EP0448469A1 - Elastic and compressible blanket forming element - Google Patents
Elastic and compressible blanket forming element Download PDFInfo
- Publication number
- EP0448469A1 EP0448469A1 EP91400756A EP91400756A EP0448469A1 EP 0448469 A1 EP0448469 A1 EP 0448469A1 EP 91400756 A EP91400756 A EP 91400756A EP 91400756 A EP91400756 A EP 91400756A EP 0448469 A1 EP0448469 A1 EP 0448469A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- layer
- cellular rubber
- elasticity
- modulus
- blanket
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001971 elastomer Polymers 0.000 claims abstract description 40
- 230000001413 cellular effect Effects 0.000 claims abstract description 39
- 238000007639 printing Methods 0.000 claims abstract description 20
- 239000004744 fabric Substances 0.000 claims abstract description 15
- 230000006835 compression Effects 0.000 claims abstract description 10
- 238000007906 compression Methods 0.000 claims abstract description 10
- 229920001875 Ebonite Polymers 0.000 claims abstract description 6
- 239000012779 reinforcing material Substances 0.000 claims description 3
- 239000000806 elastomer Substances 0.000 claims description 2
- 238000007645 offset printing Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 80
- 239000000463 material Substances 0.000 description 7
- 238000006073 displacement reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N10/00—Blankets or like coverings; Coverings for wipers for intaglio printing
- B41N10/02—Blanket structure
- B41N10/04—Blanket structure multi-layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N10/00—Blankets or like coverings; Coverings for wipers for intaglio printing
- B41N10/02—Blanket structure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N2210/00—Location or type of the layers in multi-layer blankets or like coverings
- B41N2210/04—Intermediate layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N2210/00—Location or type of the layers in multi-layer blankets or like coverings
- B41N2210/06—Backcoats; Back layers; Bottom layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N2210/00—Location or type of the layers in multi-layer blankets or like coverings
- B41N2210/14—Location or type of the layers in multi-layer blankets or like coverings characterised by macromolecular organic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/909—Resilient layer, e.g. printer's blanket
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/24992—Density or compression of components
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249976—Voids specified as closed
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249976—Voids specified as closed
- Y10T428/249977—Specified thickness of void-containing component [absolute or relative], numerical cell dimension or density
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249981—Plural void-containing components
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3854—Woven fabric with a preformed polymeric film or sheet
- Y10T442/3911—Natural or synthetic rubber sheet or film
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/674—Nonwoven fabric with a preformed polymeric film or sheet
- Y10T442/679—Natural or synthetic rubber sheet or film
Definitions
- the present invention essentially relates to an elastic and compressible printing element, this element constituting what is called a blanket and can be fixed on the surface of cylinders that are found in printing machines.
- printing blankets currently used in printing machines essentially comprise a lithographic layer allowing the transfer of information from the blanket cylinder onto a strip of paper, and a compressible structure consisting of a layer of cellular rubber taken up sandwich between two fabric layers.
- Document FR-A-2 461 596 has also proposed a blanket essentially comprising a lithographic layer, a layer of cellular rubber and a stabilization or base layer composed of several layers of tissue adhered with neoprene.
- such a blanket is likely to generate high pressures in the interval between two cylinders carrying the blankets, while this should be avoided so as not to alter the structure of the blanket, and such a blanket can also present risks of shearing, that is to say of lateral displacement of the blanket material, which leads to the drawbacks mentioned above.
- the present invention aims to remedy all these drawbacks by proposing a blanket which will have no tendency, when compressed, to cause lateral displacements of the material which constitutes it so that the printing quality and the scrolling of the paper strip will remain satisfactory, and which will always exhibit a neutral dynamic behavior under the effect of a compression force.
- the subject of the invention is an elastic and compressible printing element of the type comprising a lithographic or printing layer with which is associated a structure with compressible layers, characterized in that said structure consists of at least one fabric layer or the like sandwiched between two layers of cellular rubber having identical or different compressibility properties.
- the layer of cellular rubber situated on the side of the lithographic layer has a higher modulus of elasticity in compression than the other layer of cellular rubber.
- the layer of lower modulus of elasticity is associated with a base layer of fabric or other reinforcing material.
- the layer of lower modulus of elasticity itself constitutes the base layer.
- the elastic and compressible printing element according to this invention also comprises a layer of hard and possibly reinforced elastomer, which is interposed between the lithographic layer and the layer of cellular rubber closest to this lithographic layer.
- the thickness of the fabric layer or the like is between approximately 0.1 and 1 mm, and the thicknesses of the two cellular rubber layers are each between 0.1 and 0, 8 mm.
- the thickness of the tissue layer or the like is 0.35 mm
- the thickness of the cellular layer with a lower modulus of elasticity is 0.5 mm
- the cellular rubber layer has higher modulus of elasticity is 0.45 mm.
- the thickness of the abovementioned layer of hard elastomer is between approximately 0.5 and 0.05 mm, and is preferably equal to 0.15 mm.
- the two above-mentioned cellular rubber layers have a modulus of elasticity of between approximately 0.2 and 50 megapascals (MPa) for the layer of modulus of elasticity plus high, and between about 0.1 and 25 MPa for the lower elasticity layer.
