EP0467481A2 - Package containing a powdered detergent - Google Patents
Package containing a powdered detergent Download PDFInfo
- Publication number
- EP0467481A2 EP0467481A2 EP91201897A EP91201897A EP0467481A2 EP 0467481 A2 EP0467481 A2 EP 0467481A2 EP 91201897 A EP91201897 A EP 91201897A EP 91201897 A EP91201897 A EP 91201897A EP 0467481 A2 EP0467481 A2 EP 0467481A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- package
- detergent
- powdered detergent
- foil
- agglomerates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/18—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient
- B65D81/20—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas
- B65D81/2007—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas under vacuum
- B65D81/2023—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents providing specific environment for contents, e.g. temperature above or below ambient under vacuum or superatmospheric pressure, or in a special atmosphere, e.g. of inert gas under vacuum in a flexible container
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
Definitions
- This invention relates to a package containing a powdered detergent, more particularly to a gas and/or vapour tight package.
- powdered detergents have always been packed as loose powder, i.e. the contents of the package were, at least partly, filled with air. Also because of the low density of powdered detergents, such packages occupy a large volume.
- One object of the invention is to provide a package containing a powdered detergent which occupies little volume, without necessarily using the high-density formulation for the powdered detergent.
- the invention relates to a package containing a powdered detergent, which is characterized in that the powdered detergent is packed in compressed form in a gas and/or vapour tight foil.
- the invention basically comprises three variants of packaging detergents utilizing compression, namely under vacuum, in a shrink-foil or under external overpressure.
- the detergent is compressed, so that it occupies a minimal volume and does not set during storage and transport.
- the detergent is packaged under vacuum, which means that a vacuum is produced after filling of the package, so that the powder is compressed after the package has been closed.
- This system has long been known for the packaging of ground coffee.
- a requirement for this variant is that the foil should be reasonably gas tight.
- an underpressure of 0.1 to 0.9 bar is used in this package.
- a shrink-foil is used.
- the powder is packaged in a foil, which is heated after packaging and then shrinks, thereby compressing the powder.
- the package can be sealed hermetically. However, this is not necessary.
- the third variant of the invention comprises packaging the powder under pressure.
- a particular requirement for the package in this variant is that it must be resistant to the forces generated as a result of the pressure applied.
- the overpressure employed preferably ranges from 0.5 to 15 bar.
- a surprising advantage of the invention is that for packaging, relatively inexpensive, and often environment-friendly, materials can be used, such as paper or synthetic foils, for example surlyn foil, polypropylene foil or polyethylene foil, optionally coated and/or laminated with a lacquer, nylon, polyester or aluminum.
- the invention can be used for all types of powdered detergents.
- the powdered detergent preferably consists of agglomerates which are composed of a core, in which the more hygroscopic ingredients are located, and a shell, in which the less hygroscopic ingredients are located.
- the present invention also relates to a powdered detergent which is suitable for use in compressed form, as defined according to the invention.
- Such a powdered detergent consists of agglomerates having a core, in which the more hygroscopic ingredients are located, and a shell, in which the less hygroscopic ingredients are located.
- detergent-active agents and bleaching agents are located in the core, while bicarbonate is incorporated in the shell.
- the shell can also contain a metal soap.
- the proportions of the amounts of the core and the shell can vary within broad limits. These proportions also depend strongly on the composition of the detergent. In general, the core constitutes about 20-80% by weight of the total detergent and the shell about 20-80% by weight.
- the detergent consists of
- the detergent agents used are preferably anionic or non-ionic detergents, such as fatty alcohol ethoxylate and/or sodium dodecyl benzene sulfonate. More particularly, fatty alcohol ethoxylate and sodium dodecyl benzene sulfonate are used in equal amounts by weight.
- a bleaching agent preferably sodium perbonate is used, preferably with 4 molecules of water of crystallization, although the modification with one molecule of water of crystallization can also be used.
