EP0490949B1 - Metall-kunststoffverbunde, verfahren zur herstellung sowie ihre verwendung - Google Patents

Metall-kunststoffverbunde, verfahren zur herstellung sowie ihre verwendung Download PDF

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Publication number
EP0490949B1
EP0490949B1 EP90913480A EP90913480A EP0490949B1 EP 0490949 B1 EP0490949 B1 EP 0490949B1 EP 90913480 A EP90913480 A EP 90913480A EP 90913480 A EP90913480 A EP 90913480A EP 0490949 B1 EP0490949 B1 EP 0490949B1
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EP
European Patent Office
Prior art keywords
composite film
adhesion
thermoplastic composite
thermoplastic
layer
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EP90913480A
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German (de)
English (en)
French (fr)
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EP0490949A1 (de
Inventor
Hans-Henning Hub
Siegfried Krause
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BASF Farben und Fasern AG
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BASF Lacke und Farben AG
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34—Auxiliary operations
    • B29C44/56—After-treatment of articles, e.g. for altering the shape
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/026—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing of layered or coated substantially flat surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/68—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
    • B29C70/74—Moulding material on a relatively small portion of the preformed part, e.g. outsert moulding
    • B29C70/747—Applying material, e.g. foam, only in a limited number of places or in a pattern, e.g. to create a decorative effect
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles

Definitions

  • the present invention relates to a metal sheet with a laminated thermoplastic film, the film having a repeating pattern of thickenings.
  • the invention also relates to processes for the production of the metal sheets, the thermoplastic composite films used for coating the metal sheets, and the use of the coated metal sheets for the production of packaging containers and of closure parts for packaging containers.
  • sheets of tinplate, chromated steel such as ECCS (electrolytic chromium-coated steel) and aluminum are coated in sheet or strip form.
  • the lacquer layer acts as a protective layer to protect the metal against attack by the filling material and the resulting corrosion on the one hand and to influence it on the other to prevent the filling material from corrosion products of the metal.
  • the lacquer layer itself for example by detached lacquer components, must not influence or impair the contents, neither during the sterilization of the contents after filling, nor during the subsequent storage of the packed goods, especially food.
  • the lacquers must be constructed in such a way that they withstand the mechanical stresses that occur during the further processing of the coated sheets into cans or closures, for example during shaping, punching, flanging, beads, and the like. the sheets, withstand.
  • a sealing material is additionally required to ensure the tightness either between the metal parts or between metal and glass or similar. to manufacture.
  • This sealing function is generated by applying a sealing compound to the coated and already deformed packaging parts (bases, lids, closures) and gelling or drying the sealing compound at elevated temperatures.
  • lids and bottoms of cans and closures are associated with a high expenditure of energy, since lacquer and sealant are baked separately. Due to the high number of lids, bottoms and closures manufactured, this additional process step also represents a considerable cost factor.
  • Foil coating of metal sheets has proven to be an advantageous method for coating metal sheets, which are used in particular for the production of food packaging.
  • DE-A-3128641 describes a process for the production of laminates for food packaging in which the metal sheet and a thermoplastic resin film, together with an adhesive arranged between these layers, are heated to temperatures above the melting point of the adhesive and based on a carboxyl group-containing polyolefin then cooled together using pressure, thereby producing the metal-plastic composite.
  • the sealing compound In the manufacture of lids and bottoms as well as closure parts, the sealing compound must also be introduced into the preformed lids and bottoms in a further process step and cured.
  • laminates and food packaging containers, in particular bags, made from these laminates are also known from DE-A-2912023, GB-A-2027391 and EP-B-31701. However, the use of these laminates for the production of closure parts for packaging containers is not described.
  • EP-B-167775 describes a method and a device for the continuous production of objects or coatings with complexly shaped contours, for example for retreading car tires, in which a liquid material between at least two moving, endless, shaping Surfaces are introduced and hardened.
