EP0392353B1 - Dispersions aqueuses de résines - Google Patents
Dispersions aqueuses de résines Download PDFInfo
- Publication number
- EP0392353B1 EP0392353B1 EP90106518A EP90106518A EP0392353B1 EP 0392353 B1 EP0392353 B1 EP 0392353B1 EP 90106518 A EP90106518 A EP 90106518A EP 90106518 A EP90106518 A EP 90106518A EP 0392353 B1 EP0392353 B1 EP 0392353B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polymer
- weight
- aqueous
- dispersion
- synthetic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000006185 dispersion Substances 0.000 title claims description 46
- 239000011347 resin Substances 0.000 title 1
- 229920005989 resin Polymers 0.000 title 1
- 239000004745 nonwoven fabric Substances 0.000 claims description 32
- 229920000642 polymer Polymers 0.000 claims description 30
- 229920003002 synthetic resin Polymers 0.000 claims description 22
- 239000000057 synthetic resin Substances 0.000 claims description 22
- 239000000178 monomer Substances 0.000 claims description 17
- 239000000835 fiber Substances 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 239000011230 binding agent Substances 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- 230000009477 glass transition Effects 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- NPWGWQRXHVJJRD-UHFFFAOYSA-N N-hydroxyglycine Chemical class ONCC(O)=O NPWGWQRXHVJJRD-UHFFFAOYSA-N 0.000 claims description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 238000007789 sealing Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- -1 aliphatic monocarboxylic acids Chemical class 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000007720 emulsion polymerization reaction Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 150000002763 monocarboxylic acids Chemical class 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 229920001567 vinyl ester resin Polymers 0.000 description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- NEYTXADIGVEHQD-UHFFFAOYSA-N 2-hydroxy-2-(prop-2-enoylamino)acetic acid Chemical compound OC(=O)C(O)NC(=O)C=C NEYTXADIGVEHQD-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000005396 acrylic acid ester group Chemical group 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 0 *C(*)NC(C(*)=C)=O Chemical compound *C(*)NC(C(*)=C)=O 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical class ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical class CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000035508 accumulation Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 150000001470 diamides Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000120 polyethyl acrylate Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical class C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- ZIGVUIYVPLQEAL-UHFFFAOYSA-M sodium;2-tetradecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O ZIGVUIYVPLQEAL-UHFFFAOYSA-M 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- AYFACLKQYVTXNS-UHFFFAOYSA-M sodium;tetradecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCS([O-])(=O)=O AYFACLKQYVTXNS-UHFFFAOYSA-M 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
Definitions
- the N-hydroxycarboxymethylamides of acrylic and / or methacrylic acid are only moderately water-soluble, their water-soluble alkali metal or ammonium salts, in particular their sodium and potassium salts, are preferably used for the preparation of aqueous solutions of the polymers B.
- the polymerization is particularly preferably carried out in aqueous solutions which contain mixtures of free acids and their corresponding alkali metal or ammonium salts and preferably have a pH of 2 to 7, particularly preferably 2 to 4.
- the effectiveness of the polymers B is not significantly impaired, since they additionally contain water-soluble monomers such as acrylic acid, methacrylic acid or their amides in copolymerized form in amounts of up to 20% of their weight.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Graft Or Block Polymers (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paper (AREA)
Claims (3)
- Dispersions aqueuses de résines synthétiques, que l'on peut obtenir par le fait de réunir une dispersion aqueuse de départ d'un polymère A, qui possède une température de transition vitreuse de -50 à +60°C et qui est constitué de monomères monoéthyléniquement insaturés, qui, exception faite de radicaux carboxyle et de leurs dérivés, ne portent pas de groupements polymérisables ou mutuellement condensables supplémentaires et éventuellement de butadiène et une solution aqueuse d'un polymère B, qui est essentiellement constitué de N-hydroxycarboxyméthylamides de l'acide acrylique et/ou de l'acide méthacrylique et/ou de sels solubles dans l'eau de ces N-hydroxycarboxyméthylamides, au début, au cours et/ou après la réalisation de la préparation de la dispersion aqueuse de départ, avec la condition que la proportion de matière solide du polymère B, rapportée à la quantité totale de polymère A et de polymère B, atteigne 0,5 à 10°% en poids.
- Procédé de préparation de dispersions aqueuse de résines synthétiques suivant la revendication 1, caractérisé en ce qu'au début, au cours et/ou après la réalisation de la préparation d'une dispersion aqueuse de départ d'un polyamide A, on réunit cette dispersion de départ et une solution aqueuse d'un polymère B avec la condition que la proportion de substance solide du polymère B, rapportée à la quantité totale de polymère A et de polymère B, atteigne 0,5 à 10% en poids.
