EP0499033B1 - Irritant agent cartridge or projectile with moulded on irritant agent charge in paste - Google Patents

Irritant agent cartridge or projectile with moulded on irritant agent charge in paste Download PDF

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Publication number
EP0499033B1
EP0499033B1 EP92100493A EP92100493A EP0499033B1 EP 0499033 B1 EP0499033 B1 EP 0499033B1 EP 92100493 A EP92100493 A EP 92100493A EP 92100493 A EP92100493 A EP 92100493A EP 0499033 B1 EP0499033 B1 EP 0499033B1
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EP
European Patent Office
Prior art keywords
irritant agent
irritant
containers
cartridge
charge
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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EP92100493A
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German (de)
French (fr)
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EP0499033A1 (en
Inventor
Uwe Dr. Sliwczuk
Hans Hibinger
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Piepenbrock Pyrotechnik GmbH
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Piepenbrock Pyrotechnik GmbH
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Priority to AT9292100493T priority Critical patent/ATE105629T1/en
Publication of EP0499033A1 publication Critical patent/EP0499033A1/en
Application granted granted Critical
Publication of EP0499033B1 publication Critical patent/EP0499033B1/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42AMMUNITION; BLASTING
    • F42BEXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B12/00Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
    • F42B12/02Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
    • F42B12/36Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information
    • F42B12/46Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information for dispensing gases, vapours, powders or chemically-reactive substances

Definitions

  • the present invention relates to an irritant cartridge or a projectile, in particular for firing from small arms according to the preamble of claim 1.
  • Known irritant cartridges essentially consist of a primer arranged in the bottom of the cartridge, the firing located above it and the compressed irritant set again arranged above it.
  • the latter consists of a mixture of a heating set with the required amounts of chloroacetophenone (CN) or chlorobenzylidenmalononitrile (CS).
  • CN chloroacetophenone
  • CS chlorobenzylidenmalononitrile
  • the primer is destroyed by escaping irritant gas over time.
  • the present invention has therefore set itself the task of creating a new structure of the irritant cartridge, in the manufacture and storage of which the release of irritant gas is largely restricted.
  • the irritant charge consists of pasty or melted and flowable active substance and is located in separate containers provided with a protective layer, the containers being on rest the heating set or the lighting and are covered by a perforated disc and held in the cartridge.
  • the melting and casting does not require high temperatures, CN melts at about 55 ° C and CS at about 95 ° C, the melting and casting can be carried out particularly easily in closed devices provided for this purpose.
  • a protective layer e.g. a film is glued or welded on, after which the containers can be stored temporarily without any significant amounts of CN or CS molecules being able to escape through the container walls (preferably plastic) or the protective layer.
  • the irritant can also be processed as a paste, for which it is heated to the melting temperature and, if necessary, mixed warm with a suitable filler in the desired ratio and brought into the mold.
  • the melting points of CN are around 55 ° C and of CS at 95 ° C, which is useful for paste production.
  • Filler can be paraffin, for example.
  • the irritant cartridge can be a normal cartridge with its own primer, but it can also be used as a "star", whereby a propellant drives the cartridge out and ignites the heating unit.
  • the containers can be cylindrical and e.g. as a circle lie against the heating unit or the lighting.
  • the pouring of larger volumes is preferred, preferably in a receptacle corresponding to a cake pan with a central, upstanding central part, the height of which corresponds approximately to that of the container rim.
  • a central opening is provided in the middle part, just like in the perforated disc, which is used to ignite the propellant for firing, e.g. with a corresponding star structure or for the directed outflow of the hot gas released by the heating unit, the latter heat the container to such an extent that the container wall and / or the cover is destroyed and irritant gas is released.
  • the perforated disk made of a suitable material, preferably made of metal, covers the containers, and the irritant gas initially emerges through the holes.
  • the opening of the mold and the number of holes and their size in the perforated disc can be used to control or optimize the discharge of irritant gas, which is particularly advantageous if the heating unit is mixed with a smoke component.
  • Containers and cover plates can be made of plastic that burns without leaving residues, e.g. Polyethylene.
  • a particularly simple way of sealing the containers against outgassing irritant is to heat seal the set after casting with a wax, in particular with paraffin, this only on the surface of the irritant needs to be poured on. The wax and irritant can then cool down and solidify together.
  • the containers can be held in the cartridge by a clamped ring over the perforated disk, in particular in the case of a star that can be closed with a propellant and inserted into a cartridge, it is proposed to crimp the cartridge rim and thereby press the perforated disk onto the container or containers, thereby the whole sentence is fixed.
  • Figure 1 shows in section a tear gas star, which is fired with the aid of a propellant (not shown). It consists of the charge sleeve 8 made of aluminum and the heating set 4 located therein and the firing 5 above it.
  • the heating set consists of suitable pyrotechnic, preferably a smoldering set of potassium chlorate and organic fuels and the firing.
  • a cake-shaped container 3 with CN, CR or CS cast therein as an irritant charge 1 rests on the firing 5.
  • the irritant charge 1 is covered by paraffin as a protective layer 2.
  • a disc 6 with circular holes 11 is placed on the upper edge 10 of the container 3 and pressed against the container edge 10 by the crimp 9, so that the entire set rests stably in the sleeve 8 .
  • the disc 6 has a central opening 7 as the ignition channel, which lies coaxially above a central opening in the raised central part 12 of the container 3 and thus forms an access to the lighting 5.
  • the free space within the central part 12 can be filled with a heating set and / or an ignition set, and the peripheral area around the container can be filled with a heating set.
  • the star is housed in a cartridge, the central openings 7, 7 'are used to ignite through the primer of the cartridge.
  • the heating element can contain smoke, e.g. Ammonium chloride can be added.
  • the sleeve 8 can be ejected as a whole from the cartridge casing in order to then expel irritant gas.
  • Figure 2 shows an enlarged view of the cake-shaped container 3 in section. It preferably consists of plastic that burns without residues and is filled with the melted and cast or pasty irritant charge 1.
  • a cast and solidified protective layer 2 On top of the solidified irritant gas there is a cast and solidified protective layer 2, preferably made of paraffin, whereby the irritant is sealed gas-tight to the outside.
  • the central opening 7 is left open for ignition.
  • the edge 10 is supported against the inner wall of the charge sleeve.
  • a sealing film 13 can also be glued or welded onto the edge 10, as indicated by dashed lines, for which purpose the edge 10 has an annular protrusion 14 and the middle part 12 can be provided with a flattened area 15 for sealing purposes or welding to provide enough space.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Portable Nailing Machines And Staplers (AREA)
  • Cosmetics (AREA)
  • Toys (AREA)
  • Medical Preparation Storing Or Oral Administration Devices (AREA)
  • Packaging Of Annular Or Rod-Shaped Articles, Wearing Apparel, Cassettes, Or The Like (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Medicinal Preparation (AREA)