- the elastic modulus of the layer of cellular rubber located on the side of the lithographic layer is 10 MPa, while the elastic modulus of the other layer of cellular rubber is 5 MPa.
- the percentage by volume of the gas enclosed in the two layers of cellular rubber, preferably in closed cells is between approximately 10 and 80%, and is preferably equal to 30% for the layer of higher modulus of elasticity and 35% for the layer of lower modulus of elasticity.
- the invention also relates to the cylinders equipped with a printing element forming a blanket meeting the above characteristics.
- Figure 1 is an enlarged sectional view of a printing blanket according to the invention.
- Figure 2 is an enlarged sectional view of another embodiment of the blanket according to this invention.
- FIG. 3 schematically and partially illustrates two blankets according to this invention, in the compressed state, and carried respectively by two cylinders between which a strip of paper passes, the assembly being related to a reference system with axes of orthogonal coordinates where l he abscissa axis coincides with the direction of the paper strip and where the ordinate axis intersects the abscissa axis in the center of the compressed area of the two blankets.
- FIG. 4 represents three curves illustrating, in millimeters, the lateral displacement of the material constituting the blanket on either side of the center O of the compression zone - visible deformation in FIG. 3, as a function of the distance, from this point O and along the abscissa axis OX in FIG. 3, these three curves corresponding respectively to a blanket as commonly used today and which will be called hereinafter blanket of the prior art, a blanket according to document FR-A-2 461 596, and a blanket according to the invention.
- FIG. 5 also represents three curves illustrating the relative pressure in the interval between blankets, for the three blankets above, as a function of the position, on the axis of the abscissae OX, relative to the center O of the pressure zone .
- an elastic and compressible element or printing blanket successively comprises an external lithographic or printing layer 1, a layer of hard elastomer 2, a layer of cellular rubber 3, a layer of fabric or the like 4 and another layer 5 of cellular rubber.
- the blanket also has a base layer 6 of fabric or other suitable reinforcing material.
- the base layer 6 When fixing the blanket to a cylinder (not shown), the base layer 6 will be applied to the peripheral surface of this cylinder, while, in the case of the blanket of FIG. 1, the base layer applied to the cylinder consists of the layer of cellular rubber 5.
- the layers of cellular rubber 3 and 5 can be identical or different in terms of their elastic modulus in particular.
- the layer 3 located on the side of the lithographic layer 1 will have a higher modulus of elasticity in compression and between approximately 0.2 and 50 MPa, while the layer 5 forming the base layer (FIG. 1 ) or associated with the base layer 6 (FIG. 2) will have a lower modulus of elasticity between approximately 0.1 and 25 MPa.
- the modulus of elasticity of the layer 3 can be equal to 10 MPa, and the modulus of elasticity in compression of the other layer 5 of cellular rubber can be equal to 5 MPa.
- the difference in elastic modulus between the two layers of cellular rubber 3 and 5 can be obtained by varying the percentage by volume of the gas enclosed in the two layers, preferably in closed cells, as shown diagrammatically on the figures.
- the percentage in question may be equal to 30% for layer 3 of higher elastic modulus, and 35% for layer 5 of lower elastic modulus.
- the thicknesses of the two cellular rubber layers 3 and 5 can each be between 0.1 and 0.8 mm. We can thus provide a thickness of 0.45 mm for layer 3 and a thickness of 0.5 mm for layer 5.
- the thickness of the fabric layer or the like 4 sandwiched between the two cellular rubber layers 3 and 5 may be between approximately 0.1 and 1 mm and for example be equal to 0.35 mm.
- the thickness of the layer 2 of hard elastomer it will be between approximately 0.5 and 0.05 mm and will preferably be equal to 0.15 mm.
- the first column indicates the thicknesses in millimeters of the layers.
- the second column appear the successive layers of a blanket according to the invention and as shown in FIG. 2.
- the third column appear the successive layers of a blanket according to the prior art, which comprises, as mentioned at the beginning from this description, a layer of cellular rubber interposed between two layers of tissue, while the blanket of the invention comprises, conversely, a layer of tissue interposed between two layers of cellular rubber.
- the blanket layers according to document FR-A-2 461 596 which, it should be remembered, comprises only a single layer of cellular rubber and a base layer formed by several layers of fabric bonded with neoprene. In the three cases, as seen on the table, a hard elastomer layer is associated with the lithographic layer.
- FIG. 4 represents the displacement of material or the shear C as a function of the distance D relative to the center O of the pressure zone, and this for the three blankets of the table above.
- curve C1 which corresponds to the blanket of the invention is substantially flat, that is to say that practically no lateral movement of the blanket material according to the invention does not occurs, under compression, unlike the blanket of the prior art (curve C2) and the blanket according to document FR-A-2 461 596 (curve C3), which however has a less marked tendency to shear than the blanket according to the prior art (curve C2).
- the print quality and the movement of the strip of paper P passing between two blanket cylinders will be very greatly improved due to the absence of lateral displacement or surface shear.
- the blankets of the invention will have a neutral dynamic behavior on rolling on the strip of paper P.
- the blanket according to the invention is remarkable in particular from the point of view of the gain in compressibility and the absence of shear, which has an advantageous effect on the print quality of the paper, on the throughput or the flow of the paper, and on the longevity of the blanket, this essentially thanks to the provision in said blanket of a layer of sandwiched fabric between two layers of cellular rubber having identical or different modulus of elasticity.