  • a liquid material between at least two moving, endless, shaping Surfaces are introduced and hardened.
  • thermoplastic composite films or the use of the method for producing metal sheets for use as closure parts of packaging containers is not described.
  • US Pat. No. 3,265,785 describes a method for producing closure parts of packaging containers, in which a foamable vinyl resin plastisol is added to the already deformed closure part as a sealing compound and is deformed in such a way that the plastisol layer forms an annular ("O-ring") has bead-like thickening.
  • the plastisol is heated to a sufficiently high temperature before, during or after the shaping in order to decompose the foaming agent contained in the plastisol.
  • DE-A-19 03 783 describes a method for coating substrates with a thermoplastic film, the thermoplastic film having a preselected profile of zones of different thicknesses. This process is used to produce coated box or carton blanks that are used for packaging liquids, such as. As milk or juice can be used. These coated box or cardboard blanks have an increased layer thickness in the area of the sealing or weld seams in order to be able to be made leakproof.
  • the present invention was therefore based on the object of providing coated metal sheets which are suitable for use as packaging material.
  • these coated metal sheets as a closure part such. B. can lid, can bottom, valve plate and screw cap the packaging container by means of a be simple and inexpensive to produce, this method should not have the disadvantages of the prior art.
  • these coated sheets should meet the requirements mentioned with regard to mechanical properties and with regard to the compatibility and protective effect against the filling goods.
  • thermoplastic composite film consisting of at least one adhesion promoter layer and at least one further thermoplastic layer arranged on the adhesion promoter layer, characterized in that the thermoplastic composite film has annular or disk-shaped bead-like thickenings of the adhesion promoter and / or cover layer and that the bead-like thickenings form a pattern that is repeated both in the transverse and in the longitudinal direction.
  • the present invention also relates to a metal sheet with the laminated thermoplastic composite film, a method for producing the metal sheets according to the invention and the use of the metal sheets according to the invention for the production of packaging containers and closure parts of packaging containers.
  • the advantages of the coated metal sheets according to the invention can be seen essentially in the fact that they are outstanding for the production of closure parts of packaging containers, such as e.g. Lids, bottoms and closures are suitable, it being particularly advantageous that the integrated sealing function of the coated metal sheets eliminates the process step of introducing a sealing compound that is otherwise required in the manufacture of closure parts.
  • the packaging containers can therefore be produced using a simple and, above all, inexpensive process.
  • Suitable for producing the coated metal sheets according to the invention are sheets with a thickness of 0.04 to 1 mm made of black sheet, tinplate, aluminum and various iron alloys, which are optionally provided with a passivation layer based on nickel, chromium and zinc compounds.
  • metal sheets are coated with one or more, possibly different, resin layers, it being essential to the invention that the coated metal sheet has the bead-shaped thickened portions which take on the sealing function.
  • the metal sheets are obtained by using thermoplastic composite films for coating the metal sheets, which consist of at least one adhesion promoter layer and at least one further thermoplastic layer arranged on the adhesion promoter layer.
  • Thermoplastic top layer of the composite film is the thermoplastic top layer of the composite film.
  • thermoplastic resin films or films used according to the invention as a cover layer include polyolefins, polyamides, polyesters, polyvinyl chloride, polyvinylidene chloride and polycarbonates each in the form of a film or a film. They also include composite films and films (composite films and films) which are obtained, for example, by extruding together at least two of the above-mentioned resins.
  • the preferred thermoplastic film or film, which is the innermost layer (this is the layer in contact with the fillings) of the metal-plastic composites preferably comprises a film or a film made of a polyolefin, polyester or Polyamide.
  • Such foils and films are known and are available in a large number on the market.
  • Such polyolefin films are produced by known processes (blowing process, chill-roll process, etc.) from granules of homopolymers of ethylene and propylene and copolymers.
