EP0465734B1 - Composition traitante claire et méthode pour donner des propriétés de condition améliorées à la chevelure - Google Patents

Composition traitante claire et méthode pour donner des propriétés de condition améliorées à la chevelure Download PDF

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Publication number
EP0465734B1
EP0465734B1 EP90307451A EP90307451A EP0465734B1 EP 0465734 B1 EP0465734 B1 EP 0465734B1 EP 90307451 A EP90307451 A EP 90307451A EP 90307451 A EP90307451 A EP 90307451A EP 0465734 B1 EP0465734 B1 EP 0465734B1
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composition
hair
weight
compound
volatile
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EP0465734A1 (fr
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Ben Janchipraponvej
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Helene Curtis Inc
Helene Curtis Industries Inc
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Helene Curtis Inc
Helene Curtis Industries Inc
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
    • A61K8/585—Organosilicon compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention relates to a clear hair-treating composition and to a method of treating hair with such a composition.
  • hair shampoos generally are formulated with highly effective synthetic surfactants, like anionic surfactants, that primarily clean the hair rather than condition it. Therefore, shampoos usually neither aid in the detangling of wet hair nor impart any residual conditioning benefits to dry hair, such as manageability or styleability of hair sets.
  • anionic surfactants not only remove the dirt and soil from the hair, but also remove essentially all of the sebum naturally present on the surface of the hair fibres. Therefore, it was found that the desirable properties of anionic surfactants that effectively clean the hair also serve to leave the hair in a cosmetically-unsatisfactory condition.
  • hair shampoo compositions containing anionic surfactants, or non-ionic surfactants or amphoteric surfactants leave the hair with an undesirable harsh, dull and dry touch, or feel, usually called "creak", after the hair is shampooed and then rinsed with water.
  • conditioning compositions normally are applied separately from the hair shampoo, and usually are rinses or cream-like emulsions or lotions containing a cationic compound.
  • cationic compounds to adsorb or react with the keratinous material of the hair makes them the most desirable compounds for imparting the desired improvement in wet hair detangling and dry hair manageability.
  • hair conditioning compositions including cationic compounds that adsorb particularly strongly to the hair also can reduce the elasticity, body and set of the dried hair. Therefore, although conditioning compositions for application to freshly shampooed hair are well known, new and improved conditioning formulations based on cationic compounds are continually sought. For example, the majority of present-day, commercial hair-conditioner compositions are emulsion-type products that leave too great a conditioning-compound residue on the hair.
  • the present invention is directed to a new, non-emulsified, clear hair-conditioning composition
  • a new, non-emulsified, clear hair-conditioning composition comprising a combination of suitable hair-conditioning ingredients that is aesthetically acceptable to consumers, improves the wet combing and dry combing properties of hair, and also leaves the dry hair with satisfactory cosmetic properties and physical properties, including, in particular, dry combing and feel, less hair coating, manageability, body, condition of the ends and set.
  • Hair conditioning compositions such as emulsion-type creme rinses, are well known in the art for improving the combing properties of wet hair and dry hair.
  • These conditioning compositions typically are aqueous emulsions including a cationic compound, like a quaternary ammonium compound, as the principal conditioning agent.
  • the prior art describes the quaternary ammonium compound either as a polymeric material having a plurality of quaternary nitrogen atoms per molecule or as a molecule having at least one long carbon atom chain and an average of one quaternary nitrogen atom per molecule.
  • the prior art also describes hair conditioning compositions as including silicon-containing compounds, substituted amines and amides, nonionic surfactants, long carbon chain alcohols, and other ingredients to facilitate composition formulation and enhance consumer appeal.
  • U.S. Patent No. 3,993,744 to Cella et al discloses that cationic compounds, such as quaternary ammonium compounds, and silicones can be combined with perfluorinated compounds to provide hair treatment compositions.
  • the silicones specifically disclosed by Cella et al are surfactant-like polyoxyethylene polymethylsiloxanes that are presumed to be water-soluble or dispersible. According to Cella et al, both the quaternary ammonium compounds and the silicones are utilized in relatively small amounts, e.g., about 0.05 weight percent of the composition.
  • Other prior art patents disclosing the use of silicones having viscosities greater than about 100 centistokes at 25°C. to provide lubricity or sheen to various cosmetic preparations include U.S. Patent Nos. 2,942,008; 3,594,409; 3,824,303; and 4,014,995.
  • Matravers in U.S. Patent No. 4,725,433, discloses a clear conditioning composition comprising an aqueous blend of a polymeric quaternary ammonium salt, ethoxylated lauryl alcohol, ethoxylated cholesterol and hydroxyethylcellulose.
  • each of the ingredients included in the Matravers composition is water-soluble or water-dispersible.
  • the volatile conditioning agent utilized in the present invention such as a volatile silicone or a volatile hydrocarbon, is water insoluble, and, therefore, is the most difficult component of the composition to solubilize.
  • the composition disclosed by Matravers does not include a water-insoluble, volatile conditioning agent, and there is no suggestion or teaching of the desirability of including a water-insoluble conditioning agent in the composition disclosed in U.S. Patent No. 4,725,433.
  • British Patent No. 1,598,567 further discloses the use of a linear or a cyclic, volatile polydimethylsiloxanes, i.e., having a boiling point in the range of 99°C to 265°C, in hair conditioning compositions.
  • the composition of British Patent No. 1,598,567 is described as avoiding the formation of an oleophilic hair surface that usually occurs when using a quaternary ammonium hair conditioning agent.
  • South African Patent Application 666,421 also teaches the use of compositions containing straight chain and volatile cyclic silicone fluids to provide gloss and conditioning effects to hair dressings.
  • Nachtigal et al in U.S. Patent No. 4,275,055, discloses a pearlescent hair conditioner composition including a quaternized tertiary amidoamine, a quaternary ammonium compound and, optionally, a tertiary amidoamine, i.e., stearamidoethyldiethylamine.
  • the composition of Nachtigal et al is directed to achieving a stable pearlescent effect and neither includes a volatile conditioning agent nor is the composition a clear conditioning composition that demonstrates any improved rinsability.
  • Bolich et al in U.S. Patent No. 4,374,825, discloses an aqueous hair conditioning composition comprising a volatile hydrocarbon or volatile silicone, a cationic hair conditioning agent and a nonionic thickening agent.
  • Bolich et al in U.S. Patent No. 4,472,375 discloses a hair conditioning composition comprising a volatile hydrocarbon or a volatile silicone, a nonionic thickening agent, a quaternary ammonium salt and a salt of a fatty amine.
  • Neither Bolich et al patent teaches or suggests using a combination of a solubilizing nonionic surfactant with a polyhydric compound to completely solubilize the volatile conditioning agent.
  • Bolich in U.S. Patent No. 4,387,090, also discloses a hair-conditioner composition comprising a volatile hydrocarbon or a volatile silicone conditioning agent and a hydrophobic thickening agent.
  • Other prior art references relating to the use of a volatile conditioning agent in hair-conditioning compositions include U.S. Patent Nos. 3,577,528; 3,932,610; and 3,818,105.
  • Japanese TKS 57-50909 discloses a hair conditioner composition comprising a volatile silicone and a combination of two water-insoluble quaternary ammonium salts, wherein each quaternary ammonium salt includes two long chain alkyl groups.
  • Japanese TKS 57-50909 does not teach or suggest using an amidoamine compound in a composition to impart unexpected hair conditioning properties to hair or the desirability of solubilizing a water-insoluble volatile conditioning agent to provide a clear hair-conditioning composition.