Landscapes
- Printing Plates And Materials Therefor (AREA)
- Manufacture Or Reproduction Of Printing Formes (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Dental Preparations (AREA)
- Prostheses (AREA)
- Brushes (AREA)
Abstract
Description
La présente invention à essentiellement pour objet un élément élastique et compressible d'impression, cet élément constituant ce que l'on appelle un blanchet et pouvant être fixé sur la surface de cylindres que l'on trouve dans les machines à imprimer.The present invention essentially relates to an elastic and compressible printing element, this element constituting what is called a blanket and can be fixed on the surface of cylinders that are found in printing machines.
La plupart des blanchets d'impression actuellement utilisés dans les machines à imprimer comportent essentiellement une couche lithographique permettant le transfert d'informations du cylindre porte-blanchet sur une bande de papier, et une structure compressible constituée d'une couche en caoutchouc cellulaire prise en sandwich entre deux couches en tissu.Most printing blankets currently used in printing machines essentially comprise a lithographic layer allowing the transfer of information from the blanket cylinder onto a strip of paper, and a compressible structure consisting of a layer of cellular rubber taken up sandwich between two fabric layers.
Mais la compressibilité d'un tel blanchet, c'est-à-dire sa faculté de se déformer sous l'effet d'un effort exercé par la machine sur le cylindre porte-blanchet en appui sur un autre cylindre porte-blanchet, par exemple, demeure limitée. Dès lors un effort relativement important devra être exercé sur le blanchet et cet effort se traduira, à la longue, par un affaissement du blanchet qui ne reprendra plus son épaisseur ni sa géométrie initiales. Au surplus, il faut noter que, dans les machines à imprimer modernes et rapides, il se produira des échauffements favorisant l'affaissement du blanchet, et, bien évidemment la qualité de l'impression de la bande de papier passant entre les deux cylindres porte-blanchet et le défilement de cette bande seront fortement affectés.However, the compressibility of such a blanket, that is to say its ability to deform under the effect of a force exerted by the machine on the blanket cylinder bearing on another blanket cylinder, by example, remains limited. Consequently, a relatively large effort will have to be exerted on the blanket and this effort will result, in the long run, in a sagging of the blanket which will no longer resume its initial thickness or geometry. In addition, it should be noted that, in modern and fast printing machines, there will be overheating favoring the sagging of the blanket, and, obviously, the quality of the printing of the strip of paper passing between the two cylinders carries -blanchet and the scrolling of this strip will be strongly affected.
En outre, avec de tels blanchets qui sont peu compressibles et qui engendrent de fortes pressions pour un intervalle donné entre les deux cylindres porte-blanchet, il y a des risques de cisaillement importants. Plus précisément, le matériau qui constitue le blanchet tend à se déplacer latéralement pour former en quelque sorte des protubérances, ce qui est hautement préjudiciable à la qualité d'impression de la bande de papier et au défilement correct de cette bande.In addition, with such blankets which are not very compressible and which generate high pressures for a given interval between the two cylinders blanket holder, there is a significant risk of shearing. More precisely, the material which constitutes the blanket tends to move laterally in a way to form protuberances, which is highly detrimental to the print quality of the paper strip and to the correct running of this strip.
On a également proposé dans le document FR-A-2 461 596 un blanchet comprenant essentiellement une couche lithographique, une couche en caoutchouc cellulaire et une couche de stabilisation ou de base composée de plusieurs couches de tissu adhérisées avec du néoprène.Document FR-A-2 461 596 has also proposed a blanket essentially comprising a lithographic layer, a layer of cellular rubber and a stabilization or base layer composed of several layers of tissue adhered with neoprene.
Mais, là encore, un tel blanchet est susceptible d'engendrer des pressions élevées dans l'intervalle entre deux cylindres portant les blanchets, alors que cela devra être évité de façon à ne pas altérer la structure du blanchet, et un tel blanchet peut aussi présenter des risques de cisaillement, c'est-à-dire de déplacement latéral du matériau du blanchet, ce qui conduit aux inconvénients mentionnés plus hauts.But, here again, such a blanket is likely to generate high pressures in the interval between two cylinders carrying the blankets, while this should be avoided so as not to alter the structure of the blanket, and such a blanket can also present risks of shearing, that is to say of lateral displacement of the blanket material, which leads to the drawbacks mentioned above.
Aussi, la présente invention a pour but de remédier à tous ces inconvénients en proposant un blanchet qui n'aura aucune tendance, lorsqu'il est comprimé, à provoquer des déplacements latéraux du matériau qui le constitue de sorte que la qualité d'impression et le défilement de la bande de papier demeureront satisfaisants, et qui présentera toujours un comportement dynamique neutre sous l'effet d'un effort de compression.Also, the present invention aims to remedy all these drawbacks by proposing a blanket which will have no tendency, when compressed, to cause lateral displacements of the material which constitutes it so that the printing quality and the scrolling of the paper strip will remain satisfactory, and which will always exhibit a neutral dynamic behavior under the effect of a compression force.