  • PE-LD Low density polyethylene
  • PE-MD medium density
  • PE-HD high density
  • PE-LLD linear low and linear very low density polyethylene
  • PE-VLD PE-VLD polypropylene
  • polyolefins are commercially available, for example, under the following brand names: Escorene, Lupolen, Lotader, Lacqtene, Orerac, Lucalen, Dowlex, Primacor, Surlyn, Admer, Novatec, Sclair, Stamylan and others
  • polyamides suitable as a cover layer are polyamide 6 (polyamide made from ⁇ -aminocaproic acid), polyamide 6.6 (polyamide made from hexamethylene diamine and sebacic acid), polyamide 66.6 (mixed polyamide consisting of polyamide 6 and polyamide 6.6), Polyamide 11 (polyamide made from ⁇ -aminoundecanoic acid) and polyamide 12 (polyamide made from ⁇ -aminolauric acid or from lauryl lactam). Examples of commercial products are Grilon, Sniamid and Ultramid.
  • Polyesters used with preference are polyethylene terephthalate, polybutylene terephthalate and polyester based on terephthalic acid, ethylene and butylene glycol.
  • polyesters based on terephthalic acid, isophthalic acid and phthalic acid and various polyols such as polyethylene glycol and polytetramethylene glycols with different degrees of polymerization are also suitable.
  • Examples of suitable commercial products are Hostaphan, Melinex and Hostadur.
  • the polymers used as an adhesion promoter layer in the process according to the invention can be both copolymers, terpolymers, graft copolymers and ionomers, with the proviso that they have carboxyl or anhydride groups or groups which can be hydrolyzed to carboxyl groups and that the melt index of the polymers measured at 190 ° C and a load of 2.16 kg is between 0.1 and 30 g / 10 min, preferably between 0.2 and 25 g / 10 min and particularly preferably between 0.5 and 20 g / 10 min.
  • Suitable copolymers or terpolymers can be prepared by copolymerizing ethylene with ⁇ , ⁇ -unsaturated carboxylic acids such as acrylic acid, methacrylic acid, itaconic acid, crotonic acid, isocrotonic acid, maleic acid and fumaric acid, the corresponding anhydrides or the corresponding esters or half-esters with 1 to 8 C- Atoms in the alcohol residue such as the methyl, ethyl, propyl, butyl, pentyl, hexyl, cyclohexyl, heptyl, octyl and 2-ethylhexyl esters of the acids listed.
  • the corresponding salts of the listed carboxylic acids such as the sodium, potassium, lithium, magnesium, calcium, zinc and ammonium salts, can also be used.
  • the carboxylic acids and their anhydrides are preferably used.
  • the amounts of the monomers used are chosen so that the resulting polymer has a carboxyl group content of 0.1 to 30% by weight, preferably 2 to 20% by weight, and that the ethylene unit content in the polymer is between 99.9% by weight. %, preferably between 75 and 95% by weight.
  • Suitable graft copolymers can be prepared by grafting at least one polymer from the group of the polyolefins with up to 10% by weight, preferably up to 5% by weight, based on the total weight of the monomers of at least one monomer from the group of the ⁇ , ⁇ -unsaturated Carboxylic acids, their anhydrides, their esters or salts in the presence or absence of peroxides.
  • suitable polyolefins are the polyolefins already mentioned in the description of the cover layers on page 7 of this description.
  • suitable carbonyl compounds are the carbonyl compounds listed above in the description of the copolymer-based adhesion promoters.
  • the ionomers used as an adhesion promoter layer can be prepared by the copolymerization of ethylene and possibly further monomers with salts ⁇ , ⁇ -unsaturated carboxylic acids already described above or by partial neutralization of the above-described carboxylic acid-containing co-, ter- and graft polymers with salts, oxides and Hyroxides of Sodium, potassium, lithium, magnesium, calcium, zinc and ammonium.
  • the neutralization can be carried out in the melt or in the solution.
  • the amount of basic compound is chosen so that the degree of neutralization of the polymer is between 0.1 and 99%, preferably between 0.1 and 75% and very particularly preferably between 0.1 and 40%.