  • Wagman et al in U.S. Patent No. 4,777,037 discloses a hair conditioner composition comprising a polydimethyl cyclosiloxane, a quaternary-nitrogen containing conditioning agent having two long alkyl chains of twelve to eighteen carbons and two short alkyl chains of one or two carbon atoms, a long chain fatty alcohol and a tertiary amidoamine of the general structural formula (III): wherein R5 is a fatty chain having from about 11 to about 17 carbon atoms, R6 is an alkylene group having 2 or 3 carbon atoms and R7 is either methyl or ethyl.
  • the compositions of Wagman et al are emulsions as opposed to the clear hair-conditioning compositions of the present invention.
  • a clear hair-conditioner composition of the present invention comprising a quaternary ammonium compound, a volatile conditioning agent, an amidoamine compound e.g. of general structural formula (I) or (II), a solubilizing nonionic surfactant and a polyhydric compound, unexpectedly exhibits improved rinsability from the hair and imparts improved conditioning properties upon application to human hair.
  • Another object of the present invention is to provide a clear hair-treating composition that is capable of conditioning the hair and imparting improved physical and cosmetic properties to the hair over a pH range of 4 to 7.
  • Another object of the present invention is to provide a method of treating hair with a clear hair-treating composition to achieve an improved condition of the hair.
  • Another object of the present invention is to provide a method of treating hair by contacting the hair with a clear composition having a pH of between 4 and 7 and then drying the hair, to condition the hair and to impart improved physical and cosmetic properties to the hair.
  • Another object of the present invention is to provide a new and improved clear hair conditioning composition capable of conditioning the hair and imparting improved physical, cosmetic and aesthetic properties both to normal hair and to tinted, frosted, bleached or other substantially-damaged hair.
  • Still another object of the present invention is to provide a method of treating the hair to yield unexpectedly well-conditioned hair having aesthetically-pleasing physical properties by contacting the hair with a clear, aqueous spray or solution to treat the hair, without heat, in either a rinse-off or leave-on method.
  • a clear hair-conditioning composition characterised in that it comprises from 0.5% to 5% by weight of a quaternary ammonium compound; from 0.1% to 5% by weight of an amidoamine compound; from 0.5% to 5% by weight of a volatile conditioning agent; from 1% to 10% by weight of a nonionic surfactant capable of solubilising the volatile conditioning agent; from 10% to 30% of a polyhydric compound; and a suitable liquid vehicle.
  • the present invention comprises a clear hair-treating composition
  • a clear hair-treating composition comprising from 0.5% to 5% by weight of a quaternary ammonium compound, such as dicetyldimonium chloride; from 0.1% to 5% by weight of an amidoamine compound having the general structural formula (I) or (II): wherein R1 is a fatty acid chain containing from 11 to 21 carbon atoms, R2 is an alkylene group containing from two to four carbon atoms, R3 is hydrogen, methyl, ethyl or a hydroxyalkylene group containing from one to three carbon atoms, R4 is methyl, ethyl or a hydroxyalkylene group containing from one to three carbon atoms, and Y is a heterocyclic nitrogen-containing moiety, like morpholine or pyridine; from 0.5% to 5% by weight of a volatile conditioning agent, such as a volatile hydrocarbon compound or a volatile silicone compound, like cyclomethicone; from
  • the clear composition of the present invention can be applied to the hair from an aqueous solution or spray, a conditioner formulation, a hair colour and/or other similar hair treatment products, over a pH range of from 4 to 7, to improve both the wet stage and the dry stage properties of the hair.
  • the invention may be considered to extent to a method of treating hair which comprises contacting the hair for a sufficient time with a transparent hair-conditioning composition as defined above in order to impart hair-conditioning properties to the hair.
  • the present invention may also be considered to extent to a method of treating the hair with a clear, homogeneous composition
  • a clear, homogeneous composition comprising (a) a quaternary ammonium compound; (b) a volatile conditioning agent, such as a volatile silicone, like a low molecular weight polydimethylsiloxane compound; (c) an amidoamine compound, wherein the amidoamine compound has the general structural formula (I) or (II): wherein R1 is a fatty acid chain containing from 11 to 21 carbon atoms, R2 is an alkylene group containing from two to four carbon atoms, R3 is hydrogen, methyl, ethyl or a hydroxyalkylene group containing from one to three carbon atoms, R4 is methyl, ethyl or a hydroxyalkylene group containing from one to three carbon atoms, and Y is a heterocyclic nitrogen-containing moiety; (d) a solubilizing noninic surfactant
  • the easy-to-apply clear composition imparts excellent wet stage and excellent dry stage conditioning properties to the hair and exhibits improved rinsability from the hair.
  • hair treated with the clear composition of the present invention also demonstrates improved physical properties and cosmetic properties, such as wet and dry feel, less coating, wet and dry combing, thickness, overall hair condition, manageability and body.
  • the clear hair-conditioning composition of the present invention imparts improved conditioning properties to treated hair while coating the hair with less of the quaternary ammonium compound and volatile conditioning agent.
  • hair conditioning properties are surprisingly and unexpectedly improved by a method of contacting the hair with a clear composition
  • a clear composition comprising a quaternary ammonium compound, a volatile conditioning agent, an amidoamine compound of general structural formula (I) or (II), a solubilizing nonionic surfactant and a polyhydric compound.
  • the compositions of the present invention can be applied to the hair from an aqueous vehicle at ambient temperature and are allowed to contact the hair for relatively short times to provide the benefits and advantages of a hair conditioner. Consequently, the method and composition of the present invention condition the hair to provide more manageable and aesthetically-pleasing hair.
  • the clear hair-conditioning composition of the present invention preferably therefore comprises (a) a quaternary ammonium compound; (b) a volatile conditioning agent, like a low molecular weight polydimethylsiloxane compound or a low molecular weight hydrocarbon compound; (c) an amidoamine compound having the general structural formula (I) or (II): wherein R1 is a fatty acid chain containing from 11 to 21 carbon atoms, R2 is an alkylene group containing from two to four carbon atoms, R3 is hydrogen, methyl, ethyl or a hydroxyalkylene group containing from one to three carbon atoms, R4 is methyl, ethyl or a hydroxyalkylene group containing from one to three carbon atoms, and Y is a heterocyclic nitrogen-containing moiety, like morpholine or pyridine; (d) a solubilizing nonionic surfactant, like an N-alkylated pyrrolidone; and (e
  • the quaternary ammonium compounds useful in the composition of the present invention preferably are water-soluble quaternary ammonium compounds having one or two long chain alkyl groups containing from 8 to 18 carbon atoms.
  • the long chain alkyl groups also can include, in addition to, or in replacement of, carbon and hydrogen atoms, ether linkages or similar water-solubilizing linkages.
  • the remaining two to three substituents of the quaternary nitrogen of the quaternary ammonium compound can be hydrogen; or benzyl; or short chain alkyl or hydroxyalkyl groups, such as methyl, ethyl, hydroxymethyl or hydroxyethyl groups; or combinations thereof, either of the same or of different identity.
  • an oil-soluble, water-dispersible quaternary ammonium compound either alone or in combination with a water-soluble quaternary ammonium compound also can be used in the composition of the present invention.
  • the oil-soluble quaternary ammonium compounds useful in the composition of the present invention are quaternary ammonium compounds having one or two long chain alkyl groups including from 14 to 22 carbon atoms. The remaining two to three substituents present on the quaternary nitrogen of the quaternary ammonium compound can be hydrogen; or benzyl; or short chain alkyl groups, such as methyl, or ethyl; or combinations thereof.