- supplementary additives may be used as well, as is conventional for powdered detergents of the present type.
- supplementary additives are colourings, optical whitening agents, perfume, enzymes and the like.
- the invention also relates to a method for preparing such a powdered detergent, which comprises agglomerating a part of the components of the detergent to form primary agglomerates, followed by agglomerating said primary agglomerates with the remaining component(s).
- the more hygroscopic components are agglomerated to form primary agglomerates, whereupon these primary agglomerates are agglomerated with the less hygroscopic components.
- This method can be carried out in the conventional apparatus for powdered detergents, using the conventional conditions.
- Example 1 An enzymatic soaking detergent
- the dose for I is 90 g detergent for a normal washing machine load that is to be soaked.
- the dose for II is 130 grams.
- the sodium sulfate together with half the amount of the sodium carbonate is initially present.
- the product formed is stored in a closed vessel in a room of low humidity.
- the temperature of the room is 15° C and the humidity is less than 40%.
- the cooled product is finally packaged in a vacuum-packaging machine in an externally lacquered polyethylene foil package, formed in the machine.
- Example 2 An enzymatic prewash detergent
- the dose for I is 60 g detergent for a normal washing machine load that is to be soaked.
- the dose for II is 87 g.
- the total amount of B and half the amount of A is applied to a fluid bed apparatus. Added thereto is the mixture of D and E in a melted state, so finely divided and so slowly that a pulpy, granular product is obtained. During the subsequent cooling period, C is added first, and then the enzyme granulates and the residue of A and the minors are admixed.
- the sodium sulfate together with half of the amount of the sodium carbonate is initially present.
- the product formed is cooled in a closed vessel in a room of low humidity.
- the temperature of the room is 15° C and the humidity is less than 40%.
- the cooled product is finally packaged in a vacuum-packaging machine in a package that is formed in the machine from a polyethylene foil coated with aluminum.
- Example 3 An enzymatic soaking detergent
- the dose for I is 90 grams of detergent for a normal washing machine load to be soaked.
- the dose for II is 130 grams.
- Half of the amount of A and the total amount of B are initially present in a Z-blade mixer of sufficient capacity, after which C and D are successively added. After C, D and F have been added, E, heated to about 90 C, is added so slowly that a product of the desired grain size is obtained. After cooling, the minors are added first, followed by the enzyme granulates and, finally, the residue of A.
- the sodium sulfate together with half of the amount of the sodium carbonate is initially present.
- the product formed is stored in a closed vessel in a room of low humidity.
- the temperature of the room is 15° C and the humidity is 40%.
- the finished product is finally packed in a vacuum-packaging machine in an externally lacquered polyethylene foil package, which is formed in the machine.
- the dose for II is 87 grams.
- B together with half of the amount of A is intially present in a Z-blade mixer of sufficient capacity, after which C and D are successively added.
- E heated to about 90 C, is added so slowly that a product of the desired grain size is obtained.
- the minors are added, followed by the enzyme granulates and finally B.
- the sodium sulfate together with half of the amount of the sodium bicarbonate and the soda is initially present.
- the product formed is stored in a closed vessel in a room of low humidity.
- the temperature of the room is 15° C and the humidity is 40%.
- the finished product is finally packed in a vacuum-packaging machine in an externally lacquered polyethylene foil package, formed in the machine.
- Example 5 An enzymatic main wash detergent
- the dose is 90 grams of detergent for a normal washing machine (taking in 18 liters of water for washing).
- A is initially present in a Z-blade mixer of sufficient capacity, after which B, D, and C are successively added. Subsequently, E is heated to about 90 C and sprayed on so slowly that a product of the desired grain size is obtained. After cooling, first the minors are added, followed by the enzyme granulates and finally F.
- the product formed is stored in a closed vessel in a room of low humidity.
- the temperature of the room is 15° C and the humidity is 40%.
- the finished product is finally packed in a vacuum-packaging machine in an externally lacquered polyethylene foil package, formed in the machine.