A cet effet, l'invention a pour objet un élément élastique et compressible d'impression du type comprenant une couche lithographique ou d'impression à laquelle est associée une structure à couches compressibles, caractérisé en ce que ladite structure est constituée par au moins une couche en tissu ou analogue prise en sandwich entre deux couches de caoutchouc cellulaire possédant des propriétés de compressibilité identiques ou différentes.To this end, the subject of the invention is an elastic and compressible printing element of the type comprising a lithographic or printing layer with which is associated a structure with compressible layers, characterized in that said structure consists of at least one fabric layer or the like sandwiched between two layers of cellular rubber having identical or different compressibility properties.
Suivant une réalisation préférée, la couche de caoutchouc cellulaire située du côté de la couche lithographique possède un module d'élasticité en compression plus élevé que l'autre couche de caoutchouc cellulaire.According to a preferred embodiment, the layer of cellular rubber situated on the side of the lithographic layer has a higher modulus of elasticity in compression than the other layer of cellular rubber.
Suivant une autre caractéristique de l'invention, à la couche de module d'élasticité plus faible est associée une couche de base en tissu ou autre matière renforçante.According to another characteristic of the invention, the layer of lower modulus of elasticity is associated with a base layer of fabric or other reinforcing material.
Selon un autre mode de réalisation, la couche de module d'élasticité plus faible constitue elle même la couche de base.According to another embodiment, the layer of lower modulus of elasticity itself constitutes the base layer.
L'élément élastique et compressible d'impression selon cette invention comprend encore une couche d'élastomère dure et éventuellement renforcée, qui est interposée entre la couche lithographique et la couche de caoutchouc cellulaire la plus proche de cette couche lithographique.The elastic and compressible printing element according to this invention also comprises a layer of hard and possibly reinforced elastomer, which is interposed between the lithographic layer and the layer of cellular rubber closest to this lithographic layer.
Suivant encore une autre caractéristique de l'invention, l'épaisseur de la couche en tissu ou analogue est comprise entre environ 0,1 et 1 mm, et les épaisseurs des deux couches en caoutchouc cellulaire sont chacune comprises entre 0,1 et 0,8 mm.According to yet another characteristic of the invention, the thickness of the fabric layer or the like is between approximately 0.1 and 1 mm, and the thicknesses of the two cellular rubber layers are each between 0.1 and 0, 8 mm.
Selon une réalisation préférée, l'épaisseur de la couche de tissu ou analogue est de 0,35 mm, l'épaisseur de la couche cellulaire à module d'élasticité plus faible est de 0,5 mm, et la couche de caoutchouc cellulaire à module d'élasticité plus élevé est de 0,45 mm.According to a preferred embodiment, the thickness of the tissue layer or the like is 0.35 mm, the thickness of the cellular layer with a lower modulus of elasticity is 0.5 mm, and the cellular rubber layer has higher modulus of elasticity is 0.45 mm.
On précisera encore ici que l'épaisseur de la couche précitée d'élastomère dure est comprise entre environ 0,5 et 0,05 mm, et est de préférence égale à 0,15 mm.It will also be specified here that the thickness of the abovementioned layer of hard elastomer is between approximately 0.5 and 0.05 mm, and is preferably equal to 0.15 mm.
Suivant encore une autre caractéristique de l'élément d'impression selon cette invention, les deux couches de caoutchouc cellulaire précitées possèdent un module d'élasticité compris entre environ 0,2 et 50 mégapascals (MPa) pour la couche de module d'élasticité plus élevé, et entre environ 0,1 et 25 MPa pour la couche d'élasticité plus faible.According to yet another characteristic of the printing element according to this invention, the two above-mentioned cellular rubber layers have a modulus of elasticity of between approximately 0.2 and 50 megapascals (MPa) for the layer of modulus of elasticity plus high, and between about 0.1 and 25 MPa for the lower elasticity layer.
Suivant une réalisation préférée, le module d'élasticité de la couche de caoutchouc cellulaire située du côté de la couche lithographique est de 10 MPa, tandis que le module d'élasticité de l'autre couche de caoutchouc cellulaire est de 5 MPa.According to a preferred embodiment, the elastic modulus of the layer of cellular rubber located on the side of the lithographic layer is 10 MPa, while the elastic modulus of the other layer of cellular rubber is 5 MPa.
On précisera encore ici que le pourcentage en volume du gaz enfermé dans les deux couches de caoutchouc cellulaire, de préférence dans des cellules fermées, est compris entre environ 10 et 80%, et est de préférence égal à 30% pour la couche de module d'élasticité plus élevé et à 35% pour la couche de module d élasticité plus faible.It will also be specified here that the percentage by volume of the gas enclosed in the two layers of cellular rubber, preferably in closed cells, is between approximately 10 and 80%, and is preferably equal to 30% for the layer of higher modulus of elasticity and 35% for the layer of lower modulus of elasticity.
L'invention vise également les cylindres équipés d'un élément d'impression formant blanchet répondant aux caractéristiques ci-dessus.The invention also relates to the cylinders equipped with a printing element forming a blanket meeting the above characteristics.
Mais d'autres caractéristiques et avantages de l'invention apparaîtront mieux dans la description détaillée qui suit et se réfère aux dessins annexés, donnés uniquement à titre d'exemple, et dans lesquels.However, other characteristics and advantages of the invention will appear better in the detailed description which follows and refers to the appended drawings, given solely by way of example, and in which.