  • the quaternary ammonium compound useful in the present invention is a water-soluble or oil-soluble quaternary ammonium compound, or combinations thereof, depicted by the following general structural formula: wherein R8 is an alkyl group including from 8 to 22 carbon atoms; R9 is selected from the group consisting of an alkyl group including from 8 to 22 carbon atoms, a hydrogen atom, a methyl group, an ethyl group, a hydroxymethyl group and a hydroxyethyl group; R10 is selected from the group consisting of a benzyl group, a hydrogen atom, a methyl group, an ethyl group, a hydroxymethyl group and a hydroxyethyl group; R11 is selected from the group consisting of a hydrogen atom, a methyl group, an ethyl group, a hydroxymethyl group and a hydroxyethyl group; and X is selected from the group consisting of chloride, bromide, methosul
  • quaternary ammonium compounds are well-known hair conditioners.
  • the quaternary ammonium salts are substantive to the hair and provide some of the properties desired in well-conditioned hair. Consequently, several quaternary ammonium compounds have been found useful as hair conditioning agents, and therefore can be used as the quaternary ammonium compound conditioning component in the composition and method of the present invention. Consequently, the following water-soluble quaternary ammonium compounds are exemplary of water-soluble quaternary ammonium compounds that can be used in the method and composition of the present invention, either alone or in combination: wherein the name in parenthesis is the compound name given by the Cosmetic, Toiletry and Fragrance Association, Inc. in the CTFA Cosmetic Ingredient Dictionary , 3rd ed., 1982, hereinafter referred to as the CTFA Dictionary .
  • oil-soluble quaternary ammonium compounds is exemplary, but not limiting, of oil-soluble, water-dispersible quaternary ammonium compounds that can be used in the method and composition of the present invention, either alone, in combination, or in combination with the water-soluble quaternary ammonium compounds: wherein the name in parenthesis is the compound name given in the CTFA Dictionary .
  • cetrimonium chloride cetrimonium chloride; laurtrimonium chloride; Quaternium-16; laurylpyridinium chloride; mytrimonium chloride; Quaternium-24; soyatrimonium chloride; cetylpyridinium chloride; cetalkonium chloride; olealkonium chloride; dicetyldimonium chloride; lauralkonium chloride; Polyquaternium-11; distearyldimonium chloride; stearalkonium chloride; behenalkonium chloride; mytrimonium bromide, cetethylmorpholinium ethosulphate; and combinations thereof.
  • a long alkyl chain of the quaternary ammonium compound does not have to be solely, or primarily, of one chain length, i.e., the long chain need not be only lauryl (C12), myristyl (C14), stearyl (C18) or behenyl (C22). Rather, a quaternary ammonium compound wherein the long alkyl chain is a mixture of lengths can be used.
  • Such quaternary ammonium conditioning agents are prepared conveniently from naturally-occurring materials, such as tallow, coconut oil, soya oil and the like, or from synthetically produced mixtures.
  • water-soluble quaternary ammonium compounds having mixed carbon chain lengths include N-(soyaalkyl)-N,N,N-trimethyl ammonium chloride (soyatrimonium chloride); polyoxyethylene(2)cocomonium chloride (PEG-2 cocomonium chloride); and dimethyldi(hydrogenated tallow) ammonium chloride (Quaternium 18).
  • the quaternary ammonium compound is included in the clear hair-conditioner composition of the present invention in an amount of from 0.5% to 5% by weight of the composition.
  • the quaternary ammonium compound is present in an amount ranging from 1% to 4% by weight of the composition, and to achieve the full advantage of the present invention, the quaternary ammonium compound is present in an amount ranging from 1% to 2.5% by weight of the composition. It has been found that an amount of quaternary ammonium compound of at least about 0.5% by weight is necessary to provide a clear hair conditioning composition of the present invention that imparts an unexpectedly high degree of hair conditioning to treated hair.
  • the composition of the present invention also includes from 0.5% to 5%, and preferably from 1% to 4%, by weight of a volatile conditioning agent.
  • the volatile conditioning agent is added to the clear composition of the present invention in an amount sufficient to provide improved combing and improved feel of the treated hair.
  • the volatile conditioning can be either a volatile, low molecular weight silicone or a volatile, low molecular weight hydrocarbon.
  • the volatile low molecular weight silicone normally is a low molecular weight polydimethylsiloxane compound, however a low molecular weight polydimethylsiloxane including some phenyl substituents also is useful in the compositions of the present invention.
  • the low molecular weight polydimethylsiloxane compound can be a linear or a cyclic polydimethylsiloxane compound, and can include phenyl substituents, as long as the polydimethylsiloxane compound provides sufficient lubrication and imparts hair conditioning properties to wet hair, and has sufficient volatility to slowly volatilize from the hair such that a residual buildup of silicone compound is not present on dry hair.
  • hexamethyldisiloxane an example of a linear, low molecular weight, volatile polydimethylsiloxane compound useful in the composition and method of the present invention is the compound named in the CTFA Dictionary as hexamethyldisiloxane, available commercially under the tradename DOW CORNING 200 FLUID, from Dow Corning Corp., Midland, Michigan.
  • Hexamethyldisiloxane has a viscosity of 0.65 cs (centistokes), is highly volatile, is non-greasy, provides lubrication, and improves the overall combing properties of the hair.
  • linear polydimethylsiloxanes such as decamethyltetrasiloxane, having a boiling point of about 195°C and a viscosity of 1.5 centistokes; octamethyltrisiloxane; and dodecamethylpentasiloxane, also have sufficient volatility to be useful in the composition of the present invention, and are preferred over hexamethyldisiloxane due to a lower volatility than hexamethyldisiloxane.
  • decamethyltetrasiloxane having a boiling point of about 195°C and a viscosity of 1.5 centistokes
  • octamethyltrisiloxane octamethyltrisiloxane
  • dodecamethylpentasiloxane also have sufficient volatility to be useful in the composition of the present invention, and are preferred over hexamethyldisiloxane due to a lower volatility than hexamethyldisiloxane.
  • linear, low molecular weight, volatile polydimethylsiloxane compounds having a viscosity at 25°C in the range of from 0.5 cs to 5 cs, and a boiling point at atmospheric pressure ranging from 100°C to 250°C, are suitable for use in the clear hair-treating composition of the present invention.
  • cyclic, low molecular weight, volatile polydimethylsiloxanes are useful in the clear composition and method of the present invention.
  • the cyclomethicones useful in the present invention are low molecular weight, water-insoluble cyclic compounds having an average of 3 to 6 -[O-Si(CH3)2]- repeating group units per molecule and boil at atmospheric pressure in a range of from about 150°C to about 250°C.
  • the polydimethyl cyclosiloxanes having an average of 4 to 5 repeating units per molecule, i.e., the tetramer and pentamer, are preferred.
  • polydimethyl cyclosiloxanes having boiling points at atmospheric pressure in the range of 170°C to 220°C, and viscosities at 25°C of from 2 to 6 centistokes are included in the composition.
  • Suitable cyclomethicones are available commercially under the tradenames SILICONE SF-1173 (octamethylcyclotetrasiloxane) and SILICONE SF-1202 (decamethylcyclopentasiloxane) from General Electric, Waterford, New York, and SILICONE 334 FLUID and SILICONE 345 FLUID from Dow Corning Corporation, Midland, Michigan, the tetramer being listed first in each instance.
  • the volatile conditioning agent included in the composition of the present invention also can be a volatile hydrocarbon, such as a hydrocarbon including from 10 carbon atoms to 26 carbon atoms, that have sufficient volatility to slowly volatilize from the hair such that a residual buildup of hydrocarbon is not present on dry hair.
  • a volatile hydrocarbon such as a hydrocarbon including from 10 carbon atoms to 26 carbon atoms, that have sufficient volatility to slowly volatilize from the hair such that a residual buildup of hydrocarbon is not present on dry hair.
  • the volatile hydrocarbon provides essentially the same benefits as the volatile silicone, such as lubrication and wet hair conditioning.
