority
EP
European Patent Office
Prior art keywords
label
label according
plastics
adhesive layer
underside
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP92105700A
Other languages
German (de)
French (fr)
Other versions
EP0510403A1 (en
Inventor
Hans-Peter Ast
Robert Busler
Edgar Fleischmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Steinbeis Packaging GmbH
Steinbeis PPL GmbH
Original Assignee
Zweckform Etikettiertechnik GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zweckform Etikettiertechnik GmbH filed Critical Zweckform Etikettiertechnik GmbH
Publication of EP0510403A1 publication Critical patent/EP0510403A1/en
Application granted granted Critical
Publication of EP0510403B1 publication Critical patent/EP0510403B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08—Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/0208—Indicia
    • G09F2003/021—Indicia behind the front foil
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/0222—Features for removal or adhesion, e.g. tabs
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/023—Adhesive
    • G09F2003/0242—Adhesive soluble in water
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/023—Adhesive
    • G09F2003/0244—Adhesive soluble in chemicals
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/0255—Forms or constructions laminated
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02—Forms or constructions
    • G09F2003/0272—Labels for containers

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Adhesive Tapes (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Holo Graphy (AREA)
  • Laminated Bodies (AREA)
  • Details Of Rigid Or Semi-Rigid Containers (AREA)

Abstract

The invention relates to a label, the underside of which is to be adhesively bonded, by means of an adhesive which is essentially completely soluble in a washing liquid, to an object, especially to an object made of plastic, and preferably to a bottle crate made of plastic, which label is characterised in that the adhesive is disposed on the underside of the label in the form of a pressure-sensitive layer essentially completely soluble in the washing liquid. <IMAGE>

Description

Die Erfindung betrifft ein Etikett, dessen Unterseite mittels einer auf seiner Unterseite befindlichen, in einer Waschflüssigkeit im wesentlichen voll löslichen Haftklebstoffschicht auf einen Gegenstand zu kleben ist. Ein solches Etikett ist nach der EP-A 368 326 bekannt. Etiketten dieser Art dienen insbesondere zum Aufkleben auf Gegenstände aus Kunststoff, insbesondere auf aus Kunststoff bestehende Flaschenkästen.The invention relates to a label, the underside of which is to be adhered to an object by means of a pressure-sensitive adhesive layer which is located on its underside and is substantially fully soluble in a washing liquid. Such a label is known from EP-A 368 326. Labels of this type are used, in particular, for sticking onto plastic objects, in particular plastic bottle crates.

Aufgabe der Erfindung ist es, ein Etikett dieser Art anzugeben, das besonders leicht mittels der Waschflüssigkeit von dem Gegenstand gelöst werden kann, auf den es geklebt ist.The object of the invention is to provide a label of this type which can be detached particularly easily by means of the washing liquid from the object to which it is glued.

Zur Lösung dieser Aufgabe ist das Etikett dadurch gekennzeichnet, daß die Haftklebstoffschicht die Unterseite des Etiketts unter Freilassung unterspülbarer Zonen bedeckt.To achieve this object, the label is characterized in that the pressure-sensitive adhesive layer covers the underside of the label, leaving zones that can be rinsed free.

Das Etikett ist besonders witterungsbeständig, wenig schmutzanfällig und leicht wiederaufbereitbar (recycelbar), wenn es dadurch gekennzeichnet ist, daß es aus einem einen Kunststoffolienverbund enthaltenden, nach seinem Ablösen von dem Gegenstand wiederaufbereitbaren Verbundmaterial besteht.The label is particularly weather-resistant, less susceptible to dirt and easily reprocessable (recyclable) if it is characterized in that it consists of a composite material containing a plastic film composite that can be reprocessed after being detached from the object.

