EP0435968B2 - Verfahren zur herstellung von umformteilen aus coilbreak-freiem warmband - Google Patents
Verfahren zur herstellung von umformteilen aus coilbreak-freiem warmband Download PDFInfo
- Publication number
- EP0435968B2 EP0435968B2 EP90906870A EP90906870A EP0435968B2 EP 0435968 B2 EP0435968 B2 EP 0435968B2 EP 90906870 A EP90906870 A EP 90906870A EP 90906870 A EP90906870 A EP 90906870A EP 0435968 B2 EP0435968 B2 EP 0435968B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel
- hot strip
- strip
- hot
- coil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 33
- 239000010959 steel Substances 0.000 claims abstract description 33
- 239000010936 titanium Substances 0.000 claims abstract description 25
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 24
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 238000004804 winding Methods 0.000 claims 1
- 238000005275 alloying Methods 0.000 abstract description 9
- 230000007774 longterm Effects 0.000 abstract 1
- 230000032683 aging Effects 0.000 description 19
- 238000010586 diagram Methods 0.000 description 13
- 239000000523 sample Substances 0.000 description 10
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 7
- 239000011572 manganese Substances 0.000 description 6
- 239000010955 niobium Substances 0.000 description 5
- 229910052758 niobium Inorganic materials 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 238000000418 atomic force spectrum Methods 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000012946 outsourcing Methods 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000004881 precipitation hardening Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
Definitions
- the invention relates to a method for producing formed parts from a hot strip.
- the hot strip to be unwound can work without braking or without sufficient tension between the unwinding system and the introduction rolls of a processing system both in a large arc and also run in a tight arc, depending on whether it is leading or lagging behind. Especially when it comes to small bow and with frequent changes between leading and lagging, which is too strong Beats in the strip, coil breaks occur as serious damage to the strip surface. Fast uncoiling has a particularly strong hitting and accordingly strong coil breaks Episode.
- Coil breaks between the straightening rolls can also occur. Due to the sinusoidal continuous bending of the band, the tension in the different band sections is distributed unevenly, so that flow can start at different loads. Coil breaks can no longer be eliminated by subsequent straightening, bending, pickling or skin-dressing. The tendency towards coil breaks increases the softer, thinner and narrower the hot strip to be unwound. The same applies to smaller coil diameters.
- the object of the invention is therefore to provide a method for producing soft coilbreak-free Steel strip with permanent yield point elongation and good mechanical properties to indicate the lowest possible consumption of alloying elements.
- the manufacturing method according to the invention for the formed parts from hot strip provides for a defined titanium content in the steel to be made more uniform, which has the following analytical values in% by weight: C 0.02 - 0.08% Si 0.01 - 0.40% Mn 0.05-1.00% P 0.002 - 0.025% S 0.001 - 0.015% al 0.015-0.080% N ⁇ 0.0080% Ti > 0.04 - 0.080%
- Remainder iron and unavoidable impurities whereby the steel is cast into slabs using the continuous casting process and then finished from a slab heated from room temperature to over 1100 ° C. to a hot strip of 2 to 6 mm thickness at temperatures above the Ar 3 point, at temperatures of 550 to reel up to 400 ° C.
- the hot strip has an almost constant yield strength of less than 350 N / mm 2 in the freshly rolled state and after prolonged aging.
- the titanium content of the steel for the production of coilbreak-free hot strip with a longer-term Elongation at stretch is set according to the invention so that it is larger than for setting Nitrogen, but less than is stoichiometrically necessary for the additional setting of carbon.
- Hot strip remains coilbreak-free even after prolonged cold or warm aging, has good mechanical properties and can be produced with low consumption of alloying elements.
- Examples of the coil break-free hot strip produced according to the invention and comparison strips are based on the composition in Table 1 (extract from the melt analysis), final rolling temperature and coil temperature characterized hot strip samples.
- the steel strip is cooled in the coil in still air in relatively fresh rolling Condition assembled as hot strip or for cutting, punching or Bent parts machined after decoiling.
- coil breaks can be done Avoid if the hot strip has been previously treated or if a special additional, and therefore expensive, Wrapping process with the help of a so-called McKay roll system, with the deliberately minimal, technically ineffective coil breaks can be used.
- the uniformity of the yield point elongation occurs in all examined sample layers.
- Table 2 in all sample layers with a steel with 0.033% by weight carbon, 0.20% by weight manganese and 0.04% by weight titanium and a reel temperature of 450 ° C., the yield strength and tensile strength values according to the method according to the invention achieved that correspond to those of the known soft, non-microalloyed grades according to US standard SAE 1006/1008.
- this material is characterized by high elongation values of around 45% (A 5 standard sample).
- Oil filter lids were produced from this tape and had such a flat surface that they did not need to be reworked.
- formed parts can advantageously be produced from the coilbreak-free hot strip, the surface of which has to meet increased requirements.
