EP0400123A1 - Verfahren zum zumischen fliessfähiger zusätze zu polyol und vorrichtung zur durchführung des verfahrens - Google Patents
Verfahren zum zumischen fliessfähiger zusätze zu polyol und vorrichtung zur durchführung des verfahrensInfo
- Publication number
- EP0400123A1 EP0400123A1 EP89912869A EP89912869A EP0400123A1 EP 0400123 A1 EP0400123 A1 EP 0400123A1 EP 89912869 A EP89912869 A EP 89912869A EP 89912869 A EP89912869 A EP 89912869A EP 0400123 A1 EP0400123 A1 EP 0400123A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polyol
- mixing device
- container
- heat exchanger
- tank
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 150000003077 polyols Chemical class 0.000 title claims abstract description 61
- 229920005862 polyol Polymers 0.000 title claims abstract description 59
- 238000000034 method Methods 0.000 title claims abstract description 31
- 239000000654 additive Substances 0.000 title claims abstract description 25
- 238000002156 mixing Methods 0.000 claims abstract description 43
- 230000009969 flowable effect Effects 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 239000006260 foam Substances 0.000 claims description 11
- 230000000996 additive effect Effects 0.000 claims description 5
- 239000000523 sample Substances 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- 229920005830 Polyurethane Foam Polymers 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000011496 polyurethane foam Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 description 6
- 239000004971 Cross linker Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000003431 cross linking reagent Substances 0.000 description 5
- 238000007792 addition Methods 0.000 description 4
- 238000005266 casting Methods 0.000 description 3
- 230000001143 conditioned effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000221013 Viscum album Species 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/49—Mixing systems, i.e. flow charts or diagrams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0005—Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
- B29K2105/0032—Pigments, colouring agents or opacifiyng agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
Definitions
- the invention relates to a method for admixing flowable additives to polyol and a device for carrying out this method according to the features of the preamble of claim 1 and those of the preamble of claim 4.
- Polyol is the starting material for a number of different chemical processes for the preparation or production for the final consumption of certain products, for example for the production of solid plastic articles such as parts of household appliances or shoe soles made of PUR foam.
- polyol is chemically very inert even under normal conditions, so that for processing it must first be mixed with at least one additive to increase its reactivity, which is a so-called crosslinker in the case of articles made from PUR foam. which must be mixed with the polyol before it is combined with isocyanate to form the PUR foam.
- further additions to the polyol may also be necessary, for example in the case of the production of articles from PUR foam, a dye addition. " It has proven to make sense in any case to add the additives to the polyol in the same state of matter as its own, namely the liquid.
- the flowable additives are added to the polyol either directly at the manufacturer of the polyol and / or the additives, the polyol prepared in this way then normally being transported very quickly to the processor must, since the processed polyol usually loses its properties required for further processing within a shorter period of time - after admixing a conventional liquid crosslinking agent, for example within 3 to 6 days - due to chemical reactions, or the processor carries out the admixture according to the strictly observable regulations of the manufacturer (s) immediately before the upcoming processing itself, whereby it is customary in the industry - at least for the producers of solid plastic articles made of PUR foam - that the polyol in general - like that, by the way
- the aforementioned processed polyol is present in 200 1-roll drums and the additives are stored in delivery containers that are designed as a maximum of 200 1-roll drums.
- a 200 1-roll drum to be reprocessed with polyol is first brought to a — elevated — temperature in a heating cabinet, which is selected such that the reprocessed polyol to be produced essentially changes after the admixing is complete used for further processing - for example, by ⁇ the-blending, one Verhetzers in a reaction injection for the production of solid Kunststoff ⁇ fabric articles from .PUR foam - comprising temperature required in that this heated polyol after the opening of the barrel each prescribed quantity filled each Addition is added by hand and the contents of the drum are then subjected to a mixing process over a long period of time by means of an electromechanical agitator which can be displaced vertically, if necessary by hand, in a frame-like holder.
- the polyol prepared in this way is transferred into the so-called day container of the respective device for processing the polyol, for example a reaction casting machine for producing solid plastic articles from PUR foam, this day container generally being a device for maintaining a predetermined one Temperature and on the other hand has an internal agitator.
- this day container generally being a device for maintaining a predetermined one Temperature and on the other hand has an internal agitator.
- the present invention therefore has the task of specifying a method by means of which polyol, with the addition of flowable additives, for example a crosslinking agent liquid and / or a dye solution, largely without the use of human labor and without the risk of unintentional release of chemical substances punching from a delivery container or tank into the day container of a device for processing processed polyols, for example a reaction casting machine for producing solid plastic articles from PUR foam, each additive being made available in its own delivery container.
- the invention has at the same time the object of specifying a device for carrying out the aforementioned method, this device also being intended to meet the requirement for the simplest possible handling and compactness.
- the invention solves this problem with regard to the method with the aid of the features of the characterizing part of patent claim 1 and with regard to the device with the features of the characterizing part of patent claim 4.