Beim Wiederaufbereiten eines solchen Etiketts entstehen nicht wie bei einem Papieretikett in der Waschflüssigkeit Papierfasern, die u.a. durch das Verstopfen von Filtern die Wiederaufbereitung erschweren. Vielmehr schwimmt das Etikett auf der Waschflüssigkeit und kann von der Waschflüssigkeit leicht abgetrennt werden.When such a label is reprocessed, paper fibers do not arise in the washing liquid as in the case of a paper label, which, among other things, is caused by the clogging of filters Complicate reprocessing. Rather, the label floats on the washing liquid and can be easily separated from the washing liquid.

Das gilt auch dann und insbesondere dann, wenn sich - in an sich bekannter Weise - auf der Oberseite des Etiketts ein Aufdruck befindet, der von einer mittels eines Kaschierklebstoffs aufgeklebten, durchsichtigen Kunststoffolie abgedeckt ist.This also applies and in particular when - in a manner known per se - there is an imprint on the top of the label which is covered by a transparent plastic film glued on by means of a laminating adhesive.

Die Schwimmfähigkeit des Etiketts auf der Waschflüssigkeit ist besonders hoch, wenn der Kunststoffolienverbund des Etiketts eine Vakuolen enthaltende Folie - insbesondere PP-Folie - zwischen zwei keine Vakuolen enthaltenden Folien - insbesondere PP-Folien - aufweist.The ability of the label to float on the washing liquid is particularly high if the plastic film composite of the label has a film containing vacuoles - in particular PP film - between two films containing no vacuoles - in particular PP films.

Eine hohe Fälschungssicherheit erhält man, wenn wenigstens eine der genannten Folien - am besten aber alle genannten Folien - biaxial gereckt ist bzw. sind. Ein mit wenigstens einer derart biaxial gereckten Folie versehenes Etikett verformt sich nämlich beim Abziehen vom Gegenstand und kann nicht wieder verwendet werden.A high level of security against counterfeiting is obtained if at least one of the films mentioned - but preferably all the films mentioned - is or have been biaxially stretched. A label provided with at least one such biaxially stretched film deforms when it is pulled off the object and cannot be used again.

Das Aufbringen des Etiketts auf den Gegenstand erfolgt vorteilhaft durch Ablösen von einem Trägerband, das über eine Umlenkkante gezogen wird in an sich bekannter Weise. Bevorzugt befindet sich das Etikett vor seinem Aufkleben auf die Gegenstände ablösbar auf einem wiederaufbereitbaren Trägermaterial. Als ein solches Trägermaterial hat sich besonders ein Trägermaterial bewährt, das als Unterlage ein Kraftpapier aufweist, auf dem über einen PE-Film eine das Ablösen des Etiketts erleichternde Silikonschicht haftet.The label is advantageously applied to the object by detaching it from a carrier tape which is pulled over a deflection edge in a manner known per se. The label is preferably detachably on a reprocessable carrier material before it is attached to the objects. A carrier material which has a kraft paper as a base on which a silicone layer which facilitates the removal of the label adheres via a PE film has proven particularly useful as such a carrier material.

Um die Haftung des Etiketts auf einem aus Kunststoff bestehenden Gegenstand zu vergrößern, ist bevorzugt der eine Flächenbereich eines solchen Gegenstands, auf den das Etikett aufzukleben ist, durch Beflammung oder Coronaentladung vorbehandelt.In order to increase the adhesion of the label to an object made of plastic, the one surface area of such an object is preferably on which the label is to be glued, pretreated by flame or corona discharge.

Aus der Waschflüssigkeit ist der Klebstoff besonders einfach zu entfernen, wenn die Waschflüssigkeit aus basische Zusätze wie NaOH, NH4Cl, NH3 enthaltendem Wasser besteht und wenn der Klebstoff aus einem Material besteht, das - in der Waschflüssigkeit gelöst - durch Neutralisation der basischen Zusätze in der Wasch flüssigkeit ausfällbar ist.The adhesive is particularly easy to remove from the washing liquid if the washing liquid consists of basic additives such as NaOH, NH 4 Cl, NH 3 and if the adhesive consists of a material which - dissolved in the washing liquid - by neutralizing the basic additives is precipitable in the washing liquid.