Abstract

The present invention relates to an irritant agent cartridge or a projectile, consisting of a charge case (8), if appropriate a detonator, a heating set (4), if appropriate a primer (5) and an irritant agent such as chloroacetophenone (CN), chlorobenzylidenemalononitrile (CS) or dibenzoxazepine (CR), the irritant agent charge (1) being located in separate containers (3) provided with a protective layer (2) and consisting of molten or pasty active compound introduced into the containers in a flowable state and these containers resting on the heating set or the primer and being held in the cartridge by means of a perforated disc (6). <IMAGE>

Description

Die vorliegende Erfindung betrifft eine Reizstoffpatrone oder einen Wurfkörper, insbesondere zum Abschuß aus Handfeuerwaffen gemäß Oberbegriff des Anspruchs 1.The present invention relates to an irritant cartridge or a projectile, in particular for firing from small arms according to the preamble of claim 1.

Bekannte Reizstoffpatronen (EP-A-0255578) bestehen im wesentlichen aus einem im Boden der Patrone angeordneten Zündhütchen, darüber befindlicher Anfeuerung und wieder darüber angeordnetem verpreßten Reizstoffsatz. Letzterer besteht aus einer Mischung aus einem Heizsatz mit den erforderlichen Mengen an Chloracetophenon (CN) oder Chlorbenzylidenmalonsäuredinitril (CS). Beim Abbrennen, d.h. nach der Zündung durch die Anfeuerung, erwärmt der Heizsatz das Reizgas und treibt dieses aus.Known irritant cartridges (EP-A-0255578) essentially consist of a primer arranged in the bottom of the cartridge, the firing located above it and the compressed irritant set again arranged above it. The latter consists of a mixture of a heating set with the required amounts of chloroacetophenone (CN) or chlorobenzylidenmalononitrile (CS). When burning, i.e. after ignition by the ignition, the heating set heats the irritant gas and drives it out.