La figure 1 est une vue en coupe agrandie d'un blanchet d'impression conforme à l'invention.Figure 1 is an enlarged sectional view of a printing blanket according to the invention.
La figure 2 est une vue en coupe agrandie d'un autre mode de réalisation de blanchet selon cette invention.Figure 2 is an enlarged sectional view of another embodiment of the blanket according to this invention.
La figure 3 illustre schématiquement et partiellement deux blanchets selon cette invention, à l'état comprimé, et portés respectivement par deux cylindres entre lesquels passe une bande de papier, l'ensemble étant rapporté à un système de référence à axes de coordonnées orthogonaux où l'axe des abscisses est confondu avec la direction de la bande de papier et où l'axe des ordonnées coupe l'axe des abscisses au centre de la zone comprimée des deux blanchets.FIG. 3 schematically and partially illustrates two blankets according to this invention, in the compressed state, and carried respectively by two cylinders between which a strip of paper passes, the assembly being related to a reference system with axes of orthogonal coordinates where l he abscissa axis coincides with the direction of the paper strip and where the ordinate axis intersects the abscissa axis in the center of the compressed area of the two blankets.
La figure 4 représente trois courbes illustrant, en millimètres, le déplacement latéral du matériau constituant le blanchet de part et d'autre du centre O de la zone de compression - déformation visible sur la figure 3, en fonction de la distance, à partir de ce point O et suivant l'axe des abscisses OX sur la figure 3, ces trois courbes correspondant respectivement à un blanchet tel que couramment utilisé actuellement et que l'on appellera ci-après blanchet de l'art antérieur, à un blanchet suivant le document FR-A-2 461 596, et à un blanchet selon l'invention.FIG. 4 represents three curves illustrating, in millimeters, the lateral displacement of the material constituting the blanket on either side of the center O of the compression zone - visible deformation in FIG. 3, as a function of the distance, from this point O and along the abscissa axis OX in FIG. 3, these three curves corresponding respectively to a blanket as commonly used today and which will be called hereinafter blanket of the prior art, a blanket according to document FR-A-2 461 596, and a blanket according to the invention.
La figure 5 représente encore trois courbes illustrant la pression relative dans l'intervalle entre blanchets, pour les trois blanchets ci-dessus, en fonction de la position, sur l'axe des abscisses OX, par rapport au centre O de la zone de pression.FIG. 5 also represents three curves illustrating the relative pressure in the interval between blankets, for the three blankets above, as a function of the position, on the axis of the abscissae OX, relative to the center O of the pressure zone .
Suivant l'exemple de réalisation représenté sur la figure 1, un élément élastique et compressible ou blanchet d'impression selon cette invention comprend successivement une couche externe lithographique ou d'impression 1, une couche d'élastomère dure 2, une couche de caoutchouc cellulaire 3, une couche en tissu ou analogue 4 et une autre couche 5 en caoutchouc cellulaire.According to the embodiment shown in FIG. 1, an elastic and compressible element or printing blanket according to this invention successively comprises an external lithographic or
Dans la variante représentée sur la figure 2, on retrouve dans le même ordre, les couches 1 à 5 mentionnées ci-dessus, mais ici, le blanchet comporte en plus une couche de base 6 en tissu ou autre matière renforçante appropriée.In the variant shown in Figure 2, there are in the same order, the
Lors de la fixation du blanchet sur un cylindre (non représenté), la couche de base 6 sera appliquée sur la surface périphérique de ce cylindre, alors que, dans le cas du blanchet de la figure 1, la couche de base appliquée sur le cylindre est constituée par la couche de caoutchouc cellulaire 5.When fixing the blanket to a cylinder (not shown), the
Dans les deux modes de réalisation représentés aux figures 1 et 2, les couches de caoutchouc cellulaire 3 et 5 peuvent être identiques ou différentes sur le plan de leur module d'élasticité notamment.In the two embodiments shown in FIGS. 1 and 2, the layers of
D'une façon préférée, la couche 3 située du côté de la couche lithographique 1 possèdera un module d'élasticité en compression plus élevé et compris entre environ 0,2 et 50 MPa, tandis que la couche 5 formant couche de base (figure 1) ou associée à la couche de base 6 (figure 2) possèdera un module d'élasticité plus faible et compris entre environ 0,1 et 25 MPa. C'est ainsi que le module d'élasticité de la couche 3 peut être égal à 10 MPa, et le module d'élasticité en compression de l'autre couche 5 de caoutchouc cellulaire pourra être égal à 5 MPa.Preferably, the
On observera ici que la différence de module d'élasticité entre les deux couches de caoutchouc cellulaire 3 et 5 pourra être obtenue par une variation du pourcentage en volume du gaz enfermé dans les deux couches, de préférence dans des cellules fermées, comme montré schématiquement sur les figures. Ainsi, le pourcentage en question pourra être égal à 30% pour la couche 3 de module d'élasticité plus élevé, et à 35% pour la couche 5 de module d'élasticité plus faible.It will be observed here that the difference in elastic modulus between the two layers of
Quant aux épaisseurs des deux couches en caoutchouc cellulaire 3 et 5, elles peuvent être comprises chacune entre 0,1 et 0,8 mm. On pourra ainsi prévoir une épaisseur de 0,45 mm pour la couche 3 et une épaisseur de 0,5 mm pour la couche 5.As for the thicknesses of the two
L'épaisseur de la couche en tissu ou analogue 4 prise en sandwich entre les deux couches en caoutchouc cellulaire 3 et 5 pourra être comprise entre environ 0,1 et 1 mm et être par exemple égale à 0,35 mm.The thickness of the fabric layer or the like 4 sandwiched between the two
Quant à l'épaisseur de la couche 2 en élastomère dure, elle sera comprise entre environ 0,5 et 0,05 mm et sera de préférence égale à 0,15 mm.As for the thickness of the
Mais, pour une meilleure compréhension de l'invention, on expliquera ci-après l'intérêt et les avantages exceptionnels du blanchet de l'invention comparativement à un blanchet de l'art antérieur, c'est-à-dire un blanchet du type couramment utilisé aujourd'hui, et à un blanchet selon le document FR-A-2 461 596.But, for a better understanding of the invention, the interest and the exceptional advantages of the blanket of the invention will be explained below compared to a blanket of the prior art, that is to say a blanket of the type commonly used today, and a blanket according to document FR-A-2 461 596.