  • Both the adhesion promoter layer and the thermoplastic top layer can also contain conventional additives such as e.g. contain internal and external lubricants, antiblocking agents, stabilizers, antioxidants, pigments, crystallization aids and the like. These additives are used in the amounts necessary for production, processing, assembly and application in the form of powder, powder, pearls or a concentrate incorporated directly into the corresponding polymer. Further details on the amounts usually used and examples of suitable additives can be found, for example, from Gumbleter-Müller, Kunststoffadditive, Carl-Hanser Verlag. These additives are preferably incorporated into the cover layer.
  • Thermoplastic composite films with a structured surface in which at least one layer consists of a foamed plastic
  • the metal sheet is covered with the described thermoplastic composite film with a structured surface such that the adhesive layer of the composite touches the metal surface.
  • the application of pressure and heat is produced either by means of a temperature-controlled press or in the nip of a rolling mill or calender by means of temperature-controlled rollers of the metal-plastic composite.
  • the pressure and the temperature are to be chosen so that on the one hand the bonding agent forms a firm and stable connection with the metal foil or the metal sheet and on the other hand the thermoplastic cover layer does not melt or lose the embossed structure.
  • thermoplastic composite film directly onto the metal sheet and, following the coextrusion, to directly deform the composite obtained in such a way that the cover layer consisting of the thermoplastic material has bead-like thickenings, which can be found both in the transverse and also form a repeating geometric pattern in the longitudinal direction.
  • the devices used to deform the metal-plastic composites are identical to the devices for producing the composite film with a profiled surface. It is therefore only here on the corresponding points of the present description.
  • sealing compounds can also be applied in the form of laminates to the coated metal sheets which have not yet been deformed into closure parts.
  • the cover layer can also consist of a foamed polymer.
  • the coating of the metal sheet or the thermoplastic composite film generally has a total dry film thickness (without thickening) of less than 500 ⁇ m, preferably 10 to 200 ⁇ m and particularly preferably less than 100 ⁇ m.
  • the thickness of the adhesion promoter layer is between 0.5 and 100 ⁇ m in the case of the composite films.
  • the thickness of the top layer results from values between 10 and 499.5 ⁇ m.
  • thermoplastic composite films can be used which only consist of an adhesion promoter and a cover layer, but composite films of several layers can also be used. In this case, both the different adhesion promoter layers and the different thermoplastic layers can each consist of the same or different material in the same or different layer thickness.
  • the bead-like thickenings of the coated metal sheet that are essential to the invention are ring-shaped or disk-shaped with a regular or irregular circumferential line and have a thickness of at least 2 ⁇ m, preferably at least 5 ⁇ m and very particularly preferably thicknesses of at least 50 ⁇ m in order to achieve good sealing properties.
  • the inside angle of the flank to the film web is 1 to 90 °, preferably 3 to 85 °.
  • the width of the annular bead-like thickenings generally varies between 1 and 20 mm, depending on the intended use of the coated metal sheets, and is preferably between 2 and 10 mm.
  • the coated metal sheets according to the invention are used to produce packaging containers, specifically in particular for the production of bases or lids of cans, valve plates of aerosol cans and closures.
  • the closure parts are produced by the usual methods (cf. for example VR-INTERPACK 1969, pages 600-606: W. Panknin, A. Breuer, M. Sodeik, "ironing as a method for producing cans from tinplate”; SHEET METAL INDUSTRIES , August 1976: W. Panknin, Ch. Schneider, M. Sodeik, "Plastic Deformation of Tinplate in Can Manufacturing”;maschines-Rundschau, Issue 4/1971, pages 450-458: M. Sodeik, I.
  • FIG. 1 shows a section of a structured thermoplastic composite film (1) from a thermoplastic cover layer (2) and an adhesion promoter layer (3), in which the thermoplastic cover layer (2) has the bead-shaped thickenings.