- Hot strip / melt sample Location R eH N / mm 2 R m N / mm 2 FIG.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Coating With Molten Metal (AREA)
- Heat Treatment Of Steel (AREA)
- Vessels, Lead-In Wires, Accessory Apparatuses For Cathode-Ray Tubes (AREA)
Description
Coilbreaks sind durch ein nachträgliches Richten, Biegen, Beizen oder Dressieren nicht mehr zu beseitigen. Die Neigung zu Coilbreaks nimmt zu, je weicher, dünner und schmaler das abzuwickelnde Warmband ist. Gleiches gilt auch für kleiner werdende Coildurchmesser.
- N, der durch Bildung von Aluminiumnitrid vermeidbar sei sowie
- hoher Haspeltemperatur,
- Abschreckalterung durch die Feuerverzinkung aufgrund des Kohlenstoffgehaltes beschrieben.
Das Band wurde gehaspelt. die Haspeltemperaturen betrugen zum Beispiel 490, 500, 450, 430, 710 und 500 °C.
| C | 0,02 - 0,08 % |
| Si | 0,01 - 0,40 % |
| Mn | 0,05-1,00 % |
| P | 0,002 - 0,025 % |
| S | 0,001 - 0,015 % |
| Al | 0,015-0,080 % |
| N | ≦ 0,0080 % |
| Ti | >0,04 - 0,080 % |
Vielmehr kommt es erfindungsgemäß darauf an, daß das Warmband bei Bestehen einer ausgeprägten Streckgrenze eine möglichst gleichmäßige Streckgrenzendehnung aufweist, beziehungsweise im Spannungs-Dehnungs-Diagramm oder Kraft-Verlängerungs-Diagramm im Bereich der Streckgrenzendehnung die Spannung keine alternierenden Maxima und Minima, also einen möglichst glatten Verlauf hat. Damit wird das bisher bestehende Vorurteil überwunden, daß es zur Vermeidung von Fließfiguren oder Coilbreaks notwendig sei, das Auftreten einer ausgeprägten Streckgrenze zu vermeiden. Das erfindungsgemäße. Warmband bleibt auch bei längerer kalter oder warmer Auslagerung coilbreak-frei, weist gute mechanische Eigenschaften auf und kann bei geringem Verbrauch an Legierungselementen hergestellt werden.
- Fig. 1
- die gemessenen Kraft-Verlängerungs-Diagramme der Warmbandprobe Z im Ausgangszustand (linkes Teilbild) und im Zustand nach Auslagerung (rechtes Teilbild);
- Fig. 2
- die gemessenen Kraft-Verlängerungs-Diagramme der Warmbandprobe Y im Ausgangszustand (linkes Teilbild) und im Zustand nach Auslagerung (rechtes Teilbild);
- Fig. 3
- die gemessenen Kraft-Verlängerungs-Diagramme der Warmbandprobe X im Ausgangszustand (linkes Teilbild) und im Zustand nach Auslagerung (rechtes Teilbild);
- Fig. 4
- die gemessenen Kraft-Verlängerungs-Diagramme der Warmbandprobe W im Ausgangszustand (linkes Teilbild) und im Zustand nach Auslagerung (rechtes Teilbild);
- Fig. 5
- die gemessenen Kraft-Verlängerungs-Diagramme der Warmbandprobe V im Ausgangszustand (linkes Teilbild) und im Zustand nach Auslagerung (rechtes Teilbild);
- Fig. 6
- die gemessenen Kraft-Verlängerungs-Diagramme der Warmbandprobe U1 im Ausgangszustand (linkes Teilbild) und im Zustand nach Auslagerung (rechtes Teilbild);
- Fig. 7
- die gemessenen Kraft-Verlängerungs-Diagramme der Warmbandprobe U2 im Ausgangszustand (linkes Teilbild) und im Zustand nach Auslagerung (rechtes Teilbild) für die Probenlagen B, M, G und E.
