JPH0574440B2 - - Google Patents
Info
- Publication number
- JPH0574440B2 JPH0574440B2 JP12032785A JP12032785A JPH0574440B2 JP H0574440 B2 JPH0574440 B2 JP H0574440B2 JP 12032785 A JP12032785 A JP 12032785A JP 12032785 A JP12032785 A JP 12032785A JP H0574440 B2 JPH0574440 B2 JP H0574440B2
- Authority
- JP
- Japan
- Prior art keywords
- sodium
- bath water
- alkaline earth
- earth metal
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000002978 peroxides Chemical class 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 8
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 6
- 235000002639 sodium chloride Nutrition 0.000 description 5
- -1 organic acid salts Chemical class 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000001488 sodium phosphate Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 239000012425 OXONE® Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- HJKYXKSLRZKNSI-UHFFFAOYSA-I pentapotassium;hydrogen sulfate;oxido sulfate;sulfuric acid Chemical compound [K+].[K+].[K+].[K+].[K+].OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-] HJKYXKSLRZKNSI-UHFFFAOYSA-I 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229940099112 cornstarch Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- HUPXVBJTMJUPEX-UHFFFAOYSA-L disodium hydrogen peroxide hydrogen sulfate chloride Chemical compound [Cl-].[Na+].OO.S(=O)(=O)([O-])O.[Na+] HUPXVBJTMJUPEX-UHFFFAOYSA-L 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229960001790 sodium citrate Drugs 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 1
- 229940039790 sodium oxalate Drugs 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Detergent Compositions (AREA)
Description
〔産業上の利用分野〕
本発明は風呂水清浄剤に関する。
〔従来の技術〕
従来、無機過酸化物は、その良好な漂白性能、
殺菌性能、更には特有の臭機を有しない等の優れ
た性能の故に、家庭用衣類の漂白、洗浄槽やプー
ルの殺菌等の用途に使用されてきた。また、最近
では無機過酸化物のこれらの特性を生かして、こ
れを風呂水清浄剤に利用すべく検討が加えられて
いる。
〔発明が解決しようとする問題点〕
しかしながら、無機過酸化物は保存時の安定性
に乏しく、分解して酸素ガスを発生し、期待通り
の浄化能力を発揮しないことがあつたり、包装容
器の腐食等の不都合を生じることがある。このた
め、無機過酸化物を各種の安定化剤と共に配合し
て使用する方法が提案されている。しかし、これ
ら安定化剤を添加してもなお、無機過酸化物の安
定性は十分とは云えるものではない。
そこで、これら無機過酸化物を含有する風呂水
清浄剤は粉末状のまま使用せずに１回の使用分ご
とに錠剤にして使用される。こうすると便利なだ
けでなく、安定性の向上にもつながる。更に、こ
の錠剤の１錠１錠をアルミニウム／ポリエチレン
ラミネート包装しておけば外部からの吸湿を防止
することができる。しかし、それでも製造時の湿
度条件によつては安定性を損なう場合がある。
〔問題点を解決するための手段〕
斯かる実情において、本発明者は無機過酸化物
を配合した従来の風呂水清浄剤の有する上記欠点
を克服すべく鋭意研究を行なつた結果、無機過酸
化物をアルカリ土類金属の酸化物と共に配合すれ
ば、顕著な安定化効果の得られることを見出し、
本発明を完成した。
すなわち本発明は、無機過酸化物及びアルカリ
土類金属の酸化物を含有する風呂水清浄剤を提供
するものである。
本発明で使用す無機過酸化物は、例えば過炭酸
ナトリウム、過硼酸ナトリウム、モノ過硫酸カリ
ウム複塩、硫酸ナトリウム−塩化ナトリウム−過
酸化水素付加体が挙げられる。就中、モノ過硫酸
カリウム複塩が好適である。
また、アルカリ土類金属の酸化物としては、酸
化バリウム、酸化マグネシウム、酸化カルシウム
が好ましく、就中酸化カルシウムが特に好まし
い。これら酸化バリウム等の酸化物は、他のアル
カリ土類金属の酸化物に比べ量的に入手しやす
く、また、無機過酸化物の安定化のための所要量
は酸化カルシウム、酸化マグネシウム、酸化バリ
ウムの順に多くなる傾向があるためである。アル
カリ土類金属の酸化物は、単独であるいは２種以
上を組み合せて使用することができる。
本発明の風呂水清浄剤に使用される無機過酸化
物とアルカリ土類金属の酸化物との配合比率は特
に限定されないが、実質的には重量比にして99／
１〜80／20の範囲が好ましい。アルカリ土類金属
の酸化物の量が少ないと十分な安定化効果が得ら
れず、また多くても無駄になるばかりでなく溶け
残つたアルカリ土類金属の酸化物が容器底面にた
まりザラツキ等の原因となり好ましくない。
本発明の風呂水清浄剤は、無機過酸化物とアル
カリ土類金属の酸化物を単に混合すればよく、そ
の製造法は特に制限されないが、両者とも16メツ
シユ篩を通過するものが95％以上の粒度のものを
使用するのが好ましい。
本発明の風呂水清浄剤には更に必要に応じて、
硫酸ナトリウム、重炭酸ナトリウム、炭酸ナトリ
ウム、トリポリリン酸ナトリウム、ピロリン酸ナ
トリウム、リン酸一ナトリウム、リン酸二ナトリ
ウム、リン酸三ナトリウムの如き希釈剤としての
無機塩；クエン酸ナトリウム、修酸ナトリウム、
酒石酸ナトリウム、コハク酸ナトリウム、ニトリ
ロトリ酢酸ナトリウム、エチレンジアミン四酢酸
ナトリウム、ポリエチレングリコール（分子量
2000〜20000）、カルボキシメチルセルロースナト
リウム塩、ヒドロキシエチルセルロース、アルキ
ルベンゼンスルホン酸ナトリウム、アルキル硫酸
ナトリウム、アルキルスルホン酸ナトリウム、ポ
リエチレングリコールアルキルエーテル、ポリエ
チレングリコールアルキルフエノールエーテル等
の有機酸塩；高分子化合物、金属キレート剤、陰
イオン性界面活性剤、非イオン性界面活性剤等
等、更には香料、顔料、染料等々、風呂水清浄剤
の用途に対する製品をつくるための常用成分を添
加することができる。
本発明の風呂水清浄剤は、粉末、錠剤等の種々
の剤型とすることができるが、特に錠剤とするの
が好ましい。錠剤として使用する場合には、ヒド
ロキシプロピルセルロース、カルボキシメチルセ
ルロース、ソルビトール、ポリアクリル酸ナトリ
ウム、コーンスターチ等の結合剤；芒硝、食塩等
の賦形剤；安息香酸塩等の滑沢剤；重炭酸ナトリ
ウム等の発泡剤、崩壊剤等を配合することができ
る。
〔作用〕
本発明はいかなる機作にもとづいて効果発現す
るか未だ完全には解明されていない。
〔発明の効果〕
本発明の風呂水清浄剤は、吸湿による有効酸素
の低下が少なく保存安定性に優れたものである。
〔実施例〕
次に実施例を挙げて説明する。
実施例 １
表−１に示す組成を有する11種類の無機過酸化
物系風呂水清浄剤を、夫々３ｇづつ粉末のまま、
あるいは夫々３ｇづつ錠剤に打錠し、アルミピロ