- Example 6 An enzymatic main wash detergent
- the dose is 90 grams of detergent for a normal washing machine (taking in 18 liters of water for washing).
- A is initially present in a Z-blade mixer of sufficient capacity, after which C and D are successively added. Subsequently, E, heated to about 90 C, is sprayed onto the prepared powder mixture, so slowly that a product of the desired grain size is obtained. After cooling, the minors are added first, followed by the enzyme granulates and, finally, B and F.
- the product formed is stored in a closed vessel in a room of low humidity.
- the temperature of the room is 15° C and the humidity is less than 40%.
- the finished product is finally packed in a vacuum-packaging machine in an externally lacquered polyethylene foil package, formed in the machine.
- Example 7 A concentrated, enzymatic main wash detergent for lower temperatures. The new method is also very useful in this modern trend in the detergent industry.
- the dose is 45 grams of detergent for a normal washing machine (taking in 18 liters of water for washing).
- F is initially present in a fluid bed of sufficient capacity, after which A, C, D, and E are successively added. Subsequently, B, heated to about 90 C, is added so slowly that a product of the desired grain size is obtained. After cooling, the minors are added first, and finally the enzyme granulates.
- the product formed is stored in a closed vessel in a room of low humidity.
- the temperature of the room is 15° C and the humidity is about 40%.
- the finished product is finally packed in a vacuum-packaging machine in a package of externally lacquered polyethylene foil, formed in the machine.
- Example 8 A concentrated, enzymatic main wash detergent for lower temperatures. The new method is also eminently useful in this modern trend in the detergent industry. Also for a less conventional composition.
- the dose is 45 grams of detergent for a normal washing machine (taking in 18 liters of water for washing).
- F is initially present in a fluid bed of sufficient capacity, after which A, C, D, and E are successively added. Subsequently, B, heated to about 90 C, is added so slowly that a product of the desired grain size is obtained. After cooling, the minors are added first, and finally the enzyme granulates.
- the product formed is stored in a closed vessel in a room of low humidity.
- the temperature of the room is 15° C and the humidity is about 40%.
- the finished product is finally packed in a vacuum-packaging machine in an externally lacquered polyethylene foil package, formed in the machine.
Abstract
Description
- This invention relates to a package containing a powdered detergent, more particularly to a gas and/or vapour tight package.
- Heretofore, powdered detergents have always been packed as loose powder, i.e. the contents of the package were, at least partly, filled with air. Also because of the low density of powdered detergents, such packages occupy a large volume.
- A recent development in the field of powdered detergents concerns detergents of high density. By omitting fillers and other less active components, a detergent with a high concentration of detergent-active components is obtained, so that less volume and weight are required to achieve the same detergency. Thus, a saving of volume has already been achieved.
- One object of the invention is to provide a package containing a powdered detergent which occupies little volume, without necessarily using the high-density formulation for the powdered detergent.
- The invention relates to a package containing a powdered detergent, which is characterized in that the powdered detergent is packed in compressed form in a gas and/or vapour tight foil.
- Surprisingly, it has been found that it is possible to package a powder detergent in compressed form without problems arising that involve its stability or its caking into large lumps.
- The invention basically comprises three variants of packaging detergents utilizing compression, namely under vacuum, in a shrink-foil or under external overpressure.
- In all of these cases the detergent is compressed, so that it occupies a minimal volume and does not set during storage and transport.
- According to the first variant of the invention, the detergent is packaged under vacuum, which means that a vacuum is produced after filling of the package, so that the powder is compressed after the package has been closed. This system has long been known for the packaging of ground coffee. A requirement for this variant is that the foil should be reasonably gas tight. Preferably, an underpressure of 0.1 to 0.9 bar is used in this package.
- In the second variant of the invention, a shrink-foil is used. The powder is packaged in a foil, which is heated after packaging and then shrinks, thereby compressing the powder. Optionally, after shrinking, the package can be sealed hermetically. However, this is not necessary.