On se reportera au tableau qui suit et qui énonce les diverses couches des trois blanchets ci-dessus et pour lesquelles on a adopté une même épaisseur de façon que les résultats soient comparables. Reference is made to the table which follows and which states the various layers of the three blankets above and for which the same thickness has been adopted so that the results are comparable.
Plus précisément, on voit sur ce tableau, à partir de la gauche, que la première colonne indique les épaisseurs en millimètres des couches. Dans la deuxième colonne figurent les couches successives d'un blanchet selon l'invention et tel que représenté sur la figure 2. Dans la troisième colonne figurent les couches successives d'un blanchet selon l'art antérieur, qui comporte, comme mentionné au début de cette description, une couche de caoutchouc cellulaire interposée entre deux couches de tissu, alors que le blanchet de l'invention comporte, à l'inverse, une couche de tissu interposée entre deux couches de caoutchouc cellulaire. Enfin, dans la quatrième colonne du tableau, figurent les couches du blanchet selon le document FR-A-2 461 596 qui, rappelons-le, ne comporte qu'une seule couche de caoutchouc cellulaire et une couche de base formée de plusieurs couches de tissu adhérisées avec du néoprène. Dans les trois cas, comme on le voit sur le tableau, une couche dure en élastomère est associée à la couche lithographique.More precisely, we see on this table, from the left, that the first column indicates the thicknesses in millimeters of the layers. In the second column appear the successive layers of a blanket according to the invention and as shown in FIG. 2. In the third column appear the successive layers of a blanket according to the prior art, which comprises, as mentioned at the beginning from this description, a layer of cellular rubber interposed between two layers of tissue, while the blanket of the invention comprises, conversely, a layer of tissue interposed between two layers of cellular rubber. Finally, in the fourth column of the table, there are the blanket layers according to document FR-A-2 461 596 which, it should be remembered, comprises only a single layer of cellular rubber and a base layer formed by several layers of fabric bonded with neoprene. In the three cases, as seen on the table, a hard elastomer layer is associated with the lithographic layer.
Le comportement à la compression des trois blanchets ci-dessus a été étudié pour ce qui concerne la matière du blanchet qui est chassée ou déplacée, lors de la compression, à droite et/ou à gauche du centre O de la zone de pression, comme matérialisé par les flèches F sur la figure 3.The compression behavior of the three blankets above has been studied with regard to the blanket material which is driven out or displaced, during compression, to the right and / or left of the center O of the pressure zone, as materialized by the arrows F in Figure 3.
On se reportera à la figure 4 qui représente le déplacement de matière ou le cisaillement C en fonction de la distance D par rapport au centre O de la zone de pression, et cela pour les trois blanchets du tableau ci-dessus. On voit tout de suite que la courbe C1 qui correspond au blanchet de l'invention est sensiblement plate, c'est-à-dire que pratiquement aucun déplacement latéral de la matière du blanchet selon l'invention ne se produit, à la compression, contrairement au blanchet de l'art antérieur (courbe C2) et au blanchet selon le document FR-A-2 461 596 (courbe C3), qui toutefois présente une tendance moins marquée au cisaillement que le blanchet selon l'art antérieur (courbe C2).Reference will be made to FIG. 4 which represents the displacement of material or the shear C as a function of the distance D relative to the center O of the pressure zone, and this for the three blankets of the table above. It can be seen immediately that the curve C1 which corresponds to the blanket of the invention is substantially flat, that is to say that practically no lateral movement of the blanket material according to the invention does not occurs, under compression, unlike the blanket of the prior art (curve C2) and the blanket according to document FR-A-2 461 596 (curve C3), which however has a less marked tendency to shear than the blanket according to the prior art (curve C2).