包装に密封して50℃、40℃及び20℃の恒温室に３
ケ月保存し、アルミピロ包装のふくれ、腐蝕を観
察した。また、浴槽内に200の水道水を入れ、
所定期間保存した風呂水清浄剤を投入し、発泡性
及び溶解後の浴槽の底面のザラツキを観察した。
結果を表−２に示す。
[Industrial Field of Application] The present invention relates to a bath water cleaner. [Prior Art] Conventionally, inorganic peroxides have good bleaching performance,
Because of its excellent sterilizing performance and the fact that it does not have a unique odor mechanism, it has been used for purposes such as bleaching household clothes and sterilizing washing tanks and swimming pools. Furthermore, recently, studies have been conducted to take advantage of these properties of inorganic peroxides and use them as bath water purifiers. [Problems to be solved by the invention] However, inorganic peroxides have poor stability during storage, decompose and generate oxygen gas, and may not exhibit the expected purification ability, and may cause damage to packaging containers. This may cause problems such as corrosion. For this reason, methods have been proposed in which inorganic peroxides are used in combination with various stabilizers. However, even if these stabilizers are added, the stability of the inorganic peroxide cannot be said to be sufficient. Therefore, bath water cleaners containing these inorganic peroxides are not used in powder form, but are used in the form of tablets for each use. This is not only convenient, but also improves stability. Furthermore, if each of these tablets is packaged in an aluminum/polyethylene laminate, moisture absorption from the outside can be prevented. However, stability may still be impaired depending on the humidity conditions during production. [Means for Solving the Problems] Under these circumstances, the present inventor has conducted extensive research to overcome the above-mentioned drawbacks of conventional bath water cleaners containing inorganic peroxides, and has developed an inorganic peroxide solution. We discovered that a remarkable stabilizing effect can be obtained by blending an oxide with an alkaline earth metal oxide,
The invention has been completed. That is, the present invention provides a bath water cleaner containing an inorganic peroxide and an oxide of an alkaline earth metal. Examples of the inorganic peroxide used in the present invention include sodium percarbonate, sodium perborate, potassium monopersulfate double salt, and sodium sulfate-sodium chloride-hydrogen peroxide adduct. Among these, potassium monopersulfate double salt is preferred. Moreover, as the alkaline earth metal oxide, barium oxide, magnesium oxide, and calcium oxide are preferable, and calcium oxide is particularly preferable. These oxides such as barium oxide are easier to obtain in quantity than oxides of other alkaline earth metals, and the required amount for stabilizing inorganic peroxides is calcium oxide, magnesium oxide, barium oxide. This is because there is a tendency for the number to increase in this order. The alkaline earth metal oxides can be used alone or in combination of two or more. The blending ratio of the inorganic peroxide and the alkaline earth metal oxide used in the bath water cleaner of the present invention is not particularly limited, but the weight ratio is substantially 99/
A range of 1 to 80/20 is preferred. If the amount of alkaline earth metal oxide is small, a sufficient stabilizing effect will not be obtained, and if it is large, it will not only be wasted, but the undissolved alkaline earth metal oxide will accumulate on the bottom of the container and cause roughness etc. This is not desirable because it causes The bath water cleaner of the present invention can be produced by simply mixing an inorganic peroxide and an alkaline earth metal oxide, and the manufacturing method is not particularly limited, but 95% or more of both pass through a 16-mesh sieve. It is preferable to use particles with a particle size of . The bath water cleaner of the present invention further includes, if necessary,