Besonders hat sich dabei ein Klebstoff bewährt, der als Basismaterial ein Polymethylmetacrylat aufweist.An adhesive which has a polymethyl methacrylate as the base material has proven particularly useful.

Eine besonders gute Haftung des Klebstoffs an der Unterseite des Etiketts erhält man, wenn der Klebstoff über eine Primerschicht (Haftvermittlerschicht) an der Unterseite des Etiketts haftet.Particularly good adhesion of the adhesive to the underside of the label is obtained if the adhesive adheres to the underside of the label via a primer layer (adhesion promoter layer).

Je nach den Bedingungen, unter denen das Entfernen des Etiketts vom Gegenstand mittels der Waschflüssigkeit erfolgt, liegen die unterspülbaren Zonen im Randbereich des Etiketts und/oder zwischen Bereichen der Haftklebstoffschicht.Depending on the conditions under which the label is removed from the object by means of the washing liquid, the washable zones lie in the edge area of the label and / or between areas of the pressure-sensitive adhesive layer.

Will man einen aus Kunststoff bestehenden Gegenstand, der mit einem Etikett genannter Art versehen ist, zusammen mit dem Etikett etwa nach Granulieren wiederaufbereiten, um etwa den Kunststoff rückzugewinnen, so hat das Etikett bevorzugt den gleichen MFI-Schmelzindex wie der Kunststoff des Gegenstands.If you want to reprocess an object made of plastic, which is provided with a label of the type mentioned, together with the label, for example after granulation, in order to recover the plastic, for example, the label preferably has the same MFI melt index as the plastic of the object.

Die Erfindung wird im folgenden an einem Ausführungsbeispiel unter Hinweis auf die beigefügten Zeichnungen erläutert.The invention is explained below using an exemplary embodiment with reference to the accompanying drawings.

Fig. 1 zeigt einen Querschnitt eines Etiketts auf einem Träger.Fig. 1 shows a cross section of a label on a carrier.

Fig. 2 zeigt eine Ansicht des von dem Träger gelösten Etiketts nach Fig. 1 von unten.FIG. 2 shows a bottom view of the label according to FIG. 1 detached from the carrier.

Der Träger 1 des Etiketts besteht aus einem weißen Kraftpapier einer Stärke von 60 - 74 g/qm, insbesondere 67 g/qm. Auf dem Träger 1 haftet über einen PE-Film 10 eine Silikonschicht 2. Auf der Silikonschicht 2 haftet ablösbar eine Haftklebstoffschicht 3 an der Unterseite eines Folienverbunds 12. Die Stärke der Haftklebstoffschicht 3 beträgt 12 - 24 µ, bevorzugt 18 µ. Die Stärke des Folienverbunds 12 beträgt 20 - 120 µ, besser 30 - 50 µ, bevorzugt 40 µ.The carrier 1 of the label consists of white kraft paper with a thickness of 60-74 g / m2, in particular 67 g / m2. A silicone layer 2 adheres to the carrier 1 via a PE film 10. A pressure-sensitive adhesive layer 3 removably adheres to the silicone layer 2 on the underside of a film composite 12. The thickness of the pressure-sensitive adhesive layer 3 is 12-24 μm, preferably 18 μm. The thickness of the film composite 12 is 20-120 μm, better 30-50 μm, preferably 40 μm.