Die Herstellung dieses gepreßten Satze ist mit großer Belastung des Arbeitspersonals verbunden, da während der gesamten Herstellung - Mischen, Mahlen, Pressen, Dosieren und Montieren - ständig Reizgas austritt, was zu Irritationen der Augen, der Schleimhäute und der Haut führt.The production of these pressed sets is associated with a great deal of strain on the working personnel, since irritant gas is constantly emitted during the entire production process - mixing, grinding, pressing, dosing and assembling, which leads to irritation of the eyes, mucous membranes and skin.

Außerdem wird das Zündhütchen durch austretendes Reizgas im Laufe der Zeit zerstört.In addition, the primer is destroyed by escaping irritant gas over time.

Die vorliegende Erfindung hat sich daher die Aufgabe gestellt, einen neuen Aufbau der Reizstoffpatrone zu schaffen, bei dessen Herstellung und bei Lagerung das Freiwerden von Reizgas weitestgehend eingeschränkt ist.The present invention has therefore set itself the task of creating a new structure of the irritant cartridge, in the manufacture and storage of which the release of irritant gas is largely restricted.

Die Lösung dieser Aufgabe gelingt, ausgehend vom Stand der Technik bei einer Reizstoffpatrone der eingangs geschilderten Art, erfindungsgemäß dadurch, daß die Reizstoffladung aus pastösem oder erschmolzenem und fließfähig eingetragenem Wirkstoff besteht und sich in separaten, mit einer Schutzschicht versehenen Behältnissen befindet, wobei die Behältnisse auf dem Heizsatz bzw. der Anfeuerung ruhen und von einer Lochscheibe überdeckt und in der Patrone gehalten sind.This object is achieved, starting from the prior art in the case of an irritant cartridge of the type described at the outset, according to the invention in that the irritant charge consists of pasty or melted and flowable active substance and is located in separate containers provided with a protective layer, the containers being on rest the heating set or the lighting and are covered by a perforated disc and held in the cartridge.

Wesentlich ist dabei, daß nunmehr Heizsatz und Reizstoff getrennt voneinander vorliegen, wobei der Reizstoff in die Behältnisse vergossen wird, wonach diese versiegelt werden.It is essential that the heating element and irritant are now separate from one another, the irritant being poured into the containers, after which they are sealed.

Das Aufschmelzen und Vergießen erfordert keine hohen Temperaturen, CN schmilzt bei etwa 55°C und CS bei etwa 95°C, wobei das Aufschmelzen und Vergießen besonders leicht in abgeschlossenen, dafür vorgesehenen Vorrichtungen vorgenommen werden kann. Nach dem Abkühlen wird auf das Behältnis eine Schutzschicht, z.B. eine Folie aufgeklebt oder aufgeschweißt, wonach die Behältnisse ohne weiteres zwischenlagerfähig sind, ohne daß durch die Behälterwandungen (vorzugsweise Kunststoff) oder die Schutzschicht nennenswerte Mengen an CN- oder CS-Molekülen austreten können.The melting and casting does not require high temperatures, CN melts at about 55 ° C and CS at about 95 ° C, the melting and casting can be carried out particularly easily in closed devices provided for this purpose. After cooling, a protective layer, e.g. a film is glued or welded on, after which the containers can be stored temporarily without any significant amounts of CN or CS molecules being able to escape through the container walls (preferably plastic) or the protective layer.

Der Reizstoff kann auch als Paste verarbeitet werden, wozu dieser auf Schmelztemperatur erwärmt und gegebenenfalls mit geeignetem Füllstoff im gewünschten Mengenverhältnis warm abgemischt und in die Form gebracht wird. Die Schmelzpunkte von CN liegen bei etwa 55°C und von CS bei 95°C, was der Pastenherstellung entgegenkommt. Füllstoff kann z.B. Paraffin sein.The irritant can also be processed as a paste, for which it is heated to the melting temperature and, if necessary, mixed warm with a suitable filler in the desired ratio and brought into the mold. The melting points of CN are around 55 ° C and of CS at 95 ° C, which is useful for paste production. Filler can be paraffin, for example.

Die Reizstoffpatrone kann dabei eine normale Patrone mit eigenem Zündhütchen sein, sie kann jedoch auch als "Stern" verwendet werden, wobei ein Treibsatz die Patrone austreibt und die Anfeuerung des Heizsatzes zündet.The irritant cartridge can be a normal cartridge with its own primer, but it can also be used as a "star", whereby a propellant drives the cartridge out and ignites the heating unit.

Die Behältnisse können zylinderförmig ausgebildet sein und z.B. als Mehrzahl kreisförmig gegen den Heizsatz oder die Anfeuerung anliegen.The containers can be cylindrical and e.g. as a circle lie against the heating unit or the lighting.