Ainsi, on comprend qu'avec le blanchet de l'invention, la qualité d'impression et le défilement de la bande de papier P passant entre deux cylindres porte-blanchet (figure 3) seront très fortement améliorés en raison de l'absence de déplacement latéral ou de cisaillement en surface. C'est dire que les blanchets de l'invention auront un comportement dynamique neutre au roulage sur la bande de papier P.Thus, it is understood that with the blanket of the invention, the print quality and the movement of the strip of paper P passing between two blanket cylinders (FIG. 3) will be very greatly improved due to the absence of lateral displacement or surface shear. This means that the blankets of the invention will have a neutral dynamic behavior on rolling on the strip of paper P.
Par ailleurs, il convient d'observer que pour une distance AA′ donnée par la machine (voir figure 3), il y a intérêt à avoir une pression engendrée plus faible. Autrement dit, il y a intérêt à obtenir un gain en compressibilité de façon notamment, comme expliqué au début de cette description, à éviter un affaissement à la longue du blanchet.Furthermore, it should be observed that for a distance AA ′ given by the machine (see FIG. 3), it is advantageous to have a lower generated pressure. In other words, it is advantageous to obtain a gain in compressibility so as in particular, as explained at the beginning of this description, to avoid collapse in the long run of the blanket.
Ce gain en compressibilité est clairement illustré par la courbe C4 de la figure 5 correspondant au blanchet selon cette invention. Cette courbe montre que le gain en compressibilité par rapport aux blanchets de l'art antérieur (courbe C5) et aux blanchets selon le document FR-A-2 461 596 (courbe C6) est nettement amélioré, ces dernières présentant cependant un certain gain en compressibilité, par rapport aux blanchets de l'art antérieur (courbe C5).This gain in compressibility is clearly illustrated by the curve C4 in FIG. 5 corresponding to the blanket according to this invention. This curve shows that the gain in compressibility compared to the blankets of the prior art (curve C5) and the blankets according to document FR-A-2 461 596 (curve C6) is significantly improved, the latter however having a certain gain in compressibility, compared to the blankets of the prior art (curve C5).
Il résulte de tout ce qui précède que le blanchet selon l'invention est remarquable notamment du point de vue du gain en compressibilité et de l'absence de cisaillement, ce qui se répercute avantageusement sur la qualité d'impression du papier, sur le débit ou le défilement du papier, et sur la longévité du blanchet, cela essentiellement grâce à la prévision dans ledit blanchet d'une couche de tissu prise en sandwich entre deux couches de caoutchouc cellulaire possédant des modules d'élasticité identiques ou différents.It follows from all of the above that the blanket according to the invention is remarkable in particular from the point of view of the gain in compressibility and the absence of shear, which has an advantageous effect on the print quality of the paper, on the throughput or the flow of the paper, and on the longevity of the blanket, this essentially thanks to the provision in said blanket of a layer of sandwiched fabric between two layers of cellular rubber having identical or different modulus of elasticity.
Bien entendu, l'invention n'est nullement limitée aux modes de réalisation décrits et illustrés qui n'ont été donnés qu'à titre d'exemple.Of course, the invention is in no way limited to the embodiments described and illustrated which have been given only by way of example.
Au contraire, l'invention comprend tous les équivalents techniques des moyens décrits ainsi que leurs combinaisons, si celles-ci sont effectuées suivant son esprit.On the contrary, the invention includes all the technical equivalents of the means described as well as their combinations, if these are carried out according to the spirit.
Claims (11)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9003771A FR2659903B1 (en) | 1990-03-23 | 1990-03-23 | ELASTIC AND COMPRESSIBLE PRINTING ELEMENT FORMING BLANCHET. |
FR9003771 | 1990-03-23 |
Publications (2)
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EP0448469A1 true EP0448469A1 (en) | 1991-09-25 |
EP0448469B1 EP0448469B1 (en) | 1995-02-15 |
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EP91400756A Expired - Lifetime EP0448469B1 (en) | 1990-03-23 | 1991-03-20 | Elastic and compressible blanket forming element |
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US (1) | US5431989A (en) |
EP (1) | EP0448469B1 (en) |
JP (1) | JP3057104B2 (en) |
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CA (1) | CA2038909C (en) |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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DE4315456A1 (en) * | 1993-05-10 | 1993-11-18 | Ritz Karl Friedrich Axel Prof | Dye-carrying current for offset and flexo printing - has compressible elastomer layer(s) on flexible substrate |