  • a composite film can be produced by the method 1 explained in the present description.
  • Fig. 2 shows a section of a structured thermoplastic composite film (1) from a thermoplastic cover layer (2) and an adhesion promoter layer (3), in which the adhesion promoter layer (3) has the bead-shaped thickenings.
  • a composite film can be produced by the method 2 explained in the present description.
  • Fig. 3 shows a section of a structured thermoplastic composite film (1) from an adhesion promoter layer (3) and a thermoplastic cover layer (4) made of foamed plastic.
  • a composite film can be produced by the method IV explained in the present description.
  • Fig. 4 shows a section of a coated metal sheet with bead-like thickenings (5) of the cover layer (2) in a ring shape in a perspective view. Furthermore, a part punched out of the metal sheet and required for producing a closure part is shown.
  • Fig. 5 shows a section along the line A - B. You can see the metal sheet (6), the adhesion promoter layer (3) and the cover layer (2) with the bead-shaped thickenings (5).
  • the embossing roller is heated to a temperature of 5 to 20 ° C below the melting point of the polyethylene, the smooth pressure roller to 40 ° C below the temperature of the embossing roller. Up to 80% of the circumference of the embossing roller is wrapped in the coextruded film in order to enable optimal heat transfer.
  • the pressure roller has a Teflon or rubber-coated surface to avoid sticking.
  • the embossing roller has annular depressions (0.05 mm deep, 5 mm wide).
  • the contact pressure is 200 N / mm gap length.
  • Melt temperature 180 ° C, coating speed 150 m / min, temperature of the chill roll 5 ° C, thickness of the layer 0.1 mm.
  • the composite HDPE layer is structured by extrusion of the melt (290 ° C, 150 m / min) onto a chill roll (15 ° C) with removable surface parts.
  • the removable parts are 2 mm thick, chrome-plated half-shells in the circular depressions (width 7 mm and 3 mm, depth for film 4 0.15 mm, for film 5 0.1 mm and for film 6 0.01 mm) by spark erosion the chrome plating.
  • the composite consists of 0.1 mm HDPE, 0.02 mm g-LLDPE, 0.05 mm ethylene vinyl alcohol copolymer and 0.03 mm g-LLDPE.
  • a 2.5 mm thick Teflon film was attached to the surface of the chill-roll, which has ring-shaped depressions (0.05 mm deep and 5 mm wide).
  • the polypropylene film extruded on this surface is smoothed by a pressure roller and pulled off after half a wrap of the cylinder.
  • Technically known processes electrical discharge, corona and plasma treatment, flame treatment) pretreat the flat surface of the structured film so that there is a surface tension of 45 to 65 m N / m.
  • the melt temperature is 205 ° C, the coating speed 100 m / min.
  • thermoplastic composite film 8 is produced analogously to the composite film 7, with the only difference from the production of the composite film 7 that the annular depressions of the teflon film of the chill roll now have a depth of 0.03 mm (instead of 0.05 mm).
  • thermoplastic composite film 9 is produced analogously to the composite film 7, with the only difference that the ring-shaped depressions of the teflon film of the chill roll now have a depth of 0.005 mm instead of 0.05 mm.
  • the depressions are filled and a composite film of 0.24 mm thick (0.2 mm polypropylene, 0.04 mm graft copolymer) with 0.08 mm high bead-shaped thickenings on the polypropylene side is obtained.
  • Melt temperature 290 ° C, application thickness 50 g / m2.
  • the melt temperature is 220 ° C.
  • Both melt streams are brought together in the feed block nozzle and extruded on a smooth chill roll (temperature 15 ° C).
  • the 0.2 mm thick film consists of 0.15 mm polyethylene and 0.05 mm copolymer.
  • the film is placed with the copolymer side on a degreased steel sheet (0.3 mm ECCS, electrolytic chromium coated steel, chromed steel).
  • a Teflon film (2 mm thick) with annular depressions is placed on the polyethylene side.