  • the preferred volatile hydrocarbon compound is an aliphatic hydrocarbon including from 12 to 24 carbon atoms, and has a boiling point in the range of from 100°C to 300°C.
  • Exemplary volatile hydrocarbons are depicted in general structural formula (V), wherein n ranges from 2 to 5,
  • Examples of volatile hydrocarbons useful in the clear hair-conditioning composition of the present invention are the commercially-available compounds PERMETHYL 99A and PERMETHYL 101A, corresponding to compounds of general structure (V) wherein n is 2 and 3, respectively, from Permethyl Corporation, Frazer, PA.
  • a volatile hydrocarbon compound is useful in the clear hair-conditioning composition of the present invention either alone, in combination with another volatile hydrocarbon, or in combination with a volatile silicone.
  • a volatile polydimethylsiloxane, or a volatile hydrocarbon compound, as described above to be combined with a quaternary ammonium compound, an amidoamine compound of general structural formula (I) or (II), a solubilizing nonionic surfactant and a polyhydric compound to provide a clear, hair-conditioning composition that imparts such improved wet stage properties, dry stage properties, rinsing properties, and overall conditioning benefits to treated hair, like a reduction of split ends, improved body and improved manageability.
  • aqueous hair conditioners including a volatile silicone or a volatile hydrocarbon compound were emulsion-type products because of the inherent water-insolubility of the silicone and hydrocarbon compounds.
  • the composition of the present invention is a stable and clear solution, or dispersion, of the volatile silicone and/or volatile hydrocarbon compound in an aqueous vehicle.
  • the composition of the present invention also includes from 0.1% to 5%, and preferably from 0.1% to 2%, by weight of an amidoamine compound.
  • an amidoamine compound having the general structural formula (I) or (II): wherein R1 is a fatty acid chain containing from 11 to 21 carbon atoms, R2 is an alkylene group containing from two to about four carbon atoms, R3 is hydrogen, methyl, ethyl or a hydroxyalkylene group containing from one to three carbon atoms, R4 is methyl, ethyl or a hydroxyalkylene group containing from one to three carbon atoms, and Y is a heterocyclic nitrogen-containing moiety, like morpholine, is included, and solubilized, in a clear composition of the present invention to impart improved physical and cosmetic properties to hair.
  • amidoamine compound having the general structural formula (I) that is useful in the composition and method of the present invention is the compound named in the CTFA Dictionary as stearamidopropyldimethylamine, available commercially under the tradename LEXAMINE S-13 from Inolex Chemical Div., Philadelphia, PA, and having the structural formula (VI):
  • suitable amidoamine compounds include, but are not limited to, compounds designated in the CTFA Dictionary as stearamidoethyldiethanolamine, isostearamidopropylmorpholine, stearamidopropylmorpholine and stearamidoethylethanolamine, having structural formulas (VII), (VIII), (IX) and (X), respectively.
  • amidoamine compounds include compounds having either one or two hydroxymethyl, hydroxypropyl, methyl or ethyl moieties, or combinations thereof, present on an amino nitrogen in place of the hydroxyethyl moieties.
  • amidoamine compounds include dimethylaminopropyl stearamide, diethylaminoethyl stearamide, and dimethylaminopropyl myristamide.
  • the fatty acid chain R1 of compounds of general structural formulas (I) and (II) does not have to be solely, or primarily, of one chain length, i.e., the long chain need not be derived only from lauryl (C12), myristyl (C14), cetyl (C16), or stearyl (C18). Rather, amidoamine compounds of general structural formulas (I) and (II) wherein the long alkyl chain is a mixture of lengths can be used. Such amidoamine compounds are prepared conveniently from naturally-occurring materials, such as tallow, coconut oil, soya oil and the like, or from synthetically produced mixtures.
  • the above-described amidoamine compounds of general structural formulas (I) and (II) exhibit the properties of a cationic surfactant.
  • the amidoamine compounds In the free amine state, as depicted in structural formulas (VI) through (X), the amidoamine compounds generally are insoluble in water. However, after pH adjustment, the amidoamine compounds exhibit increased water solubility. Consequently, in the neutralized state, the amidoamine compound behaves like a cationic surfactant, and therefore is substantive to the hair and imparts conditioning properties to the hair.
  • the acid used to adjust the pH of the composition can be essentially any organic acid or mineral acid.
  • Such acids include hydrochloric acid, sulfuric acid, nitric acid, phosphoric acid, lactic acid, citric acid, tartaric acid, acetic acid, gluconic acid, glycolic acid and propionic acid, or combinations thereof.
  • the composition pH is adjusted with an organic acid, like lactic acid.
  • a sufficient amount of acid is added to adjust the final pH of the hair-treating composition to within a range of from 4 to 7, and more preferably to within a pH range of from 5.5 to 6.5.
  • the clear hair-conditioning composition of the present invention also includes a solubilizing nonionic surfactant.
  • the solubilizing nonionic surfactant is present in the composition in an amount ranging from 1% to 10% by weight of the composition.
  • the solubilizing nonionic surfactant is included in the composition to sufficiently solubilize the volatile conditioning compound, and to assist in solubilizing the amidoamine compound, such that the resulting conditioning composition is clear and homogeneous.
  • the solubilizing nonionic surfactant and volatile conditioning agent are present in the composition in a weight ratio of from at least 1 to 1 and up to 10 to 1.
  • solubilizing nonionic surfactant to volatile conditioning agent is less than about 1 to 1, the volatile conditioning agent is not sufficiently solubilized to provide a clear hair-conditioning composition. Furthermore, if the weight ratio is greater than about 10 to 1, no further solubilizing benefits are realized and the solubilizing nonionic surfactant is present in excess and merely rinsed away from the hair without achieving any further solubilizing benefits or imparting any conditioning benefits.
  • a weight ratio of solubilizing nonionic surfactant to volatile condition agent in the range of from 2 to 1 to 4 to 1 provides a clear composition that imparts superior conditioning properties to the hair, without using an appreciable excess amount of solubilizing nonionic surfactant that eventually is wasted.
  • Suitable solubilizing nonionic surfactants include any nonionic surfactant that effectively solubilizes a volatile silicone conditioning compound or a volatile hydrocarbon conditioning compound that yields a clear, aqueous-based conditioner composition and that does not adversely affect either the quaternary ammonium compound, the amidoamine compound, or the volatile conditioning agent in regards to conditioning treated hair.
  • Particular solubilizing nonionic surfactants found to be useful in the method and composition of the present invention include the N-alkylated-2-pyrrolidones of general structural formula XI, wherein R12 is an alkyl moiety, straight chain or branched chain, including from 8 to 16 carbon atoms:
  • Specific N-alkylated-2-pyrrolidones found useful in the composition of the present invention include decyl pyrrolidone (N-decyl-2-pyrrolidone) and lauryl pyrrolidone (N-dodecyl-2-pyrrolidone), available commercially under the tradenames SURFADONE LP-100 and SUFRADONE LP-300, respectively, from GAF Corporation, Wayne, NJ. Both SURFADONE LP-100 and SURFADONE LP-300 sufficiently solubilized the volatile conditioning agent to provide a clear conditioning composition that effectively imparted hair conditioning properties to treated hair.
  • the clear hair conditioning composition of the present invention also includes from 10% to 30% by weight of a polyhydric compound.
  • the clear hair-conditioning composition includes from 15% to 25% by weight of the polyhydric compound, and, to achieve the full advantage of the present invention, the composition includes from 18% to 22% by weight of the polyhydric compound.
  • the polyhydric compound serves to couple the quaternary ammonium compound, the amidoamine compound, the volatile conditioning agent and the solubilizing nonionic surfactant to provide a clear, non-turbid, aqueous-based hair-conditioning composition.
  • the polyhydric compound can be a glycol, a triol or a polyol.