| Warmband/ Schmelze | Probenlage | ReH N/mm2 | Rm N/mm2 | Fig. | Bemerkung |
| U2 | B | 286 | 385 | 7 | walzfrisch, Banddicke 2.9 mm |
| M | 274 | 382 | 7 | ||
| G | 284 | 389 | 7 | ||
| E | 319 | 407 | 7 |
| Warmband/ Schmelze | ReH N/mm2 | Rm N/mm2 | Banddicke mm |
| T1 | 314 | 374 | 2,09 |
| T2 | 288 | 378 | 2,10 |
| S | 312 | 386 | 3,10 |
| R1 | 308 | 384 | 4,10 |
| R2 | 314 | 374 | 4,20 |
| Q | 311 | 385 | 4,10 |
Claims (1)
- Verfahren zur Herstellung von Umformteilen aus einem coilbreak-freien Warmband von 2 bis 6 mm Dicke mit einer Streckgrenze von weniger als 350 N/mm2 mit zeitlich beständiger Streckgrenzendehnung ohne alternierende Minima und Maxima, hergestellt aus Stahl folgender Zusammensetzung in Gewichtsprozenten:
Rest Eisen und unvermeidliche Verunreinigungen, der im Strang vergossen, eine abgetrennte Bramme von etwa Raumtemperatur auf mindestens 1100°C erwärmt, dann bei Temperaturen oberhalb des Ar3-Punktes zu Warmband fertiggewalzt, schließlich im Temperaturbereich von 550 bis 400°C gehaspelt wird und nach Abhaspelung zu Schneid-, Stanz- oder Biegeteilen maschinell zugerichtet wird, wobeiC 0,02 - 0,08 % Si 0,01 - 0,40 % Mn 0,05 - 1,00 % P 0,002 - 0,025 % S 0,001 - 0,015 % Al 0,015 - 0,080 % N ≦ 0,0080 % Ti >0,04 - 0,080 %
der Titangehalt des Stahles auf mindestens der zur Abbindung des Stickstoffes und weniger als zur zusätzlichen vollständigen Abbindung des Kohlenstoffes stöchiometrisch notwendigen Menge eingestellt wird.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3915445 | 1989-05-09 | ||
| DE3915445 | 1989-05-09 | ||
| PCT/DE1990/000338 WO1990013672A1 (de) | 1989-05-09 | 1990-05-09 | Verfahren zur herstellung von coilbreak-freiem warmband und alterungsbeständigem feuerverzinktem kaltband |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0435968A1 EP0435968A1 (de) | 1991-07-10 |
| EP0435968B1 EP0435968B1 (de) | 1995-08-09 |
| EP0435968B2 true EP0435968B2 (de) | 2002-06-05 |
Family
ID=6380474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP90906870A Expired - Lifetime EP0435968B2 (de) | 1989-05-09 | 1990-05-09 | Verfahren zur herstellung von umformteilen aus coilbreak-freiem warmband |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0435968B2 (de) |
| JP (1) | JPH04500541A (de) |
| AT (1) | ATE126276T1 (de) |
| DE (2) | DE59009505D1 (de) |
| DK (1) | DK0435968T3 (de) |
| ES (1) | ES2075899T3 (de) |
| WO (1) | WO1990013672A1 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2675891C1 (ru) * | 2018-05-22 | 2018-12-25 | Публичное акционерное общество "Северсталь" | Способ производства горячекатаных листов из низколегированной стали класса прочности К60 толщиной до 40 мм |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19543804B4 (de) * | 1995-11-24 | 2004-02-05 | Salzgitter Ag | Verfahren zur Herstellung von feuerverzinktem Stahlband und damit hergestelltes feuerverzinktes Blech oder Band aus Stahl |
| DE19708666A1 (de) * | 1997-03-04 | 1998-09-10 | Schloemann Siemag Ag | Verfahen und Anlage zum Herstellen von Metallband |
| KR20060028909A (ko) * | 2004-09-30 | 2006-04-04 | 주식회사 포스코 | 형상 동결성이 우수한 고강도 냉연강판 및 그 제조방법 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5241209B1 (de) * | 1970-12-19 | 1977-10-17 | ||
| US3947293A (en) * | 1972-01-31 | 1976-03-30 | Nippon Steel Corporation | Method for producing high-strength cold rolled steel sheet |
| JPS5669358A (en) * | 1979-10-18 | 1981-06-10 | Kobe Steel Ltd | Ultra low carbon cold rolled steel sheet with superior press formability |
| DE3603691A1 (de) * | 1986-02-06 | 1987-08-20 | Hoesch Stahl Ag | Alterungsfreier bandstahl |
| US4931106A (en) * | 1987-09-14 | 1990-06-05 | Kawasaki Steel Corporation | Hot rolled steel sheet having high resistances against secondary-work embrittlement and brazing embrittlement and adapted for ultra-deep drawing and a method for producing the same |
| DE3803064C2 (de) * | 1988-01-29 | 1995-04-20 | Preussag Stahl Ag | Kaltgewalztes Blech oder Band und Verfahren zu seiner Herstellung |
-
1990
- 1990-05-09 WO PCT/DE1990/000338 patent/WO1990013672A1/de not_active Ceased
- 1990-05-09 AT AT90906870T patent/ATE126276T1/de active
- 1990-05-09 DE DE59009505T patent/DE59009505D1/de not_active Expired - Fee Related
- 1990-05-09 ES ES90906870T patent/ES2075899T3/es not_active Expired - Lifetime
- 1990-05-09 EP EP90906870A patent/EP0435968B2/de not_active Expired - Lifetime
- 1990-05-09 DE DE4015248A patent/DE4015248A1/de not_active Withdrawn
- 1990-05-09 JP JP2506903A patent/JPH04500541A/ja active Pending
- 1990-05-09 DK DK90906870.2T patent/DK0435968T3/da active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2675891C1 (ru) * | 2018-05-22 | 2018-12-25 | Публичное акционерное общество "Северсталь" | Способ производства горячекатаных листов из низколегированной стали класса прочности К60 толщиной до 40 мм |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH04500541A (ja) | 1992-01-30 |
| EP0435968B1 (de) | 1995-08-09 |
| WO1990013672A1 (de) | 1990-11-15 |
| DE59009505D1 (de) | 1995-09-14 |
| ES2075899T3 (es) | 1995-10-16 |
| EP0435968A1 (de) | 1991-07-10 |
| ATE126276T1 (de) | 1995-08-15 |
| DK0435968T3 (da) | 1995-12-27 |
| DE4015248A1 (de) | 1991-01-03 |
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