FR2718079A1 (en) * | 1994-03-31 | 1995-10-06 | Rollin Sa | Improved printing blanket and printing cylinder equipped with this blanket. |
US5860360A (en) * | 1996-12-04 | 1999-01-19 | Day International, Inc. | Replaceable printing sleeve |
WO1999036270A1 (en) * | 1998-01-15 | 1999-07-22 | Day International, Inc. | Replaceable sleeve |
WO2003086760A1 (en) * | 2002-04-11 | 2003-10-23 | Koenig & Bauer Aktiengesellschaft | Characterization, detection of a reference number, and selection of suitable winding materials for rollers of a printing press |
USRE38468E1 (en) | 1996-12-04 | 2004-03-23 | Day International, Inc. | Replaceable sleeve |
EP1525997A1 (en) * | 2003-10-21 | 2005-04-27 | Koenig & Bauer Aktiengesellschaft | Blanket on a roller and printing units of a printing machine equipped with the roller |
US7055428B2 (en) | 2002-04-11 | 2006-06-06 | Koenig & Bauer Aktiengesellschaft | Characterization, determination of a characteristic number and selection of suitable dressings on cylinders of a printing press |
WO2008113621A1 (en) * | 2007-03-22 | 2008-09-25 | Contitech Elastomer Beschichtungen Gmbh | Printing blanket having a non-stretchable carrier layer |
Families Citing this family (13)
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KR970702158A (en) * | 1994-03-28 | 1997-05-13 | 하시모토 신이치 | LITHOGRAPHIC FORM PLATE |
WO1996025295A1 (en) * | 1995-02-14 | 1996-08-22 | Toray Industries, Inc. | Lithographic form plate |
IL114992A0 (en) * | 1995-08-17 | 1995-12-08 | Indigo Nv | Intermediate transfer blanket and method of producing the same |
JP3357587B2 (en) * | 1997-11-14 | 2002-12-16 | 住友ゴム工業株式会社 | Printing blanket |
JP3467456B2 (en) * | 1999-09-10 | 2003-11-17 | 住友ゴム工業株式会社 | Printing blanket |
US6640711B2 (en) * | 2002-01-15 | 2003-11-04 | Michael A. Smoot | Bridge mandrel for use as a repeat builder in a printing machine |
DE10237205B4 (en) | 2002-04-18 | 2009-02-12 | Koenig & Bauer Aktiengesellschaft | Elevator on a roller, arrangements of the roller to a second roller and printing units of a printing press with the roller |
JP4041378B2 (en) * | 2002-10-28 | 2008-01-30 | 株式会社明治ゴム化成 | Blanket for printing |
JP4486313B2 (en) * | 2003-03-31 | 2010-06-23 | 株式会社明治ゴム化成 | Image transfer sheet |
DE102004056389B4 (en) * | 2004-09-16 | 2008-05-21 | Koenig & Bauer Aktiengesellschaft | Printing unit of an offset printing press with at least one forme cylinder and one transfer cylinder |
EP2070717B1 (en) | 2007-12-10 | 2013-05-15 | Folex Coating GmbH | Method for mounting a rubber blanket in offset printing |
IT1401471B1 (en) | 2010-06-28 | 2013-07-26 | Trelleborg Engineered Systems Italy S P A | ARMOR FOR COVERING OF CYLINDERS FOR PRINTING WITH DOUBLE LAYER COMPRIMIBLE BASE POLYMERIC |
FR2970953B1 (en) * | 2011-02-01 | 2014-01-03 | Gascogne Laminates | FILM FOR PACKAGING PRODUCT, IN PARTICULAR AN ENVELOPE |
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- 1991-03-20 EP EP91400756A patent/EP0448469B1/en not_active Expired - Lifetime
- 1991-03-20 ES ES91400756T patent/ES2071245T3/en not_active Expired - Lifetime
- 1991-03-20 DE DE69107317T patent/DE69107317T2/en not_active Expired - Fee Related
- 1991-03-20 DK DK91400756.2T patent/DK0448469T3/en active
- 1991-03-20 DE DE199191400756T patent/DE448469T1/en active Pending
- 1991-03-20 AT AT91400756T patent/ATE118406T1/en not_active IP Right Cessation
- 1991-03-22 ZA ZA912201A patent/ZA912201B/en unknown
- 1991-03-22 AU AU73770/91A patent/AU639540B2/en not_active Ceased
- 1991-03-22 JP JP3083295A patent/JP3057104B2/en not_active Expired - Fee Related
- 1991-03-22 CA CA002038909A patent/CA2038909C/en not_active Expired - Fee Related
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DE4315456A1 (en) * | 1993-05-10 | 1993-11-18 | Ritz Karl Friedrich Axel Prof | Dye-carrying current for offset and flexo printing - has compressible elastomer layer(s) on flexible substrate |
FR2718079A1 (en) * | 1994-03-31 | 1995-10-06 | Rollin Sa | Improved printing blanket and printing cylinder equipped with this blanket. |
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US7055428B2 (en) | 2002-04-11 | 2006-06-06 | Koenig & Bauer Aktiengesellschaft | Characterization, determination of a characteristic number and selection of suitable dressings on cylinders of a printing press |
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WO2008113621A1 (en) * | 2007-03-22 | 2008-09-25 | Contitech Elastomer Beschichtungen Gmbh | Printing blanket having a non-stretchable carrier layer |
Also Published As
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ZA912201B (en) | 1992-01-29 |
ES2071245T3 (en) | 1995-06-16 |
NZ237510A (en) | 1992-11-25 |
JPH04221699A (en) | 1992-08-12 |
FR2659903B1 (en) | 1994-11-04 |
ATE118406T1 (en) | 1995-03-15 |
EP0448469B1 (en) | 1995-02-15 |
DK0448469T3 (en) | 1995-07-17 |
DE69107317T2 (en) | 1995-09-28 |
US5431989A (en) | 1995-07-11 |
JP3057104B2 (en) | 2000-06-26 |
CA2038909A1 (en) | 1991-09-24 |
DE448469T1 (en) | 1992-08-13 |
DE69107317D1 (en) | 1995-03-23 |
CA2038909C (en) | 2002-05-28 |
AU639540B2 (en) | 1993-07-29 |
AU7377091A (en) | 1991-10-03 |
FR2659903A1 (en) | 1991-09-27 |
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