- The third variant of the invention comprises packaging the powder under pressure. In practice, this means that the powder is put in the package and, subsequently, the assembly is placed under external pressure and sealed, or an overpressure is created during packaging. A particular requirement for the package in this variant is that it must be resistant to the forces generated as a result of the pressure applied. The overpressure employed preferably ranges from 0.5 to 15 bar.
- A surprising advantage of the invention is that for packaging, relatively inexpensive, and often environment-friendly, materials can be used, such as paper or synthetic foils, for example surlyn foil, polypropylene foil or polyethylene foil, optionally coated and/or laminated with a lacquer, nylon, polyester or aluminum.
- In principle, the invention can be used for all types of powdered detergents. In view of storage stability and caking tendencies, however, it is preferred to use an adapted formulation. In this formulation the powdered detergent preferably consists of agglomerates which are composed of a core, in which the more hygroscopic ingredients are located, and a shell, in which the less hygroscopic ingredients are located.
- The present invention also relates to a powdered detergent which is suitable for use in compressed form, as defined according to the invention.
- Such a powdered detergent consists of agglomerates having a core, in which the more hygroscopic ingredients are located, and a shell, in which the less hygroscopic ingredients are located.
- More particularly, detergent-active agents and bleaching agents are located in the core, while bicarbonate is incorporated in the shell. The shell can also contain a metal soap.
- The proportions of the amounts of the core and the shell can vary within broad limits. These proportions also depend strongly on the composition of the detergent. In general, the core constitutes about 20-80% by weight of the total detergent and the shell about 20-80% by weight.
-
- The detergent agents used are preferably anionic or non-ionic detergents, such as fatty alcohol ethoxylate and/or sodium dodecyl benzene sulfonate. More particularly, fatty alcohol ethoxylate and sodium dodecyl benzene sulfonate are used in equal amounts by weight. As a bleaching agent, preferably sodium perbonate is used, preferably with 4 molecules of water of crystallization, although the modification with one molecule of water of crystallization can also be used.
- Within the scope of the present invention, supplementary additives may be used as well, as is conventional for powdered detergents of the present type. Examples are colourings, optical whitening agents, perfume, enzymes and the like.
- The invention also relates to a method for preparing such a powdered detergent, which comprises agglomerating a part of the components of the detergent to form primary agglomerates, followed by agglomerating said primary agglomerates with the remaining component(s).
- First, the more hygroscopic components are agglomerated to form primary agglomerates, whereupon these primary agglomerates are agglomerated with the less hygroscopic components.
- This method can be carried out in the conventional apparatus for powdered detergents, using the conventional conditions.
- The invention is explained in and by the following examples, which are not intended to limit the application.
-
- The dose for I is 90 g detergent for a normal washing machine load that is to be soaked. The dose for II is 130 grams.
- Half of the amount of A is applied to a fluid bed apparatus. Added thereto is the mixture of C and D in melted state, so finely divided and so slowly that a pulpy, granular product is obtained. During the subsequent cooling period, B is added first, and then the enzyme granulates and the rest of A and the minors are admixed.
- For formulation II, the sodium sulfate together with half the amount of the sodium carbonate is initially present.
- After cooling, the product formed is stored in a closed vessel in a room of low humidity. The temperature of the room is 15° C and the humidity is less than 40%. The cooled product is finally packaged in a vacuum-packaging machine in an externally lacquered polyethylene foil package, formed in the machine.
- After three months of storage under severe conditions - 30°C and 80% relative humidity - the activity of the enzymes in the vacuum-packed product has remained constant within the margin of measurement error, while the enzyme activity in the normally packed product has decreased by well over 10%. The vacuum-packed powder is reasonably free-flowing, while the normally packed product has coagulated into a lump. This applies to both the new formulation I and the 'old' formulation II with sodium sulfate.
-
- The dose for I is 60 g detergent for a normal washing machine load that is to be soaked. The dose for II is 87 g.