- Utilisation de dispersions aqueuses de résines synthétiques suivant la revendication 1, à titre de liants pour la fabrication de nappes de mats de fibres.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3911942A DE3911942A1 (de) | 1989-04-12 | 1989-04-12 | Waessrige kunstharzdispersionen |
DE3911942 | 1989-04-12 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0392353A2 EP0392353A2 (fr) | 1990-10-17 |
EP0392353A3 EP0392353A3 (fr) | 1991-08-07 |
EP0392353B1 true EP0392353B1 (fr) | 1994-03-23 |
Family
ID=6378476
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90106518A Expired - Lifetime EP0392353B1 (fr) | 1989-04-12 | 1990-04-05 | Dispersions aqueuses de résines |
Country Status (9)
Country | Link |
---|---|
US (1) | US5081178A (fr) |
EP (1) | EP0392353B1 (fr) |
JP (1) | JPH02294334A (fr) |
CA (1) | CA2013061A1 (fr) |
DE (2) | DE3911942A1 (fr) |
DK (1) | DK0392353T3 (fr) |
ES (1) | ES2062150T3 (fr) |
FI (1) | FI98919C (fr) |
NO (1) | NO176718C (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7399818B2 (en) | 2004-03-16 | 2008-07-15 | Rohm And Haas Company | Curable composition and use thereof |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7008634B2 (en) * | 1995-03-03 | 2006-03-07 | Massachusetts Institute Of Technology | Cell growth substrates with tethered cell growth effector molecules |
US5910533A (en) * | 1997-08-04 | 1999-06-08 | Reichhold Chemicals, Inc. | Elastomeric material for rubber articles |
PT1038433E (pt) | 1999-03-19 | 2008-09-11 | Saint Gobain Cultilene B V | Substrato de cultura fora-solo |
US6369154B1 (en) | 1999-07-26 | 2002-04-09 | Reichhold, Inc. | Compositions suitable for making elastomeric articles of manufacture |
DE102005037113A1 (de) * | 2005-08-03 | 2007-02-08 | Basf Ag | Verwendung einer thermisch härtbaren wässrigen Zusammensetzung als Bindemittel für Substrate |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4167501A (en) * | 1978-04-13 | 1979-09-11 | Dow Corning Corporation | Process for preparing a textile-treating composition and resin-silicone compositions therefor |
DE2920377A1 (de) * | 1979-05-19 | 1980-12-04 | Basf Ag | Binde-, impraegnier- und ueberzugsmittel auf basis einer waessrigen dispersion eines amidgruppenhaltigen copolymerisats |
US4774283A (en) * | 1987-03-02 | 1988-09-27 | Air Products And Chemicals, Inc. | Nonwoven binders of vinyl acetate/ethylene/self-crosslinking monomers/acrylamide copolymers having improved blocking resistance |
EP0302588A3 (fr) * | 1987-07-31 | 1990-02-28 | Reichhold Chemicals, Inc. | Liant pour étoffes non tissées ne dégageant pas de formaldéhyde |
DE3734752A1 (de) * | 1987-10-14 | 1989-05-03 | Basf Ag | Verfahren zur herstellung von waessrigen (meth)acrylsaeureester-copolymer-dispersionen in zwei stufen und deren verwendung als impraegnier-, ueberzugs- und bindemittel fuer flaechige fasergebilde |
-
1989
- 1989-04-12 DE DE3911942A patent/DE3911942A1/de not_active Withdrawn
-
1990
- 1990-03-26 CA CA002013061A patent/CA2013061A1/fr not_active Abandoned
- 1990-04-04 US US07/503,925 patent/US5081178A/en not_active Expired - Fee Related
- 1990-04-05 EP EP90106518A patent/EP0392353B1/fr not_active Expired - Lifetime
- 1990-04-05 DE DE90106518T patent/DE59005048D1/de not_active Expired - Lifetime
- 1990-04-05 DK DK90106518.5T patent/DK0392353T3/da active
- 1990-04-05 ES ES90106518T patent/ES2062150T3/es not_active Expired - Lifetime
- 1990-04-09 JP JP2092363A patent/JPH02294334A/ja active Pending
- 1990-04-10 FI FI901813A patent/FI98919C/fi not_active IP Right Cessation
- 1990-04-10 NO NO901629A patent/NO176718C/no unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7399818B2 (en) | 2004-03-16 | 2008-07-15 | Rohm And Haas Company | Curable composition and use thereof |
Also Published As
Publication number | Publication date |
---|---|
EP0392353A2 (fr) | 1990-10-17 |
NO176718C (no) | 1995-05-16 |
FI98919C (fi) | 1997-09-10 |
FI98919B (fi) | 1997-05-30 |
DE3911942A1 (de) | 1990-10-18 |
CA2013061A1 (fr) | 1990-10-12 |
DK0392353T3 (da) | 1994-04-11 |
JPH02294334A (ja) | 1990-12-05 |
NO901629D0 (no) | 1990-04-10 |
NO901629L (no) | 1990-10-15 |
FI901813A0 (fi) | 1990-04-10 |
EP0392353A3 (fr) | 1991-08-07 |
DE59005048D1 (de) | 1994-04-28 |
ES2062150T3 (es) | 1994-12-16 |
US5081178A (en) | 1992-01-14 |
NO176718B (no) | 1995-02-06 |
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