Inorganic salts as diluents such as sodium sulfate, sodium bicarbonate, sodium carbonate, sodium tripolyphosphate, sodium pyrophosphate, monosodium phosphate, disodium phosphate, trisodium phosphate; sodium citrate, sodium oxalate,
Sodium tartrate, sodium succinate, sodium nitrilotriacetate, sodium ethylenediaminetetraacetate, polyethylene glycol (molecular weight
2000-20000), organic acid salts such as carboxymethyl cellulose sodium salt, hydroxyethyl cellulose, sodium alkylbenzene sulfonate, sodium alkyl sulfate, sodium alkyl sulfonate, polyethylene glycol alkyl ether, polyethylene glycol alkyl phenol ether; polymer compounds, metal chelating agents , anionic surfactants, nonionic surfactants, etc., as well as perfumes, pigments, dyes, etc., conventional ingredients for making products for bath water cleaner applications can be added. The bath water cleaner of the present invention can be made into various dosage forms such as powder and tablets, but tablets are particularly preferred. When used as a tablet, binders such as hydroxypropyl cellulose, carboxymethyl cellulose, sorbitol, sodium polyacrylate, and cornstarch; excipients such as mirabilite and common salt; lubricants such as benzoate; sodium bicarbonate, etc. A blowing agent, a disintegrant, etc. can be added. [Operation] The mechanism by which the present invention exerts its effects has not yet been completely elucidated. [Effects of the Invention] The bath water cleaner of the present invention exhibits less decrease in effective oxygen due to moisture absorption and has excellent storage stability. [Example] Next, an example will be given and explained. Example 1 3g of each of 11 types of inorganic peroxide bath water cleaners having the compositions shown in Table 1 were powdered.
Alternatively, compress 3g of each into tablets, seal in aluminum pillow packaging, and store in thermostatic chambers at 50℃, 40℃, and 20℃ for 3 days.
After storage for several months, the aluminum pillow packaging was observed for blistering and corrosion. Also, put 200 ml of tap water in the bathtub,
A bath water cleaner that had been stored for a predetermined period of time was added to the bath, and the foaming properties and roughness of the bottom of the bathtub after dissolution were observed.
The results are shown in Table-2.
【表】【table】
【表】【table】
【表】【table】
Claims (1)
を含有する風呂水清浄剤。1. A bath water cleaner containing an inorganic peroxide and an alkaline earth metal oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12032785A JPS61278394A (en) | 1985-06-03 | 1985-06-03 | Purifying agent for bath water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12032785A JPS61278394A (en) | 1985-06-03 | 1985-06-03 | Purifying agent for bath water |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61278394A JPS61278394A (en) | 1986-12-09 |
| JPH0574440B2 true JPH0574440B2 (en) | 1993-10-18 |
Family
ID=14783510
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12032785A Granted JPS61278394A (en) | 1985-06-03 | 1985-06-03 | Purifying agent for bath water |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61278394A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69328173T2 (en) * | 1993-07-14 | 2000-11-09 | Procter & Gamble | Detergent compositions |
| FR2728171B1 (en) | 1994-12-14 | 1997-01-24 | Chemoxal Sa | PRODUCTION OF BIOCIDAL DISINFECTANT FORMULATIONS BASED ON PERACETIC IONS |
| JP2016050199A (en) * | 2014-08-29 | 2016-04-11 | 株式会社 生活と科学社 | Oxygen-based mold removing agent, mold removing method, oxygen-based cleanser, and cleansing method using the same |
-
1985
- 1985-06-03 JP JP12032785A patent/JPS61278394A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61278394A (en) | 1986-12-09 |
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