- The total amount of B and half the amount of A is applied to a fluid bed apparatus. Added thereto is the mixture of D and E in a melted state, so finely divided and so slowly that a pulpy, granular product is obtained. During the subsequent cooling period, C is added first, and then the enzyme granulates and the residue of A and the minors are admixed.
- For formulation II, the sodium sulfate together with half of the amount of the sodium carbonate is initially present.
- After cooling, the product formed is cooled in a closed vessel in a room of low humidity. The temperature of the room is 15° C and the humidity is less than 40%. The cooled product is finally packaged in a vacuum-packaging machine in a package that is formed in the machine from a polyethylene foil coated with aluminum.
- After three months of storage under severe conditions - 30°C and 80% relative humidity - the activity of the enzymes in the vacuum-packed product has remained constant within the margin of measurement error, while the enzyme activity in the normally packed product has decreased by well over 10%. The vacuum-packed powder is reasonably free-flowing, while the normally packed product has coagulated into a lump. This applies to both the new formulation I and the 'old' formulation II with sodium sulfate.
-
- The dose for I is 90 grams of detergent for a normal washing machine load to be soaked. The dose for II is 130 grams.
- Half of the amount of A and the total amount of B are initially present in a Z-blade mixer of sufficient capacity, after which C and D are successively added. After C, D and F have been added, E, heated to about 90 C, is added so slowly that a product of the desired grain size is obtained. After cooling, the minors are added first, followed by the enzyme granulates and, finally, the residue of A.
- For formulation II, the sodium sulfate together with half of the amount of the sodium carbonate is initially present. The product formed is stored in a closed vessel in a room of low humidity. The temperature of the room is 15° C and the humidity is 40%. The finished product is finally packed in a vacuum-packaging machine in an externally lacquered polyethylene foil package, which is formed in the machine.
- After three months of storage under severe conditions - 30°C and 80% relative humidity - the activity of the enzymes in the vacuum-packed product has remained constant within the margin of measurement error, while the enzyme activity in the normally packed product has decreased by well over 10%. The vacuum-packed powder is reasonably free-flowing, while the normally packed product has coagulated into a lump. This applies to both the new formulation I and the 'old' formulation II with sodium sulfate.
-
- The dose for II is 87 grams.
- B together with half of the amount of A is intially present in a Z-blade mixer of sufficient capacity, after which C and D are successively added. After this addition, E, heated to about 90 C, is added so slowly that a product of the desired grain size is obtained. After cooling, first the minors are added, followed by the enzyme granulates and finally B.
- For formulation II, the sodium sulfate together with half of the amount of the sodium bicarbonate and the soda is initially present.
- The product formed is stored in a closed vessel in a room of low humidity. The temperature of the room is 15° C and the humidity is 40%. The finished product is finally packed in a vacuum-packaging machine in an externally lacquered polyethylene foil package, formed in the machine.
- After three months of storage under severe conditions - 30°C and 80% relative humidity - the activity of the enzymes in the vacuum-packed product has remained constant within the margin of measurement error, while the enzyme activity in the normally packed product has decreased by well over 10%. The vacuum-packed powder is reasonably free-flowing, while the normally packed product has coagulated into a lump. This applies to both the new formulation I and the 'old' formulation II with sodium sulfate.
-
- The dose is 90 grams of detergent for a normal washing machine (taking in 18 liters of water for washing).
- A is initially present in a Z-blade mixer of sufficient capacity, after which B, D, and C are successively added. Subsequently, E is heated to about 90 C and sprayed on so slowly that a product of the desired grain size is obtained. After cooling, first the minors are added, followed by the enzyme granulates and finally F.
- The product formed is stored in a closed vessel in a room of low humidity. The temperature of the room is 15° C and the humidity is 40%. The finished product is finally packed in a vacuum-packaging machine in an externally lacquered polyethylene foil package, formed in the machine.