Vorgezogen wird jedoch das Vergießen von größeren Volumina, vorzugsweise in eine einer Kuchenform entsprechende Aufnahme mit einem zentralen, hochstehenden Mittelteil, dessen Höhe derjenigen des Behältnisrandes etwa entspricht. Im Mittelteil ist dabei, ebenso wie in der Lochscheibe, eine zentrale Öffnung vorgesehen, die dem Durchzünden vom Treibsatz zur Anfeuerung, z.B. bei entsprechendem Aufbau eines Sternes bzw. zum gerichteten Ausströmen des vom Heizsatz freigesetzten Heißgases dient, die letztere die Behälter soweit erhitzen, daß die Behälterwandung und/oder die Abdeckung zerstört und Reizgas freigesetzt wird.However, the pouring of larger volumes is preferred, preferably in a receptacle corresponding to a cake pan with a central, upstanding central part, the height of which corresponds approximately to that of the container rim. A central opening is provided in the middle part, just like in the perforated disc, which is used to ignite the propellant for firing, e.g. with a corresponding star structure or for the directed outflow of the hot gas released by the heating unit, the latter heat the container to such an extent that the container wall and / or the cover is destroyed and irritant gas is released.

Die Lochscheibe aus geeignetem Werkstoff, vorzugsweise aus Metall, überdeckt die Behältnisse, und über die Löcher tritt anfänglich das Reizgas aus.The perforated disk made of a suitable material, preferably made of metal, covers the containers, and the irritant gas initially emerges through the holes.

Die Öffnung der Form sowie die Lochanzahl und deren Größe in der Lochscheibe können zur Steuerung oder Optimierung des Reizgasaustrittes dienen, was insbesondere dann von Vorteil ist, wenn dem Heizsatz ein Rauchsatzanteil zugemischt ist.The opening of the mold and the number of holes and their size in the perforated disc can be used to control or optimize the discharge of irritant gas, which is particularly advantageous if the heating unit is mixed with a smoke component.

Behältnisse und Abdeckscheibe können dabei aus rückstandsfrei verbrennendem Kunststoff, wie z.B. Polyethylen, bestehen.Containers and cover plates can be made of plastic that burns without leaving residues, e.g. Polyethylene.

Eine besonders einfache Möglichkeit, die Behältnisse gegen ausgasenden Reizstoff zu versiegeln, besteht darin, den Satz nach dem Vergießen mit einem Wachs, insbesondere mit Paraffin heiß zu versiegeln, wobei dieses lediglich auf die Oberfläche des Reizstoffes aufgegossen zu werden braucht. Wachs und Reizstoff können danach gemeinsam abkühlen und erstarren.A particularly simple way of sealing the containers against outgassing irritant is to heat seal the set after casting with a wax, in particular with paraffin, this only on the surface of the irritant needs to be poured on. The wax and irritant can then cool down and solidify together.

Die Behältnisse können in der Patrone durch einen eingespannten Ring über die Lochscheibe gehalten werden, insbesondere bei einem mit einem Treibsatz zu verschließenden, in eine Patrone einsetzbaren Stern, wird vorgeschlagen, den Patronenrand einzubördeln und dadurch die Lochscheibe auf das oder die Behältnisse zu drücken, wodurch der ganze Satz fixiert wird.The containers can be held in the cartridge by a clamped ring over the perforated disk, in particular in the case of a star that can be closed with a propellant and inserted into a cartridge, it is proposed to crimp the cartridge rim and thereby press the perforated disk onto the container or containers, thereby the whole sentence is fixed.

Anhand der beiliegenden Figuren wird die vorliegende Erfindung beispielhaft näher erläutert.

Figur 1
zeigt einen Tränengasstern
Figur 2
zeigt einen Einstellbehälter.
The present invention is explained in more detail by way of example with reference to the accompanying figures.
Figure 1
shows a tear gas star
Figure 2
shows an adjustment container.