- the latter has a recirculation line between the outlet of the heat exchanger and the input area of the mixing device, which allows it during the pause between two discrete refill phases of the day container to recycle the conditioned and tempered polyol present in the mixing device and the heat exchanger - and in the recirculation line - in order to counter the risk of segregation and / or temperature change of this polyol before the subsequent refilling phase.
- Fig. 1 Schematic representation of an inventive device for admixing flowable additives to polyol in section.
- Tank 1 shows a tank 1 which is filled with polyol 2 and a delivery container 3 which contains a crosslinker 4 in a flowable state.
- Tank 1 and delivery container 3 are each connected via a speed-controlled dosing pump 5 with a downstream check valve 6 to a mixing device 7, preferably a static mixer of a known type.
- the mixing device 7 is followed by a heat exchanger 8, in which the polyol 2 mixed with crosslinking agent 4 is adjusted to the temperature of the day container 9, which in turn is connected downstream of the heat exchanger.
- the day container 9 provided with an agitator and a heating device, not shown, is firmer in one of the circuit-like supply lines of a mixing head 10, only indicated here, of a device for reaction casting
- Another check valve 11 is installed between the heat exchanger 8 and the day container 9.
- a recirculation line 12 is arranged between the outlet of the heat exchanger 8 and the input area of the mixing device 7, into which, on the one hand, a recirculation line tion pump 13 and on the other hand a further check valve 14 is integrated.
- a fill level probe of a known type for example a capacitive fill level probe, sends a signal corresponding to a falling below a predetermined minimum fill of the day container 9 to a tax - likewise not shown in FIG. 1 - and outputs control unit of a known type, this causes the metering pumps 5 to be switched on and the recirculation pump 13 to be switched off.
- the operation of the metering pumps 5 now builds up pressure in all of the lines running to the day container, which on the one hand opens the check valves 6 and 11, but closes the check valve 14.
- the conditioned and tempered polyol present in the mixing device and in the heat exchanger at this time is pressed into the day container 9, while at the same time, discrete portions of fresh polyol are fed by the speed-controlled metering pumps 5, which operate at predetermined different speeds and each have the same running time 2 and fresh crosslinker 4 are conveyed into the mixing device 7 in a mutually predetermined fixed ratio.
- the processed polyol which has now been formed by admixing the crosslinker 4 to the polyol 2 passes into the heat exchanger 8, in which it is adjusted to the temperature of the downstream day container 9, in order to pass into the heat exchanger 8 after passing through the heat exchanger 8 this day container 9 to be entered.
- the aforementioned control and regulating unit on the one hand switches off the metering pumps 5 and on the other hand switches on the recirculation pump 13. This creates a pressure profile directed from the day container 9 to the metering pumps 5, which the check valves 6 and 11 closes, the check valve 14 opens.
- FIG. 2 shows a switchover valve 15 between the metering pumps 5 and the check valves 6, which here is shown as a three-way valve for the sake of simplicity, these switchover valves 15 during continuous operation of the metering pumps 5 Polyol 2 from the tank 1 and a crosslinker 4 from the delivery container 3 either
- both the polyol 2 and all flowable additives - for example a crosslinking agent 4 - can be continuously operated in a circuit under constant pressure, this circuit only being interrupted by the changeover valves 15 at a relatively short time, if the
- Mixing device 7 must be loaded.
- the advantage of this procedure is that the adherence to the quantity specifications for the individual components cannot be falsified by the starting and braking processes of the metering pumps 5.
- the recirculation pump 13 acts in the opposite direction to that of the mixing device. direction 7 open state of the changeover valves 15 instead of for driving the metering pumps 5 in the case shown in FIG. 1; the activity of the check valves 11 and 14 remains unchanged.