- After three months of storage under severe conditions - 30° C and 80% relative humidity - the hydrogen peroxide content and the activity of the enzymes in the vacuum-packed product have remained constant within the margin of measurement error, while they have practically disappeared from the normally packed product. The vacuum-packed powder is reasonably free-flowing, while the normally packed product has coagulated into a lump.
-
- The dose is 90 grams of detergent for a normal washing machine (taking in 18 liters of water for washing).
- A is initially present in a Z-blade mixer of sufficient capacity, after which C and D are successively added. Subsequently, E, heated to about 90 C, is sprayed onto the prepared powder mixture, so slowly that a product of the desired grain size is obtained. After cooling, the minors are added first, followed by the enzyme granulates and, finally, B and F.
- The product formed is stored in a closed vessel in a room of low humidity. The temperature of the room is 15° C and the humidity is less than 40%. The finished product is finally packed in a vacuum-packaging machine in an externally lacquered polyethylene foil package, formed in the machine.
- After three months of storage under severe conditions - 30° C and 80% relative humidity - the hydrogen peroxide content and the activity of the enzymes in the vacuum-packed product have remained constant within the margin of measurement error, while they have practically disappeared from the normally packed product. The vacuum-packed powder is reasonably free-flowing, while the normally packed product has coagulated into a lump.
-
- The dose is 45 grams of detergent for a normal washing machine (taking in 18 liters of water for washing).
- F is initially present in a fluid bed of sufficient capacity, after which A, C, D, and E are successively added. Subsequently, B, heated to about 90 C, is added so slowly that a product of the desired grain size is obtained. After cooling, the minors are added first, and finally the enzyme granulates.
- The product formed is stored in a closed vessel in a room of low humidity. The temperature of the room is 15° C and the humidity is about 40%. The finished product is finally packed in a vacuum-packaging machine in a package of externally lacquered polyethylene foil, formed in the machine.
- After three months of storage under severe conditions - 30 C and 80% relative humidity - the hydrogen peroxide content and the activity of the enzymes in the vacuum-packed product have remained constant within the margin of measurement error, while they have largely disappeared from the normally packed product. The vacuum-packed powder is reasonably free-flowing, while the normally packed product has coagulated into a lump.
- Example 8: A concentrated, enzymatic main wash detergent for lower temperatures. The new method is also eminently useful in this modern trend in the detergent industry. Also for a less conventional composition.
-
- F is initially present in a fluid bed of sufficient capacity, after which A, C, D, and E are successively added. Subsequently, B, heated to about 90 C, is added so slowly that a product of the desired grain size is obtained. After cooling, the minors are added first, and finally the enzyme granulates.
- The product formed is stored in a closed vessel in a room of low humidity. The temperature of the room is 15° C and the humidity is about 40%. The finished product is finally packed in a vacuum-packaging machine in an externally lacquered polyethylene foil package, formed in the machine.
- After three months of storage under severe conditions - 30 C and 80% relative humidity - the hydrogen peroxide content and the activity of the enzymes in the vacuum-packed product have remained constant within the margin of measurement error, while they have largely disappeared from the normally packed product. The vacuum-packed powder is reasonably free-flowing, while the normally packed product has coagulated into a lump.