Der Folienverbund 12 besteht aus einer weißen, Vakuolen enthaltenden, biaxial gereckten PP-Folie 5 zwischen zwei weißen, biaxial gereckten, keine Vakuolen enthaltenden PP-Folien 4, 6. Die Vakuolen in der Folie 5 können dadurch erzeugt werden, daß das PP im flüssigen Zustand, bevor aus ihm durch Auspressen aus einer Düse eine Folie gebildet wird, mit feingemahlener Kreide versetzt wird. Beim biaxialen Recken bilden sich dann die Vakuolen. Auf der Oberseite der Folie 6 befindet sich ein Aufdruck 7. Dieser Aufdruck 7 ist von einer durchsichtigen Folie 9 abgedeckt, die mittels eines Kaschierklebstoffs auf den Aufdruck 7 und die freien Bereiche der Folie 6 aufgeklebt wird. Die Folie 9 hat eine Stärke von 8 - 16 µ, bevorzugt 12 µ, und besteht aus biaxial gerecktem PP.The film composite 12 consists of a white, vacuole-containing, biaxially stretched PP film 5 between two white, biaxially stretched, no vacuoles-containing PP films 4, 6. The vacuoles in the film 5 can be created in that the PP in the liquid Condition before it is pressed out of a nozzle to form a film and finely ground chalk is added. The vacuoles then form during biaxial stretching. On the top of the film 6 there is an imprint 7. This imprint 7 is covered by a transparent film 9, which is glued onto the imprint 7 and the free areas of the film 6 by means of a laminating adhesive. The film 9 has a thickness of 8-16 μ, preferably 12 μ, and consists of biaxially stretched PP.

Die Haftklebstoffschicht 3 ist in drei Bereiche 3a, 3b, 3c unterteilt, die durch klebstoffreie Zonen 14, 16 voneinander getrennt sind. Die klebstoffreien Zonen 14, 16 sind streifenförming und münden in einer klebstoffreien Zone 18, die die Bereiche 3a, 3b, 3c in Form eines Streifens umschließt.The pressure-sensitive adhesive layer 3 is divided into three areas 3a, 3b, 3c, which are separated from one another by adhesive-free zones 14, 16. The adhesive-free zones 14, 16 are strip-shaped and open into an adhesive-free zone 18 which encloses the areas 3a, 3b, 3c in the form of a strip.

Claims (14)

  1. Label, the underside of which is to be stuck to an object by means of a contact adhesive layer (3) which is provided on the underside and is substantially totally soluble in a washing liquid, characterised in that the contact adhesive layer (3) covers the underside of the label, leaving exposed certain zones (14, 16, 18) which can be underwashed.
  2. Label according to claim 1, characterised in that it consists of a composite material containing a combination of plastics films (12) and recyclable after removal from the object.
  3. Label according to claim 1 or 2, characterised in that, on its upper surface, there is an imprint (7) which is covered by a transparent plastics film (9) attached by means of a laminating adhesive (8).
  4. Label according to claim 2 or 3, characterised in that the combination of plastics films (12) comprises a plastics film - especially PP film - which contains vacuoles between two plastics films (4, 6) - especially PP films - which do not contain vacuoles.
  5. Label according to claim 2 to 4, characterised in that at least one of the plastics films (4, 5, 6, 9) is biaxially stretched.
  6. Label according to one of the preceding claims, characterised in that, before it is stuck onto the object, it is removably held on a recyclable carrier material.
  7. Label according to claim 6, characterised in that the carrier material (1, 2, 10) has as its substrate a sulfate paper (1) to which a silicone layer (2) adheres via a PE film (10).
  8. Label according to one of the preceding claims, characterised in that the surface region of an object made of plastics, onto which the label is to be stuck, is pretreated by flaming or corona discharge.
  9. Label according to one of the preceding claims, characterised in that the washing liquid consists of water containing basic additives such as NaOH, NH4Cl or NH3 and in that the adhesive of the contact adhesive layer (3) consists of a material which, once dissolved in the washing liquid, can be precipitated by neutralisation of the basic additives.
  10. Label according to one of the preceding claims, characterised in that the adhesive of the contact adhesive layer (3) comprises a polymethyl methacrylate as basis material.
  11. Label according to one of the preceding claims, characterised in that the adhesive of the contact adhesive layer (3) adheres to the underside of the label via a primer layer (adhesion promoter layer).
  12. Label according to one of the preceding claims, characterised in that there are underwashable zones (18) in the edge region of the label.
  13. Label according to one of the preceding claims, characterised in that there are underwashable zones (14, 16) between regions (3a, 3b, 3c) of the contact adhesive layer (3).
  14. Label, particularly according to one of the preceding claims, characterised in that it has the same MFI melt flow index as the object made of plastics.
EP92105700A 1991-04-26 1992-04-02 Label Expired - Lifetime EP0510403B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4113751 1991-04-26
DE4113751A DE4113751A1 (en) 1991-04-26 1991-04-26 LABEL