  • the vehicle of the hair-treating composition is preferably predominantly water, but organic solvents also can be included in order to facilitate manufacturing of the composition or to provide esthetic properties to the composition, such as viscosity control.
  • Suitable solvents include the lower alcohols like ethyl alcohol and isopropyl alcohol; glycol ethers, like 2-butoxyethanol, ethylene glycol monoethyl ether, propylene glycol and diethylene glycol monoethyl ether or monomethyl ether; and mixtures thereof.
  • These non-aqueous solvents can be present in the clear hair-conditioning composition of the present invention in an amount from 1 to 50% by weight and in particular from 5 to 25% by weight, relative to the total weight of the carrier vehicle in the composition.
  • the clear hair-conditioning compositions of the present invention also can be thickened, for example, with sodium alginate; guar gum; xanthan gum; gum arabic; cellulose derivatives such as methylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose and carboxymethylcellulose; and various polymeric thickeners, such as polyacrylic acid derivatives. These thickeners are present in an amount ranging from 0.1% to 3%, and preferably from 0.25% to 1%, by weight relative to the total weight of the composition.
  • the clear hair-conditioning compositions also can include inorganic salts, humectants and similar materials to provide esthetic properties and desirable physical properties to the composition.
  • inorganic salts such optional ingredients are present in weight percentages ranging from 0.1% to 10% each, and from 0.1% to 20% in total, relative to the total weight of the composition.
  • compositions of the present invention are clear, relatively viscous compositions that are stable to phase separation at a temperature of about 25°C for an indefinite period of time.
  • the clear compositions of the present invention have demonstrated sufficient stability to phase separation at temperatures normally found in commercial product storage and shipping to remain unaffected for periods of one year or more.
  • a composition of the present invention can resist phase separation for even substantially longer storage periods. It also has been found that a clear, viscous composition has enhanced customer appeal compared to the present-day, emulsion-type conditioner compositions.
  • the hair-treating composition of the present invention comprising a quaternary ammonium compound; a volatile conditioning agent; an amidoamine compound of general structural formula (I) or (II); a solubilizing nonionic surfactant; and a polyhydric compound. It has been demonstrated that, to provide a clear composition and to maximize hair conditioning properties, the hair-treating composition of the present invention must include both a volatile conditioning agent, such as a volatile silicone, and a solubilizing nonionic surfactant.
  • the volatile conditioning agent is pre-solubilized in the solubilizing nonionic surfactant, then this mixture is combined with the other composition ingredients to provide a clear conditioning composition.
  • the resulting clear hair-conditioning composition is more easily rinsed from the hair, and imparts excellent conditioning properties to the hair utilizing a lower amount of the conditioning agents. Consequently, the amount of conditioners coating the hair is decreased and residual conditioner buildup on the hair is reduced.
  • laboratory and salon testing has shown that optimum conditioning properties are imparted to the hair when quaternary ammonium compound, an amidoamine compound and a solubilized volatile conditioning agent are present in the clear, conditioning composition in sufficient quantity.
  • a quaternary ammonium compound should be present in the clear hair-conditioning compositions of the present invention.
  • an amount of quaternary ammonium compound in the composition above about 0.5% by weight further improves performance of the hair-conditioning composition up to a level of about 5% by weight of the quaternary ammonium compound.
  • a level of quaternary ammonium compound in the composition above 5% by weight such as up to 15% by weight, does not adversely affect composition performance, but may affect the clarity of the composition and also does not appreciably improve the performance of the hair-conditioning composition. Therefore, any amounts of quaternary ammonium compound in the composition above about 5% by weight are apparently wasted because the excess quaternary ammonium compound is rinsed from the hair during the rinsing step of the hair treatment.
  • compositions comprising a quaternary ammonium compound; an amidoamine of general structural formula (I) or (II); a volatile, conditioning silicone or hydrocarbon; a solubilizing nonionic surfactant; and a polyhydric compound.
  • a clear conditioning composition comprising a quaternary ammonium compound; an amidoamine of general structural formula (I) or (II); a volatile, conditioning silicone or hydrocarbon; a solubilizing nonionic surfactant; and a polyhydric compound.
  • the particular quaternary ammonium compound used in Examples 1 through 12 was dicetyldimonium chloride, available under the tradename ADOGEN 432ET, from Sherex Chemical Co., Dublin, O. and including 70% by weight of dicetyldimonium chloride; the amidoamine compound used was stearamidopropyldimethylamine, available under the tradename LEXAMINE S-13, from Inolex Corp., Philadelphia, PA. and including 100% by weight of stearamidopropyldimethylamine; the volatile, low molecular weight polydimethylsiloxane compound used was cyclomethicone, available under the tradename SILICONE SF1173 from G.E.
  • Examples 1 through 30 may not include particular essential ingredients of the clear hair-treating compositions of the present invention.
  • Examples 1 through 24 were prepared and tested to help determine the limits of essential ingredients that can be present in the clear hair-treating compositions of the present invention, and the effects of omitting an essential ingredient from the hair-treating composition.
  • compositions of Examples 1 through 30 were prepared in an identical manner.
  • the composition of Example 1 was prepared by first producing a premix of the ADOGEN 432ET and a minor amount of soft water.
  • a second premix including the cyclomethicone and the SURFADONE LP300 was prepared. The two premixes then were combined and thoroughly admixed to form the main batch.
  • a third premix of the octoxynol-9 and the fragrance was added to the main batch, and the resulting mixture was stirred until homogeneous.
  • the thickener then was homogeneously dispersed in the major amount of soft water, and the aqueous thickener dispersion was added to the main batch. After thorough blending, the preservative was added to the resulting composition.
  • the composition of Example 1, lacking the amidoamine compound and the polyhydric compound was an emulsion-type product.
  • Example 6 the composition of Example 6 was prepared by first producing a premix including the hexylene glycol, the LEXAMINE S-13 and the lactic acid. The premix was heated to about 66°C (150°F) to about 74°C (165°F), then held at the elevated temperature for about 30 minutes. After cooling to about 38°C (100°F), a second premix including the ADOGEN 432ET and ethanol was added to the first premix, and the two premixes were thoroughly blended until homogeneous. Then a previously prepared dispersion of the thickener and the major portion of the soft water was added to the homogeneous premix blend to form the main batch.
  • a premix including the hexylene glycol, the LEXAMINE S-13 and the lactic acid.
  • the premix was heated to about 66°C (150°F) to about 74°C (165°F), then held at the elevated temperature for about 30 minutes. After cooling to about 38°C (100°F), a second premix
  • Example 1 and 2 each without the polyhydric compound, i.e., hexylene glycol, were emulsions as opposed to clear compositions.
  • Example 3 including the hexylene glycol but without the quaternary ammonium compound, ADOGEN 432ET, produced a hazy composition.
  • Example 4 including each of the five essential ingredients of the present invention, was a hazy composition, thereby showing that at least about 10% of the polyhydric compound should be present in the composition.
  • Example 6 demonstrates that the amount of polyhydric compound can be reduced to below 10%, if an alcohol also is included in the composition.
  • Example 5 demonstrates that an alcohol alone does not produce a clear composition, therefore requiring that a polyhydric compound be present in the composition.