Claims (13)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL9001651A NL9001651A (en) | 1990-07-19 | 1990-07-19 | PACKAGING CONTAINING A POWDER DETERGENT. |
NL9001651 | 1990-07-19 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0467481A2 true EP0467481A2 (en) | 1992-01-22 |
EP0467481A3 EP0467481A3 (en) | 1992-04-08 |
EP0467481B1 EP0467481B1 (en) | 1995-04-26 |
Family
ID=19857443
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91201897A Expired - Lifetime EP0467481B1 (en) | 1990-07-19 | 1991-07-18 | Package containing a powdered detergent |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0467481B1 (en) |
JP (1) | JPH04226600A (en) |
AT (1) | ATE121772T1 (en) |
AU (1) | AU651602B2 (en) |
DE (1) | DE69109200D1 (en) |
DK (1) | DK0467481T3 (en) |
NL (1) | NL9001651A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994021853A1 (en) * | 1993-03-23 | 1994-09-29 | Henkel-Ecolab Gmbh & Co. Ohg | Powder-aspiration probe |
EP0634485A1 (en) * | 1993-07-14 | 1995-01-18 | The Procter & Gamble Company | Detergent-package combination |
WO1997018129A1 (en) * | 1995-11-15 | 1997-05-22 | Henkel Kommanditgesellschaft Auf Aktien | Method for the packaging of mixtures of substances |
WO1998002516A1 (en) * | 1996-07-11 | 1998-01-22 | Henkel Kommanditgesellschaft Auf Aktien | Process for producing oxidation-stable washing agent components, thus obtained washing agents and their use |
WO1998040464A1 (en) * | 1997-03-07 | 1998-09-17 | Unilever Plc | Detergent-package combination |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001254097A (en) * | 2000-03-10 | 2001-09-18 | Kao Corp | Article for washing |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1575326A (en) * | 1967-08-01 | 1969-07-18 | ||
FR2225095A1 (en) * | 1973-04-11 | 1974-11-08 | Inst Scient Tech Alimentat | Packaging roasted coffee in gas-tight packets - with preservative gas to assist aroma retention |
-
1990
- 1990-07-19 NL NL9001651A patent/NL9001651A/en not_active Application Discontinuation
-
1991
- 1991-07-18 DK DK91201897.5T patent/DK0467481T3/en active
- 1991-07-18 AT AT91201897T patent/ATE121772T1/en not_active IP Right Cessation
- 1991-07-18 DE DE69109200T patent/DE69109200D1/en not_active Expired - Lifetime
- 1991-07-18 EP EP91201897A patent/EP0467481B1/en not_active Expired - Lifetime
- 1991-07-19 JP JP3179713A patent/JPH04226600A/en not_active Withdrawn
- 1991-07-19 AU AU81131/91A patent/AU651602B2/en not_active Ceased
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1575326A (en) * | 1967-08-01 | 1969-07-18 | ||
FR2225095A1 (en) * | 1973-04-11 | 1974-11-08 | Inst Scient Tech Alimentat | Packaging roasted coffee in gas-tight packets - with preservative gas to assist aroma retention |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994021853A1 (en) * | 1993-03-23 | 1994-09-29 | Henkel-Ecolab Gmbh & Co. Ohg | Powder-aspiration probe |
EP0634485A1 (en) * | 1993-07-14 | 1995-01-18 | The Procter & Gamble Company | Detergent-package combination |
TR27893A (en) * | 1993-07-14 | 1995-10-11 | Procter & Gamble | Detergent-packet combination with selected equilibrium relative humidity and moisture vapor transfer rate. |
WO1997018129A1 (en) * | 1995-11-15 | 1997-05-22 | Henkel Kommanditgesellschaft Auf Aktien | Method for the packaging of mixtures of substances |
WO1998002516A1 (en) * | 1996-07-11 | 1998-01-22 | Henkel Kommanditgesellschaft Auf Aktien | Process for producing oxidation-stable washing agent components, thus obtained washing agents and their use |
WO1998040464A1 (en) * | 1997-03-07 | 1998-09-17 | Unilever Plc | Detergent-package combination |
Also Published As
Publication number | Publication date |
---|---|
EP0467481B1 (en) | 1995-04-26 |
ATE121772T1 (en) | 1995-05-15 |
AU8113191A (en) | 1992-01-23 |
DK0467481T3 (en) | 1995-07-17 |
AU651602B2 (en) | 1994-07-28 |
EP0467481A3 (en) | 1992-04-08 |
NL9001651A (en) | 1992-02-17 |
JPH04226600A (en) | 1992-08-17 |
DE69109200D1 (en) | 1995-06-01 |
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