Figur 1 zeigt im Schnitt einen Tränengasstern, der mit Hilfe eines (nicht dargestellten) Treibsatzes verschossen wird. Er besteht aus der Ladungshülse 8 aus Aluminium sowie dem darin befindlichen Heizsatz 4 und der darüber liegenden Anfeuerung 5. Der Heizsatz besteht aus geeignetem pyrotechnischen, vorzugsweise einem Schwelsatz aus Kaliumchlorat und organischen Brennstoffen und der Anfeuerung. Auf der Anfeuerung 5 ruht ein kuchenformartiges Behältnis 3 mit darin eingegossenem CN, CR oder CS als Reizstoffladung 1. Figure 1 shows in section a tear gas star, which is fired with the aid of a propellant (not shown). It consists of the charge sleeve 8 made of aluminum and the heating set 4 located therein and the firing 5 above it. The heating set consists of suitable pyrotechnic, preferably a smoldering set of potassium chlorate and organic fuels and the firing. A cake-shaped container 3 with CN, CR or CS cast therein as an irritant charge 1 rests on the firing 5.

Die Reizstoffladung 1 ist überdeckt von Paraffin als Schutzschicht 2. Auf den oberen Rand 10 des Behältnisses 3 ist eine Scheibe 6 mit kreisförmigen Löchern 11 gelegt und durch die Einbördelung 9 gegen den Behälterrand 10 gedrückt, so daß der gesamte Satz stabil in der Hülse 8 ruht.The irritant charge 1 is covered by paraffin as a protective layer 2. A disc 6 with circular holes 11 is placed on the upper edge 10 of the container 3 and pressed against the container edge 10 by the crimp 9, so that the entire set rests stably in the sleeve 8 .

Die Scheibe 6 weist als Zündkanal eine zentrale Öffnung 7 auf, die koaxial über einer mittigen Öffnung im erhabenen Mittelteil 12 des Behältnisses 3 liegt und so einen Zugang zur Anfeuerung 5 bildet. Der Freiraum innerhalb des Mittelteils 12 kann mit einem Heizsatz und/oder einem Zündsatz ausgefüllt sein, ebenso kann der periphere Bereich um das Behältnis mit Heizsatz ausgefüllt sein.The disc 6 has a central opening 7 as the ignition channel, which lies coaxially above a central opening in the raised central part 12 of the container 3 and thus forms an access to the lighting 5. The free space within the central part 12 can be filled with a heating set and / or an ignition set, and the peripheral area around the container can be filled with a heating set.

Der Stern ist in einer Patrone untergebracht, die zentralen Öffnungen 7, 7' dienen zum Durchzünden durch das Zündhütchen der Patrone.The star is housed in a cartridge, the central openings 7, 7 'are used to ignite through the primer of the cartridge.

Dem Heizsatz kann Rauchanteil, z.B. Ammoniumchlorid beigemischt werden.The heating element can contain smoke, e.g. Ammonium chloride can be added.

Anstelle eines einzelnen Einstellbehälters können natürlich auch mehrere kreisförmige Behälter einer geeigneten Form kreisförmig unter Freilassung einer als Zündkanal dienenden zentralen Öffnung um die Mittelachse herum angeordnet sein.Instead of a single adjusting container, it is of course also possible to arrange a plurality of circular containers of a suitable shape in a circular manner, leaving a central opening serving as an ignition channel around the central axis.

Die Hülse 8 kann nach Zündung als ganzes aus dem Patronenmantel ausgestoßen werden, um danach Reizgas auszutreiben.After ignition, the sleeve 8 can be ejected as a whole from the cartridge casing in order to then expel irritant gas.

Figur 2 zeigt in vergrößerter Darstellung das kuchenformartige Behältnis 3 im Schnitt. Es besteht vorzugsweise aus rückstandsfrei verbrennendem Kunststoff und ist mit der erschmolzenen und vergossenen oder pastösen Reizstoffladung 1 gefüllt. Figure 2 shows an enlarged view of the cake-shaped container 3 in section. It preferably consists of plastic that burns without residues and is filled with the melted and cast or pasty irritant charge 1.

Oben auf dem erstarrten Reizgas liegt eine vergossene und erstarrte Schutzschicht 2 aus vorzugsweise Paraffin, wodurch der Reizstoff gasdicht nach außen abgeschlossen ist. Mittig ist die zentrale Öffnung 7 zum Durchzünden freigelassen.On top of the solidified irritant gas there is a cast and solidified protective layer 2, preferably made of paraffin, whereby the irritant is sealed gas-tight to the outside. The central opening 7 is left open for ignition.

Der Rand 10 stützt sich gegen die Innenwandung der Ladungshülse ab.The edge 10 is supported against the inner wall of the charge sleeve.