  • the rings have an inside diameter of 54 mm and 59 mm outside with different depths of 0.003, 0.01, 0.05 and 0.1 mm. Prepressed for 1 min at 200 ° C. under a weak pressure of ⁇ 0.5 kg / cm2, then for 3 min at a pressure of 5 kg / cm2 and then cooled to room temperature under pressure.
  • the thickness distribution of the composite film is 0.20 mm polyethylene to 0.05 mm copolymer. The copolymer adheres to 0.2 mm tinplate E 5.6 / 5.6 with 69 N / 15 mm.
  • Table 2 The results of further adhesion tests of the adhesion promoter layer on other substrates are shown in Table 2.
  • the embossing roller has regular circular depressions 5 mm wide and 0.01 mm deep.
  • the temperature of the preheating roller of the film is 80 ° C, that of the embossing roller and pressure roller is 15 ° C.
  • the sheet metal is preheated to 150 ° C.
  • the composite consists of 0.01 mm polyester and 0.07 mm terpolymer.
  • this film is placed with the copolymer side on a degreased steel sheet (0.2 mm TFS).
  • a steel plate (0.2 mm thick) provided with annular depressions is placed on the polyester side.
  • the rings have an inside diameter of 25 mm and 32 mm outside with different depths of 0.01 and 0.05 mm. Prepressed for 1 min at 250 ° C. under a weak pressure of ⁇ 0.5 kg / cm2, then for 3 min at a pressure of 5 kg / cm2 and then cooled to room temperature under pressure. The ring-shaped depressions are completely filled. The results of various liability tests are shown in Tables 1 and 2.
  • a 35 cm wide metal strip is heated to a temperature between the melting temperature of the bonding agent and 250 ° C (for the respective temperatures see also Tables 1 and 2) by suitable methods (HF heating, gas flames, etc.), with the bonding agent side of a 35 cm wide one Partial web of the composite foils 1 to 11 occupied and connected to a metal-plastic laminate between the rollers of a stamping mill.
  • the pressure roller is rubberized and the contact pressure ( ⁇ 50 N contact force per mm gap length) selected so that the Decrease in the height of the structures is less than 10% of the original height.
  • a peeling test based on ASTM D 1876 was carried out on some selected composites. The test results are shown in Tables 1 and 2.
  • a 35 cm wide metal strip is coated with the adhesion promoter side of a 35 cm wide partial web of the composite films 1 to 11, the metal side by suitable methods (HF heating, gas flames, etc.) to a temperature higher than the melting point of the adhesion promoter (for the respective temperatures see. Table 1) heated and this laminate pressed between a smooth metal roller and a rubber roller (structured polymer side) of an embossing mill to a metal-plastic laminate. The pressure force is adjusted so that the reduction in the height of the structures is less than 10% of the original height.
  • a peeling test based on ASTM D 1876 was also carried out for some selected composites. The test results are shown in Tables 1 and 2.
  • a 35 cm wide metal strip is heated to a temperature ⁇ 300 ° C (for the respective temperature see Table 1) by suitable methods (HF heating, gas flames, etc.) and one of the composite films 1 to 11 is added to the adhesion promoter side in the nip of a stamping mill a metal-plastic laminate.
  • the pressure roller is rubberized and the contact pressure ( ⁇ 100 N Contact force per mm gap length) selected so that the reduction in the height of the structures is less than 10% of the original height.
  • a peeling test based on ASTM D 1876 was also carried out for some selected composites. The test results are shown in Tables 1 and 2.
  • Coated metal sheets are made using the thermoplastic composite sheet 12 using method b. Some peelings also carried out a peel test based on ASTM 1876. The test results are shown in Tables 1 and 2.
  • Tin can lids were punched out of the plastic-metal composites of Examples 15, 19, 20 and 21 produced by method a-c and their suitability for use as tin can material was checked in a short test.