  • Examples 7 through 12 demonstrate that increased amounts of hexylene glycol further clarify the composition, with a clear composition resulting over the range of from about 10% to about 30% by weight hexylene glycol, and with maximum clarity achieved at polyhydric compound levels of from about 18% to about 22% by weight of the composition.
  • Example 13 shows that a composition including only water and four of the five essential ingredients, adjusted to the proper pH, provides a clear conditioning composition if the ratio of SURFADONE LP300 to cyclomethicone is sufficiently high.
  • Examples 13 through 15 demonstrate that the amount of amidoamine compound, LEXAMINE S-13, and/or the amount of the solubilizing nonionic surfactant, SURFADONE LP300, can be varied to yield a clear conditioning composition when the SURFADONE/silicone ratio is at least about 4 to 1 even though the ADOGEN 432ET is absent.
  • Examples 14 through 17 show that if the amount of amidoamine is increased significantly, and the ratio of SURFADONE LP300 to cyclomethicone is significantly reduced, a clear composition without the quaternary ammonium compound does not result.
  • Examples 18 through 21 demonstrate the effect of eliminating at least one of the essential ingredients from the composition.
  • the composition was opaque and unstable, separating into distinct aqueous and nonaqueous phases within a short time period.
  • Example 21 further shows that an alcohol alone will not solubilize the cyclomethicone and SURFADONE LP300, and
  • Example 19 shows that the polyhydric compound alone will not solubilize the cyclomethicone and SURFADONE LP300.
  • Examples 22 through 24 showed that linear volatile silicones, either dimethylpolysiloxanes or phenyl-substituted dimethylpolysiloxanes are useful as the volatile conditioning agent of the composition of the present invention.
  • Examples 25 through 29 in TABLE II show that a volatile hydrocarbon can be used as the volatile conditioning agent in a clear hair-conditioning composition of the present invention.
  • the compositions of Examples 25 through 29 were produced by a method similar to producing the compositions of Examples 1 through 24.
  • a volatile hydrocarbon can be used as the volatile conditioning agent to provide a clear conditioning composition of the present invention (EXS. 25, 26 and 29).
  • conditioning compositions including a volatile hydrocarbon as the volatile conditioning apparently are more sensitive to the amount of polyhydric compound present in the composition.
  • Examples 27 and 28 show that, even if the ratio of SURFADONE LP300 to volatile hydrocarbon is relatively high, the composition is cloudy unless a sufficient amount of polyhydric compound is included in the composition.
  • compositions including a quaternary ammonium compound, an amidoamine of general structural formula (I) or (II), a volatile conditioning agent, a solubilizing nonionic surfactant and a polyhydric compound effectively impart hair conditioning properties to treated hair
  • compositions of Examples 1 through 12 were applied to hair.
  • These particular compositions were compared to two leading commercial hair conditioners, HAIR SPECIFICS and FINESSE, both available from Helene Curtis, Inc., Chicago, IL., for an ability to impart hair conditioning properties the hair.
  • HAIR SPECIFICS and FINESSE are traditional emulsion-type hair conditioner products.
  • the composition of Example 12 was applied to human hair and conditioning properties were compared to the condition properties imparted by FINESSE or HAIR SPECIFICS.
  • a group of five trained judges rated hair treated with the composition of Example 12 and either the commercially-available hair conditioner FINESSE or the commercially-available hair conditioner HAIR SPECIFICS in a salon evaluation.
  • FINESSE includes a quaternary ammonium compound, an amidoamine compound and a polydimethylsiloxane in a total amount of about 4.4% by weight.
  • HAIR SPECIFICS includes a quaternary ammonium compound, dimethicone and a quaternized protein in a total amount of about 4% by weight. Both HAIR SPECIFICS and FINESSE are commercially available, with FINESSE being recognized as an exceptional hair conditioning product and HAIR SPECIFICS being recognized as a premium hair conditioning product. It should be noted that in this subjective salon testing, if a composition imparts hair conditioning properties to treated hair equivalent to the properties imparted by FINESSE, the composition is considered an exceptional conditioner because FINESSE is recognized as a benchmark for hair conditioning performance.
  • composition imparts hair conditioning properties to treated hair equivalent to properties imparted by HAIR SPECIFICS
  • the composition is considered a premium conditioner because HAIR SPECIFICS is recognized as a superior hair-conditioner, but not as efficacious as FINESSE.
  • composition of interest is applied to one side of a head of hair, and the product used for comparison, i.e., either FINESSE or HAIR SPECIFICS, is applied to the other side of the head.
  • product used for comparison i.e., either FINESSE or HAIR SPECIFICS
  • each side of hair is judged for a variety of hair conditioning properties by a panel of five trained judges on a ranking of 1 unit (worst) to 5 units (best). Then ratings of the judges for each hair conditioning property are averaged, and a difference in rating one side of hair compared to the other side of hair of at least 0.3 units is considered a significant difference for that particular hair conditioning property.
  • the judges rate the hair for such hair conditioning properties as ease of application, fragrance, ease of rinsing, wet feel, wet comb, residue, dry combing, dry feel, coating, flakes/dust, static, manageability, condition of ends, sheen/luster, body, effect on hair color, irritation and overall condition.
  • a clear composition of the present invention including 2% by weight ADOGEN 432ET, 1% by weight cyclomethicone, 2% by weight SURFADONE LP300, 0.8% by weight LEXAMINE S-13 and 10% by weight hexylene glycol (Ex. 30), was compared to the HAIR SPECIFICS conditioner. It was found that in a salon comparative test of the composition of Example 30 and HAIR SPECIFICS conditioner, that a significant improvement (i.e., at least 0.3 rating units) in wet feel, dry feel, dry combing, coating, manageability, condition of ends, and overall condition was found in hair treated with the composition of Example 30. It should be noted that among the numerous hair conditioning properties, these properties are considered the key properties in regard to hair conditioning. Furthermore, for each of the twenty-one conditioning properties that were compared, the composition of Example 30 at least equalled the conditioning properties imparted by HAIR SPECIFICS.
  • Example 30 an identical salon comparative test was performed between the composition of Example 30 and FINESSE.
  • the composition of Example 30 and FINESSE compared essentially identically, except that FINESSE demonstrated a 0.3 unit superiority in dry combing and dry feel.
  • the ratings between the composition of Example 30 and FINESSE were identical or less than the significant difference of 0.3 rating units.
  • EX. 30 a composition of the present invention
  • the above salon comparative tests demonstrate that the clear conditioning compositions of the present invention, including a quaternary ammonium compound, a volatile conditioning agent, an amidoamine compound, a solubilizing nonionic surfactant, and a polyhydric compound, surprisingly and unexpectedly possess an improved ability to impart hair conditioning properties to hair.
  • the method and composition of the present invention impart exceptional hair conditioning properties to treated hair usually demonstrated only by premium hair conditioner compositions. It is both surprising and unexpected for an aqueous composition of the present invention, including a water-insoluble volatile conditioning agent, to be a consumer-appealing clear product, to maintain product stability over long storage times, and to impart such excellent hair conditioning properties to treated hair.
  • the clear compositions of the present invention coat the hair more effectively and also are especially easy to rinse from the hair. Consequently, an improved and more effective coating of the hair requires less conditioner composition to be applied to the hair, thereby also reducing the amount of dulling, chemical residue that coats the hair shaft.
  • the method of the present invention provides the further benefits of not leaving the hair tacky or sticky; not forming a crust and therefore providing combability; and providing manageable and styleable hair having body.
  • the hair feels natural and thickened, has body, is soft, shiny, manageable, and combable.