Anstelle der Isolationsschicht 2 kann auf den Rand 10 - wie strichliert angedeutet - auch eine abdichtende Folie 13 aufgeklebt oder aufgeschweißt sein, wozu der Rand 10 einen ringförmigen Überstand 14 aufweisen und das Mittelteil 12 mit einer Abflachung 15 versehen sein kann, um für das abdichtende Kleben oder Schweißen genügend Fläche zur Verfügung zu stellen.Instead of the insulation layer 2, a sealing film 13 can also be glued or welded onto the edge 10, as indicated by dashed lines, for which purpose the edge 10 has an annular protrusion 14 and the middle part 12 can be provided with a flattened area 15 for sealing purposes or welding to provide enough space.

Claims (6)

  1. Irritant agent cartridge or projectile consisting of a charge shell, possibly a detonating cap, a heating composition, possibly an igniter and an irritant agent, such as chloroacetophenone (CN), chlorobenzylidenemalonic acid dinitrile (CS) or dibenzoxazepin (CR), characterised by the following features
    a) the irritant agent charge (1) is present in separate containers (3) provided with a protective layer (2);
    b) the irritant agent charge (1) consists of a melted or pasty active material introduced into the containers (3) in flowable state;
    c) the containers (3) rest on the heating composition (4) or on the igniter (5) and are covered by a perforated disc (6) and held by means of this in the cartridge or in the projectile.
  2. Irritant agent cartridge according to claim 1, characterised in that several containers (3) are arranged in a circle on the heating composition (4) or the igniter (5).
  3. Irritant agent cartridge according to claim 1, characterised in that the container (3) has the form of a cake mould and preferably possesses as ignition canal an opening (7) in the middle just like the perforated disc.
  4. Irritant agent cartridge according to at least one of claims 1 to 3, characterised in that the containers (3) consist of plastic or metal.
  5. Irritant agent cartridge according to at least one of claims 1 to 4, characterised in that the protective layer (2) consists of inhibitor, preferably of paraffin, or is a foil seal.
  6. Irritant agent cartridge according to at least one of claims 1 to 5, characterised in that the cartridge casing (8) is crimped above the perforated disc (6), whereby the crimping (9) lies on the perforated disc (6) and holds the pyrotechnical composition in press fit.
EP92100493A 1991-02-14 1992-01-14 Irritant agent cartridge or projectile with moulded on irritant agent charge in paste Expired - Lifetime EP0499033B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT9292100493T ATE105629T1 (en) 1991-02-14 1992-01-14 IRRITANT CARTRIDGE OR CASTING BODY WITH POURED RESP. PASTOUS IRRITANT LOAD.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4104427 1991-02-14
DE4104427A DE4104427A1 (en) 1991-02-14 1991-02-14 LUBRICANT CARTRIDGE OR THROWING BODY WITH PILLED OR. PASTOESER LIQUID LOAD

Publications (2)

Publication Number Publication Date
EP0499033A1 EP0499033A1 (en) 1992-08-19
EP0499033B1 true EP0499033B1 (en) 1994-05-11

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EP92100493A Expired - Lifetime EP0499033B1 (en) 1991-02-14 1992-01-14 Irritant agent cartridge or projectile with moulded on irritant agent charge in paste

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EP (1) EP0499033B1 (en)
AT (1) ATE105629T1 (en)
DE (2) DE4104427A1 (en)
ES (1) ES2055620T3 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU728433B2 (en) * 1993-11-23 2001-01-11 Regents Of The University Of California, The Abundant extracellular products and methods for their production and use
DE19601458A1 (en) * 1996-01-17 1997-07-24 Loh Kg Rittal Werk Device to make electrical contact with mounting plate in switching cubicle
FR2746179B1 (en) * 1996-03-15 1998-06-05 PROJECTILE FOR AMMUNITION OF LARGE-CALIBER FIREARMS
FR2800867B1 (en) * 1999-11-09 2002-10-31 Manurhin Defense CARTRIDGE FOR SPRAYING A LIQUID, METHOD AND TOOLS FOR MOUNTING SUCH A CARTRIDGE

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2505480B1 (en) * 1981-05-11 1985-12-27 Poudres & Explosifs Ste Nale INTERVENTION GRENADE WITH LOW IGNITION CHARGE
DE3617888A1 (en) * 1986-05-28 1987-12-03 Dynamit Nobel Ag CARTRIDGE OR THROWING BODY

Also Published As

Publication number Publication date
ATE105629T1 (en) 1994-05-15
ES2055620T3 (en) 1994-08-16
DE59200154D1 (en) 1994-06-16
EP0499033A1 (en) 1992-08-19
DE4104427A1 (en) 1992-08-20

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