- the need for the shut-off effect of the check valves 6 is now reduced to the case that one or more metering pumps 5 do not operate at the predetermined speed when the switching valves 15 are open to the mixing device 7 and therefore do not maintain the pressure to be generated by them.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Polyurethanes Or Polyureas (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3838251A DE3838251C1 (enrdf_load_stackoverflow) | 1988-11-11 | 1988-11-11 | |
DE3838251 | 1988-11-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0400123A1 true EP0400123A1 (de) | 1990-12-05 |
Family
ID=6366950
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89912869A Pending EP0400123A1 (de) | 1988-11-11 | 1989-11-08 | Verfahren zum zumischen fliessfähiger zusätze zu polyol und vorrichtung zur durchführung des verfahrens |
EP89120678A Withdrawn EP0368270A1 (de) | 1988-11-11 | 1989-11-08 | Verfahren zum Zumischen fliessfähiger Zusätze zu Polyol und Vorrichtung zur Durchführung des Verfahrens |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP89120678A Withdrawn EP0368270A1 (de) | 1988-11-11 | 1989-11-08 | Verfahren zum Zumischen fliessfähiger Zusätze zu Polyol und Vorrichtung zur Durchführung des Verfahrens |
Country Status (11)
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4211777A1 (de) * | 1991-07-04 | 1993-01-07 | Bayer Ag | Verfahren zum herstellen von elastomeren polyurethanen, insbesondere in form von schuhsohlen |
DE19848780C1 (de) * | 1998-10-22 | 2000-05-25 | Krauss Maffei Kunststofftech | Homogenisier- und Temperierbehälter |
DE20001649U1 (de) * | 2000-01-31 | 2001-06-28 | Wassermann Dental-Maschinen GmbH, 21031 Hamburg | Dosiervorrichtung |
KR100473253B1 (ko) * | 2002-07-24 | 2005-03-10 | 금호타이어 주식회사 | 고무배합용 노화방지제의 공급장치 |
US7059760B2 (en) | 2003-04-02 | 2006-06-13 | Bostik, Inc. | Method of post mixing additives to hot melt adhesives |
FR2877333B1 (fr) * | 2004-11-02 | 2007-09-07 | Snpe Materiaux Energetiques Sa | Procede et dispositif de preparation d'une pate de propergol de type composite |
DE102007014768B4 (de) * | 2007-03-28 | 2016-09-01 | Hennecke Gmbh | Verfahren und Vorrichtung zur Herstellung von Dämmelementen |
JP2009208298A (ja) * | 2008-03-03 | 2009-09-17 | Bridgestone Corp | ゴム組成物の混合方法および混合装置 |
ES2929455T3 (es) * | 2013-03-15 | 2022-11-29 | Basf Se | Método para formar una espuma de poliuretano que incluye la introducción bajo demanda de aditivo al componente de resina y método para formar y pulverizar una espuma de poliuretano que incluye la introducción bajo demanda de aditivo al componente de resina |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1279406A (fr) * | 1960-11-08 | 1961-12-22 | Autocoussin Sa | Procédé et machine pour la fabrication de plastiques cellulaires |
DE2054605C2 (de) * | 1970-11-06 | 1983-08-04 | Fa. Carl Freudenberg, 6940 Weinheim | Vorrichtung zur unterbrochenen, verhältnisgleichen Einspeisung und Vermischung von drei flüssigen Komponenten in eine Mischkammer |
DE2721169C2 (de) * | 1977-05-11 | 1985-12-05 | Draiswerke Gmbh, 6800 Mannheim | Verfahren und Anlage zum Aufbereiten von Thermoplasten oder Duroplasten |
DE3147160A1 (de) * | 1981-11-27 | 1983-06-01 | Bayer Ag, 5090 Leverkusen | Verfahren und einrichtung zum herstellen eines fliessfaehigen, massivstoff oder schaumstoff bildenden reaktionsgemisches |
-
1988
- 1988-11-11 DE DE3838251A patent/DE3838251C1/de not_active Expired - Lifetime
-
1989
- 1989-10-27 PT PT92130A patent/PT92130A/pt unknown
- 1989-11-06 CA CA002002274A patent/CA2002274A1/en not_active Abandoned
- 1989-11-08 EP EP89912869A patent/EP0400123A1/de active Pending
- 1989-11-08 BR BR898907165A patent/BR8907165A/pt unknown
- 1989-11-08 EP EP89120678A patent/EP0368270A1/de not_active Withdrawn
- 1989-11-08 KR KR1019900701447A patent/KR900701491A/ko not_active Withdrawn
- 1989-11-08 DD DD89334381A patent/DD285949A5/de not_active IP Right Cessation
- 1989-11-08 JP JP2500518A patent/JPH03502185A/ja not_active Expired - Lifetime
- 1989-11-08 AU AU45278/89A patent/AU4527889A/en not_active Abandoned
- 1989-11-08 WO PCT/EP1989/001333 patent/WO1990005054A1/de not_active Application Discontinuation
-
1990
- 1990-07-10 DK DK166190A patent/DK166190D0/da not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO9005054A1 * |
Also Published As
Publication number | Publication date |
---|---|
EP0368270A1 (de) | 1990-05-16 |
DK166190A (da) | 1990-07-10 |
PT92130A (pt) | 1990-05-31 |
WO1990005054A1 (de) | 1990-05-17 |
DD285949A5 (de) | 1991-01-10 |
KR900701491A (ko) | 1990-12-03 |
BR8907165A (pt) | 1991-02-26 |
DE3838251C1 (enrdf_load_stackoverflow) | 1990-03-08 |
CA2002274A1 (en) | 1990-05-11 |
DK166190D0 (da) | 1990-07-10 |
AU4527889A (en) | 1990-05-28 |
JPH03502185A (ja) | 1991-05-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
17P | Request for examination filed |
Effective date: 19900720 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE FR GB IT NL |
|
XX | Miscellaneous |
Free format text: VERFAHREN ABGESCHLOSSEN INFOLGE VERBINDUNG MIT 89120678.1/0368270 (EUROPAEISCHE ANMELDENUMMER/VEROEFFENTLICHUNGSNUMMER) VOM 27.02.91. |