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Claims (27)

  1. Composition limpide de conditionnement de cheveux, caractérisée en ce qu'elle comprend de 0,5 à 5% en poids d'un composé d'ammonium quaternaire ; de 0,1 à 5% en poids d'une amino-amine ; de 0,5 à 5% en poids d'un agent volatil de conditionnement ; de 1 à 10% en poids d'un tensioactif non ionique capable de solubiliser l'agent volatil de conditionnement ; de 10 à 30% d'un composé polyhydrique ; et un véhicule liquide approprié.
  2. Composition selon la revendication 1, caractérisée en ce que le tensioactif non ionique et l'agent volatil de conditionnement sont présents en un rapport pondéral du tensioactif non ionique à l'agent volatil de conditionnement compris entre 1:1 et 10:1, de préférence entre 2:1 et 5:1.
  3. Composition selon la revendication 1 ou 2, caractérisée en ce que le composé d'ammonium quaternaire est présent en une quantité de 1 à 4% en poids de la composition, de préférence de 1 à 2,5% en poids de la composition.
  4. Composition selon l'une quelconque des revendications précédentes caractérisée en ce que le composé d'ammonium quaternaire présente la structure générale :
    Figure imgb0029
     dans laquelle R₈ est un radical alkyle de 8 à 22 atomes de carbone ; R₉ est un radical alkyle de 8 à 22 atomes de carbone, un atome d'hydrogène, un radical méthyle, un radical éthyle, un radical hydroxyméthyle ou bien un radical hydroxyéthyle ; R₁₀ est un radical benzyle, un atome d'hydrogène, un radical méthyle, un radical éthyle, un radical hydroxyméthyle ou un radical hydroxyéthyle ; R₁₁ est un atome d'hydrogène, un radical méthyle, un radical éthyle, un radical hydroxyméthyle ou un radical hydroxyéthyle ; et X est un radical chlorure, bromure, méthosulfate, éthosulfate, tosylate, acétate, phosphate ou nitrate.
  5. Composition selon l'une quelconque des revendications 1 à 3, caractérisée en ce que le composé d'ammonium quaternaire est choisi parmi le chlorure de laurtrimonium ; le Quaternium-16 ; le chlorure de lauralconium; le chlorure d'oléalconium, le chlorure de dilauryldimonium; le chlorure de cétalconium ; le chlorure de dicétyldimonium; le chlorure de laurylpyridinium ; le Polyquaternium-6 ; le Polyquaternium-7 ; le chlorure de guar-hydroxypropyltrimonium ; le Polyquaternium-11 ; le Polyquaternium-5 ;le Polyquaternium-10 ; le Polyquaternium-24 ; le chlorure de cetrimonium ; le Quaternium-24, le chlorure de mytrimonium ; le chlorure de Cocomonium PEG-2 ; le Cocoyl-Quaternium-4 PEG-2 ; le Cocoyl-Quaternium-4 PEG 15 ; le Stearyl-Quaternium-4 PEG 2 ; Le Stearyl-Quaternium-4 PEG 15; l'Oléyl-Quaternium-4 PEG 2 ; l'Oléyl-Quaternium-4 PEG 15 ; le bromure de cétrimonium, l'éthosulfate de cététhylmorpholinium ; le chlorure de béhénalconium ; le chlorure de béhentrimonium ; le chlorure de mytrimonium et leurs combinaisons.
  6. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que l'amidoamine est présente en une proportion de 0,1 à 2% en poids de la composition.
  7. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que l'amidoamine répond à la formule générale :
    Figure imgb0030
     dans laquelle R₁ est une chaîne d'acide gras contenant de 11 à 22 atomes de carbone ; R₂ est un radical alkylène contenant de 2 à 4 atomes de carbone ; R₃ est un atome d'hydrogène, un radical méthyle, un radical éthyle ou un radical hydroxyalkylène contenant 1 à 3 atomes de carbone; R₄ est un radical méthyle, un radical éthyle ou un radical hydroxyalkylène contenant 1 à 3 atomes de carbone ; et Y est un fragment contenant n groupes d'azote organique hétérocyclique.
  8. Composition selon la revendication 7, caractérisée en ce que l'amido-amine est choisie parmi la stéaramidoéthyléthanolamine, la stéaramidoéthyldiéthanolamine, l'isostéaramidopropylmorpholine, la stéaramidopropylmorpholine, la stéaramidopropyldiméthylamine, le didiéthyl-aminoéthylstéaramide, la diméthylaminopropylmyristamine et leurs combinaisons.
  9. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que l'agent volatil de conditionnement est présent à raison de 1 à 4% en poids de la composition.
  10. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que l'agent volatil de conditionnement est une silicone volatile et/ou un hydrocarbure volatil.
  11. Composition selon la revendication 10, caractérisée en ce que la silicone volatile est un polydiméthylsiloxane de basse masse moléculaire ou un polydiméthylsiloxane à substitution phénylique de basse masse moléculaire.
  12. Composition selon la revendication 11, caractérisée en ce que le polydiméthylsiloxane de basse masse moléculaire est un polydiméthylsiloxane linéaire ou un polydiméthylsiloxane cyclique.
  13. Composition selon la revendication 12, caractérisée en ce que le polydiméthylsiloxane linéaire présente une viscosité à 25°C comprise entre 0,5 et 5 cs et un point d'ébullition sous pression atmosphérique compris entre 100 et 250°C, et il comprend de préférence de l'hexaméthyldisiloxane et/ou de l'octaméthyltrisiloxane et/ou du decaméthyltetrasiloxane.
  14. Composition selon la revendication 12, caractérisée en ce que le polydiméthylsiloxane cyclique présente une viscosité à 25°C de 2 à 6 cs et un point d'ébullition sous pression atmosphérique de 150 à 250°C, et il comprend de préférence de l'hexaméthylcyclotrisiloxane et/ou de l'octaméthylcyclotetrasiloxane et/ou du decaméthylcyclopentasiloxane et/ou du dodecaméthylcyclohexasiloxane.
  15. Composition selon la revendication 10, caractérisée en ce que l'hydrocarbure volatil est un hydrocarbure de basse masse moléculaire, comprenant de 12 à 24 atomes de carbone, par exemple un hydrocarbure aliphatique de basse masse moléculaire comprenant de 12 à 16 atomes de carbone.
  16. Composition de conditionnement de cheveux selon la revendication 10, caractérisée en ce que l'hydrocarbure volatil présente un point d'ébullition à 25°C et sous pression atmosphérique compris entre 100 et 300°C et répond de préférence à la formule structurale :
    Figure imgb0031
     dans laquelle n est compris entre 2 et 5, et des mélanges de ceux-ci.
  17. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que le tensio-actif non ionique est présent à raison de 1 à 10% en poids de la composition.
  18. Composition selon l'une quelconque des vendications précédentes, caractérisée en ce que le tensio-actif non ionique est une pyrrolidone N-alkylée, contenant de préférence un radical alkyle de 10 à 16 atomes de carbone, par exemple la lauryl-pyrrolidone et/ou la décyl-pyrrolidone.
  19. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que le composé sé polyhydrique est présent en une quantité de 10 à 30% en poids de la composition, de préférence de 15 à 25% en poids de la composition et, surtout, de 18 à 22% en poids de la composition.
  20. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que le composé polyhydrique est un glycol, un triol, et/ou un polyol, et est choisi de préférence parmi l'éthylène-glycol, le propylène-glycol, le butylène-glycol, l'hexylène-glycol, le glycérol, le diéthylène-glycol, le triéthylène-glycol, le dipropylène-glycol, le tripropylène-glycol, le polypropylène-glycol ayant une masse moléculaire moyennen pouvant atteindre environ 500, le polyéthylène-glycol ayant une masse moléculaire moyenne pouvant atteindre environ 500 et des mélanges de ceux-ci.
  21. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que le véhicule liquide comprend de l'eau.
  22. Composition selon la revendication 21, caractérisée en ce que le véhicule liquide comprend en outre de 1 à 50% et, de préférence, de 5 à 25% par rapport au poids total du véhicule liquide, d'un alcool inférieur et/ ou d'un éther-glycol, choisi de préférence parmi l'alcool éthylique, l'alcool isopropylique, le 2-butoxyéthanol. l'éther monoéthylique d'éthylène-glycol, l'éther mono-éthylique de diéthylène-glycol, l'éther monométhylique de diéthylène-glyol et des combinaisons de ceux-ci.
  23. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce que son pH est de 4 à 7, de préférence de 5,5 à 6,5.
  24. Composition selon la revendication 1, caractérisée en ce que le composé d'ammonium quaternaire est le chlorure de dicétyldimonium ; l'amido-amine est la stéaramidopropyl-diméthylamine ; l'agent volatil de conditionnement est la cyclométhicone ; le tensioactif non ionique est la lauryl-pyrrolidone et le composé polyhydrique est l'hexylène-glycol.
  25. Composition selon la revendication 24, caractérisée en ce que le rapport pondéral de la lauryl-pyrrolidone à la cyclométhicone est compris entre 2:1 et 5:1 ; l'hexylène-glycol est présent en une quantité comprise entre 15 et 25% en poids ; et le pH de la composition est compris entre 5,5 et 6,5.
  26. Composition selon l'une quelconque des revendications précédentes, caractérisée en ce qu'elle est limpide.
  27. Procédé pour conférer des propriétés de conditionnement aux cheveux, caractérisé en ce qu'on met en contact les cheveux pendant une durée suffisante pour que les cheveux réagissent, avec une composition selon l'une quelconque des revendications précédentes et, de préférence, on rince ensuite les cheveux avec de l'eau.
EP90307451A 1989-05-31 1990-07-09 Composition traitante claire et méthode pour donner des propriétés de condition améliorées à la chevelure Expired - Lifetime EP0465734B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/359,483 US4954335A (en) 1989-05-31 1989-05-31 Clear conditioning composition and method to impart improved properties to the hair