  • the test shows good resistance to the usual test solutions (lactic acid, acetic acid, saline, H2O) at sterilization conditions of 121 ° C for 30 min.
  • a cup with a diameter of 33 mm and a height of 25 mm was drawn from the composite of Examples 6, 17 and 28 produced in process A-C and then stored in isopropanol, xylene, solvent naphtha 100, solvent, naphtha 150. Before the start and after 72 hours, the liability was checked with a Tesatest. No reduction in liability was found.
  • Beverage cans shells were punched from the composites of Examples 4 and 38. These were sterilized for 30 min at 78 ° C and 100 ° C in water. The test shows that the bond is completely stable (no water absorption, no loss of adhesion).

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Laminated Bodies (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
EP90913480A 1989-09-08 1990-08-18 Metall-kunststoffverbunde, verfahren zur herstellung sowie ihre verwendung Expired - Lifetime EP0490949B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3929942A DE3929942A1 (de) 1989-09-08 1989-09-08 Metallkunststoffverbunde mit profilierter oberflaeche, verfahren zur herstellung sowie die verwendung der verbunde zur herstellung von verpackungsbehaeltern
DE3929942 1989-09-08

Publications (2)

Publication Number Publication Date
EP0490949A1 EP0490949A1 (de) 1992-06-24
EP0490949B1 true EP0490949B1 (de) 1993-10-27

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EP (1) EP0490949B1 (pt)
AT (1) ATE96376T1 (pt)
CA (1) CA2065426A1 (pt)
DE (2) DE3929942A1 (pt)
DK (1) DK0490949T3 (pt)
ES (1) ES2047341T3 (pt)
IE (1) IE63937B1 (pt)
NO (1) NO178722C (pt)
PT (1) PT95238B (pt)
WO (1) WO1991003373A1 (pt)
YU (1) YU47086B (pt)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4229419A1 (de) * 1992-09-03 1994-03-10 Basf Lacke & Farben Polypropylenfolie - Haftvermittler - Metall-Verbund sowie dessen Verwendung zur Herstellung von Verpackungsbehältern
US5888599A (en) * 1993-04-19 1999-03-30 E. I. Du Pont De Nemours And Company Multi-layer lidding film having improved heat seal properties and methods relating thereto
DE19924604B4 (de) * 1999-05-28 2005-06-30 Faist Automotive Gmbh & Co. Kg Verfahren zur Herstellung eines dreidimensionalen Formkörpers
DE102005015340B4 (de) * 2005-04-01 2011-11-17 Jowat Ag Verfahren zur Herstellung von mit einer Bedruckung oder einem Dekorversehenen Formkörpern und auf diese Weise hergestellte Formkörper
DE102009003683B4 (de) 2009-03-26 2011-03-24 Hydro Aluminium Deutschland Gmbh Verfahren zur Herstellung eines beschichteten Aluminiumbandes, Aluminiumband und dessen Verwendung

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3265785A (en) * 1964-07-31 1966-08-09 Chemical Products Corp Method of molding a foamed plastic sealing liner having a transparent central portion
GB1231144A (pt) * 1968-01-26 1971-05-12

Also Published As

Publication number Publication date
YU47086B (sh) 1994-12-28
ES2047341T3 (es) 1994-02-16
IE63937B1 (en) 1995-06-28
DK0490949T3 (da) 1994-03-21
DE3929942A1 (de) 1991-03-21
DE59003269D1 (de) 1993-12-02
WO1991003373A1 (de) 1991-03-21
PT95238A (pt) 1991-05-22
NO920891D0 (no) 1992-03-06
ATE96376T1 (de) 1993-11-15
EP0490949A1 (de) 1992-06-24
PT95238B (pt) 1997-09-30
NO178722B (no) 1996-02-12
IE903185A1 (en) 1991-03-13
NO920891L (no) 1992-03-06
NO178722C (no) 1996-05-22
CA2065426A1 (en) 1991-03-09
YU169890A (sh) 1992-12-21

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