Publications (2)

Publication Number Publication Date
EP0510403A1 EP0510403A1 (en) 1992-10-28
EP0510403B1 true EP0510403B1 (en) 1996-10-16

Family

ID=6430470

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92105700A Expired - Lifetime EP0510403B1 (en) 1991-04-26 1992-04-02 Label

Country Status (5)

Country Link
EP (1) EP0510403B1 (en)
AT (1) ATE144341T1 (en)
DE (2) DE4113751A1 (en)
DK (1) DK0510403T3 (en)
ES (1) ES2093132T3 (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE9312382U1 (en) * 1993-08-18 1993-11-04 Zweckform Etikettiertechnik label
DE29506051U1 (en) * 1995-04-07 1995-12-07 Pago Etikettiersysteme Gmbh PSA label
NZ331863A (en) * 1996-03-20 2000-02-28 Heineken Tech Services Transfer label having ink containment layers, container comprising a transfer layer and method of washing such a container
EP0824251A1 (en) * 1996-08-12 1998-02-18 Heineken Technical Services B.V. Transfer label having ink containment layers, container comprising a transfer layer and method of washing such a container
US6616786B2 (en) * 1996-03-20 2003-09-09 Heineken Technical Services B.V. Process for applying an ink-only label to a polymeric surface
EP0824250A1 (en) * 1996-08-12 1998-02-18 Heineken Technical Services B.V. Transfer label, comprising a backing layer and a transfer layer, container comprising such a transfer layer and method of removing a transfer layer from a container
PT888601E (en) * 1996-03-20 2002-06-28 Heineken Tech Services A stapling container comprising a backing layer and a backing layer, a container comprising a backing layer and a process for removing a backing layer from a container
DE19801148A1 (en) * 1998-01-14 1999-07-15 Schreiner Etiketten Adhesive paper label for labeling bottles etc.
DE29803159U1 (en) * 1998-02-23 1998-04-23 Schreiner Etiketten Label and bottle crate
DE29806781U1 (en) * 1998-04-15 1999-09-02 Zweckform Etikettiertechnik Easily removable label for reusable containers
ATE260507T1 (en) 1998-11-06 2004-03-15 Jackstaedt Gmbh MEAT STICKER LABEL
CA2370038C (en) 1999-04-14 2008-06-17 Steinbeis Ppl Gmbh Easily removable label for reusable containers
DE102008045547A1 (en) * 2008-09-03 2010-03-04 Ccl Label Meerane Gmbh Label, in particular for a reusable container
EP2196510A1 (en) 2008-12-09 2010-06-16 AMC Pancke AG Label based on polyolefin film
DE102010020209A1 (en) * 2010-05-12 2011-11-17 X-Label Gmbh - Holding Adhesive label composite and method for producing a printed adhesive label composite

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3838027A1 (en) * 1988-11-09 1990-05-10 Zweckform Etikettiertechnik ADHESIVE LABEL FOR STICKING ON A PACKAGE OF PP
US5096767A (en) * 1989-02-03 1992-03-17 Mitsubishi Paper Mills Limited Alkali-removable label support and label

Also Published As

Publication number Publication date
EP0510403A1 (en) 1992-10-28
DK0510403T3 (en) 1996-11-18
DE59207361D1 (en) 1996-11-21
DE4113751A1 (en) 1992-10-29
ATE144341T1 (en) 1996-11-15
ES2093132T3 (en) 1996-12-16

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