Publications (2)

Publication Number Publication Date
EP0465734A1 EP0465734A1 (fr) 1992-01-15
EP0465734B1 true EP0465734B1 (fr) 1994-03-02

Family

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EP90307451A Expired - Lifetime EP0465734B1 (fr) 1989-05-31 1990-07-09 Composition traitante claire et méthode pour donner des propriétés de condition améliorées à la chevelure

Country Status (8)

Country Link
US (1) US4954335A (fr)
EP (1) EP0465734B1 (fr)
JP (1) JPH075453B2 (fr)
AT (1) ATE102013T1 (fr)
DE (1) DE69007097T2 (fr)
DK (1) DK0465734T3 (fr)
ES (1) ES2062377T3 (fr)
ZA (1) ZA905718B (fr)

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EP2764860A1 (fr) 2013-02-06 2014-08-13 Basf Sa Amidoamines d'acide gras de Cupuassu et de leurs dérivés

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US6858202B2 (en) 1999-05-27 2005-02-22 Johnson & Johnson Consumer Companies, Inc. Detergent compositions with enhanced depositing, conditioning and softness capabilities
US6908889B2 (en) 1999-05-27 2005-06-21 Johnson & Johnson Consumer Companies, Inc. Detergent composition with enhanced depositing, conditioning and softness capabilities
EP2764860A1 (fr) 2013-02-06 2014-08-13 Basf Sa Amidoamines d'acide gras de Cupuassu et de leurs dérivés

Also Published As

Publication number Publication date
JPH03128309A (ja) 1991-05-31
EP0465734A1 (fr) 1992-01-15
DE69007097T2 (de) 1994-06-01
ATE102013T1 (de) 1994-03-15
US4954335A (en) 1990-09-04
JPH075453B2 (ja) 1995-01-25
DK0465734T3 (da) 1994-05-09
ES2062377T3 (es) 1994-12-16
DE69007097D1 (de) 1994-04-07
ZA905718B (en) 1991-05-29

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